Double Layer Electrolytic Capacitor Patents (Class 361/502)
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Patent number: 11164703Abstract: The present invention provides a supercapacitor assembly which is characterised by comprising: a supercapacitor comprised of carbon-containing anode(s) and cathode(s), intermediate porous membrane(s) and an ionic liquid electrolyte; an electrical heater for heating the supercapacitor; and a thermostat for controlling the heater and maintaining the temperature of the ionic liquid at a temperature such that its viscosity is in the range 1 to 50 centipoise. In particular, there are provided supercapacitors which can operate at voltages greater than 3.5v (for example, in the range 3.5 to 6v) without significant long term redox degradation.Type: GrantFiled: March 9, 2017Date of Patent: November 2, 2021Assignee: Oxcion LimitedInventors: Stephen David Voller, Timothy Walder, Marappa Rajendran, Jonathan Tuck
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Patent number: 11145469Abstract: A method for producing a porous carbon electrode includes preparing a slurry by mixing a porous, particulate, conductive carbon powder with a solution of a polymer binding agent for the particulate carbon powder in a solvent for the polymer binding agent, forming a precursor electrode by casting the slurry as a layer and subjecting the cast layer to a wet phase inversion to realize porosity in the cast layer, subjecting the thus obtained precursor electrode to a thermal treatment to cause oxidative stabilization, carbonization, dehydrogenation or cyclisation of the polymer binding agent or a combination of two or more of the afore mentioned phenomena by heating the precursor electrode and converting the polymer binding agent into a conductive binding agent binding the particles of the conductive carbon powder together.Type: GrantFiled: December 27, 2017Date of Patent: October 12, 2021Assignee: VITO NVInventors: Willy Doyen, Dennis Cardoen, Joost Helsen, Andre-Viktor Claes
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Patent number: 11139499Abstract: Disclosed are an apparatus for manufacturing a membrane electrode assembly to provide excellent mass transfer characteristics and durability and a manufacturing method using the same. A porosity gradient may be continuously imparted to electrodes of the membrane electrode assembly in a thickness direction thereby improving reactivity with external gas and transfer of internal ions.Type: GrantFiled: December 7, 2018Date of Patent: October 5, 2021Assignees: Hyundai Motor Company, Kia Motors CorporationInventors: Woo Jin Lee, Min Jin Kim, Ki Sub Lee, Su Won Seol
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Patent number: 11133133Abstract: A supercapacitor module is provided. In some implementations, the supercapacitor module may include a first supercapacitor having a first parameter value for a capacitor parameter in a first test condition. The supercapacitor module may include a second supercapacitor having a second parameter value for the capacitor parameter in about the first test condition. A ratio of the second parameter value to the first parameter value may be from about 0.8 to about 1.2. The supercapacitor module may prevent overvoltages across the first and second supercapacitors, such that the supercapacitor module may satisfactorily operate without a balancing circuit.Type: GrantFiled: September 6, 2018Date of Patent: September 28, 2021Assignee: AVX CorporationInventor: Shawn Hansen
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Patent number: 11127537Abstract: Electric double layer capacitor devices are disclosed. The devices may be suitable for operation of wide temperature ranges. In some cases, the capacitor features a solid state electrolyte that includes an ionic liquid doped polymer matrix.Type: GrantFiled: July 26, 2017Date of Patent: September 21, 2021Assignee: FASTCAP SYSTEMS CORPORATIONInventors: Nicolò Michele Brambilla, Fabrizio Martini
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Patent number: 11123696Abstract: The present invention relates to a method of manufacturing an integrated structure using microbubbles, and an integrated structure manufactured by the method.Type: GrantFiled: February 13, 2019Date of Patent: September 21, 2021Assignee: RESEARCH & BUSINESS FOUNDATION SUNGKYUNKWAN UNIVERSITYInventors: Pil Jin Yoo, Seon Ju Yeo, Min Jun Oh
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Patent number: 11120952Abstract: A process for producing a supercapacitor cell, comprising (a) Assembling a porous cell framework composed of a first conductive foam structure, a second conductive foam structure, and a porous separator, wherein the first and/or second conductive foam structure has a thickness no less than 200 ?m and at least 80% by volume of pores; (b) Preparing a first suspension of an anode active material dispersed in a liquid electrolyte and a second suspension of a cathode active material (e.g. graphene sheets) dispersed in a liquid electrolyte; and (c) Injecting the first suspension into pores of the first conductive foam structure to form an anode and injecting second suspension into pores of the second conductive foam structure to form a cathode, wherein the anode active material or the cathode active material constitutes an electrode active material loading >10 mg/cm2, preferably >15 mg/cm2, more preferably >20 mg/cm2.Type: GrantFiled: July 14, 2017Date of Patent: September 14, 2021Assignee: Nanotek Instruments Group, LLCInventors: Aruna Zhamu, Bor Z. Jang
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Patent number: 11118073Abstract: The present disclosure provides supercapacitors that may avoid the shortcomings of current energy storage technology. Provided herein are electrochemical systems, comprising three dimensional porous reduced graphene oxide film electrodes. Prototype supercapacitors disclosed herein may exhibit improved performance compared to commercial supercapacitors. Additionally, the present disclosure provides a simple, yet versatile technique for the fabrication of supercapacitors through the direct preparation of three dimensional porous reduced graphene oxide films by filtration and freeze casting.Type: GrantFiled: May 31, 2019Date of Patent: September 14, 2021Assignee: The Regents of the University of CaliforniaInventors: Richard Barry Kaner, Yuanlong Shao
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Patent number: 11107640Abstract: An energy storage device can include a cathode, an anode, and a separator between the cathode and the anode, and an electrolyte where the electrolyte includes one or more additives and/or solvent components selected from vinylene carbonate (VC), vinyl ethylene carbonate (VEC), dimethylacetamide (DMAc), hydro fluorinated ether branched cyclic carbonate, a hydro fluorinated ether ethylene carbonate (HFEEC), hydro fluorinated ether (HFE), and fluorinated ethylene carbonate (FEC). The electrolyte may include a carbonate based solvent and one or more solvent components and/or one or more of vinylene carbonate (VC), vinyl ethylene carbonate (VEC), dimethylacetamide (DMAc), hydro fluorinated ether branched cyclic carbonate, a hydro fluorinated ether ethylene carbonate (HFEEC), hydro fluorinated ether (HFE), and fluorinated ethylene carbonate (FEC).Type: GrantFiled: March 29, 2019Date of Patent: August 31, 2021Assignee: Maxwell Technologies, Inc.Inventors: Santhanam Raman, Xiaomei Xi, Xiang-Rong Ye, Jian Hong
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Patent number: 11087928Abstract: An electrolytic capacitor includes an anode body including a dielectric layer, a cathode body, and a conductive polymer layer and a liquid component that are disposed between the anode body and the cathode body. The cathode body includes a base material part having an outer surface that is roughened surface and has a pore opened at the outer surface, and an inorganic conductive layer covering at least a part of the outer surface. The base material part includes a first coating layer disposed along at least a part of inner wall of the pore. The first coating layer contains phosphorus.Type: GrantFiled: March 20, 2019Date of Patent: August 10, 2021Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.Inventors: Yoshiaki Ishimaru, Kazunari Imamoto, Tatsuji Aoyama
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Patent number: 11050080Abstract: An electrochemical cell includes an all-solid-state electrode body in which a positive electrode layer and a negative electrode layer are laminated together through a solid electrolyte and an exterior body having a cavity in which the electrode body is stored. The exterior body has a first case and a second case which sandwich the electrode body and a sealing member that defines the cavity together with the first case and the second case by joining the first case and the second. The thermal expansion coefficients of the electrode body, the first case, the second case, and the sealing member are all 10×10?6/° C. or lower.Type: GrantFiled: June 7, 2016Date of Patent: June 29, 2021Assignees: SEIKO INSTRUMENTS INC., OHARA INC.Inventors: Shunji Watanabe, Tsuneaki Tamachi, Kazuhito Ogasa, Ryohei Sato
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Patent number: 11037736Abstract: The present invention provides a lithium ion capacitor (LIC) that achieves high specific capacity and high energy density. The lithium ion capacitor according to the present invention includes a cathode, an anode arranged apart from the cathode, and a Li-ion electrolyte with which a space between the cathode and the anode is filled. The cathode is made of a composite of graphene and carbon nanotubes, the anode is made of a Li-doped composite of graphene and carbon nanotubes, and the mass ratio of the anode to the cathode is larger than 0 and less than 1.0.Type: GrantFiled: January 24, 2018Date of Patent: June 15, 2021Assignee: NATIONAL INSTITUTE FOR MATERIALS SCIENCEInventors: Jie Tang, Yige Sun, Luchang Qin
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Patent number: 11017958Abstract: Disclosed are methods for fabricating supercapacitors (SCs) via vapor printing, specifically oxidative chemical vapor deposition (oCVD). Also disclosed are methods of using the supercapacitors, in particular for energy storage devices and photovoltaics.Type: GrantFiled: February 7, 2018Date of Patent: May 25, 2021Assignee: Massachusetts Institute of TechnologyInventors: Andong Liu, Karen K. Gleason, Peter Kovacik
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Patent number: 11015067Abstract: According to one of various aspects of the present invention, a slurry for a flexible electrode contains a component (a) dispersed in an aqueous emulsion. The emulsion includes one or more polymer components selected from the group consisting of acrylic polymers, urethane polymers, fluorine polymers, urea polymers, chloroprene polymers, and butadiene polymers. The emulsion has a pH of 6.5 to 8.0. In the slurry, the total of the polymer component(s) and the component (a) is 20 to 30% by mass. Of the total of the polymer component(s) and the component (a) in the slurry, the polymer component(s) is 60 to 85% by mass, and the component (a) is 15 to 40% by mass. Component (a) is carbon black having a DBP absorption amount under uncompressed conditions of 150 to 300 mL/100 g and a BET specific surface area of 35 to 140 m2/g.Type: GrantFiled: August 6, 2018Date of Patent: May 25, 2021Assignee: DENKA COMPANY LIMITEDInventors: Yoko Horikoshi, Tetsuya Ito
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Patent number: 11007489Abstract: A carbonized PVDC copolymer useful for the separation of an olefin from its corresponding paraffin may be made by heating a polyvinylidene chloride copolymer film or hollow fiber having a thickness of 1 micrometer to 20 micrometers to a pretreatment temperature of 100° C. to 180° C. to form a pretreated polyvinylidene chloride copolymer film and then heating the pretreated polyvinylidene chloride copolymer film to a maximum pyrolysis temperature from 350° C. to 750° C. A process for separating an olefin from its corresponding paraffin in a gas mixture is comprised of flowing the gas mixture through the aforementioned carbonized polyvinylidene chloride (PVDC) copolymer to produce a permeate first stream having an increased concentration of the olefin and a second retentate stream having an increased concentration of its corresponding paraffin.Type: GrantFiled: March 14, 2017Date of Patent: May 18, 2021Assignee: Dow Global Technologies LLCInventors: Junqiang Liu, Janet M. Goss, Edward M. Calverley, Douglas E. Beyer
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Patent number: 10991476Abstract: A new solvent-based method is presented for making low-cost composite graphite electrodes containing a thermoplastic binder. The electrodes, termed thermoplastic electrodes (TPEs), are easy to fabricate and pattern, give excellent electrochemical performance, and have high conductivity (1500 S m?1). The thermoplastic binder enables the electrodes to be hot embossed, molded, templated, and/or cut with a CO2 laser into a variety of intricate patterns. These electrodes show a marked improvement in peak current, peak separation, and resistance to charge transfer over traditional carbon electrodes. The impact of electrode composition, surface treatment (sanding, polishing, plasma treatment), and graphite source were found to impact fabrication, patterning, conductivity, and electrochemical performance. Under optimized conditions, electrodes generated responses similar to more expensive and difficult to fabricate graphene and highly oriented pyrolytic graphite electrodes.Type: GrantFiled: May 22, 2020Date of Patent: April 27, 2021Assignee: Colorado State University Research FoundationInventors: Charles S. Henry, Kevin Klunder
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Patent number: 10987650Abstract: One aspect of the present invention relates to an adsorption filter containing an activated carbon and a fibrous binder. The adsorption filter has a density of 0.400 g/ml or more, and a pore volume at a pore diameter of 1 to 20 ?m is 0.60 ml/g or less as measured by mercury intrusion porosimetry.Type: GrantFiled: December 18, 2018Date of Patent: April 27, 2021Assignee: KURARAY CO., LTD.Inventors: Keita Takahashi, Takayuki Yoshikawa, Tetsuya Hanamoto, Hiroe Yoshinobu, Takayuki Yamada
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Patent number: 10984963Abstract: The present invention relates to a carbonaceous material having a specific surface area of 1,800 m2/g to 3,000 m2/g according to a BET method, an R-value of 1.2 or more and a G-band half-value width of 70 cm?1 or more according to a Raman spectrum.Type: GrantFiled: February 23, 2018Date of Patent: April 20, 2021Assignee: KURARAYCO., LTD.Inventors: Shohei Kobayashi, Motomi Matsushima, Taketoshi Okuno, Hideharu Iwasaki
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Patent number: 10968103Abstract: Copper-filled carbon nanotubes and methods of synthesizing the same are provided. Plasma-enhanced chemical vapor deposition can be used to synthesize vertically aligned carbon nanotubes filled with copper nanowires. The copper filling can occur concurrently with the carbon nanotube growth, and the carbon nanotubes can be completely filled by copper. The filling of Cu inside the CNTs can be controlled by tuning the synthesis temperature.Type: GrantFiled: July 23, 2020Date of Patent: April 6, 2021Assignee: The Florida International University Board of TrusteesInventors: Wenzhi Li, Arun Thapa
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Patent number: 10959467Abstract: The present invention provides to a wearable smart device having electrical wiring comprising a stretchable conductive composition having excellent in durability such as repeated bending properties and repeated twisting properties, a material for realizing the wearable smart device, and a method for producing the wearable start device. An electrical wiring including a fine line having an electrical line interval of 1 mm or less, preferably the line width of less than 1 mm, is formed by printing a paste for forming a stretchable conductor containing metal-based conductive particles and a non-crosslinked elastomer, and further dried and cured at a low temperature condition of 120° C. for 30 minutes. As a result, the wearable smart device having electrical wiring constituted by fine lines without sagging of the edge is obtained.Type: GrantFiled: March 7, 2017Date of Patent: March 30, 2021Assignee: TOYOBO CO., LTD.Inventors: Yuko Nakao, Satoshi Imahashi, Michihiko Irie, Takashi Kondo, Maki Kinami
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Patent number: 10957495Abstract: Provided is a supercapacitor comprising an anode, a cathode, an ion-permeable separator disposed between the anode and the cathode, and an electrolyte in ionic contact with the anode and the cathode, wherein at least one of the anode and the cathode contains multiple graphene sheets spaced by cellulosic nanofibers and has a specific surface area from 50 to 3,300 m2/g. Also provided is a process for producing an electrode for such a supercapacitor having a large electrode thickness, high active mass loading, high tap density, and exceptional energy density.Type: GrantFiled: January 3, 2018Date of Patent: March 23, 2021Assignee: Nanotek Instruments Group, LLCInventors: Aruna Zhamu, Bor Z. Jang
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Patent number: 10957492Abstract: An electrolytic capacitor is disclosed. In an embodiment an electrolytic capacitor includes a housing having a base and an opening arranged opposite the base and a closure element being at least partly introduced into the opening, wherein the closure element is configured to close the housing, wherein the closure element includes a sealing element for electrically insulating a connection between closure element and housing, and wherein the closure element comprises at least one first contact element for electrically conductive connecting a second contact element.Type: GrantFiled: March 27, 2017Date of Patent: March 23, 2021Assignee: TDK ELECTRONICS AGInventors: Norbert Will, Fabio Augusto Bueno de Camargo Mello, Igor Peretta, Emerson Almeida, Moisés Coster, Thales Machado
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Patent number: 10942099Abstract: A self-healing method for fractured single crystal SiC nanowires. A hair in a Chinese brush pen of yellow weasel's hair moves and transfers nanowires, which are placed on an in-situ TEM mechanical microtest apparatus. An in-situ nanomechanical tension test is realized. The nanowires are loaded. Displacement is 0-200 nm. Fracture strength of the single crystal nanowires is 12-15 GPa. After the nanowires are fractured, unloading causes slight contact between the fractured end surfaces, electron beam is shut off, and self-healing of the nanowires is conducted in a vacuum chamber. Partial recrystallization is found at a fracture after self-healing through in-situ TEM representation. A fracture strength test is conducted again after self-healing. A fractured position after healing is the same as the position before healing. The fracture strength of the single crystal nanowires after self-healing is 1-2.5 GPa. The recovery ratio of the fracture strength is 10-20%.Type: GrantFiled: November 15, 2017Date of Patent: March 9, 2021Assignee: Dalian University of TechnologyInventors: Zhenyu Zhang, Junfeng Cui, Yuefeng Du, Dongming Guo
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Patent number: 10944109Abstract: A Li/CFx primary battery having a lithium-based anode and a fluorinated carbon cathode. The fluorinated carbon cathode includes fluorinated carbon nanoparticles. The structure and size distribution of the carbon precursor carbon nanotubes are configured to provide improved battery performance. The fluorinated carbon nanoparticles can be formed by fluorinating carbon nanoparticles using a fluorine-based reactive gas at a temperature in the range from 300 to 600° C., and the fluorinated carbon nanoparticles can further be used to form the cathode of the primary battery. Producing the Li/CFx primary batter can also include heating the fluorinated carbon nanoparticles under an inert atmosphere before the fluorinated carbon nanoparticles are used to form the cathode of the primary battery.Type: GrantFiled: May 10, 2019Date of Patent: March 9, 2021Assignee: SCHLUMBERGER TECHNOLOGY CORPORATIONInventors: Hanpu Liang, Nathan Lawrence, Timothy Jones, Steven Gahlings, Christine Jarvis, Wen Rong Li, Rogerio Tadeu Ramos, Vladimir Hernandez Solis
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Patent number: 10943745Abstract: The electric storage device includes an electrode assembly having a positive electrode and a negative electrode, a case for housing the electrode assembly, a pressure relief valve, and positive and negative electrode conductive members that are electrically connected to the respective corresponding electrodes. The case has a wall in which the pressure relief valve is disposed. At least one of the positive and negative electrode conductive members includes an interposing portion located between the inner surface of the wall and an end face of the electrode assembly facing the inner surface, and a shielding portion located closer to the end face of the electrode assembly than the interposing portion. The shielding portion covers the pressure release valve from a side of the wall where the electrode assembly is located.Type: GrantFiled: March 31, 2017Date of Patent: March 9, 2021Assignee: KABUSHIKI KAISHA TOYOTA JIDOSHOKKIInventors: Yusuke Yamashita, Takayuki Hirose, Shinji Suzuki, Yasuaki Takenaka, Masato Ogasawara, Atsushi Minagata, Hirokuni Akiyama, Motoaki Okuda
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Patent number: 10938032Abstract: Provided herein are energy storage devices having an anode comprising a layered double hydroxide comprising divalent ions and trivalent ions both of which contribute to energy storage. In some embodiments, the specific combination of device chemistry, active materials, and electrolytes described herein form storage devices that operate at high voltage and exhibit the capacity of a battery and the power performance of supercapacitors in one device.Type: GrantFiled: February 7, 2020Date of Patent: March 2, 2021Assignee: The Regents of the University of CaliforniaInventors: Maher F. El-Kady, Haosen Wang, Richard B. Kaner
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Patent number: 10930444Abstract: An electrochemical device includes an element body, an exterior sheet, a seal part, and a leading terminal. The element body includes a pair of inner electrodes laminated to sandwich a separator sheet. The exterior sheet covers the element body. The seal part seals a peripheral part of the exterior sheet for immersing the element body in an electrolyte. The leading terminal extends outward from the seal part of the exterior sheet. The exterior sheet includes a front sheet and a back sheet. The front sheet includes a front-side metal sheet. The back sheet includes a back-side metal sheet.Type: GrantFiled: February 12, 2019Date of Patent: February 23, 2021Assignee: TDK CORPORATIONInventors: Hiroaki Hasegawa, Hidetake Itoh, Yoshihiko Ohashi, Yuji Yoshino, Kazunori Yoshikawa
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Patent number: 10923295Abstract: An energy storage device can include a cathode, an anode, and a separator between the cathode and the anode, where the anode and/or electrode includes an electrode film having a super-fibrillized binder material and carbon. The electrode film can have a reduced quantity of the binder material while maintaining desired mechanical and/or electrical properties. A process for fabricating the electrode film may include a fibrillization process using reduced speed and/or increased process pressure such that fibrillization of the binder material can be increased. The electrode film may include an electrical conductivity promoting additive to facilitate decreased equivalent series resistance performance. Increasing fibrillization of the binder material may facilitate formation of thinner electrode films, such as dry electrode films.Type: GrantFiled: February 27, 2017Date of Patent: February 16, 2021Assignee: Maxwell Technologies, Inc.Inventors: Santhanam Raman, James Borkenhagen, Xiaomei Xi, Xiang-Rong Ye
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Patent number: 10923729Abstract: A method of manufacturing a Lithium battery (100) with a current collector formed of pillars (11) on a substrate face (10), wherein the method comprises: forming elongate and aligned structures forming electrically conductive pillars (11) on the substrate face (10) with upstanding pillar walls extending from a pillar base to a pillar top; wherein the pillars are covered with a laminate comprising a first electrode (12), a solid state electrolyte layer (13); a second electrode layer (14), and a topstrate (20) forming an electrode part; and wherein at least one of the first electrode layer, second electrode layer and topstrate layer is non-conformally coated to prevent Lithium intercalation into the first or second electrode near the pillar base by limiting cracking at the pillar base when volume expansion/contraction of the electrode layers happens during the battery charge/discharge cycles.Type: GrantFiled: July 15, 2016Date of Patent: February 16, 2021Assignee: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk onderzoek TNOInventors: Sandeep Unnikrishnan, Lucas A. Haverkate
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Patent number: 10920334Abstract: A method for the electrohydrodynamic deposition of carbonaceous materials utilizing an electrohydrodynamic cell comprising two electrodes comprised of a conductive material, by first combining a solid phase comprising a carbonaceous material and a suspension medium, placing the suspension between the electrodes, applying an electric field in a first direction, varying the intensity of the electric field sufficiently to drive lateral movement, increasing the electrical field to stop the lateral transport and fix the layers in place, then removing the applied field and removing the electrodes. Among the many different possibilities contemplated, the method may advantageously utilize: varying the spacing between the electrodes; removing the buildup from one or both electrodes; placing the electrodes into different suspensions; adjusting the concentration, pH, or temperature of the suspension(s); and varying the direction, intensity or duration of the electric fields.Type: GrantFiled: March 21, 2017Date of Patent: February 16, 2021Assignee: THE TRUSTEES OF PRINCETON UNIVERSITYInventors: Ilhan A. Aksay, Valerie Alain-Rizzo, Michael Bozlar, David J. Bozym, Daniel M. Dabbs, Nicholas Szamreta, Cem B. Ustundag
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Patent number: 10910167Abstract: An electrochemical device, which can be thin enough to be built into a thin electronic device, and a method for manufacturing the same. The electrochemical device has: an element body on which a pair of internal electrodes are laminated so as to sandwich a separator sheet; an outer sheet covering the element body; sealing parts for sealing the peripheral edge of the outer sheet so that the element body is immersed in an electrolyte solution; and lead terminals electrically connected to either one of internal electrodes and leading out from the sealing parts of the outer sheet. At least a portion of a resin tape constituting the sealing parts, from which the lead terminals lead out, is thermally fused to an inside layer made from resin, which is present on the inner face of the outer sheet, in a position that does not overlap with the internal electrodes.Type: GrantFiled: February 3, 2017Date of Patent: February 2, 2021Assignee: TDK CORPORATIONInventors: Hiroaki Hasegawa, Hidetake Itoh, Yuji Yoshino, Kazunori Yoshikawa
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Patent number: 10910165Abstract: A process for forming high surface area graphene structures includes: depositing at least one metal on a surface of silicon carbide; heating the at least one metal and the silicon carbide to cause at least one of the metals to react with a portion of the silicon carbide to form silicide regions extending into an unreacted portion of the silicon carbide and graphene disposed between the silicide regions and the unreacted portion of the silicon carbide; and removing the silicide regions to provide a silicon carbide structure having a highly irregular surface and a surface layer of graphene.Type: GrantFiled: March 4, 2016Date of Patent: February 2, 2021Assignee: UNIVERSITY OF TECHNOLOGY SYDNEYInventors: Mohsin Ahmed, Francesca Iacopi
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Patent number: 10892112Abstract: A method of making an energy storage article having a metal nitride electrode is disclosed where metal nitride is made by nitriding particles of a metal or oxide of a metal selected from vanadium molybdenum, titanium, niobium, tungsten, or combinations including any of the foregoing by contacting the particles with a gas of nitrogen and hydrogen, or ammonia, in a fluidized bed reactor to form particles of metal nitride for the electrode.Type: GrantFiled: June 24, 2016Date of Patent: January 12, 2021Assignee: RAYTHEON TECHNOLOGIES CORPORATIONInventors: Randolph Carlton McGee, Ying She, Zissis A. Dardas
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Patent number: 10892109Abstract: The present disclosure provides supercapacitors that may avoid the shortcomings of current energy storage technology. Provided herein are supercapacitor devices, and methods of fabrication thereof comprising the manufacture or synthesis of an active material on a current collector and/or the manufacture of supercapacitor electrodes to form planar and stacked arrays of supercapacitor electrodes and devices. Prototype supercapacitors disclosed herein may exhibit improved performance compared to commercial supercapacitors. Additionally, the present disclosure provides a simple, yet versatile technique for the fabrication of supercapacitors through masking and etching.Type: GrantFiled: November 22, 2019Date of Patent: January 12, 2021Assignee: The Regents of the University of CaliforniaInventors: Richard Barry Kaner, Maher F. El-Kady
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Patent number: 10886075Abstract: The present invention relates to an electric double-layer capacitor and its manufacturing method. The ultracapacitor comprises a cylindrical housing having a bottom at one end and the housing is closed by an end cap integrated with first current terminal. From the bottom of the housing protrudes a terminal end of the second current terminal. Unlike to the previously known solutions the current terminals are arranged into the ultracapacitor, and spot welded to the electrode terminal to decrease internal resistance and to reach optimal packing density.Type: GrantFiled: May 26, 2017Date of Patent: January 5, 2021Assignee: OÜ Skeleton Technologies GroupInventors: Jaan Leis, Ann Laheäär, Priit Pihlakas, Mati Arulepp, Anti Perkson, Taavi Madiberk
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Patent number: 10879552Abstract: A electrochemical storage device, referred to herein as a radical-ion battery, is described. The radical-ion battery includes an electrolyte, first free radicals, and second free radicals, wherein the first free radicals and the second free radicals are different chemical species. The radical-ion battery also includes a separator that allows select ions to pass therethrough, but separates the electrolyte from the second free radicals.Type: GrantFiled: February 16, 2017Date of Patent: December 29, 2020Assignee: National Technology & Engineering Solutions of Sandia, LLCInventor: Jeffrey P. Koplow
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Patent number: 10879014Abstract: A carbonaceous material for electric double-layer capacitors that is based on a plant-derived carbon precursor, in which carbonaceous material: a BET specific surface area is 1,900 to 2,500 m2/g; an average pore size is 2.2 to 2.6 nm as determined by a nitrogen adsorption method; a volume of micropores having a pore size of 2 nm or smaller is 0.84 to 1.30 cm3/g as determined by the MP method; a ratio of a volume of micropores having a pore size of 1 to 2 nm with respect to the volume of the micropores having a pore size of 2 nm or smaller is 25 to 50% as determined by the MP method; and a volume of mesopores having a pore size of 2 to 50 nm is 0.16 to 0.4 cm3/g as determined by the BJH method.Type: GrantFiled: November 13, 2017Date of Patent: December 29, 2020Assignee: KURARAY CO., LTD.Inventors: Yumika Nishita, Shushi Nishimura, Yoshifumi Egawa, Kiyoto Otsuka
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Patent number: 10872737Abstract: An ultracapacitor that includes an energy storage cell immersed in an electrolyte and disposed within an hermetically sealed housing, the cell electrically coupled to a positive contact and a negative contact, wherein the ultracapacitor has a gel or polymer based electrolyte and is configured to output electrical energy at temperatures between about ?40° C. and about 250° C. Methods of fabrication and use are provided.Type: GrantFiled: November 28, 2016Date of Patent: December 22, 2020Assignee: FASTCAP SYSTEMS CORPORATIONInventor: Nicolò Michele Brambilla
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Patent number: 10872735Abstract: A high volumetric energy and power density supercapacitor is provided. This supercapacitor includes a coin cell, a spring lamination, a working electrode, a counter electrode, a separator, and an ionic liquid electrolyte. The working and counter electrodes are N—P doping porous graphene coated on Al substrate. The ionic liquid electrolyte is EMI-FSI. The method of producing N—P doping porous graphene includes following steps: S1: Graphite oxide is quickly transferred into the furnace, which had been held at 300° C. and the porous graphene can be produced. S2: The porous graphene and red phosphorus are put together in the evacuated tube furnace and heated to 700° C. for 1 hr. S3: Heated to 800° C. for 30 min in a mixed argon and ammoniac atmosphere and then the N—P doping porous graphene can be made. The capacitance of the supercapacitor is 105 F/g and the volumetric power density is 1.19 kW/L.Type: GrantFiled: November 28, 2018Date of Patent: December 22, 2020Assignee: National Chung-Shan Institute of Science and TechnologyInventors: Chien-Liang Chang, Wu-Ching Hung, Jeng-Kuei Chang, Bo-Rui Pan
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Patent number: 10865474Abstract: Embodiments of the present technology include graphene-metal composites. An example graphene-metal composite includes a porous metal foam substrate, a graphene layer deposited to the porous metal foam substrate, a metal layer applied to the graphene layer, and another graphene layer deposited to the metal layer; the multilayered porous metal foam substrate being compressed to form a graphene-metal composite, and depositing a thin metal coating on an outer surface of the porous metal foam substrate or an outer surface of the graphene using any of physical vapor deposition and chemical vapor deposition.Type: GrantFiled: January 28, 2019Date of Patent: December 15, 2020Assignee: Fourté International, SDN. BHDInventors: James J. Farquhar, Choon Ming Seah
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Patent number: 10855179Abstract: A power converter may be adapted to provide an output voltage from one of two input voltages. The power converter may include two or more buck converters that share a plurality of power converter components and each converts an individual input voltage to the output voltage. The power converter may include any of a variety of charge equalizing components that may be coupled between input terminals and optional input capacitors, which are coupled between the input terminals and ground. The charge equalizing component(s) provide(s) a fast conduction path for the equalization of input voltages and charge/voltage of the optional input capacitors. The charge equalizing component(s) can mitigate large currents created by differential voltages between the input terminals, which currents would otherwise flow through and potentially damage or destroy the power converter's switching devices.Type: GrantFiled: March 28, 2017Date of Patent: December 1, 2020Assignee: Apple Inc.Inventors: Khaleel Shaik, Di Zhao, Sivasankari Krishnanji
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Patent number: 10840029Abstract: The invention relates to a capacitor with a layered construction on a base element having open pores with inner pore surfaces. The base element is electrically conductive at least in a part of the inner pore surfaces and therefore forms a continuous electrode. The electrically conductive part of the inner pore surfaces is nanostructured. In the capacitor a layer of a solid body electrolyte is directly arranged on the electrode and an electrically conductive counter-electrode layer forming a counter electrode is directly arranged on the solid body electrolyte. The counter electrode is applied as a thin layer so that within the open pores a continuous free space remains. The invention also relates to a construction element comprising a foam structure which is part of such a capacitor. The invention also relates to a method of manufacturing such a construction element.Type: GrantFiled: June 21, 2018Date of Patent: November 17, 2020Assignee: DEUTSCHES ZENTRUM FÜR LUFT- UND RAUMFAHRT E.V.Inventors: Sebastian Geier, Thorsten Mahrholz
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Patent number: 10825616Abstract: Method of preparing a nonaqueous lithium power storage element, by providing a nonaqueous lithium power storage element comprising a positive electrode precursor containing a lithium compound other than an active material, a negative electrode, a separator, a nonaqueous electrolytic solution containing lithium ions, and a casing; and applying a voltage of 4.2V or more to the nonaqueous lithium power storage element to decompose the lithium compound in the positive electrode precursor and pre-dope the negative electrode with the lithium ions, while releasing a gas generated from decomposition of the lithium compound either out of an opening of the casing or through a degassing valve or gas permeable film.Type: GrantFiled: July 3, 2019Date of Patent: November 3, 2020Assignee: Asahi Kasei Kabushiki KaishaInventors: Kazuteru Umetsu, Nobuhiro Okada, Takeshi Kamijo
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Patent number: 10826054Abstract: An object of the present invention is to improve the electron conductivity and ion conductivity of the surface of a positive electrode active material to provide a lithium ion battery having high capacity and high output. The present invention relates to a positive electrode for a lithium ion secondary battery, including a mixture layer containing a positive electrode active material for a lithium ion secondary battery and graphene, wherein the mixture layer has a percentage of abundance of silicon composing a siloxane bond in total elements of 0.4 atomic % or more as measured by X-ray photoelectron spectroscopy.Type: GrantFiled: September 29, 2016Date of Patent: November 3, 2020Assignee: TORAY INDUSTRIES, INC.Inventors: Takashi Konishi, Eiichiro Tamaki, Manabu Kawasaki, Koki Miyazono
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Patent number: 10818441Abstract: An energy storage device can have a first graphite film, a second graphite film and an electrode divider ring between the first graphite film and the second graphite film, forming a sealed enclosure. The energy storage device may be compatible with an aqueous electrolyte or a non-aqueous electrolyte. A method of forming an energy storage device can include providing an electrode divider ring, a first graphite film and a second graphite film. The method can include pressing a first edge of the electrode divider ring into a surface of the first graphite film, and pressing a second opposing edge of the electrode divider ring into a surface of the second graphite film to form a sealed enclosure. The sealed enclosure may have as opposing surfaces the surface of the first graphite film and the surface of the second graphite film.Type: GrantFiled: October 5, 2018Date of Patent: October 27, 2020Assignee: Maxwell Technologies, Inc.Inventors: Porter Mitchell, Thomas J. Dougherty
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Patent number: 10804042Abstract: Provided is a supercapacitor electrode, comprising: (a) preparing a deformable mass of multiple flakes of exfoliated graphite worms or expanded graphite dispersed in or impregnated by a liquid or gel electrolyte; and (b) subjecting the deformable mass to a forced assembling and orientating procedure, forcing the deformable mass to form the electrode, wherein these fakes are spaced by thin electrolyte layers, having an electrolyte layer thickness from 0.4 nm to 10 nm, and the flakes are substantially aligned along a desired direction, and wherein the electrode has a physical density from 0.5 to 1.7 g/cm3 and a specific surface area from 50 to 3,300 m2/g, when measured in a dried state of the flakes without the electrolyte. This supercapacitor has a large electrode thickness, high active mass loading, high tap density, and exceptional energy density.Type: GrantFiled: November 8, 2018Date of Patent: October 13, 2020Assignee: Nanotek Instruments Group, LLCInventors: Aruna Zhamu, Bor Z. Jang
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Patent number: 10797319Abstract: An object of the present invention is to provide a non-aqueous electrolyte secondary battery that has a large charge/discharge capacity, has a small irreversible capacity, which is the difference between the doping capacity and the de-doping capacity, and is capable of effectively using an active material. The problem described above can be solved by a method for producing a carbonaceous material for a non-aqueous electrolyte secondary battery anode, the method including: (1) an alkali metal compound impregnating step of adding an elemental alkali metal or a compound containing an elemental alkali metal to a carbonaceous precursor to obtain an alkali-impregnated carbonaceous precursor; (2) a heat treatment step of: (a) obtaining a heat-treated product by performing main heat treatment on the alkali-impregnated carbonaceous precursor at 800° C. to 1500° C.Type: GrantFiled: August 10, 2015Date of Patent: October 6, 2020Assignee: KUREHA CORPORATIONInventors: Naohiro Sonobe, Kazuhiko Shimizu
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Patent number: 10770731Abstract: The present invention provides a positive electrode current collector, and a preparation method and use thereof. The positive electrode current collector is of a multilayered structure and comprises a plastic thin film, wherein the upper and lower surfaces of the plastic thin film are coated with a bonding force enhancement layer, an aluminum metal coating layer and an anti-oxidization layer in sequence. The preparation method comprises the steps of coating the bonding force enhancement layer, the aluminum metal coating layer and the anti-oxidization layer in sequence through an evaporation film-coating process. Use of the positive electrode current collector in a lithium ion battery is further provided. By virtue of the positive electrode current collector according to the present invention, light weight and improved energy density of the battery is realized, and the aluminum coating layer is not easily peeled off, and insusceptible to oxidization.Type: GrantFiled: August 1, 2018Date of Patent: September 8, 2020Inventors: Zuoyi Yan, Wenqing Liu
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Patent number: 10756346Abstract: A porous carbon material is provided. The porous carbon material having a value of specific surface area of at least 10 m2/g as measured by a nitrogen BET method, a pore volume of at least 0.1 cm3/g as measured by a BJH method and a MP method, and a R value of 1.5 or greater, wherein the R value is expressed as R=B/A, wherein A is an intensity at an intersection between a baseline of a diffraction peak of a (002) plane as obtained based on powdery X-ray diffractometry of the porous carbon material and a perpendicular line downwardly drawn from the diffraction peak of the (002) plane, and wherein B is an intensity of the diffraction peak of the (002) plane.Type: GrantFiled: January 27, 2017Date of Patent: August 25, 2020Assignee: Sony CorporationInventors: Seiichiro Tabata, Shinichiro Yamada, Masayoshi Kanno, Tsutomu Noguchi, Takeshi Horie
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Patent number: 10741337Abstract: A mesoporous, nanocrystalline, metal oxide construct particularly suited for capacitive energy storage that has an architecture with short diffusion path lengths and large surface areas and a method for production are provided. Energy density is substantially increased without compromising the capacitive charge storage kinetics and electrode demonstrates long term cycling stability. Charge storage devices with electrodes using the construct can use three different charge storage mechanisms immersed in an electrolyte: (1) cations can be stored in a thin double layer at the electrode/electrolyte interface (non-faradaic mechanism); (2) cations can interact with the bulk of an electroactive material which then undergoes a redox reaction or phase change, as in conventional batteries (faradaic mechanism); or (3) cations can electrochemically adsorb onto the surface of a material through charge transfer processes (faradaic mechanism).Type: GrantFiled: March 13, 2018Date of Patent: August 11, 2020Assignee: THE REGENTS OF THE UNIVERSITY OF CALIFORNIAInventors: Bruce S. Dunn, Sarah H. Tolbert, John Wang, Torsten Brezesinski, George Gruner