Titanium Containing Patents (Class 420/126)
  • Patent number: 11427898
    Abstract: A steel sheet has a composition comprising, by weight: 0.010%?C?0.080%, 0.06%?Mn?3%, Si?1.5%, 0.005%?Al?1.5%, S?0.030%, P?0.040%, Ti and B such that: 3.2%?Ti?7.5% and (0.45×Ti)?1.35?B?(0.45×Ti)?0.43, optionally Ni?1%, Mo?1%, Cr?3%, Nb?0.1%, V?0.1%, the remainder being iron and unavoidable impurities resulting from the smelting. The steel sheet has a structure consisting of ferrite, at most 10% of austenite, and precipitates comprising eutectic precipitates of TiB2, the volume fraction of TiB2 precipitates with respect to the whole structure being of at least 9%, the proportion of TiB2 precipitates having a surface area lower than 8 ?m2 being of at least 96%.
    Type: Grant
    Filed: April 20, 2018
    Date of Patent: August 30, 2022
    Assignee: ARCELORMITTAL
    Inventors: Frédéric Bonnet, Manuel Bobadilla, Bertrand Bele, Valérie Daeschler
  • Patent number: 10538823
    Abstract: A high-strength steel sheet has a chemical composition comprising C: 0.05-0.20%, Si: 0.02-3.0%, Mn: 0.5-3.0%, P: at most 0.5%, S: at most 0.05%, Cr: 0.05-1.0%, sol. Al: 0.01-1.0%, one or more elements selected from the group consisting of Ti, Nb, Mo, V, and W: a total of 0.002-0.03%, and a remainder of Fe and impurities. The sheet has an average grain diameter of ferrite of at most 3.0 ?m at least in a region of 100-200 ?m in the sheet thickness direction from the surface of the steel sheet. The average spacing in the sheet thickness direction of the remaining structure in this region is at most 3.0 ?m. Mechanical properties include at least 750 MPa tensile strength and at least 13,000 MPa·% (tensile strength×elongation).
    Type: Grant
    Filed: May 27, 2010
    Date of Patent: January 21, 2020
    Assignee: NIPPON STEEL CORPORATION
    Inventors: Yasuaki Tanaka, Toshiro Tomida, Kaori Kawano
  • Publication number: 20150079420
    Abstract: The steel for hot forming has the following composition in weight %: C: 0.10-0.25, Mn: 1.4-2.8, Si: ?1.0, Cr: ?1.0, Ti: ?0.05, Nb: ?0.05, V: ?0.1, Mo: ?0.1, Al: ?0.05, P: ?0.02, S: ?0.005, Ca: ?0.005, O: ?0.01, N: ?0.02, B: ?0.0004, the remainder being iron and unavoidable impurities. Also disclosed is a strip, sheet or blank produced with such a steel, a method for producing a hot formed product, such a product and the use thereof.
    Type: Application
    Filed: September 17, 2014
    Publication date: March 19, 2015
    Inventors: David Neal HANLON, Stefanus Matheus Cornelis VAN BOHEMEN
  • Publication number: 20150078956
    Abstract: A method forms a steel sheet having a tensile strength of 440 MPa or more into a press-formed part including a flange portion and other portions by press forming. The method includes: heating the steel sheet to a temperature of 400° C. to 700° C.; and press-forming the heated steel sheet by crash forming to obtain a press-formed part such that an average temperature difference among a flange portion and other portions of the press-formed part immediately after the formation is kept within 100° C. Geometric changes such as springback that occur in a panel can thus be suppressed, dimensional accuracy of the panel can be enhanced accordingly, and the desired mechanical properties can easily be obtained in the press-formed part.
    Type: Application
    Filed: March 4, 2013
    Publication date: March 19, 2015
    Inventors: Yoshikiyo Tamai, Yuichi Tokita, Toru Minote, Takeshi Fujita
  • Publication number: 20150064052
    Abstract: A method of forming a steel sheet having a tensile strength of 440 MPa or more into a press-formed part including a flange portion and other portions by press forming includes: heating the steel sheet to a temperature of 400° C. to 700° C.; and press-forming the heated steel sheet using draw forming to obtain a press-formed part, with the steel sheet being held at a press bottom dead point in the die for one second to five seconds. Geometric changes such as springback that occur in a panel can thus be suppressed, the dimensional accuracy of the panel can be enhanced, and the desired mechanical properties can easily be obtained in the press-formed part.
    Type: Application
    Filed: March 4, 2013
    Publication date: March 5, 2015
    Inventors: Yuichi Tokita, Yoshikiyo Tamai, Toru Minote, Takeshi Fujita
  • Patent number: 8961816
    Abstract: Getter devices based on powders of alloys particularly suitable for hydrogen and nitrogen sorption are described. Such alloys have a composition including zirconium, vanadium, titanium and, optionally, one or more elements selected from iron, chromium, manganese, cobalt, nickel and aluminum.
    Type: Grant
    Filed: May 13, 2013
    Date of Patent: February 24, 2015
    Assignee: Saes Getters S.p.A.
    Inventors: Alberto Coda, Alessandro Gallitognotta, Antonio Bonucci, Andrea Conte
  • Publication number: 20150044086
    Abstract: A steel wire rod or steel bar as hot-rolled, including: by mass %: C: 0.1 to 0.6%, Si: 0.01 to 1.5%, Mn: 0.05 to 2.5%, Al: 0.015 to 0.3%, and N: 0.0040 to 0.0150%, and P: limited to 0.035% or less and S: limited to 0.025% or less, and the balance substantially consisting of iron and unavoidable impurities, wherein a depth of d (mm) from the surface of the surface layer region with 20 HV 0.2 or more higher, relative to HV 0.2 that is the average hardness in the region where the depth from the surface is from sectional radius R×0.5 (mm) to the center satisfies the formula (1); the steel structure of the surface layer region has a ferrite fraction of 10% or less by area ratio, with the balance being one or two or more of martensite, bainite and pearlite; the steel structure where the depth from the surface is from the sectional radius R×0.
    Type: Application
    Filed: April 1, 2013
    Publication date: February 12, 2015
    Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Kei Miyanishi, Atsushi Monden, Shingo Yamasaki, Shunta Homma
  • Publication number: 20150034049
    Abstract: A rolled steel bar for hot forging consisting, by mass percent, of C: 0.25-0.50%, Si: 0.40-1.0%, Mn: 1.0-1.6%, S: 0.005-0.035%, Al: 0.005-0.050%, V: 0.10-0.30%, and N: 0.005-0.030%, and the balance of Fe and impurities, i.e., P: 0.035% or less and O: 0.0030% or less, wherein Fn1=C+Si/10+Mn/5+5Cr/22+1.65V?5S/7 is 0.90 to 1.20. The predicted maximum width of nonmetallic inclusions at the time when a cumulative distribution function obtained by extreme value statistical processing by taking the width of nonmetallic inclusion in an R1/2 part of a longitudinal cross section of the steel bar as W (mm) is 99.99% is 100 mm or narrower. The number density of sulfides each having a circle-equivalent diameter of 0.3 to 1.0 mm observed per unit area of the R1/2 part of a transverse cross section of the steel bar is 500 pieces/mm2 or higher.
    Type: Application
    Filed: February 5, 2013
    Publication date: February 5, 2015
    Inventors: Naoki Matsui, Masashi Higashida, Hitoshi Matsumoto, Yutaka Neishi, Talzo Makino, Kouji Morita, Yoshihiro Tanimura, Naoyuki Sashima, Toshimasa Itou
  • Publication number: 20150023835
    Abstract: Martensitic steel compositions and methods of production thereof are provided. More specifically, a martensitic steel having tensile strengths ranging from 1700 to 2200 MPa are provided. Most specifically, the present invention provides thin gage (thickness of ?1 mm) ultra high strength steel with an ultimate tensile strength of 1700 to 2200 MPa and methods of production thereof.
    Type: Application
    Filed: November 28, 2012
    Publication date: January 22, 2015
    Inventors: Rongjie Song, Narayan S. Pottore
  • Publication number: 20150023834
    Abstract: A hot-rolled steel sheet including, in terms of % by mass, 0.030% to 0.120% of C, 1.20% or less of Si, 1.00% to 3.00% of Mn, 0.01% to 0.70% of Al, 0.05% to 0.20% of Ti, 0.01% to 0.10% of Nb, 0.020% or less of P, 0.010% or less of S, and 0.005% or less of N, and a balance consisting of Fe and impurities, in which 0.106?(C %-Ti %*12/48-Nb %*12/93)>0.012 is satisfied; a pole density of {112}(110) at a position of ¼ plate thickness is 5.7 or less; an aspect ratio (long axis/short axis) of prior austenite grains is 5.3 or less; a density of (Ti, Nb)C precipitates having a size of 20 nm or less is 109 pieces/mm3 or more; a yield ratio YR, which is the ratio of a tensile strength to a yield stress, is 0.80 or more; and a tensile strength is 590 MPa or more.
    Type: Application
    Filed: January 8, 2013
    Publication date: January 22, 2015
    Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Eisaku Sakurada, Kunio Hayashi, Koichi Sato, Shunji Hiwatashi
  • Publication number: 20150017052
    Abstract: A method for joining metal components by welding includes welding a first component to a second component. At least one of the components is a nitrogen-containing component, and titanium is added to at least one of the components before the welding step.
    Type: Application
    Filed: November 15, 2012
    Publication date: January 15, 2015
    Inventor: Mario Matic
  • Patent number: 8920713
    Abstract: A steel for a welded structure includes the following composition: by mass %, C at a C content [C] of 0.010 to 0.065%; Si at a Si content [Si] of 0.05 to 0.20%; Mn at a Mn content [Mn] of 1.52 to 2.70%; Ni at a Ni content [Ni] of 0.10% to 1.50%; Ti at a Ti content [Ti] of 0.005 to 0.015%; O at an O content [O] of 0.0010 to 0.0045%; N at a N content [N] of 0.002 to 0.006%; Mg at a Mg content [Mg] of 0.0003 to 0.003%; Ca at a Ca content [Ca] of 0.0003 to 0.003%; and the balance composed of Fe and unavoidable impurities. A steel component parameter PCTOD is 0.065% or less, and a steel component hardness parameter CeqH is 0.235% or less.
    Type: Grant
    Filed: May 21, 2010
    Date of Patent: December 30, 2014
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Yoshiyuki Watanabe, Kazuhiro Fukunaga, Akihiko Kojima, Ryuji Uemori, Rikio Chijiiwa
  • Publication number: 20140314616
    Abstract: Provided is a hot-rolled steel sheet having a composition containing 0.04 mass percent to 0.20 mass percent C, 0.7 mass percent to 2.3 mass percent Si, 0.8 mass percent to 2.8 mass percent Mn, 0.1 mass percent or less P, 0.01 mass percent or less S, 0.1 mass percent or less Al, and 0.008 mass percent or less N, the remainder being Fe and inevitable impurities. Internal oxides containing one or more selected from the group consisting of Si, Mn, and Fe are present at grain boundaries and in grains in a base metal. The internal oxides present at the grain boundaries in the base metal are located within 5 ?m from the surface of the base metal. The difference between the depths at which the internal oxides are formed in the cross direction of the steel sheet is 2 ?m or less.
    Type: Application
    Filed: November 2, 2012
    Publication date: October 23, 2014
    Applicant: JFE STEEL CORPORATION
    Inventors: Mai Miyata, Yoshitsugu Suzuki, Yasunobu Nagataki, Yoshiyasu Kawasaki, Hirokazu Sugihara
  • Patent number: 8840734
    Abstract: A non-oriented electrical steel sheet, containing: C: 0.01 mass % or less; Si: 1.0 mass % or more and 3.5 mass % or less; Al: 0.1 mass % or more and 3.0 mass % or less; Mn: 0.1 mass % or more and 2.0 mass % or less; P: 0.1 mass % or less; S: 0.005 mass % or less; Ti: 0.001 mass % or more and 0.01 mass % or less; N: 0.005 mass % or less; and Y: more than 0.05 mass % and 0.2 mass % or less, with the balance being iron and inevitable impurities.
    Type: Grant
    Filed: February 5, 2013
    Date of Patent: September 23, 2014
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Masafumi Miyazaki, Hideaki Yamamura, Kazuto Kawakami
  • Patent number: 8821652
    Abstract: Steel for induction hardening wherein coarsening of austenite crystal grains can be prevented even at a high temperature of over 1100° C. such as which occurs at projecting parts of steel parts at the time of induction hardening, the steel for induction hardening characterized by containing, by mass %, C: 0.35 to 0.6%, Si: 0.01 to 1%, Mn: 0.2 to 1.8%, S: 0.001 to 0.15%, Al: 0.001 to 1%, Ti: 0.05 to 0.2%, and Nb: 0.001 to 0.04%, restricting N: 0.0060% or less, P: 0.025% or less, and O: 0.0025% or less, satisfying Nb/Ti?0.015, and having a balance of iron and unavoidable impurities.
    Type: Grant
    Filed: October 7, 2010
    Date of Patent: September 2, 2014
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Shuji Kozawa, Manabu Kubota
  • Patent number: 8801874
    Abstract: A steel plate for line pipes containing, in terms of % by weight, C: 0.02 to 0.06%, Si: 0.5% or less, Mn: 0.8 to 1.6%, P: 0.008% or less, S: 0.0008% or less, Al: 0.08% or less, Nb: 0.005 to 0.035%, Ti: 0.005 to 0.025%, and Ca: 0.0005 to 0.0035%, and optionally contains one or more of Cu: 0.5% or less, Ni: 1% or less, Cr: 0.5% or less, Mo: 0.5% or less and V: 0.1% or less, and has a CP value of 0.95 or less represented by CP=4.46C(%)+2.37Mn(%)/6+{1.18Cr(%)+1.95Mo(%)+1.74V(%)}/5+{1.74Cu(%)+1.7Ni(%)}/15+22.36P(%), and a Ceq value of 0.30 or more represented by Ceq=C(%)+Mn(%)/6+{Cr(%)+Mo(%)+V(%)}/5 +{Cu(%)+Ni(%)}/15.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: August 12, 2014
    Assignee: JFE Steel Corporation
    Inventors: Nobuyuki Ishikawa, Makoto Suzuki, Tomohiro Matsushima, Akiyoshi Tsuji, Shinichi Kakihara, Nobuo Shikanai, Yutaka Awajiya
  • Patent number: 8802241
    Abstract: In an embodiment of a steel sheet having high Young's modulus, the steel can include in terms of mass %, e.g., C: 0.0005 to 0.30%, Si: 2.3% or less, Mn: 2.7 to 5.0%, P: 0.15% or less, 0.015% or less, Mo: 0.15 to 1.5%, B: 0.0006 to 0.01%, and Al: 0.15% or less, with the remainder being Fe and unavoidable impurities. One or both of {110}<223> pole density and {110}<111> pole density in the ? sheet thickness layer can be 10 or more, and a Young's modulus in a rolling direction can be more than 230 GPa. Other embodiments can include, e.g., Mn: 0.1 to 5.0%, N: 0.01% or less, and one or more of Mo: 0.005 to 1.5%, Nb: 0.005 to 0.20%, Ti: at least 48/14×N (mass %) and 0.2% or less, and B: 0.0001 to 0.01%, at a total content of 0.015 to 1.91 mass %.
    Type: Grant
    Filed: September 26, 2011
    Date of Patent: August 12, 2014
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Natsuko Sugiura, Naoki Yoshinaga, Shunji Hiwatashi, Manabu Takahashi, Koji Hanya, Nobuyoshi Uno, Ryoichi Kanno, Akihiro Miyasaka, Takehide Senuma
  • Patent number: 8801872
    Abstract: A case hardened gear steel having enhanced core fracture toughness includes by weight percent about 16.3Co, 7.5Ni, 3.5Cr, 1.75Mo, 0.2W, 0.11C, 0.03Ti, and 0.02V and the balance Fe, characterized as a predominantly lath martensitic microstructure essentially free of topologically close-packed (TCP) phases and carburized to include fine M2C carbides to provide a case hardness of at least about 62 HRC and a core toughness of at least about 50 ksi?in.
    Type: Grant
    Filed: August 20, 2008
    Date of Patent: August 12, 2014
    Assignee: QuesTek Innovations, LLC
    Inventors: James A. Wright, Jason Sebastian
  • Patent number: 8795443
    Abstract: A steel sheet undergone precipitation strengthening and refinement in crystal grain size by containing at least one element of 0.005% to 0.05% of Nb, 0.005% to 0.05% of Ti, and 0.0005% to 0.005% of B as a chemical composition is produced through continuous annealing. A steel containing at least one element of Nb, Ti, and B is hot rolled, cooled at a cooling rate of 40° C./s or less, and coiled at 550° C. or higher to facilitate precipitation of cementite after recrystallization annealing. As a result, a steel sheet for a can having a tensile strength of 450 to 550 MPa, a total elongation of 20% or more, and a yield elongation of 5% or less is produced.
    Type: Grant
    Filed: April 14, 2008
    Date of Patent: August 5, 2014
    Assignee: JFE Steel Corporation
    Inventors: Yuka Nishihara, Katsumi Kojima, Hiroki Iwasa, Yoshun Yamashita
  • Patent number: 8764918
    Abstract: The present invention provides high strength steel pipe for line pipe superior in low temperature toughness suppressed in drop of toughness of the HAZ and a method of production of the same, more particularly high strength steel plate for line pipe used as a material for high strength steel pipe for line pipe and a method of production of the same, in particular high strength steel pipe for line pipe superior in low temperature toughness characterized in that the chemical compositions of the base metal is, by mass %, C: 0.020 to 0.080%, Si: 0.01 to 0.50%, Mo: 0.01 to 0.15%, Al: 0.0005 to 0.030%, and Nb: 0.0001 to 0.030% contained in a range of C+0.25Si+0.1Mo+Al+Nb: 0.100% or less and the mixture of austenite and martensite present along prior austenite grain boundaries of the reheated part of the heat affected zone has a width of 10 ?m or less and a length of 50 ?m or less.
    Type: Grant
    Filed: July 2, 2007
    Date of Patent: July 1, 2014
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Takuya Hara, Hitoshi Asahi, Yoshio Terada
  • Patent number: 8747577
    Abstract: High yield ratio high-strength hot rolled thin steel sheet superior in weldability and ductility comprising, by mass %, C: over 0.030 to less than 0.10%, Si: 0.30 to 0.80%, Mn: 1.7 to 3.2%, P: 0.001 to 0.02%, S: 0.0001 to 0.006%, Al: 0.060% or less, N: 0.0001 to 0.0070%, containing further Ti: 0.01 to 0.055%, Nb: 0.012 to 0.055%, Mo: 0.07 to 0.55%, B: 0.0005 to 0.0040%, and simultaneously satisfying 1.1?14×Ti(%)+20×Nb(%)+3×Mo(%)+300×B(%)?3.7, the balance comprised of iron and unavoidable impurities, and having a yield ratio of 0.64 to less than 0.92, a TS×El1/2 of 3320 or more, an YR×TS×El1/2 of 2320 or more, and a maximum tensile strength (TS) of 780 MPa or more.
    Type: Grant
    Filed: June 3, 2011
    Date of Patent: June 10, 2014
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Naoki Yoshinaga, Shunji Hiwatashi, Yasuharu Sakuma, Atsushi Itami
  • Patent number: 8747576
    Abstract: This high-carbon pearlitic steel rail having excellent ductility, includes: in terms of percent by mass, C: more than 0.85% to 1.40%; Si: 0.10% to 2.00%; Mn: 0.10% to 2.00%; Ti: 0.001% to 0.01%; V: 0.005% to 0.20%; and N: less than 0.0040%, with the balance being Fe and inevitable impurities, wherein contents of Ti and V fulfill the following formula (1), and a rail head portion has a pearlite structure.
    Type: Grant
    Filed: April 14, 2010
    Date of Patent: June 10, 2014
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Teruhisa Miyazaki, Masaharu Ueda, Suguru Yoshida
  • Patent number: 8741216
    Abstract: Disclosed is steel for a leaf spring with high fatigue strength containing, in mass percentage, C: 0.40 to 0.54%, Si: 0.40 to 0.90%, Mn: 0.40 to 1.20%, Cr: 0.70 to 1.50%, Ti: 0.070 to 0.150%, B: 0.0005 to 0.0050%, N: 0.0100% or less, and a remainder composed of Fe and impurity elements. Also disclosed is a high fatigue-strength leaf spring part obtained by forming the steel. The steel for a leaf spring is prepared to have a Ti content and a N content to satisfy a relation of Ti/N?10. Preferably, the leaf spring part is subjected to a shot peening treatment in a temperature range of the room temperature through 400° C. with a bending stress of 650 to 1900 MPa being applied to it.
    Type: Grant
    Filed: December 15, 2010
    Date of Patent: June 3, 2014
    Assignee: NHK Spring Co., Ltd.
    Inventors: Atsushi Sugimoto, Kiyoshi Kurimoto, Akira Tange, Yurika Goto, Mamoru Akeda
  • Publication number: 20140141280
    Abstract: Provided is a high-strength steel sheet having good warm press formability and excellent strength and ductility after warm press forming, and a method for manufacturing such. The high-strength steel sheet has a tensile strength at room temperature not less than 780 MPa, a yield stress at a heating temperature range of 400° C. to 700° C. not more than 80% of the yield stress at room temperature, total elongation at the heating temperature range not less than 1.1 times the total elongation at room temperature, yield stress and total elongation after the steel sheet is heated to the heating temperature range, subjected to a strain of not more than 20%, and cooled from the heating temperature to room temperature, not less than 70% of the yield stress and total elongation, respectively, at room temperature before the heating.
    Type: Application
    Filed: July 11, 2012
    Publication date: May 22, 2014
    Applicant: JFE Steel Corporation
    Inventors: Noriaki Kosaka, Yoshimasa Funakawa, Masato Shigemi, Hidekazu Okubo
  • Patent number: 8721807
    Abstract: A method of making a hypereutectoid, head-hardened steel rail is provided that includes a step of head hardening a steel rail having a composition containing 0.86-1.00 wt % carbon, 0.40-0.75 wt % manganese, 0.40-1.00 wt % silicon, 0.05-0.15 wt % vanadium, 0.015-0.030 wt % titanium, and sufficient nitrogen to react with the titanium to form titanium nitride. Head hardening is conducted at a cooling rate that, if plotted on a graph with xy-coordinates with the x-axis representing cooling time in seconds, and the y-axis representing temperature in Celsius of the surface of the head of the steel rail, is maintained in a region between an upper cooling rate boundary plot defined by an upper line connecting xy-coordinates (0 s, 775° C.), (20 s, 670° C.), and (110 s, 550° C.) and a lower cooling rate boundary plot defined by a lower line connecting xy-coordinates (0 s, 750° C.), (20 s, 610° C.), and (110 s, 500° C.).
    Type: Grant
    Filed: August 13, 2012
    Date of Patent: May 13, 2014
    Assignee: Arcelormittal Investigacion Y Desarrollo, S.L.
    Inventors: Bruce L. Bramfitt, Fred B. Fletcher, John A. Davis, Jr.
  • Patent number: 8709336
    Abstract: The invention concerns a method for making an abrasion resistant steel plate having a chemical composition comprising: 0.35%?C?0.8%, 0%?Si?2%, 0%?Al?2%, 0.35%?Si+Al?2%, 0%?Mn?2.5%, 0%?Ni?5%, 0%?Cr?5%, 0%?Mo?0.50%, 0%?W?1.00%, 0.1%?Mo+W/2?0.50%, 0%?B?0.02%, 0%?Ti?2%, 0%?Zr?4%, 0.05%?Ti+Zr/2?2%, 0%?S?0.15%, N<0.03%; optionally from 0% to 1.5% of Cu; optionally Nb, Ta or V with Nb/2+Ta/4+V?0.5%; optionally less than 0.1% of Se, Te, Ca, Bi or Pb; the rest being iron and impurities; the composition satisfying: 0.1%?C*=C?Ti/4?Zr/8+7×N/8?0.55% and 1.05×Mn+0.54×Ni+0.50×Cr+0.3×(Mo+W/2)1/2+K>1.8, with K=0.5 if B?0.0005% and K=0 if B<0.0005% and Ti+Zr/2?7×N/2?0.05%; hardening after austenitization while cooling at a speed>0.5° C./s between a temperature>AC3 and ranging between T=800?270×C*?90×Mn?37×Ni?70×Cr?83×(Mo+W/2) and T?50° C.; then at a core speed Vr<115×ep?1.7 between T and 100° C., (ep=plate thickness in mm); cooling down to room temperature. The invention also concerns the resulting plate.
    Type: Grant
    Filed: June 17, 2008
    Date of Patent: April 29, 2014
    Assignee: Industeel Creusot
    Inventors: Jean Beguinot, Jean-Georges Brisson
  • Patent number: 8691030
    Abstract: The present application describes a steel composition that provides enhanced corrosion resistance. This steel composition includes one of vanadium in an amount of 1 wt % to 9 wt %, titanium in an amount of about 1 wt % to 9 wt %, and a combination of vanadium and titanium in an amount of 1 wt % to about 9 wt %. In addition, the steel composition includes carbon in an amount of 0.03 wt % to about 0.45 wt %, manganese in an amount up to 2 wt % and silicon in an amount up to 0.45 wt %. In one embodiment, the steel composition includes a microstructure of one of the following: ferrite, martensite, tempered martensite, dual phase ferrite and martensite, and dual phase ferrite and tempered martensite. Further, the present application describes a method for processing the steel composition and use of equipment such as oil country tubular goods, fabricated with the steel composition.
    Type: Grant
    Filed: May 2, 2008
    Date of Patent: April 8, 2014
    Assignee: ExxonMobil Upstream Research Company
    Inventors: Dylan V. Pugh, Joseph C. Bondos, Shiun Ling, Raghavan Ayer, Shalawn K. Jackson, Jayoung Koo, Swarupa S. Bangaru
  • Patent number: 8668784
    Abstract: A steel for a welded structure includes the following composition: by mass %, C at a C content [C] of 0.015 to 0.045%; Si at a Si content [Si] of 0.05 to 0.20%; Mn at a Mn content [Mn] of 1.5 to 2.0%; Ni at a Ni content [Ni] of 0.10 to 1.50%; Ti at a Ti content [Ti] of 0.005 to 0.015%; O at an O content [O] of 0.0015 to 0.0035%; and N at a N content [N] of 0.002 to 0.006%, and a balance composed of Fe and unavoidable impurities. In the steel for a welded structure, the P content [P] is limited to 0.008% or less, the S content [S] is limited to 0.005% or less, the Al content [Al] is limited to 0.004% or less, the Nb content [Nb] is limited to 0.005% or less, the Cu content [Cu] is limited to 0.24% or less, the V content [V] is limited to 0.020% or less, and a steel composition parameter PCTOD is 0.065% or less, and a steel composition hardness parameter CeqH is 0.235% or less.
    Type: Grant
    Filed: May 18, 2010
    Date of Patent: March 11, 2014
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Yoshiyuki Watanabe, Kazuhiro Fukunaga, Akihiko Kojima, Ryuji Uemori, Rikio Chijiiwa
  • Patent number: 8657970
    Abstract: This hot-rolled steel sheet contains, in terms of mass %, C: 0.015% or more to less than 0.040%; Si: less than 0.05%; Mn: 0.9% or more to 1.8% or less; P: less than 0.02%; S: less than 0.01%; Al: less than 0.1%; N: less than 0.006%; and Ti: 0.05% or more to less than 0.11%, with the remainder being Fe and inevitable impurities, wherein Ti/C is in a range of 2.5 or more to less than 3.5, Nb, Zr, V, Cr, Mo, B and W are not included, a microstructure includes a mixed microstructure of polygonal ferrite and quasi-polygonal ferrite in a proportion of greater than 96%, a maximum tensile strength is 520 MPa or more and less than 720 MPa, an aging index AI is more than 15 MPa, a product of a hole expansion ratio (?) % and a total elongation (El) % is 2350 or more, and a fatigue limit is 200 MPa or more.
    Type: Grant
    Filed: November 12, 2008
    Date of Patent: February 25, 2014
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Naoki Yoshinaga, Masafumi Azuma, Yasuharu Sakuma, Naoki Maruyama
  • Publication number: 20140044987
    Abstract: A steel sheet for a hot stamping member contains, as a chemical composition, 0.10 mass % to 0.35 mass % of C; 0.01 mass % to 1.0 mass % of Si; 0.3 mass % to 2.3 mass % of Mn; 0.01 mass % to 0.5 mass % of Al; limited to 0.03 mass % or less of P; limited to 0.02 mass % or less of S; limited to 0.1 mass % or less of N; and a balance consisting of Fe and unavoidable impurities, in which a standard deviation of diameters of iron carbides which are contained in a region from a surface to a ¼ thickness position of the steel sheet is less than or equal to 0.8 ?m.
    Type: Application
    Filed: April 26, 2012
    Publication date: February 13, 2014
    Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Hiroyuki Tanahashi, Jun Maki
  • Patent number: 8647449
    Abstract: Disclosed herein are iron-based alloys having a microstructure comprising a fine-grained ferritic matrix and having a 60+ Rockwell C surface, wherein the ferritic matrix comprises <10 ?m carbide precipitates. Also disclosed are methods of welding comprising forming a crack free hardbanding weld overlay coating with such an iron-based alloy. Also disclosed are families of alloys capable of forming crack-free weld overlays after multiple welding passes.
    Type: Grant
    Filed: March 6, 2012
    Date of Patent: February 11, 2014
    Assignee: Scoperta, Inc.
    Inventors: Justin Lee Cheney, John Hamilton Madok
  • Patent number: 8623154
    Abstract: An electron-beam welded joint including, by mass %, C: 0.02% to 0.1%, Si: 0.03% to 0.30%, Mn: 1.5% to 2.5%, Ti: 0.005 to 0.015%, N: 0.0020 to 0.0060%, O: 0.0010% to 0.0035%, Nb: 0% to 0.020%, V: 0% to 0.030%, Cr: 0% to 0.50%, Mo: 0% to 0.50%, Cu: 0% to 0.25%, Ni: 0% to 0.50%, B: 0% to 0.0030%, S: limited to 0.010% or less, P: limited to 0.015% or less, Al: limited to 0.004% or less, and a balance consisting of iron and unavoidable impurities, wherein an index value CeEB is 0.49% to 0.60%, a number of oxides having an equivalent circle diameter of 1.0 ?m or more is 20 pieces/mm2 or less, and a number of oxides having an equivalent circle diameter of 0.05 ?m or more and less than 0.5 ?m is 1×103 pieces/mm2 to 1×105 pieces/mm2 at a thickness center portion.
    Type: Grant
    Filed: October 27, 2011
    Date of Patent: January 7, 2014
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Ryuichi Honma, Ryuji Uemori, Tadashi Ishikawa, Akihiko Kojima, Manabu Hoshino
  • Publication number: 20130323112
    Abstract: In a hot-rolled sheet, an average value of pole densities of an orientation group {100}<011> to {223}<110>, which is represented by an arithmetic mean of pole densities of orientations {100}<011>, {116}<110>, {114}<110>, {112}<110>, and {223}<110> in a thickness center portion of a thickness range of ? to ? from a surface of the steel sheet, is 1.0 to 6.5 and a pole density of a crystal orientation {332}<113> is 1.0 to 5.0; and a Lankford value rC in a direction perpendicular to a rolling direction is 0.70 to 1.10 and a Lankford value r30 in a direction that forms 30° with respect to the rolling direction is 0.70 to 1.10.
    Type: Application
    Filed: March 5, 2012
    Publication date: December 5, 2013
    Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Riki Okamoto, Nobuhiro Fujita, Manabu Takahashi, Kunio Hayashi, Tetsuo Kishimoto, Kazuaki Nakano, Takeshi Yamamoto
  • Patent number: 8562762
    Abstract: The present invention provides high strength hot rolled steel plate for line-pipes superior in low temperature toughness, and a method of production of the same, containing, by mass %, C: 0.01 to 0.1%, Si: 0.05 to 0.5%, Mn: 1 to 2%, P: ?0.03%, S: ?0.005%, O: ?0.003%, Al: 0.005 to 0.05%, N: 0.0015 to 0.006%, Nb: 0.005 to 0.08%, and Ti: 0.005 to 0.02%, where N?14/48×Ti>0% and Nb?93/14×(N?14/48×Ti)>0.005%, and a balance of Fe and unavoidable impurities, said steel plate characterized in that its microstructure is a continuously cooled transformed structure, a reflected X-ray intensity ratio {211}/{111} of the {211} plane and {111} plane parallel to the plate surface in the texture at the center of plate thickness is 1.1 or more, and an in-grain precipitate density of the precipitates of Nb and/or Ti carbonitrides is 1017 to 1018/cm3.
    Type: Grant
    Filed: February 29, 2008
    Date of Patent: October 22, 2013
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Tatsuo Yokoi, Masanori Minagawa, Takuya Hara, Osamu Yoshida, Hiroshi Abe
  • Publication number: 20130272914
    Abstract: The steel wire material of the present invention contains 0.05 to 1.2% of C (mass %; same for the chemical components hereafter), 0.01 to 0.5% of Si, 0.1 to 1.5% of Mn, 0.02% or less (but not 0%) of P, 0.02% or less (but not 0%) of S, and 0.005% or less (but not 0%) of N, with the balance being iron and inevitable impurities. The wire material has a scale layer that is no thicker than 7.0 ?m or less. The scale layer has an FeO percentage of 30 to 80 vol % and an Fe2SiO4 percentage of less than 0.1 vol %. The scale layer that is formed will not peel when cooled after hot rolling or during storage and transport, but will easily peel during mechanical descaling.
    Type: Application
    Filed: January 6, 2012
    Publication date: October 17, 2013
    Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel. Ltd.)
    Inventors: Mikako Takeda, Shohei Nakakubo, Kazuhiko Kirihara, Masayuki Endo
  • Publication number: 20130272913
    Abstract: This steel wire material contains 0.05%-1.2% C (“%” means “% by mass,” same hereinafter for chemical components.), 0.01%-0.7% Si, 0.1%-1.5% Mn, 0.02% max. P (not including 0%), 0.02% max. S (not including 0%), and 0.005% max. N (not including 0%), with the remainder being iron and unavoidable impurities. The steel wire material has a scale 6.0-20 ?m thick and holes of an equivalent circle diameter of 1 ?m max. in said scale that occupy 10% by area max. Said scale does not detach in the cooling process after hot rolling or during storage or transportation but can readily detach during mechanical descaling.
    Type: Application
    Filed: December 9, 2011
    Publication date: October 17, 2013
    Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
    Inventors: Mikako Takeda, Shohei Nakakubo, Kazuhiko Kirihara, Masayuki Endo
  • Patent number: 8535459
    Abstract: The present invention provides a steel material for hardening, including chemical components, by mass %, of: C: 0.15 to 0.60%; Si: 0.01 to 1.5%; Mn: 0.05 to 2.5%; P: 0.005 to 0.20%; S: 0.001 to 0.35%; Al: over 0.06 to 0.3%; and total N: 0.006 to 0.03%, with a balance including Fe and inevitable impurities including B of not more than 0.0004%, in which a hardness R at a position 5 mm away from a quenching end measured through a Jominy-type end-quenching method specified in JIS G 0561, and a calculation hardness H at a position 4.763 mm away from the quenching end satisfy the following Equation (1). H×0.948?R?H×1.
    Type: Grant
    Filed: May 17, 2011
    Date of Patent: September 17, 2013
    Assignee: Nippon Steel & Sumitomo Metal Corporation
    Inventors: Kei Miyanishi, Manabu Kubota, Shuji Kozawa
  • Patent number: 8518191
    Abstract: It is an object of the present invention to provide a high strength cold-rolled steel sheet, which has superior bake hardenability, aging resistance at room temperature and secondary work embrittlement resistance, and a method for manufacturing the same. The steel sheet has a grain size of ASTM No. of 9 or more after annealing, a BH of 30 MPa or more, an AI of 30 MPa or less, and a tensile strength of 340˜390 MPa through appropriate control of solute elements in steel by addition of a small amount of Ti, addition of Al and Mo, and control of manufacturing conditions, and refinement of crystal grains after annealing. The cold-rolled steel sheet and the galvannealed steel sheet produced using the cold-rolled steel sheet have the superior bake hardenability, aging resistance at room temperature, and secondary work embrittlement resistance.
    Type: Grant
    Filed: January 27, 2012
    Date of Patent: August 27, 2013
    Assignee: POSCO
    Inventor: Seong-Ho Han
  • Publication number: 20130153091
    Abstract: A hot-rolled steel sheet has an average value of the X-ray random intensity ratio of a {100} <011> to {223} <110> orientation group at least in a sheet thickness central portion that is in a sheet thickness range of ? to ? from a steel sheet surface of 1.0 to 6.0, an X-ray random intensity ratio of a {332} <113> crystal orientation of 1.0 to 5.0, rC which is an r value in a direction perpendicular to a rolling direction of 0.70 to 1.10, and r30 which is an r value in a direction that forms an angle of 30° with respect to the rolling direction of 0.70 to 1.10.
    Type: Application
    Filed: July 27, 2011
    Publication date: June 20, 2013
    Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATION
    Inventors: Nobuhiro Fujita, Kunio Hayashi, Riki Okamoto, Manabu Takahashi, Tetsuo Kishimoto, Hiroshi Yoshida
  • Publication number: 20130076017
    Abstract: Hot-rolled high-strength steel elongated structural members and method of making same are disclosed by hot-rolling high-strength steel having a specific chemical composition to provide the members of desired geometrical configuration including a thin web with opposed thicker flanges extending therefrom to increase the load bearing capacity of the members.
    Type: Application
    Filed: September 23, 2011
    Publication date: March 28, 2013
    Applicant: CONSOLIDATED METAL PRODUCTS, INC.
    Inventor: Hugh M. Gallagher, JR.
  • Patent number: 8388770
    Abstract: A cold-rolled steel sheet has a composition containing, by mass percent, 0.0040% or less of C, 0.02% or less of Si, 0.14% to 0.25% of Mn, 0.020% or less of P, 0.015% or less of S, 0.0040% or less of N, 0.020% to 0.070% of Al, 0.005% to 0.030% of Nb, 0.005% to 0.030% of Ti, (0.0003% to 0.0010% of the equivalent amount of solid solution B (from which the amount of B forming BN has been subtracted)), and the balance composed of Fe and inevitable impurities, wherein even when the rolling reduction of cold rolling is 85% or less, the average grain size of a ferrite structure is reliably 12.0 ?m or less, and the relationship ?0.20??r?0.20 can be reliably satisfied and which has an excellent earing property.
    Type: Grant
    Filed: March 13, 2007
    Date of Patent: March 5, 2013
    Assignee: JFE Steel Corporation
    Inventors: Nobuko Mineji, Eiko Yasuhara, Reiko Sugihara, Tadashi Inoue
  • Patent number: 8361248
    Abstract: The present invention provides a high strength steel having unprecedentedly superior CTOD (fracture toughness) properties satisfying not only the CTOD properties of the FL zone at ?60° C., but also the CTOD properties of the ICHAZ zone in small and medium heat input multilayer welding, etc.; and a method of production of the same. The steel of the present invention is steel superior in CTOD properties of the heat-affected zone containing, by mass %, C: 0.015 to 0.045%, Si: 0.05 to 0.2%, Mn: 1.5 to 2.0%, Cu: 0.25 to 0.5%, Ni: 0.7 to 1.5%, P: 0.008% or less, S: 0.005% or less, Al: 0.004% or less, Ti: 0.005 to 0.015%, Nb: 0.005% or less, O: 0.0015 to 0.0035%, and N: 0.002 to 0.006%, PCTOD: 0.065 or less, CeqH: 0.235 or less and the balance consisting of Fe and unavoidable impurities.
    Type: Grant
    Filed: December 4, 2008
    Date of Patent: January 29, 2013
    Assignee: Nippon Steel Corporation
    Inventors: Rikio Chijiiwa, Ryuji Uemori, Yoshiyuki Watanabe, Kazuhiro Fukunaga, Akihiko Kojima, Yoshihide Nagai
  • Publication number: 20130022833
    Abstract: A silicon steel sheet formed from a silicon steel alloy composition includes, in parts by weight, iron, carbon present in an amount of from about 0.002 to about 0.06, silicon present in an amount of from about 1.5 to about 4.0, aluminum present in an amount of from about 0.1 to 1.0, titanium present in an amount of less than or equal to about 0.03, vanadium present in an amount of less than or equal to about 0.005, and cobalt present in an amount of from about 0.001 to about 5.0 based on 100 parts by weight of the composition. Neither niobium nor zirconium is present in the composition. A silicon steel sheet system including the silicon steel sheet and a coating disposed thereon, and an electromagnetic machine having a magnetic core including a plurality of sheets stacked adjacent one another are also disclosed.
    Type: Application
    Filed: July 22, 2011
    Publication date: January 24, 2013
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventor: Shekhar G. Wakade
  • Publication number: 20120279616
    Abstract: The present invention provides a steel material for hardening, including chemical components, by mass %, of: C: 0.15 to 0.60%; Si: 0.01 to 1.5%; Mn: 0.05 to 2.5%; P: 0.005 to 0.20%; S: 0.001 to 0.35%; Al: over 0.06 to 0.3%; and total N: 0.006 to 0.03%, with a balance including Fe and inevitable impurities including B of not more than 0.0004%, in which a hardness R at a position 5 mm away from a quenching end measured through a Jominy-type end-quenching method specified in JIS G 0561, and a calculation hardness H at a position 4.763 mm away from the quenching end satisfy the following Equation (1). H×0.948?R?H×1.
    Type: Application
    Filed: May 17, 2011
    Publication date: November 8, 2012
    Inventors: Kei Miyanishi, Manabu Kubota, Shuji Kozawa
  • Patent number: 8303734
    Abstract: The present invention provides a high strength thick steel material excellent in toughness and weldability reduced in amount of C and amount of N, containing suitable amounts of Si, Mn, Nb, Ti, B, and O, having contents of C and Nb satisfying C—Nb/7.74?0.004, having a density of Ti-containing oxides of a particle size of 0.05 to 10 ?m of 30 to 300/mm2, and having a density of Ti-containing oxides of a particle size over 10 ?m of 10/mm2 or less, produced by treating steel by preliminary deoxidation to adjust the dissolved oxygen to 0.005 to 0.015 mass %, then adding Ti and, furthermore, vacuum degassing the steel for 30 minutes or more, smelting it, then continuously casting it to produce a steel slab or billet, heating the steel slab or billet to 1100 to 1350° C., hot rolling the slab or billet to a thickness of 40 to 150 mm, then cooling it.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: November 6, 2012
    Assignee: Nippon Steel Corporation
    Inventors: Suguru Yoshida, Hiroshi Kita, Teruhisa Okumura, Hirokazu Sugiyama, Teruyuki Wakatsuki
  • Patent number: 8257647
    Abstract: A micro-alloyed low carbon steel strip is obtained by hot rolling at temperature of the pre-strip never lower than 900° C. and shows such metallurgical and geometrical features, as well as relating to planarity and deformability, to render the same suitable to obtain structures of low weight and good mechanical resistance, thus being able for use in replacement of cold rolled strips for the production of finished stamped or cut pieces. Said steel strip, having thickness>0.7 mm, has a ratio yield load/breaking load>70%, a fine grain structure better than grade 10 of ASTM E 112 standard in a percentage higher than 90% of the whole structure and a ratio between breaking limit under strain and yield point ?/RPo.2>90%.
    Type: Grant
    Filed: January 26, 2006
    Date of Patent: September 4, 2012
    Inventor: Giovanni Arvedi
  • Publication number: 20120193000
    Abstract: Steel for induction hardening wherein coarsening of austenite crystal grains can be prevented even at a high temperature of over 1100° C. such as which occurs at projecting parts of steel parts at the time of induction hardening, the steel for induction hardening characterized by containing, by mass %, C: 0.35 to 0.6%, Si: 0.01 to 1%, Mn: 0.2 to 1.8%, S: 0.001 to 0.15%, Al: 0.001 to 1%, Ti: 0.05 to 0.2%, and Nb: 0.001 to 0.04%, restricting N: 0.0060% or less, P: 0.025% or less, and O: 0.0025% or less, satisfying Nb/Ti?0.015, and having a balance of iron and unavoidable impurities.
    Type: Application
    Filed: October 7, 2010
    Publication date: August 2, 2012
    Applicant: Nippon Steel Corporation
    Inventors: Shuji Kozawa, Manabu Kubota
  • Patent number: 8192562
    Abstract: An object of the preset invention is to provide a spring steel wire that: shows excellent wire drawability not only when it is used as a spring steel wire for cold-winding formed into a steel spring by applying quenching and tempering treatment after wiredrawing but also when it is used as a spring steel wire for cold-winding formed into a steel spring as it is wiredrawn; and secures a spring having an excellent fatigue characteristic after the spring steel wire is formed into the spring. The spring steel wire according to the present invention is a spring steel wire excellent in fatigue characteristic and wire drawability, wherein: the contents of C, Si, Mn, Cr, Ti, B, and other elements are specified; the contents (mass %) of B, Ti, and N satisfy the expression (1) below; the amount of solid solute B is in the range of 0.0005% to 0.0040%; the remainder in the spring steel wire is composed of Fe and unavoidable impurities; and the solid solute B concentrates at the grain boundaries of pearlite nodules, 0.
    Type: Grant
    Filed: October 30, 2007
    Date of Patent: June 5, 2012
    Assignee: Kobe Steel, Ltd.
    Inventor: Nao Yoshihara
  • Publication number: 20120132323
    Abstract: A steel product having, by weight, less than 0.25% carbon, between 0.20 and 2.0% manganese, between 0.05 and 0.50% silicon, aluminum 0.008% or less by weight, and at least one element selected from the group consisting of titanium between about 0.01% and about 0.20%, niobium between about 0.01% and about 0.20%, molybdenum between about 0.05% and about 0.50%, and vanadium between about 0.01% and about 0.20%, and having a microstructure comprised of a majority bainite, and fine oxide particles of silicon and iron distributed through the steel microstructure of average precipitate size less than 50 nanometers. The yield strength of the steel product may be at least 55 ksi (380 MPa) or the tensile strength of at least 500 MPa, or both. The steel product may have total elongation of at least 6% or 10%, and thickness less than 3.0 mm.
    Type: Application
    Filed: October 18, 2011
    Publication date: May 31, 2012
    Applicant: NUCOR CORPORATION
    Inventors: Christopher Ronald KILLMORE, James Geoffrey WILLIAMS
  • Patent number: 8187530
    Abstract: An object of this invention is to provide a steel for high-cleanliness spring which is useful for the production of a spring excellent in fatigue characteristics in high Si steels. The steel for high-cleanliness spring with excellent fatigue characteristics according to the invention contains: in terms of mass %, C: 1.2% or less (excluding 0%); Si: 1.8% to 4%; Mn: 0.1% to 2.0%; and total Al: 0.01% or less (excluding 0%), with the remainder being iron and inevitable impurities, in which the Si amount and a solute (SIMS) Ca amount in the steel satisfy a relationship of the following expression (1): Si×10?7?solute (SIMS) Ca?Si×5×10?7??(1) (in which each of the solute (SIMS) Ca and Si represents the amount thereof (mass %) in the steel).
    Type: Grant
    Filed: March 27, 2008
    Date of Patent: May 29, 2012
    Assignee: Kobe Steel, Ltd.
    Inventors: Tomoko Sugimura, Koichi Sakamoto, Yoshio Fukuzaki, Atsuhiko Yoshida, Takeshi Inoue