Abstract: An immersion device is provided for molten metal, as well as a method for making steel. The immersion device allows a trouble free operation. The immersion device includes a measuring head, a carrier for the measuring head, and a lance detachably connected to the carrier, preferably by a detachable tubular connecting element. A gas path runs from the lance to the detachable tubular connecting element. A gas tight connection is provided between a connecting surface of the lance and the detachable tubular connecting element. The tubular connecting element has wipers in the form of fins, which wipe the connecting surface of the lance during attaching and/or detaching the tubular connecting element and the lance.

Abstract: A vessel comprises a probe oriented downward from an outside surface of the vessel to an inside surface of the vessel. A method of operating a vessel, the vessel comprising a vessel wall having an inside surface and an outside surface, comprises: defining a hole extending through the vessel wall, the hole being oriented at a downward angle from the outside surface to the inside surface; and placing a probe in the hole; and preventing slag buildup around the probe during operation of the vessel.

Abstract: A method and measurement system for the control of an active charge surface in a low pressure carburizing process can avoid formation of by-products and achieve regular carburized layers. This can be achieved through sampling of outlet gas at a specified time and comparison with experimentally set model characteristics.

Abstract: An installation for non-destructive control for a metal tube in which an ultrasound sensor includes transducer elements that can be excited each at selected times. A downstream circuit for processing the sensed signals analyzes a global response of the tube at ultrasonic excitation. The transducer elements are only excited to produce a single emission and the downstream circuit recovers the samples of the sensed signals each through a transducer element, to associate therewith successive times respectively offset, to calculate plural global responses of the tube at a single emission, by modifying the shifts between the successive times.

Abstract: A system for determining process parameters for the ladle refinement of steel includes a computer executing a number of software algorithms for determining one or more process parameters for various steel refinement process steps. In one embodiment, for example, the computer is configured to determine the total amount of flux additions to achieve a desired sulfur percentage as part of a steel desulfurization process. In another embodiment, the computer is configured to determine the total quantity of oxygen to be injected into the steel as part of a steel reoxidation process. In still another embodiment, the computer is configured to determine a melting temperature of inclusions within the refined steel, and to determine whether this melting temperature is within an acceptable range to successfully process the steel in a continuous steel strip casting apparatus/process, or whether the steel must be reworked to achieve an acceptable inclusion melting temperature.

Abstract: A system for determining process parameters for the ladle refinement of steel includes a computer executing a number of software algorithms for determining one or more process parameters for various steel refinement process steps. In one embodiment, for example, the computer is configured to determine the total amount of flux additions to achieve a desired sulfur percentage as part of a steel desulfurization process. In another embodiment, the computer is configured to determine the total quantity of oxygen to be injected into the steel as part of a steel reoxidation process. In still another embodiment, the computer is configured to determine a melting temperature of inclusions within the refined steel, and to determine whether this melting temperature is within an acceptable range to successfully process the steel in a continuous steel strip casting apparatus/process, or whether the steel must be reworked to achieve an acceptable inclusion melting temperature.

Abstract: A method of recovering copper from a copper bearing sulphide mineral which includes the steps of subjecting the slurry to a bioleaching process, supplying a feed gas which contains in excess of 21% oxygen by volume, to the slurry, and recovering copper from a bioleach residue of the bioleaching process.

Abstract: A sampler for melts, in particular for slag, includes a body having an inlet and a sample chamber with an inlet opening. The inlet opening is located in a chamber wall delimited by a first metal plate with an opening. Removal of a sample from the sample chamber is simplified by arranging a second metal plate flat against the first metal plate, with the second metal plate having an opening that, together with the opening of the first metal plate, forms the inlet opening.

Abstract: The present invention provides a possibility to evaluate cooling curves recorded in near-eutectic cast iron melts. The curves are evaluated by generated in the melt in the center of the sample to the melt as a function of time. This information is then used to identify the part of the centrally recorded cooling curve that can be used as a basis for determining the amount of structure-modifying agent that must be added to produce compacted graphite cast iron, and/or spheroidal graphite cast iron, and to identify the part of said curve that is associated with formation of primary austenite.

Abstract: The present invention provides a pre-treatment apparatus for an analytical metal sample, the apparatus including (1) a treatment chamber having a sample charging port which can be opened and closed and provided at the top of the chamber, a sample discharging port which can be opened and closed and provided at the bottom of the chamber, and a gas inlet and gas outlet, (2) a sample carrying bar joined to a sample holder also used as a sputtering electrode, and provided to pass through at least one side wall of the treatment chamber so as to be substantially horizontally movable and axially rotatable, and (3) a sputtering counter electrode at least having portions arranged opposite to each other in a region not inhibiting the charge and discharge of an analytical metal sample so that the sample holder can be arranged in the counter electrode.

Abstract: An electron probe microanalyzer determines the particle size of intermetallic inclusions in a master while scanning an area of &phgr;5 mm located at an arbitrary location on the surface of the master. A calibration curve representative of the relationship between the particle size of intermetallic inclusions and the emission spectrum intensity of an constituent element constituting intermetallic inclusions is generated based on the determined particle size of the intermetallic inclusions. Intermetallic inclusions existing on emission spots on the surface of a test sample are specified based on data of emission spectrum intensity of an element existing on the emission spots, and a particle size of the specified intermetallic inclusions is determined based on the data of emission spectrum intensity and the generated calibration curve.

Abstract: A sampler for melts, in particular for slag, includes a body having an inlet and a sample chamber with an inlet opening. The inlet opening is located in a chamber wall delimited by a first metal plate with an opening. Removal of a sample from the sample chamber is simplified by arranging a second metal plate flat against the first metal plate, with the second metal plate having an opening that, together with the opening of the first metal plate, forms the inlet opening.

Abstract: A sampling vessel having a thermocouple for obtaining a cooling curve of molten metals consisting of a long cylindrical body made of ceramics. A sample chamber is formed in the body and the chamber is connected with an inlet formed in a bottom of the body by a runner. An air exhausting passage is formed from the chamber to an outlet formed in a top wall of the body.

Abstract: A method and apparatus are provided for rapidly and accurately processing the chemical composition of a molten metal bath within a furnace. The apparatus includes a robotically-controlled probe which operates to obtain a sample from any predetermined depth of the vessel. The probe is moved from the vessel to a thermostabilized atomic emission spectrometer in nearby proximity to the vessel wherein a part of the probe containing the sample is joined with an upper chamber housing to form an excitation chamber. Within the excitation chamber, the optical emission spectrum of the sample is excited by an excitation source. The optical spectrum is transmitted to an analyzer where the elemental concentration of the sample is determined. Immediately responsive to this analysis, adjustments are made in processing to achieve the target grade of steel.

Abstract: A method for controlling the composition of a cast iron melt is presented. A cast iron melt is prepared which has added to it a structure modifying agent and a nucleating agent in amounts selected to produce a fully compacted graphite iron upon solidification of the melt. A sample vessel, having an inner wall having an active portion coated with a material which will lower the concentration of dissolved modifying agent and an inert portion, is used to extract a sample of the melt. Three temperature measuring devices are used to measure temperatures at three locations within the melt. One measuring device measures the temperature at the center of the vessel, one measures the temperature at the inert portion of the vessel's inner surface and one measures the temperature at the active portion of the vessel's inner surface. In another aspect of the invention, two sample vessels are used, one having an active surface and the other having an inert surface.

Abstract: A method and apparatus for improved control of continuous electric arc furnace steelmaking in which a charge velocity detector measures charge velocity of metallic charge introduced to the furnace. A charge mass detector measures a charge mass of metallic charge introduced to the furnace. A computer determines a feed rate based on the charge velocity and the charge mass. An automatic bath level probe detects a steel bath. The computer determines a steel bath level and optimal positions to insert a temperature probe and an oxygen lance, and further predicts new bath levels from one tapping time to the next tapping time. The temperature probe is inserted to an optimal measurement position based on the steel bath level and measures a steel bath temperature. The oxygen lance is positioned and maintained at an optimal oxygen injection position and injects oxygen into the bath.

Abstract: A method and apparatus for producing direct reduced iron from dry compacts composed of iron oxide and carbonaceous material by feeding compacts no more than two layers deep onto a hearth and removing all the volatiles and metallizing the compacts by exposing said compacts to a radiant heat source at a temperature of from about 2400.degree. to about 2600.degree. F. (1316.degree.-1427.degree. C.) for a total time period of about four to ten minutes and partially cooling the compacts while discharging them from the hearth.

Abstract: A device for sampling flue gas from a duct includes a casing tube having a longitudinal axis, and a port for connecting an interior of the casing tube with a source of cooling fluid, an extraction tube having an end part disposed in the interior of the casing tube, an end of the extraction tube extending through the casing tube to form an inlet opening, an intermediate tube disposed between the casing tube and the extraction tube and spaced from the casing tube and the extraction tube to define a cooling fluid circuit and a sampling tube extending in an interior of the extraction tube and having an opening in an interior of the extraction tube.

Abstract: A process for recovering metal from scrap using a furnace having a bath chamber, a dry hearth chamber, an exhaust duct, and an incinerator for burning fumes from the dry hearth chamber is presented. The process includes conveying oxygen or oxygen enriched air to the incinerator in order to produce a desired oxygen concentration within the incinerator; introducing at least a major portion of the gases leaving the incinerator into the bath chamber; venting a minor portion of the gases from the bath chamber through the exhaust duct; and passing at least a major portion of the balance of the gases through the dry hearth chamber and recycling the balance of the gases to the incinerator, and wherein the concentration of oxygen present in one of the furnace and a duct which conveys hot combustion gases from the incinerator to the furnace is determined, and the volume of oxygen admitted to the incinerator is controlled in order to maintain the desired oxygen concentration within the incinerator.

Abstract: An inexpensive crucible capable of obtaining a high analytical accuracy is provided. A circular projection is formed in a portion above a portion having an intermediate height on an inner circumferential surface of the graphite crucible to prevent contamination of the sample gases.

Abstract: This invention provides a method and appratus whereby steel of various compositions may be produced from iron ore and coal through a series of stages without the intermediate production of liquid iron. A reforming reactor receives top gases from the steel making reactors, and converts them to high reduction potential gases which are returned to the steel making reactors. The iron ore and reductants, such as coal, are charged to a controlled atmosphere reactor which may be an inclined rotary cylindrical shaft. From the controlled atmosphere reactor the charge is moved to a potential shift reactor which is inclined or vertical and encounters increasing heat and rising gases for converting the carbonised sponge into a semi-molten state. The charge then passes to a high temperature reactor where it encounters the reducing gases from the reforming reactor and preheated oxygen to create temperature in which steel is made.

Abstract: An installation for heat treatment or thermochemical treatment of steel permit instantaneous and permanent checking of the concentration of carbon at the surface of the steel, particularly in the course of the carbon enrichment of the surface zone of a workpiece. The process provides for the circulation in contact with this surface zone of a gaseous flux permitting the saturation concentration of carbon at the surface to be obtained at maximum speed, and for regulating this flux as a function of time. The installation comprises a monitored-atmosphere furnace having an input and an outlet for a gaseous flux, feed means forming this gaseous flux, and means for regulating the gaseous flux; it is equipped with data-storage and/or calculating means, and the feed means are designed to form a gaseous flux suitable for obtaining a saturation concentration of carbon at the surface of the workpieces in less than one minute.

Abstract: The tubular rod (7) for sampling, mounted in a duct for the evacuation of fumes for example from a heat treatment or a melting furnace, includes an extractor tube (8) extending in a closed sleeve (9) comprising an inlet (11) and an outlet (12) of cooling fluid, the extractor tube having an end part opening outside the sleeve by means of an opening (10) for sampling fumes and a connecting part (14) extending outside the sleeve for connection to a circuit of analysis including a suction pump. The opening (10) is advantageously directed in counter-current with respect to the direction of circulation (F) of the fumes (11). Application such as for process control in an electrical furnace for the production of steel with injection of oxygenated gas.

Abstract: A method is disclosed for melting copper without incorporating unwanted oxygen and/or hydrogen into the copper by effectively controlling the burners used to melt the copper within desired fuel/air ratio operating limits by employing a special fuel/air mixture sampling and control system.

Abstract: There are disclosed a method and an arrangement for preventing the agglomeration of crusts in a lance opening passing a wall of a metallurgical vessel and provided for a lance carrying a measuring and/or sampling probe. During the metallurgical process proceeding within the metallurgical vessel and during the taking of a measurement and/or sample by means of a lance introduced into the metallurgical vessel through the lance opening, a gas that is inert relative to a melt bath contained in the metallurgical vessel, or air, is injected into the lance opening from outside, which gas produces a gas veil at the mouth of the lance opening facing the melt bath.

Abstract: An arrangement for introducing and removing a lance into and out of a tiltable metallurgical vessel has drive means stationarily arranged in the direction of the lance axis and means for pivotal mounting of the drive means. The lance is designed as a guide and is guided by the drive means and is movable in the direction of its axis. In a method using the above arrangement for positioning the lance relative to the metallurgical vessel, the actual position of the vessel is taken up by a position transmitter on said vessel, and the drive means is actuated to position the lance in dependence on that actual position.

Abstract: Sampling devices for molten metal are known that consist of at least two cup-shaped, metallic components, which are arranged in such a way that their front (mating) surfaces face each other. These components form a sampling chamber, and they have an inlet pipe extending into the chamber. In order to construct a sampling device in a way that makes it quick and easy to remove the sample after the fluid metal has solidified, the chamber is coated with a wear-resistant layer which is temperature-stable up to approximately 1700.degree. C. This layer should be applied at least in the area of the orifice and the wall area opposite the orifice. The front surfaces of the cup-shaped components can remain uncoated.

Abstract: There is disclosed a metallurgical vessel, such as a steelworks converter, having a refractory brick lining and a probe opening passing a wall of the vessel for introducing a measuring and/or sampling probe. In order that the probe opening will get obstructed only minimally, if at all, and possible deposits of slag will be removed easily and quickly, the probe opening is provided with a lining of graphite or a graphite/alumina mixture.

Abstract: Apparatus for retrieving a sample of slag from the surface of molten steel contained in a ladle. A hoist positioned above the ladle lowers and raises an elongated metal rod which has cardboard and metal sleeves surrounding the lower portion of the elongated metal rod. A clean sample of molten slag tightly adheres to the metal sleeve as it is raised from the molten slag layer. The metal sleeve and slag sample are easily removed from the elongated metal rod for analysis.

Abstract: A method and apparatus for introducing an additive material into a metallurgical sample. In a preferred embodiment, the method and apparatus of the present invention comprises introducing a stabilizer, for example, tellurium and/or bismuth, into a metallurgical sample of cast iron or blast furnace hot metal to induce white solidification comprising a probe having a generally enclosed sample cavity and a conduit extending from the cavity for receiving a flow of molten metal for collection in the cavity. A distribution member proximate the conduit is employed for inserting a predetermined quantity of the additive material at a predetermined rate into the molten metal flowing through the conduit so that the additive material is homogeneously distributed throughout the molten metal within the sample cavity.

Abstract: A torsion pendulum apparatus and a dialometer are combined for simultaneous measurement of the internal friction and the expansion of an alloy. The combination is controlled by a programmable controller so as to conduct in-situ measurements of the internal friction and the expansion of a metal during its phase transformation or specific heat treatment. The results of the internal friction measurement and the expansion measurement can be checked and assumed by one another so that more accurate and detailed information can be obtained for the study of metal alloys.

Abstract: A method for controlling the magnesium content of molten aluminum includes the steps of injecting a halogen gas into the molten aluminum, sampling a portion of the resulting gases evolved from the molten aluminum, detecting the presence of constituents in the sampled gases and/or characteristics of the sampled gases indicative of the imminent evolution of unreacted halogen gas, and adjusting the rate of halogen gas injection to approach the point where unreacted halogen gas is about to be evolved. In the preferred embodiment, the halogen gas is chlorine; the detected constituents are gaseous hydrogen chloride (CHl) and aluminum chlorhydrate compounds (Al.sub.2 Cl.sub.x .multidot.(OH).sub.6-x); and the detected characteristic is the opacity of the sampled gases. The invention includes a technique for adjusting the rate of halogen gas injection so as to approach the optimal rate. The invention also includes (1) a sensor for detecting the content of HCl and Al.sub.2 Cl.sub.x .multidot.(OH).sub.

Abstract: The level of the surface of a bath of molten metal beneath a fluid layer of slag in a metallurgical vessel is measured by a detector which is moved through the slag layer into the metal bath and then withdrawn. To improve accuracy and to avoid the need for a separate measurement the detector used comprises an oxygen concentration sensor which emits signals indicating the boundary between the molten metal and the slag, whereby the height of said boundary is determined.

Abstract: In a process for continuously melting scrap (6) and/or pig iron within a converter (1), the converter (1) is heated in proximity of the bottom (3) with sub-stoichiometric burners (4), having their flames (5) essentially radially directed into the interior of the converter (1). In this case, secondary air or O.sub.2 is supplied at a distance above the burner plane for the purpose of completing the combustion. The melt is, optionally together with slag, discharged via a tapping means (9) laterally connected to the converter (1) into a mobile ladle (19). For the purpose of interchanging ladles (19), the converter (1) is swivelled into a position in which the level of the melt is located below the taphole (11).

Abstract: A method and apparatus for operating a rotary retort heat treating furnace involves incorporating an outlet for withdrawing furnace atmosphere from the retort above the axis of rotation and conveying the withdrawn gas remotely form measurement at the temperature conditions where the heat treatment process occurs. The method and apparatus also involves introducing the treatment atmosphere and sampling the atmosphere at a point adjacent the retort product discharge outlet. The use of the above-center outlet and remote probe eliminate structural problems encountered in prior art attempts to measure and control the furnace atmosphere in rotary retort furnaces.

Abstract: In an apparatus for feeding a sintering raw mix, a plurality of bars downwardly sloped in a falling direction of the sintering raw mix onto a pallet of a sintering apparatus is provided so that the falling direction of the raw mix is opposite to the advancing direction of the pallet, a screen is formed by rotatably supporting the bars, and the upper ends of the bars are connected to a rotating drive(s).

Abstract: Sub-lance installation for carrying out measurements and/or taking samples in a metallurgical furnace, has an elongate tubular lance which is rotatable around its longitudinal axis and is attached at its upper end with its longitudinal axis vertical to a carriage by means of which the lance is moved vertically, the installation also including means for rotating the lance about its longitudinal axis. In order that the rotation of the sub-lance can be achieved by a robust apparatus, which does not itself require power and can operate automatically, said means for rotating the lance comprises a helical guide system which imparts rotation to the lance. The helical guide system comprises mutually cooperating helical projections and recesses mounted respectively on the lance and a guide for the lance.

Abstract: A process and apparatus for measuring and regulating the variable pressure furnace gas chemistry is described. The method makes use of mass spectrometer measurements, in the preferred form of the invention, in which gas species percent composition is obtained quantitatively independent of total furnace pressure variation. Using such a real time measurement capability, active control of batch process furnace operations is possible by intrinsic measurement of the part outgassing rather than by assumption of batch part status as a function of extrinsic parameters such as temperature and total pressure. Thus, by a combination of batch process temperature ramp control and variable admittance of suitable gas into the furnace, uniform batch processing is possible by closed loop control, due to renormalization of furnace residual gas chemistry from day to day drift and from batch part chemistry variation.

Abstract: This process and this installation permit taking samples of blast-furnace gas from a series of orifices (T1, T2 . . . ) located at different levels along a generatrix of the body of the blast-furnace. There are performed, in sequence, operations for preparing sampling lines, operations for the analysis of the gases in a device (G), and pressure measuring operations in a pressure sensor (P). These various operations are managed by a programmable automaton (A) and the data obtained are used in a computer (C) in accordance with an embodiment of the installation.

Abstract: An apparatus is disclosed for manipulating and handling sampling tubes in relation to a metallurgical vessel. The apparatus includes a generally vertically oriented guide frame, mounted for limited tilting about a horizontal axis. Rails on the guide frame permit a carriage to run thereon, the carriage will carry a measuring lance. A tube manipulator is pivotably mounted to the guide frame, and includes a tube holding structure for holding a tube on an axis leading directly into the vessel and being coaxial with an axis of the lance, as moved by the carriage, while being alternatively positionable in coaxial relationship with a horizontal delivery axis.

Abstract: A blast furnace off-gas sampling apparatus comprising a valved sample line for continuously withdrawing a sample off-gas from an off-gas line, pressure and temperature sensing means for determining the pressure and temperature within the sample line and pressure filter means attached to the sample line for removing particulate matter from the off-gas going through the sample line, and:A method for determining gas scrubber efficiency in steel mill furnace off-gas systems which comprises the steps of:(a) Withdrawing a side stream sample from untreated gas flowing through an off-gas line,(b) passing said sample through a pressure filter for a fixed period of time whereby the particulate matter in the sample is collected,(c) withdrawing a side stream sample from the same off-gas line after chemical treatment has been added to the off-gas and passing the treated sample through a pressure filter for the same fixed period of time used in step (b), whereby the particulate matter in the treated matter is collected.

Abstract: The buoyancy change of a probe as it is lowered into a molten metal melt is detected and the lowering of the probe terminated a predetermined time after the detection of the buoyancy change to precisely position the probe at a predetermined level below the surface of the melt without the need for a contact detector which actually touches the melt.

Abstract: A method for estimating the geographical distribution of a cohesive zone in a blast furnace which is intermittently charged with an iron ore material to produce molten iron substantially in a continuous manner is disclosed. The method comprises altering the whole or part of the composition of the charging iron ore material at a certain time point, measuring variations in the composition of produced molten iron ore slag over a given time period, and estimating the shape of the cohesive zone in the furnace on the basis of a pattern of variation of one selected component and the speed of gravitational descent of the charged material through the furnace.

Abstract: A ferrous melt, e.g. of steel, is refined beneath a slag layer by blowing from above with an oxygen-containing gas through a lance and by bubbling an inert gas through the melt from the bottom. According to the invention, the consistency of the slag layer and/or its level is continuously detected on the one hand and the rate of decarburation of the bath is detected on the other hand and in response to these measurements the volume rate of flow of the bubbling gas is controlled on the one hand to maintain a predetermined spacing of the slag layer from the head of the lance and, on the other hand, a fluid consistency of the slag.

Abstract: A gravity fed water bath process treats waste water from spray rinses containing compounds of copper and like heavy metals. For displacing heavy metals, such as copper, the bath has a substantially pure metal with an electrode potential greater than the heavy metal contained in the rinse water. A system for controlling the pH level of the water bath treatment and for supplying acid at the beginning of the bath, and alkaline at the end of the bath provides a highly acidic pH level for the water bath and heavy metal removal chamber, and adjusts the pH level of the discharged water for satisfactory deposit in municipal sewer systems.A method for displacing the heavy metal from the compound in solution requires exposing the heavy metal compound to a substantially pure metal having an electrode potential greater than the heavy metal of the compound, in an acidic bath whose pH level is controlled.

Abstract: A transfer and storage mechanism is provided for disposable tube probes used in metallurgy. The transfer mechanism is arranged to select from several vertical stacks of such probes and to transfer the selected probe to a lance for insertion into a converter. The same mechanism provides several functions in that it holds the selected probe tube, pivots it into position for engagement with the lance and centers the probe for engagement for the lance. Moreover, arrangements are provided for engaging and sliding the selected tube out of the storage area into the transfer mechanism.

Abstract: An apparatus for and method of recovering silver from liquid solution containing silver, the apparatus comprising an ionic exchange chamber wherein a sludge containing silver is precipitated from the solution, the apparatus further comprising a device to measure the flow of solution through the chamber and to obtain a representative sample from the solution displaced therethrough. In accordance with one aspect of the invention, the metering and sampling are accomplished in a single unit. It is preferred that the metering and sampling unit be situated to receive solution prior to its entry into the precipitation chamber, although the effluent solution leaving the chamber may be metered and sampled as well. The metering and sampling device illustrated comprises a tilting tray pivotally disposed in a metering chamber. Upon each oscillation of the tray, a known amount of solution is thus caused to be discharged from the compartments of the tray.

Abstract: In an apparatus for feeding a sintering raw mix, a plurality of bars downwardly sloped in a falling direction of the sintering raw mix onto a pallet of a sintering apparatus is provided so that the falling direction of the raw mix is opposite to the advancing direction of the pallet, a screen is formed by rotatably supporting the bars, and the upper ends of the bars are connected to a rotating drive(s).