Solidification Patents (Class 405/129.3)
  • Patent number: 10633940
    Abstract: A method for reducing lost circulation in a subterranean formation. The method includes providing a treatment fluid comprising a base fluid and a lost circulation material comprising red mud. The treatment fluid is introduced into a wellbore within the subterranean formation such that at least a portion of the red mud bridges openings in the subterranean formation to reduce loss of fluid circulation into the subterranean formation.
    Type: Grant
    Filed: January 30, 2015
    Date of Patent: April 28, 2020
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Thomas Jason Pisklak, Kyriacos Agapiou, Darrell Chad Brenneis, James Robert Benkley, Jiten Chatterji
  • Patent number: 10323479
    Abstract: A method for using an extended-life settable composition is disclosed. The method includes providing an extended-life settable composition comprising red mud, calcium hydroxide, water, and a cement set retarder. The method further includes activating the extended-life settable composition. The method additionally includes introducing the extended-life settable composition into a subterranean formation and allowing the extended-life settable composition to set in the subterranean formation.
    Type: Grant
    Filed: January 29, 2015
    Date of Patent: June 18, 2019
    Assignee: Halliburton Energy Services, Inc.
    Inventors: Juan Humberto Martinez, Thomas Jason Pisklak, Jiten Chatterji, Darrell Chad Brenneis
  • Patent number: 9752088
    Abstract: A method for producing an ashless coal includes an extraction step, a separation step and an ashless coal acquirement step. In the extraction step, a slurry obtained by mixing a coal with a solvent is heated and thereby a solvent-soluble component of the coal is extracted. In the separation step, the slurry is separated into a solution of the solvent-soluble component of the coal and a solid content-concentrated liquid. In the ashless coal acquirement step, an ashless coal is obtained by evaporating and separating the solvent from the solution. The solvent is a mixture of a dissolution medium and a coal extraction accelerator added thereto. The solvent contains a bicyclic aromatic compound that is liquid at ordinary temperature. The coal extraction accelerator containing no nitrogen has two benzene rings and has at least one cyclic structure having no double bond.
    Type: Grant
    Filed: October 8, 2014
    Date of Patent: September 5, 2017
    Assignee: Kobe Steel, Ltd.
    Inventors: Koji Sakai, Noriyuki Okuyama, Shigeru Kinoshita, Takuya Yoshida
  • Patent number: 8926220
    Abstract: The present invention provides a process for thickening drilling mud waste materials including the steps of mixing a drilling mud waste materials having greater than zero percent by weight free liquid with an effective amount of one or more anionic copolymers to form a treated drilling mud waste materials. The anionic copolymer is derived from either (a) an anionic monomer, a nonionic monomer, and a cross-linking monomer, resulting in a cross-linked anionic copolymer; or (b) a non-cross-linked, linear chain co-polymer of an anionic polymer and a nonionic polymer; or (c) a blend of the combination of (a) and (b). A modified drilling mud waste material is disclosed having zero percent by weight free liquid.
    Type: Grant
    Filed: May 14, 2012
    Date of Patent: January 6, 2015
    Assignee: Henwil Corporation
    Inventors: Craig D. Iman, James T. George, James S. Herceg, Craig W. Vaughan, Todd W. Groff
  • Patent number: 8911177
    Abstract: A method of stowing a goaf of potash salt ore comprising making wall slurry into barricades each have the same area as the sectional area of a tunnel and a thickness of 0.5 to 5 meters inside the underground tunnels in goaf of potash salt ore, with the interval between adjacent barricades being 5 to 100 meters, then stowing the interval between the barricades by using the filling slurry is described. The stowing method uses the wall slurry of high strength that is solidified with a gelling agent as the main bearing material, and uses the solidified filling slurry with a low strength as the main filling material, which has a good effect when compared with conventional filling materials. Moreover, the stowing method effectively utilizes the tail liquids, thereby reducing the addition of other additives, decreasing the cost, avoiding the discharge of liquid waste and relieving the environmental pressure.
    Type: Grant
    Filed: December 28, 2012
    Date of Patent: December 16, 2014
    Assignee: Sino-Agri Mining Investment Co., Ltd.
    Inventor: Wang Quan
  • Patent number: 8608405
    Abstract: In some embodiments, methods of disposing of produced water recovered during hydrocarbon drilling, production, transportation or storage operations include collecting produced water, mixing Type I Portland cement with produced water to form a cementitious slurry, introducing the cementitious slurry into an underground void and allowing the cementitious slurry to set and form cement.
    Type: Grant
    Filed: November 24, 2010
    Date of Patent: December 17, 2013
    Assignee: Baker Hughes Incorporated
    Inventors: John St. Clergy, Freddie L. Toney
  • Patent number: 8529155
    Abstract: The present invention relates to a method for making pure salt comprises recapturing post-drilling flowback water from hydro-fracturing; removing oil from the flowback water; filtering the flowback water using an ultra filter with a pore size of about 0.1 microns or less to remove solid particulates and large organic molecules, such as benzene, ethylbenzene, toluene, and xylene, from the water; concentrating the flowback water to produce a brine that contains from about 15 wt % to about 40 wt % of salt relative to the total weight of the flowback brine; performing one or more chemical precipitation process using an effective amount of reagents to precipitate out the desired high quality commercial products, such as, barium sulfate, strontium carbonate, calcium carbonate; and crystallizing the chemically treated and concentrated flowback brine to produce greater than 99.5% pure salt products, such as sodium and calcium chloride.
    Type: Grant
    Filed: March 15, 2012
    Date of Patent: September 10, 2013
    Assignee: FracPure Holdings LLC
    Inventors: Frank A. DiTommaso, Peter N. DiTommaso
  • Patent number: 8490795
    Abstract: Containers and methods for disposing unused pharmaceutical product are disclosed. Each container (100, 200, 300) may include a container body (104, 204, 304) with an internal chamber (116, 216, 316) for storing pharmaceutical product, along with a cover (124, 224, 324) for selectively limiting access to the chamber (116, 216, 316). An encapsulation component (128, 228, 328) may be selectively disposable within the chamber (116, 216, 316), and may be operable to encapsulate the pharmaceutical product within the container (100, 200, 300). For instance, the encapsulation component (128, 228, 328) may melt and/or flow into contact with the pharmaceutical product and thereafter solidify to encapsulate the pharmaceutical product. The encapsulation component (128, 228, 328) may melt and thereafter solidify between the cover (124, 224, 324) and shell (104, 204, 304) to limit removal of the cover (124, 224, 324) from the shell (104, 204, 304).
    Type: Grant
    Filed: January 27, 2011
    Date of Patent: July 23, 2013
    Assignee: Mallinckrodt LLC
    Inventor: Robert J. Ziemba
  • Publication number: 20130170912
    Abstract: The present invention relates to a stowing method for a goaf of potash salt ore comprising making wall slurry into barricades each have the same area as the sectional area of a tunnel and a thickness of 0.5 to 5 meters inside the underground tunnels in the goaf of potash salt ore, with the interval between adjacent barricades being 5 to 100 meters, then stowing the interval between said barricades by using the filling slurry. The stowing method of the present invention uses the wall slurry of high strength that is solidified with a gelling agent as the main bearing material, and uses the solidified filling slurry with a low strength as the main filling material, which has a good effect when compared with conventional filling materials in that, the amount of additives that are used is smaller, the solidification time is short, the stowing strength is more adjustable, and the stowing cost is lower.
    Type: Application
    Filed: December 28, 2012
    Publication date: July 4, 2013
    Inventor: Wang QUAN
  • Publication number: 20120294679
    Abstract: The present invention provides a process for thickening drilling mud waste materials including the steps of mixing a drilling mud waste materials having greater than zero percent by weight free liquid with an effective amount of one or more anionic copolymers to form a treated drilling mud waste materials. The anionic copolymer is derived from either (a) an anionic monomer, a nonionic monomer, and a cross-linking monomer, resulting in a cross-linked anionic copolymer; or (b) a non-cross-linked, linear chain co-polymer of an anionic polymer and a nonionic polymer; or (c) a blend of the combination of (a) and (b). A modified drilling mud waste material is disclosed having zero percent by weight free liquid.
    Type: Application
    Filed: May 14, 2012
    Publication date: November 22, 2012
    Inventors: Craig D. Iman, James T. George, James S. Herceg, Craig W. Vaughan, Todd W. Groff
  • Patent number: 7364387
    Abstract: The invention relates to a method and device for accelerating the decomposition of biogenic organic matter in refuse disposal sites. According to the method, at least one suction line is inserted into a disposal site debris heap (11) via which the arising refuse site gases are removed by suction. According to the invention, the quantity of gas removed by suction in the area of the bottom of the refuse disposal site should be greater than the quantity of gas arising in this area due to decomposition whereby enabling oxygen from the outside air to penetrate into the debris heap and transforming the decomposition process into an, at least to a large extent, aerobic decomposition.
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: April 29, 2008
    Assignees: A3-Abfall-Abwasser-Anlagentechnik GmbH, Stadtreninigung Hamburg
    Inventors: Jürgen Kanitz, Jürgen Forsting
  • Patent number: 7284930
    Abstract: An alternative cover for landfill may be formed from a slurry mixture of water, cementitious binder, adhesion enhancing admixture and fiber. These constituents may be mixed and applied to cover landfilled wastes, granular material piles or for soil erosion control. The cover will harden to minimize water infiltration, wind blown dust, odor and affinity to birds, flies and other insects. The water may include tap water, landfill leachate and wastewater. The binder may include Portland cement, blended cement, cement kiln dust, class C fly ash, and/or calcium sulphate hemihydrate. The adhesion enhancing admixture includes water-dispersible polymers. The fibers may comprise shredded paper or wood or plastic fibers.
    Type: Grant
    Filed: October 20, 2003
    Date of Patent: October 23, 2007
    Assignee: CJS Technology, Inc.
    Inventors: Caijun Shi, Yanzhong Wu
  • Patent number: 7059805
    Abstract: The process for environmental pacification of drill cuttings which contain drilling fluid residue is characterized by mixing said cuttings with dehydrated limestone coke ash in the presence of water. Upon mixing the drilling fluid residue becomes entrapped into a non-leaching solid. Following treatment of drill cuttings with dehydrated limestone coke ash the resulting product has particular use as a road or work area base in connection with a topping which includes calcium sulfate hemihydrates.
    Type: Grant
    Filed: June 6, 2003
    Date of Patent: June 13, 2006
    Inventor: Fred E. Addison, Sr.
  • Patent number: 6846131
    Abstract: The invention pertains to business methods for enabling the creation of positive revenue streams from previously negative assets, and particularly from those facilities formed from gypsum waste, such as gypsum stacks. Waste containment or landfill facilities are formed from the conversion of gypsum refuse waste materials derived from gypsum mining and processing, such as from existing gypsum stacks, or from facilities formed in place from gypsum-based refuse. Such facilities are utilized, rented or leased as waste containment facilities for the short-term, long-term or permanent storage of non-gypsum waste materials such as solid waste, community refuse materials, biomass, industrial waste, phosphate waste, and for composting or otherwise processing materials such as biomass.
    Type: Grant
    Filed: May 19, 2003
    Date of Patent: January 25, 2005
    Inventors: Peter J. Ianniello, Mark Topp, Tracy R. Johnson
  • Publication number: 20040126189
    Abstract: A cost-effective, long-term, permanent method for stabilizing chromium in a chromium-contaminated waste matrix characterized by high concentrations of alkaline material (such as lime) includes the steps of contacting a source of hexavalent chromium with a source of ferrous ions to produce ferric ions; oxidizing iron pyrite to produce ferrous sulfate and sulfuric acid; and contacting the alkaline chromium-contaminated particulate matter with the ferrous sulfate and the sulfuric acid for a time sufficient to convert ferrous sulfate into ferric sulfate and to reduce mobile hexavalent chromium to non-leachable trivalent chromium. The method is integrated in that ferrous sulfate produced by oxidizing iron pyrite serves as a source of ferrous ions in the first contacting step. Optionally, ferric ions can be generated in a side reactor and then used to produce ferrous ions. The ferrous ions can be used both to produce further ferric ions in the side reactor and to treat COPR waste.
    Type: Application
    Filed: July 22, 2003
    Publication date: July 1, 2004
    Inventor: Ajit K. Chowdhury
  • Patent number: 6609578
    Abstract: A water-base fluid for use in drilling wells and other drilling operation includes a shale which swells in the presence of water. The fluid preferably includes: an aqueous based continuous phase, and a shale hydration inhibition agent having the formula: H2N—R—{OR′}x—Y in which R and R′ are alkylene groups having 1 to 6 carbon atoms and x is a value from about 1 to about 25. The Y group should be an amine or alkoxy group, preferably a primary amine or a methoxy group. The shale hydration inhibition agent should be present in sufficient concentration to reduce the swelling of the shale. The fluid may be used for formulating drilling fluids such as invert emulsion drilling muds or clear brine drilling fluids. The fluid may also be used in the slurrification and disposal of drill cuttings that contain water swellable clays or shales.
    Type: Grant
    Filed: June 18, 2001
    Date of Patent: August 26, 2003
    Assignee: Mo M-I LLC
    Inventors: Arvind D. Patel, Emanual Stamatakis, Eric Davis
  • Patent number: 6607474
    Abstract: A method for stabilizing chromium in a chromium-contaminated waste matrix characterized by high concentrations of alkaline material (such as lime) includes the steps of contacting a source of hexavalent chromium with a source of ferrous ions to produce ferric ions; oxidizing iron pyrite to produce ferrous sulfate and sulfuric acid; and contacting the alkaline chromium-contaminated particulate matter with the ferrous sulfate and the sulfuric acid for a time sufficient to convert ferrous sulfate into ferric sulfate and to reduce mobile hexavalent chromium to non-leachable trivalent chromium. The method is integrated in that ferrous sulfate produced by oxidizing iron pyrite serves as a source of ferrous ions in the first contacting step.
    Type: Grant
    Filed: June 27, 2001
    Date of Patent: August 19, 2003
    Assignee: RMT, Inc.
    Inventor: Ajit K. Chowdhury
  • Publication number: 20020015619
    Abstract: A method for filling a void using an aggregate material, such as mine tailings, the fill material being pumped from a site which is located remote from the void. A fluid, aerated material is formed by mixing the particulate solid material with finished foam. The aerated material may also include cement or another binder for applications requiring structural strength. The bubble structure which results from incorporating the foam constituent in the fill material renders this much more fluid and pumpable, thereby allowing the use of much higher solids-to-water ratios than would otherwise be possible while still being able to pump the material over significant distances. This reduces the possibly of fluidic collapse of the material in the void, and produces other advantages as well.
    Type: Application
    Filed: October 15, 2001
    Publication date: February 7, 2002
    Inventor: Patrick J. Stephens
  • Patent number: 6322489
    Abstract: A method of restoring wetlands is provided, by separating drill cuttings from drilling fluid, mixing the cuttings with a stabilization medium, and then filling a desired position in the marshland or wetlands with the reconstituted material.
    Type: Grant
    Filed: January 19, 2000
    Date of Patent: November 27, 2001
    Assignee: M-I LLC
    Inventors: Timothy R. Richardson, Paul M. Hanson
  • Patent number: 6309338
    Abstract: In a method for the treatment, in particular stabilization, of materials containing environmentally noxious constituents, especially from the incineration of waste, in which the materials are treated with ferrous compounds and water, the materials are washed and stabilized chemically using a solution containing ferrous ions (Fe++) which allows the formation of stabilizing ferric oxides (Fe+++) on the materials, the ferric oxide formation being carried out by means of an oxidation under controlled conditions with respect to the nature and the amount of oxidizing agent, temperature and pH, whereafter, if desired, the treated materials are subjected to a thermal after-treatment.
    Type: Grant
    Filed: February 26, 1999
    Date of Patent: October 30, 2001
    Assignee: Babcock & Wilcox Volund ApS
    Inventor: Thomas Højlund Christensen