Abstract: A ceramic slurry composition has a powdered ceramic uniformly dispersed therein without excessive damage thereto. A method for producing a ceramic green sheet using the ceramic slurry composition and a method for producing multilayer ceramic electronic devices are also disclosed. The ceramic slurry composition contains the powdered ceramic, a dispersing agent, a binder and a solvent, in which an anionic dispersing agent is used as the dispersing agent, and the content of the anionic dispersing agent is set to be such that the total acid content thereof corresponds to about 10 to 150% of the total base content of the powdered ceramic. In addition, the powdered ceramic having an average particle diameter of about 0.01 to 1 ?m is used.

Abstract: Methods for changing the shape of a surface of an article are disclosed. The methods may include providing a liquid polymer precursor, casting the precursor against a first tool assembly, curing the precursor to form a shape memory polymer substrate, deforming one or more surfaces of the substrate, and mobilizing the shape memory polymer to shift the deformed surface of the substrate from a deformed shape to a pre-set shape.

Abstract: There is provided a production process of a sheet-like dense cordierite sintered body which hardly generates cracks when dried and sintered, and has excellent formability. A production process of a sheet-like dense cordierite sintered body which has a step of forming a raw material containing cordierite powders having an average particle size of greater than 2 ?m but not greater than 4 ?m into a cordierite green sheet; and sintering the cordierite green sheet at from 1350 to 1450° C.

Abstract: Recycled ceramic slurry is produced by a method including the steps: dissolving the waste material of unfired ceramic in a solvent to form a waste solution; and adjusting a composition of the waste solution to thereby produce the recycled ceramic slurry. If the waste material of unfired ceramic includes a metal component, the metal component may be removed therefrom before the step of adjusting the composition of the waste solution.

Abstract: A capacitive vacuum measuring cell includes first and second ceramic housing bodies (1, 4) joined by an edge seal (3). A thin ceramic membrane (2) is supported between first and second housing bodies (1, 4) by the edge seal (3) at a small distance from the first housing body (1) creating a reference vacuum chamber (25) therebetween. An electrically conductive material (7) coats opposing surfaces of the first housing body (1) and the membrane (2) to form a capacitor. A measurement vacuum chamber (26) is provided between the membrane (2) and the second housing body (4). A port (5) communicates with the second housing body (4) to connect the measurement vacuum chamber (26) of the measuring cell to the medium to be measured. The membrane (2) is made from an Al2O3 slurry that is sintered in a first heating step, cooled, and then reheated to smooth the membrane.

Abstract: A method of production of a ceramic electronic device such as a multilayer ceramic capacitor, comprising forming a first ceramic coating layer on the surface of a substrate, forming an internal electrode on the surface of the first ceramic coating layer, then forming a second ceramic coating layer on the surface of the first ceramic coating layer so as to cover the internal electrode. In this case, when a mean particle size of ceramic particles of the first ceramic coating layer is ?1, a thickness of the first ceramic coating layer is T1, a mean particle size of ceramic particles of the second ceramic coating layer is ?2, and a thickness of the second ceramic coating layer is T2, the conditions of ?1??2, 0.05<?1?0.35 ?m, T1<T2, and 0<T1<1.5 ?m are satisfied. As a result, it is possible to provide a ceramic electronic device, in particular a multilayer ceramic capacitor, resistant to short-circuit defects, withstand voltage defects, and other structural defects.

Abstract: The production of low-loss, tunable composite ceramic materials with improved breakdown strengths is disclosed. The composite materials comprise ferroelectric perovskites such as barium strontium titanate or other ferroelectric perovskites combined with other phases such as low-loss silicate materials and/or other low-loss oxides. The composite materials are produced in sheet or tape form by methods such as tape casting. The composite tapes exhibit favorable tunability, low loss and tailorable dielectric properties, and can be used in various microwave devices.

Abstract: A thermochemically stable oxidic thermal insulating material presenting phase stability, which can be used advantageously as a thermal insulating layer on parts subjected to high thermal stress, such as turbine blades or such like. The thermal insulating material can be processed by plasma spraying and consists preferably of a magnetoplumbite phase whose preferred composition is MMeAl11O19, where M is La or Nd and where Me is chosen from among zinc, the alkaline earth metals, transition metals, and rare earths, preferably from magnesium, zinc, cobalt, manganese, iron, nickel and chromium.

Abstract: The present invention relates to filtration media having both hydrophobic (water-repellent) properties. The filtration media are produced using a fluorothermoplastic material, such as a terpolymer of tetrafluoroethylene, vinylidene fluoride, and hexafluoropropylene. The invention also relates to methods of preparing such filtration media using casting solution phase inversion.

Abstract: A method for forming plate-like ceramic articles, comprising at least one step for deposition by pouring of at least one layer of a ceramic mixture that comprises an aqueous vehicle on a substantially absorbent transfer surface adapted to draw the aqueous vehicle, at least one step for drying so as to obtain a continuous material strand, and a cutting step for cutting the strand into a plurality of ceramic articles. An apparatus for performing the method comprising a framework for supporting an absorbent transfer surface, at least one unit for depositing at least one mixture layer onto the surface, at least one drying unit for at least partial drying of the mixture layer to obtain a continuous strand of plastic ceramic material, and a cutting unit.

Abstract: A method for producing high-alumina bodies with superior chemical properties at reduced sintering temperatures, including the steps of providing an alumina powder precursor, adding about 4 weight percent magnesia powder precursor, homogenizing the resultant green powder precursor, pressing a green body from the green powder precursor, removing residual moisture and organic material from the green body, and firing the green body to about cone 13, wherein the resulting high-alumina body is substantially non-vitreous, has a substantially uniformly sized grain structure, is very resistant to dissolution in molten aluminum, and has superior resistance to chemical attack over substantially the entire pH range.

Abstract: A method to make thick or thin films a very low cost. The method is generally similar to the conventional tape casting techniques while being more flexible and versatile. The invention involves preparing a slip (solution) of desired material and including solvents such as ethanol and an appropriate dispersant to prevent agglomeration. The slip is then sprayed on a substrate to be coated using an atomizer which spreads the slip in a fine mist. Upon hitting the substrate, the solvent evaporates, leaving a green tape containing the powder and other additives, whereafter the tape may be punctured, cut, and heated for the desired application. The tape thickness can vary from about 1 &mgr;m upward.

Abstract: The present invention relates to filtration media having both hydrophobic (water-repellent) properties. The filtration media are produced using a fluorothermoplastic material, such as a terpolymer of tetrafluoroethylene, vinylidene fluoride, and hexafluoropropylene. The invention also relates to methods of preparing such filtration media using casting solution phase inversion.

Abstract: A coated sintered cemented carbide body includes a cemented carbide body, a first layer adjacent the cemented carbide body, the first layer including Ti(C,N) and having a thickness of from about 3 to about 20 &mgr;m, an alumina layer adjacent said first layer, the alumina layer including &agr;-Al2O3 or &kgr;-Al2O3 and having a thickness of from about 1 to about 15 &mgr;m, and a further layer adjacent the aluminum layer of a carbide, carbonitride or carboxynitride of one or more of Ti, Zr and Hf, the further layer having a thickness of from about 1 to 15 &mgr;m. A friction-reducing layer, including one or more of &ggr;-Al2O3, &kgr;-A12O3 and nanocrystalline Ti(C,N) and having a thickness of from about 1 to about 5 &mgr;m, can be adjacent to the further layer. A method to cut steel with a sintered cemented carbide body where the alumina is &agr;-Al2O3 and a method to cut cast iron with a sintered cemented carbide body where the alumina is &agr;-Al2O3.

Abstract: A dielectric ceramic article precursor and a process for preparing a dielectric ceramic article are presented. The ceramic article precursor comprises a crystalline aluminosilicate zeolite or an amorphous aluminosilicate, a zinc oxide additive and a glass phase. The ceramic article precursor can optionally contain at least one forming aid selected from binders, plasticizers and surfactants. The process for preparing a dielectric ceramic article involves forming a mixture from the above components into a shaped article such as a tape and then calcining the shaped article at a temperature of about 700° C. to about 1000° C. for a time of about 0.5 to about 24 hours.

Abstract: A ceramic powder of grains having a shape-anisotropy is mixed with a calcined or uncalcined (or both) powder of a ceramic raw material. A ceramic slurry containing the produced mixed powder, a solvent and a binder is prepared and the ceramic slurry is formed into a sheet. A laminate comprised of a plurality of the sheets laminated to each other is uniaxially pressed to form an oriented product in such a manner that the length of the laminate in the direction parallel to the pressing axis becomes larger than that before the pressing, and the area of a plane perpendicular to the pressing axis of the laminate becomes larger than that before the pressing. The oriented formed product is fired and sintered.

Abstract: The method for fabricating a ceramic substrate comprises the step of screen-printing a first dielectric material in a first region of a resin film 30 and screen-printing a second dielectric material of a dielectric constant different from that of the first dielectric material in a second region of the resin film 30 to form a layer including on the resin film 30 a high dielectric layer 20a of the first dielectric material and a base dielectric layer 24a of the second dielectric material, the step of releasing the layer from the resin film 30, and the step of sintering the layer released form the resin film 30.

Abstract: A drying apparatus 10 for casting machine 80, including tunnel 20 divided into first chamber 41 and second chamber 46 by barrier 35. Each chamber 41,46 includes gas inlet 50 connected to gas source 100 for introducing inert carrier gas into chamber 41,46 and gas outlet 60 connected to condenser 71 for removing carrier gas with dissolved solvent from chamber 41,46. Porous diffuser 55 and slotted cover 63 cooperate to maintain smooth plug flow of carrier gas in chamber 41,46. Carrier gas flow is parallel to movement of support strip 91 in first chamber 41 and counter to movement of strip 91 in second chamber 46. Slurry 102 is converted to gel in first chamber 41. Gel is dried to green tape in second chamber 46. Gas pump 76 and flowmeter 77 determine flow rate of carrier gas in chamber 41,46. Partial pressure of solvent vapor is near saturation in first chamber 41; cover heat means 37 prevents condensation of solvent vapor inside tunnel 20. Condenser 71 removes solvent vapor from carrier gas for reuse.

Abstract: A ceramic green sheet is manufactured by preparing a support which includes a releasing layer formed on its top surface and has a smoothness that at least a region of the top surface of the support to be coated with a ceramic slurry has substantially no projections having a height of equal to or more than about 1 &mgr;m, and applying a ceramic slurry to the releasing layer of the support, which ceramic slurry contains a ceramic powder dispersed in a medium. This ceramic green sheet has a small thickness of, for example, about 0.3 to 3 &mgr;m, has no depressions or through holes caused by a filler in the support and is excellent in smoothness.

Abstract: A uniform suspension of ceramic powder and method for making the same. The suspension is prepared by mixing finely divided ceramic powder in an aqueous carrier fluid, combining with a dispersing agent, and alternatively, an organic binder when forming a slip. The ceramic powder has an average particle size of about 0.5 micron or less and is present in the suspension in a loading of up to 30% by volume of the total solids in suspension. A passivating agent is present in the carrier fluid in an amount of 0.5 to 5% by weight of the ceramic powder present for suspension and slip respectively. After the addition of a dispersant, the suspension has a Bingham yield point of less than 230 dynes/cm2 and an apparent viscosity of less than 3000 cps. A green layer produced from the slip exhibits a pore size of less than 0.5 micron.

Abstract: A ceramic membrane for a capacitive vacuum measuring cell includes a thin ceramic membrane with a thickness of <250 &mgr;m, in particular less than 120 &mgr;m. The membrane is produced from a ribbon-shaped green body of Al2O3, and is given high planarity by smoothing the membrane after sintering. The green body is sintered at a sintering temperature that is higher than the smoothing temperature applied following sintering.

Abstract: A method of producing ceramic slurry capable of producing uniformly dispersed ceramic slurry without excessively damaging a ceramic powder, and a method of producing a ceramic slurry composition used for producing a multilayer ceramic electronic part, from which an undissolved binder is precisely removed. Also provided is a method of producing a ceramic green sheet, and a method of producing a multilayer ceramic electronic part. A ceramic powder having an average particle diameter of about 0.01 to 1 &mgr;m is mixed with a dispersion solvent (solvent) and disintegrated by a medium-type dispersion method using a dispersion medium such as balls, beads, or the like to obtain mixed and disintegrated slurry, followed by high-pressure dispersion under a pressure of about 100 kg/cm2 or more.

Abstract: An improved method for manufacturing a porcelain object in a desired shape, from a mixture of at least clay, feldspar and quartz. According to the method, an aqueous dispersion of vinyl acetate and ethylene based copolymer is added to the mixture, and the mixture transformed into an aqueous mass in the shape of a foil with a thickness of 50 &mgr;m to 3 mm and dried. The dried foil is then formed into a desired object shape, and permanently hardened by a ceramic firing process. The dried foil may be brought into the desired object shape by known processes such as rolling, laminating, calendering, cutting, punching, paper folding methods and deep drawing. Once brought into the desired object shape, no drying is required before ceramic firing.

Abstract: A method for producing ceramic green sheets allows the foreign substances on the surface of a carrier film to be reliably removed, prevents fluctuation of the path line when a carrier film is transferred by a foreign substance removal device, and enables a ceramic green sheet having a low local variation in thickness to be achieved. In this method for ceramic green sheets, a carrier film is transferred, the transfer direction of the carrier film is changed by a support roll, and the foreign substances on the carrier film surface are removed by an adhesive roll as a foreign substance removal device at the area where the carrier film is in contact with the peripheral surface of the support roll. Then ceramic slurry is applied on the carrier film using a ceramic slurry applying unit, and thereby a ceramic green sheet is formed.

Abstract: A method for producing ceramic bodies, particularly ceramic foils, from a castable slip made of a dispersion of a ceramic powder in a solvent. A dispersion of an aqueous vinyl-acetate homopolymer or an aqueous vinyl-acetate/ethene copolymer being used as the solvent.

Abstract: Flexible graphite article of manufacture made by compressing a mixture of expanded graphite particle and a fluoro-resin including ethylene-tetrafluoroethylene (ETFE) copolymers after additional heat treatment. An article of manufacture of a gasket material made shows enhanced mechanical properties especially after oil immersion and reduced leakage.

Abstract: A method of manufacturing a ceramic body and a gas sensor is disclosed. The method comprises mixing a ceramic material and an organometallic material with a solvent to form a mixture. The organometallic material comprises both a metallic component and an organic ligand. The mixture is disposed onto a surface, dried, and removed to form the ceramic body. The sensor is made by disposing the ceramic body adjacent to an unfired electrolyte body having an electrode disposed on each side thereof to form a green sensor. The green sensor is co-fired to form the sensor.

Abstract: A ceramic membrane for a capacitive vacuum measuring cell includes a thin ceramic membrane with a thickness of <250 &mgr;m, in particular less than 120 &mgr;m. The membrane is produced from a ribbon-shaped green body of Al2O3, and is given high planarity by smoothing the membrane after sintering. The green body is sintered at a sintering temperature that is higher than the smoothing temperature applied following sintering.

Abstract: A cold isopressing method in which two or more layers of material are formed within an isopressing mold. One of the layers consists of a tape-cast film. The layers are isopressed within the isopressing mold, thereby to laminate the layers and to compact the tape-cast film. The isopressing mold can be of cylindrical configuration with the layers being coaxial cylindrical layers. The materials used in forming the layers can contain green ceramic materials and the resultant structure can be fired and sintered as necessary and in accordance with known methods to produce a finished composite, ceramic structure. Further, such green ceramic materials can be of the type that are capable of conducting hydrogen or oxygen ions at high temperature with the object of utilizing the finished composite ceramic structure as a ceramic membrane element.

Abstract: The disclosed invention relates to unsupported, anisotropically shaped, cubic SrTiO3 single crystal particles and their method of manufacture. The particles have a rectangular face and measure about 10-40 micron in edge length, and about 2-5 micron in thickness. The anisotropically shaped, cubic SrTiO3 single crystal particles are made by reacting tabular Sr3Ti2O7 with TiO2 in the presence of a molten alkali salt.

Abstract: A ceramic powder of grains having a shape-anisotropy is mixed with a calcined or uncalcined (or both) powder of a ceramic raw material. A ceramic slurry containing the produced mixed powder, a solvent and a binder is prepared and the ceramic slurry is formed into a sheet. A laminate comprising a plurality of the sheets laminated to each other is uniaxially pressed to form an oriented product in such a manner that the length of the laminate in the direction parallel to the pressing axis becomes larger than that before the pressing, and the area of a plane perpendicular to the pressing axis of the laminate becomes larger than that before the pressing. The oriented formed product is fired and sintered.

Abstract: A high density ceramic thick film is fabricated by providing vehicle comprising an organic binder and solvent, dispersing ceramic powders into the vehicle to be paste, forming the paste to thick film by screen printing, removing the organic binder from the film, applying sol or sol-like solution to the surface of the film so that the sol or sol-like solution can infiltrate into the film, removing remaining sol or sol-like solution from the surface of the film, drying and preheating the film, and sintering the film.

Abstract: A series of three-dimensional burls are formed in a filled acrylic solid surface material by curing two partially mixed casting compositions with defined parameters of viscosity, density and surface tension.

Abstract: A ceramic green sheet is manufactured by preparing a support which includes a releasing layer formed on its top surface and has a smoothness that at least a region of the top surface of the support to be coated with a ceramic slurry has substantially no projections having a height of equal to or more than about 1 &mgr;m, and applying a ceramic slurry to the releasing layer of the support, which ceramic slurry contains a ceramic powder dispersed in a medium. This ceramic green sheet has a small thickness of, for example, about 0.3 to 3 &mgr;m, has no depressions or through holes caused by a filler in the support and is excellent in smoothness.

Abstract: A method of manufacturing a ceramic body and a gas sensor is disclosed. The method comprises mixing a ceramic material and an organometallic material with a solvent to form a mixture. The organometallic material comprises both a metallic component and an organic ligand. The mixture is disposed onto a surface, dried, and removed to form the ceramic body. The sensor is made by disposing the ceramic body adjacent to an unfired electrolyte body having an electrode disposed on each side thereof to form a green sensor. The green sensor is co-fired to form the sensor.

Abstract: The dielectric constant of low loss tangent glass-ceramic compositions, such as cordierite-based glass ceramics, is modified over a range by selective addition of high dielectric constant ceramics, such as titanates, tantalates and carbides and metals, such as copper. The low loss tangent is retained or improved over a range of frequencies, and the low CTE of the glass-ceramic is maintained. BaTiO3, SrTiO3 and Ta2O5 produce the most effective results.

Abstract: Provided are a method for producing ceramic green sheets used for making a ceramic substrate which is reduced in cracking failure and improved in adhesion between laminated layers and is high in lamination property, high in strength and excellent in surface roughness, said method including heat-treating the ceramic powder having a specific particle size by dry grinding a ceramic powder to prepare ceramic powder having a specific average degree of aggregation and preparing a slurry using the ceramic powder so that a green density of the resulting ceramic green sheets is in a desired range, and a method for making a ceramic laminated substrate having excellent various properties by laminating the above ceramic green sheets and firing the laminate.

Abstract: Disclosed is a sol-gel process for making high-density monolithic alpha-alumina articles. Cracking problems caused by shrinkage of the gel during the drying and firing stages are minimized by controlling the temperature and humidity during the drying process and by using molds formed of prescribed polymeric materials, preliminarily coated with a silicone release agent. The process of the invention provides porous alpha-alumina articles having a controlled microstructure and a controlled pore size distribution, which are beneficial features when the material is used in practical applications, e.g., as substrates for gas sensors.

Abstract: A method of removing substantially all of the volatile component in a green, volatile-containing ceramic article is disclosed. The method comprises freezing the ceramic article; and then subjecting the frozen article to a vacuum for a sufficient time to freeze-dry the article. Frequently, the article is heated while being freeze-dried. Use of this method efficiently reduces the propensity for any warpage of the article. The article is often formed from a ceramic slurry in a gel-casting process. A method for fabricating a ceramic core used in investment casting is also described.

Abstract: The invention provides a setter which comprises a sheet ceramic containing 40% to 90% by weight of an [NiO] unit; a process for producing a porous ceramic sheet containing nickel oxide and stabilized zirconia, by the use of the setter; and a porous ceramic sheet having a ratio X of a ratio Xa relative to a ratio Xb ranging from 0.85 to 1.18, where the ratio Xa is a ratio of an X-ray diffraction peak intensity of the (200) line of nickel oxide relative to an X-ray diffraction peak intensity of the (111) line of the stabilized zirconia on one side of the sheet, and the ratio Xb is a ratio of an X-ray diffraction peak intensity of nickel oxide in the (200) line relative to an X-ray diffraction peak intensity of the (111) line of the stabilized zirconia on the other side, where the ceramic sheet is mainly produced by the process.

Abstract: Ceramic green sheets of controlled microporosity and method of making same have been provided. Controlled microporosity is achieved by including certain ionic species in the ceramic composition, particularly boron, phosphorus and copper oxide.

Abstract: A process for producing a body having a porous matrix of at least one recrystallized ceramic material, or for producing a similar fiber-reinforced body, includes shaping a raw material batch which contains a raw material powder and then sintering. A raw material powder is used which has grain size distribution of a fine grain fraction of an average grain size of at most approximately 2 &mgr;m and a coarse grain fraction of an average grain size of approximately 1.5 &mgr;m to approximately 30 &mgr;m, and the sintering process is carried out at a temperature of at most approximately 1,800° C. Because of the selected grain sizes and grain size distributions, the sintering process can be carried out at lower temperatures. In particular, reinforcing fibers can be worked in which can withstand higher sintering temperatures. By defining the grain size of the powder, a porosity can also be set which permits a good impregnating with organic and/or inorganic substances.

Abstract: An economical process for the manufacture of a polycrystalline, sintered, ceramic abrasive from a powder raw material is described, which process is characterized by the following process steps: preparation of a slip largely free from polymerizing and/or coagulating additives from the powder raw material; pressureless shallow casting of the slip in a vessel; degassing, drying and crushing of the cast sheet to obtain a fabricated material and sintering of the fabricated material to create the abrasive. This process can be used to manufacture an abrasive that permits extremely high grinding performance due to its extraordinary density and structural integrity.

Abstract: A rubber-modified styrene type polymer excellent in transparency and excellent in impact strength and moldability, is presented. A rubber-modified styrene type polymer comprising from 1 to 15 parts by weight of a dispersed phase made of a rubber-like elastic material and from 99 to 85 parts by weight of a continuous phase made of a polymer comprising from 35 to 75 wt % of styrene type monomer units and from 65 to 25 wt % of (meth)acrylate type monomer units, wherein the rubber-like elastic material is a styrene (30 to 50 wt %)-butadiene (70 to 50 wt %) block copolymer, the weight average molecular weight (Mw) of the polystyrene portions of this block copolymer is from 45,000 to 75,000, and the ratio (Mw/Mn) of MW to the number-average molecular weight (Mn) is from 1.20 to 1.80.

Abstract: A process for preparing complex-shaped, ceramic-metal composite articles, comprising: (a) contacting a non-wettable powder that is non-wetting to a metal to be used for infiltration with a shaped ceramic body to form a layer of the non-wettable powder on one or more surfaces of the shaped ceramic body, wherein the shaped ceramic body has a region where there is no layer of the non-wettable powder, and (b) infiltration the shaped ceramic body with the metal through the region or regions where there is no layer of the non-wettable powder, such that a complex-shaped ceramic-metal composite comprising one or more metal phases and one or more ceramic phases is formed, wherein the article has substantially the net shape of the shaped ceramic body and undesirable regions of excess metal on the surface and undesirable phases within the complex-shaped ceramic-metal composite article near the surface are located only in the region or regions where there is no layer of the non-wettable powder.

Abstract: The present invention is to produce a ceramic green sheet with an even thickness. By supplying a ceramic slurry to a slurry room comprising a slurry coater, contacting a carrier film to the fringe part of an opening of the slurry room with pressure so as to close the opening, and moving the carrier film along the opening in the state, a ceramic green sheet made from the slurry can be formed on the carrier film. At the time, based on the actual flow rate data on the actual flow rate of the slurry measured by the flow meter and the actual thickness data on the actual thickness of the green sheet measured by the film thickness meter, appropriate flow rate data on the appropriate flow rate of the slurry to be supplied for obtaining a green sheet with a desired thickness are sought in an appropriate flow rate data calculating means so that the flow rate of the slurry is controlled by the flow rate controlling means based thereon.

Abstract: Provided is a production method and a production apparatus for a ceramic green sheet, capable of achieving a thin layer without using an aqueous or organic solvent. The method of producing a ceramic green sheet includes a first step of charging a carrier sheet, a second step of attaching chargeable powder charged in the polarity opposite to that of the carrier sheet, on the surface of the carrier sheet by electrostatic force, and a third step of applying heat to the chargeable powder attached on the surface of the carrier sheet by electrostatic force so as to fix the chargeable powder onto the surface of the carrier sheet.

Abstract: Disclosed are a ceramics sheet which has an area of 400 cm.sup.2 or more, thickness of 0.4 mm or less, maximum waviness height of 100 .mu.m or less, and warp of 0.1% or less and in which frequency of generated cracking and breakage is 10% or less when a load-applying test and a deflection-loading test each described in the text are carried out in succession, and a flat and large ceramics sheet having an area of 600 cm.sup.2 or more and thickness of 1 mm or less.

Abstract: A method of forming an electrolyte matrix for a carbonate fuel cell. An .alpha.-LiAlO.sub.2 ceramic is mixed in an aqueous solvent having a citric acid dispersant and deflocculated using a high energy attrition milling. The deflocculated mixture is added to an alcohol/glycerol aqueous binder system to form a slurry which is degassed and then tape cast to form the matrix.

Abstract: A method of unidirectionally aligning the whiskers during tape casting and a sintered silicon nitride laminate of controlled properties and microstructure through alignment of the reinforcing grains fabricated by using the method are disclosed. The whiskers are unidirectionally oriented by placing a row of guides 0.2-0.5 mm apart from each other at exit of the reservoir of the slip containing the whiskers during tape casting. The silicon nitride comprising 10-30 volume % of elongated large grains growing from the .beta.-Si.sub.3 N.sub.4 whiskers and oriented unidirectionally in the fine grained matrix is fully densified by gas pressure sintering at 1900.degree. C. It exhibits a fracture toughness value as high as 9.24 Mpa m normal to the whisker alignment according to the Evans-Charles' method disclosed in the Journal of the American Ceramic Society, 59 [7-8], 371-372 (1976).