Heat And Pressure Simultaneously To Effect Sintering Patents (Class 419/48)
  • Patent number: 6024776
    Abstract: Cermets having a Co--Ni--Fe-binder are described. The Co--Ni--Fe-binder is unique in that even when subjected to plastic deformation, the binder substantially maintains its face centered cubic crystal structure and avoids stress and/or strain induced phase transformations. Stated differently, the Co--Ni--Fe-binder exhibits reduced work hardening.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: February 15, 2000
    Assignee: Kennametal Inc.
    Inventors: Hans-Wilm Heinrich, Manfred Wolf, Dieter Schmidt, Uwe Schleinkofer
  • Patent number: 6024915
    Abstract: A process for producing a metal-base sinter, comprising sintering coated metal particles wherein the particles are prepared for sintering by the steps of: dispersing a powder of metal core particles in a gaseous atmosphere to form a mixture of a gas and particles in a powder of highly dispersed core particles; charging a precursor for the coat forming substance that has been formed via the vapor phase and/or a precursor for the coat forming substance in a vapor-phase state and the mixture of the gas and the powder of highly dispersed core particles that have a predetermined dispersity according to the average diameter of the core particles in a coating start region of a coating space; coating the surfaces of the core particles with the coat forming substance by allowing the precursor to contact and/or impinge against the core particles; shaping and sintering the thus coated metal core particles or a mixture containing them under appropriate sintering conditions.
    Type: Grant
    Filed: October 14, 1997
    Date of Patent: February 15, 2000
    Assignees: Agency of Industrial Science & Technology, Nisshin Flour Milling Co., Ltd.
    Inventors: Shoichi Kume, Haruo Yoshida, Yukiyoshi Yamada, Tadashi Fuyuki, Satoshi Akiyama, Yoshiaki Hamada, Eisuke Kuroda
  • Patent number: 6022508
    Abstract: In a method of powder metallurgical manufacturing of a composite material containing particles in a metal matrix, said composite material having a high wear resistance in combination with a high toughness, the powder particles (I) of a first powder of a first metal or alloy having a high content of hard particles (HT) dispersed in the matrix of said first powder particles, are dispersed in a second powder consisting of particles (II) of a second metal or alloy having a low content of hard particles dispersed in the matrix of said second powder particles, wherein a mutual contact between the hard particles and/or between the particles of said first powder is substantially avoided, and the mixture of said first and second powders is transformed to a solid body through hot compaction.
    Type: Grant
    Filed: August 6, 1997
    Date of Patent: February 8, 2000
    Assignees: Koppern GmbH & Co., KG, Germany, Erasteel Kloster Aktiebolag, Sweden
    Inventor: Hans Berns
  • Patent number: 6019936
    Abstract: A method for manufacturing a dense and functionally gradient composite material is provided. The method includes steps of preparing a reactant compact made of composite materials, igniting the reactant compact so that a combustion wave is propagating on the reactant compact, and compressing the reactant compact while the temperature profile of the reactant compact is gradient to obtain the dense and functionally gradient composite material.
    Type: Grant
    Filed: April 30, 1999
    Date of Patent: February 1, 2000
    Assignee: National Science Council
    Inventors: Shyan-Lung Chung, Jiang-Ming Soon
  • Patent number: 5993734
    Abstract: The invention relates to the manufacture of sputtering targets of tungsten-titanium alloy using high purity tungsten and titanium hydride powders. The powders are blended and placed in a containment vessel holding a die. The die is heated to a temperature of about 700.degree. C. to about 1000.degree. C. in an argon atmosphere while under pressure. The combination of temperature and pressure is high enough to dehydrate the titanium hydride and to remove the gases. The die is then heated to a higher temperature, in the range of about 1250.degree. C. to 1350.degree. C. while the pressure is increased so as to compact and alloy the powders. The pressure and temperature are held constant until there is no further movement of the ram. The resulting compacted alloy material is then machined to provide a sputtering target with a density between 96% and 100% of theoretical and a gas content less than 850 p.p.m.
    Type: Grant
    Filed: March 25, 1998
    Date of Patent: November 30, 1999
    Assignees: Sony Corporation, Materials Research Corporation
    Inventors: Alfred Snowman, Thomas J. Hunt
  • Patent number: 5993732
    Abstract: An R--T--M alloy material, wherein R is at least one rare earth metal including Y, T is Fe or an Fe component partially replaced by Co or Ni, M is B or a B component partially replaced by C as primary components is prepared by heating the alloy at a temperature from room temperature to a specific temperature of less than 500.degree. C. in a non-oxidizing atmosphere and holding it at the given temperature, if necessary; performing hydrogenation by holding the alloy in a hydrogen atmosphere or a mixed gas atmosphere of hydrogen and an inert gas at a specific temperature in the range of 500-1,000.degree. C.; medial annealing the alloy by holding the R--T--M alloy after the hydrogenation step in an inert gas atmosphere at a specific temperature in the range of 500-1,000.degree. C.; and dehydrogenating the alloy by holding the alloy in a vacuum of less than 1 Torr for dehydrogenation, and then cooling the alloy.
    Type: Grant
    Filed: July 13, 1998
    Date of Patent: November 30, 1999
    Assignee: Mitsubishi Materials Corporation
    Inventors: Ryoji Nakayama, Yoshinari Ishii, Norihito Fukatsu, Koichiro Morimoto
  • Patent number: 5993733
    Abstract: A synchronizing ring 10 having an annular structural part 11 and a frictional layer 12 is manufactured by filling a mold 20 with a material for the structural part or a material for the frictional layer and compacting the material filled in the mold 20, filling the mold with a material for the frictional layer or a material for the structural part and compacting the material filled into the mold to unify the structural part and the frictional layer, and sintering the unified structural part 11 and frictional layer 12 in a sintering furnace. The frictional layer 12 can be combined with the structural part 11 without forcibly mounting the frictional layer 12 on the structural part 11. The material for the frictional layer need not be presintered, and the frictional layer can be formed by a single sintering cycle.
    Type: Grant
    Filed: January 23, 1997
    Date of Patent: November 30, 1999
    Assignee: Dynax Corporation
    Inventor: Satoshi Kawai
  • Patent number: 5981863
    Abstract: Molten thermoelectric alloy expressed as (Bi, Sb).sub.2 (Te, Se).sub.3 is rapidly cooled at 10.sup.4 to 10.sup.6 .degree. K/second so as to crystallize the thermoelectric alloy, and powder of the thermoelectric alloy is hot pressed under the pressure equal to or greater than 400 kgf/cm.sup.2 at 200 degrees to 400 degrees in centigrade for a time period between {(-T/5)+90} minutes and 150 minutes or at 400 degrees to 500 degrees in centigrade for a time period between 5 minutes and 150 minutes so as to increase the figure of merit by virtue of the strain left in the crystal and/or micro crystal grain.
    Type: Grant
    Filed: February 29, 1996
    Date of Patent: November 9, 1999
    Assignee: Yamaha Corporation
    Inventors: Hiroyuki Yamashita, Yuma Horio, Toshiharu Hoshi
  • Patent number: 5930580
    Abstract: A porous material of desired porosity and pore size is made by mixing a piculate material and fungible beads that are thermally decomposable until the desired distribution is attained; compacting the mixed material and beads to form a green body that has sufficient strength to be handled where the beads are undecomposed; and compacting and heating the green body to fuse the material particles and to decompose the beads to gas.
    Type: Grant
    Filed: April 30, 1998
    Date of Patent: July 27, 1999
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventor: Richard K. Everett
  • Patent number: 5901336
    Abstract: A process for bonding a first metal such as beryllium to a second metal such as a copper alloy using a powder metallurgy compositional gradient. According to one aspect of the present invention, a sequence of powder layers is located between beryllium and copper alloy pieces, the layers containing mixtures of a beryllium powder and a copper powder, e.g., of a copper alloy, high purity copper and/or the like. The composition of the layers is adjusted such that the layer adjacent the beryllium piece is beryllium rich, and so that the layers become progressively richer in copper as they get closer to the copper piece. The variation in composition between the pieces produces the compositional gradient. Bonding of the beryllium and copper alloy pieces is then accomplished by a hot consolidation technique such as hot isostatic pressing, vacuum hot pressing, solid state bonding or diffusion bonding at a temperature generally within a range of 500.degree. and 800.degree. C.
    Type: Grant
    Filed: August 30, 1996
    Date of Patent: May 4, 1999
    Assignee: Brush Wellman Inc.
    Inventor: David E. Dombrowski
  • Patent number: 5889219
    Abstract: A sintered body having diamond grains dispersed and held in a matrix of cemented carbide or cermet is obtained by direct resistance heating and pressurized sintering. The sintering is performed at a liquid phase generating temperature in a short time, so that the diamond grains are not directly bonded to each other. Thus, a superhard composite member that has excellent hardness and wear resistance can be obtained without employing an ultra high-pressure vessel.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: March 30, 1999
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Hideki Moriguchi, Yoshifumi Arisawa, Michio Otsuka
  • Patent number: 5887241
    Abstract: A method for shaping a consolidated, substantially oxygen-free, equiaxed MoSi.sub.2 /SiC composite body having an average grain size of 10 .mu.m or less, a SiC content of 2 to 60 v/o and relatively low strength and relatively high ductility comprising subjecting the composite body to plastic deformation under conditions of forming temperature and rate of deformation such that grain growth is substantially avoided, the MoSi.sub.2 /SiC composite body being obtained by providing particles of molybdenum, silicon and carbon in a proportion relative to each other required to produce a composite powder of MoSi.sub.2 and SiC having a composition in that segment of the ternary diagram of FIG. 1 designated A, and subjecting the particles to mechanical alloying under conditions and for a time sufficient to produce the composite powder, followed by consolidation of the composite powder.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: March 23, 1999
    Assignee: University of Florida
    Inventors: S. Jayashankar, Kyung-Tae Hong, Michael J. Kaufman
  • Patent number: 5812925
    Abstract: A method for joining a first metal surface to a second metal surface that includes providing powder metal particles substantially all of which have hardnesses lower than the hardnesses of the first and second metal surfaces, at normal temperatures; locating the particles in a layer between the first and second metallic surfaces, to form an assembly; heating the assembly to an elevated temperature or temperatures below the softening temperature of the first and second metallic surfaces; and effecting compression of the layer by and between the first and second surfaces at a pressure level or levels below the compressive yield strengths of the first and second surfaces, and above the compressive yield strengths of the particles, and for a time duration to effect a bond between the first and second metallic surfaces.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: September 22, 1998
    Inventor: Gunes M. Ecer
  • Patent number: 5808282
    Abstract: A microwave susceptor bed useful for sintering ceramics, ceramic composites and metal powders is disclosed. The susceptor bed contains granules of a major amount of a microwave susceptor material, and a minor amount of a refractory parting agent, either dispersed in the susceptor material, or as a coating on the susceptor material. Alumina is the preferred susceptor material. Carbon is the most preferred parting agent. A sintering process using the bed and novel silicon nitride products produced thereby are described.
    Type: Grant
    Filed: April 28, 1997
    Date of Patent: September 15, 1998
    Assignee: Microwear Corporation
    Inventors: Prasad Shrikrishna Apte, Larry Roy Morris
  • Patent number: 5799238
    Abstract: A method making a titanium ceramic composite involves forming a hot pressed powder body having a microstructure comprising at least one titanium metal or alloy layer and at least one ceramic particulate reinforced titanium metal or alloy layer and hot forging the hot pressed body follwed by hot rolling to substantially reduce a thickness dimension and substantially increase a lateral dimension thereof to form a composite plate or sheet that retains in the microstructure at least one titanium based layer and at least one ceramic reinforced titanium based layer in the thickness direction of the composite plate or sheet.
    Type: Grant
    Filed: June 14, 1995
    Date of Patent: August 25, 1998
    Assignee: The United States of America as represented by the United States Department of Energy
    Inventors: George T. Fisher, II, Jeffrey S. Hansen, Laurance L. Oden, Paul C. Turner, Thomas L. Ochs
  • Patent number: 5794113
    Abstract: A method for preparing a highly dense product from a powdered mixture of reactants, whereby simultaneous application of a high current and pressure enables synthesis and densification of a variety of high temperature materials. The combination of field-activated combustion synthesis and the application of mechanical pressure was employed to produce dense MoSi.sub.2.
    Type: Grant
    Filed: May 1, 1995
    Date of Patent: August 11, 1998
    Assignee: The Regents of the University of California
    Inventors: Zuhair Abdul Razzak Munir, In-Jin Shon, Kazuo Yamazaki
  • Patent number: 5773735
    Abstract: A cemented tungsten carbide body having a transition metal binder phase selected from the group consisting of iron, nickel and cobalt is formed, wherein the WC grains have an average WC grain size of at most about 0.5 micrometer in diameter and a maximum WC grain size of at most about 0.8 micrometer in diameter. Also, about 50 percent by volume of the WC grains in the body are angular grains and the body (1) contains an amount of the transition metal ranging from about 3 percent to about 18 percent by weight of the body, (2) is essentially free of grain growth inhibitors and (3) is essentially pore free.
    Type: Grant
    Filed: November 20, 1996
    Date of Patent: June 30, 1998
    Assignee: The Dow Chemical Company
    Inventors: Ellen M. Dubensky, Robert T. Nilsson
  • Patent number: 5752156
    Abstract: High-temperature-stable, fiber-reinforced beryllium metal matrix composite materials are fabricated using coating, infiltration and hot-pressing procedures. High-temperature-stable fibers of metal oxides, carbon or silicon carbide are coated with reaction barrier coatings which prevent chemical reactions from occurring at the interface with the surrounding metallic beryllium matrix at temperatures up to close to the melting point of beryllium. Coatings such as yttria, YAG and mixtures of yttria and YAG or of yttria and beryllia are employed exterior of metal oxide fibers, such as alumina or alumina-silica fibers. Suitable reaction barrier coatings are also employed over carbon fibers (or silicon carbide fibers) which preferably include an interior coating of elemental silicon upon the exterior surface of the carbon fibers. Oxide coatings are preferably applied by immersion in a liquid bath containing a suitable coating solution, preferably an alcohol solvent alkoxide sol-gel.
    Type: Grant
    Filed: March 4, 1996
    Date of Patent: May 12, 1998
    Assignee: General Atomics
    Inventors: Kuo-Chun Chen, Paul W. Trester, Khodabakhsh S. Mazdiyasni
  • Patent number: 5722037
    Abstract: There is provided a process for producing titanium composite, comprising the steps of: molding titanium powder, titanium alloy powder, or powder comprising titanium into a certain shape by a cold isostatic press or cold press; reacting the shape with hydrocarbon gas at its decomposition temperature or higher, to form TiC therein; and providing the shape with high density by vacuum sintering, hot isostatic pressing, hot forging, hot rolling and/or the combinations thereof. TiC a reinforcing material, is in-situ formed by reacting a cold-pressed body of the powder with hydrocarbon gas and cleaner than the externally added one and distributed more uniformly and finely in the Ti matrix, leading to a significant improvement in wear resistance and high temperature property.
    Type: Grant
    Filed: May 9, 1996
    Date of Patent: February 24, 1998
    Assignee: Korea Institute of Machinery & Materials
    Inventors: Hyung-Sik Chung, Yong-Jin Kim, Byung-Kee Kim, Jian-Qing Jiang
  • Patent number: 5710384
    Abstract: The invention provides a magneto-optical recording medium target and a manufacture method thereof which target can produce the leakage magnetic flux in sufficient density and has the high mechanical strength. The target is a sintered body containing 15 to 30 atomic % at least one rare earth metal and the balance at least one transition metal, in which alloy powder having such a composition is sintered so that the original morphology of the alloy powder essentially remains. Specifically, the target has a micro structure in which the alloy powder particles consisted of the rare earth metal and the transition metal are interconnected through grain boundary phases. The target is able to have the deflective strength not less than 50 MPa, the relative density not less than 99%, and the content of oxygen not more than 1000 ppm. Particulate micro structures preferably have a grain size d.ltoreq.250 .mu.m and a volume mean size d.sub.av of 50.ltoreq.d.sub.ad .ltoreq.120 .mu.m.
    Type: Grant
    Filed: March 8, 1996
    Date of Patent: January 20, 1998
    Assignee: Hitachi Metals, Ltd.
    Inventor: Kaoru Masuda
  • Patent number: 5705758
    Abstract: The object of the present invention is to provide a non-magnetic or feebly magnetic diamond sintered compact available for a magnetic article or magnetic material. This object can be achieved by a non-magnetic or feebly magnetic diamond sintered compact whose magnetic susceptibility is at most 3% of Fe, consisting of a high hardness sintered compact comprising at least 50 volume % of diamond with a grain size of 0.1 to 100 .mu.m and a binder phase containing a metallic component selected from the group consisting of ferromagnetic iron group metals such as Ni, Co, Fe, etc. and mixtures thereof, in which at least one of feebly magnetic metal components each having a magnetic susceptibility of at most 5.times.10.sup.-8 (emu/g), for example, Cr, V, Cu, Si, Zn, Al Mo, W, etc.
    Type: Grant
    Filed: January 29, 1996
    Date of Patent: January 6, 1998
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Takayoshi Wakabayashi, Akihiko Yamamura
  • Patent number: 5701575
    Abstract: An article essentially consisting of one or more of Ti--Al intermetallic compounds is fabricated so as to have a volume ratio of voids no more than 3.5%, by preparing a mixture of materials selected from a group consisting of Ti, Ti alloys, Al, Al alloys, and Ti--Al compounds, having a composition suitable for forming a desired Ti--Al intermetallic compound, and heating said mixture so that said mixture may be sintered. Typically, the temperature and pressure for the heating or sintering process is appropriately selected so that the desired porosity may be obtained. The mechanical strength of an article according to the present invention is not only improved but is highly predictable, or, in other word, highly reliable. The fabrication costs can be reduced because the fabrication process involves only relatively low temperatures when pressing and heating the work at the same time.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: December 23, 1997
    Assignee: NHK Spring Co., Ltd.
    Inventors: Kohei Taguchi, Michihiko Ayada, Hideo Shingu
  • Patent number: 5697045
    Abstract: An aluminum alloy brazing agent containing a flux is made by compacting a powder mixture of a matrix powder and a flux powder at a first temperature so as to form a rigid piece, and then conducting a secondary forming of the rigid piece into a desired shape at a second temperature. The first temperature is lower than 480.degree. C., preferably lower than 400.degree. C., and more preferably room temperature, so that the compacting may be conducted in the air. The second temperature is 300.degree.-575.degree. C. for the secondary forming, which also may preferably be conducted in an non-oxidizing atmosphere, so that the brazing agent can be of an improved capability of brazing aluminum articles and be produced inexpensively.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: December 9, 1997
    Assignee: Showa Aluminum Corporation
    Inventors: Yasuhiro Osame, Shoichi Sato
  • Patent number: 5678166
    Abstract: The present invention pertains to an apparatus to hot triaxially compact powder. The apparatus includes a device for hydrostatically stressing the powder. The apparatus also includes a device for applying a shear stress to the powder simultaneously with the hydrostatic stress. Additionally, there is a device for heating the powder while the powder is hydrostatically in shear stress. The presence of the shear stress during the compaction of the powder has three primary effects. It can increase the final density and the densification rate of the compacted powder. It can cause microstructural changes in the compacted powder, and it can disrupt heterogeneities.
    Type: Grant
    Filed: July 31, 1995
    Date of Patent: October 14, 1997
    Assignee: Henry R. Piehler
    Inventors: Henry R. Piehler, Daniel M. Watkins
  • Patent number: 5641921
    Abstract: This invention is directed toward a material which is used to coat or create a surface for machine cutting tools, all types of drill bit teeth, saw teeth, bearing surfaces valve seats, nozzles and the like, thereby producing surfaces which are highly abrasion and erosion resistant. Furthermore, this invention includes some of the possible methods for producing such a material given that the methods and apparatus required provide a significant cost reduction over those required for producing prior art surface materials with similar abrasion and erosion resistant properties. More specifically, the material set forth can be formed at relatively low temperatures and relatively low pressures by sintering mixtures for a relatively short period of time.
    Type: Grant
    Filed: August 22, 1995
    Date of Patent: June 24, 1997
    Assignee: Dennis Tool Company
    Inventors: Mahlon Denton Dennis, Barton Hampshire
  • Patent number: 5640666
    Abstract: A method of producing a composite powder by providing particles of (I) tungsten, niobium, zirconium, titanium or mixtures thereof, (II) silicon and (III) carbon in a proportion relative to each other so as to possess an overall chemical composition in that segment of the ternary diagram of FIGS. 2(a), 2(b), 2(c) and 2(d) designated A, and subjecting the particles to a mechanical alloying process under conditions and for a time sufficient to produce the composite powder. Also disclosed is a method of forming a substantially oxygen-free composition of matter comprising a matrix substance of WSi.sub.2, NbSi.sub.2, ZrSi.sub.2, TiSi.sub.2 or alloys thereof having SiC dispersed therein, the method comprising consolidating the above-described composite powder. Also disclosed is a method of forming oxidation- and wear-resistant coatings by subjecting the composite powder whose composition lies in segment A to a metallurgical process such as plasma spraying.
    Type: Grant
    Filed: October 2, 1995
    Date of Patent: June 17, 1997
    Assignee: University of Florida
    Inventors: S. Jayashankar, Michael J. Kaufman
  • Patent number: 5624475
    Abstract: A composite material comprising a pure copper or dispersion strengthened copper matrix and a boron rich species, such as, but not limited to, elemental boron or boron carbide, for use in the fabrication of baskets that support spent nuclear fuel in nuclear waste containers. A method for manufacturing the composite material using powder metallurgy and hot extrusion.
    Type: Grant
    Filed: December 2, 1994
    Date of Patent: April 29, 1997
    Assignee: SCM Metal Products, Inc.
    Inventors: Anil V. Nadkarni, Jack D. Troxell
  • Patent number: 5607780
    Abstract: Disclosed are a target material for magneto-optical recording medium having a structure formed by sintering of an RE-TM phase (A) having a composition with an RE content higher than that of the composition of an intermetallic compound represented by the chemical formula TM.sub.2 RE, and a TM-RE phase (B) having a composition with an RE content equal to or lower than that of the composition of an intermetallic compound represented by the chemical formula TM.sub.2 E, wherein RE denotes at least one rare earth element selected from the group of elements consisting of Nd, Gd, Tb, Dy, Ho and Er, and TM denotes at least one element selected from the group of metals of the iron group which consists of Fe, Co and Ni; and a process for producing the same.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: March 4, 1997
    Assignee: Hitachi Metals, Ltd.
    Inventors: Kaoru Masuda, Takashi Meguro
  • Patent number: 5589652
    Abstract: In the metallic member of the invention, ceramic super fine particles, and solid lubricant particles or short size fibers are dispersed, and the grain size of the ceramic particles is smaller than the solid lubricant particle size or fiber diameter.
    Type: Grant
    Filed: February 23, 1994
    Date of Patent: December 31, 1996
    Assignee: Hitachi, Ltd.
    Inventors: Toshiaki Arato, Yasuhisa Aono, Shigeo Tsuruoka, Katsuhiro Komuro
  • Patent number: 5590393
    Abstract: The invention relates to a neutron-absorbing material and to its production process.This material comprises a homogeneous, boron carbide matrix 1 in which are dispersed e.g. pseudospherical, 150 to 500 .mu.m , calibrated clusters 3 of boride such as HfB.sub.2, in order to prevent the propagation of cracks F in the material and improve its thermal shock resistance.
    Type: Grant
    Filed: February 7, 1995
    Date of Patent: December 31, 1996
    Assignee: Commissariat a l'Energie Atomique
    Inventors: Guy M. Decroix, Dominique Gosset, Bernard Kryger
  • Patent number: 5567382
    Abstract: A dispersion strengthened copper alloy and a method for producing the alloy are provided. The alloy preferably comprises aluminum, titanium and hafnium as alloying elements that are internally oxidized under controlled conditions to produce a dispersion strengthened copper material having good hardness and high conductivity. A method for reducing the adverse effects of hydrogen on such materials is also provided. The dispersion strengthened material can be useful in many applications, including welding electrodes and electrical contacts.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: October 22, 1996
    Assignee: OTD Products L.L.C.
    Inventor: Evgeny P. Danelia
  • Patent number: 5556719
    Abstract: This invention disclosures a method to make an improved hydrogen/hydride electrode for electro-chemical applications. The method comprises the steps of: (1) preparing the slurry of hydrogen storage material; (2) pasting the slurry onto and/or into a substrate current collector to make a wet pasted electrode; (3) drying the wet pasted electrode; and (4) sintering the pasted electrode. The aforementioned method is very useful for the hydrogen storage alloy comprising of Ti, 2-70 at. %; Zr, 2-70 at. % and Ni, 5-80 at. %. It is also useful for a pseudo AB.sub.5 - or AB.sub.2 -type alloy. In particular, a high capacity hydrogen storage electrode comprising a multicomponent hydrogen storage alloy having composition represented by the formula: Ti.sub.a Zr.sub.b Ni.sub.c Nb.sub.y R.sub.z M.sub.
    Type: Grant
    Filed: June 27, 1994
    Date of Patent: September 17, 1996
    Inventors: Kuochih Hong, Kuoshiu Hong, Huiyim Hong
  • Patent number: 5547632
    Abstract: In a powder forging process, a heated green compact is placed in a stationary die and subjected to a press-forging carried out mainly to reduce the thickness thereof by cooperation of the stationary die with a movable die. The press-forging is performed at two pressing steps. After placement of the green compact into the concave molding portion of the stationary die, the pressing step were carried out. Thus, it is possible to produce a forged product having a high strength and a high toughness. A heated heat insulator also may be placed in the stationary die to provide a temperature-retaining effect to the green compact before and during pressing.
    Type: Grant
    Filed: December 20, 1994
    Date of Patent: August 20, 1996
    Assignees: Sumitomo Electric Industries, Ltd., Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Hiroyuki Horimura, Kenji Okamoto, Masahiko Minemi, Toshihiko Kaji, Yoshinobu Takeda, Yoshishige Takano
  • Patent number: 5529746
    Abstract: The invention relates to a process for pressing electrically conductive powders to high-density compacts in dimensionally stable pressing molds, whereby the achievable compression density is greater than 96% and, in many cases, amounts to almost 100% of the theoretical density of suitable materials. For said purpose, static pressing of the powders according to conventional methods is superimposed by a second process step, in which from 1 to 3 electric current pulses of from 5.times.10.sup.-5 to 5.times.10.sup.-2 s duration and high electric power are applied to the punches of the press. As opposed to known methods, no notable sintering of powder of particles occurs in such process. The process is especially suitable for the manufacture of high-density and high-strength, sintered mass-produced components, where compacts are produced on automatic presses with high cycle frequencies.
    Type: Grant
    Filed: March 8, 1995
    Date of Patent: June 25, 1996
    Inventors: Walter Knoss, Manfred Schlemmer
  • Patent number: 5523048
    Abstract: A process for producing high density refractory metal warhead liners from near net shape blanks. A shaped mold is filled with pure or solid solution molybdenum or tungsten powders. The powders may be isostatically pressed and sintered to form a near net shape blank. A hot isostatic press may be used in combination with these steps or by itself to form the near net shape blank. The hot isostatic press densifies the near net shape blank to at least 90% of theoretical density. Where wrought properties are desired, a final forging step is performed. Alternatively, a process such as vacuum plasma spraying may be used to form the near net shape blank. A hot isostatic press densifies the near net shape blank. A final machining step achieves a finished refractory metal warhead liner.
    Type: Grant
    Filed: July 29, 1994
    Date of Patent: June 4, 1996
    Assignee: Alliant Techsystems Inc.
    Inventors: Jonathan S. Stinson, Stanley R. Nelson, Craig L. Wittman
  • Patent number: 5523049
    Abstract: A heat sink composed of thermally conductive particles dispersed in a monolithic structure having a continuous microstructure; and the method of forming a heat sink by molding the heat sink from a thermoplastic or epoxy material which has been filled with thermally conductive particles, debinding the molded heat sink and densifying the debound heat sink into a monolithic structure.
    Type: Grant
    Filed: November 1, 1994
    Date of Patent: June 4, 1996
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Robert L. Terpstra, Barbara K. Lograsso, Iver E. Anderson, Jeffrey A. Moore
  • Patent number: 5522976
    Abstract: The target element (2) is formed from an inorganic compound layer (16) with a melting point above 300.degree. C. deposited on a foam or metallic felt support layer such that the layer of inorganic compound sinks to part of its depth into the support layer to define a composite layer (17). In order to form the target element, a precursor system of the inorganic compound is applied to the support layer, the assembly so formed is subjected to a pressure of between 0.1 MPa and 15 MPa, the resulting assembly is maintained at between 300.degree. C. and 1600.degree. C. and below the melting temperature of the support in order to obtain a sintered assembly. Said assembly is than cooled to an ambient temperature avoiding any sudden cooling. In order to produce the target, the element (2) is glued to a metallic substrate (4) using a conductive adhesive.
    Type: Grant
    Filed: June 14, 1994
    Date of Patent: June 4, 1996
    Assignee: Societe Nationale Elf Aquitaine
    Inventors: Guy Campet, Jean-Michel Chabagno, Claude Delmas, Joseph Portier, Jean Salardenne
  • Patent number: 5518383
    Abstract: To manufacture a reflector formed by a reflective metallic layer on a metallic matrix composite support, a metallic layer having a reflective surface whose shape is at least approximately identical to the required geometrical shape is disposed on a mold surface having a geometrical shape complementary to the required geometrical shape of the reflector. Fibers to constitute the composite support are draped on the metallic layer. They are metallized by the metallic or intermetallic material to form the metallic matrix. This layer and the metallized fibers are subjected to temperature and pressure conditions adapted to press the reflective surface strongly against the mold surface and to cause diffusion welding of the layer with the metallized fibers and of the metallized fibers with themselves so as to integrate the layer to the composite support during consolidation of the latter.
    Type: Grant
    Filed: May 9, 1994
    Date of Patent: May 21, 1996
    Assignee: Aerospatiale Societe Nationale Industrielle
    Inventor: Henri Abiven
  • Patent number: 5512235
    Abstract: Supported polycrystalline compacts having improved shear strength, impact, and fracture toughness properties, and methods for making the same under high temperature/high pressure (HT/HP) processing conditions. The method involves a HT/HP apparatus formed of a generally cylindrical reaction cell assembly having an inner chamber of predefined axial and radial extents and containing pressure transmitting medium, and a charge assembly having axial and radial surfaces and formed of at least one sub-assembly comprising a mass of crystalline particles adjacent a metal carbide support layer. The charge assembly is disposed within the chamber of the reaction cell assembly, with the pressure transmitting medium being interposed between the axial and radial surfaces of the charge assembly and the extents of the reaction cell chamber to define an axial pressure transmitting medium thickness, L.sub.h, and a radial pressure transmitting medium thickness, L.sub.r, the ratio of which, L.sub.h /L.sub.
    Type: Grant
    Filed: May 6, 1994
    Date of Patent: April 30, 1996
    Assignee: General Electric Company
    Inventors: David B. Cerutti, Henry S. Marek
  • Patent number: 5508116
    Abstract: A metal matrix composite reinforced with shape memory alloy is disclosed ch is formed by blending metal particles and shape memory alloy particles to form a homogeneous powder blend, and consolidating the powder blend to form a unitary mass. The unitary mass is then plastically deformed such as by extrusion in the presence of heat so as to cause an elongation thereof, whereby the metal particles form a matrix and the shape memory alloy partices align in the direction of elongation of the unitary mass. The composite can be used in structural applications and will exhibit shape memory characteristics.
    Type: Grant
    Filed: April 28, 1995
    Date of Patent: April 16, 1996
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventor: David J. Barrett
  • Patent number: 5503794
    Abstract: Metal alloy foils are made directly from metal alloy powders by hot pressing. These metal alloy foils are characterized by having a thickness of 0.017 in. or less, and by the fact that they are fine-grained and substantially free of oxygen, nitrogen and deformation-induced defects. In particular, Ti-base alloy foils having an average thickness of about 0.011 in. have been formed directly from Ti-base alloy powders. These as-pressed Ti-base alloy foils are also ductile and adapted for subsequent forming operations, including cold rolling. The deformation which may be imparted in a single pass through cold-rolling to these Ti-base alloy foils is at least about 5%, with up to about 45% deformation imparted to one of these alloys in multiple passes without stress relief annealing. Total reductions in thickness of up to 90% are achieved by a combination of cold-rolling and stress relief annealing.
    Type: Grant
    Filed: June 27, 1994
    Date of Patent: April 2, 1996
    Assignee: General Electric Company
    Inventors: Ann M. Ritter, John R. Hughes
  • Patent number: 5500182
    Abstract: This invention relates generally to a novel method for forming a self-supporting body. Specifically, the formed self-supporting body has a higher volume percent of metallic constituent relative to a body formed by similar techniques. A first porous self-supporting body is formed by reactively infiltrating a molten parent metal into a bed or mass containing a boron donor material and a carbon donor material (e.g., boron carbide) and/or a boron donor material and a nitrogen material (e.g., boron nitride) and, optionally, one or more inert fillers. Additionally, powdered parent metal may be admixed with a mass to be reactively infiltrated to form additional porosity therein. The porous self-supporting body which is formed by the reactive infiltration process according to this invention should contain at least some interconnected porosity which is capable of being filled in a subsequent step with additional metal, thus increasing the volume percent of parent metal in the body at the expense of porosity.
    Type: Grant
    Filed: January 11, 1993
    Date of Patent: March 19, 1996
    Assignee: Lanxide Technology Company, LP
    Inventor: Philip J. Roach
  • Patent number: 5498393
    Abstract: An aluminum alloy powder or a green compact thereof is prepared, wherein: (1) the composition formula is Al.sub.100-a-b Fe.sub.a X.sub.b where a and b in atomic % are 4.0.ltoreq.a.ltoreq.6.0, 1.0.ltoreq.b.ltoreq.4.0, and where X is at least one alloy element selected from Y and Mm (mish metal); or (2) the composition formula is Al.sub.100-a-b-c Fe.sub.a Si.sub.b X.sub.c, where a, b and c in atomic % are 3.0.ltoreq.a.ltoreq.6.0, 0.5.ltoreq.b.ltoreq.3.0, and 0.5.ltoreq.c.ltoreq.3.0, and where X is at least one alloy element selected from Ti, Co, Ni, Mn and Cr, and wherein both (1) and (2) include an amorphous phase of at least 1% by volume. The aluminum alloy powder or the green compact thereof is heated at a temperature increasing at a rate of at least 80.degree. C./min. to a predetermined temperature of at least 560.degree. C. and not more than a temperature at which 10% by volume of a liquid phase is contained in the alloy powder or green compact.
    Type: Grant
    Filed: July 26, 1994
    Date of Patent: March 12, 1996
    Assignees: Honda Giken Kogyo Kabushiki Kaisha, Sumitomo Electric Industries, Ltd.
    Inventors: Hiroyuki Horimura, Kenji Okamoto, Masahiko Minemi, Toshihiko Kaji, Yoshishige Takano, Yoshinobu Takeda
  • Patent number: 5482673
    Abstract: A process for preparing ceramic composite comprising blending TiC particulates, Al.sub.2 O.sub.3 particulates and nickle aluminide and consolidating the mixture at a temperature and pressure sufficient to produce a densified ceramic composite having fracture toughness equal to or greater than 7 MPa m.sup.1/2, a hardness equal to or greater than 18 GPa.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: January 9, 1996
    Assignee: Martin Marietta Energy Systems, Inc.
    Inventors: Kathleen B. Alexander, Terry N. Tiegs, Paul F. Becher, Shirley B. Waters
  • Patent number: 5476633
    Abstract: An INVAR 36 material having long-term dimensional stability is produced by sintering a blend of powders of nickel and iron under pressure in an inert atmosphere to form an alloy containing less than 0.01 parts of carbon and less than 0.1 part aggregate and preferably 0.01 part individually of Mn, Si, P, S, and Al impurities. The sintered alloy is heat treated and slowly and uniformly cooled to form a material having a coefficient of thermal expansion of less than 1 ppm/.degree.C. and a temporal stability of less than 1 ppm/year.
    Type: Grant
    Filed: July 6, 1994
    Date of Patent: December 19, 1995
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Witold M. Sokolowski, Marc S. Lane, Cheng H. Hsieh, Timothy P. O'Donnell
  • Patent number: 5470524
    Abstract: A method is provided for manufacturing a bladed ring for drum-shaped rotors of turbomachinery, especially rotors for axial compressors of gas turbine engines. The bladed ring is to be manufactured by hot isostatic pressing (HIP) and the fiber rings are formed in a metallic powder material for the bladed ring arranged in a circumferential direction. The fiber rings are bonded with spacing therebetween. The fiber rings are reinforced by fibers embedded in a metal matrix. The bladed ring prefabricated in this fashion by HIP is machined down to its required dimensions.
    Type: Grant
    Filed: June 14, 1994
    Date of Patent: November 28, 1995
    Assignee: MTU Motoren- Und Turbinen-Union Muenchen GmbH
    Inventors: Wolfgang Krueger, William Wei
  • Patent number: 5470527
    Abstract: A sputtering target that consists essentially of a continuous matrix of Ti-W phase, Ti phase having a particle diameter of 50 .mu.m or less distributed in the matrix, and a W phase having a particle diameter of 20 .mu.m or less also distributed in the matrix. Preferably the target contains aluminum in the range of 1 ppm or less. The target has high density and a low impurity content, which reduces the generation of particles from the target when it is used for sputtering. A method of manufacturing the sputtering target is also disclosed.
    Type: Grant
    Filed: September 12, 1994
    Date of Patent: November 28, 1995
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Takashi Yamanobe, Michio Satou, Takashi Ishigami, Minoru Obata, Mituo Kawai, Noriaki Yagi, Toshihiro Maki, Shigeru Ando
  • Patent number: 5466277
    Abstract: A sintered Al-alloy, which has a composition of 0.2 to 2.0% of Mg, 10.0 to 35.0% of Si, from 0.2 to 4.0% of Cu, and Al and unavoidable impurities in balance, is produced by using a mixture of the main powder (10.0-35.0% of Si, 0.2-2.0% of Cu, and Al and unavoidable impurities in balance) and at least one metal or mother-alloy powder selected from (a)-(i): (a) Mg powder; (b) Al--Mg powder; (c) Al--Cu powder; (d) Al--Mg--Si powder; (e) Al--Cu--Si powder; (f) Al--Mg--Cu powder; (g) Al--Mg--Cu--Si powder; (h) Mg--Cu powder; and, (i) Mg--Cu--Si powder.
    Type: Grant
    Filed: March 30, 1994
    Date of Patent: November 14, 1995
    Assignee: Showa Denko K.K.
    Inventors: Shin Miura, Youichi Hirose, Mitsuaki Sato
  • Patent number: 5462575
    Abstract: A powder metallurgy article formed from a Co--Cr--Mo alloy powder and a method for making the article are disclosed. The Co--Cr--Mo alloy powder contains, in weight percent, about 0.35% max. C, about 1.00% max. Mn, about 1.00% max. Si, about 26.0-30.0% Cr, about 5.0-7.0% Mo, about 3% max. Ni, about 0.25% max. N, about 1.00% max. Fe, about 0.01% max. of oxide forming metals, and the balance is essentially Co. Within their respective weight percent limits C and N are controlled such that they satisfy the relationship:62.866+360.93.times.(%C)+286.633.times.(%N)-682.165.times.(%C).sup.2 -641.702.times.(%N).sup.2 .gtoreq.120.
    Type: Grant
    Filed: December 23, 1993
    Date of Patent: October 31, 1995
    Assignee: CRS Holding, Inc.
    Inventor: Gregory J. Del Corso
  • Patent number: 5460640
    Abstract: A fully dense ceramic-metal body including 40-88 v/o of an oxide hard phase of, in v/o of the body, 4-88 v/o M-aluminum binary oxides, where the binary oxide has a C-type rare earth, garnet, .beta.-MAl.sub.11 O.sub.18, or perovskite crystal structure, and M is a lanthanide or indium, and 0-79 v/o .alpha.-alumina; about 10-50 v/o of a hard refractory carbide, nitride, or boride as a reinforcing phase; and about 2-10 v/o of a dispersed metal phase combining Ni and Al mostly segregated at triple points of the microstructure. The preferred metal phase contains a substantial amount of the Ni.sub.3 Al ordered crystal structure. In the preferred body, the reinforcing phase is silicon carbide partially incorporated into the oxide grains, and bridges the grain boundaries. The body including a segregated metal phase is produced by densifying a mixture of the hard phase components and the metal component, with the metal component being present in the starting formulation as Ni powder and Al powder.
    Type: Grant
    Filed: August 17, 1992
    Date of Patent: October 24, 1995
    Assignee: Valenite Inc.
    Inventor: Sergej-Tomislav Buljan