Abstract: The invention is a coded cat's eye retro-reflector array fabricated using data-driven, ink jet micro-dispensing technology. Specifically the invention claims the apparatus, the method of fabricating the apparatus, and the method of using the apparatus. The function of the apparatus is the identification of objects, materials and gasses from a distance using light beams. The apparatus is based upon the cat's eye retro-reflector device that is well known to one skilled in the art.

Abstract: Color shifting retroreflective articles can provide features such as decorative effects, evidence of tampering, security authentication or positional information. In some embodiments, the color shifting retroreflective article includes a layer of microspheres, and a reflective coating that is disposed in optical association with the layer of microspheres. The reflective coating includes a spacer layer disposed between a semitransparent first reflective layer and a second reflective layer. The first reflective layer includes a reflective layer disposed adjacent the layer of microspheres. At least one layer of the reflective coating includes a non-uniform thickness associated with each of a plurality of microspheres such that light incident on the article from a first direction is retroreflected at a first color and light incident on the article from a second direction is retroreflected at a second color visibly different from the first color.

Abstract: The invention relates to a reflector system for positioning a medical instrument or of body parts of a patient or for any determination of position, which is characterized by reflectors (3, 4, 5) that are configured as transparent retroreflective spheres and may consist of a material with a refractive index of preferably 1.9.

Abstract: A process for manufacturing retroreflective printed material, the process comprising a) providing a composite comprising a temporary support sheet with a layer of microspheres partially embedded in the temporary support sheet such that the surfaces of the microspheres are partially exposed; b) applying a reflecting layer on the microspheres; c) applying a priming layer either on the partially exposed surfaces of the microspheres or on the reflecting layer; d) transferring a printed design layer from a transfer medium with the printed design on the primer layer and separating the transfer medium without the printed design from the printed design layer; e) applying a binder layer on the printed design layer; f) applying a base fabric on the binder layer and separating the temporary support sheet from the layer of microspheres, thereby creating the retroreflective printed material. A retroreflective printed material made according to the process.

Abstract: Retrochromic articles have a retrochromic pattern comprising first and second viewable retroreflective regions, wherein at least one viewable retroreflective region comprises a plurality of intrinsically retrochromic beads. Methods for making such articles are also provided. Articles according to the present invention have covert security features, and may be used, for example, to authenticate security articles.

Abstract: Sign band (1) for day and night road signs, comprising a band-shaped support (6) having a first and second outer surface (6a) and 6b), a reflecting substance (7) arranged in a portion of at least one of said outer surfaces (6a) and (6b), a transparent gluing substance spread onto said reflecting substrace (7), and a plurality of transparent microspheres (9) anchored within said gluing substrate.

Abstract: A exposed-lens retroreflective article exhibiting retroreflection under dry and wet conditions is provided. The inventive article comprises a first set of optical elements having a first reflective layer disposed on the embedded portion of the elements. The first set contributes mainly to dry retroreflection. The article further comprises a second set of optical elements having a second reflective layer behind a spacing layer. The second set contributes mainly to wet retroreflection. In one embodiment, the first and second sets of optical elements have substantially the same average diameters, refractive index, and density.

Abstract: A light reflective film having a multi-layered structure including a light reflective membrane layer on a web. A plurality of transparent spherical glass beads are provided on the light reflective membrane layer. A transparent film layer is provided on the glass beads and is spaced away from the light reflective membrane layer by an air gap. A transparent coating encapsulates all of the component layers to form the light reflective film. The light reflective film is flexible and durable, and effectively reflects light when under water.

Abstract: A composite on the surface of a substrate, and a method for producing the composite are disclosed. The composite includes a first coating, reflective beads, and a clear coating. The method for preparing the composite includes the stepwise application of coating compositions and reflective beads. The composite, which is wear-resistant and retroreflective, is useful as a traffic marking.

Abstract: In an optical sheet 10 having a prism surface 16 formed by providing unit prisms 14 on the upper surface of a transparent base material 12, a coating layer 18 is provided on the reverse surface of the transparent base material opposite to the prism surface 16, spherical beads 20 are arranged projecting from the surface of the coating layer 18 by 1 to 10 &mgr;m in height, and the coating layer 18 is brought into contact with the flat and smooth surface 22A of the light-transmissive material 22 through the spherical beads 20 which are put between them. The spherical beads are 1 &mgr;m or less in half bandwidth of the distribution of particle diameters and are made uniform in height projecting from the coating layer 18.

Abstract: Sign band (1) for day and night road signs, comprising a band-shaped support (6) having a first and second outer surface (6a) and 6b), a reflecting substance (7) arranged in a portion of at least one of said outer surfaces (6a) and (6b), a transparent gluing substance spread onto said reflecting substrace (7), and a plurality of transparent microspheres (9) anchored within said gluing substrate.

Abstract: An image forming apparatus that is capable of scanning at a proper speed at all positions on a main scan line without being affected by variations in the characteristics of a f-&thgr; lens, variations in the laser beam wavelength, irregularities in the rotational speed of a polygon mirror and fluctuations in the characteristics of the f-&thgr; lens due to changes in ambient temperature. An image clock signal for exposure control is generated for each of a plurality of segments obtained by dividing a main scan line on a photosensitive drum scanned by a laser beam, based on a modulation coefficient. The modulation coefficient is corrected based on the detected phase difference between detection timing of the terminating end of the main scan line and generation timing of the last image clock signal for the last segment.

Abstract: A composite fabric structure having unique visual and physical properties is described. The composite fabric includes a textile fabric layer having a visual surface and a rear surface. A layer of diffractive or retroreflective material is secured beneath the textile fabric layer, either directly or beneath a layer of substantially transparent material. The textile fabric layer is of an open or semi-transparent construction, so that light can pass through it to reach the layer of diffractive or retroreflective material and be reflected back through the layer of textile fabric, to provide a unique appearance to its visual surface. Because fabric constructions can be provided which are extremely conspicuous, they have particular utility in the formation of safety equipment and automobile components. Furthermore, the fabrics have high durability, improved hand, and in many embodiments can be stretched as well as molded.

Abstract: In an optical sheet 10 having a prism surface 16 formed by providing unit prisms 14 on the upper surface of a transparent base material 12, a coating layer 18 is provided on the reverse surface of the transparent base material opposite to the prism surface 16, spherical beads 20 are arranged projecting from the surface of the coating layer 18 by 1 to 10 &mgr;m in height, and the coating layer 18 is brought into contact with the flat and smooth surface 22A of the light-transmissive material 22 through the spherical beads 20 which are put between them. The spherical beads are 1 &mgr;m or less in half bandwidth of the distribution of particle diameters and are made uniform in height projecting from the coating layer 18.

Abstract: Many embodiments of the present invention are imbued with both sight-facilitative and touch-facilitative characteristics. The invention's unitary resinous matrix configuration encompasses, in the form of small discrete bodies, three genres (luminescent, reflective, retroreflective) of visually enhancing material along with tactilely enhancing material. The retroreflective and abrasive bodies partially project at a light-exposable surface of the resinous matrix material; the luminescent and reflective (diffuse and/or specular) bodies lie beneath the light-exposable surface. The luminescent, reflective and retroreflective bodies are complementarily and cumulatively effective; in particular, they versatilely afford increased visibility at practically all angular lines of sight as well as under practically all deficient illuminative conditions. The abrasive bodies afford vehicular skid prevention, surefootedness and the capability to manually and/or pedally “feel one's way” to safety.

Abstract: An adhesive layer is provided on a base material in the shape of an elongated film, powder particles are adhered thereon, and then other powder particles and media vibrated in a container are contacted with this adhesive layer. Next, the powder particles are embedded on the surface of the adhesive layer as a monolayer in which part of the powder particle protrudes, so as to form a laminate, and excess powder particles adhered to the laminate are removed. Therefore, a monolayer powder film, consisting of many powder particles embedded as a monolayer so that part thereof protrudes, is produced.

Abstract: Sheeting material is disclosed that contains a retroreflective layer and a layer of luminescent material on the bottom or lower surface of the retroreflective layer. The sheeting material can be formed into signage or decorative articles that are highly visible under a variety of lighting conditions. A portion of the retroreflective layer is visible through the luminescent layer or through one or more openings in the luminescent layer which are in the form of slits, perforations, alphanumeric or other patterns. The luminescent layer can be imaged using analog or digital printing processes. The sheeting material can be made from materials that are suitable for back-lit illumination. Adhesives or other conventional attachment means can be employed to anchor the signs in interior or exterior environments.

Abstract: This invention relates to retroreflective sheeting which has an image, such as an image. More specifically, the image has varying appearance at different angles of view. The retroreflective sheeting has a layer of transparent microsphere lenses, a transparent polymeric spacing layer underlying, contacting, and conforming to the bottom of the lenses, the spacing and conformation of which is critical to the optimal performance of the retroreflective article, a reflective layer having a top surface in contact with the back surface of the spacing layer and a topcoat and/or cover sheet overlying and conforming to the top surfaces of the lenses and having a flat top surface or face. In another embodiment, the retroreflective sheeting includes a pressure sensitive adhesive underlying and in contact with the reflective layer. The retroreflective sheeting has an image whose proportions are determined by a non-conformity of the reflective and spacing layer to the bottom of the lenses.

Abstract: Retrochromic articles have a retrochromic pattern comprising first and second viewable retroreflective regions, wherein at least one viewable retroreflective region comprises a plurality of intrinsically retrochromic beads. Methods for making such articles are also provided. Articles according to the present invention have covert security features, and may be used, for example, to authenticate security articles.

Abstract: A process for forming a retroreflective layer on a powder coated substrate is provided. The substrate is powder coated and the powder coating is subsequently partially cured. Reflective elements are then partially embedded in the semi-cured powder. The powder is then fully cured to permanently bond the reflective elements with the powder coating. The resultant retroreflective assembly can be used in any application requiring high detectability in poor visibility conditions, such as road signs and the like.

Abstract: The invention relates to a reflector system for positioning a medical instrument or of body parts of a patient or for any determination of position, which is characterized by reflectors (3, 4, 5) that are configured as transparent retroreflective spheres and may consist of a material with a refractive index of preferably 1.9.

Abstract: This invention relates to retroreflective sheeting which has an image, such as an image. More specifically, the image has varying appearance at different angles of view. The retroreflective sheeting has a layer of transparent microsphere lenses, a transparent polymeric spacing layer underlying, contacting, and conforming to the bottom of the lenses, the spacing and conformation of which is critical to the optimal performance of the retroreflective article, a reflective layer having a top surface in contact with the back surface of the spacing layer and a topcoat and/or cover sheet overlying and conforming to the top surfaces of the lenses and having a flat top surface or face. In another embodiment, the retroreflective sheeting includes a pressure sensitive adhesive underlying and in contact with the reflective layer. The retroreflective sheeting has an image whose proportions are determined by a non-conformity of the reflective and spacing layer to the bottom of the lenses.

Abstract: Encapsulated-lens retroreflective sheeting is described which contains an improved binder layer. The binder layer is obtained from a film-forming mixture which comprises: (A) a vinyl chloride copolymer, (B) a thermoplastic polyurethane, and (C) an aminoplast resin. Such binder layer exhibits improved adhesion to metallized beads and to a variety of cover films such as acrylic films.

Abstract: A reflective pavement marker comprises an integrally molded one-piece structural body and at least one reflective plate attachment, said structural body having two opposing planar inclined reflective faces, multiple hollow cavities which are defined by partitioning and load carrying walls with wedge shaped top surfaces, said hollow cavities open within a recessed portion of said reflective faces, two arcuate sides and integrally sealed planar base surface with textures and recessed grooves. The reflective plates are welded within the periphery of said recessed portion that includes wedge shaped top surfaces of the hollow cavity walls. This marker provides to enhance the reflective cell sizes, improved impact resistance and improve resistance to flexural stresses due to automobiles impact forces; this is accomplished by maximizing the base surface area for adhesive wetting parameter. The body can be made of various recycled or virgin structural plastics with high impact resistance and UV stability.

Abstract: The present invention relates to reflective elements comprising reinforcement particles dispersed within a glass or ceramic core and optical elements partially embedded into the core. The invention further relates to reflective articles, and in particular pavement markings, comprising the reflective elements as well as methods of making the reflective elements.

Abstract: This invention relates to retroreflective sheeting which has an image, such as an image. More specifically, the image has varying appearance at different angles of view. The retroreflective sheeting has a layer of transparent microsphere lenses, a transparent polymeric spacing layer underlying, contacting, and conforming to the bottom of the lenses, the spacing and conformation of which is critical to the optimal performance of the retroreflective article, a reflective layer having a top surface in contact with the back surface of the spacing layer and a topcoat and/or cover sheet overlying and conforming to the top surfaces of the lenses and having a flat top surface or face. In another embodiment, the retroreflective sheeting includes a pressure sensitive adhesive underlying and in contact with the reflective layer. The retroreflective sheeting has an image whose proportions are determined by a non-conformity of the reflective and spacing layer to the bottom of the lenses.

Abstract: In an optical sheet 10 having a prism surface 16 formed by providing unit prisms 14 on the upper surface of a transparent base material 12, a coating layer 18 is provided on the reverse surface of the transparent base material opposite to the prism surface 16, spherical beads 20 are arranged projecting from the surface of the coating layer 18 by 1 to 10 &mgr;m in height, and the coating layer 18 is brought into contact with the flat and smooth surface 22A of the light-transmissive material 22 through the spherical beads 20 which are put between them. The spherical beads are 1 &mgr;m or less in half bandwidth of the distribution of particle diameters and are made uniform in height projecting from the coating layer 18.

Abstract: Retroreflective sheeting (1) comprises a reflective base (2), a transparent film layer (4) which is colored different from the color of reflected light of the reflective base (2) and a pressure-sensitive adhesive layer (3). The transparent film layer (4) is removably provided on the reflective base (2) via the pressure-sensitive adhesive layer (3). Part (4′) of the transparent film layer (4) is to be cut out on use so that the transparent film layer (4) may form a desired image. The peel strength between the transparent film layer (4) and the reflective base (2) is 25 to 400 gf/25 mm. After the transparent film layer (4) is pressed to the reflective base (2) under a pressure of 5 kgf/cm2, the peel strength between the transparent film layer (4) and the reflective base (2) is 700 gf/25 mm or greater.

Abstract: The articles of the present invention comprise pavement marking articles which are retroreflective under dry and/or wet conditions. The articles comprise a monolayer of exposed-lens optical elements, a spacing layer, and a reflective layer. The present invention also provides a method of making said pavement marking articles.

Abstract: To provide a retroreflective sheet which is suitable for co-molding by injection molding or the like, wherein the retroreflective sheet can be laid within a mold and molded with a resin to form a molded product, and, after molding, the sheet retains a significant portion of its reflection luminance and appearance as compared with the reflection luminance value before molding. A retroreflective sheet used for a co-molding, comprising a metallic reflective layer, a microspherical lens layer disposed as a single layer, and a transparent focal resin layer disposed between the reflective layer and the microspherical lens layer, in which the focal resin layer comprises a mixture of cellulose ester and polyvinyl butyral resin.

Abstract: A retroreflective article that exhibits suitable retroreflective luminance under dry and dynamic wet conditions. The article includes an enclosed-lens retroreflective sheeting that, under dry conditions, exhibits a coefficient of retroreflective luminance of about 40 (millicandela/m2)/lux as measured by ASTM D 4061-94 and, under dynamic wet conditions the sheeting increases in coefficient of retroreflective luminance. The article further includes a plurality of retroreflective elements partially embedded in a light transmissible bonding layer on the front, reflective surface of the retroreflective sheeting.

Abstract: Exposed lens retroreflective appliques incorporate a monolayer of beads and a dielectric mirror proximate the beads. A pigmented or otherwise colored bead bond layer in which the beads are partially embedded is visible through the dielectric mirror, giving the article a highly colored daytime appearance. The appliques exhibit an initial reflectivity. By appropriate materials selection, the appliques can be made to retain at least 75%, and in most instances at least 90%, of the initial reflectivity if subjected to fifty home laundering cycles. In one case the dielectric mirror includes zinc sulfide as a relatively high refractive index material and calcium fluoride as a relatively low refractive index material. In another case the dielectric mirror includes zinc sulfide as the relatively high refractive index material and silicon dioxide as the relatively low refractive index material.

Abstract: The pavement marking article comprises a substrate, a plurality of protrusions provided on the surface of the substrate, and first transparent microspheres having a refractive index of not less than 2.0 fixed at least on the surface of the substrate between adjacent protrusions.

Abstract: A cube corner article having a structured surface of geometric structures, each geometric structure having a plurality of faces at least some of which are arranged as a cube corner element, is made by providing a first substrate having a plurality of grooves therein, replicating the first substrate in a second substrate, and forming a second plurality of grooves in the second substrate. Geometric structures in the second substrate are formed in part by replication of the first plurality of grooves and in part by the formation of the second plurality of grooves.

Abstract: Surface coverings for marking road surfaces are disclosed including elastic particles for application to the road surface, the elastic particles including a plurality of light reflectors such as glass beads or ceramic particles, which can also include various pigments.

Abstract: The articles of the present invention comprise pavement marking articles which are retroreflective under dry and/or wet conditions. The articles comprise a monolayer of exposed-lens optical elements, a spacing layer, and a reflective layer. The present invention also provides a method of making said pavement marking articles.

Abstract: This invention relates to retroreflective sheeting which has an image, such as an image. More specifically, the image has varying appearance at different angles of view. The retroreflective sheeting has a layer of transparent microsphere lenses, a transparent polymeric spacing layer underlying, contacting, and conforming to the bottom of the lenses, the spacing and conformation of which is critical to the optimal performance of the retroreflective article, a reflective layer having a top surface in contact with the back surface of the spacing layer and a topcoat and/or cover sheet overlying and conforming to the top surfaces of the lenses and having a flat top surface or face. In another embodiment, the retroreflective sheeting includes a pressure sensitive adhesive underlying and in contact with the reflective layer. The retroreflective sheeting has an image whose proportions are determined by a nonconformity of the reflective and spacing layer to the bottom of the lenses.

Abstract: A retroreflective article that has a layer of optical elements and a multilayer reflective coating disposed on the optical elements. The reflective coating reflects light back into the optical elements so that it can be returned toward the light source. The multilayer reflective coating has multiple polymer layers and has layers that possess different refractive indices.

Abstract: A manufacturing method of a compound substrate for light-reflective application is proposed, by which the mechanical utility can be simplified, the cost is reduced and the light-reflective article made by the compound substrate has uniform light-reflecting effect.

Abstract: In an optical sheet 10 having a prism surface 16 formed by providing unit prisms 14 on the upper surface of a transparent base material 12, a coating layer 18 is provided on the reverse surface of the transparent base material opposite to the prism surface 16, spherical beads 20 are arranged projecting from the surface of the coating layer 18 by 1 to 10 &mgr;m in height, and the coating layer 18 is brought into contact with the flat and smooth surface 22A of the light-transmissive material 22 through the spherical beads 20 which are put between them. The spherical beads are 1 &mgr;m or less in half bandwidth of the distribution of particle diameters and are made uniform in height projecting from the coating layer 18.

Abstract: A fluorescent red article comprising a polymer matrix; and a perylene dicarboximide dye, wherein the article has chromaticity coordinates (x, y) within the area defined by (0.648, 0.351), (0.735, 0.265), (0.629, 0.281) and (0.565, 0.346) in terms of the CIE 1931 Standard Colorimetric System and measured using 0/45 geometry and evaluated with CIE Standard Illuminant D65 and a fluorescence luminance factor of at least about 8, and laminates, retroreflective materials, and methods of making thereof.

Abstract: Thin multilayer signature control films having a large differential between the indices of refraction of adjoining layers are characterized by the use as the low index layer or layers of a material having a high coefficient of extinction and a very low index of refraction. The enhanced differential between the indices of refraction results in signature control materials which, in one embodiment, may be comprised of just a substrate and a coating and, in another embodiment, may be a supported or unsupported multilayer film comprised of as few as three layers that have performance characteristics equal to or exceeding prior art films comprised of 15-30 layers. Both continuous films and pigmented liquid coating compositions for signature control are provided. Improved pigments for liquid coating compositions are comprised of appropriately coated microspheres and microballoons.

Abstract: A sure and efficient manufacturing method of a translucent type screen using micro glass beadsis probided. A carbon toner is scattered onto micro glass beads which are buried and fixed in a UV curable resin layer, and the carbon toner is uniformly filled in the gaps between the micro glass beads by a rotating brush or a press roll or the like. The supply and filling of the carbon toner may be simultaneously performed by an air jet nozzle. Subsequently, an extra fine fiber cloth, sticky roll or the like is continuously brought into contact with the upper surface of the carbon toner to remove the carbon toner at the light emission portion of the micro glass beads.

Abstract: Disclosed herein are novel electrophoretic displays and materials useful in fabricating such displays. In particular, novel encapsulated displays are disclosed. Particles encapsulated therein are dispersed within a suspending, or electrophoretic, fluid. This fluid may be a mixture of two or more fluids or may be a single fluid. The displays may further comprise particles dispersed in a suspending fluid, wherein the particles contain a liquid. In either case, the suspending fluid may have a density or refractive index substantially matched to that of the particles dispersed therein. Finally, also disclosed herein are electro-osmotic displays. These displays comprise at least one capsule containing either a cellulosic or gel-like internal phase and a liquid phase, or containing two or more immiscible fluids. Application of electric fields to any of the electrophoretic displays described herein affects an optical property of the display.

Abstract: A retroreflective article that has a layer of optical elements and a multilayer reflective coating disposed on the optical elements. The reflective coating reflects light back into the optical elements so that it can be returned toward the light source. The multilayer reflective coating has multiple polymer layers and has layers that possess different refractive indices.

Abstract: A simplified method and apparatus for creating counterfeit-resistant labels is described. A laser is used to mark a retro-reflective material such that light only from specific directions are reflected back towards the source. During authentication of the labels, the label is tilted to verify that only light from the specific directions are reflected back towards the source.

Abstract: A simplified method and apparatus for creating counterfeit-resistant labels is described. A laser is used to mark a retro-reflective material such that light only from specific directions are reflected back towards the source. During authentication of the labels, the label is tilted to verify that only light from the specific directions are reflected back towards the source.

Abstract: A retroreflective article that has a layer of optical elements and a multilayer reflective coating disposed on the optical elements. The reflective coating reflects light back into the optical elements so that it can be returned toward the light source. The multilayer reflective coating has multiple polymer layers and has layers that possess different refractive indices.

Abstract: An improved, “fail-safe” safety device comprising, in combination, a backlighted fluorescent film and a retroreflective sheet.

Abstract: In an optical sheet 10 having a prism surface 16 formed by providing unit prisms 14 on the upper surface of a transparent base material 12, a coating layer 18 is provided on the reverse surface of the transparent base material opposite to the prism surface 16, spherical beads 20 are arranged projecting from the surface of the coating layer 18 by 1 to 10 .mu.m in height, and the coating layer 18 is brought into contact with the flat and smooth surface 22A of the light-transmissive material 22 through the spherical beads 20 which are put between them. The spherical beads are 1 .mu.m or less in half bandwidth of the distribution of particle diameters and are made uniform in height projecting from the coating layer 18.