Silver Metal With Metal Oxide Patents (Class 419/21)
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Patent number: 10610931Abstract: Methods and systems comprise new design procedures that can be implemented for additive manufacturing technologies that involve evaluation of stress concentration sites using finite element analysis and implementation of scanning strategies during fabrication that improve performance by spatially adjusting thermal energy at potential failure sites or high stress regions of a part.Type: GrantFiled: February 16, 2017Date of Patent: April 7, 2020Assignee: Board of Regents, The University of Texas SystemInventors: Philip A. Morton, Ryan Wicker, Jorge Mireles, Alejandro Hinojos
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Patent number: 8980166Abstract: The invention relates to a method for producing a strand-like, particularly band-like semi-finished part for electrical contacts, wherein the semi-finished part has a top side intended for making the electrical contact, said top side made from a silver-based composite material in which one or multiple metal oxides or carbon are embedded, and has a carrier layer supporting the composite material made of silver or a silver-based alloy, said method having the following steps: Powder-metallurgic production of a block made from the silver-based composite material, encasing of the block made of the composite material with a powder made primarily of silver, compressing the block, encased by the metal powder, to condense the metal powder, sintering the compressed block, reshaping the sintered block by extrusion pressing, creating a partial strand with a top side made from composite material and a bottom side made from silver or a silver-based alloy.Type: GrantFiled: October 27, 2009Date of Patent: March 17, 2015Assignee: Doduco GmbHInventors: Helmut Heinzel, Andreas Kraus, Evelyn Mahle-Moessner, Johann Wenz
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Patent number: 8967815Abstract: A process for manufacturing mirrors with increased reflectance includes forming a silver layer on a surface of a glass substrate, during which the surface is contacted with a silvering solution, and painting at least one paint layer to cover the silver layer. Between forming the silver layer and the painting, the process includes reheating the silver layer to a temperature of at least 200° C.Type: GrantFiled: October 5, 2009Date of Patent: March 3, 2015Assignee: AGC Glass EuropeInventors: Lionel Ventelon, Bruno Cosijns, Pierre Boulager, Joseph Leclercq
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Patent number: 8758476Abstract: Provided are a method of producing mixed powder comprising noble metal powder and oxide powder, wherein powder of ammonium chloride salt of noble metal and oxide powder are mixed, the mixed powder is subsequently roasted, and ammonium chloride is desorbed by the roasting process in order to obtain mixed powder comprising noble metal powder and oxide powder, and mixed powder comprising noble metal powder and oxide powder, wherein chlorine is less than 1000 ppm, nitrogen is less than 1000 ppm, 90% or more of the grain size of the noble metal powder is 20 ?m or less, and 90% or more of the grain size of the oxide powder is 12 ?m or less. Redundant processes in the production of noble metal powder are eliminated, and processes are omitted so that the inclusion of chlorine contained in the royal water and nitrogen responsible for hydrazine reduction reaction is eliminated as much as possible.Type: GrantFiled: August 18, 2009Date of Patent: June 24, 2014Assignee: JX Nippon Mining & Metals CorporationInventors: Atsutoshi Arakawa, Kazuyuki Satoh, Atsushi Sato
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Patent number: 8740044Abstract: A method for bonding a heat-conducting substrate and a metal layer is provided. A heat-conducting substrate, a first metal layer and a preformed layer are provided. The preformed layer is between the heat-conducting substrate and the first metal layer. The preformed layer is a second metal layer or a metal oxide layer. A heating process is performed to the preformed layer in an oxygen-free atmosphere to convert the preformed layer to a bonding layer for bonding the heat-conducting substrate and the first metal layer. The temperature of the heating process is less than or equal to 300° C.Type: GrantFiled: March 6, 2013Date of Patent: June 3, 2014Assignee: Subtron Technology Co., Ltd.Inventor: Chien-Ming Chen
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Publication number: 20130266468Abstract: A method of preparing silver-based oxide electrical contact materials with fiber-like arrangement, includes the following steps of: (1) uniformly mixing the silver-metal alloy powders and graphite powders and then ball-milling; (2) internally oxidizing the ball-milled powders; (3) sieving; (4) placing the sieved powders and the matrix powders into the powder mixer for mixing; (5) cold-isostatically pressing; (6) sintering; (7) hot-pressing; and (8) hot-extruding, thereby obtaining the silver-based oxide electrical contact material with fiber-like arrangement. The method of the present invention can obtain the silver-based oxide electrical contact material having neat fiber-like arrangement with no specific requirement on processing deformation, plasticity and ductility of the reinforcing phase. The production process in this method is simple and is easy to operate. Besides, there is no particular requirement on the equipment.Type: ApplicationFiled: April 11, 2011Publication date: October 10, 2013Inventors: Lesheng Chen, Xian Chen, Gengxin Qi, Chengfa Mu
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Publication number: 20100186999Abstract: An object of the present invention is to provide a method for producing a conductive material that allows a low electric resistance to be generated, and that is obtained by using an inexpensive and stable conductive material composition containing no adhesive. The conductive material can be provided by a producing method that includes the step of sintering a first conductive material composition that contains silver particles having an average particle diameter (median diameter) of 0.1 ?m to 15 ?m, and a metal oxide, so as to obtain a conductive material. The conductive material can be provided also by a method that includes the step of sintering a second conductive material composition that contains silver particles having an average particle diameter (median diameter) of 0.1 ?m to 15 ?m in an atmosphere of oxygen or ozone, or ambient atmosphere, at a temperature in a range of 150° C. to 320° C., so as to obtain a conductive material.Type: ApplicationFiled: January 9, 2009Publication date: July 29, 2010Inventors: Masafumi Kuramoto, Satoru Ogawa, Katsuaki Suganuma, Keun-Soo Kim
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Publication number: 20090053089Abstract: A method of making a homogeneous granulated metal-based powder, comprises steps of: providing preselected amounts of at least one metal element or metal alloy, at least one ceramic compound, and/or at least one non-metallic element; forming a homogeneous slurry/suspension or wet mixture comprising the preselected amounts of metal element(s) and/or metal alloys, ceramic compound(s), and/or non-metallic element(s), a liquid phase comprising at least one liquid, and at least one binder material; drying the slurry/suspension or mixture to remove at least a portion of the liquid phase and form a powder mixture comprising partially or completely dried granules; and subjecting the granules to a thermal de-binder process for effecting: additional removal of any remaining liquid phase, if necessary; removal of the at least one binder material; reduction of carbon content; reduction of oxygen on the surfaces or interior of the metal or metal alloy phases in the granules; and optional partial sintering for strengtheningType: ApplicationFiled: August 20, 2007Publication date: February 26, 2009Applicant: HERAEUS INC.Inventors: Fenglin YANG, Carl Derrington, Bernd Kunkel
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Method for preparing Ag-ZnO electric contact material and electric contact material produced thereby
Patent number: 6432157Abstract: An object of the present invention is to provide a method of producing an Ag—ZnO electric contact material which can uniformly disperse ZnO micrograms in Ag; which maintains low contact resistance; which exhibits enhanced welding resistance and wear resistance; and which is suitable in view of production costs. The method of producing an Ag—ZnO electrical contact material comprises casting Ag and Zn at predetermined proportions and subjecting the resultant Ag—ZnO alloy to internal oxidation so as to disperse ZnO in Ag, the method being characterized in that an Ag—Zn alloy comprising 5-10 wt. % (as reduced to weight of metal) Zn, the balance being Ag, is formed into chips; the chips are subjected to internal oxidation; the internally oxidized chips are compacted to thereby form billets; the billets are pressed and sintered; and subsequently, the sintered billets are extruded, to thereby yield uniform dispersion, in Ag, of ZnO micrograms.Type: GrantFiled: November 30, 2000Date of Patent: August 13, 2002Assignee: Tanaka Kikinzoku Kogyo K.K.Inventors: Tetsuya Nakamura, Osamu Sakaguchi, Hiroyuki Kusamori, Osamu Matsuzawa, Masahiro Takahashi, Toshiya Yamamoto -
Publication number: 20010051102Abstract: A method for producing composite powders based on silver-tin oxide, by chemically reductive precipitation of silver onto particulate tin oxide. A solution of a silver compound and a solution of a reducing agent are simultaneously added in stoichiometrically equivalent amounts, separately and continuously with intensive mixing, to an aqueous suspension of tin oxide.Type: ApplicationFiled: April 4, 2001Publication date: December 13, 2001Inventors: Roger Wolmer, Mechthild Mueller, Frank Heringhaus, Dietrich Ruehlicke, Dan Goia
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Patent number: 6056916Abstract: A process for producing a product made of a contact material. The contact material is formed of a powder mixture containing silver and iron as a main active component. The iron is an iron powder having an average particle size in excess of 1 .mu.m. Further processing of the powder mixture using powder metallurgy methods are performed for forming a product in which the iron has been oxidized to an iron oxide.Type: GrantFiled: February 1, 1999Date of Patent: May 2, 2000Assignee: Metalor Contacts Deutschland GmbHInventor: Franz Hauner
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Patent number: 5985440Abstract: Sintered silver-iron material for electrical contacts, with properties comparable with those of silver-nickel materials, is obtained by using iron powder having more than 0.25% carbon by weight and microhardness higher than 200 HV 0.025 and sintering in a hydrogen-free protective gas.Type: GrantFiled: February 27, 1997Date of Patent: November 16, 1999Assignee: Degussa AktiengesellschaftInventors: Wolfgang Weise, Willi Malikowski, Roger Wolmer, Peter Braumann, Andreas Koffler
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Patent number: 5963772Abstract: Electrical contact material made from intimate mixtures of silver powder and a powder of a second phase material is shown in which the powder of the second phase material is milled to produce a selected grain distribution of approximately 90% less than 7-10 microns, approximately 50% between 2 and 5 microns and approximately 10% less than 0.8 to 1.0 microns. The powder of the second phase material is added to a silver salt solution, ammonium hydroxide and hydrazine hydrate to form a precipitate of second phase material particles covered with silver. For applications in which the particles need to be free flowing the particles are compacted together without any binder, broken into chunks and milled to provide granules. In one embodiment homogeneously doped tin oxide particles are disclosed in which tin oxide and the oxide of the dopant are dissolved in nitric acid to produce finely dispersed tin oxide and dopant oxide. The oxides are calcined and ground to the selected grain size distribution.Type: GrantFiled: December 3, 1998Date of Patent: October 5, 1999Assignee: Chemet CorporationInventors: Ernest M. Jost, Kirk McNeilly
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Patent number: 5846288Abstract: Electrical contact material made from intimate mixtures of silver powder and a powder of a second phase material is shown in which the powder of the second phase material is milled to produce a selected grain distribution of approximately 90% less than 7-10 microns, approximately 50% between 2 and 5 microns and approximately 10% less than 0.8 to 1.0 microns. The powder of the second phase material is added to a silver salt solution, ammonium hydroxide and hydrazine hydrate to form a precipitate of second phase material particles covered with silver. For applications in which the particles need to be free flowing the particles are compacted together without any binder, broken into chunks and milled to provide granules. In one embodiment homogeneously doped tin oxide particles are disclosed in which tin oxide and the oxide of the dopant are dissolved in nitric acid to produce finely dispersed tin oxide and dopant oxide. The oxides are calcined and ground to the selected grain size distribution.Type: GrantFiled: November 26, 1996Date of Patent: December 8, 1998Assignee: Chemet CorporationInventors: Ernest M. Jost, Kirk McNeilly
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Patent number: 5841044Abstract: Silver-iron materials for electrical switching contacts with properties which come very close to those of silver-nickel materials formed of 0.5 to 4.5% by weight iron and 0.05 to 2% by weight of one or more of the oxides magnesium oxide, calcium oxide, yttrium oxide, lanthanum oxide, titanium oxide, zirconium oxide, hafnium oxide, cerium oxide, niobium oxide, tantalum oxide, chromium oxide, manganese oxide, iron oxide, zinc oxide, aluminum oxide, indium oxide, silicon oxide, and tin oxide, the balance being silver.Type: GrantFiled: November 19, 1996Date of Patent: November 24, 1998Assignee: Degussa AktiengesellschaftInventors: Wolfgang Weise, Willi Malikowski, Roger Wolmer, Peter Braumann, Andreas Koffler
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Patent number: 5822674Abstract: A material for electric contacts based on silver-tin oxide is obtained by mixing a powder of silver or an alloy mainly containing silver with a powder consisting mainly of tin oxide and 0.01 to 10 wt. % (in relation to the quantity of tin oxide) of an additive consisting of one or more compounds containing silver, oxygen and a metal from sub-groups II to VI of the periodic system and/or antimony, bismuth, germanium, indium and gallium, compacting the mixture and sintering it. The tin oxide may be replaced by zinc oxide.Type: GrantFiled: May 18, 1995Date of Patent: October 13, 1998Assignee: Doduco GmbH + Co. Dr. Eugen DurrwachterInventors: Volker Behrens, Thomas Honig
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Patent number: 5808213Abstract: Silver-iron materials for electrical switching contacts with properties which come very close to those of silver-nickel materials formed of 4.6 to 15% by weight iron and 0.05 to 5% by weight of one or more of the oxides magnesium oxide, calcium oxide, yttrium oxide, lanthanum oxide, cerium oxide, chromium oxide, iron oxide, aluminum oxide, indium oxide, silicon oxide, and tin oxide, the balance being silver.Type: GrantFiled: November 19, 1996Date of Patent: September 15, 1998Assignee: Degussa AktiengesellschaftInventors: Wolfgang Weise, Willi Malikowski, Roger Wolmer, Peter Braumann, Andreas Koffler
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Patent number: 5798468Abstract: An electrical contact material for switching rated currents between 20 and 100 Ampere having improved operational life made of 3.2 to 19.9 wt-% tin oxide and 0.05 to 0.4 wt-%, in each case, of indium oxide and bismuth oxide, the remainder being silver. In the course of the manufacture of the material by powder metallurgy more than 60 wt-% of the tin oxide should exhibit a particle size of more than 1 .mu.m.Type: GrantFiled: January 31, 1996Date of Patent: August 25, 1998Assignee: Degussa AktiengesellschaftInventors: Wolfgang Weise, Roger Wolmer, Peter Braumann
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Patent number: 5796017Abstract: Contact material based on silver, use of such a contact material in a switching device in power engineering, and process for preparing the contact material.For contact pieces in low-voltage switches, in particular, substitute materials based on silver-iron oxide are proposed for the silver-nickel hitherto often used in practice. According to the invention, such a material contains, as a further effective component, an oxide of a metal of the third sub-group, yttrium oxide (Y.sub.2 O.sub.3) being especially designed for this purpose. For example, a material of the composition Ag/Fe.sub.2 O.sub.3 10/Y.sub.2 O.sub.3 1 meets, with its favourable temperature behaviour, the properties required with respect to the contact property spectrum. In addition, at least one metal oxide which contains elements of the sixth sub-group of the Periodic Table of the Elements, preferably iron tungstate (FeWO.sub.4), can be present. In particular, a material of the composition Ag/Fe.sub.2 O.sub.3 9/Y.sub.2 O.sub.3 1/FeWO.sub.4 0.Type: GrantFiled: February 23, 1996Date of Patent: August 18, 1998Assignee: Siemens AktiengesellschaftInventor: Franz Hauner
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Patent number: 5794112Abstract: A process for making an inert electrode composite wherein a metal oxide and a metal are reacted in a gaseous atmosphere at an elevated temperature of at least about 750.degree. C. The metal oxide is at least one of the nickel, iron, tin, zinc and zirconium oxides and the metal is copper, silver, a mixture of copper and silver or a copper-silver alloy. The gaseous atmosphere has an oxygen content that is controlled at about 5-3000 ppm in order to obtain a desired composition in the resulting composite.Type: GrantFiled: June 26, 1997Date of Patent: August 11, 1998Assignee: Aluminum Company of AmericaInventors: Siba P. Ray, Robert W. Woods
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Patent number: 5728194Abstract: Silver-iron materials for electrical switching contacts with properties which come very close to those of silver-nickel materials formed of 0.5 to 20% by weight iron 0.5 to 5% by one or more of the elements rhenium, iridium, and ruthenium, and 0.05 to 2% by weight of one or more of the oxides magnesium oxide, calcium oxide, yttrium oxide, lanthanum oxide, titanium oxide, zirconium oxide, hafnium oxide, cerium oxide, niobium oxide, tantalum oxide, chromium oxide, manganese oxide, iron oxide, zinc oxide, copper oxide, aluminum oxide, indium oxide, silicon oxide, and tin oxide, the balance being silver.Type: GrantFiled: November 19, 1996Date of Patent: March 17, 1998Assignee: Degussa AktiengesellschaftInventors: Wolfgang Weise, Willi Malikowski, Roger Wolmer, Peter Braumann, Andreas Koffler
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Patent number: 5552370Abstract: A method for making metal/ceramic superconductor thick film structures including the steps of preparing a silver/superconductor ink, applying the ink to a substrate, evaporating the ink's binder, decomposing a silver compound in the residue to coat the superconductor grains, sintering the coated superconductor grains, and oxygenating the superconductor grains through the silver coating. The resultant inter-granular silver increases the critical current and mechanical strength of the superconductor.Type: GrantFiled: January 18, 1994Date of Patent: September 3, 1996Assignee: Hewlett-Packard CompanyInventors: John T. Anderson, V. K. Nagesh, Richard C. Ruby
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Patent number: 5480728Abstract: A conductive contact for use with metal oxide superconductors is described. The conductive contact comprises a metal contact which is attached by a diffusion bonding means to a superconductive metal oxide substrate. In a preferred embodiment, diffusion bonding means comprises a metal paint which includes metal particles and an organic binder which is heated to pyrolized the organic binder and form metallic diffusion bonds to the metal contact and metal oxide substrate. The invention also comprises a method for forming the conductive contact which includes selecting the superconducting metal oxide substrate, coating the substrate with a metal paint, placing the metal contact in touching contact with the metal paint and heating the combination of materials described above to pyrolized the organic binder and coalesce the metal particles.Type: GrantFiled: January 3, 1994Date of Patent: January 2, 1996Assignee: General Electric CompanyInventor: John E. Tkaczyk
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Patent number: 5455225Abstract: A method of producing a high-performance connection between a metal and a solid superconductive ceramic member is effected by introducing into a mold, in juxtaposition, grains or powder of the ceramic or of its precursors and a volume of silver or gold powder, and ceramic grains or powder at the level of an incorporated silver, gold or copper porous body of the foam, straw or lattice type prior to compression of the ceramic powder and sintering of the same. The electrical connection so formed exhibits a low electrical resistance capable of carrying high currents at rated temperature without interfering with the zero resistance state of the superconductive ceramic, with the metal connection free of cracking and having a contact resistance that is substantially constant throughout the range of superconductive material operating conditions.Type: GrantFiled: September 22, 1993Date of Patent: October 3, 1995Assignee: GEC Alsthom SAInventors: Ferard Duperray, Simon Lempereur
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Patent number: 5443786Abstract: A composition for the formation of vias on a ceramic substrate, the composition including (a) at least one powder containing copper, gold, silver, tungsten, molybdenum, nickel, palladium, platinum, aluminium, or an alloy thereof; and (b) 5 to 40 wt %, based on the weight of the powder in the composition, of one or more of an organosilicic compound, an organoaluminium compound, an organozirconium compound, and an organomagnesium compound. A further embodiment of a composition for the formation of vias includes (a) and (b) above and, in addition, (c) a binder material including a cellulose derivative or a heat decomposable polymethamethyl acrylate binder, and (d) a high boiling point organic solvent. The invention also includes a method for use in the formation of vias on a substrate having perforating holes therein. Such a substrate could be a glass ceramic composite substrate, an alumina substrate, a magnesia substrate, a zirconia substrate, or green sheets thereof.Type: GrantFiled: December 17, 1991Date of Patent: August 22, 1995Assignee: Fujitsu LimitedInventors: Hiromitsu Yokoyama, Koji Omote, Hitoshi Suzuki, Mineharu Tsukada, Nobuo Kamehara, Koichi Niwa
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Patent number: 5429791Abstract: An article and method of manufacture of a (Bi,Pb)--Sr--Ca--Cu--O superconductor comprisingcalcinating powders of superconductor precursors of PbO, Bi.sub.2 O.sub.3, SrCO.sub.3 or SrO, CaCO.sub.3 or CaO in air to obtain a 2223 superconductor lump and second phases;crushing the lump into powder;molding the powder into a superconductor body;disposing the body within silver powder to form a composite;molding the composite;heat treating the composite to increase the bond strength of the silver powder; andworking the composite into a useable shape by rolling and drawing while applying intermediate and final heat treatments to obtain a final product.Type: GrantFiled: June 23, 1994Date of Patent: July 4, 1995Assignees: Korea Atomic Energy Research Institute, Korea Electric Power CorporationInventors: Hee-Gyun Lee, Seon-Chil Kweon, Dong-Yeon Won, Gye-Won Hong
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Patent number: 5413753Abstract: Methods of forming composite articles of superconducting materials and metal at ambient temperature by applying a mixture of metal and binder to a ceramic oxide preform to yield a coated preform which is then heat treated to provide composite articles of superconducting ceramic and metal.Type: GrantFiled: September 17, 1993Date of Patent: May 9, 1995Assignee: E. I. Du Pont de Nemours and CompanyInventor: George E. Zahr
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Patent number: 5399312Abstract: A process for fabricating Thallium-based superconducting tapes comprising the steps of: (1) preparing a powder mixture having a nominal composition of (Tl.sub.1-x-y Bi.sub.y Pb.sub.z)(Ba.sub.2-z Sr.sub.z)Ca.sub.2 Cu.sub.3 O.sub.9 ; (2) placing the powder mixture into a silver tube and drawing and/or swaging the silver tube containing the powder mixture into a wire having a pre-determined diameter, wherein x and y are real numbers between 0.2 and 0.4, and z is a real number between 0 and 2; (3) rolling the wire into a tape having a pre-determined thickness; and (4) subjecting the tape to a two-stage single-sintering process at two respective sintering temperatures. The two-stage single-sintering process of the present invention allows Thallium-based superconducting tapes to be fabricated which exhibit substantially increased critical current density, without causing a substantially increased cost and complexity, as do other prior art processes, such as the double-sintering process.Type: GrantFiled: October 4, 1993Date of Patent: March 21, 1995Assignee: Industrial Technology Research InstituteInventors: Ru-Shi Liu, Sheng-Feng Wu, Chung-Ho Tai, Der-Shiuh Shy
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Patent number: 5338507Abstract: A method for making metal/ceramic superconductor thick film structures including the steps of preparing a silver/superconductor ink, applying the ink to a substrate, evaporating the ink's binder, decomposing a silver compound in the residue to coat the superconductor grains, sintering the coated superconductor grains, and oxygenating the superconductor grains through the silver coating. The resultant inter-granular silver increases the critical current and mechanical strength of the superconductor.Type: GrantFiled: August 29, 1991Date of Patent: August 16, 1994Assignee: Hewlett-Packard CompanyInventors: John T. Anderson, V. K. Nagesh, Richard C. Ruby
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Patent number: 5326525Abstract: A process is disclosed for fabricating a metal aluminide composite which comprises providing a metal aluminide, such as titanium aluminide, or a titanium aluminide alloy, and a reinforcing fiber material, such as silicon carbide fiber, and placing an interlayer or diffusion barrier layer in the form of a metal selected from the group consisting of silver, copper and gold, and alloys thereof, between the metal aluminide and the reinforcing fiber material. The interlayer metal can be a foil of the metal or in the form of a coating, such as a silver coating, on the reinforcing fiber material. The metal aluminide, the reinforcing fiber material, and the metal interlayer, e.g., in the form of a packet of a plurality of alternate layers of metal aluminide alloy and reinforcing fiber material, each layer being separated by the metal interlayer, is pressed and heated at an elevated temperature, e.g., ranging from about 900.degree. to about 1200.degree. C., at which diffusion bonding occurs.Type: GrantFiled: July 11, 1988Date of Patent: July 5, 1994Assignee: Rockwell International CorporationInventor: Amit K. Ghosh
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Patent number: 5286441Abstract: A silver-metal oxide composite material comprising a silver matrix, (a) from 1 to 20% by weight, in terms of elemental metal, of an oxide of at least one element selected from the group consisting of Sn, Cd, Zn and In and, optionally, (b) an oxide of Mg, Zr, etc. and/or (c) an oxide of Cd, Sb, etc.; the oxides being dispersed in the form of fine particles with a particle size of not more than about 0.1 .mu.m uniformly and being bound to the silver matrix with no space left, and a process for producing the same. The composite material is excellent in physical and chemical strengths at high temperatures. The process can produce the composite product even with thick walls, within a markedly short time in high productivity. The composite material is useful as electrical contact materials and electrode materials for electric welding.Type: GrantFiled: June 3, 1992Date of Patent: February 15, 1994Assignees: Akira Shibata, Sumico Management Planning Company, Ltd.Inventor: Akira Shibata
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Patent number: 5284527Abstract: A method of making silver-metal oxide materials suitable for use in electrical contacts includes oxidizing a silver-solute metal alloy in an oxidizing atmosphere. The oxidizing atmosphere has a sufficient amount of halide to inhibit the formation of a protective oxide scale around the alloy.Type: GrantFiled: January 21, 1992Date of Patent: February 8, 1994Assignee: United Technologies CorporationInventors: John G. Smeggil, Norman J. Becker
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Patent number: 5258052Abstract: A powder metallurgy material for use in the manufacture of electrical contacts and having enhanced cold workability consists essentially, by weight percent, of 5 to 20% tin oxide, 2000 to 5000 ppm, preferably 2000 to less than 4000 ppm copper, 20 to 200 ppm, preferably 20 to 100 ppm, lithium, balance silver. Such materials are produced by compacting the powdered components and heating to sinter the material to at least 93% of theoretical density. Such materials subsequently can be hot or cold worked to a form useful for the manufacture of electrical contacts.Type: GrantFiled: June 18, 1992Date of Patent: November 2, 1993Assignee: Advanced Metallurgy IncorporatedInventor: Richard C. Bevington
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Patent number: 5223480Abstract: A novel method for forming homogeneous silver high temperature superconductor (HTS) composites. The novel method comprises a chemical coprecipitation of silver, barium, yttrium, and copper salts solutions, followed by calcination and milling processes. The novel method has an advantage of retaining all the virtues immanent in a composite HTS, for example, increased critical current density (Jc), and improved mechanical properties, while bypassing extant and deficient methodologies for forming a composite, the deficient composites characterized by heterogeneity.Type: GrantFiled: April 22, 1991Date of Patent: June 29, 1993Assignee: Eastman Kodak CompanyInventors: Ashok K. Agarwala, Paul A. Christian, Kenneth B. Quinn
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Patent number: 5200392Abstract: An improved ceramic-plus-metal superconducting composition of YBa.sub.2 Cu.sub.3 O.sub.6+x plus substantially pure aluminum for ultimate use in making superconducting devices such as wires and tapes for utilization in motors, generators, electric circuits, etc.Type: GrantFiled: October 18, 1990Date of Patent: April 6, 1993Assignee: The United States of America as represented by the Secretary of the NavyInventors: A. Srinivasa Rao, Om P. Arora
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Patent number: 5179075Abstract: A method of making at least one low electrical resistance connection between a metal and a high T.sub.c superconducting ceramic part, said part being made from a ceramic powder which is placed in a mold, compressed, and sintered, wherein at least one volume of silver or gold powder corresponding to the shape of said connection and situated at the desired location is placed inside said mold in juxtaposition with said ceramic powder but without being mixed therewith, after which the compression and the sintering are performed under an atmosphere containing oxygen and at a temperature that is lower than the melting temperature of silver or gold.Type: GrantFiled: October 29, 1990Date of Patent: January 12, 1993Assignee: GEC Alsthom SAInventors: Albert Leriche, Gerard Duperray, Fernand Grivon
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Patent number: 5160366Abstract: A silver-metal oxide composite material comprising a silver matrix, (a) from 1 to 20% by weight, in terms of elemental metal, of an oxide of at least one element selected from the group consisting of Sn, Cd, Zn and In and, optionally, (b) an oxide of Mg, Zr, etc. and/or (c) an oxide of Cd, Sb, etc.; the oxides being dispersed in the form of fine particles with a particle size of not more than about 0.1 .mu.m uniformly and being bound to the silver matrix with no space left, and a process for producing the same. The composite material is excellent in physical and chemical strengths at high temperatures. The process can produce the composite product even with thick walls, within a markedly short time in high productivity. The composite material is useful as electrical contact materials and electrode materials for electric welding.Type: GrantFiled: March 14, 1991Date of Patent: November 3, 1992Assignees: Sumico Management Planning Company, Ltd., Akira ShibataInventor: Akira Shibata
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Patent number: 5071826Abstract: A method for making metal/ceramic superconductor thick film structures including the steps of preparing a silver/superconductor ink, applying the ink to a substrate, evaporating the ink's binder, decomposing a silver compound in the residue to coat the superconductor grains, sintering the coated superconductor grains, and oxygenating the superconductor grains through the silver coating. The resultant inter-granular silver increases the critical current and mechanical strength of the superconductor.Type: GrantFiled: October 13, 1989Date of Patent: December 10, 1991Assignee: Hewlett-Packard CompanyInventors: John T. Anderson, V. K. Nagesh, Richard C. Ruby
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Patent number: 5041416Abstract: A superconductor metal matrix composite formable into an electrical current carrying material. A superconductive particulate is intermixed with a normal metal matrix, pressed into form and heated to form the composite. The metal matrix surrounds the superconductive particulate to prevent loss of oxygen from the superconductive particulate so the particulate retains its superconductive properties. The metal matrix also becomes superconductive due to proximity effect.Type: GrantFiled: October 16, 1990Date of Patent: August 20, 1991Assignee: FMC CorporationInventor: Charles N. Wilson
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Patent number: 5041414Abstract: Continuous malleable superconductive material which can be machined, rolled and soldered, being the product of sintering at an elevated temperature and pressure of a metal plated powder of a compound QBa.sub.2 Cu.sub.3 O.sub.7-x wherein Q is yttrium or europium, where x is smaller than one. The metal is advantageously silver and the plating process is one without the use of electricity. A preferred range of silver content is about 5 to 32 weight per cent, and the silver forms an essentially continuous phase in the superconductive material. Sintering can be done at from about 350.degree. and 950.degree. C., with a preferred range of 400.degree. to 900.degree. C. The superconductive material of the invention exhibits transition to zero-resisitivity state and the Meissner effect.Type: GrantFiled: February 13, 1989Date of Patent: August 20, 1991Assignee: Yeda Research and Development Company LimitedInventor: Shymon Reich
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Patent number: 5034373Abstract: The invention provides a process for production of silver-containing precursor alloys to oxide superconductors, said alloys having reduced amounts of intermetallics. Powders containing metallic elemental components of an oxide superconductor are high energy milled for a predetermined amount of time to increase homogeneity of the mixed metallic elemental components of the oxide superconductor. Silver is then high energy milled into the metallic components. The mixed silver and metallic elemental components of the oxide superconductor are compacted for the silver-containing superconductor precursor. The compacted powder is preferably hot worked at a temperature of at least 50% of the precursor alloy's melting temperature in degrees Kelvin.Type: GrantFiled: December 22, 1989Date of Patent: July 23, 1991Assignees: Inco Alloys International, Inc., American Superconductor CorporationInventors: Gaylord D. Smith, Jon M. Poole, Marvin G. McKimpson, Lawrence J. Masur, Kenneth H. Sandhage
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Patent number: 5000909Abstract: A composite comprised of a sintered matrix of spinel ferrite and a non-exposed continuous phase of elemental silver or Ag-Pd alloy ranging to 25 atomic % Pd is produced by co-firing a laminated structure of ferrite powder-containing tapes containing non-exposed metallization-forming material. The composite can be formed into a composite product which contains a continuous silver or Ag-Pd alloy phase with two end portions wherein only the end portions are exposed.Type: GrantFiled: May 7, 1990Date of Patent: March 19, 1991Assignee: General Electric CompanyInventors: Richard J. Charles, Achuta R. Gaddipati
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Patent number: 4999155Abstract: The present invention is directed to a method for forming porous oxide dispersion strengthened molten carbonate fuel cell anodes having improved anode creep resistance. The method comprises the steps of forming an alloy powder comprised of a base metal and an alloy metal, forming the alloy into a porous anode structure by sintering, and then placing the porous anode structure under conditions in which the base metal is reduced and the alloy metal is oxidized, thereby internally oxidizing the alloy metal to form oxide particles therein.Type: GrantFiled: October 17, 1989Date of Patent: March 12, 1991Assignee: Electric Power Research Institute, Inc.Inventors: Estela T. Ong, Diane S. Erickson, Leonard G. Marianowski
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Patent number: 4983572Abstract: A superconductive body of an oxidic superconductive material having good mechanical properties is characterized in that the oxidic material forms a matrix through which finely divided particles are mixed at least the surface of which consists of a metal or a metal alloy. Particles in the form of fibres are preferably used and the surface of the particles consists of silver or gold.Type: GrantFiled: August 25, 1988Date of Patent: January 8, 1991Assignee: U.S. Philips CorporationInventor: Gijsbertus De With
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Patent number: 4980125Abstract: Sinter materials having the constitution AgSnO.sub.2 Bi.sub.2 O.sub.3 CuO produced from an intraoxidized alloy powder have added thereto bismuth zirconate and/or bismuth titanate in parts by weight of preferably between 0.1 and 5%. For the production of these materials, bismuth zirconate and/or bismuth titanate is added as a separate powder to the intraoxidized alloy powder of AgSnO.sub.2 Bi.sub.2 O.sub.3 CuO. With such a contact material, the excess temperature behavior in motor contactors is significantly improved.Type: GrantFiled: November 17, 1989Date of Patent: December 25, 1990Assignee: Siemens AktiengesellschaftInventors: Wolfgang Haufe, Ralf-Dieter Krause, Bernhard Rothkegel, deceased
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Patent number: 4975414Abstract: The method of producing a superconducting product includes: providing a pressed-powder preform consisting essentially of REBa.sub.2 Cu.sub.3 O.sub.x where 6.0<x<7.0; preheating the preform to elevated temperature for a time period between 0 and 10 minutes, within a medium consisting of a mixture of refractory ceramic particles, carbonaceous particles and ultra fine graphitic particles; providing a preheated grain bed and embedding the heated preform in that bed, the bed having the same composition as the medium; and consolidating the preform to at least about 95% of theoretical density by application of pressure to the grain bed, thereby to form the product.Type: GrantFiled: November 13, 1989Date of Patent: December 4, 1990Assignee: Ceracon, Inc.Inventors: Henry S. Meeks, Sundeep V. Rele
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Patent number: 4971754Abstract: The method concerns preparing a contact material constituted by silver and tin oxide.According to the invention the method comprises the following steps:preparing an aqueous solution containing dissolved silver nitrate and tin oxide particles in suspension, with the size of said particles measured in terms of specific surface area using the BET method lying between about 2 m.sup.2 /g and 6 m.sup.2 /g;causing silver nitrate to precipitate in silver hydroxide by rapidly adding a strong base and stirring, with silver hydroxide being unstable and transforming progressively into silver oxide;eliminating the ions from the solution and then the water in order to obtain a dry product; andheating the dry product to a temperature of about 200.degree. C. to 500.degree. C. in order to reduce the silver oxide to metallic silver.The invention is applicable to manufacturing electrical contacts for opening and closing in electromechanical apparatuses.Type: GrantFiled: November 22, 1989Date of Patent: November 20, 1990Assignee: TelemecaniqueInventors: Gerard Fontet, Michel Leclercq, Jacques Muniesa, Thierry Pagnier, Tretarre Rene
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Patent number: 4966625Abstract: A composite comprises of a sintered matrix of spinel ferrite and an electrically conductive phase of elemental silver is produced by co-firing a laminated structure of ferrite powder-containing tapes containing a silver metallization-forming material having two end portions wherein only the end portions are exposed.Type: GrantFiled: June 5, 1989Date of Patent: October 30, 1990Assignee: General Electric CompanyInventors: Richard J. Charles, Achuta R. Gaddipati
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Patent number: 4954170Abstract: High density compacts are made by providing a compactable particulate combination of Class 1 metals selected from at least one of Ag, Cu and Al, with material selected from at least one of CdO, SnO, SnO.sub.2, C, Co, Ni, Fe, Cr, Cr.sub.3 C.sub.2, Cr.sub.7 C.sub.3, W, WC, W.sub.2 C, WB, Mo, Mo.sub.2 C, MoB, Mo.sub.2 B, TiC, TiN, TiB.sub.2, Si, SiC, Si.sub.3 N.sub.4, usually by mixing powders of each, step (1); uniaxially pressing the powders to a density of from 60% to 95%, to provide a compact, step (2); hot densifying the compact at a pressure between 352 kg/cm.sup.2 (5,000 psi) and 3,172 kg/cm.sup.2 (45,000 psi) and at a temperature from 50.degree. C. to 100.degree. C. below the melting point or decomposition point of the lower melting component of the compact, to provide densification of the compact to over 97% of theoretical density; step (3); and cooling the compact, step (4).Type: GrantFiled: June 30, 1989Date of Patent: September 4, 1990Assignee: Westinghouse Electric Corp.Inventors: Maurice G. Fey, Natraj C. Iyer, Alan T. Male, William R. Lovic
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Patent number: 4948424Abstract: Sinter contact materials produced from an intraoxidized alloy powder having the constitution AgSnO.sub.2 Bi.sub.2 O.sub.3 CuO have added thereto at least zirconium oxide and optionally additionally bismuth oxide in parts by weight of preferably between 0.1 and 5%. For the production of these materials, zirconium oxide power and optionally additionally bismuth oxide powder is added to the intraoxidized alloy powder AgSnO.sub.2 Bi.sub.2 O.sub.3 CuO. With such a contact material, the excess temperature behavior in motor contactors is improved.Type: GrantFiled: November 17, 1989Date of Patent: August 14, 1990Assignee: Siemens AktiengesellschaftInventors: Wolfgang Haufe, Bernard Rothkegel, deceased