Abstract: An electrochromic mirror comprising two conductive substrates, at least one of which is transparent, and both of an ion conductor layer and an electrochromic color-developing layer sandwiched between the substrates, wherein the color-developing layer contains a high-molecular compound having a biologen structure.

Abstract: Described is an optical element having a region arranged on a first substrate and comprising at least one layer, the region containing a reactive material, a dye, and ion storage, whereby a redox system and at least one ion are present in the ion storage. The dye is hereby in contact with the reactive material, either directly or by means of a conductive layer, such that an optically induced charge transfer flow (forward reaction) can be achieved from the dye to the reactive material, either directly or by means of the conductive layer within the region that comprises at least one layer. A charge carrier return flow (reverse reaction) can occur via the same interface as the forward reaction, or alternatively, via external wiring and a second electrode. The external wiring can contain a switch.

Abstract: An interior rearview mirror assembly for a vehicle includes a reflective element, a housing or casing supporting the reflective element, and the casing including a storage space. The storage space provides storage for at least one accessory and for storing the accessory in the location easily accessible by an occupant of the vehicle whereby the accessory can be inserted into and removed from the storage space for use by an occupant of the vehicle. The storage space may take the form of a recess provided in a top wall of the casing, a recessed portion provided in a front wall, back wall, or end wall of the casing. In one form, the recessed portion houses a pendent accessory which is movable between a retracted position within the recess to an extended position for viewing by an occupant of the vehicle. For example, the pendent accessory may include a reflective element or a display element, for displaying information to an occupant of the vehicle.

Abstract: Electrochromic and photoelectrochromic devices using nanocrystalline semiconductor electrodes with a high specific surface area and surface-absorbed electrochromic molecules are disclosed.

Abstract: The present invention relates to electrochromic ploymeric solid films, manufacturing electrochromic devices using such solid films and processes for making such solid films and devices. The electrochromic polymeric solid films of the present invention exhibit beneficial properties and characteristics, especially when compared to known electrochromic media. The electrochromic polymeric solid films are transformed in situ from a low viscosity electrochromic monomer composition by exposure to electromagnetic radiation, and in so doing minimum shrinkage occurs. The electrochromic polymeric solid films of the present invention also perform will under prolonged coloration, outdoor weathering and all-climate exposure, and provide an inherent safety aspect not known to electrochromic media heretofore.

Abstract: This invention relates to an electrochromic system containing at least one oxidizable substance RED1 and at least one reducible substance OX2 linked covalently by a bridge that are suitable for use in electrochromic devices.

Abstract: An electro-optical device is provided having a structure which, in particular, allows the device to be made smaller and thinner, and the heat-dissipation capability to be increased in order to prevent overheating. A positioning section which accommodates an opposing substrate, and which contacts an edge of an element substrate is provided in a case member accommodating an electro-optical panel which consists of the opposing substrate and the element substrate.

Abstract: An electrochromic mirror is disclosed for use in a vehicle rearview mirror assembly having a light source positioned behind the electrochromic mirror for selectively projecting light through the mirror. The electrochromic mirror includes front and rear spaced elements each having front and rear surfaces and being sealably bonded together in a spaced-apart relationship to define a chamber, a layer of transparent conductive material disposed on the rear surface of the front element, at least one solution-phase electrochromic material contained within the chamber, and a second electrode overlying the front surface of the rear element in contact with the electrochromic material. The second electrode includes a layer of reflective material and a coating of electrically conductive material that is at least partially transmissive and is disposed over substantially all of the front surface of the rear element.

Abstract: UV-stabilized electrochromic assemblies having a layer structure, characterized in that one layer contains an electrically conductive, electrochromic polydioxythiophene and a further layer contains an inorganic ion-storage compound based on metal oxides or a mixture of such ion-storage compounds, where the gel electrolyte contains a mixed-in UV absorber.

Abstract: The invention relates to an electrochromic device comprising a pair of transparently and conductively coated glass or plastic plates, one of which is optionally mirrored and the conductive layer of one or both of which is optionally subdivided into separate individually electrically contacted segments, wherein (1) the plates are joined together on the sides of their conductive coating by an adhesive bead into which spacers are optionally embedded, wherein the adhesive used for the adhesive bead is a thermally or photochemically curing epoxy adhesive or an epoxy adhesive that cures thermally after photochemical initiation, (2) the volume formed by the two plates and the adhesive bead is filled with an electrochromic fluid through one or more apertures, and (3) the filling aperture or apertures required for introduction of the electrochromic fluid are sealed with an adhesive after filling has taken place, wherein the adhesive used for sealing is a photochemically curing acrylate adhesive or an epoxy adhesive

Abstract: An electrochromic device comprising at least one substantially transparent substrate having an electrically conductive material associated therewith, and an electrochromic medium which comprises a solvent, a cathodic material, and an anodic electrochromic material represented by the formula: wherein R1-R10 are the same or different and at least three of R1-R10 are the same or different and comprise a straight or branched alkyl, aryl, alkaryl, or aralkyl group containing approximately 1 to approximately 40 carbon atom(s), and/or a silyl or siloxyl group containing approximately 1 to approximately 40 silicon atom(s), wherein the carbon or silicon atom(s) may be a linking group to, or part of, one or more functional groups comprising nitrites; nitro constituents; sulfoxides; sulfonates; phosphonium constituents; phosphonates; phosphonites; ammonium constituents; viologens, including bipyridinyl constituents; carbonyls, including carbonates, carbamates; ketones; esters; and amides; ethers, inclu

Abstract: An electro-optic polarizor, grating assembly or cell (10) includes a first glass plate (12) to form the foundation of the cell. A first alignment surfactant (14) is coated on one surface of the first glass plate (12). Similarly, a second alignment surfactant (24) is coated on one surface of a second glass plate (22). A transparent interdigitated electrode pattern (30) is disposed between the second glass plate (22) and the second alignment surfactant (24). A thin film of homeotropically aligned nematic liquid crystal (40) is sandwiched between the first and second alignment surfactants (14) and (24) for applying a lateral electric field caused by the control voltage or signal (50) across the liquid crystal (40) to alter the optical properties of the liquid crystal (40) such that a polarization depended grating (60) is induced by the lateral electric field (50).

Abstract: The invention relates to a method of processing an electrochemical device having at least one carrier substrate (1) provided with a stack (2) of functional layers, including at least one electrochemically active layer (4) which is capable of reversibly and simultaneously inserting ions and electrons and is arranged between two electroconductive layers, in particular a device of the electrochromic type. The processing consists in locally inhibiting the functionality of at least one of the functional layers, with the exception of one of the electroconductive layers (3, 8), so as to delimit an inactive peripheral region in the stack (2).

Abstract: Electrochromic compositions suitable for use in electrochromic media in electrochromic devices contain minimally two electrochromic compounds of the same redox type, whose redox potentials are greater than 30 mV.

Abstract: This invention relates to UV-protected electrochromic solutions suitable for use in electrochromic devices and containing at least one oxidizable substance RED1 and at least one reducible substance OX2 linked by a bridging group and a UV absorber component.

Abstract: A glazing/window assembly with reduced ultraviolet (UV) radiation transmission may include at least a pair of glass panels or other elements confining an electrochromic medium therebetween. Ultraviolet radiation reducing material is incorporated for reducing ultraviolet radiation transmission through the assembly. The ultraviolet radiation reducing material comprises at least one of an ultraviolet absorber, an ultraviolet absorbing polymer, and an ultraviolet absorbing glass. At least one of a laminated glass panel, tempered glass panel and a polymeric layer is provided to prevent injury upon impact to the assembly. A color tint may be included in the assembly to provide a tint to transmitted light.

Abstract: A photoelectrochemical-electrochromic device comprising a first transparent electrode and a second transparent electrode in parallel, spaced relation to each other. The first transparent electrode is electrically connected to the second transparent electrode. An electrochromic material is applied to the first transparent electrode and a nanoporous semiconductor film having a dye adsorbed therein is applied to the second transparent electrode. An electrolyte layer contacts the electrochromic material and the nanoporous semiconductor film. The electrolyte layer has a redox couple whereby upon application of light, the nanoporous semiconductor layer dye absorbs the light and the redox couple oxidizes producing an electric field across the device modulating the effective light transmittance through the device.

Abstract: Electrochromic devices and materials having enhanced daylight stability are described. The materials have a redox center linked to an energy receptor site that may serve to dissipate excited state energy from the redox center, alternatively the receptor site may absorb harmful radiation prior to the absorption by the redox center.

Abstract: An image display medium including a pair of electroconductive layers, at least one of which is light-transmissive and which are opposed each other to form a cell; and a dispersion contained in the cell, wherein the dispersion includes a colored particulate material having at least one of an acidic group and a basic group; a hydrocarbon solvent; a resin soluble in the hydrocarbon solvent and having at least one of a basic group and an acidic group; and a compound having a nonionic polar group, and wherein when the particulate material has an acidic group, the resin has a basic group, and when the particulate material has a basic group, the resin has an acidic group.

Abstract: Increased stability of electrochromic devices containing an electrochromic medium having two or more electroactive compounds is accomplished by establishing current limiting concentrations of electroactive compounds with the larger redox potential difference. A process for production of electrochromic devices uses targeted concentrations of electroactive materials during preparation of the electrochromic medium which results in substantially no devices being produced wherein the current is limited by an electroactive compound having a low redox potential difference.

Abstract: An active matrix electrophoretic display is driven. In a reset period Tr a reset voltage is applied to each pixel electrode. Next, in a writing period an applied voltage is applied to each of said pixel electrode during a time period corresponding to a gradation value designated by an image data. Next, a common voltage is applied to each of said pixel electrode, so that electric charge accumulated in each capacitor is taken away and no electric field is applied to each dispersal system, thereby a displayed image is held.

Abstract: An electrochromic window assembly includes a security system for monitoring breakage of the electrochromic window assembly. Control circuitry is connected to the electrochromic window assembly for monitoring an electrical characteristic of one or more conductive coatings within the electrochromic window assembly, such as electrical resistance. Upon detecting a change in the electrical resistance, such as that caused by a break in one or more conductive coating, an alarm signal is generated and is sent to an alarm trigger circuit for activating an alarm. A method for monitoring penetration or breakage of an electrochromic window assembly is also provided, which method involves applying electrical activation to an electrochromic assembly and monitoring for a change in an electrical characteristic based on the applied electrical potential. Electrochromic window assemblies incorporating security alarm features in accordance with the present invention are particularly useful in automobile applications.

Abstract: Coupling of anodic electrochromic compounds by a covalent bond or a bridge link which provides for electronic communication between the coupled electrochromic compounds results in coupled electrochromic compounds which exhibit greater stability as well as electrochromic activity that differs from the monomeric electrochromic compounds. Extension of the absorption spectrum into the near-infrared region of the spectrum is frequently observed. The coupled electrochromic compounds are highly suitable for use in electrochromic media used to produce electrochromic devices.

Abstract: The invention relates to an electrochromic contrast plate which is either arranged as a discrete unit in front of the screen or is connected to the outer surface of the screen through a common sheet, consisting of a pair of transparent glass or plastic sheets which are provided, on one side each, with an electroconductive, transparent coating, and which are joined together on the sides of their conductive coating via a sealing ring, and in which the volume formed by the two sheets and the sealing ring is filled with an electrochronic medium, characterized in that the electrochromic medium is a liquid, a gel or a polymer.

Abstract: The present invention relates to electrochromic polymeric solid films, manufacturing electrochromic devices using such solid films and processes for making such solid films and devices. The electrochromic polymeric solid films of the present invention exhibit beneficial properties and characteristics, especially when compared to known electrochromic media. The electrochromic polymeric solid films are transformed in situ from a low viscosity electrochromic monomer composition by exposure to electromagnetic radiation, and in so doing minimum shrinkage occurs. The electrochromic polymeric solid films of the present invention also perform well under prolonged coloration, outdoor weathering and all-climate exposure, and provide an inherent safety aspect not known to electrochromic media heretofore.

Abstract: Electrochromic devices and materials having enhanced daylight stability are described. The materials have a redox center linked to an energy receptor site that may serve to dissipate excited state energy from the redox center, alternatively the receptor site may absorb harmful radiation prior to the absorption by the redox center.

Abstract: Anodic electrochromic materials for use in an electrochromic device comprising a first moiety, wherein the first moiety comprises a metallocene or a substituted metallocene, and a second moiety, wherein the second moiety comprises at least one constituent which serves to increase the solubility of the first moiety in an associated solvent relative to solubility of the first moiety without the second moiety.

Abstract: An electrochromic device, such as a window or mirror, is disclosed that includes first and second substrates each having an inner surface spaced apart from one another to define a chamber, first and second electrodes carried on the inner surface of the second substrate and disposed thereon to be electrically isolated from one another, and an electrochromic medium disposed in the chamber. The electrodes may be disposed on the inner surface of the second substrate in substantially co-planar relation. Alternatively, the electrodes may be arranged in a stacked relation, with a layer of dielectric material provided therebetween.

Abstract: An improved electrochromic rearview mirror for motor vehicles, the mirror incorporating thin front and rear spaced glass elements having a thickness ranging from about 0.5 to about 1.5. A layer of transparent conductive material is placed onto the mirror's second surface, and either another layer of transparent conductive material or a combined reflector/electrode is placed onto the mirror's third surface. A chamber, defined by the layers on the interior surfaces of the front and rear glass elements and a peripheral sealing member, contains a free-standing gel comprising a solvent and a crosslinked polymer matrix. The chamber further contains at least one electrochromic material in solution with the solvent and interspersed in the crosslinked polymer matrix.

Abstract: The invention relates to electrochromic assemblies having a layer structure, characterized in that one layer is an electrically conductive, electrochromic polydioxythiophene and a further layer is an ion-storage compound selected or a mixture of ion-storage compounds of the formulae (I) to (XIV). Me1O (I) Me1(OH)2 (IX) Me1OX (II) Me1O(OH) (X) MXMe1O (III) MMe1O2 (XI) MXMe1O2 (IV) Me1O2 (XII) MxMe1Oy (V) Me12O3 (XIII) Me2O3 (VI) Me12O3.H2O (XIV) MXMe2O3 (VII) MXMe2(1−x)O3 (VIII) where Me1 and Me2 each represent a metal transition group VI or VII of the Mendeleev Periodic Table, M represents a metal of main group I of the Mendeleev Periodic Table or a proton, x represents a number from 0.001 to 5, y represents a number from 0.001 to 5.

Abstract: Edge busbars on a substantial perimeter of an electrochromic device are disclosed having electrical paths wrapping over the perimeter edge. Internal busbars interior from the perimeter are disclosed which lower the conductivity of the conductive layer of an electrochromic device. Signals supplied to the busbars to control the electrochromic device are controlled by a switching power supply that allows the maintaining of the color of the electrochromic device without application of continuous power.

Abstract: An electrochromic medium for use in a normally operating electrochromic device comprising an anodic material and a cathodic material wherein both of the anodic and cathodic materials are electroactive and at least one of the anodic and cathodic materials is electrochromic, an additive, and means associated with the additive for maintaining a colorless or nearly colorless electrochromic medium while the electrochromic medium is in a high transmission state relative to an electrochromic medium without the additive.

Abstract: An electrochromic device comprising two plates or films, of which at least one is transparent and which are provided with a conductive layer on the sides facing one another, where at least one of the conductive layers is transparent, where the plates or films and a sealing ring define a volume in which an electrochromic medium is located comprising at least one reducible compound OX2 and at least one oxidizable compound RED1 which convert into their respective redox states RED2 and OX, by taking up electrons at the negative electrode or by releasing electrons at the positive electrode, where, after charge equalization between RED2 and OX1, the original redox states OX2 and RED1 are in each case re-formed, wherein at least one RED1 or OX2 is an electrochromic compound in which two identical or different coloring units are connected via at least one bridge in such a way that, on oxidation or reduction, a &sgr;-bond is formed or broken between the two units with a color change of the compound in question, is dis

Abstract: An electrochromic glazing assembly with reduced ultraviolet (UV) radiation transmission may include at least a pair of glass panels or other elements confining an electrochromic medium therebetween. Ultraviolet radiation reducing element or material are incorporated for reducing ultraviolet radiation transmission through the assembly. The ultraviolet radiation reducing element or material comprises at least one of an ultraviolet absorber, an ultraviolet absorbing polymer, and an ultraviolet absorbing glass.

Abstract: Reversible electrochemical mirror (REM) devices typically comprise a conductive oxide mirror electrode that is substantially transparent to radiation of some wavelengths, a counter electrode that may also be substantially transparent, and an electrolyte that contains ions of an electrodepositable metal. A voltage applied between the two electrodes causes electrodeposition of a mirror deposit on the mirror electrode and dissolution of the mirror deposit on the counter electrode, and these processes are reversed when the polarity of the applied voltage is changed. Such REM devices provide precise control over the reflection and transmission of radiation and can be used for a variety of applications, including smart windows and automatically adjusting automotive mirrors. According to the present invention, measurements of the sheet resistance of the mirror electrode in a REM device are correlated with the thickness of electrodeposited mirror metal and can be used to monitor the reflectance of the device.

Abstract: Electrochromic compositions suitable for use in electrochromic media in electrochromic devices contain minimally two electrochromic compounds of the same redox type, whose redox potentials are greater than 30 mV. The lower redox potential electrochromic compound makes a large contribution to the absorbancy of the electrochromic medium despite being present in only minor concentration.

Abstract: A solid type EC mirror with improved corrosion resistance of its reflecting metal film is provided. On one surface (i.e., rear surface as viewed from the side on which light is incident) of a glass substrate are successively laminated an ITO transparent electrode film and an EC device consisting of three layers of an anode compound film, a solid electrolyte film and a cathode compound film. On the surface thereof are further successively laminated a high reflecting metal material film and a high corrosion resistant metal film. Since the high reflecting metal material film is covered with the high corrosion resistant metal film, a corrosion prevention effect against corrosion by moisture permeating from outside is enhanced and an offset width of the EC mirror can be reduced and a range of effective field of view can be enlarged.

Abstract: An improved electrochromic rearview mirror for motor vehicles, the mirror incorporating thin front and rear spaced glass elements having a thickness ranging from about 0.5 to about 1.5. A layer of transparent conductive material is placed onto the mirror's second surface, and either another layer of transparent conductive material or a combined reflector/electrode is placed onto the mirror's third surface. A chamber, defined by the layers on the interior surfaces of the front and rear glass elements and a peripheral sealing member, contains a free-standing gel comprising a solvent and a crosslinked polymer matrix. The chamber further contains at least one electrochromic material in solution with the solvent and interspersed in the crosslinked polymer matrix.

Abstract: Electrochromic devices incorporate reversible oxidizers to improve device kinetics, incorporate counterelectrodes composed of an alkali metal oxide and vanadium oxide to improve stability, and doped tungsten or molybdenum oxide in the electrochromic layer to improve UV durability.

Abstract: Electrochromic mirrors comprises a transparent conductive substrate, a reflective conductive substrate, and an ion conductive layer disposed therebetween wherein at least one of said substrates is provided on the peripheral portions of its conductive surface with a highly conductive layer having smaller resistance than the surface resistance of said conductive surface.

Abstract: Anodic electrochromic materials for use in an electrochromic device comprising a first moiety, wherein the first moiety comprises a metallocene or a substituted metallocene, and a second moiety, wherein the second moiety comprises at least one constituent which serves to increase the solubility of the first moiety in an associated solvent relative to solubility of the first moiety without the second moiety.

Abstract: A method for producing a cell for an electrochromic mirror which comprises a step of applying a epoxy-based sealant containing beads by a method selected from the group consisting of dispensing or screen-printing on a predetermined position of the surface peripheral edge of at least one of two electrically conductive substrates; and a step of superposing the two substrates such that the width of the applied sealant is made 2 mm or less.

Abstract: An electrochromic device comprising: a first glass element having an electrically conductive material associated therewith, wherein said first element comprises a height (h1), a width (w1), a thickness (t1), an inner surface, and an outer surface; a second element having an electrically conductive material associated therewith, wherein said second element comprises a height (h2), a width (w2) , and a thickness (t2), an inner surface, and an outer surface; a cell spacing (c) which comprises a distance between said inner surface of said first element and said inner surface of said second element; a gelled electrochromic medium contained within a chamber positioned between said first and second elements; wherein (h1), (w1), (t1), (h2), (w2), (t2), and (c) are numerical values in millimeters; and wherein (h1), (w1), and (t1) of said first element, and (h2), (w2), and (t2) of said second element and (c) comprise numerical values such that the following inequality is satisfied: 1 2 ⁢ h 1 5 ⁡ ( 1 -

Abstract: A method for producing a cell for an electrochromic mirror by laminating two electrically conductive substrates which comprises the step of placing at least two plates each having at least one linear portion and provided with in a predetermined position with a punched-out portion having a shape corresponding to that of said substrate, such that each of said linear portions is located on the same line or on each of two lines offset from each other, in a juxtaposed relationship at a predetermined interval; the step of positioning said two substrates by inserting them into each of said punched-out portions; the step of shifting one of said plates holding said substrates therein over the other plate such that the substrates are located in a superposed relationship to each other; and the step of laminating said substrates.

Abstract: Coupling of anodic electrochromic compounds by a covalent bond or a bridge link which provides for electronic communication between the coupled electrochromic compounds results in coupled electrochromic compounds which exhibit greater stability as well as electrochromic activity that differs from the monomeric electrochromic compounds. Extension of the absorption spectrum into the near-infrared region of the spectrum is frequently observed. The coupled electrochromic compounds are highly suitable for use in electrochromic media used to produce electrochromic devices.

Abstract: The present invention provides improved electrochromic layers, which comprise polymeric matrices with electrochromic solutions interspersed therein. Varying an electrical potential difference across a layer of the invention results in reversible variation in the transmittance of light across the layer because of electrochemical processes in the electrochromic solution of the layer. The invention further provides electrochromic devices, in which the electrochromic layers of the invention provide reversibly variable transmittance to light, and various apparatus in which the devices of the invention provide light-filtering or light-color modulation. Such apparatus include windows, including those for use inside and on the outside walls of buildings and in sunroofs for automobiles, and variable reflectance mirrors, especially rearview mirrors for automobiles.

Abstract: A simplified mirror sub-assembly for exterior automotive mirrors includes an electrochromic mirror element, a circuit board disposed on a rear surface of the mirror element, and a carrier plate attached to the circuit board via double-sided adhesive tape. The sub-assembly may include a conductive trace disposed on the surface of the circuit board that mates with the mirror element to dissipate heat generated by electronic components on the circuit board and act as a heater for the mirror element at the same time. The electronic components on the circuit board are arranged to lie in a void created by a peripheral edge in the carrier plate so that the inventive structure can incorporate a known carrier plate structure, if desired, to allow easy installation into a known mirror housing.

Abstract: Electrochromic windows and panels are provided which have first and second spaced elements that are optically transparent to visible light. The first and second elements each have first and second sides, and the windows and panels define a sealed chamber disposed between the second side of the first element and the first side of the second element. The sealed chamber is filled with an electrochromic medium, and the transmission of visible light through the electrochromic medium is variable when an electrical potential is applied to electrically conductive coatings that are provided on the second side of the first element and the first side of the second element.

Abstract: An optical apparatus having counter electrodes of ITO and working electrodes formed from a conductive paste prepared by dispersing silver or carbon conductive particles in a binder or a sintered material obtained by sintering silver or carbon conductive particles. The counter electrodes can be formed into a structure free of sharp edges which can cause a concentration of electric fields.

Abstract: The present invention discloses a method of optical correction for improving the pattern shrinkage caused by scattering of the light during photolithography processes, wherein the patterns on photomasks are corrected by providing aid patterns. Therefore, serifs or hammerheads are not necessary, and the costs can be decreased. According to the present invention, a chrome aid block is provided between the edges of the patterns. It is noted that the size of the chrome aid block is between ⅓ to ½ the wavelength of light used during exposure. Therefore, the pattern shrinkage caused by scattering of the light during exposure can be reduced, and there is no additional block formed on the photoresist layer. In addition, the standing wave effect can be prevented; thus, the pattern transfer is more accurate.