Using Oxygen Enriched Gas Or Oxidizing Atmosphere (i.e., Other Than Air, Per Se) Patents (Class 264/648)
  • Patent number: 10840668
    Abstract: A transparent ceramic optic includes: a lasing region comprising at least one lasing species dopant; and a transparent region transparent to light generated by the lasing species. At least the transparent region is doped with at least one other dopant species such that the lasing region and the transparent region are characterized by a difference in refractive index between the two regions in an amount of about 1.0×10?4 or less. Inventive formulations of inks suitable for fabricating transparent ceramic optics having desirable compositional characteristics such as concentration gradients in desired spatial arrangements, e.g. using additive manufacturing techniques such as direct ink writing and/or extrusion freeform fabrication are also disclosed, along with suitable techniques for forming the transparent ceramic optics from such inks.
    Type: Grant
    Filed: June 16, 2017
    Date of Patent: November 17, 2020
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: Stephen A. Payne, Nerine J. Cherepy, Eric B. Duoss, Ivy Krystal Jones, Zachary M. Seeley, Cheng Zhu
  • Patent number: 10804033
    Abstract: The object of the present invention is to provide a dielectric ceramic composition having good properties, particularly good IR property and high temperature accelerated lifetime. The dielectric ceramic composition of the present invention has a main component made of a perovskite type compound expressed by a compositional formula of (Ba1-x-ySrxCay)m(Ti1-zZrz)O3 (note that, m, x, y, and z of the above compositional formula all represent molar ratios, and each satisfies 0.9?m?1.1, 0?x?0.5, 0?y?0.3, 0?(x+y)?0.6, and 0.03?z?0.
    Type: Grant
    Filed: December 21, 2018
    Date of Patent: October 13, 2020
    Assignee: TDK CORPORATION
    Inventors: Dan Sakurai, Toshihiko Kaneko, Nobuto Morigasaki, Toshinari Takahashi, Yasuhiro Ito
  • Publication number: 20140145185
    Abstract: A sputtering target including a sintered body including In, Ga and Mg, the sintered body including one or more compounds selected from a compound represented by In2O3, a compound represented by In(GaMg)O4, a compound represented by Ga2MgO4 and a compound represented by In2MgO4, and having an atomic ratio In/(In+Ga+Mg) of 0.5 or more and 0.9999 or less and an atomic ratio (Ga+Mg)/(In+Ga+Mg) of 0.0001 or more and 0.5 or less.
    Type: Application
    Filed: June 28, 2012
    Publication date: May 29, 2014
    Inventors: Kazuaki Ebata, Shigekazu Tomai, Kota Terai, Shigeo Matsuzaki, Koki Yano
  • Publication number: 20140128243
    Abstract: Porous composites of acicular mullite and tialite are formed by firing an acicular mullite body in the presence of an oxide of titanium. In some variations of the process, the oxide of titanium is present when the acicular mullite body is formed. In other variations, the oxide of titanium is applied to a previously-formed acicular mullite body. Surprisingly, the composites have coefficients of linear thermal expansion that are intermediate to those of acicular mullite and tialite alone. Some of the tialite is believed to form at grain boundaries and/or points of intersection between acicular mullite needles, rather than merely coating the needles. The presence of the titanium oxide(s) during acicular mullite formation does not significantly affect the ability to produce a highly porous network of mullite needles.
    Type: Application
    Filed: March 29, 2012
    Publication date: May 8, 2014
    Applicant: Dow Global Technologies LLC
    Inventors: Daniel Grohol, Mark L. Dreibelbis, Michael T. Malanga
  • Publication number: 20130140502
    Abstract: An oxide sintered body including an oxide of indium (In), gallium (Ga), and positive trivalent and/or positive tetravalent metal X, wherein the amount of the metal X relative to the total amount of In and Ga is 100 to 10000 ppm (weight).
    Type: Application
    Filed: June 1, 2011
    Publication date: June 6, 2013
    Inventors: Shigekazu Tomai, Kazuaki Ebata, Shigeo Matsuzaki, Koki Yano
  • Publication number: 20130082218
    Abstract: An oxide sintered body including an oxide of indium and aluminum and having an atomic ratio Al/(Al+In) of 0.01 to 0.08.
    Type: Application
    Filed: May 24, 2011
    Publication date: April 4, 2013
    Inventors: Kazuaki Ebata, Shigekazu Tomai, Koki Yano, Kazuyoshi Inoue
  • Publication number: 20130037998
    Abstract: A high energy density multilayer ceramic capacitor, having at least two electrode layers and at least one substantially dense polycrystalline dielectric layer positioned therebetween. The at polycrystalline dielectric layer has an average grain size of less than about 300 nanometers, a particle size distribution of between about 150 nanometers and about 3 micrometers, and a maximum porosity of about 1 percent. The dielectric layer is selected from the group including TiO2, BaTiO3, Al2O3, ZrO2, lead zirconium titanate, and combinations thereof and has a breakdown strength of at least about 1100 kV per centimeter.
    Type: Application
    Filed: March 19, 2012
    Publication date: February 14, 2013
    Inventor: Fatih Dogan
  • Publication number: 20120091389
    Abstract: A process for the preparation of a niobium compound of formula (I): D?Nb?E?O3-???(I) wherein D is an alkali metal (e.g. Li, Na, K, Rb, Cs and/or Fr), alkaline earth metal (such as Ba, Ca, Mg and/or Sr), La and/or Bi and may be present as a mixture of two or more metals; E is Ta, Sb and/or Fe and may be present as a mixture of two or more metals; ? is a positive number ? is a positive number ? is zero or a positive number ? is a number 0???0.5; and wherein the formula (I) has the perovskite or tungsten bronze structure; comprising spray pyrolising a solution, for example an aqueous solution, comprising metal (D) ions, Nb ions and if present, metal (E) ions.
    Type: Application
    Filed: March 4, 2010
    Publication date: April 19, 2012
    Applicant: CERPOTECH AS
    Inventors: Francesco Madaro, Tor Grande, MariAnn Einarsrud, Kjell Wiik
  • Patent number: 8052918
    Abstract: A method of producing a carbon-based material having an activated surface includes: (a) mixing an elastomer and a carbon material, and dispersing the carbon material by applying a shear force to obtain a composite elastomer; and (b) heat-treating the composite elastomer at a temperature for vaporising an elastomer to vaporize the elastomer in the composite elastomer.
    Type: Grant
    Filed: July 19, 2005
    Date of Patent: November 8, 2011
    Assignee: Nissin Kogyo Co., Ltd.
    Inventors: Akira Magario, Toru Noguchi
  • Publication number: 20100294657
    Abstract: Provided is a polycrystal MgO sintered body which is capable of having a sintered density close to a theoretical density thereof, and exhibiting excellent mechanical properties and heat conductivity, while reducing contamination of an atmosphere due to gas generation, and a production method for the sintered body. The polycrystal MgO sintered body has a unique crystalline anisotropy in which (111) faces are oriented along a surface applied with a uniaxial pressure at a high rate. The polycrystalline MgO sintered body is obtained by a method which comprises the steps of: sintering an MgO raw material powder having a particle size of 1 ?m or less, under a uniaxial pressure; and then subjecting the sintered powder to a heat treatment under an atmosphere containing 0.05 volume % or more of oxygen, at a temperature of 1273 K or more for 1 minute or more.
    Type: Application
    Filed: January 27, 2009
    Publication date: November 25, 2010
    Applicants: NIPPON TUNGSTEN CO., LTD., UBE MATERIAL INDUSTRIES, LTD.
    Inventors: Mitsuyoshi Nagano, Masanobu Takasu, Yo Arita, Satoru Sano
  • Publication number: 20100176541
    Abstract: Disclosed herein is a composition comprising 50 to 73% by weight of loess, 9 to 20% by weight of clay, 3 to 10% by weight of wood flour, 3 to 7% by weight of lignum carbonized carbon body powder, 11 to 15% by weight of water and 1 to 5% by weight of ceramic glaze to manufacture a ceramic moulding including a carbon layer therein. Preferably, the composition according to the present invention further comprises elvan powder and Schmotte. Meanwhile, the present invention also provides a method of manufacturing a ceramic moulding with a carbon layer comprising forming a moulding out of the composition and firing the formed moulding with oxidizing flames.
    Type: Application
    Filed: April 13, 2007
    Publication date: July 15, 2010
    Inventor: Koo-Han Kim
  • Patent number: 7378050
    Abstract: A ceramic material powder for a translucent ceramic is molded with a binder, and the resulting green compact is embedded in a ceramic powder having the same composition with the ceramic material powder. After removing the binder, the green compact embedded in the ceramic powder is fired in an atmosphere having an oxygen concentration higher than that in the removal procedure of the binder and thereby yields a translucent ceramic represented by Formula I: Ba{(SnuZr1-u)xMgyTaz}vOw, Formula II: Ba(ZrxMgyTaz)vOw or Formula III: Ba{(SnuZr1-u)x(ZntMg1-t)yNbz}vOw. The translucent ceramic has a refractive index of 1.9 or more and is paraelectric.
    Type: Grant
    Filed: October 21, 2004
    Date of Patent: May 27, 2008
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Nobuhiko Tanaka, Yukio Higuchi, Masayoshi Katsube, Mitsuru Sube
  • Patent number: 7238319
    Abstract: A method for fabricating a green ceramic article containing organic compounds. The method involves first heating the green ceramic article to sequentially remove the organic compounds such that the organic compound with the lowest weight loss onset temperature is substantially removed prior to the next higher weight loss onset temperature organic compound. The organic compounds include but are not limited to at least an oil or oil-based compound having a flash point or an ignition temperature, higher than the weight loss onset temperature. For this system the temperature during heating is maintained below the flash point of the oil or oil-based compound until substantial removal thereof from the green ceramic structural body. After the organic compounds are substantially removed, the green ceramic article is further fired to a temperature and for a time to obtain a final fired body.
    Type: Grant
    Filed: June 26, 2003
    Date of Patent: July 3, 2007
    Assignee: Corning Incorporated
    Inventors: John H. Brennan, Gregory P. Dillon, Tudor C. Gheorghiu, Michael J. Vayansky
  • Patent number: 7141327
    Abstract: A solid electrolyte fuel cell including a protonic oxide conductor having a composition represented by Ba(Zr1?xCex)1?yMyAlzO3?? (M: one or more kinds of elements selected from a group of tri-valent rare earth elements and In, 1?x?0, 0.3>y>0, 0.04>z?0, and 1.5>?>0); and an electrode that is mainly made of platinum and has catalysis properties; wherein an electrolyte has a film thickness of 300 ?m or less, and a method of manufacturing the same are disclosed. The solid electrolyte fuel cell can obtain a cell output even at low temperatures equal to 500 degrees centigrade or less.
    Type: Grant
    Filed: June 4, 2003
    Date of Patent: November 28, 2006
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Noboru Taniguchi
  • Patent number: 6815384
    Abstract: The method for manufacturing a sintered piece comprises preparing a molded piece of a composite including calcium phosphate compound such as hydroxyapatite, and baking the molded piece in an oxygen atmosphere to obtain the sintered piece. The oxygen concentration of the oxygen atmosphere is controlled to be not less than 25 vol %, and the relative humidity of the oxygen atmosphere is controlled to be below 30% RH. The baking is performed for 30 minutes to 8 hours at a temperature not less than 1000° C. and below a temperature at which thermal decomposition of the calcium phosphate occurs.
    Type: Grant
    Filed: November 8, 2002
    Date of Patent: November 9, 2004
    Assignee: PENTAX Corporation
    Inventor: Tsuyoshi Ishikawa
  • Patent number: 6787074
    Abstract: A method of removing substantially all of the volatile component in a green, volatile-containing ceramic article is disclosed. The method comprises freezing the ceramic article; and then subjecting the frozen article to a vacuum for a sufficient time to freeze-dry the article. Frequently, the article is heated while being freeze-dried. Use of this method efficiently reduces the propensity for any warpage of the article. The article is often formed from a ceramic slurry in a gel-casting process. A method for fabricating a ceramic core used in investment casting is also described.
    Type: Grant
    Filed: February 5, 2002
    Date of Patent: September 7, 2004
    Assignee: General Electric Company
    Inventors: Frederic Joseph Klug, Sylvia Marie DeCarr
  • Patent number: 6461562
    Abstract: Methods of making metal oxide articles, preferably iron oxide articles, and articles thereby produced. The method comprises the steps of slightly pressing powder to a compact, the powder consisting essentially of a first oxide of the metal; and subjecting the compact to a heat treatment that causes the powder to sinter into a unitary body and results in the transformation of at least a portion of the first oxide to a second oxide by oxidation or deoxidation during the heat treatment. In disclosed embodiments, the heat treatment is conducted either in air at atmospheric pressure or at a subatmospheric pressure. The method optionally includes more heating/cooling steps resulting in additional oxidation/deoxidation cycles. Sintered iron oxide articles of the invention have high mechanical strengths and interconnected pore structures, providing for efficient filtering of liquids and gases.
    Type: Grant
    Filed: February 17, 1999
    Date of Patent: October 8, 2002
    Assignee: American Scientific Materials Technologies, LP
    Inventors: Konstantin Solntsev, Eugene Shustorovich, Sergei Myasoedov, Vyacheslav Morgunov, Andrei Chernyavsky, Yuri Buslaev, Richard Montano, Alexander Shustorovich
  • Patent number: 6432353
    Abstract: A ceramic molded body obtained by molding a raw material powder having a mean grain size of about 1 &mgr;m or less and a BET specific surface area of about 5 m2/g or more is fired in an atmosphere of about 95% or higher oxygen concentration at a temperature higher than an ordinary firing temperature for a time shorter than an ordinary time, whereby the sintering can be completed in a short time.
    Type: Grant
    Filed: December 9, 1999
    Date of Patent: August 13, 2002
    Assignee: Murata Manufacturing Co., Ltd.
    Inventor: Nobuhiko Michiura
  • Patent number: 6368525
    Abstract: A method of removing substantially all of the volatile component in a green, volatile-containing ceramic article is disclosed. The method comprises freezing the ceramic article; and then subjecting the frozen article to a vacuum for a sufficient time to freeze-dry the article. Frequently, the article is heated while being freeze-dried. Use of this method efficiently reduces the propensity for any warpage of the article. The article is often formed from a ceramic slurry in a gel-casting process. A method for fabricating a ceramic core used in investment casting is also described.
    Type: Grant
    Filed: February 7, 2000
    Date of Patent: April 9, 2002
    Assignee: General Electric Company
    Inventors: Frederic Joseph Klug, Sylvia Marie DeCarr
  • Patent number: 6251335
    Abstract: The process incorporating the invention enables fabrication of dense, highly textured (fraction of oriented grains >20 vol. %) alumina. The method uses a mixture of aluminum metal powder, alumina powder, tabular alumina grains and a liquid phase former. A dry powder mixtures of these components is compacted by dry forming techniques such as roll compaction, uniaxial pressing, forging and/or double action pressing. The formed part is then heated at 0.5-10° C./min. to a temperature between 450 and 500° C. and is held for 2-15 h, and is then heated at 1-10° C/min. to 900-1070° C. and is held for 2-10 hours to convert the aluminum particles into alumina. The part is then heated to a higher temperature (>1400° C.) to form a liquid phase which assists densification and promotes the growth of the tabular alumina grains. The aspect ratio range of the textured alumina grains is from 2-14.
    Type: Grant
    Filed: April 30, 1999
    Date of Patent: June 26, 2001
    Assignee: The Penn State Research Foundation
    Inventors: Gary L. Messing, Ender Suvaci
  • Patent number: 6093366
    Abstract: The present invention provides a ceramic sintered body excellent in oxidation resistance under high temperatures and markedly superior to the conventional ceramic sintered body in the mechanical strength over a wide temperature range of between room temperature and 1,500.degree. C. The ceramic sintered body of the present invention comprises at least one ceramic crystal grain selected from the group consisting essentially of a monosilicate represented by the general formula RE.sub.2 SiO.sub.5, where RE denotes a IIIa group element including yttrium, and a disilicate represented by the general formula RE.sub.2 Si.sub.2 O.sub.7, where RE denotes a IIIa group element including yttrium, and at least one additional element selected from the group consisting of Al, Cr, Hf, Nb, Zr, Ti, V, Ta, Ca and Mg which is segregated in the boundaries of the ceramic crystal grains in an amount of 0.1 to 15% by weight of the sintered body in terms of the oxide thereof.
    Type: Grant
    Filed: November 5, 1998
    Date of Patent: July 25, 2000
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Masahiro Kato, Yasuhiro Goto, Takayuki Fukasawa, Toshiaki Mizutani
  • Patent number: 5928979
    Abstract: The present invention relates to ceramics and a method for making ceramics having very little dimensional change after sintering and high dimensional accuracies, so that the characteristics of inorganic functional material are fully maintained and utilized. The ceramics of the present invention comprise grains of inorganic functional material and grains of complex oxide. The pores existing between said grains of inorganic functional material are filled with said grains of complex oxide produced by a sintering reaction between an oxidized metal and an inorganic compound.
    Type: Grant
    Filed: January 30, 1998
    Date of Patent: July 27, 1999
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Tsutomu Inuzuka, Shinji Harada, Yuji Mido, Tadashi Tojyo, Satoshi Tomioka
  • Patent number: 5854154
    Abstract: An oxide ceramic composite suitable for fabricating components of combustion turbines and similar high temperature environments. The composite is fabricated by dispersing metal particles in a fiber preform and infiltrating the fiber preform with sol-gel matrix precursor material. Alternatively, the metal particles are mixed into the sol-gel matrix precursor material and the preform is infiltrated with the mixture. Later in the fabrication process, the metal particles oxidize and become oxidized metal when the sol-gel matrix precursor material is sintered. The oxidized metal has more volume and mass than the metal particles. As a result, the oxidized metal contributes to increasing the density of the composite so that it is suitable for use in combustion turbines and similar high temperature environments.
    Type: Grant
    Filed: May 1, 1997
    Date of Patent: December 29, 1998
    Assignee: Westinghouse Electric Corporation
    Inventors: Kenneth Charles Radford, Jay Edgar Lane
  • Patent number: 5854158
    Abstract: A ZrO.sub.2 based ceramic material having excellent mechanical strength and fracture toughness comprises a first phase of ZrO.sub.2 grains containing CeO.sub.2 as a stabilizer and having an average grain size of 5 .mu.m or less, a second phase of Al.sub.2 O.sub.3 grains having an average grain size of 2 .mu.m or less, and a third phase of elongated crystals of a complex oxide of Al, Ce, and one of Mg and Ca. At least 90 vol % of the first phase is composed of tetragonal ZrO.sub.2. An aluminum (Al) content in the ceramic material is determined such that when Al of the complex oxide is converted to Al.sub.2 O.sub.3, a total amount of Al.sub.2 O.sub.3 in the ceramic material is within a range of 0.5 to 50 vol %. A content of the third phase in the ceramic material is determined within a range of 0.5 to 5 by area %. It is preferred that fine Al.sub.2 O.sub.3 grains having an average grain size of 1 .mu.m or less of the second phase are dispersed within the ZrO.sub.2 grains at a dispersion ratio of at least 2%.
    Type: Grant
    Filed: June 11, 1997
    Date of Patent: December 29, 1998
    Assignee: Matsushita Electric Works, Ltd.
    Inventors: Masahiro Nawa, Shoichi Nakamoto, Koichi Niihara, Tohru Sekino
  • Patent number: 5702650
    Abstract: A process for producing ceramic dental prostheses, with which ceramic dental prostheses may be produced in the same diversity of shapes and with the same accuracy as metal dental prostheses. The process includes shaping an unfinished piece made out of 92.1 to 93.5 wt. % zirconium oxide, 4.5 to 5.5 wt. % yttrium oxide, 1.8 to 2.2 wt. % hafnium oxide, and reworking the piece to form a dental prosthesis by means of a rotating tool made of metal-bonded diamond grains.
    Type: Grant
    Filed: March 4, 1996
    Date of Patent: December 30, 1997
    Inventor: Josef Hintersehr
  • Patent number: 5635121
    Abstract: Making denser ceramic sinters by carrying out the sintering operation at elevated temperatures and in 100% oxygen at a pressure of at least 1.5 atmospheres, and then cooling the sinter without control of the ambient atmosphere. The product has a bulk density of at least 98% of the theoretical density of the sinter.
    Type: Grant
    Filed: March 6, 1995
    Date of Patent: June 3, 1997
    Assignee: Alpha Industries
    Inventor: Robert L. Huntt