Abstract: Provided are methods of forming optical waveguides. The methods involve: (a) forming over a substrate a layer of a photodefinable composition; (b) exposing a portion of the layer to actinic radiation; (c) developing the exposed layer to form a waveguide core structure; and (d) heating the waveguide core structure to a temperature and for a time effective to reflow the structure such that it becomes at least partially rounded in cross-section. Also provided are optical waveguides formed from the described methods and electronic devices including one or more of the optical waveguides.

Abstract: An optical waveguide includes a clad of clad glass and a core of core glass. The clad glass includes gallium, lanthanum, and sulfur. The clad glass may include gallium sulfide and lanthanum oxide. The clad glass may also include lanthanum fluoride. The core glass includes gallium, lanthanum, sulfur, oxygen, and fluorine. The core glass may include gallium sulfide, lanthanum oxide, and lanthanum fluoride. An optical fiber perform is also disclosed.

Abstract: An optical element, such as a waveguide, is formed by utilizing a plasma deposited precursor optical material wherein the plasma deposition is a two-component reaction comprising a silicon donor, which is non-carbon containing and non-oxygenated, and an organic precursor, which is non-silicon containing and non-oxygenated. The plasma deposition produces a precursor optical material that can be selectively photo-oxidized by exposure to electromagnetic energy in the presence of oxygen to produce photo-oxidized regions that have a selectively lower index of refraction than that of the non-photo-oxidized regions whereby transmission of a light signal through selected non-photo-oxidized and photo-oxidized regions can be controlled. Subsequent photo-oxidation or variable photo-oxidation can be used to produce various discrete regions with different indexes of refraction for fabrication, optimization or repair of photonic structures.

Abstract: An optical waveguide device comprising a core structure formed of deuterated amorphous carbon. The optical waveguide device decreases losses due to hydrogen absorption. A process for making the optical waveguide device is also disclosed.

Abstract: An optical fiber (1?) having at least one Bragg grating (11), the fiber comprising a core (2) surrounded successively by cladding (3) and by a coating (4), the grating being obtained by being written directly in the core and/or the cladding of the fiber through the coating which is made of a material that is substantially transparent to ultraviolet type radiation used for writing the grating, and wherein the material of the coating contains a first polymer network interpenetrated by a second polymer.

Abstract: An optical fiber having at least one epoxidized polyolefin based polymer coating. The coating is formed from a crosslinkable composition having (a) at least one epoxidized polydiene oligomer having a first and a second end, the oligomer having at least one hydrocarbon chain that is substantially free of ethylenic double bonds, at least one epoxide group at the first end and at least one reactive functional group at the second end; (b) at least one hydrogenated polydiene oligomer having at least one reactive functional group capable of reacting with the epoxide groups; and (c) at least one photo-initiator. Preferably, the coating is a primary coating coated with a secondary coating.

Abstract: Telecommunication cable having a tubular element, in particular a buffer tube housing at least one transmission element. The tubular element has a polymeric composition which allows an easy tearing of the element, in order to get access to the transmission element housed therein. The tubular element is made from a polymeric composition having a heterophasic olefin copolymer which has at least one amorphous phase having sequences deriving from copolymerization of at least two different olefin monomers, at least a first crystalline phase having sequences deriving from the homopolymerization of a first olefin monomer and at least a second crystalline phase having sequences deriving from the homopolymerization of a second olefin monomer.

Abstract: The present invention provides an optical fiber providing high photosensitivity in the absence of hydrogen loading as well as a low numerical aperture. One aspect of the present invention relates to an optical fiber including a core, the core comprising silica doped with at least about 6 mol % germania and at least about 0.9 wt % fluorine; and a cladding surrounding the core. The optical fiber of the present invention is suitable for the production of fiber Bragg gratings.

Abstract: The present invention relates to an optical device comprising an ionic conductor and a pair of electrodes, the ionic conductor being made of a material that is transparent to light and contains mobile ions and the electrodes being suitable for absorbing and desorbing the ions and being in ionic contact with the ionic conductor. The refractive index in at least a zone of the ionic conductor can be varied under the effect of the voltage applied between the electrodes. The electrodes contain an electrochemically active material selected from an active carbon, a conductive polymer, and an insertion material suitable for inserting ions in its structure.

Abstract: Optical waveguides interconnect optical information processing devices, or connect such devices with other optical communication links such as glass optical fibers. Fluoropolymers consisting of alternating perfluorocyclobutane and aryl ether linkages possess suitable properties for optical waveguides and other devices due to tunability in optical properties of the copolymers. Perfluorocyclobutane (PFCB) copolymer may be employed in solutions that exhibit a high solids content. Such solutions show useful physical properties for optical waveguide devices since the solutions are capable of achieving single step film thicknesses, when applied to a substrate, of greater than about 0.6 microns, and sometimes may achieve a thickness of 10 microns or more.

Abstract: The present invention relates to fluorinated polyethers having a fluorinated aliphatic group at a main chain as represented by the formula (1), as well as a waveguide fabricated using the same: where RF represents OCH2(CF2)nCH2O, or OCH2CF2O(CF2CF2O)nCF2CH2O, where n is a natural number ranging from 1 to 12; Ar1 represents ?where B is not present or a C?O group, or Ar1 represents ?where Hal is one selected from F, Cl, Br and I; Ar2 represents ?where D is one selected from —C(CF3)2, —C(CH3)2, —CO—, —SO2—, —O— and —S—, or Ar2 represents ?where R1 and R2 are the same or different and each independently represents a halogen atom selected from F, Cl, Br and I, and m is a natural number of 1-3, or Ar2 represents E represents H, or ?where P is H or a substituted or unsubstituted phenyl group; x is a number ranging from 0.1 to 1.0; y is 1.0?x.

Abstract: It is an object of the present invention to provide an optical fiber for transmitting ultraviolet ray which has an improve transmittance and is prevented from deterioration by ultraviolet ray with which it is irradiated. It is another object of the present invention to provide an optical fiber probe which can propagate vacuum ultraviolet ray and deep ultraviolet ray at a high transmittance, is deteriorated only to a limited extent when irradiated with ultraviolet ray and can be etched to have a desired shape of the sharpened section at the fiber end. The present invention provides the optical fiber for transmitting ultraviolet ray which has a core 5 of silica glass containing a given content of fluorine and a clad 6a of silica glass containing a given content of fluorine or boron, a clad 6b of a resin which transmits ultraviolet ray or a clad 6c having air holes H. The clad may be coated with a protective layer and further with a covered layer for protection.

Abstract: A light guiding plate, characterized by comprising a transparent thermoplastic resin composition containing 1-200 ppm of fine particles having a refractive index of 1.7-3.0 and an average particle diameter of 0.01-1.0 ?m. This light guiding plate is suitable for display devices used in office automation apparatuses such as personal computers, word processors, etc. and various monitors displaying image signals such as panel monitors, television monitors, etc., display devices used in illuminators for indoor or outdoor space, and signs.

Abstract: Disclosed are an optical waveguide that comprises (A) a copolyester carbonate having aliphatic segment(s), and a method for producing it; and an optical waveguide made from a polycarbonate resin composition that comprises (A) a copolyester carbonate having aliphatic segment(s) and (B) an aromatic polycarbonate, and a method for producing it. The polycarbonate resin composition for the optical waveguide has the advantages of high mechanical strength and improved flowability.

Abstract: An electro-optic waveguide device that includes (a) an electro-optic polymer core having a refractive index and (b) an electro-optic first polymer clad in proximity to the electro-optic polymer core.

Abstract: A polyimide excelling in heat resistance, chemical resistance, water repellency, dielectric characteristics, electrical characteristics, and optical characteristics and a polyamide acid useful as the raw material therefor are provided. Specifically, a polyamide acid containing a chlorine atom and a fluorine atom and comprising a repeating unit represented by the following formula (1): (wherein X and X? independently denote a divalent organic group; Y and Y? independently denote a chlorine, bromine, or iodine atom; p and p? denote independently denote the number of fluorine atom {F in the formula (1)} bonded to the relevant benzene ring, representing an integer of 0-3; q and q? independently denote an integer of 0-3; and p+q total 3, and p?+q? total 3).

Abstract: The invention pertains to optical fiber transmission networks, and is particularly relevant to transmission of high volume of data and voice traffic among different locations. In particular, the improvement teaches improvements to an optical transport system to allow for efficient and flexible network evolution.

Abstract: An optical waveguide is provided. The optical waveguide includes a polymer substrate and a lower cladding disposed on the substrate. The lower cladding is a first perhalogenated polymer. The optical waveguide also includes a core disposed on at least a portion of the lower cladding. A method of manufacturing the optical waveguide is also provided.

Abstract: A method of preparing a planar optical waveguide assembly, comprising the steps of (i) applying a curable polymer composition to a surface of a substrate to form a polymer film; (ii) curing the polymer film to form a lower clad layer; (iii) applying a silicone composition to the lower clad layer to form a silicone film; (iv) exposing at least one selected region of the silicone film to radiation having a wavelength of from 150 to 800 nm to produce a partially exposed film having at least one exposed region and at least one non-exposed region; (v) removing the non-exposed region of the partially exposed film with a developing solvent to form a patterned film; and (vi) heating the patterned film for an amount of time sufficient to form at least one silicone core having a refractive index of from 1.3 to 1.7 at 23° C. for light having a wavelength of 589 nm; wherein the lower clad layer has a refractive index less than the refractive index of the silicone core.

Abstract: A cycloolefin in copolymeric (COC) optical communication device. The COC optical communication device includes a core section of functional metallocene cycloolefin copolymer (f-mCOC) having a refractive index n1 for light transmission, and a cladding layer of metallocene cycloolefin copolymer (mCOC), having a refractive index n2 smaller than n1, surrounding the core section and forming a waveguide structure together with the core section. Due to the fact that the various components of the optical communication device are comprised of essentially the same materials, signal transmission loss between heterogeneous interfaces is prevented, and provides excellent optical properties and superior processability.

Abstract: There is provided a material which can give a high elasticity and heat resistance to an optical waveguide member by photo-curing while maintaining transparency in a near infrared region and further makes it possible to use a film forming process by a spin coating method and a process for producing a waveguide by photolithograph, to obtain a waveguide having a large area and to produce an optical waveguide having reduced water absorption, and further there can be provided an optical waveguide member and an optical waveguide device. Namely, there are provided a fluorine-containing optical waveguide material comprising a curable fluorine-containing prepolymer (I) which is a non-crystalline polymer having a fluorine content of not less than 25% by weight and has a carbon-carbon double bond in a polymer side chain and/or at an end of a polymer trunk chain, an optical waveguide member which is a cured article of the optical waveguide material and an optical waveguide device comprising the optical waveguide member.

Abstract: The present invention provides an optical polyimide precursor for use in making a polyimide. The precursor is defined by the following formula: wherein X is Cl, Br, oxo-halide, or fully halogenated alkyl, and A is a divalent aromatic or halogenated aromatic moiety. The present invention provides a method of preparing a diamine compound for use as an optical polyimide precursor. The method includes the steps of dissolving 2-chloro-5-nitrobenzotrifluoride and a diol in N,N-dimethylacetamide to form a solution, adding potassium carbonate, tert-butylammonium chloride and copper powder to said solution and heating the resulting mixture, removing the copper, precipitating and recrystallizing a dinitro-compound resulting from heating the mixture, and dissolving the dinitro-compound and reducing the dinitro-compound to yield a diamine compound.

Abstract: Into a mixture solution 2 of a high-refractive-index photo-curable resin A and a low-refractive-index photo-curable resin B, light capable of curing only the resin A is led through an optical fiber 1 so that a cured resin 211 of the resin A having a diameter substantially equal to the diameter of a core portion of the optical fiber is formed so as to extend from a tip of the optical fiber. Then, the residual mixture solution 2 is cured. In this manner, a module having the previously cured high-refractive-index resin 211 as an optical waveguide can be formed easily. On this occasion, the mixed state of the mixture solution 2 can be kept good enough to facilitate the formation of the high-refractive-index resin 211 when the solubility parameter ?A of the high-refractive-index photo-curable resin A and the solubility parameter ?B and volume fraction ?B of the low-refractive-index photo-curable resin B satisfy the following expression (4). |?A??B|<?7.5?B+6.

Abstract: A method for making a polymer-based rare earth-doped waveguide includes the steps of: providing a substrate (11); spin coating a polymer bottom cladding layer (12) on the substrate; spin coating a core layer (13) comprising a polymer and complex rare earth metal ions, which can be excited to produce a laser, on the bottom cladding layer; using a channel patterning technique with masking and ultraviolet (UV) radiation followed by etching to form at least one channel waveguide (14); and spin coating a polymer top cladding layer (15) over the at least one channel waveguide and exposed portions of the bottom cladding layer. The method includes improving the solubility of rare earth metal ions in a polymer matrix, by forming a complex of each rare earth metal ion with an organic compound. These complexes have higher solubility in a fluorinated polymer, compared with pure rare earth metal ions.

Abstract: The present invention relates to a production method of a plastic optical fiber which comprises the steps of heat drawing an undrawn plastic optical fiber obtained by melt spinning and annealing the drawn fiber at a circumferential velocity ratio between the front and rear rollers (circumferential velocity of a rear roller/circumferential velocity of a front roller) of 0.5 to 1.2 under heating conditions which satisfy 4?y??1.5x+330 and (Tgc?5)° C.?x?(Tgc+110)° C. [Tgc: a glass transition temperature of a core, x: an annealing temperature (° C.), and y: an annealing time (seconds)]. According to the present invention, a plastic optical fiber having a small thermal shrinkage ratio and excellent heat resistance can be provided.

Abstract: The preparation of robust, thin film materials with large second-order optical nonlinearities through the covalent self-assembly of chromophoric compositions and innovative use of silyl chemistry.

Abstract: The present invention is directed to optical waveguides or waveguide systems, comprising at least (a) a first material which is a poly(perfluorocyclobutane), and in direct contact to this material, (b) a second material which is a polycyanate resin made from at least one aromatic difunctional cyanate of formula (I) wherein R1 to R8 are independently from each other hydrogen, optionally substituted C1-C10 alkyl, C3-C8 cycloalkyl, C1-C10 alkoxy, halogen, phenyl or phenoxy, the alkyl or aryl groups being unfluorinated, partly fluorinated or fully fluorinated with the proviso that (I) carries at least 1 fluorine atom, and Z is a chemical bond, SO2, CF2 CH2, CHF, CH(CH3), isopropylene, hexafluoroisopropylene, n- or iso-C1-C10 alkylene which may be partly or fully fluorinated, O, NR9 whereby R9 is hydrogen or C1-C10 alkyl, N?N, CH?CH, C(O)O, CH?N, CH?N—N?CH, alkyloxyalkylene having 1 to 8 carbon atoms, S, or Si(CH3)2 optionally in mixture with other components.

Abstract: The present invention provides a polymer lightguide which has a waveguide layer comprising a polyimide having a repeating unit represented by general formula (I): wherein R represents a bivalent organic group.

Abstract: Provided are photodefinable compositions suitable for use in forming an optical waveguide. The compositions include a silsesquioxane polymer having polymerized units of the formula (R1SiO1.5) and (R2SiO1.5), wherein R1 and R2 are different and are substituted or unsubstituted organic side chain groups and are free of hydroxy groups, and two or more functional end groups, and a photoactive component. The solubility of the silsesquioxane polymer is altered upon exposure to actinic radiation such that the composition is developable in an aqueous developer solution. Also provided are methods of forming an optical waveguide with the inventive compositions, optical waveguides, and electronic devices including one or more optical waveguide.

Abstract: Optical waveguide structures containing siloxane resin composistions as core materials and a method for preparing the waveguides are disclosed. The siloxane resin compositions can be cured by thermal energy or actinic radiation. In addition, conventional patterning techniques can be used, which makes the present method ideal for practicing on a commercial scale. The optical waveguides of the invention exhibit very low optical losses and are compatible with silicon processing requirements, which makes them useful in integrated circuitry. In addition, the high refractive index contrasts between the siloxane resin core and various claddings, including other siloxane resins, makes the waveguides particularly desirable.

Abstract: A waveguide having a spatially-variable refractive index is disclosed. The waveguide having a spatially-variable refractive index comprises a light-propagating medium and a non-uniform distribution of liquid crystal material in a matrix of dielectric material located in a portion of the light-propagating medium.

Abstract: The present invention is an optical fiber made of semi-crystalline polymer. By “semi-crystalline” it is meant that final fiber product produced by the teaching herein has from about 30% to about 99% crystallinity.

Abstract: Provided are methods of forming optical waveguides. The methods involve: (a) forming over a substrate a layer of a photodefinable composition; (b) exposing a portion of the layer to actinic radiation; (c) developing the exposed layer to form a waveguide core structure; and (d) heating the waveguide core structure to a temperature and for a time effective to reflow the structure such that it becomes at least partially rounded in cross-section. Also provided are optical waveguides formed from the described methods and electronic devices including one or more of the optical waveguides.

Abstract: This invention provides a process for manufacturing a methyl methacrylate polymer comprising the steps of feeding a monomer containing at least 80 wt % of methyl methacrylate and a radical polymerization initiator represented formula (III) to a reactor; polymerizing the material at a polymerization temperature of 110 to 160° C. under the conditions satisfying particular equations between an initiator concentration and a polymerization temperature; feeding a reaction mixture taken out from the reactor to a devolatilization step (feeding step); and separating and removing volatiles from the reaction mixture (devolatilization step). A methyl methacrylate polymer having adequately good optical properties and a plastic optical fiber having improved transmission performance can be prepared according to this invention.

Abstract: Several novel polyimide materials are disclosed.

Abstract: The present invention relates to a synthetic fiber adapted to emit a visible light as it is energized by an infrared light, which fiber has the main feature that it is made of a polymeric compound, to which a masterbatch holding a rare earth oxysulphide active substance is added.

Abstract: A process of producing a polymer optical waveguide, including (a) a step of forming an undercladding layer on a substrate; (b) a step of forming a photosensitive resin composition layer containing a 1,4-dihydropyridine derivative and a resin on the undercladding layer; (c) a step of irradiating a region of the photosensitive resin composition layer corresponding to a core pattern with UV light through a mask to form UV light-exposed areas and UV light-unexposed areas on the photosensitive resin composition layer; (d) a step of heating the UV light-exposed areas and UV light-unexposed areas of the photosensitive resin composition layer; and (e) a step of forming an overcladding layer on the photosensitive resin composition layer after heating.

Abstract: In a laser device and a light signal amplifying device with an optical fiber containing a laser activating substance in the inside for emitting a light beam from the end part in the case the laser activating substance is excited, fixed in a dense state at least partially by an optical medium, a polysilsesquioxane including a repeating unit represented by a general formula RSiO1.5 (wherein R represents an alkyl group, a hydroxyl group, a phenyl group, a vinyl group, a 2-chloroethyl group, a 2-bromoethyl group, a hydrogen, a heavy hydrogen, a fluorine, or an oxygen. However, one having R entirely as an oxygen is excluded. Moreover, R may be different per each repeating unit.) is used as the optical medium.

Abstract: A clad is produced by polymerizing methyl methacrylate and (meth)acrylic acid ester having alicyclic hydrocarbon group. A core is produced by an interfacial-gel-polymerization method. A first covering layer having a thickness being less than 500 &mgr;m is formed on an outer surface of the clad to produce a single-fiber optical cable. A plurality of the single-fiber optical cables are bundled. A gap between the single-fiber optical cables is infused with a filler. The bundled single-fiber optical cables are covered with a second covering layer to produce a multi-fiber optical cable. Since the covering layer is thin, the multi-fiber optical cable has excellent flexibility and reduced bending loss.

Abstract: A cycloolefin in copolymeric (COC) optical communication device. The COC optical communication device includes a core section of functional metallocene cycloolefin copolymer (f-mCOC) having a refractive index n1 for light transmission, and a cladding layer of metallocene cycloolefin copolymer (mCOC), having a refractive index n2 smaller than n1, surrounding the core section and forming a waveguide structure together with the core section. Due to the fact that the various components of the optical communication device are comprised of essentially the same materials, signal transmission loss between heterogeneous interfaces is prevented, and provides excellent optical properties and superior processability.

Abstract: A light fiber comprising (a) a tubular clad having a predetermined length and (b) a solid core formed by reacting a filler material with which the clad is filled, the clad and the core being closely contacted with each other by shrinkage of the clad, characterized in that: the clad is expandable under pressure, shrinkage of the clad is initiated before the completion of the reaction of the filler material and is carried out in conformity with volume reduction of the core, which accompanies the reaction of the filler material, and the number of air gap between the clad and the core, which is measured per length of 10 m, is 3 or less.

Abstract: The invention provides polymeric optical materials that can be cured in air and have low optical loss in both the C-band and the L-band of the telecommunications spectrum. The polymeric materials are made by the free radical polymerization of an at least difunctional thiol compound with an at least difunctional ethylenically unsaturated compound wherein at least one of the thiol compound and the ethylenically unsaturated compound is at least partially halogenated. The compositions of this invention may be used to fabricate planar optical waveguides with low loss and low birefringence.

Abstract: This invention provides a process for producing a three-dimensional polyimide optical waveguide, which comprises: (I) irradiating a polyamic acid film with a laser beam while converging the laser beam at an inside portion of the film and relatively moving the light convergence point, the polyamic acid film containing: (a) a polyamic acid obtained from a tetracarboxylic dianhydride and a diamine; and (b) per 100 parts of the polyamic acid, from 0.

Abstract: An optical waveguide device comprising a core structure formed of deuterated amorphous carbon. The optical waveguide device decreases losses due to hydrogen absorption. A process for making the optical waveguide device is also disclosed.

Abstract: A process for producing optical fibers is disclosed. The fibers that are characterized in having a core that contain an amorphous transparent thermoplastic polymer are prepared by a process entailing melting the polymer in an apparatus the surfaces of which that come into contact with the molten polymer are first rendered at least partially inert.

Abstract: The present invention provides an optical apparatus, a method of manufacture therefore, and an optical integrated circuit that includes the optical apparatus. The optical apparatus comprises a substrate, a first waveguide core formed in the substrate and a second waveguide core comprising an organic polymer formed in the substrate second waveguide core having a different composition than said first waveguide core and optically coupled to the first waveguide core.

Abstract: Provided are photodefinable compositions suitable for use in forming an optical waveguide. The compositions include a silsesquioxane polymer having polymerized units of the formula (R1SiO1.5) and (R2SiO1.5), wherein R1 and R2 are different and are substituted or unsubstituted organic side chain groups and are free of hydroxy groups, and two or more functional end groups, and a photoactive component. The solubility of the silsesquioxane polymer is altered upon exposure to actinic radiation such that the composition is developable in an aqueous developer solution. Also provided are methods of forming an optical waveguide with the inventive compositions, optical waveguides, and electronic devices including one or more optical waveguide.

Abstract: Electro-optic waveguide devices that comprise an electro-optic polymer core and a polymer buffer clad. The polymer buffer clad comprises an organically modified sol-gel and has a refractive index lower than the refractive index of the core.

Abstract: An electro-optic waveguide device that includes (a) an electro-optic polymer core having a refractive index and (b) an electro-optic first polymer clad in proximity to the electro-optic polymer core.

Abstract: Provided are photodefinable compositions. The compositions include a silsesquioxane oligomer that has polymerized units of the formula (RSiO1.5), wherein R is selected from hydroxyphenyl or hydroxybenzy, and a photoactive component. The solubility of the silsesquioxane oligomer is altered upon exposure to actinic radiation. Also provided are methods of manufacturing optical waveguides, optical waveguides and electronic devices.