Additional Material Is Solid Patents (Class 419/37)
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Patent number: 5330700Abstract: A porous electrode for pacemakers is comprised of a plurality of platinum globules sintered together to form a porous mass of semi-hemispherical shape at the end of a platinum electrode stem. The globules, which are themselves made by sintering together spherically-shaped particles of approximately one micron diameter, provide the globules with an irregular outer surface of high total surface area. The globules have diameters within a critical range of 40-200 microns. The large total surface area of the globules improves the sensing function of an electrode configuration of given size and surface area, while the globule diameters of 40-200 microns have been found to beneficially accommodate tissue ingrowth within the electrode. In a preferred method of making the electrode, the platinum globules, which are formed by sintering together platinum particles of much smaller size, are mixed with organic solvent and organic binder to form a paste.Type: GrantFiled: September 18, 1991Date of Patent: July 19, 1994Assignee: Siemens Pacesetter, Inc.Inventors: Thomas M. Soukup, Paul E. Kreyenhagen
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Patent number: 5314658Abstract: Tungsten and molybdenum powders are advantageously conditioned for metal injection molding by fluid energy milling the powder prior to batching. A preferred method of conditioning, jet milling, has been found to beneficially effect the particle characteristics to render the metal powder more suitable for injection molding.Type: GrantFiled: April 3, 1992Date of Patent: May 24, 1994Assignee: AMAX, Inc.Inventors: David N. Meendering, Deepak Malhotra, Linda K. Baltich
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Patent number: 5308575Abstract: A sintered dense laser block constructed of ceramic metal composition manufactured through sintering, conventional machining and electro discharge machining. A ceramic metal powder and binder are combined and shaped into a laser block. The laser block is then sintered to permit electro-discharge machining. After detailed machining various subsequent firings will yield different dielectric properties for the laser block. Other laser gyro ceramic parts may be manufactured with the method of the invention such as mirror assemblies, cathodes and laser path length controllers. The electro-discharge machining permits the construction of complex ceramic shapes from a slurry of powdered ceramic metal and binder which has been extruded or shaped and then conventional machined. The resulting part is cheaper and easier to make and the electro-discharge machining provides a method of creating very complex shapes in the part.Type: GrantFiled: September 27, 1991Date of Patent: May 3, 1994Assignee: Honeywell Inc.Inventor: Carol M. Ford
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Patent number: 5284615Abstract: The present invention presents a method of processing ferrous powder materials to produce small component parts exhibiting excellent soft magnetic properties, in particular, residual magnetic flux density. The processing steps involve, in part, mixing with a binder, dewaxing or presintering at a temperature higher than in the conventional dewaxing process, followed by final sintering and a further conversion sintering, at a temperature lower than in the conventional sintering process, to produce parts having density values of over 96% theoretical density and excellent soft magnetic properties. The invented method is suitable for producing small component parts having sufficient strength and excellent soft magnetic properties to make them suitable for miniaturized electrical and electronic equipment.Type: GrantFiled: July 15, 1992Date of Patent: February 8, 1994Assignee: Mitsubishi Materials CorporationInventors: Koshiro Ueda, Mutsumi Moribayashi, Tohru Kohno
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Patent number: 5283031Abstract: A process for producing a precision metal part of a sintered body by powder molding comprises using a metal powder of which the oxygen content and the hydrogen reduction loss are controlled to 0.5-6 wt. % and 1-7 wt. %, respectively. The sintered body has a high density near the theoretical density and is excellent in dimensional accuracy. The molding is facilitated, and the process is simple.Type: GrantFiled: July 23, 1991Date of Patent: February 1, 1994Assignee: Citizen Watch Co., Ltd.Inventors: Naoto Ogasawara, Kenji Kurimura, Ken-ichi Yoshioka, Shigeru Saito, Takao Kasai, Masami Hoshi, Seiichi Nakamura
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Patent number: 5279787Abstract: Numerous products can be formed by combining a low melting matrix made up of one or more metals and high melting, high density metal particles and wherein the products can be formed by adding the high density particles to a molten matrix metal and casting same, mixing powders of all the metals together, compacting and centering at a temperature in the low end of the melting range of the matrix alloy, or by mixing the high density particles into a paste of the matrix alloy and molding. These methods and compositions are particularly adaptable for use in forming low or non-toxic high density projectiles, such as, shot, bullets and pellets having a density comparable to that of lead while avoiding problems of toxicity associated with the use of lead.Type: GrantFiled: April 29, 1992Date of Patent: January 18, 1994Inventor: Victor C. Oltrogge
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Patent number: 5273708Abstract: In making a dual alloy gas turbine rotor, a plurality of superalloy components are formed to include an airfoil having a directionally solidified columnar grain structure or a single crystal grain structure. A boron-bearing melting point depressant material is applied to the inner surface and a side surface of the components. The components are arranged side-by-side in an annular array with the first side surface of one component juxtaposed to the second side surface of an adjacent component and with the inner surfaces defining a spray-receiving surface. The airfoils extend in a radial axis or direction of the array while the spray-receiving surface extends in a circumferential direction of the article. A sealing member is positioned adjacent an axial end of the array of the components to close off that end and form a spray-receiving cavity. Boron-bearing melting point depressant material is provided between the sealing member and the end of the array.Type: GrantFiled: June 23, 1992Date of Patent: December 28, 1993Assignee: Howmet CorporationInventor: William R. Freeman
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Patent number: 5268233Abstract: The invention relates to a method of preparing sintered shapes, comprising the steps of forming a green body from a mixture comprising (A) a major amount of at least one inorganic powder with (B) at least one reaction product of an amine other than an alkanolamine with a hydrocarbyl-substituted carboxylic acylating agent or alkylalkyleneglycolacetic acylating agent; provided the reaction product is other than an alkylene oxide treated fatty monocarboxylic amide and provided that when the hydrocarbyl-substituted carboxylic acylating agent is a nonaromatic acylating agent, then the hydrocarbyl group is other than hydrocarbyl groups having an average of about 55 to about 110 carbon atoms; and sintering the body. Sintered shapes made from the methods of the present invention have relatively high fired densities and small uniform grain sizes; and low porosity. The reaction products of the present invention help disperse the inorganic powder.Type: GrantFiled: November 22, 1991Date of Patent: December 7, 1993Assignee: The Lubrizol CorporationInventors: Fred E. Heller, William Higgins, Robert E. Quinn
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Patent number: 5266264Abstract: The present invention relates to a process for producing sinters, including a steps of mixing a powder material with a binder, injection molding the mixture, and then dewaxing and sintering the resulting injection molded article, wherein the binder comprises at least one of: copolymer, a mixture of copolymer, paraffine wax, carnauba wax, a mixture of the paraffine wax and the carnauba wax, a plasticizer, and a lubricant. According to the present invention, the dewaxing step comprises heating the injection molded article to a temperature of 250.degree.-500.degree. C. in a heating rate of 5.degree.-100.degree. C./hour under the pressure not higher than 1 Torr in order to remove 40%-95 % by weight of the binder components. Further, the temperature elevation in the sintering step is started in a vacuum atmosphere and replacing the atmosphere with an inert gas atmosphere in the process of temperature elevation.Type: GrantFiled: December 31, 1991Date of Patent: November 30, 1993Assignee: The Japan Steel Works Ltd.Inventors: Ritsu Miura, Hirokazu Madarame, Masahiro Uchida, Yasushi Owaki
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Patent number: 5262122Abstract: The disclosure relates to a method of binder removal from a green body before sintering or the like wherein the green body is initially heated to a temperature above the melting or flow point of the binder to liquify the binder and, at the elevated temperature, a small portion of the green body is brought into intimate contact with a non-supporting porous body of lower capillarity potential for the liquid binder. The liquid is drawn from all parts of the green body to the region of contact between the porous body and the green body and enters the body of lower capillarity potential preferentially, removing liquid from the green body through the surface of the green body only at said region of contact. The draining is continued with or without further increase in temperature until the green body is opened or becomes permeable.Type: GrantFiled: December 10, 1991Date of Patent: November 16, 1993Assignee: Witec Cayman Patents, Ltd.Inventor: Raymond E. Wiech, Jr.
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Patent number: 5250254Abstract: A compound for producing sintered parts in an injection molding process and the molding process used to form the parts. The compound contains materials that allow the parts to be formed at lower temperatures and higher production rates when compared to more conventional processes.Type: GrantFiled: December 20, 1991Date of Patent: October 5, 1993Assignee: Sumitomo Metal Mining Co., Ltd.Inventors: Masakazu Achikita, Akihito Ohtsuka
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Patent number: 5194219Abstract: Very good masking of pack diffusion aluminizing or chromizing on any metal to keep portions from being diffusion coated, is effected by localized coating the lowest layer of which is depletion-reducing masking powder the metal portion of which can have same composition as substrates, mixed with inert refractory diluent and non-contaminating film-former such as acrylic resin. The upper coating layer can be of non-contaminating particles like nickel or Cr.sub.2 O.sub.3 that upon aluminizing or chromizing become coherently held together to form a secure sheath. Such sheath can also be used for holding localized diffusion-coating layer in place. Film-former can be dissolved in volatile solvent, preferably methyl chloroform, in which masking powder or sheath-forming powder is suspended. Chromizing can be performed before aluminizing for greater effects. Aluminizing of metals like iron and nickel followed by leaching out much of the diffused-in aluminum, gives these substrates a pyrophoric and catalytic surface.Type: GrantFiled: July 7, 1992Date of Patent: March 16, 1993Assignee: Alloy Surfaces Company, Inc.Inventor: Alfonso L. Baldi
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Patent number: 5194203Abstract: A method of mixing a powder material and a binder in a predetermined ratio and kneading the mixture so that substantially whole surface of the powder particles are covered by the binder, molding the kneaded mixture into the shapes of desired products, then removing the binder from the moldings without causing expansion or cracks in the moldings before sintering. The binder comprises one or more organic binding substances soluble to an alcohol or to an mixed solvent of an alcohol and benzene or one or more ketones and one or more organic binding substances insoluble to the alcohol or to the mixed solvent. The moldings are put in contact with the alcohol or the mixed solvent to extract the organic binding substances soluble to the alcohol or to the mixed solvent from the moldings. The organic binding substances insoluble to the alcohol or to the mixed solvent are then removed by heat-decomposition.Type: GrantFiled: December 31, 1991Date of Patent: March 16, 1993Assignee: Mitsui Mining & Smelting Co., Ltd.Inventors: Yoshimitsu Kankawa, Yasunari Kaneko, Norio Kasahara
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Patent number: 5192372Abstract: Isotropic permanent magnet formed of a sintered body having a mean crystal grain size of 1-160 microns and a major phase of tetragonal system comprising, in atomic percent, 10-25% of R wherein R represents at least one of rare-earth elements including Y, 3-23% of B and the balance being Fe. As additional elements M, Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni or W may be incorporated.The magnets can be produced through a powder metallurgical process resulting in high magnetic properties, e.g., up to 7 MGOe or higher energy product.Type: GrantFiled: June 18, 1991Date of Patent: March 9, 1993Assignee: Sumitomo Special Metals Co., Ltd.Inventors: Setsuo Fujimura, Masato Sagawa, Yutaka Matsuura
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Patent number: 5188793Abstract: A dewaxing method of a metal and/or ceramic molded body which comprises immersing the metal and/or ceramic molded body formed through a plastic molding in a boiling solvent to extract the dispersion medium contained in the molded body with said solvent. According to the method of the invention, the dewaxing time can be shortened from about 150 hours to the sum of about 54 hours for the solvent extraction and about 11 hous for dewaxing under heating. The dewaxed molded body is a sound body containing no crack nor expansion.Type: GrantFiled: August 8, 1990Date of Patent: February 23, 1993Assignee: NKK CorporationInventor: Hiroaki Nishio
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Patent number: 5174951Abstract: A method of producing a porous metal, which comprises forming a mixture of a metal powder and a fibrous substance and subjecting the mixture to sintering treatment to obtain a porous metal; a catalyst carrier obtained by laminating a dried sheet wherein a metal powder is supported in a fibrous substance with a dried sheet obtained by corrugating a dried sheet similar to the first-mentioned sheet to form an assembly of a number of cells having both ends opened and subjecting the assembly to sintering treatment; and a filter element obtained by laminating a dried sheet wherein a metal powder is supported in a fibrous substance with a dried sheet obtained by corrugating a dried sheet similar to the first-mentioned sheet to form an assembly of a number of cells whose one end is opened and whose other end is closed and subjecting the assembly to sintering treatment.Type: GrantFiled: December 21, 1990Date of Patent: December 29, 1992Assignee: Asahi Tec CorporationInventors: Kiyoshi Nakai, Tokuhiko Ikki
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Patent number: 5154881Abstract: Methods of making sintered parts from a metal powder composition that contains an amide lubricant are provided. The composition comprises an iron-based powder and a lubricant that is the reaction product of a monocarboxylic acid, a dicarboxylic acid, and a diamine. The composition is compacted in a die, preferably at an elevated temperature of up to about 370.degree. C., at conventional compaction pressures, and then sintered according to standard powder-metallurgical techniques.Type: GrantFiled: February 14, 1992Date of Patent: October 13, 1992Assignee: Hoeganaes CorporationInventors: Howard G. Rutz, Sidney Luk
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Patent number: 5151246Abstract: A method is described for manufacturing foamable metal bodies in which a ture (17) of a metal powder (15) and a gas-splitting propellent powder (16) is hot-compacted to a semifinished product (19) at a temperature at which the joining of the metal powder particles takes place primarily by diffusion and at a pressure which is sufficiently high to hinder the decomposition of the propellent in such fashion that the metal particles form a solid bond with one another and constitute a gas-tight seal for the gas particles of the propellant. The foamable metal body can also be produced by rolling. In addition, a use of the foamable metal body (19) thus produced for manufacturing a porous metal body (21) is proposed.Type: GrantFiled: May 31, 1991Date of Patent: September 29, 1992Assignee: Fraunhofer-Gesellschaft zur Forderung der angewandten Forschung e.V.Inventors: Joachim Baumeister, Hartmut Schrader
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Patent number: 5147601Abstract: A composition comprising a powder of iron and nickel and a binder (e.g. wax) is injection molded. The powder contains 0.5 to 10% by weight of nickel and has an average particle diameter not exceeding 45 microns. The binder is removed from the molded product. The molded product is sintered, and the sintered product is cooled to room temperature slowly at a rate of 2.degree. C. to 50.degree. C. per minute. The sintered product is of an iron-nickel alloy, has a high density and a high level of soft ferromagnetic properties, and may be complicated in shape.Type: GrantFiled: March 30, 1992Date of Patent: September 15, 1992Assignee: Sumitomo Metal Mining Co., Ltd.Inventors: Akihito Ohtsuka, Yoshio Kijima
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Patent number: 5143692Abstract: A method of making a substructure for a dental restoration which comprises a substructure of a dental metal and a fired on coating of a dental ceramics, which method comprises applying a powder-form mixture of a dental metal powder and a thermoplastic polymeric material having a melting point above 50.degree. C., in the shape of the dental restoration to be made, to a porous refractory model, by means of a heated instrument, heating the assembly so obtained to a temperature at which the thermoplastic polymeric material liquefies and is sucked from the coating into the model, followed by raising the temperature of the assembly to a temperature at which the thermoplastic polymeric material disappears, and raising the temperature further to a sintering temperature at which the dental metal powder is sintered into a solid metal mass. The substructure so formed can be provided with a fired on coating of dental ceramics.Type: GrantFiled: July 2, 1991Date of Patent: September 1, 1992Assignee: Elephant Edelmetaal B.V.Inventor: Joseph M. van der Zel
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Patent number: 5125962Abstract: A sintered material resistant to heat and mechanical strain, particularly to impact and friction, for the production of molded articles, made of a matrix metal powder having approximately 70 to 100% by weight of a copper component and approximately 0 to 30% by weight of an alloy component of cobalt, chromium, iron, manganese, nickel, tungsten and/or carbon. In another embodiment, the sintered material may also include an additional high-alloy metal powder admixed as a hard phase to the matrix metal powder. The additional high-alloy metal powder is present in the amount of a maximum 30% by weight, with respect to the sum of the matrix metal powder and high-alloy metal powder. The sintered material is especially suitable for heat- and wear-resistant molded articles for use in high gas environments, for example, in internal combustion engines. For example, guides, bearings, and valve elements may be made of this material and especially valve seat rings.Type: GrantFiled: November 13, 1989Date of Patent: June 30, 1992Assignee: Sintermetallwerk Krebsoge GmbHInventor: Bernd Krentscher
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Patent number: 5122326Abstract: The present invention is a method of removing binder material which is non-sublimable at room temperature and pressures greater than 1 Torr from a binder and particulate mixture. The binder and particulate mixture is formed into a shaped article and placed in a closed furnace. The closed furnace is then adjusted to a pressure and temperature sufficient to effect transformation of the binder material from a solid to a vapor and diffusion of the binder material as a vapor through, and from, the binder and particulate mixture without formation of a liquid phase of binder material on the binder and particulate mixture surface. The shaped article is held under these processing conditions until substantially all of the binder material transforms to its vapor state and diffuses through, and from, the mixture into the closed furnace. The binder material vapor is then evacuated from the furnace through conventional means.Type: GrantFiled: March 2, 1987Date of Patent: June 16, 1992Assignee: Vacuum Industries Inc.Inventors: Martha L. Jackson, Elliot Thompson
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Patent number: 5102452Abstract: The invention relates to a method for the treatment and production of material, particularly for the treatment and production of free flowing, finely divided metal powder or metal matrix composite powder. The material is composed of tungsten carbide and at least two components, nickel and cobalt. According to the method of the invention the composite powder is first mixed with the organic binder in order to form powder agglomerate, which powder agglomerate is further subjected to sintering treatment in order to remove the binder and to improve the mechanical strength of the composite powder. Further the composite powder is subjected to classification and the classified composite powder is thermally treated at a high temperature in an at least one-step thermal treatment in order to melt the composite powder at least partially, and in order to mix the various components to each other.Type: GrantFiled: May 14, 1990Date of Patent: April 7, 1992Assignee: Outokumpu OyInventors: Pekka A. Taskinen, Markku J. Kaskiala, Seppo T. Kemppinen, Jaana L. Niemela, Heikki J. Volotinen
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Patent number: 5098620Abstract: A method and apparatus for injection molding of ceramic suspension is disclosed wherein an elastomeric bladder is disposed within a mold cavity of a mold. The elastomeric bladder, in a relaxed state, can be tubular or can be formed by bonding together sheets of material. A ceramic suspension is injected into the elastomeric bladder, whereby the elastomeric bladder is distended. Distention of the elastomeric bladder applied a significant force to the ceramic suspension for preventing jetting and formation of knit lines within the ceramic suspension. The ceramic suspension distends the elastomeric bladder until the mold cavity is filled. The ceramic suspension is then exposed to conditions sufficient to cause the injected ceramic suspension to form a molded ceramic greenware composite. The molded ceramic greenware composite can then be removed from the mold for drying and for debindering and densification to form a finished ceramic part.Type: GrantFiled: June 7, 1990Date of Patent: March 24, 1992Assignee: The Dow Chemical CompanyInventors: Norbert L. Bradley, Virgil W. Coomer
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Patent number: 5098648Abstract: Disclosed herein is an economical process for the production of a sintered Fe-Co type, Fe-Co-V type or Fe-Co-Cr type magnetic material, which comprises preparing an alloy powder of at least Fe and Co metals of a like powder, kneading it with an organic binder, conducting injection molding and debinding, and then conducting a two-stage sintering treatment consisting of low-temperature sintering and high-temperature sintering. Magnetic materials having a specific composition of the Fe-Co, Fe-Co-V or Fe-Co-Cr type and excellent magnetic properties and a low core loss value are also disclosed.Type: GrantFiled: June 13, 1991Date of Patent: March 24, 1992Assignee: Kawasaki Steel CorportionInventors: Yoshisato Kiyota, Osamu Furukimi
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Patent number: 5096661Abstract: A porous intermediate compact is first prepared from metal particles, carbon and a temporary binder. The compact is then heated to remove the binder and then infiltrated with the vapor of a metal having a melting point lower than the compact.Type: GrantFiled: April 2, 1991Date of Patent: March 17, 1992Assignee: Raybestos Products CompanyInventor: Richard D. Lang
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Method of optimizing composite preparation for electrical properties: maximum capacitance electrodes
Patent number: 5096663Abstract: Composites of a matrix of metal fibers and carbon fibers interlocked in and interwoven among a network of fused metal fibers are inherently capable of displaying a broad range of values of a particular physical property. Where the composite is made by sintering a preform of the fiber network dispersed in a matrix of an organic binder, the value of the physical property of the resulting composite is a function of several independent variabiles which can be controlled during composite fabrication. With particular regard to the capacitance of a stainless steel-carbon fiber electrode, there is described a method of optimizing capacitance during electrode fabrication.Type: GrantFiled: May 29, 1990Date of Patent: March 17, 1992Assignee: Auburn UniversityInventor: Bruce J. Tatarchuk -
Patent number: 5096662Abstract: A method for forming high abrasion resistive layers on parent materials in which power of an alloy iron including carbide generating elements is prepared using the atomizing method, sheets are formed from a mixture of the powder and a binder, the sheet is adhered to a parent material, and the sheet and the surface of the parent material are remelted by TIG arc to for a high alloy layer on the parent material.Type: GrantFiled: April 17, 1990Date of Patent: March 17, 1992Assignee: Mazda Motor CorporationInventors: Yoshifumi Yamamoto, Shigemi Ohsaki, Katsuya Ohuchi, Norio Yohshina
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Patent number: 5091022Abstract: There is disclosed a method for manufacturing intricate shaped magnetic parts having excellent soft magnetic characteristics which includes forming powders of Fe and P having particle sizes less than 45 .mu.m; mixing 0.1 to 1.0% by weight P powder with Fe powder; adding a binder; injection-molding the mixture at 1200 kg/cm.sup.2 ; removing the binder by heating; sintering the binder free part at 1200.degree.-1400.degree. C. for 30-180 min; and cooling the sintered part at a rate of less than 50.degree. C./min.Type: GrantFiled: July 19, 1990Date of Patent: February 25, 1992Assignee: Sumitomo Metal Mining Company, LimitedInventors: Masakazu Achikita, Akihito Ohtsuka
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Patent number: 5080672Abstract: A fully alloyed porous metallic coating is applied to the surface of a metallic prosthetic component by producing a slurry comprising a suspension of the alloy in particulate form in a solution of water containing a film-forming binder material, applying to one or more surfaces of the component a coating of the slurry, forming concave and re-entrant depressions by pressing heat degradable spheres into the coating to promote fixation of the component when in use, heating the slurry to dry the same, and sintering the coated component to bond the particulate alloy onto the component, the spheres burning off during the subsequent heating or sintering step.Type: GrantFiled: October 27, 1989Date of Patent: January 14, 1992Inventor: John Bellis
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Patent number: 5067979Abstract: A process is provided for the production of a sintered body. The process includes the following consecutive steps: i) mixing and kneading one or more metal powders and/or one or more alloy powder with a binder into a compound, said metal and alloy powders having an average particle size not greater than 30 .mu.m, ii) injection-molding the compound into a green body; iii) debinding the green body to form a debound body; and iv) subjecting the debound body to a first-stage sintering at 1,050.degree.-1,250.degree. C. in a reduced-pressure atmosphere and then to second-stage sintering at a temperature in a range of 1,100.degree.-400.degree. C. which is higher than that of the first-stage sintering. This process can provide sintered Ti bodies and sintered magnetic bodies of the Fe-Si type, which have a density ratio of at least 95%.Type: GrantFiled: July 6, 1990Date of Patent: November 26, 1991Assignee: Kawasaki Steel CorporationInventors: Yoshisato Kiyota, Junichi Ohta, Hiroshi Ohtsubo, Shigeaki Takajo
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Patent number: 5064609Abstract: A method of sintering a sinterable metal powder honeycomb monolith structure comprises sintering the honeycomb monolith structure in a reducing atmosphere containing hydrogen. The honeycomb monolith structure is encased in a sintering jig and thereby disposed close to or in contact with the sintering jig.Type: GrantFiled: June 29, 1990Date of Patent: November 12, 1991Assignee: NGK Insulators, Ltd.Inventors: Takashi Harada, Tsuneaki Ohashi
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Patent number: 5059387Abstract: Shaped parts are formed from a powder having the desired chemistry of the finished part by mixing the powder with a thermosetting condensation resin that acts as a binder. The resin may be partially catalyzed, or additives or surfactants added to improve rheology, mixing properties, or processing time. Upon heating, the inherently low viscosity mixture will solidify without pressure being applied to it. A rigid form is produced which is capable of being ejected from a mold. Pre-sintered shapes or parts are made by injection molding, by using semi-permanent tooling, or by prototyping. Binder removal is accomplished by thermal means and without a separate debinding step, despite the known heat resistance of thermosetting resins. Removal is due to the film forming characteristic of the binder leaving open the part's pores, by providing oxidizing conditions within the part's pores as the part is heated, and by insuring that the evolving resin vapor diffuses through the pores by heating the part in a vacuum.Type: GrantFiled: June 2, 1989Date of Patent: October 22, 1991Assignee: Megamet IndustriesInventor: Gregory M. Brasel
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Patent number: 5059388Abstract: Using an organic binder containing at least one water-soluble thermoplastic organic polymer and at least one water-insoluble thermoplastic organic polymer, the water-soluble thermoplastic organic polymer is extracted by debinding treatment in which a plastic molded part such as injection molded part and water are brought into contact with each other to prevent the occurrence of cracks in the molded part. Removal by extraction of the water-soluble thermoplastic polymer reduces the amount of the organic binder contained in the molded part sufficiently, thus preventing the softening and deformation of the molded part at the time of optionally heating and removing the remainder of the organic binder and/or sintering of the molded part and also preventing the occurrence of swelling and cracks by the effect of guide passage formed by the extraction of the organic polymer.Type: GrantFiled: October 4, 1989Date of Patent: October 22, 1991Assignees: Sumitomo Cement Co., Ltd., Seiko Instruments Inc., Seiko Electronic Components Ltd.Inventors: Hiroshi Kihara, Eiki Arai, Shigeaki Ogata, Yoshio Katagiri, Katsuyuki Fujita, Tadahiko Wachigai, Hiroyoshi Hiratsuka
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Patent number: 5059489Abstract: A structure comprising a mixture of metals and metal alloys which are sintered into a hard porous body is presented. The structure can be useful for many different chemical and physical purposes, such as for catalysis, desorption and absorption, and selective leaching of the structure components into solutions.Type: GrantFiled: July 15, 1988Date of Patent: October 22, 1991Assignee: Corning IncorporatedInventors: Charles Q. Buckwalter, Jr., Irwin M. Lachman, Mallanagouda D. Patil, Jimmie L. Williams
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Patent number: 5055128Abstract: Disclosed herein is an economical process for the production of a sintered Fe-Co type, Fe-Co-V type or Fe-Co-Cr type magnetic material, which comprises preparing an alloy powder of at least Fe and Co metals or a like powder, kneading it with an organic binder, conducting injection molding and debinding, and then conducting a two-stage sintering treatment consisting of low-temperature sintering and high-temperature sintering. Magnetic materials having a specific composition of the Fe-Co, Fe-Co-V or Fe-Co-Cr type and excellent magnetic properties and a low core loss value are also disclosed.Type: GrantFiled: January 24, 1990Date of Patent: October 8, 1991Assignee: Kawasaki Steel CorporationInventors: Yoshisato Kiyota, Osamu Furukimi
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Patent number: 5047181Abstract: Dense, flaw free, complex, 3-dimensional, metal or refractory shapes are formed by preparing a low viscosity, pourable aqueous-based suspension. The aqueous suspension preferably contains ceramic or metal particulates, water, and a compatible mixture of additives for performing dispersant, cryoprotectant, and strength enhancing functions. The low viscosity slip is cast or injection molded at low pressure into a complex mold, frozen, demolded, and freeze dried without the formation of a continuous liquid phase. The green part is subsequently sintered by conventional techniques to achieve a dense part.Type: GrantFiled: February 25, 1991Date of Patent: September 10, 1991Assignee: Ceramics Process Systems CorporationInventors: Mark A. Occhionero, Bruce E. Novich, Cathryn A. Sundback
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Patent number: 5047182Abstract: A process for forming articles from inorganic sinterable particulates includes providing a well-dispersed, low pressure injectable slurry, freeze-forming the slurry into a desired geometry, and drying the piece so formed by a predominantly sublimative process, to produce a green article that can be conventionally sintered. The vehicle has a volume change on freezing of not more than .+-.10% by volume; to further control the volume change on freezing, an emulsion derived from different vehicles can be tailored. The slurries preferably have a solids content of at least about 35 v/o, a viscosity of preferably not more than about 1000 cP at 100 s.sup.-1, and are preferably injectable at not more than about 1000 psi, usually at less than 100 psi.Type: GrantFiled: March 7, 1991Date of Patent: September 10, 1991Assignee: Ceramics Process Systems CorporationInventors: Cathryn A. Sundback, Bruce E. Novich, Angelica E. Karas, Richard W. Adams
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Patent number: 5045276Abstract: An injection molded powder metallurgy product of highly satisfactory quality is obtained by a method which comprises injection molding mixture obtained by kneading a metal powder with a binder, depriving the molded mass of the binder while keeping the molded mass at least in contact with ceramic powder, projecting beads on the molded mass free from the binder, and thereafter sintering the molded mass studded with the beads.Type: GrantFiled: October 11, 1990Date of Patent: September 3, 1991Assignee: Sumitomo Metal Mining Company LimitedInventor: Yoshio Kijima
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Patent number: 5041158Abstract: Powdered metal parts, especitally valve parts of an internal combustion engine which are subject to adhesive wear in service, withstand such wear substantially better when they have substantially uniformly dispersed through them from about 0.75% to about 7.0% by weight of hydrate magnesium silicate (talc).Type: GrantFiled: July 12, 1990Date of Patent: August 20, 1991Assignee: Eaton CorporationInventor: Jay M. Larson
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Patent number: 5033939Abstract: Shaped parts are formed from a powder having the desired chemistry of the finished part by mixing the powder with a thermosetting condensation resin that acts as a binder. The resin may be partially catalyzed, or additives or surfactants added to improve rheology, mixing properties, or processing time. Upon heating, the inherently low viscosity mixture will solidify without pressure being applied to it. A rigid form is produced which is capable of being ejected from a mold. Pre-sintered shapes or parts are made by injection molding, by using semi-permanent tooling, or by prototyping. Binder removal is accomplished by thermal means and without a separate debinding step, despite the known heat resistance of thermosetting resins. Removal is due to the film forming characteristic of the binder leaving open the part's pores, by providing oxidizing conditions within the part's pores as the part is heated, and by insuring that the evolving resin vapor diffuses through the pores by heating the part in a vacuum.Type: GrantFiled: October 29, 1990Date of Patent: July 23, 1991Assignee: Megamet IndustriesInventor: Gregory M. Brasel
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Patent number: 5034186Abstract: A titanium or titanium alloy composite having a porous surface layer, which comprises a titanium or titanium alloy substrate and a porous titanium or titanium alloy layer that adheres strongly to said substrate, said porous layer being formed by first providing said substrate with a firmly adhering sinter of a mixture of a titanium or titanium alloy powder and a magnesium powder, and then removing magnesium from the sinter. A process for producing a titanium or titanium alloy composite having a porous surface layer, comprising: providing a coating composition comprising a binder added to a mixture of a titanium or titanium alloy powder and a magnesium powder; applying said composition to the surface of a titanium or titanium alloy substrate; heating the substrate at a temperature of from 650.degree. to 800.degree. C. in vacuo or an inert atmosphere so as to form a sinter of the powders of titanium or titanium alloy and magnesium which firmly adheres to said substrate; and removing magnesium from said sinter.Type: GrantFiled: November 20, 1986Date of Patent: July 23, 1991Assignee: Permelec Electrode Ltd.Inventors: Takayuki Shimamune, Hideo Sato, Masashi Hosonuma
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Patent number: 5032354Abstract: A composition for producing a metallic sintered body consisting essentially of a mixture of a powdered metal having an average particle size of not more than 50 microns with a lactone resin having a relative viscosity value in the range of from 1.15 to 3.20 is disclosed.The composition has excellent properties such as mechanical strength of a green body thereof, and only a short time being necessary for removal or elimination of binder in comparison with conventional sintering compositions.Furthermore, the binder in the present composition is substantially composed of a single component; accordingly, manufacturing process control can be simplified by use of the lactone resin.Furthermore, a method for producing a metallic sintered body using such composition is also disclosed.Type: GrantFiled: August 28, 1990Date of Patent: July 16, 1991Assignee: Daicel Chemical Industries Ltd.Inventors: Michio Nakanishi, Takuya Miho
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Patent number: 5030277Abstract: A method for fabricating a titanium aluminide composite structure consisting of a filamentary material selected from the group consisting of silicon carbide, silicon carbide-coated boron, boron carbide-coated boron, titanium boride-coated silicon carbide and silicon-coated silicon carbide, embedded in an alpha-2 titanium aluminide metal matrix, which comprises the steps of providing a first beta-stabilized Ti.sub.3 Al powder containing a desired quantity of beta stabilizer, providing a second beta-stabilized Ti.sub.3 Al powder containing a sacrificial quantity of beta stabilizer in excess of the desired quantity of beta stabilizer, coating the filamentary material with the second powder, fabricating a preform consisting of the thus-coated filamentary materials surrounded by the first powder, and applying heat and pressure to consolidate the preform.The composite structure fabricated using the method of this invention is characterized by its lack of a denuded zone and absence of fabrication cracking.Type: GrantFiled: December 17, 1990Date of Patent: July 9, 1991Assignee: The United States of America as represented by the Secretary of the Air ForceInventors: Daniel Eylon, William C. Revelos, Paul R. Smith, Jr.
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Patent number: 5026680Abstract: A Ca carbonate powder, a Sr carbonate powder, and a Cu oxide powder are mixed in predetermined proportions, and sintered at a first predetermined temperature into a Ca-Sr-Cu--O oxide sintered body. A Bi oxide powder and a Pb oxide powder are mixed in predetermined proportions, and are sintered at a second predetermined temperature into a Bi--Pb--O oxide sintered body. The obtained Ca--Sr--Cu--O oxide sintered body and Bi--Pb--O oxide sintered body are crushed, and the resulting Ca--Sr--Cu--O oxide powder and Bi--Pb--O oxide powder are mixed in predetermined proportions. The resulting mixed powder is sintered at a third predetermined temperature into a Bi--Pb--Sr--Ca--Cu--O superconductive oxide sintered body, which is crushed into a powder of a Bi-based superconductive oxide containing Pb. A sintered body of the Bi-based superconductive oxide containing Pb is formed from the Bi-based superconductive oxide powder.Type: GrantFiled: August 7, 1989Date of Patent: June 25, 1991Assignee: Mitsubishi Metal CorporationInventors: Tadashi Sugihara, Takuo Takeshita, Yukihiro Ohuchi
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Patent number: 5021208Abstract: A method for removing a paraffin wax based binder containing a fatty acid from a green article, wherein the article is made of material selected from the group consisting of ceramic powders and metallic powders, which comprises heating the article in a non-oxidizing atmosphere in a furnace by raising the temperature at a rate of about 0.5.degree. C. to 1.0.degree. C. per minute to a first temperature of about 50.degree. C. to 80.degree. C. and thereafter maintaining the first temperature for about 30 to 90 minutes to essentially completely melt the binder, raising the temperature from the first temperature at a rate of about 0.5.degree. C. to 1.0.degree. C. per minute to a second temperature of about 200.degree. C. to 225.degree. C. and thereafter maintaining the second temperature for about 30 to 90 minutes to essentially completely vaporize the paraffin wax, raising the temperature from the second temperature at a rate of about 0.5.degree. C. to 1.0.degree. C. per minute to a third temperature of about 260.Type: GrantFiled: May 14, 1990Date of Patent: June 4, 1991Assignee: GTE Products CorporationInventors: David C. Ludwig, Joseph J. Penkunas
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Patent number: 5021213Abstract: In the method of invention, the formability is imparted to the slurry of a metal or ceramic powder by employing a porous mold and removing the dispersion medium through the evaporation or thermal decomposition thereof, or by using a silazane oil as the dispersion medium and curing it by heating. Since the phase change usually accompanying volume change does not occur in the dispersion medium, strain and deformation rarely occur in the molded body. As result, the sintered body obtained has high dimensional accuracy.Type: GrantFiled: June 20, 1990Date of Patent: June 4, 1991Assignee: NKK CorporationInventors: Hiroaki Nishio, Akira Kato, Michitaka Sato, Keiji Watanabe
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Patent number: 5015289Abstract: A manufacturing method for a metal body by means of injection molding that comprises the steps of mixing and kneading a metal powder with short fibers such as metallic fibers, carbon fibers and an organic binder, injection-molding the kneaded mixture to form a green body, removing the organic binder from the green body, and sintering the brown body. The short fibers are added in an amount ranging from about 0.1 to 20 wt. % against 100 wt. % of the metal powder and have a melting point of at least 350.degree. C., and at the time of sintering the fibers not less than 30 vol. % become fused and then integrated with the metal. The short fibers act as a reinforcement, strengthening the brown body as well as preventing deformation and cracking of the green body during debinding.Type: GrantFiled: August 10, 1990Date of Patent: May 14, 1991Assignee: King Invest Co., Ltd.Inventors: Takuo Toda, Masao Tsuda
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Patent number: 5011654Abstract: A continuous process for producing strip products which comprises forming an aqueous slurry of a mixture of a metal powder and a film-forming cellulose derivative and producing from this slurry a self-supporting strip. This self-supporting strip is fed onto an endless moving belt by which the strip is transported into and through a sinter furnace. A tensile force is applied to the sintered strip in the direction of travel of the strip, and this tensile force is controlled such that the speed at which the strip leaves the furnace is greater than the speed at which the strip enters the furnace by an amount related to the expected or actual increase in strip length occasioned by expansion of the strip during the sintering process.Type: GrantFiled: July 25, 1990Date of Patent: April 30, 1991Inventor: Roy Mathers
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Patent number: 5009842Abstract: High strength steel parts or articles are made from a powder alloy by compacting the powder into a preform, sintering the preform in a sintering furnace or the like under a highly-reducing atmosphere and at a temperature of at least 1150.degree. C., cooling the preform, preheating the sintered preform in a highly-reducing atmosphere, such as an inert gas-based atmosphere containing hydrogen or pure hydrogen, to a temperature of at least 1000.degree. C. and transferring the preheated preform to an impact forging device and impacting the preform at a peak averaging forging pressure of at least about 1000 MPa to obtain a forged part or article. The time period between removal of the preheated preform from the preheater and the first forging impact is no more than about 8 seconds. The sintering and preheating steps can be combined with the sintered preform being cooled to the preheating temperature in the sintering furnace and transferred directly from the sintering furnace to the impact forging device.Type: GrantFiled: June 8, 1990Date of Patent: April 23, 1991Assignee: Board of Control of Michigan Technological UniversityInventors: Alfred A. Hendrickson, Darrell W. Smith