Two Percent Or More Silicon Containing Patents (Class 420/117)
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Publication number: 20100227180Abstract: A spraying material for coating a metallic member, being inexpensive and having superior corrosion and erosion resistance even in high temperature environments, wherein the material is composed of an Fe—Si based compound and comprises an alloy composed of 10 to 35% by weight of Si and the remainder of Fe and inevitable impurities, and further, up to 5% by weight of B may be added to the material in terms of improvement in hardness and adhesiveness of the coating is provided in order to protect components such as heaters and water walls of coal fired boilers and heat exchanger tubes of fluidized bed boilers, etc., from corrosion and erosion. The spraying material is formed into a coating by, for example, high velocity flame spraying or atmospheric plasma spraying.Type: ApplicationFiled: March 5, 2009Publication date: September 9, 2010Applicant: BABCOCK-HITACHI KABUSHIKI KAISHAInventors: Toshinari OKAGAITO, Yuji FUKUDA, Yoshitaka KOJIMA
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Publication number: 20100221138Abstract: The present invention provides a high-strength composite steel sheet which has a tensile strength of 980 MPa class as well as excellent and excellent anti-delayed fraction property, and also has excellent spot-weldability. The high-strength composite steel sheet comprises a steel satisfying: C: 0.10 to 0.25% (% by mass in case of a chemical component, the same shall apply hereinafter), Si: 1.0 to 3.0%, Mn: 1.5 to 3.0%, P: 0.15% or less, S: 0.02% or less, Al: 0.4% or less, and comprising the remnant made from iron and unavoidable impurities; the contents of Si, Al, Mn and Cr satisfy the relationship of “(Si+Al)/Mn or (Si+Al)/(Mn+Cr)=0.74 to 1.26”; and microstructure is specified.Type: ApplicationFiled: June 4, 2007Publication date: September 2, 2010Applicants: Kabushiki Kaisha Kobe Seiko Sho, Shinshu TLO Co., Ltd.Inventors: Michiharu Nakaya, Yoichi Mukai, Koichi Sugimoto
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Publication number: 20100201469Abstract: A soft magnetic alloy including iron, cobalt, and at least one alloying addition including a platinum group metal, rhenium, or combinations thereof is provided. A device which is formed from such an alloy is also described.Type: ApplicationFiled: February 23, 2010Publication date: August 12, 2010Applicant: GENERAL ELECTRIC COMPANYInventors: Luana Emiliana Iorio, Michael Francis Xavier Gigliotti, Pazhayannur Ramanathan Subramanian, Francis Johnson, Israel Samson Jacobs
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Publication number: 20100192895Abstract: The invention relates to a steel material having a high silicon content, and to a method for the production thereof, the steel material being particularly suitable for piston rings and cylinder sleeves. In addition to iron and production-related impurities, the steel material contains 0.5 to 1.2 wt. % carbon, 3.0 to 15.0 wt. % silicon and 0.5 to 4.5 wt. % nickel. Also, the steel material can contain small amounts of the following elements Mo, Mn, Al, Co Nb, Ti, V, Sn, Mg, B, Te Ta La, Bi, Zr, Sb, Ca, Sr, Cer, rare earth metals and nucleating agents such as NiMg, MiSiMg, FeMg and FeSIMg. due to the high Si content, a degree of saturation higher than 1.0 is attained, with the melting temperature of the steel material corresponding to normal cast iron. The steel material can be produced according to a conventional cast-iron technique and has a high resistance to wear and tear and a high structural strength (minimal distortion).Type: ApplicationFiled: May 7, 2007Publication date: August 5, 2010Applicant: FEDERAL-MOGUL BURSCHEID GMBHBURGERMEISTER-SCHMIDT- STRASSE 17Inventor: Laszlo Pelsoeczy
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Patent number: 7754383Abstract: A negative electrode material for a non-aqueous electrolyte secondary battery comprising an alloy including silicon and a transition metal selected from the group consisting of titanium, zirconium, vanadium, molybdenum, tungsten, iron, and nickel; and a silicon oxide film and an oxide film of the transition metal formed on a surface of the alloy wherein the alloy includes an A phase including silicon and a B phase including a crystalline alloy of silicon and the transition metal. The negative electrode material has a silicon oxide film and an oxide film of the transition metal on the surface of the alloy wherein the thickness ratio of the transition metal oxide film to the silicon oxide film is at least 0.44 and smaller than 1.Type: GrantFiled: December 12, 2006Date of Patent: July 13, 2010Assignee: Panasonic CorporationInventors: Teruaki Yamamoto, Masaki Hasegawa, Yasuhiko Bito
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Publication number: 20100158744Abstract: The present invention has as its object the production of high strength electrical steel sheet, having a high strength of a tensile strength TS of for example 500 MPa or more, having wear resistance, and having superior magnetic properties of magnetic flux density and iron loss, that is, provides a method of production of high strength electrical steel sheet containing, by mass %, C: 0.060% or less, Si: 0.2 to 6.5%, Mn: 0.05 to 3.0%, P: 0.30% or less, S or Se: 0.040% or less, Al: 2.50% or less, N: 0.020% or less, and further one or more of Cu: 0.001 to 30.0% and Nb: 0.03 to 8.Type: ApplicationFiled: June 16, 2006Publication date: June 24, 2010Inventor: Hidekuni Murakami
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Publication number: 20100111748Abstract: High cleanliness spring steel useful in manufacturing a spring with SiO2-based inclusions being extremely controlled and excellent in fatigue properties is provided. High cleanliness spring steel which is steel containing; C: 1.2% (means mass %, hereafter the same with respect to the component) or below (not inclusive of 0%), Si: 1.2-4%, Mn: 0.1-2.0%, Al: 0.01% or below (not inclusive of 0%), and the balance comprising iron with inevitable impurities, wherein; the total of oxide-based inclusions of 4 or above of L (the large diameter of an inclusion)/D (the short diameter of an inclusion) and 25 ?m or above of D and oxide-based inclusions of less than 4 L/D and 25 ?m or above of L, in the oxide-based inclusions of 25 mass % or above of oxygen concentration and 70% (means mass %, hereafter the same with respect to inclusions) or above of SiO2 content when Al2O3+MgO+CaO+SiO2+MnO=100% is presumed, out of inclusions in the steel, is 20 nos./500 g or below.Type: ApplicationFiled: January 7, 2010Publication date: May 6, 2010Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Tomoko SUGIMURA, Sei Kimura, Koichi Sakamoto, Atsuhiko Yoshida, Takeshi Inoue
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Publication number: 20100098577Abstract: A Si-killed steel wire rod for obtaining a spring excellent in fatigue properties and a spring excellent in fatigue properties obtained from the steel wire rod are provided. The Si-killed steel wire rod of the present invention contains Sr: 0.03-20 ppm (means “mass ppm”, hereinafter the same), Al: 1-30 ppm and Si: 0.2-4% (means “mass %”, hereinafter the same) respectively, and contains Mg and/or Ca by a range of 0.5-30 ppm in total. Also, in the Si-killed steel wire rod of the present invention, oxide-based inclusions present in the wire rod contain SiO2: 30-90%, Al2O3: 2-50%, MgO: 35% or below (not inclusive of 0%), CaO: 50% or below (not inclusive of 0%), MnO: 20% or below (not inclusive of 0%) and SrO: 0.2-15% respectively, and total content of (CaO+MgO) is 3% or above. A spring excellent in fatigue properties can be obtained by forming the spring from such steel wire rod.Type: ApplicationFiled: December 3, 2007Publication date: April 22, 2010Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Tomoko Sugimura, Koichi Sakamoto
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Publication number: 20090277547Abstract: A high strength steel sheet with both excellent elongation and stretch-flanging performance is provided. The high strength steel sheet of the present invention comprises, in percent by mass, C: 0.05 to 0.3%, Si: 0.01 to 3.0%, Mn: 0.5 to 3.0%, Al: 0.01 to 0.1%, and Fe and inevitable impurities as the remainder, and has a structure mainly composed of tempered martensite and annealed bainite. The space factor of the tempered martensite is 50 to 95%, the space factor of the annealed bainite is 5 to 30%, and the mean grain size of the tempered martensite is 10 ?m or smaller in terms of the equivalent of a circle diameter. The steel sheet has a tensile strength of 590 MPa or higher.Type: ApplicationFiled: July 13, 2007Publication date: November 12, 2009Applicant: KABUSHIKI KAISHA KOBE SEIKO SHOInventors: Kenji Saito, Tomokazu Masuda, Masaaki Miura, Yoichi Mukai, Shushi Ikeda
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Publication number: 20090252641Abstract: A steel sheet contains, in terms of percent by mass, C: 0.01 to 0.2%, Si: 2.0% or less, and Mn: 3.0% or less and has a martensite phase as dominant phase and ferrite with a grain size of 20 ?m or less as a second phase. The ferrite is contained in area ratio of 1% to 30% and the amount of solute carbon being 0.01 percent by mass of more. The steel sheet can provide a hot-rolled steel sheet suitable for automobile steel sheet, i.e., has excellent press workability and excellent strain aging property whereby the tensile strength significantly increases by heat treatment at about the same temperature as typical baking process after the press-working. Moreover, hardening of the ferrite phase improves the fatigue strength after the strain aging.Type: ApplicationFiled: March 29, 2006Publication date: October 8, 2009Applicant: JFE Steel Corporation a corporation of JapanInventors: Toru Hoshi, Saiji Matsuoka
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Publication number: 20090252955Abstract: Disclosed is a steel sheet, containing: Si: 0.20-2% (the term “%” herein means “mass %”, the same is true hereinbelow), Mn: 1-2.5%, a total mass of Si and Mn being 1.5% or more, and O: 0.002% or less (exclusive of 0%), C: 0.02-0.25%, P: 0.1% or less (exclusive of 0%), S: 0.05% or less (exclusive of 0%), Al—0.02-0.2%, and N: 0.0015-0.015%. The steel sheet of the invention can be advantageously used for forming wide beads even in high-speed arc welding of 100 cm/min or higher.Type: ApplicationFiled: June 19, 2009Publication date: October 8, 2009Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)Inventors: Tetsuo Soshiroda, Reiichi Suzuki, Kei Yamazaki
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Publication number: 20080279714Abstract: The present invention provides spring steel used for spring steel wire achieving both high strength and cold coilability and spring steel wire, that is, spring steel containing, by mass %, C: 0.45 to 0.70%, Si: 1.0 to 3.0%, Mn: 0.05 to 2.0%, P: 0.015% or less, S: 0.015% or less, N: 0.0015 to 0.0200%, and t-O: 0.0002 to 0.01 and further limiting Al?0.01% and Ti?0.003%. Further, it is characterized by satisfying the following regarding the cementite-based spherical carbides present at an observed plane, an occupied area ratio of grains with a circle equivalent diameter of 0.2 ?m or more of 7% or less, a density of presence of grains with a circle equivalent diameter of 0.2 to 3 ?m of 1/?m2 or less, and a density of presence of grains with a circle equivalent diameter 3 ?m or more of 0.Type: ApplicationFiled: November 30, 2005Publication date: November 13, 2008Inventors: Masayuki Hashimura, Hiroshi Hagiwara, Takanori Miyaki, Takayuki Kisu, Kouichi Yamazaki
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Patent number: 7416615Abstract: The invention relates to a high-resistant, low-density hot laminated sheet steel comprising the following elements expressed in weight per cent: 0.04%:9 carbon?0.5%; 0.05%?manganese?3%, being able to contain hardening elements: 0.01%?niobium?0.1 0.01%?titanium?0.2% 0.01?vanadium?0.2%, either individually or combined, and/or elements acting on the transformation temperatures, 0.0005%?boron?0.005%; 0.05%?nickel?2%; 0.05%?chrome?2%; 0.05%?molybdenum?2%, either individually or combined, the remainder being iron and elements which are inherent to production, characterized in that it comprises: 2%?silicon?10%; 1%?aluminium?10%. The invention also relates to the production thereof.Type: GrantFiled: March 10, 2003Date of Patent: August 26, 2008Assignee: USINORInventors: Xavier Bano, Christian Giraud
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Publication number: 20080166257Abstract: The present invention provides a steel sheet excellent in workability, which may be used for components of an automobile or the like, and a method for producing the same. More specifically, according to one exemplary embodiment of the present invention, a steel sheet excellent in workability, including in mass, 0.08 to 0.25% C, 0.001 to 1.5% Si, 0.01 to 2.0% Mn, 0.001 to 0.06% P, at most 0.05% S, 0.001 to 0.007% N, 0.008 to 0.2% Al, at least 0.01% Fe. The steel sheet having an average r-value of at least 1.2, an r-value in the rolling direction of at least 1.3, an r-value in the direction of 45 degrees to the rolling direction of at least 0.9, and an r-value in the direction of a right angle to the rolling direction of at least 1.2.Type: ApplicationFiled: March 14, 2008Publication date: July 10, 2008Inventors: Naoki Yoshinaga, Nobuhiro Fujita, Manabu Takahashi, Koji Hashimoto, Shinya Sakamoto, Kaoru Kawasaki, Yasuhiro Shinohara, Takehide Senuma
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Publication number: 20080152531Abstract: Cast irons are provided which have no intentional addition of molybdenum (Mo) and which have compositions with additional silicon that provide certain advantages, such as lower cost, higher use temperatures, and increased tensile strength, over conventional Mo-bearing cast irons. In the cast irons, Mo is absent or present only as an impurity element.Type: ApplicationFiled: December 21, 2006Publication date: June 26, 2008Inventors: Ramesh Chimanlal Shah, Vinod K. Sikka, Govindarajan Muralidharan
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Patent number: 7004493Abstract: The invention relates to a ski edge profile made from steel. To further improve the sliding properties compared to the ski edge profiles which are known from the prior art, according to the invention it is proposed for the ski edge profile to consist of a steel alloy with a relatively low thermal conductivity.Type: GrantFiled: June 12, 2002Date of Patent: February 28, 2006Assignee: C.D. Walzholz-Brockhaus GmbHInventors: Hans-Toni Junius, Norbert Brachthäuser
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Patent number: 6918966Abstract: The object of the present invention is to provide a low iron loss and low noise grain-oriented electrical steel sheet for securing both low core loss and low noise of a transformer at the same time. The present invention relates to a grain-oriented electrical steel sheet containing Si: 1.0-4.0 wt % produced by controlling, with regard to ?O, which is defined as a 0-p value when a grain-oriented electrical steel sheet is magnetized up to a saturated magnetic flux density, and ?17, which is defined as the value obtained by subtracting a 0-p value at the magnetization magnetic flux density of 1.7 T from a 0-p value at a saturated magnetic flux density, ?OC and ?17L, which are absolute values deviated by forming a tension film and a forsterite film, and ?OL and ?17L, which are absolute values deviated by irradiating laser after the film formation, in adequate ranges respectively, and further controlling ?17, which is a 0-p value at the magnetization magnetic flux density of 1.Type: GrantFiled: November 6, 2002Date of Patent: July 19, 2005Assignee: Nippon Steel CorporationInventors: Masahiro Fujikura, Satoshi Arai, Masato Mizokami, Hisashi Mogi, Takeshi Kubota
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Patent number: 6822831Abstract: An object of the present invention is to provide a recording head having a magnetic pole simultaneously possessing a high saturation magnetic flux density, a high permeability and a high electric resistivity, and the magnetic pole of the recording head is a polycrystalline film comprising Fe whose content is not less than 57.5 atomic % and not more than 94.5 atomic %; one or more kinds of elements selected from the element group of Al, B, Ga, Si, Ge, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W and Rh, whose whole content is not less than 1 atomic % and not more than 15 atomic %; N whose content is not less than 0.5 atomic % and not more than 10 atomic %; and O whose content is not less than 1.5 atomic % and not more than 22.5 atomic %.Type: GrantFiled: February 12, 2002Date of Patent: November 23, 2004Assignee: Fujitsu LimitedInventors: Shoji Ikeda, Yuji Uehara, Ikuya Tagawa, Naoki Takeguchi, Masahiro Kakehi
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Patent number: 6800146Abstract: A magnetic circuit member contains a matrix portion including iron and silicon; and graphite particles in the matrix. Each of the graphite particles has either a spherical shape or a compact vermicular shape. The inclusion of graphite particles having a relatively low conductivity in the matrix portion having a good magnetic property prevents eddy currents from forming in the magnetic circuit member in an alternating magnetic field, thus preserving the original magnetic property found in the absence of the alternating magnetic field. Each of the graphite particles has a spherical or compact vermicular shape that does not intercept magnetic flux passing through the material forming the magnetic circuit member. The graphite contained in the material improves liquidity of the melted material in casting, thus the magnetic circuit member can be manufactured by casting.Type: GrantFiled: March 19, 2002Date of Patent: October 5, 2004Assignee: Aisin Seiki Kabushiki KaishaInventors: Akikazu Matsumoto, Wataru Yagi
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Patent number: 6723914Abstract: There is provided a composite magnetic tape which can be easily applied irrespective of the inside or outside of an electronic equipment, prevent radiation of undesired electromagnetic waves from the inside of the equipment and reflection into the inside of the equipment, and shield electromagnetic noise from the outside of the equipment. The tape may be in the form of an adhesive tape or a self-welding tape. The tape is constituted of a composite magnetic layer formed by dispersing soft magnetic powder into an organic binding agent. Alternatively, it may have a stacked structure of a composite magnetic layer and a conductor layer.Type: GrantFiled: February 23, 2000Date of Patent: April 20, 2004Assignee: NEC Tokin CorpInventors: Koji Kamei, Norihiko Ono, Mitsuharu Sato
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Patent number: 6695985Abstract: An electromagnetic wave suppressor sheet formed into a sheet-like shape out of a material made of synthetic resin in which powder of conjugated magnetic particles surface-treated with an insulating inorganic material has been dispersed.Type: GrantFiled: June 11, 2002Date of Patent: February 24, 2004Assignees: Nitto Denko Corporation, Sony CorporationInventors: Kazumasa Igarashi, Junichi Toyoda, Katsumi Okayama
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Patent number: 6565674Abstract: A high flux density grain-oriented electrical steel sheet excellent in high magnetic field core loss property containing, in percentage by weight, not greater than 0.005% of C, 2.0-7.0% of Si, not greater than 0.2% of Mn, one or both of S and Se in a total amount of not greater than 0.005%, the balance being of Fe and unavoidable impurities, optionally containing, in percentage by weight, of not greater than 0.065% of Al, not greater than 0.005% of N and 0.003-0.3% each of one or more of Sb, Sn, Cu, Mo, Ge, B, Te, As, Cr and Bi, the steel sheet having a grain orientation deviating from an ideal {110}<001> orientation by an average of not greater than 5°, having an average 180° magnetic domain width of not greater than 0.30 mm, preferably not greater than 0.26 mm or greater than 0.26 mm and not greater than 0.30 mm, and having an area ratio of magnetic domains of a width greater than 0.4 mm of greater than 3% and not greater than 20%.Type: GrantFiled: May 30, 2000Date of Patent: May 20, 2003Assignee: Nippon Steel CorporationInventors: Yousuke Kurosaki, Masahiro Fujikura
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Patent number: 6562207Abstract: Sputter target, method of manufacture of same and sputter coating process using the target as a sputtering source are disclosed. The sputter target comprises an Me/Si multi-phase, consolidated blend wherein the Si component is present in a very small amount of about trace—0.99 mole Si:1 mole Me. Preferably, Me comprises one or more of Ta, Ti, Mo, or W. The targets are made from the requisite powders via HIP consolidation to provide densities of greater than 98 % of the theoretical density. The targets are especially useful in reactive cathodic sputtering systems employing N2 as the reactive gas to form amorphous Me/Si/N layers.Type: GrantFiled: January 14, 2000Date of Patent: May 13, 2003Assignee: Tosoh SMD, Inc.Inventor: Eugene Y. Ivanov
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Patent number: 6531001Abstract: Non-oriented magnetic steel sheets, which are mainly used as materials for iron cores for use in electric apparatuses, have a low iron loss and a high magnetic flux density at the same time. The non-oriented magnetic steel sheet comprises from about 1.5 to about 8.0 weight % Si, from about 0.005 to about 2.50 weight % Mn, and not more than about 50 ppm each of C, S, N, O, and B, in which a crystal orientation parameter <&Ggr;> is 0.200 or less. In addition, the average crystal grain diameter is preferably from about 50 to about 500 &mgr;m, and an areal ratio of crystal grains on a surface of the steel sheet is preferably 20% and less, in which crystal plane orientations of the crystal grains are within 15° from the <111> axis. In addition, the non-oriented magnetic steel sheet preferably contains small amounts of elements such as Al, Sb, Ni, Sn, Cu, P, and Cr. The manufacturing method for the non-oriented magnetic steel is also described.Type: GrantFiled: May 8, 2002Date of Patent: March 11, 2003Assignee: Kawasaki Steel CorporationInventors: Yasuyuki Hayakawa, Mitsumasa Kurosawa, Masaki Kawano, Michiro Komatsubara, Yuka Komori, Kazuaki Tamura
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Publication number: 20020153067Abstract: Steels having a pearlitic structure and containing 0.60 to 1.0 weight percent carbon, 1.1 to 3.0 weight percent silicon, 0.45 to 0.85 weight percent manganese, less than 0.050 weight percent sulfur and less than 0.050 weight percent phosphorus, with the remainder of said steel being iron and incidental impurities, can be used to make railway wheels that are resistant to martensite transformations and, hence, spalling. The addition of 0.50 to 1.0 weight percent chromium to such steels further improves their resistance to spalling.Type: ApplicationFiled: April 17, 2002Publication date: October 24, 2002Inventors: Daniel Hunter, Kevin James
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Publication number: 20020134466Abstract: A silicon steel sheet having low iron loss of high frequency has a surface layer of the steel sheet which has Si concentration higher than Si concentration of a center portion of the steel sheet. Si concentration of sheet thickness center is 3.4 wt. % or more and Si concentration of the surface layer of the steel sheet is 5 wt. % or more. Si concentration in a surface layer portion is 5 to 8 wt. %. The production method comprises siliconizing treatment and diffusing treatment. Velocity of siliconizing and diffusing are controlled, and Si concentration distribution in the sheet thickness direction of the steel sheet is controlled.Type: ApplicationFiled: January 24, 2000Publication date: September 26, 2002Inventors: MISAO NAMIKAWA, YOSHIKAZU TAKADA, SHOJI KASAI, HIRONORI NINOMIYA, TSUNEHIRO YAMAJI, TATSUHIKO HIRATANI
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Patent number: 6444168Abstract: In order to produce elements for furnaces, reactors or conduits on the walls of which coke can appear, steels are used with a composition which is adapted to resist coking comprising, by weight, at most 0.25% of C, 1.5% to 5% of Si, 4% to 10% of Cr, 0.5% to 2% of Mo, 0.3% to 1% of Mn, at most 0.030% of S and at most 0.03% of P, the complement to 100% being essentially iron. Novel steel compositions for use in these applications are those which comprise, by weight, at most 0.25% of C, more than 2.5% and up to 5% of Si, 4% to 10% of Cr, 0.5% to 2% of Mo, 0.3% to 1% of Mn, at most 0.03% of S and at most 0.03% of P, the complement to 100% being essentially iron.Type: GrantFiled: October 2, 2000Date of Patent: September 3, 2002Assignee: Institu Francais du PetroleInventors: Philipe Lecour, Xavier Longaygue, Francois Ropital
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Patent number: 6432227Abstract: Electromagnetic steel sheet from a high-purity steel slab, composed essentially of Si 2.0 to 8.0 wt %, Mn 0.005 to 3.0 wt % and Al 0.0010 to 0.012 wt % with each of Se, S, N and O each not more than 30 ppm.Type: GrantFiled: October 3, 2001Date of Patent: August 13, 2002Assignee: Kawasaki Steel CorporationInventors: Yasuyuki Hayakawa, Mitsumasa Kurosawa, Michiro Komatsubara
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Patent number: 6428632Abstract: According to the invention, a nonoriented electromagnetic steel sheet being small in the magnetic anisotropy in a high frequency zone and thus excellent in the magnetic properties as a rotating machine and having an excellent press formability such as punching property or the like can be obtained stably by adjusting a chemical composition of the oriented electromagnetic steel sheet to a given range, and establishing the following equation (1) between L, C average iron loss W15/50(L+C)[W/kg] and L, C average magnetic flux density B50(L+C)[T] with respect to measured values of magnetic properties using Epstein test pieces: B50(L+C)≧0.03·W15/50(L+C)+1.63 (1) and satisfying a ratio of D iron loss W10/400(D)[W/kg] to L, C average iron loss W10/400(L+C)[W/kg] by the following equation (2): W10/400(D)/W10/400(L+C)≦1.Type: GrantFiled: July 24, 2001Date of Patent: August 6, 2002Assignee: Kawasaki Steel CorporationInventors: Toshiro Fujiyama, Keiji Sakai
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Patent number: 6423157Abstract: Grain-oriented magnetic steel sheet made by the method comprising of hot rolling and final finish annealing, wherein (1) the O content in the steel slab is limited to up to about 30 wtppm; (2) for the entire steel sheet including an oxide film before final finish annealing, from among impurities, the Al content is limited to up to about 100 wtppm, and the contents of B, V, Nb, Se, S, and N, to up to about 50 wtppm; and (3) during final finish annealing, the N content in the steel is, at least in the temperature region of from about 850 to 950° C., limited within the range of from about 6 to 80 wtppm.Type: GrantFiled: March 5, 2001Date of Patent: July 23, 2002Assignee: Kawasaki Steel CorporationInventors: Yasuyuki Hayakawa, Mitsumasa Kurosawa, Michiro Komatsubara
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Patent number: 6355212Abstract: The invention is directed to anti-corrosive alloys and relates in particular to an alloy containing cobalt, chromium, aluminum, yttrium, silicon, a metal from the second main group, together with the corresponding oxide, in the following proportions: chromium (Cr) 26.0-30%; aluminum (Al) 5.5-13.0%; yttrium (Y) 0.3-1.5%; silicon (Si) 1.5-4.5%; metal from the second main group (magnesium, calcium, barium, strontium) 0.1-2.0%; oxide of the corresponding metal from the second main group 0.1-2.0%; cobalt (Co) remaining percentage. Preferably, tantalum (Ta) is also added in a proportion of 0.5-4.0%, and the remaining percentage of cobalt is replaced by a remaining percentage of Me, Me being understood to mean a metal which may be nickel (Ni) or iron (Fe) or cobalt (Co) or a composition comprising Ni—Fe—Co, Ni—Fe, Ni—Co, Co—Fe.Type: GrantFiled: January 5, 2000Date of Patent: March 12, 2002Assignee: Turbocoating SpAInventor: Nelso Antolotti
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Patent number: 6322638Abstract: Electromagnetic steel sheets which contain Cr in an amount of from about 1.5 to 20% by weight and Si in an amount of from about 2.5 to 10% by weight, while having a total amount of C and N of not larger than about 100 ppm by weight, and which has a specific resistivity of not smaller than about 60 &mgr;&OHgr;·cm.Type: GrantFiled: August 29, 2000Date of Patent: November 27, 2001Assignee: Kawasaki Steel CorporationInventors: Shigeaki Takajo, Takako Yamashita, Akihiro Matsuzaki, Osamu Kondo
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Patent number: 6293988Abstract: A new technique for producing ferrosilicon free inoculating agents for gray and ductile irons utilizing oxy-sulfide forming elements combined with sulfur and oxygen and 1) mechanically pressed into an insert or tablet for placement into foundry sand molds or 2) a mixture of the same ingredients used as a loose or granular addition to molten iron. The inoculating agent is composed of 15 to 49% silicon, 7 to 22% calcium, 2.5 to 10% sulfur, 2 to 4% oxygen, 2.5 to 7.5% magnesium and 0.5 to 5% aluminum with the balance iron and incidental impurities, wherein the iron is the primary densification agent.Type: GrantFiled: August 4, 1998Date of Patent: September 25, 2001Inventor: Rodney Louis Naro
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Patent number: 6210496Abstract: A cold rolled steel sheet having high strength and high formability and having excellent crushing performance can include 0.05-0.40 mass % of C, 1.0-3.0 mass % of Si, 0.6-3.0 mass % of Mn, 0.02-1.5 mass % of Cr, 0.010-0.20 mass % of P and 0.01-0.3 mass % of Al, with the remainder consisting essentially of Fe. The steel sheet includes a ferrite major phase and a minor phase consisting of martensite, acicular ferrite and retained austenite. The cold rolled steel sheet can be used in automobiles.Type: GrantFiled: February 12, 1999Date of Patent: April 3, 2001Assignee: Kawasaki Steel CorporationInventors: Syusaku Takagi, Kazuya Miura, Osamu Furukimi, Kei Sakata, Takashi Obara
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Patent number: 6162306Abstract: Electromagnetic steel sheets which contain Cr in an amount of from about 1.5 to 20% by weight and Si in an amount of from about 2.5 to 10% by weight, while having a total amount of C and N of not larger than about 100 ppm by weight, and which has a specific resistivity of not smaller than about 60 .mu..OMEGA..multidot.cm.Type: GrantFiled: October 28, 1998Date of Patent: December 19, 2000Assignee: Kawasaki Steel CorporationInventors: Shigeaki Takajo, Takako Yamashita, Akihiro Matsuzaki, Osamu Kondo
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Patent number: 6103022Abstract: In a grain oriented electrical steel sheet used for cores of transformers and generators, a high alignment degree of grain orientations reduces iron loss, by precipitating very fine AlN or/and BN and providing strong inhibiting effect against the growth of the primary recrystallized grains, providing radically improved texture and grain structure in the steel.Type: GrantFiled: March 24, 1998Date of Patent: August 15, 2000Assignee: Kawasaki Steel CorporationInventors: Michiro Komatsubara, Toshito Takamiya, Kunihiro Senda
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Patent number: 6060172Abstract: The present invention relates to a rapidly quenched metal strip used as a core material for transformers, magnetic shields, choke coils, etc., and to an Fe-based rapidly quenched metal strip having a strip thickness exceeding 20 .mu.m and up to 70 .mu.m, wherein nonmetallic inclusions contained in said metal strip have a maximum particle size up to 50% of the strip thickness, and densities of the nonmetallic inclusions are up to 10 nonmetallic inclusions/mm.sup.3 for nonmetallic inclusions having a particle size exceeding 10 .mu.m and up to 50% of the strip thickness, up to 3.times.10.sup.3 nonmetallic inclusions/mm.sup.3 for nonmetallic inclusions having a particle size of at least 3 .mu.m to up to 10 .mu.m, and up to 5.times.10.sup.5 nonmetallic inclusions/mm.sup.3 for nonmetallic inclusions having a particle size of at least 0.3 .mu.m to less than 3 .mu.m, and showing the following average value <.epsilon..sub.f > of a bending fracture strain .epsilon..sub.Type: GrantFiled: April 10, 1998Date of Patent: May 9, 2000Assignee: Nippon Steel CorporationInventors: Yoshiharu Inoue, Hiroaki Sakamoto
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Patent number: 5944917Abstract: A stainless steel having excellent corrosion resistance to ozone added water, such as ozone added ultrapure water used in semiconductor manufacturing processes and the like, as well as a manufacturing method. The stainless steel comprises a base metal and an oxide film formed on the surface of the base metal, the base metal being a stainless steel which contains 12 to 30% of Cr, 0 to 35% of Ni, and 1 to 6% of Al and Si while the contents of the other alloying elements are limited to as low a level as possible, the oxide film mainly comprising Al oxide or a Si oxide or both. The oxide film may be formed on the base metal surface through the dry oxidation process or the wet oxidation process. In the stainless steel, metallic ions are rarely dissolved from the base metal into the ozone added water.Type: GrantFiled: May 29, 1997Date of Patent: August 31, 1999Assignee: Sumitomo Metal Industries, Ltd.Inventors: Kiyoko Takeda, Shigeki Azuma, Yoshio Tarutani, Yoshitaka Nishiyama, Yasushi Matsuda
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Patent number: 5919319Abstract: An Iron-cobalt alloy, whose chemical composition contains, by weight:5%.ltoreq.Co.ltoreq.40%0%.ltoreq.Si.ltoreq.5%0.2%.ltoreq.Al.ltoreq.5%0.5%.ltoreq.Si+Al.ltoreq.5%the balance being iron and impurities resulting from the smelting. Process for manufacturing a strip and strip obtained.Type: GrantFiled: January 13, 1997Date of Patent: July 6, 1999Assignee: Imphy S.A.Inventor: Georges Couderchon
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Patent number: 5902419Abstract: A silicon steel sheet contains 0.01 wt. % or less C, 4 to 10 wt. % Si, 0.5 wt. % or less Mn, 0.01 wt. % or less P, 0.01 wt. % or less S, 0.2 wt. % or less sol. Al, 0.01 wt. % or less N, 0.02 wt. % or less 0 and the balance being Fe. The silicon steel sheet has grain boundaries and carbides which are precipitated on the grain boundaries. The carbides have an area of 20% or less to an area of the grain boundaries. The steel sheet is cooled at a cooling speed of 5.degree. C./sec. or more in a temperature range of from 300 to 700.degree. C.Type: GrantFiled: September 23, 1996Date of Patent: May 11, 1999Assignee: NKK CorporationInventors: Koichiro Fujita, Yasushi Tanaka, Hironori Ninomiya, Tatsuhiko Hiratani, Shoji Kasai
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Patent number: 5885374Abstract: Producing a grain oriented silicon steel sheet by controlling physical properties of the oxides layer, formed in decarburization annealing, in the surface layer of a steel sheet. A silicon compound is adhered to the surface of steel sheet before the decarburization annealing in an amount ranging from about 0.5 to 7.0 mg per square meter, expressed as Si, and the atmosphere of an earlier portion of the temperature holding process is adjusted to a ratio of steam partial pressure to the hydrogen partial pressure of less than about 0.7, and the atmosphere of the temperature rising process up to the temperature holding process is adjusted to an atmospheric composition lower than the atmospheric composition of the earlier portion of the temperature holding process, and the atmosphere of a later part of the temperature holding process is adjusted to an atmospheric composition lower than the atmospheric composition of the earlier part of the temperature holding process and in a range from about 0.005 to 0.2.Type: GrantFiled: September 18, 1997Date of Patent: March 23, 1999Assignee: Kawasaki Steel CorporationInventors: Hirotake Ishitobi, Takafumi Suzuki, Michiro Komatsuhara, Hiroi Yamaguchi
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Patent number: 5876520Abstract: The present invention relates to a semiprocessed nonoriented magnetic steel sheet which is used in iron cores of motors and transformers, finished to a final product by rolling having a reduction rate of 2 to 18% after final annealing by a manufacturer, and assures desired magnetic characteristics due to coarsening of crystal grains during strain-relief annealing after processing by a user. The excellent magnetic characteristics can be achieved by increasing lubrication during second cold rolling so as to satisfy the equation: e.sub.c .ltoreq.e.sub.s .ltoreq.1.18e.sub.c wherein e.sub.s represents a strain value at the surface layer of the steel sheet and e.sub.c represents a strain value at the central layer.Type: GrantFiled: September 30, 1997Date of Patent: March 2, 1999Assignee: Kawasaki Steel CorporationInventors: Minoru Takashima, Akio Fujita, Keiji Sato, Masaki Kawano
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Patent number: 5873954Abstract: A ferromagnetic amorphous metallic alloy strip is annealed to minimize exciting power rather than core loss. The strip has an exciting power less than 0.5 VA/kg when measured at 60 Hz and an operating induction of 1.40 to 1.45 Tesla, the measurement being carried out at ambient temperature. Cores composed of the strip can be run at higher operating induction than those annealed to minimize core loss. The physical size of the transformer's magnetic components, including the core, is significantly reduced.Type: GrantFiled: February 5, 1997Date of Patent: February 23, 1999Assignee: AlliedSignal Inc.Inventors: Howard H. Liebermann, Nicholas J. DeCristofaro
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Amorphous Fe-B-Si-C alloys having soft magnetic characteristics useful in low frequency applications
Patent number: 5871593Abstract: A rapidly solidified amorphous metallic alloy is composed of iron, boron, silicon and carbon. The alloy exhibits in combination high saturation induction, high Curie temperature, high crystallization temperature, low core loss and low exciting power at line frequencies and is particularly suited for use in cores of transformers for an electrical power distribution network.Type: GrantFiled: January 9, 1997Date of Patent: February 16, 1999Assignee: AlliedSignal Inc.Inventors: Gordon Edward Fish, Howard Horst Liebermann, John Silgailis, V. R.V. Ramanan -
Patent number: 5833769Abstract: A wide amorphous alloy thin strip having a width of 70 mm or above and useful as an iron core of electric power transformers, composed of Fe--Si--B--C amorphous alloy. Dispersion of an amorphous structure in the width direction is prevented and deterioration of the strip properties is suppressed by adding Mn or by casting in an atmosphere containing a carbonic acid gas in an amount of about 40 vol % or more to thereby control strip surface roughness to a center line average surface roughness of about 0.7 .mu.m or less.Type: GrantFiled: October 7, 1996Date of Patent: November 10, 1998Assignee: Kawasaki Steel CorporationInventors: Fumio Kogiku, Seiji Okabe, Kensuke Matsuki, Masao Yukumoto
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Patent number: 5779819Abstract: The present invention relates to the production of a grain oriented electrical steel composition having a volume resistivity of at least 50 micro-ohm-cm. The melt composition of the steel consists essentially of, in weight %, about 0.08% max carbon, about 0.015 to about 0.05% aluminum, about 2.25 to 7% silicon, greater than about 0.5% manganese.sub.eq, about 0.001 to about 0.011% nitrogen, about 0.01% max sulfur, about 3% max chromium, about 1% max copper, about 2% max nickel and balance essentially iron. High levels of silicon are balanced with a manganese equivalent relationship which permits lower levels of carbon while still providing the desired levels of austenite during rolling and annealing. The processing also includes the addition of excess nitrogen to the steel prior to secondary grain growth which is subsequently removed during a purification treatment.Type: GrantFiled: February 20, 1997Date of Patent: July 14, 1998Assignee: Armco Inc.Inventor: Glenn Stuart Huppi
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Patent number: 5772728Abstract: The present invention relates to a method for upgrading silicon-containing solid residues obtained after leaching of copper from copper-containing residues from direct synthesis of organochlorosilanes. Solid residue, optionally together with an oxidation agent, is supplied to a smelting furnace where the residues are melted and form a molten metallic phase substantially containing silicon and a calcium silicate slag and tapping of the molten metallic phase and an inert slag from the smelting furnace.Type: GrantFiled: May 19, 1997Date of Patent: June 30, 1998Assignee: Elkem ASAInventors: Inger Johanne Eikeland, Roald Gundersen, Ragnhild Jensen
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Patent number: 5766375Abstract: A non-oriented magnetic steel sheet having excellent bending workability and magnetic characteristics is obtained by continuous annealing. The non-oriented magnetic steel sheet is obtained by the method comprising cold rolling a hot-rolled steel sheet, continuously annealing the steel sheet, and then performing skin pass rolling; the steel has a composition comprising about 0.005 mass % or less of C, about 0.05 to 0.30 mass % of Si, about 0.10 to 0.50 mass % of Mn, about 0.15 to 0.50 mass % of Al, and about 0.0050 mass % or less of N.Type: GrantFiled: March 21, 1997Date of Patent: June 16, 1998Assignee: Kawasaki Steel CorporationInventors: Susumu Okamura, Etsuji Hino, Yoshinori Fujita, Masaki Shimizu, Tetsuya Aoki, Shoichi Takenouchi
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Patent number: 5728237Abstract: Amorphous alloys having the formulaFe.sub.a Co.sub.b Ni.sub.c Si.sub.x B.sub.y M.sub.zare employed as monitoring strips for mechanically oscillating tags, for example for anti-theft protection, together with a source of a pre-magnetization field in which the strip is disposed so as to place the strip in an activated state. In the formula, M denotes one or more elements of groups IV through VII of the periodic table, including C, Ge and P, and the constituents in at % meet the following conditions: a lies between 20 and 74, b lies between 4 and 23, c lies between 5 and 50, with the criterion that b+c>14, x lies between 0 and 10, y lies between 10 and 20, and z lies between 0 and 5 with the sum x+y+z being between 12 and 21. These alloys have a resonant frequency associated therewith and when passed through an alternating field whose alternation frequency coincides with the resonant frequency, a pulse having a signal amplitude is produced.Type: GrantFiled: December 9, 1996Date of Patent: March 17, 1998Assignee: Vacuumschmelze GmbHInventor: Giselher Herzer
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Patent number: RE38098Abstract: Amorphous alloys having the formula Fea Cob Nic Six By Mz are employed as monitoring strips for mechanically oscillating tags, for example for anti-theft protection, together with a source of a pre-magnetization field in which the strip is disposed so as to place the strip in an activated state. In the formula, M denotes one or more elements of groups IV through VII of the periodic table, including C, Ge and P, and the constituents in at % meet the following conditions: a lies between 20 and 74, b lies between 4 and 23, c lies between 5 and 50, with the criterion that b+c>14, x lies between 0 and 10, y lies between 10 and 20, and z lies between 0 and 5 with the sum x+y+z being between 12 and 21. These alloys have a resonant frequency associated therewith and when passed through an alternating field whose alternation frequency coincides with the resonant frequency, a pulse having a signal amplitude is produced.Type: GrantFiled: December 15, 1998Date of Patent: April 29, 2003Assignee: Vacuumschmelze GmbHInventor: Giselher Herzer