Liquid Phase Sintering Patents (Class 419/47)
  • Patent number: 5439636
    Abstract: A large ceramic substrate article for electronic applications including at least one layer of sintered ceramic material, the layer including a plurality of greensheet segments of ceramic material joined edge to edge. Also disclosed is a method of fabricating a large ceramic greensheet article as well as a large ceramic substrate article.
    Type: Grant
    Filed: February 18, 1992
    Date of Patent: August 8, 1995
    Assignee: International Business Machines Corporation
    Inventors: Raschid J. Bezama, Jon A. Casey, Mario E. Ecker, Shaji Farooq, Irene S. Frantz, Katharine G. Frase, David H. Gabriels, Lester W. Herron, John U. Knickerbocker, Sara H. Knickerbocker, Govindarajan Natarajan, John Thomson, Yee-Ming Ting, Sharon L. Tracy, Robert M. Troncillito, Vivek M. Sura, Donald R. Wall, Giai V. Yen
  • Patent number: 5435966
    Abstract: This invention relates generally to a novel method for removing metal from a formed self-supporting body. A self-supporting body is made by reactively infiltrating a molten parent metal into a bed or mass containing a boron donor material and a carbon donor material (e.g., boron carbide) and/or a boron donor material and a nitrogen donor material (e.g., boron nitride) and, optionally, one or more inert fillers. Once the self-supporting body is formed, it is then subjected to appropriate conditions which causes metallic constituent contained in the self-supporting body to be at least partially removed.
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: July 25, 1995
    Assignee: Lanxide Technology Company, LP
    Inventors: William B. Johnson, James C. Wang
  • Patent number: 5427735
    Abstract: Dense superalloy foils are prepared by hot isostatically pressing a mixture of low melting alloy powders and high melting alloy powders at a temperature at least equal to or greater than three-quarters of the melting point of the low melting point alloy powder and below the melting point of the high melting point alloy powder, at a pressure of at least 10 thousand pounds per square inch for about one to five hours.
    Type: Grant
    Filed: February 14, 1994
    Date of Patent: June 27, 1995
    Assignee: General Electric Company
    Inventors: Ann M. Ritter, Melvin R. Jackson
  • Patent number: 5413752
    Abstract: Fatigue crack growth-resistant articles are made from powder metal or cast and wrought gamma prime precipitation strengthened nickel-base superalloy material, wherein a relatively high predetermined minimum strain rate, .epsilon..sub.min, is employed during hot working at or near the alloy's recrystallization temperature; or alternatively a relatively high strain level, .epsilon..sub.min, is employed during cold or warm working at temperatures below the alloy's recrystallization temperature. The worked articles are characterized by a uniform fine grain size, and grains which coarsen uniformly after heating at the supersolvus solutioning temperature, thereby alleviating non-uniform grain growth within the material.
    Type: Grant
    Filed: October 7, 1992
    Date of Patent: May 9, 1995
    Assignee: General Electric Company
    Inventors: Robert D. Kissinger, Michael E. Sauby, Richard G. Menzies, Allen J. Paxson
  • Patent number: 5413751
    Abstract: High density heatsinks for microcircuit packages are formed by first mold-pressing a composite powder of free-flowing spray-dried particles of copper and at least one other denser material such as tungsten and/or molybdenum, the proportions of which are adjusted to match the thermal expansion characteristics of the microcircuit material. The pressed compacts are then heated in a sintering furnace at 1,200.degree. C. to 1,350.degree. C. in order to effect an homogeneous distribution of the melting copper throughout the structure. The process results in a readily usable component having good thermal conductivity and matched thermal expansion that requires no further machining.
    Type: Grant
    Filed: May 20, 1993
    Date of Patent: May 9, 1995
  • Patent number: 5405574
    Abstract: Structure and a method for producing very dense bodies of material from powderous materials. A powderous material is placed within an electrically conductive container. A solenoid encompasses the electrically conductive container, and a large magnitude of electrical current is caused to flow through the solenoid or coil. As the electrical current flows through the solenoid or coil, large magnitudes of pressures are created upon the electrically conductive container, and the electrically conductive container is compressed, and the transverse dimension thereof is reduced. Thus, the powderous material within the electrically conductive container is very firmly compacted. A body of superconductive material of any desired size and shape can be produced by this method by the use of superconducting powderous material.
    Type: Grant
    Filed: February 10, 1992
    Date of Patent: April 11, 1995
    Assignee: IAP Research, Inc.
    Inventors: Bhanumathi Chelluri, John P. Barber
  • Patent number: 5403371
    Abstract: An iron-based powder for making wear-resisting and heat-resisting components by compacting and sintering consists of, in addition to Fe, 3-15% by weight of Mo and/or 3-20% by weight of W, the total amount of Mo+W being in the range off 3-20% by weight; 0.2-1.0% by weight of P; 0.5-1.5% by weight of C. A component is powder-metallurgically made of this iron-based powder by compacting the powder into the desired shape and sintering the compact at a temperature below about 1150.degree. C.
    Type: Grant
    Filed: November 10, 1992
    Date of Patent: April 4, 1995
    Assignee: Hoganas AB
    Inventors: Per Engdahl, Dragan Spasic, Ralf Johansson
  • Patent number: 5393613
    Abstract: Direct fabrication of three-dimensional metal parts by irradiating a thin layer of a mixture of metal powder and temperature equalization and unification vehicle to melt the metal powder and form a solid metal film. The vehicle also protects the molten metal from oxidation. The metal powder can contain an elemental metal or several metals, the vehicle can be an organic resin or an amalgam, and the irradiation can be selectively applied by a YAG laser.
    Type: Grant
    Filed: December 3, 1993
    Date of Patent: February 28, 1995
    Assignee: Microelectronics and Computer Technology Corporation
    Inventor: Colin A. MacKay
  • Patent number: 5380482
    Abstract: A method of manufacturing ingots for use in making objects having heat, thermal shock, corrosion and wear resistance by formulating a composition of about 17-80% TiB.sub.2 powder, about 0.0 to 4.0% Y.sub.2 O.sub.3 powder, and the balance of NiAl powder, the powders being thoroughly admixed, and placing the admixture into a mold in which it is subjected to a pressure of about 7000 psi and a temperature of about 1400.degree. C. for 20 to 140 minutes in an inert atmosphere, after which the mold is cooled and the ingot is removed and ready for use in manufacturing an object. In some applications the use of a ceramic filler material mixed with the powder is employed to improve the physical characteristics of the finished ingot.
    Type: Grant
    Filed: April 2, 1993
    Date of Patent: January 10, 1995
    Assignee: Aspen Research, Inc.
    Inventors: David B. Maginnis, Frank Maginnis
  • Patent number: 5372775
    Abstract: To prepare an aluminum matrix particle composite alloy, a molten metal, mainly composed of aluminum, containing ceramic particles is disintegrated by atomization, to prepare atomized powder. The atomized powder is mechanically ground/reflocculated with a ball mill or the like, to prepare mechanically ground/reflocculated powder containing ceramic particles of not more than 8 .mu.m in maximum diameter and not more than 3 .mu.m in mean particle diameter. The mechanically ground/reflocculated powder is then warm-formed/solidified. Alternatively, an aluminum alloy molten metal containing dispersed particles is disintegrated by atomization, and thereafter the powder containing the dispersed particles of not more than 20 .mu.m in mean particle diameter is warm-formed/solidified by powder forging. Thus, it is possible to obtain an aluminum matrix particle composite alloy in which extra-fine ceramic particles are homogeneously distributed without segregation.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: December 13, 1994
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Tetsuya Hayashi, Yoshinobu Takeda
  • Patent number: 5372777
    Abstract: The present invention relates to the formation of bodies having graded properties. Particularly, the invention provides a method for forming a metal matrix composite body having graded properties. The graded properties are achieved by, for example, locating differing amounts of filler material in different portions of a formed body and/or locating different compositions of filler material in different portions of a formed body and/or locating different sizes of filler materials in different portions of a formed body. In addition, the invention provides for the formation of macrocomposite bodies wherein, for example, an excess of matrix metal can be integrally bonded or attached to a graded metal matrix composite portion of a macrocomposite body.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: December 13, 1994
    Assignee: Lanxide Technology Company, LP
    Inventor: Chwen-Chih Yang
  • Patent number: 5362438
    Abstract: This invention relates to a powder substantially of dental metal, which powder is suitable for the manufacture of a dental restoration such as a crown or a bridge, comprising a substructure of dental metal and a fired on coating of a dental ceramic material. The powder comprises a core substantially of a dental metal, which core is coated with one or more layers substantially of metal which protect the dental metal of the core during sintering against oxidation and/or reduce the temperature at which the powder is sintered.The invention also relates to a process for the manufacture of a dental restoration such as a crown or a bridge, comprising a substructure of a dental metal and a fired on coating of a dental ceramic material.
    Type: Grant
    Filed: June 10, 1993
    Date of Patent: November 8, 1994
    Assignee: Elephant Edelmetaal B.V.
    Inventor: Joseph M. van der Zel
  • Patent number: 5352405
    Abstract: A method and apparatus for fabricating three-dimensional objects according to the selective laser sintering process are disclosed. In order to reduce inconsistencies in structural and textural integrity, and in thermal effects that can cause distortion, methods for ensuring that overlapping laser scans are accomplished in a consistent manner relative to the thermal flow from the sintered locations are utilized. Methods are disclosed for achieving this by limiting the extent to which the laser scans object areas in the powder layers so that the time-to-return for adjacent overlapping scans is minimized; such minimization results in significantly less variation in the time-to-return overall.
    Type: Grant
    Filed: December 18, 1992
    Date of Patent: October 4, 1994
    Assignee: DTM Corporation
    Inventors: Joseph J. Beaman, Joseph C. McGrath, Frost R. R. Prioleau
  • Patent number: 5352538
    Abstract: A surface hardened aluminum part having excellent heat resistance and abrasion resistance obtained by forming, on the surface of an aluminum base material, an alloy layer that has a uniform composition and uniform hardness, being free from cracks. An aluminum alloy powder made of aluminum and metals each of which forms an intermetallic compound of high hardness with aluminum is prepared. This aluminum alloy powder is supplied onto the aluminum base material and the aluminum or aluminum alloy contained in the aluminum base material is alloyed with the aluminum alloy powder using a high-density energy heat source to form an alloy layer. The alloy layer thus formed has an intermetallic compound of high hardness uniformly distributed throughout the layer so that the hardness of the alloy layer is uniform and cracking is unlikely to occur.
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: October 4, 1994
    Assignee: Komatsu Ltd.
    Inventors: Toshihide Takeda, Kaoru Adachi
  • Patent number: 5342573
    Abstract: A method of producing a tungsten heavy alloy product according to a powder metallurgical procedure utilizing the injection molding technique which enables production of tungsten heavy alloy products having high dimensional accuracy and complex configuration and yet having high physical strength and toughness in high productivity and at low cost. A powder mixture of tungsten powder and nickel powder, iron powder or copper powder is mixed with an organic binder and they are kneaded together. The kneaded mixture is injection molded into a predetermined shape, and thereafter the binder is removed from the molded product. Subsequently, the molded product is sintered in a temperature range of from the melting point of the bond phase of nickel, iron or copper to +50.degree. C. relative to the melting point.
    Type: Grant
    Filed: August 20, 1992
    Date of Patent: August 30, 1994
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Yoshinari Amano, Masahiro Omati, Junzo Matsumura
  • Patent number: 5338507
    Abstract: A method for making metal/ceramic superconductor thick film structures including the steps of preparing a silver/superconductor ink, applying the ink to a substrate, evaporating the ink's binder, decomposing a silver compound in the residue to coat the superconductor grains, sintering the coated superconductor grains, and oxygenating the superconductor grains through the silver coating. The resultant inter-granular silver increases the critical current and mechanical strength of the superconductor.
    Type: Grant
    Filed: August 29, 1991
    Date of Patent: August 16, 1994
    Assignee: Hewlett-Packard Company
    Inventors: John T. Anderson, V. K. Nagesh, Richard C. Ruby
  • Patent number: 5330702
    Abstract: Purely powder-metallurgical processes or sinter-impregnation processes are often used to manufacture CuCr contact materials. Here the aim is to obtain the lowest possible residual porosity, which should be <1%. According to the invention, a powder moulding of the components is densified in two stages; the first stage is a sintering process with a densification of the sintered body to a closed porosity, and the second stage is a hot-isostatic pressing operation (HIP), in which the unencased workpieces are taken to a final density amounting to a space occupation of at least 99%. Thus, an economical method of manufacturing high grade material is obtained. It is possible to produce multi-layer contacts or self-adhesive bonds between the sintered body and a solid substrate, e.g. a copper contact bolt.
    Type: Grant
    Filed: December 2, 1991
    Date of Patent: July 19, 1994
    Assignee: Siemens Aktiengesellschaft
    Inventors: Horst Kippenberg, Franz Hauner
  • Patent number: 5330701
    Abstract: A method is disclosed for controlling a self-propagating reaction in a particulate medium. The method comprises controlling the boundary heat flux of the reaction to produce reaction waves which travel through the particulate medium undergoing a self-propagating reaction. The method provides a product having a unitary, solid structure with layers of alternating density. Preferably the reaction is a reaction between two metals to produce an intermetallic compound or between a metal and a non-metal to produce a ceramic compound. Nickel aluminide is a preferred intermetallic compound. Also disclosed is a controlled reactive sintering process for producing a finely divided intermetallic compound comprising comminuting the layered body of intermetallic compound.
    Type: Grant
    Filed: February 28, 1992
    Date of Patent: July 19, 1994
    Assignee: Xform, Inc.
    Inventors: Karl G. Shaw, David E. Alman, Rene M. Cooper, Randall M. German, Kazuo P. McCoy
  • Patent number: 5318746
    Abstract: Oxide-free metallic, alloy or intermetallic compound formed by coating a powder of at least one member selected from the group consisting of elemental metallic, alloy and intermetallic compound with an oxide-replacing metal. The oxide-free compound may be compacted without the addition of a liquid sintering agent and at temperatures below the melting point of the compound, under sufficient pressure to form a uniform, consolidated intermetallic body.
    Type: Grant
    Filed: December 4, 1991
    Date of Patent: June 7, 1994
    Assignee: The United States of America as represented by the Secretary of Commerce
    Inventors: David S. Lashmore, John A. Tesk, Moshe P. Dariel, Edward Escalante
  • Patent number: 5314714
    Abstract: Process for increasing the density and improving the homogeneity of Chevrel phase powders and Chevrel phase wire obtained using said process. Chevrel phase powers are compounds of lead, mobydenum, and sulfur. Metallic additives in the range of 0.5% to 20% by weight are introduced in the Chevrel phase powders by a physical or chemical process. The melting temperature of the metallic additives is lower than the synthesis temperature of the Chevrel phase powders so as to increase the homogeneity. The wires obtained using this process are capable of generating high magnetic fields.
    Type: Grant
    Filed: September 3, 1990
    Date of Patent: May 24, 1994
    Assignee: Promogap
    Inventors: Bernd Seeber, Oystein Fischer, Michel Decroux
  • Patent number: 5312584
    Abstract: Disclosed is a method of making moldless/coreless single crystal castings of NiAl(.beta.') alloys. Drops of molten NiAl(.beta.') alloy is deposited on a starter seed block of single crystal alloy and casting structures are epitaxially grown to predetermined configurations and shapes by repeatedly dropping and solidifying molten NiAl(.beta.') materials.
    Type: Grant
    Filed: February 18, 1992
    Date of Patent: May 17, 1994
    Assignee: General Motors Corporation
    Inventors: Donald J. Frasier, Ralph E. Peeler, John H. Lane, Heidi Mueller-Largent
  • Patent number: 5310519
    Abstract: To make a sintered member having a molybdenum-containing wear-resisting layer it is known to compact a low-alloy iron powder for forming the body of said member and a non-alloyed iron-base metal powder, which contains molybdenum and is intended to form the wear-resisting layer, so as to form a shaped member, which is subsequently sintered. In order to reduce the manufacturing costs, it is proposed that in such process the metal powder for forming the wear-resisting layer contains a low-alloy iron powder and 10 to 30% by weight molybdenum and contains a total of 1.5 to 3.0% by weight carbon and phosphorus, carbon and phosphorus are optionally contained as alloying constituents in the iron powder of said metal powder in a total amount of 0.3 to 0.7% by weight, and the shaped member consisting of the body and the wear-resisting layer is subjected to liquid-phase sintering at temperatures from 1070.degree. to 1130.degree. C.
    Type: Grant
    Filed: June 22, 1992
    Date of Patent: May 10, 1994
    Assignee: Miba Sintermetall Aktiengesellschaft
    Inventor: Franz Blaimschein
  • Patent number: 5306569
    Abstract: A titanium-tungsten target material capable of limiting the amount of particles generated during sputtering and a method of manufacturing this titanium-tungsten material. The titanium-tungsten target material has a titanium-tungsten alloy phase which occupies 98% or more of the whole area of the material as observed in a micro-structure thereof. In one example of the manufacturing method, an ingot obtained by melting tungsten and titanium is processde by a solution treatment to form a titanium-tungsten target, or a power obtained by melting the ingot is sintered to form a target. Preferably, the melting may be performed under reduced pressure in an electron beam melting manner. In another example of the manufacturing method, a powder is formed from a molten metal by an atomization method and the obtained powder is sintered to form a titanium-tungsten target. For sintering of the powder, it is preferable to apply hot isostatic pressing or hot pressing.
    Type: Grant
    Filed: July 16, 1992
    Date of Patent: April 26, 1994
    Assignee: Hitachi Metals, Ltd.
    Inventor: Akitoshi Hiraki
  • Patent number: 5304343
    Abstract: An aluminum-alloy main-starting powder for producing a sintered aluminum-alloy consists of from 0.1 to 3.0% of Cu, the balance being Al and unavoidable impurities. Mother alloy powder consists of from 4 to 20% of Mg, from 12 to 30% of Si, and Al and unavoidable impurities in balance.
    Type: Grant
    Filed: October 19, 1992
    Date of Patent: April 19, 1994
    Assignee: Showa Denko K.K.
    Inventors: Shin Miura, Youichi Hirose, Yoshio Machida, Mitsuaki Sato
  • Patent number: 5304342
    Abstract: A sintered product useful for abrasion- and impact-resistant tools and the like is provided comprising an iron-group metal binder and refractory metal carbide particles, e.g. tungsten carbide, formed in situ during sintering by the exothermic reaction of a carbide-forming refractory metal powder with a carbon source mixed therewith. The sintering is carried out at an elevated temperature and at a pressure at which diamond is stable in the presence of a liquid phase comprised substantially of an iron-group binder metal, refractory metal, and dissolved carbon. The product may optionally contain diamond, up to about 95% in volume, enabling its properties to be tailored for a wide range of applications.
    Type: Grant
    Filed: June 11, 1992
    Date of Patent: April 19, 1994
    Inventors: H. Tracy Hall, Jr., David R. Hall
  • Patent number: 5273204
    Abstract: A method of joining metal materials by spraying molten metal into a cavity between the articles to be joined. Prior to deposition of the metal, the surface of the cavity is cleaned and the articles to be joined are preheated. Subsequent to deposition of the metal within the cavity, the joined articles are cooled at a rate that precludes damage due to thermal effects and the deposited metal is consolidated in the cavity by hot pressing.
    Type: Grant
    Filed: March 25, 1988
    Date of Patent: December 28, 1993
    Assignee: Howmet Corporation
    Inventors: Ranes P. Dalal, John M. McFadden, Mark J. Straszheim, Louis E. Dardi
  • Patent number: 5273710
    Abstract: A process of manufacturing a member formed with a shaft-receiving opening in that a compact formed with a through hole and comprising a sinterable powder is subjected to liquid-phase sintering is improved in that a bushing, which is made of a material produced by fusion metallurgy and is dimensionally stable under the conditions under which the compact is to be sintered, is inserted into the through opening of the compact with a play which is smaller than the extent of the unrestrained radial shrinkage of the compact at its through opening during its liquid-phase sintering, and the compact is subjected to liquid-phase sintering after the bushing has thus been inserted.
    Type: Grant
    Filed: February 7, 1992
    Date of Patent: December 28, 1993
    Assignee: Miba Sintermetall Aktiengesellschaft
    Inventor: Osman Z. Zengin
  • Patent number: 5248475
    Abstract: Methods are provided for fabricating a sintered and solid element from an otherwise unsinterable material, utilizing the property of that material that it will form an eutectic composition or alloy with a suitable alloying agent at a temperature which is below the plastic deformation temperature of the material. Discrete particles of the material to be sintered--such as grains or wire pieces--are coated with a thin coating of the alloying agent and are packed into the position where they are to be sintered. Then, the coated grains or wire pieces are heated so that at least the coating and the regions of the grains just below the coating are slowly raised in temperature. Diffusion regions of the alloying agent into the grains of the sinterable material will then occur. Further heating continues so that at least the diffusion regions increase in temperature to just slightly above the eutectic melting point.
    Type: Grant
    Filed: October 24, 1991
    Date of Patent: September 28, 1993
    Assignee: Derafe, Ltd.
    Inventor: Robert S. Feldstein
  • Patent number: 5240672
    Abstract: The present invention relates to the formation of bodies having graded properties. Particularly, the invention provides a method for forming a metal matrix composite body having graded properties. The graded properties are achieved by, for example, locating differing amounts of filler material in different portions of a formed body and/or locating different compositions of filler material in different portions of a formed body and/or locating different sizes of filler materials in different portions of a formed body. In addition, the invention provides for the formation of macrocomposite bodies wherein, for example, an excess of matrix metal can be integrally bonded or attached to a graded metal matrix composite portion of a macrocomposite body.
    Type: Grant
    Filed: April 29, 1991
    Date of Patent: August 31, 1993
    Assignee: Lanxide Technology Company, LP
    Inventor: Chwen-Chih Yang
  • Patent number: 5223054
    Abstract: Hydrogen storage alloy includes porous base hydrogen storage alloy and Mg which is fused, conjugated with the base hydrogen storage alloy and diffused in the base hydrogen storage alloy.
    Type: Grant
    Filed: March 18, 1992
    Date of Patent: June 29, 1993
    Assignee: Mazda Motor Corporation
    Inventors: Kazuyuki Yoshimoto, Toru Ogasawara, Eiji Hiraki, Shinichi Tanioka
  • Patent number: 5200392
    Abstract: An improved ceramic-plus-metal superconducting composition of YBa.sub.2 Cu.sub.3 O.sub.6+x plus substantially pure aluminum for ultimate use in making superconducting devices such as wires and tapes for utilization in motors, generators, electric circuits, etc.
    Type: Grant
    Filed: October 18, 1990
    Date of Patent: April 6, 1993
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: A. Srinivasa Rao, Om P. Arora
  • Patent number: 5183632
    Abstract: A method of manufacturing an aluminum-base composite disc rotor comprising the steps of preparing a rough-shaped disc rotor made of a mixture of aluminum powder or aluminum alloy powder with reinforcing particles or aluminum alloy, placing a mixture of aluminum powder or aluminum alloy powder with reinforcing particles or a preform made thereof on each of fixed positions of the rough-shaped disc rotor, and heating the mixture or the preform to at least a region of mashy state temperature to mold under pressure. Thereby the heat resistance and the wear resistance of the aluminum-base composite disc rotor for light-duty cars and industrial machinery are improved.
    Type: Grant
    Filed: March 3, 1992
    Date of Patent: February 2, 1993
    Assignees: Akebono Brake Industry Co., Ltd., Akebono Research and Development Centre Ltd.
    Inventors: Manabu Kiuchi, Masao Arai
  • Patent number: 5167697
    Abstract: A substrate material for mounting a semiconductor device thereon, comprises a skeleton prepared by liquid-phase presintering the composition of W and/or Mo powder in which Cu and/or Ag powder is uniformly dispersed, and a Cu and/or Ag phase infiltrated into the pores of the skeleton. The total amount of Cu and/or Ag in the product is adjusted to 10-50 vol. %. The substrate material is manufactured by two steps of: presintering the Cu and/or Ag-contng. powdery composition to form a porous skeleton, and infiltrating Cu and/or Ag into the pores of the skeleton. Since the skeleton contng. Cu and/or Ag exhibits an excellent affinity to molten Cu and/or Ag, the infiltration of molten Cu and/or Ag is performed uniformly into every nook and corner of the skeleton. Consequently, the obtained product is free from pores which would deteriorate a junction plane between the substrate and a semiconductor device mounted thereon.
    Type: Grant
    Filed: April 17, 1991
    Date of Patent: December 1, 1992
    Assignee: Nippon Tungsten Co., Ltd.
    Inventors: Takeshie Koumura, Yoshihiro Umeda, Jitsuo Matsumoto
  • Patent number: 5151247
    Abstract: The present invention is a method for densifying powder metallurgical parts to 100% theoretical density. The method comprises applying a high pressure of 0.1-100 MPa during sintering in a high pressure furnace at a temperature before which the liquid phase is formed and maintaining this pressure during the rest of the sintering cycle until the furnace has cooled to almost room temperature. The method achieves rapid, complete closure of the porosity which results in parts with close dimensional tolerances and practically no warpage.
    Type: Grant
    Filed: November 1, 1991
    Date of Patent: September 29, 1992
    Assignee: Sandvik AB
    Inventors: Bengt O. Haglund, Bengt N. During
  • Patent number: 5145512
    Abstract: A consolidated tungsten alloy body consisting essentially of from about 88% to about 98% by weight of tungsten, balance, nickel and iron, produced by liquid phase sintering, containing a continuous phase of a tungsten, nickel and iron alloy and a discontinuous phase of elongated grains of tungsten having an aspect ratio of at least 4:1 relatively uniformly distributed throughout the continuous phase and wherein said body has a recrystallization temperature of from about 1000.degree. C. to about 1200.degree. C. A process for producing the consolidated bodies comprises working and annealing at controlled temperatures to achieve the desired properties. The working temperatures are from about 700.degree. C. to about 900.degree. C. and the annealing temperature is preferably 1200.degree. C.
    Type: Grant
    Filed: January 3, 1989
    Date of Patent: September 8, 1992
    Assignee: GTE Products Corporation
    Inventors: James R. Spencer, James A. Mullendore
  • Patent number: 5145505
    Abstract: Disclosed are a high toughness cermet comprising a sintered alloy comprising 75 to 95% by weight of a hard phase of carbide, nitride or carbonitride containing Ti, at least one of W, Mo and Cr, and N and C, and the balance of a binder phase composed mainly of an iron group metal, and inevitable impurities,wherein the content of Ti in said sintered alloy is 35 to 85% by weight calculated on TiN or TiN and TiC, and the contents of W, Mo and Cr are 10 to 40% by weight in total calculated on WC, Mo.sub.2 C and/or Cr.sub.3 C.sub.2,the relative concentration of said binder phase at the 0.01 mm-inner portion from the surface of said sintered alloy is 5 to 50% of the average binder phase concentration of the inner portion, and the relative concentration of said binder phase at the 0.1 mm-inner portion from the surface of said sintered alloy is 70 to 100% of the average binder phase concentration of the inner portion, anda compression stress of 30 kgf/mm.sup.
    Type: Grant
    Filed: February 7, 1992
    Date of Patent: September 8, 1992
    Assignee: Toshiba Tungaloy Co., Ltd.
    Inventors: Takeshi Saito, Kozo Kitamura, Mitsuo Ueki
  • Patent number: 5124120
    Abstract: A method for making zinc electrodes for alkaline-zinc batteries comprising the steps of: mixing an amount of a zinc-magnesium binder alloy with an amount of a material chosen from zinc and a second zinc-magnesium alloy to form a mechanical mixture. The melting temperature of the material is at least 15 Celsius degrees higher than the melting temperature of the binder alloy. The mixture is applied to a current collector and the current collector with applied mixture is heated to a temperature at which incipient melting of the binder alloy causes sintering of the mixture with the formation of a coherent layer solidly bonded to the current collector. The compositions and the amount of the binder alloy and the second alloy are selected such that the active material in the layer of the electrode contains no more than about 15% magnesium, preferably no more than about 10% magnesium.
    Type: Grant
    Filed: July 16, 1990
    Date of Patent: June 23, 1992
    Assignee: Cominco Ltd.
    Inventors: Jack Sklarchuck, Hans Rensing
  • Patent number: 5114469
    Abstract: A process for producing high-strength, substantially nonporous alloys by means of a three-component mixture, including admixing a first component of one or more low-melting temperature metals or alloys thereof, a second component of one or more high-melting temperature metals or alloys thereof, and a substantially inert third component of one or more refractory compounds, subjecting the mixture to changes in temperature so as to form a mixture capable of being shaped at a temperature well below the melting or decomposition temperature of the highest melting metal and the inert refractory compound.
    Type: Grant
    Filed: December 10, 1987
    Date of Patent: May 19, 1992
    Assignee: General Dynamics Corporation Air Defense Systems Division
    Inventor: Sam M. Weiman
  • Patent number: 5100736
    Abstract: A polymer-reinforced metal matrix composite is disclosed which is formed by lending metal particles and polymer particles to form a homogeneous powder blend, and consolidating the powder blend to form a unitary mass. The unitary mass is then plastically deformed such as by extrusion in the presence of heat so as to cause an elongation thereof, whereby the metal particles form a matrix and the polymer particles form elongated filaments uniformly dispersed throughout the matrix and aligned in the direction of elongation of the unitary mass. An aluminum matrix reinforced with polyether-etherketone is shown to have enhanced specific strength and modulus over those of the aluminum alone.
    Type: Grant
    Filed: February 19, 1991
    Date of Patent: March 31, 1992
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Gilbert J. London, William E. Frazier, John G. Williams
  • Patent number: 5098469
    Abstract: A powder metallurgy process for producing near-net shape, near-theoretical density structures of multiphase nickel, aluminum and/or titanium intermetallic alloys is provided by employing pressureless sintering techniques. The process consists of blending a brittle aluminide master alloy powder with ductile nickel powder, so as to achieve the desired composition. Then, after cold compaction of the powdered mixture, the compact is liquid phase sintered. The four step liquid phase sintering process is intended to ensure maximum degassing, eliminate surface nickel oxide, homogenize the alloy, and complete densification of the alloy by liquid phase sintering.
    Type: Grant
    Filed: September 12, 1991
    Date of Patent: March 24, 1992
    Assignee: General Motors Corporation
    Inventor: Vadim Rezhets
  • Patent number: 5070591
    Abstract: Metal and ceramic particles of various morphologies are clad with a coating from the transition metal group consisting of silver, gold, copper, nickel, iron, cobalt, aluminum etc., or combinations thereof, to provide improved coated particles for microelectronics or metal matrix composites or other uses. Refractory metal precursor core particles, such as tungsten, molybdenum, niobium and zirconium, as examples, are provided from a composite of tungsten and copper, for example, made by pressurizing and infiltrating or liquid phase sintering of molten copper into a porous tungsten skeleton. Precursor chip particles derived from a tungsten impregnated billet are used as starter particles which may be further enhanced by cogrinding in an attritor ball mill with smaller copper particles to thereby produce an enhanced copper clad-coating of tungsten particles with predetermined percent by weight of copper and tungsten content.
    Type: Grant
    Filed: January 22, 1990
    Date of Patent: December 10, 1991
    Inventors: Nathaniel R. Quick, James C. Kenney
  • Patent number: 5069867
    Abstract: To permit an economical manufacture of high-strength sintered members for use in valve timing mechanisms of internal combustion engine by powder metallurgy with liquid-phase sintering, an iron-base powder mixture is provided, which contains 13 to 18% by weight chromium or 3 to 6% by weight molybdenum as a carbide-forming alloying element in the iron alloy powder and also contains 1.5 to 2.6% carbon and 0.4 to 1.0% by weight phosphorus. A corresponding molten iron alloy is atomized into an entraining gas or water jet and is subsequently mixed with the remaining components of the powder.
    Type: Grant
    Filed: February 19, 1991
    Date of Patent: December 3, 1991
    Assignee: Miba Sintermetall Aktiengesellschaft
    Inventor: Osman Z. Zengin
  • Patent number: 5061439
    Abstract: The invention relates to a method for the manufacture of dimensionally precise pieces which are at least in part made of a sintered material. The material comprises a mixture of at least three pulverous constituents, of which the first is mainly of a metal of the iron group and coarse by its particle size, the second constituent contains copper and/or phosphorus, and the third constituent contains mainly copper. For the material, a powder mixture is made which contains the largest amount of the third constituent and substantially less of both the first and the second constituents. The powder mixture is fed into a cavity preferably a mold-cavity and is sintered without compression of the powder mixture, without pressure, in this cavity and at a temperature which is above the melting point of the said second constituent.
    Type: Grant
    Filed: November 29, 1990
    Date of Patent: October 29, 1991
    Assignee: Aktiebolaget Electrolux
    Inventors: Olli J. Nyrhila, Seppo O. Syrjala
  • Patent number: 5049355
    Abstract: Process for producing a ductile, high strength, oxide dispersion hardened sintered alloy based on a metal having a high melting point. In the past, oxide dispersion has played only a minor role in comparison with other known processes for increasing strength. The process disclosed permits cost effective production of metallic materials which possess a strength hitherto unattainable by oxide dispersion and a higher ductility than prior art materials. As a result, the metallic and nonmetallic foreign components in the sintered alloy can be restricted to the relatively small quantities of dispersoids and any dissolved residual oxygen. The process consists in an annealing treatment and calls for a specific choice of basis metal and suitable oxide dispersoid.
    Type: Grant
    Filed: January 8, 1990
    Date of Patent: September 17, 1991
    Assignee: Schwarzkopf Development Corporation
    Inventors: Udo Gennari, Wolfgang Glatzle
  • Patent number: 5024813
    Abstract: A Mg-Ti type alloy comprises 0.04 to 99.96% by weight of Ti and 99.96 to 0.04% by weight of Mg. The Mg-Ti type alloy is produced by compounding and mixing at least one of a powder of Ti and a powder of titanium hybride with a powder of Mg, so that the Ti composition in a sintered product may be in a range of 0.04 to 99.96% by weight; forming the resulting mixture into a predetermined shape, and sintering the formed material at a temperature in a range of from a solid phase point of Mg to a liquid phase point.
    Type: Grant
    Filed: June 19, 1989
    Date of Patent: June 18, 1991
    Inventor: Katsuhiro Nishiyama
  • Patent number: 5008071
    Abstract: A consolidated tungsten alloy body consisting essentially of from about 70% to about 98% by weight of tungsten, balance nickel and iron in essentially an 8:2 weight ratio. A process for producing the consolidated bodies where the tungsten content is greater than about 88% by weight comprises forming a relative uniform blend of the described metal powders, compacting the powders to form a green body then liquid phase sintering the green body to full density. For alloys containing less than about 90% tungsten solid state sintering can be used.
    Type: Grant
    Filed: November 25, 1988
    Date of Patent: April 16, 1991
    Assignee: GTE Products Corporation
    Inventors: James R. Spencer, James A. Mullendore
  • Patent number: 4988386
    Abstract: A copper-tungsten mixture net-shaped product produced using powder metallurgical techniques with injection molding and liquid phase sintering. The product has a very low leak rate in helium gas, a high thermal conductivity and a rate of thermal expansion which is substantially the same as some glass and ceramic materials.
    Type: Grant
    Filed: June 29, 1988
    Date of Patent: January 29, 1991
    Assignee: Fine Particles Technology Corporation
    Inventors: James B. Oenning, Ian S. R. Clark
  • Patent number: 4986961
    Abstract: A consolidated tungsten heavy alloy body consisting essentially of from about 88% to about 98% by weight of tungsten, from about 0.25% to about 1.5% by weight of a grain size reducing additive selected from the group consisting of ruthenium, rhenium and mixtures thereof, balance iron and nickel in a weight ratio of nickel to iron of from about 1:1 to about 9:1 wherein the consolidated body has greater than about 2500 grains per square millimeter as determined from the microstructure of the body. A process for producing the consolidated body comprises forming a relative uniform blend of the described metal powders, compacting the powders to form a green body then solid state sintering to remove binders followed by liquid phase sintering the green body to full density.
    Type: Grant
    Filed: October 2, 1989
    Date of Patent: January 22, 1991
    Assignee: GTE Products Corporation
    Inventors: James R. Spencer, James A. Mullendore
  • Patent number: 4979984
    Abstract: A process is claimed for the manufacture of an insert. The process includes the steps of filling a die cavity defined by a die mold with powdered metal, the die cavity conforming to the required shape of the insert. The powdered metal is compressed within the die cavity such that a compact of the insert is formed within the die cavity. The compact is sintered within a sintering furnace so that a first porton of the compact is in the solid phase and a second portion of the compact is in the liquid phase. The compact is rapidly cooled within the sintering furnace to a temperature below the melting point of the powdered metal. Such temperature is maintained so that densification of the first portion to substantially full density is achieved. The arrangement is such that the profile integrity of the compact is retained. the resltant insert is then subsequently cooled.
    Type: Grant
    Filed: March 16, 1990
    Date of Patent: December 25, 1990
    Assignee: Inserts Ltd.
    Inventor: Linwood R. Anderson
  • Patent number: 4937042
    Abstract: A mixture of two powdered alloys of the M, Cr, Al type, M being Co and/or Ni, is disclosed, in one form, for use in providing an abradable surface of an article and is characterized by the substantial absence of B. The first alloy has substantially no Si and has a higher melting range than that of the second alloy. The second alloy has substantially no Y and consists essentially of, by weight, 8-12% Si, 1.5-4% Al, 10-30%Cr, with the balance M and incidental impurities. The total mixture composition consists essentially of, by weight, 10-35% Cr, 4-10% Al, from a small but effective amount up to about 0.09% Y, 2-6% Si, with the balance M and incidental impurities.
    Type: Grant
    Filed: March 23, 1989
    Date of Patent: June 26, 1990
    Assignee: General Electric Company
    Inventors: Roger J. Perkins, Murray S. Smith, Jr.