Abstract: An electric storage device includes a negative electrode, a positive electrode, and a separator interposed between the negative electrode and the positive electrode, the negative electrode including a negative electrode layer including an active material including an amorphous carbon particle capable of occluding and releasing at least one of an alkali metal and an alkaline earth metal, and a binder. The negative electrode layer includes a plurality of pores, and a ratio S1/S2 of a specific surface area (S1) of micropores having a pore diameter of 1 nm or more and 3 nm or less in the pores to a specific surface area (S2) of mesopores having a pore diameter of 20 nm or more and 100 nm or less therein is 0.3 or more and 0.9 or less.

Abstract: An improved carbon dioxide composite getter having a CO2-permeable envelope containing powders of two active materials (11, 11?, 11?, 12, 12?, 12?) and sealed systems employing such improved carbon dioxide composite getter are described.

Abstract: Embodiments described herein relate generally to electric double layer capacitors having an electrolyte formulation that includes a quantity of a stabilizing additive such that the electrochemical double layer capacitors retain cell capacitance for longer periods of time, generate less gas during operation, and experience less long term ESR. In some embodiments, an electrolyte formulation includes an ionic species, a solvent, and a stabilizer. In some embodiments the stabilizer contains a moiety that promotes adsorption to a surface, such as a carbon surface, and a moiety that promotes polarity of the stabilizer. In some embodiments, the solvent can be a nitrile compound and the stabilizer can be a compound of the formula I: Such that R is H, saturated or unsaturated, linear or branched, acyclic carbon group, OH, halogen NH2, NO2, (SO)2CF3, or monocyclic or polycyclic aryl, and n is an integer from 0 to 5.

Abstract: Provided are a multi-layered graphene film, a method of manufacturing the multi-layered graphene film, and an energy storage device using the multi-layered graphene film as an electrode. The multi-layered graphene film includes a first graphene layer, a spacer layer provided on the first graphene layer, and an upper graphene layer provided on the spacer layer. The spacer layer is provided to maintain a desired distance between the first graphene layer and the upper graphene layer. A plurality of layers with different layer configurations are further provided between the spacer layer and the upper graphene layer. The spacer layer may a graphene or a graphene oxide layer.

Abstract: The invention concerns a positioning spacer for positioning electrical energy storage elements, such as supercapacitors or ultracapacitors connected in series, in an electrical energy storage module, wherein the spacer comprises a first support part and a second part forming a rim relative to the first part, the positioning spacer comprising, at the free end of the second part thereof, at least one housing recess, the spacer being made from an electrically insulating material.

Abstract: Embodiments of the present disclosure, in one aspect, relate to composites including a carbon nanomaterial having a redox-active material, such as a polymer containing redox groups, disposed on the carbon nanomaterial, methods of making the composite, methods of storing energy, and the like.

Abstract: A process for fabricating an electrochemical supercapacitor is disclosed herein. The process comprises depositing a carbon nanotube layer onto a first substrate; depositing a layer of metal oxide material onto the substrate forming a first electrode; depositing an electrolytic material onto the electrode; and joining the electrode to a first face of a solid electrolyte membrane such that the electrolytic material is disposed between the electrode and the electrolytic membrane. The carbon nanotubes, the metal oxide and the electrolytic material comprise distinct layers. An electrochemical supercapacitor fabricated by the above-referenced process is also disclosed.

Abstract: A storage cell includes a positive electrode that includes a positive electrode current collector and a positive electrode active material layer which is formed on a surface of the positive electrode current collector and contains activated carbon, a negative electrode that includes a negative electrode current collector and a negative electrode active material layer which is formed on a surface of the negative electrode current collector and contains lithium titanate, and a separator that is disposed between the positive electrode active material layer and the negative electrode active material layer and is impregnated with an electrolytic solution which has lithium ion conductivity, in which a charge and discharge capacity through lithium ion occlusion is 16 mAh to 152 mAh per gram of the lithium titanate.

Abstract: An ultracapacitor that includes an energy storage cell immersed in an electrolyte and disposed within an hermetically sealed housing, the cell electrically coupled to a positive contact and a negative contact, wherein the ultracapacitor is configured to output electrical energy within a temperature range between about 80 degrees Celsius to about 210 degrees Celsius. Methods of fabrication and use are provided.

Abstract: The present disclosure provides a separator and an electrochemical device, the separator is provided with a folded structure unit across a widthwise direction of the separator, and an overlapping part of the folded structure unit is filled with an adhesive. When the separator is applied into a production of the electrochemical device, a winding process can be performed as usual. After an electrolyte injection or high temperature aging of the electrochemical device, the adhesive filled in the folded structure unit of the separator may be dissolved into the electrolyte, the folded structure unit can be unfolded to a flat position again, so as to effectively eliminate deformation of the electrochemical device, which may be caused by thermal contraction of the separator, over stress in the separator wound in a cell, or the separator's binding on expansion of negative and positive electrodes, during operation and production of the electrochemical device.

Abstract: The invention relates to a method for manufacturing a unit for storing electrical energy, comprising a cover and an outer casing, the method including a closing step (400) consisting of contactlessly applying a compressive force to one of the parts forming the storage unit, such that the cover and the outer casing are mechanically titled into one another so as to close the outer casing using the cover by means of the engagement of the shapes thereof.

Abstract: An energy storage device comprises at least one porous structure (500, 900) containing multiple channels (510), each one of which has an opening to a surface (505) of the porous structure. Each one of the channels has a first end (511) having a first average width (513) and a second end (512) having a second average width (514), with the first end being located where the channel opens to the surface of the porous structure and the second end being located at a distance from the first end as measured along a length of the channel. For at least some of the channels, the first average width is larger than the second average width.

Abstract: Ultracapacitor electrodes having an enhanced electrolyte-accessible surface area are provided. Such electrodes can include a porous substrate having a solution side and a collector side, the collector side operable to couple to a current collector and the solution side positioned to interact with an electrolytic solution when in use. The electrode can also include a conductive coating formed on the solution side of the porous substrate. The coating can have a first side positioned to interact with an electrolytic solution when in use and a second side opposite the first side. The coating can have discontinuous regions that allow access of an electrolyte solution to the second side during use to enhance electrolyte-accessible surface area of the conductive coating.

Abstract: A porous coordination polymer-ionic liquid composite according to the present invention includes an insulating structure composed of a porous coordination polymer, and an ionic liquid retained inside pores of the porous coordination polymer. The porous coordination polymer preferably has a main chain containing a typical metal element.

Abstract: Electrodes, energy storage devices using such electrodes, and associated methods are disclosed. In an example, an electrode for use in an energy storage device can comprise porous silicon having a plurality of channels and a surface, the plurality of channels opening to the surface; and a structural material deposited within the channels; wherein the structural material provides structural stability to the electrode during use.

Abstract: The present invention relates to electrolyte systems and electrochemical cells comprising conductive salts having different anionic and/or cationic radii.

Abstract: The present disclosure includes various assemblies to be used with one or more energy storage devices. In one embodiment, an energy storage device assembly can include a plurality of energy storage devices, and each of these energy storage devices can include a first projecting electrode and a second projecting electrode. The energy storage devices can be connected to each other through a weld, which can directly bond the adjacent first and second projecting electrodes of adjacent energy storage devices to one another. This configuration can allow each of the energy storage devices to be connected together in series.

Abstract: A storage module includes a plurality of stacked cell units, in which each of the cell units has a storage cell that has a pair of electrode tabs, and a frame body where the electrode tab of the storage cell that is adjacent in a stacking direction of the cell units is fixed, and each of the frame bodies has an elastic portion that presses the electrode tab to the other frame body other than one of the frame bodies.

Abstract: The present invention relates to a sheet composite of a metal compound and a fibrous carbon that can yield an electrode or an electrochemical element which achieves output property and high energy density, as well as a manufacturing method thereof. Sheer stress and centrifugal force are applied to a solution comprising a starting material metal compound and a fibrous carbon and reacted in a rotating reaction container to produce a composite material of metal compound and fibrous carbon. The composite material and a binder which is a fibrous carbon are stirred to produce a mixed solvent. The mixed solvent is subjected to suction filtration and vacuum drying. This mixed solution is molded in a paper machine to prepare a sheet composite. The fibrous carbon is carbon nanotubes having a specific surface area of 600 to 2600 m2/g.

Abstract: Embodiments of the present disclosure provide an energy storage device assembly, which may include: a plurality of energy storage devices, each energy storage device having a first electrode and a second electrode, the plurality of energy storage devices being connected to one another in series; and a liquid coolant transmission line in thermal communication with at least one of the plurality of energy storage devices.

Abstract: The present invention relates to a yarn-type micro-supercapacitor fabricated by twisting a hybrid nanomembrane coated with a conducting polymer on a carbon nanotube sheet. Thus, the yarn-type micro-supercapacitor has superior performance. Particularly, since a 2-ply electrode manufactured by being twisted together with a metal wire has very high power and energy density in liquid or solid electrolyte and also has superior mechanical strength and flexibility, the yarn-type micro-supercapacitor may be variously deformed—for example, bent, twisted, or woven—to maintain superior electrochemical performance.

Abstract: A power storage module for a hybrid system. The module includes internal absorption elements for absorbing electrolytes, and gasses thereof, that may have separated from a storage cell within the module owing to overvoltages. The module may further include external indicator(s) for indicating that such separated electrolytes are contained within the module case. It is possible to protect a user of the power storage module who wants to open the case of this module, in the event that the power storage cell has released electrolyte in gaseous and/or liquid form into the interior of the case.

Abstract: An electrochemical device has a lid, case, electric storage element, electrolyte, and conductive bonding material layer. The case has a via hole and forms a solution chamber between itself and the lid. The electric storage element is accommodated in the solution chamber. The electrolyte is accommodated in the solution chamber. The wiring has a via hole part provided in the via hole and connects the interior and exterior of the solution chamber. The conductive bonding material layer fixes the electric storage element onto the case while electrically connecting the electric storage element and via hole part, where the conductive bonding material layer has a contact area that contacts the case and non-contact area that does not contact the case and the non-contact area is formed in a manner surrounding the via hole.

Abstract: The invention relates to an electrical energy storage assembly comprising an envelope and a capacitive element (30) contained in the envelope, said envelope comprising: at least one side wall (22); and two bottom walls (41) each located at an end of the side wall. Said storage assembly comprises at least one electroconductive intermediate connection part (50) to be arranged between the capacitive element and a bottom wall (41), in addition to a covering plate (51) for covering the end of the capacitive element (20), said covering plate (51) including at least one vent (53) for the passage of a fluid. The covering plate (51) is fixed to the capacitive element in such a way as to be in electrical contact therewith, and the intermediate connection part (50) is also fixed to the envelope in certain areas enabling a deformation of the bottom wall in relation to the intermediate connection part.

Abstract: An energy storage device having improved energy density performance may include an electrolyte having a salt concentration of about 0.6 moles/L (M) to about 0.95M. A final energy storage device product having a total mass of electrolyte that is at least 100% of a saturation quantity of electrolyte sufficient to fully saturate one or more electrode(s) and separator(s) of the device, and below a threshold quantity above the saturation quantity.

Abstract: Provided is an energy storage device provided with a negative electrode including a negative substrate having a surface, and a negative composite layer formed on the surface of the negative substrate and including a negative active material; a positive electrode including a positive substrate, and a positive composite layer formed on the positive substrate and including a positive active material; and a separator placed between the positive electrode and the negative electrode. 10% cumulative diameter D10 in the particle size distribution of the negative active material on a volume basis is 1.3 ?m or more, and 90% cumulative diameter D90 in the particle size distribution of the negative active material on a volume basis is 8.9 ?m or less. The surface of the negative substrate has a center line roughness Ra of 0.205 ?m or more and 0.781 ?m or less, and has a center line roughness Ra to a ten-point mean height Rz of 0.072 or more and 0.100 or less.

Abstract: A three-dimensional network aluminum porous body in which the amount of aluminum forming a skeleton of the three-dimensional network aluminum porous body is uneven in the thickness direction, and a current collector and an electrode each using the aluminum porous body, and a manufacturing method thereof. In such a sheet-shaped three-dimensional network aluminum porous body for a current collector, the amount of aluminum forming a skeleton of the three-dimensional network aluminum porous body is uneven in the thickness direction. For example, in the case where a cross section in the thickness direction of the three-dimensional network aluminum porous body is divided into three regions of a region 1, a region 2 and a region 3 in this order, each region is configured so that the average of the amounts of aluminum in the region 1 and the region 3 differs from the amount of aluminum in the region 2.

Abstract: An electric storage device having a multilayer body in which a separator layer is provided between a positive or negative first electrode and a second electrode of the opposite polarity to the first electrode, an electrolyte, and a package that holds the multilayer body and the electrolyte, and includes at least two first-polarity compound sheets, each configured by integrating a first-polarity collector electrode, a first-polarity active material layer provided on one main surface of the first-polarity collector electrode, and a separator layer that covers at least part of the one main surface. Another main surface of the first-polarity collector electrode in one of the at least two first-polarity compound sheets and another main surface of the first-polarity collector electrode in another of the first-polarity compound sheets are opposed to each other and joined via a joining layer. The joining layer contains a high-polymer having imide coupling in its main chain.

Abstract: Systems and methods in accordance with embodiments of the invention implement high-temperature tolerant supercapacitors. In one embodiment, a high-temperature tolerant super capacitor includes a first electrode that is thermally stable between at least approximately 80° C. and approximately 300° C.; a second electrode that is thermally stable between at least approximately 80° C. and approximately 300° C.; an ionically conductive separator that is thermally stable between at least approximately 80° C. and 300° C.; an electrolyte that is thermally stable between approximately at least 80° C. and approximately 300° C.; where the first electrode and second electrode are separated by the separator such that the first electrode and second electrode are not in physical contact; and where each of the first electrode and second electrode is at least partially immersed in the electrolyte solution.

Abstract: A multi-layer composite getter is described. Also described is a method for the manufacturing of the multi-layer composite getter and electrochemical devices for energy storage that employ the multi-layer composite getter.

Abstract: The invention generally encompasses phosphonium ionic liquids, salts, compositions and their use in many applications, including but not limited to: as electrolytes in electronic devices such as memory devices including static, permanent and dynamic random access memory, as electrolytes in energy storage devices such as batteries, electrochemical double layer capacitors (EDLCs) or supercapacitors or ultracapacitors, electrolytic capacitors, as electrolytes in dye-sensitized solar cells (DSSCs), as electrolytes in fuel cells, as a heat transfer medium, among other applications. In particular, the invention generally relates to phosphonium ionic liquids, salts, compositions, wherein the compositions exhibit superior combination of thermodynamic stability, low volatility, wide liquidus range, ionic conductivity, and electrochemical stability. The invention further encompasses methods of making such phosphonium ionic liquids, salts, compositions, operational devices and systems comprising the same.

Abstract: The invention provides an electrochemical cell comprising an electrolyte and a multi-layer article, the multi-layer article comprising a first electrode, a second electrode in ionically conductive contact with the first electrode, and a separator disposed between and in contact the first electrode and the second electrode. The separator comprises a nanoweb, the nanoweb comprising nanofibers of a cross-linked polyimide, wherein the cross-linked polyimide is derived from an aromatic dianhydride, an aromatic diamine, and a reactive end-capper. The reactive end-capper is at least one of a functionalized anhydride or a functionalized amine, functionalized with a reactive functionality selected from the group consisting of acetylene, vinyl, epoxide, nitrile, and ester. The electrochemical cell also comprises a first current collector in electrically conductive contact with the first electrode and a second current collector in electrically conductive contact with the second electrode.

Abstract: Described herein are liquid, organosilicon compounds that including a substituent that is a cyano (—CN), cyanate (—OCN), isocyanate (—NCO), thiocyanate (—SCN) or isothiocyanate (—NCS). The organosilicon compounds are useful in electrolyte compositions and can be used in any electrochemical device where electrolytes are conventionally used.

Abstract: A capacitor has a positive electrode, a negative electrode, and a solid electrolyte layer arranged between the electrode layers. At least one of the electrode layers of this capacitor has an Al porous body, and an electrode body held in this Al porous body to polarize the electrolyte. The oxygen content in the surface of the Al porous body is 3.1% by mass or less. The matter that the oxygen content in the surface of the Al porous body is 3.1% by mass or less is equal to the matter that a high-resistance oxide film is hardly formed on the surface of the Al porous body. Thus, this Al porous body makes it possible to make the current collector area of the electrode layer large so that the capacitor can be improved in capacity.

Abstract: Disclosed is an electrochemical capacitor that can be reflow soldered, and wherein film package is used on the capacitor body. The container (20) of the electrochemical capacitor (ECC) stores the film package (11) of the capacitor body (10) within a storage space (SR) such that sealing sections (11a-11c) do not contact the inner surface of the storage space (SR). Inner material (30), which cover the sealing sections (11a-11c) and rear edge of the film package 11 and are adhered to the inner surface of the storage space (SR), affixing the film package (11) within the storage space (SR), are provided in a rectangular framework to the regions in the storage space (SR) of the container (20) that correspond to said sealing sections (11a-11c) and rear edge.

Abstract: An electrode for an electrochemical device includes a current collector and an electrode layer. The current collector has a main face and a side face. The side face has a concave-convex shape whose convex part is constituted by a projection extending along the main face. The projection is formed along a periphery of the electrode layer, forming a support portion. The electrode layer contains active material and is formed on and in contact with the main face including a surface formed by the support portion. The electrode is capable of mitigating the concentration of current at the edges of the electrode layer.

Abstract: An electrode for an electrochemical device includes a current collector, electrode layer, and active material layer. The electrode layer is formed on the current collector and contains an active material. The active material layer is formed in an area on the current collector where the electrode layer is not formed, and contains an active material. The electrode is capable of reducing the leak current while improving the device reliability.

Abstract: Techniques described herein generally relate to the fabrication of ultra-capacitor. In one or more embodiments of the present disclosure, methods for fabricating an ultra-capacitor are described that may include preparing a substrate surface of a silicon wafer. The methods may further include etching one or more nano-structures on the substrate surface of the silicon wafer with a galvanic displacement process, and constructing electrodes for the ultra-capacitor from the silicon wafer with the one or more nano-structures.

Abstract: Improved electrodes and currents through the use of organic and organometallic high dielectric constant materials containing dispersed conductive particles in energy storage devices and associated methods are disclosed. According to an aspect, a dielectric material includes at least one layer of a substantially continuous phase material comprising a combination of organometallic having delocalized electrons, organic compositions and containing metal particles in dispersed form, in another aspect, the novel material is used with a porous electrode to further increase charge and discharge currents.

Abstract: The present invention relates to a method for manufacturing an electrode of a supercapacitor, comprising: (A) providing a carbon substrate and a phosphorus-containing precursor, and mixing the carbon substrate and the phosphorus-containing precursor at a ratio of 1:100 to 1000:1 by weight; (B) heating the mixture of the carbon substrate and the phosphorus-containing precursor to a temperature between 300° C. and 1100° C. to obtain a P-doped carbon substrate; and (C) forming an electrode of a supercapacitor by using the P-doped carbon substrate. The present invention also relates to a supercapacitor which comprises: a first electrode; a second electrode; and an electrolyte that is interposed between the first electrode and the second electrode, wherein at least one of the first electrode and the second electrode is prepared by the above-mentioned method.

Abstract: A composite electrode structure and methods of making and using thereof are disclosed. The structure has a metal substrate with a metal oxide layer. The average thickness of the metal oxide layer is less than 150 nm, and comprises at least a first metal and a second metal, wherein the first metal and the second metal are different elements. A plurality of carbon nanotubes is disposed on a first surface of the metal oxide layer. At least a portion of the carbon nanotubes are disposed such that one end of the carbon nanotube is positioned at least 5 nm below the surface of the metal oxide layer.

Abstract: One object is to provide a power storage device including an electrolyte using a room-temperature ionic liquid which includes a univalent anion and a cyclic quaternary ammonium cation having excellent reduction resistance. Another object is to provide a high-performance power storage device. A room-temperature ionic liquid which includes a cyclic quaternary ammonium cation represented by a general formula (G1) below is used for an electrolyte of a power storage device. In the general formula (G1), one or two of R1 to R5 are any of an alkyl group having 1 to 20 carbon atoms, a methoxy group, a methoxymethyl group, and a methoxyethyl group. The other three or four of R1 to R5 are hydrogen atoms. A? is a univalent imide anion, a univalent methide anion, a perfluoroalkyl sulfonic acid anion, tetrafluoroborate (BF4?), or hexafluorophosphate (PF6?).

Abstract: Provided is a supercapacitor including: a power storage aggregate in which a plurality of unit modules are laminated; a case in which the power storage aggregate is disposed; an upper plate that is sealably mounted on an upper surface of the case; a lower plate that is sealably mounted on a lower surface of the case; and reinforcing plates that are disposed in the inner surfaces of the upper plate and the lower plate thereby reinforcing strength of the upper and lower plates, to thereby provide an effect of preventing the upper plate and the lower plate from being bent due to a rolling force of a power storage aggregate that is laminated in the case, and block an electrolyte from leaking.

Abstract: A self-charging power pack (300) includes a cathode (312) and an anode (310) that is spaced apart from the cathode (312). An electrolyte (318) is disposed between the anode (310) and the cathode (312). A piezoelectric ion transport layer (322) is disposed between the anode (310) and the cathode (312). The piezoelectric ion transport layer (322) has a piezoelectric property that generates a piezoelectric field when a mechanical force is applied thereto. The piezoelectric field causes transportation of ions in the electrolyte (318) through the piezoelectric ion transport layer (322) towards the anode (310).

Abstract: The invention pertains to an aqueous electrode-forming composition comprising:—at least one fluoropolymer [polymer (F)];—particles of at least one powdery active electrode material [particles (P)], said particles (P) comprising a core of an active electrode compound [compound (E)] and an outer layer of a metallic compound [compound (M)] different from Lithium, said outer layer at least partially surrounding said core; and—water, to a process for its manufacture, to a process for manufacturing an electrode structure using the same, to an electrode structure made from the same and to an electrochemical device comprising said electrode structure.

Abstract: A process for manufacturing an electrode utilizing electron beam (EB) or actinic radiation to cure the electrode binder is provided. A process is also disclosed for mixing specific actinic or EB radiation curable polymer precursors with electrode solid particles to form an aqueous mixture, application of the mixture to an electrode current collector, followed by the application of actinic or EB radiation to the current collector for curing the polymer, thereby binding the electrode binder to the current collector. Lithium ion batteries, electric double layer capacitors, and components produced therefrom are also provided.

Abstract: Supercapacitors have composite electrodes that include a porous carbonaceous material such as graphene onto which a metal oxide pseudocapacitor material is deposited in the form of nano-scale particles or a nano-scale film. The composite electrodes exhibit excellent specific capacitance, even at high scan rates.

Abstract: A capacitor provides a plurality of selectable capacitance values, by selective connection of six capacitor sections of a capacitive element each having a capacitance value. The capacitor sections are provided in a plurality of wound cylindrical capacitive elements. Two vertically stacked wound cylindrical capacitance elements may each provide three capacitor sections. There may be six separately wound cylindrical capacitive elements each providing a capacitor section. The capacitor sections have a common element terminal.

Abstract: An energy storage device comprises a first porous semiconducting structure (510) comprising a first plurality of channels (511) that contain a first electrolyte (514) and a second porous semiconducting structure (520) comprising a second plurality of channels (521) that contain a second electrolyte (524). In one embodiment, the energy storage device further comprises a film (535) on at least one of the first and second porous semiconducting structures, the film comprising a material capable of exhibiting reversible electron transfer reactions. In another embodiment, at least one of the first and second electrolytes contains a plurality of metal ions. In another embodiment, the first and second electrolytes, taken together, comprise a redox system.

Abstract: A carbon based material produced from the consolidation of amorphous carbon by elevated temperature compression. The material having unique chemical and physical characteristics that lend themselves to a broad range of applications such as in electrical, electrochemical and structural fields.