Processes Patents (Class 420/29)
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Patent number: 9908986Abstract: The present disclosure relates to an inorganic, halogen-free flameproofing agent produced from modified, carbonized red mud (MKRS-HT) having, in some examples, a mineral composition of 10 to 50 weight % of iron compounds, 12 to 35 weight % of aluminum compounds, 5 to 17 weight % of silicon compounds, 2 to 10 weight % of titanium dioxide, 0.5 to 6 weight % of calcium compounds, the weight ratio of Fe (II) carbonate to the oxides of iron being at least 1. Examples of the agent can be used as a flame retardant in the high-temperature range. The disclosure further relates to an agent produced from modified, carbonized and rehydrated red mud, which can be used as a flame retardant in the low-temperature and high-temperature ranges, methods for producing same and use as flame retardants. The disclosure further relates to a flameproofed material system and methods for producing same.Type: GrantFiled: January 16, 2014Date of Patent: March 6, 2018Assignee: FLUORCHEMIE GMBH FRANKFURTInventor: Christian Rocktäschel
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Inorganic, halogen-free flameproofing agent on the basis of chemically modified recarbonized red mud
Patent number: 9902832Abstract: The disclosure relates to an inorganic, halogen-free flameproofing agent produced from modified, recarbonized red mud (MKRS-HT). The agent may have a mineral composition of 10 to 50 weight % of iron compounds, 12 to 35 weight % of aluminum compounds, 5 to 17 weight % of silicon compounds, 2 to 10 weight % of titanium dioxide, 0.5 to 6 weight % of calcium compounds the weight ratio of Fe (II) carbonate to the oxides of iron being at least 1. The agent, according to examples, can be used as a flame retardant in the high-temperature range. The disclosure further relates to flameproofing agent produced from modified, recarbonized and rehydrated red mud, which may be a flame retardant in the low-temperature range as well as in the high-temperature range, methods for producing same and use as flame retardants, substitutes, synergists, thermal stabilizers, heat accumulators, heat insulators and/or sound insulators and/or as electromagnetic radiation shielding materials.Type: GrantFiled: January 16, 2014Date of Patent: February 27, 2018Assignee: FLUORCHEMIE GMBH FRANKFURTInventor: Christian Rocktäschel -
Patent number: 8486329Abstract: A process for the production of a semi-solidified iron alloy slurry having a crystallized solid phase and a residual liquid phase, wherein a material having a hypoeutectic cast iron composition is used, and an additive agent having a boiling point that is lower than at least a crystallization initiation temperature of primary crystals of the material is added to a melt of the material when the melt temperature is within a specific temperature range of not lower than the crystallization initiation temperature of the primary crystals and not greater than a temperature that is 50° C. higher than the crystallization initiation temperature, to thereby simultaneously conduct the stirring of the melt by the boiling of the additive agent and the cooling of the melt to a temperature falling within a semi-solidification temperature range thereof.Type: GrantFiled: March 12, 2009Date of Patent: July 16, 2013Assignee: Kogi CorporationInventors: Syuichi Shikai, Yasushi Fujinaga, Minoru Sasaki, Toshio Ohkado, Susumu Nishikawa
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Publication number: 20120301345Abstract: The invention provides a flake graphite cast iron being highly strong and excellent in workability such as cutting performance, which is suitable for use, for example, in internal combustion engine parts and the like, and a production method thereof without using a misch metal. Specifically, the flake graphite cast iron according to the invention includes an A-type graphite with a uniformly and disorderly distributed existence form without directionality; and has a chemical composition containing 2.8 to 4.0 mass % of C, 1.2 to 3.0 mass % of Si, 1.1 to 3.0 mass % of Mn, 0.01 to 0.6 mass % of P, 0.01 to 0.30 mass % of S and the remainder being Fe and inevitable impurities, wherein the ratio (Mn/S) of the Mn content to the S content is within a range of 3 to 300.Type: ApplicationFiled: August 2, 2012Publication date: November 29, 2012Applicants: Nippon Piston Ring Co., Ltd., Incorporated National University Iwate UniversityInventors: Hiroshi Horie, Toshinori Kowata, Yoshiki Ishikawa
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Patent number: 8187529Abstract: A wear resistant, high chromium white iron, in an unheat-treated condition has a microstructure substantially comprising austenite and M7C3 carbides. The white iron contains at least one martensite promoter and at least one austenite stabilizer which are present at respective levels to achieve a balance between their effects whereby the white iron has a microstructure characterized by at least one of: i) being substantially free of martensite at interfaces between the austenite and M7C3 carbides; and ii) having a relatively low level of interconnectivity between carbide particles; such that the white iron is substantially crack-free. The white iron may be as-cast or comprise weld deposited hardfacing.Type: GrantFiled: October 27, 2004Date of Patent: May 29, 2012Assignee: Global Tough Alloys Pty Ltd.Inventor: Graham Leonard Fraser Powell
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Patent number: 7824605Abstract: An as-cast carbidic ductile iron is provided, having a pearlitic matrix with 5-50% by volume carbides and high wear resistance properties. The as-cast carbidic ductile iron is produced without an austempering heat treatment step. The as-cast carbidic ductile iron preferably includes a carbide stabilizing element and a spheroidizing agent.Type: GrantFiled: December 15, 2006Date of Patent: November 2, 2010Assignee: Dexter Foundry, Inc.Inventors: Jeffrey Paul Lemke, Robert Edward Eppich
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Patent number: 6857962Abstract: A simplified method for producing internally threaded blind fasteners includes cold forming of the thin deformable walls of the fastener into bowed out sections by reverse extrusion to form deep grooves, and subsequent further cold forming to increase the diameter of this thin walled portion of the fastener to form it into bowed out sections. Three or more or even five or more sections may be formed, to increase the “pull-out” resistance by increasing the “footprint” of the deformed sections of the blind fastener.Type: GrantFiled: December 6, 2002Date of Patent: February 22, 2005Assignee: AVK Industrial Products, a division of SPS Technologies Inc.Inventor: Michael J. Weedon
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Patent number: 6800146Abstract: A magnetic circuit member contains a matrix portion including iron and silicon; and graphite particles in the matrix. Each of the graphite particles has either a spherical shape or a compact vermicular shape. The inclusion of graphite particles having a relatively low conductivity in the matrix portion having a good magnetic property prevents eddy currents from forming in the magnetic circuit member in an alternating magnetic field, thus preserving the original magnetic property found in the absence of the alternating magnetic field. Each of the graphite particles has a spherical or compact vermicular shape that does not intercept magnetic flux passing through the material forming the magnetic circuit member. The graphite contained in the material improves liquidity of the melted material in casting, thus the magnetic circuit member can be manufactured by casting.Type: GrantFiled: March 19, 2002Date of Patent: October 5, 2004Assignee: Aisin Seiki Kabushiki KaishaInventors: Akikazu Matsumoto, Wataru Yagi
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Patent number: 6793707Abstract: A method for inoculating molten iron. The method comprises passing the molten iron through a filter assembly at an approach velocity of about 1 to about 60 cm/sec. The filter assembly comprises a filter element and an inoculation pellet in contact with the filter element. The pellet has an inoculant dissolution rate of at least 1 mg/sec. to no more than 320 mg/sec. and comprises about 40-99.9%, by weight, carrier comprising ferrosilicon. The pellet further comprises about 0.1-60%, by weight, at least one inoculating agent selected from a group consisting of cerium, strontium, zirconium, calcium, manganese, barium, bismuth, magnesium, titanium and aluminum or from rare earths.Type: GrantFiled: January 10, 2002Date of Patent: September 21, 2004Assignees: Pechiney Electrometallurgie, Porvair PLCInventors: Donald B. Craig, Leonard S. Aubrey, Thomas J. Margaria
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Patent number: 6328783Abstract: A method of producing iron from iron carbide is disclosed. Solid iron carbide is injected into a molten bath comprising molten iron and slag and dissolves in the molten bath. An oxygen-containing gas is injected into a gas space above the surface of the molten bath to cause combustion of at least a portion of combustible material in the gas space. In addition splashes and/or droplets of molten iron and/or slag are ejected upwardly from the molten bath into the gas space above the quiescent bath surface to form a transition zone. The transition zone is a region in which heat generated by combustion of combustible material is transferred to the splashes and/or droplets of molten iron and/or slag and thereafter is transferred to the molten bath when the splashes and/or droplets of molten iron and/or slag return to the molten bath.Type: GrantFiled: June 17, 1999Date of Patent: December 11, 2001Assignee: Technological Resources PTY LTDInventor: Cecil Peter Bates
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Patent number: 6261339Abstract: In a method for desiliconizing pig iron prior to subsequent refining to steel molten steel slag after blast furnace tapping is charged onto the tapped pig iron bath, and optionally onto the blast furnace slag bath, in an amount corresponding to the Si content of the pig iron and the Fe and/or Cr oxide contents of the slag. The amount of steel slag is calculated such that the Si content of the pig iron is reduced to below 0.5% by weight at a simultaneous increase in the SiO2 content of the slag while reducing to liquid metals the Fe and/or Cr oxides of the slag. The slag-iron bath temperature is maintained at below 1500° C.Type: GrantFiled: February 9, 2000Date of Patent: July 17, 2001Assignee: “Holderbank” Financiere Glarus AGInventor: Alfred Edlinger
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Patent number: 6210460Abstract: Compositions suitable for use as an inoculant for cast iron. The composition includes granules of intermetallic alloys selected from Al4Sr, Al2Sr, and AlSr. The composition consists essentially of 40 to 81 percent strontium by weight.Type: GrantFiled: December 18, 1998Date of Patent: April 3, 2001Assignee: Timminco LimitedInventors: Douglas J. Zuliani, Bahadir Kulunk
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Patent number: 6197088Abstract: A method of liquid iron production using high sulfur fuels is provided in which the level of sulfur in the iron is maintained below 0.1%. The low sulfur content is achieved even in the presence of high sulfur concentrations in the reducing gases and without the introduction of lime or limestone. According to one aspect, liquid iron in the fusion zone of a smelting system is saturated with carbon, thereby desulfurizing the liquid iron. The carbon saturation level is at least 4.5% carbon by weight and preferably, at least 5.0% carbon by weight. According to another aspect, the desulfurization of the liquid iron is enhanced by elevating the tapping temperatures to temperatures in excess of 1465° C., and preferably of about 1490° C. According to another aspect, the desulfurization process is supplemented by the presence of significant levels of silicon and/or manganese, both of which are highly soluble in the liquid iron.Type: GrantFiled: March 15, 1999Date of Patent: March 6, 2001Assignee: Bechtel Group, Inc.Inventor: Richard B. Greenwalt
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Patent number: 6177045Abstract: A composition for inoculating grey iron, particularly low sulphur grey iron, comprises by weight: rare earth 1.0-4.0%, preferably 1.5-2.5%; strontium 0.5-1.5%, preferably 0.7-1.0%; calcium 1.5% maximum, preferably 0.5% maximum; aluminum 2.0% maximum, preferably 0.5% maximum; silicon 40.0-80.0%, preferably 70.0-75.0%; iron balance. The composition is most preferably free of calcium and aluminum. The rare earth may be cerium, mischmetall or a mixture of cerium and other rare earths. The composition may be a mixture of ferrosilicon and the other constituents, a ferrosilicon alloy containing the other constituents or a rare earth and a silicon-bearing inoculant containing strontium.Type: GrantFiled: August 29, 1998Date of Patent: January 23, 2001Assignee: Elkem ASAInventors: Christopher Ecob, Douglas White, David Butler
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Patent number: 5639420Abstract: A method of manufacturing compacted graphite cast iron, in which graphite modifying alloying agents, in the form of a so-called treatment alloy, are added to low-sulphurous molten cast iron. The treatment alloy is added to the molten iron by being sprayed into a jet of the molten iron as the latter is being discharged from a casting furnace. A dosed amount of treated iron is maintained for a predetermined period of time inside a casting box for homogenization and slag flotation, whereupon it is poured into a casting mold.Type: GrantFiled: January 28, 1993Date of Patent: June 17, 1997Assignee: AB VolvoInventors: Bertil Nils Gunnar Sander, Berndt Ingar Resne Gyllensten, Lars-Eric Thorsten Uhr, Per Inge Dahlof, Olov Skarg.ang.rd, Sven-Eric Dahlberg
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Patent number: 5634960Abstract: The process feeds a mixture of scrap metal, quartzite, carbonaceous material and wood chips to a submerged arc furnace to make a base iron suitable for iron foundry purposes. The mixture contains 1 to 20% quartzite, 5 to 15% carbonaceous material, 0 to 10% wood chips, all based on the weight of scrap in the mixture. By maintaining the charge in the furnace, good efficiencies are obtained.Type: GrantFiled: February 16, 1995Date of Patent: June 3, 1997Assignee: Elkem A/SInventor: Peter Cowx
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Patent number: 5224985Abstract: The improved method of melting a metal, especially cast iron, in a cokeless cupola furnace includes the step of injecting at least one case product quality improving and stabilizing substance into a space between the grate and the burners. The quality improving and stabilizing substance can be refining substance and a nuclear-enriching substance of the type used in code-fired cupola furnaces including nitrogen-containing substances such as ammonia and hydrazine and halogen-containing substances. A suitable apparatus for performing the improved process is also described having a downwardly direct lance for injection of the quality improving and stabilizing substance with an upwardly-directed mouth portion for forming an upwardly directed jet inserted through a furnace wall in a throughgoing guideway.Type: GrantFiled: January 16, 1991Date of Patent: July 6, 1993Assignee: La Bonvarite S.A.R.L.Inventors: Wolfgang Kullik, Rainer Graf, Alfred Langner
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Patent number: 4970051Abstract: The present invention provides an agent for the introduction of nitrogen into cast iron, wherein it contains or consists of at least 50% by weight of at least one nitrogen-containing compound with an N--C--N structure and/or a mixture of calcium cyanamide with nitrides of silicon, ferrosilicon, manganese and chromium.The present invention also provides a process for the introduction of nitrogen into cast iron using this agent.Type: GrantFiled: September 30, 1988Date of Patent: November 13, 1990Assignees: SKW Trostberg Aktiengesellschaft, Halbergerhuette GmbHInventors: Friedrich Wolfsgruber, Hartmut Meyer-Grunow, Detlef Missol, Jochem Richter, Julius Veit
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Patent number: 4889687Abstract: Nodular cast iron having favorable mechanical properties, in particular a high impact strength at low temperatures, comprising: from 3.0 to 4.0% of carbon; from 1.5 to 2.3% of silicon; less than 0.3% of manganese; not more than 0.03% of phosphorus; less than 0.10% of chromium; from 0.02 to 0.06% of magnesium; and from 0.0015 to 0.0150 weight % of bismuth with the balance consisting of iron and inevitable impurities and the CE (carbon equivalent) value being from 3.9 to 4.6%. This material is characterized by a low silicon content. Adding from 0.5 to 2.0% of nickel thereto improves its tensile strength and yield strength. Preferably, from 0.005 to 0.03% of bismuth is added to this nodular cast iron in molten state so as to produce more than 300 graphite nodules per mm.sup.2. The remaining bismuth content is preferably from 0.0015 to 0.015%, more preferably from 0.0015 to 0.004%.Type: GrantFiled: March 9, 1988Date of Patent: December 26, 1989Assignees: Hitachi Metals, Ltd., Honda Giken Kogyo K.K.Inventors: Yasuoki Ishihara, Fumio Obato, Jun Sakai, Takeshi Natsume
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Patent number: 4686081Abstract: A method of adding a low-melting point metal (e.g. Pb or Bi) to liquid steel for producing a free-cutting steel in a consistent manner and in high yield of addition is disclosed. In accordance with the method, at least one member selected from said low-melting point metal and an oxide thereof, and at least one member selected from the group consisting of quick lime and a carbonaceous material are mixed in specified optimum proportions and the mixture is blown into the liquid steel through an injection lance. The liquid steel may be agitated while the mixture is added, and the appropriate conditions for the agitation of the steel are also specified.Type: GrantFiled: May 21, 1986Date of Patent: August 11, 1987Assignee: Nippon Steel CorporationInventors: Kiyoshi Takashima, Isao Suzuki, Masashi Yoshida, Ryutatsu Tanaka, Noriyuki Masumitsu, Kazuhiro Kinoshita, Hiromi Ishii