Zirconium Containing Patents (Class 420/406)
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Publication number: 20150140352Abstract: A semifinished product for an implant and implants produced from the semifinished product, the semifinished product comprising or consisting of a region of a magnesium alloy, which is characterized by a grain size gradient of the magnesium alloy between two opposed surfaces from ?3 ?m to ?8 ?m, in each case in relation to the average grain size. Use of the semifinished product for producing corresponding implants, and also a method for producing semifinished products.Type: ApplicationFiled: October 28, 2014Publication date: May 21, 2015Inventors: Ullrich Bayer, Okechukwu Anopuo, Bernd Block
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Patent number: 9017604Abstract: Magnesium alloys containing: Y: 2.0-6.0% by weight Nd: 0-4.0% by weight Gd: 0-5.5% by weight Dy: 0-5.5% by weight Er: 0-5.5% by weight Zr: 0.05-1.0% by weight Zn+Mn: <0.11% by weight, optionally other rare earths and heavy rare earths, the balance being magnesium and incidental impurities and the total content of Gd, Dy and Er is in the range of 0.3-12% by weight, wherein either the alloy contains low amounts of Yb and Sm and exhibits a corrosion rate as measured according to ASTM B 117 of less than 30 Mpy, and/or the area percentage of any precipitated particles arising when the alloy is processed having an average particle size greater than 1 [mu]m and less than 15 [mu]m is less than 3%.Type: GrantFiled: September 30, 2009Date of Patent: April 28, 2015Assignee: Magnesium Elektron LimitedInventors: Paul Lyon, Ismet Syed, Anthony James Boden, Kenneth Savage
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Publication number: 20150064054Abstract: An implant made in total or in parts of a biodegradable magnesium alloy consisting of Y: 2.0-6.0% by weight, Nd: 1.5-4.5% by weight, Gd: 0-4.0% by weight, Dy: 0-4.0% by weight, Er: 0-4.0% by weight, Zr: 0.1-1.0% by weight, Li: 0-0.2% by weight, Al: 0-0.3% by weight, under the condition that a) a total content of Er, Gd and Dy is in the range of 0.5-4.0% by weight and b) a total content of Nd, Er, Gd and Dy is in the range of 2.0-5.5% by weight, the balance being magnesium and incidental impurities up to a total of 0.3% by weight.Type: ApplicationFiled: November 7, 2014Publication date: March 5, 2015Inventor: Bodo Gerold
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Patent number: 8915953Abstract: An implant made in total or in parts of a biodegradable magnesium alloy consisting of Y: 2.0-6.0% by weight, Nd: 1.5-4.5% by weight, Gd: 0-4.0% by weight, Dy: 0-4.0% by weight, Er: 0-4.0% by weight, Zr: 0.1-1.0% by weight, Li: 0-0.2% by weight, Al: 0-0.3% by weight, under the condition that a) a total content of Er, Gd and Dy is in the range of 0.5-4.0% by weight and b) a total content of Nd, Er, Gd and Dy is in the range of 2.0-5.5% by weight, the balance being magnesium and incidental impurities up to a total of 0.3% by weight.Type: GrantFiled: September 24, 2009Date of Patent: December 23, 2014Assignee: Biotronik VI Patent AGInventor: Bodo Gerold
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Publication number: 20140248288Abstract: The invention relates to biodegradable, metal alloy-containing compositions, methods for their preparation and applications for their use. The compositions include magnesium and other components, such as yttrium, calcium, silver, cerium, and zirconium; or zinc, silver, cerium, and zirconium; or aluminum, zinc, calcium, manganese, silver, yttrium; or strontium, calcium, zinc. The compositions are prepared by vacuum induction/crucible melting together the components and casting the melted mixture in a preheated mild steel/copper mold. In certain embodiments, the compositions of the invention are particularly useful for forming medical devices for implantation into a body of a patient.Type: ApplicationFiled: October 5, 2012Publication date: September 4, 2014Applicant: UNIVERSITY OF PITTSBURGH-OF THE COMMONWEALTH SYSTEM OF HIGHER EDUCATIONInventors: Prashant N. Kumta, Da-Tren Chou, Daeho Hong, Partha Saha
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Patent number: 8815148Abstract: Multi-component magnesium-based alloy consisting essentially of about 1.0-15.0 wt. % of scandium, about 0.1-3.0 wt. % of yttrium, about 1.0-3.0 wt. % of rare-earth metal, about 0.1-0.5 wt. % of zirconium. Purity degree of magnesium base is not less of 99.995 wt. %. Impurities of Fe, Ni and Cu do not exceed 0.001 wt. % of everyone, the contents of other impurity in an alloy does not exceed 0.005 wt. %. The alloy demonstrates an improved combination of strength, deformability and corrosion resistance at room temperature. The alloy does not contain harmful and toxic impurities. The alloy can be used in the various practical applications demanding a combination of high strength, deformability and corrosion resistance, preferably in the field of medicine.Type: GrantFiled: March 15, 2007Date of Patent: August 26, 2014Assignee: Acrostak Corp. BVIInventors: Youri Popowski, Igor Isakovich Papirov, Vladimir Sergeevitch Shokurov, Anatoliy Ivanovitch Pikalov, Sergey Vladimirovitch Sivtsov
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Publication number: 20130195714Abstract: Magnesium alloys which possess good processability and/or ductility whilst retaining good resistance to corrosion and/or degradation comprising Y: 0-10% by weight, Nd: 0-5% by weight, wherein the total of Y+Nd is at least 0.05% by weight, one or more heavy rare earths selected from Ho, Lu, Tm and Tb in a total amount of above 0.5% and no more than 5.5% by weight, Gd: 0-3.0% by weight, and Sm: 0-0.2% by weight. The alloy optionally includes one or more of: Dy: 0-8% by weight; Zr: 0-1.2% by weight; Al: 0-7.5% by weight; Zn and/or Mn: 0-2% by weight in total; Sc: 0-15% by weight; In: 0-15% by weight; Ca: 0-3% by weight; Er up to 5.5% by weight, provided that the total of Er, Ho, Lu, Tm and Tb is no more than 5.5% by weight; and one or more rare earths and heavy rare earths other than Y, Nd, Ho, Lu, Tm, Tb, Dy, Gd and Er in a total amount of up to 0.5% by weight; the balance being magnesium and incidental impurities up to a total of 0.3% by weight.Type: ApplicationFiled: March 23, 2011Publication date: August 1, 2013Applicant: Magnesium Elektron LimitedInventor: Paul Lyon
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Patent number: 8475608Abstract: Magnesium-based hydrogen storage alloys having metallic magnesium (Mg) and a magnesium-containing intermetallic compound (MgxMy wherein y is 1?x) and containing not less than 60 mass-% of magnesium in total, and having a phase of a primarily crystallized magnesium-containing intermetallic compound in its solidification structure.Type: GrantFiled: November 25, 2005Date of Patent: July 2, 2013Assignee: Japan Metals and Chemicals Co., Ltd.Inventors: Masahito Osawa, Hidenori Tomioka, Naoyoshi Terashita, Noboru Hayami, Shigeru Tsunokake
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Publication number: 20130144290Abstract: The invention relates to a magnesium alloy containing (in % by weight) more than 0.0 to 7.0% zinc, optionally more than 0.0 to 1.0% zirconium, optionally more than 0.0 to 1.0% calcium, optionally more than 0.0 to 1.0% manganese, optionally more than 0.0 to 0.5% silicon, optionally more than 0.0 to 1.0% silver, a max. up to 0.5% aluminum and at least one element selected from the group comprising more than 0.05 to 0.6% yttrium, more than 0.05 to 4.0% ytterbium, more than 0.05 to 4.0% gadolinium, with the residue being magnesium and impurities due to production. The invention also relates to a use of a magnesium alloy of this type and an implant therefrom and a method for producing a body of a magnesium alloy according to the invention.Type: ApplicationFiled: June 15, 2011Publication date: June 6, 2013Applicant: AIT AUSTRIAN INSTITUTE OF TECHNOLOGY GMBHInventors: Andreas Schiffl, Bernhard Mingler
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Publication number: 20130060326Abstract: An implant made in total or in parts of a biodegradable magnesium alloy consisting of Y: 2.0-6.0% by weight, Nd: 1.5-4.5% by weight, Gd: 0-4.0% by weight, Dy: 0-4.0% by weight, Er: 0-4.0% by weight, Zr: 0.1-1.0% by weight, Li:0-0.2% by weight, Al: 0-0.3% by weight, under the condition that a) a total content of Er, Gd and Dy is in the range of 0.5-4.0% by weight and b) a total content of Nd, Er, Gd and Dy is in the range of 2.0-5.5% by weight, the balance being magnesium and incidental impurities up to a total of 0.3% by weight.Type: ApplicationFiled: October 31, 2012Publication date: March 7, 2013Applicant: BIOTRONIK VI PATENT AGInventor: Biotronik Vi Patent Ag
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Patent number: 8361383Abstract: Provided is an allergen reduction-processing agent capable of giving an allergen reducing effect to a fibrous product while restraining whitening, and chalk marks. As chemical agents having an allergen-restraining effect, a zirconium based compound and a sulfonyl group-containing aromatic compound are used. An aqueous dispersion containing these components is used as an allergen reduction-processing agent for processing a fibrous product. The ratio by weight of the zirconium based compound to the aromatic compound is preferably 1 to 6:0.05 to 1.5.Type: GrantFiled: April 26, 2011Date of Patent: January 29, 2013Assignees: Honda Motor Co., Ltd., T.B. Kawashima Co., Ltd.Inventors: Rie Hayashi, Masato Ishibashi, Kohei Ohara, Takayuki Oishi, Eiken Kuzutani, Yumiko Hikida
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Patent number: 8293031Abstract: A magnesium alloy, comprising: Y: 0.5-10? Zn: 0.5-6?? Ca: 0.05-1?? Mn: ??0-0.5 Ag: 0-1 Ce: 0-1 Zr: 0-1 or Si: 0-0.4, wherein the amounts are based on weight-percent of the alloy and Mg, and manufacturing-related impurities constitute the remainder of the alloy to a total of 100 weight-percent. Also disclosed is a method for manufacturing such an alloy and a biodegradable implant formed therefrom.Type: GrantFiled: July 27, 2007Date of Patent: October 23, 2012Assignee: Biotronik VI Patent AGInventors: Bodo Gerold, Heinz Mueller, Joerg Loeffler, Anja Haenzi, Peter Uggowitzer
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Patent number: 8268235Abstract: An implant consisting entirely or in part of a biocorrodible magnesium alloy having the composition Gd: 2.7-15.0 wt %, Zn: 0-0.5 wt %, Zr: 0.2-1.0 wt %, Nd: 0-4.5 wt %, Y: 0-2.0 wt %, where magnesium and impurities due to the production process account for the remainder to a total of 100 wt %.Type: GrantFiled: December 17, 2009Date of Patent: September 18, 2012Assignee: Biotronik VI Patent AGInventor: Bodo Gerold
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Publication number: 20120195787Abstract: The present invention relates to single-phase solid solution magnesium alloys suitable for the applications as cast or wrought. These alloys are prepared by multi-microalloying with rare earth elements (including gadolinium, yttrium, dysprosium, samarium, lanthanum, cerium, neodymium and praseodymium). Each alloy contains 0.5 to less than 5 wt. % rare earth elements with a content of 0.05-2.0% by weight. The total amount of rare earth elements is controlled below 5% by weight in order for economical considerations. The amount of grain refiner calcium or zirconium is in the range of 0.05-0.6% by weight. These alloys can be prepared by die casting, permanent casting, chill casting, semi-solid processes, continuous casting and continuous twin roll casting.Type: ApplicationFiled: January 18, 2012Publication date: August 2, 2012Applicant: Helmholtz-Zentrum Geesthacht Zentrum fun Material-und Kustenforschung GmbHInventors: Yuanding Huang, Qiumin Peng, Norbert Hort, Karl U. Kainer
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Publication number: 20120100035Abstract: A magnesium alloy sheet having high impact resistance at low temperature, a magnesium alloy structural member using this sheet, and a method for producing a magnesium alloy sheet are provided. The magnesium alloy sheet is composed of a magnesium alloy containing Al and Mn. When a region from a surface of the alloy sheet to 30% of the thickness of the alloy sheet in a thickness direction of the magnesium alloy sheet is defined as a surface region and when a 50 ?m2 sub-region is arbitrarily selected from this surface region, the number of grains that are crystallized phases containing both Al and Mn is 15 or less. The maximum diameter of each of the crystallized phases is 0.1 to 1 ?m and the mass ratio Al/Mn of Al to Mn is 2 to 5. This magnesium alloy sheet has high impact resistance since it contains crystallized phases that are small in size and in amount contained and cause breaking and the like, and exhibits good mechanical properties even in a low-temperature environment.Type: ApplicationFiled: June 8, 2010Publication date: April 26, 2012Applicant: Sumitomo Electric Industries, Ltd.Inventors: Yukihiro Oishi, Takahiro Kitamura, Nozomu Kawabe
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Publication number: 20110293465Abstract: The present invention provides a heat-resistant magnesium alloy for gravity casting, which has excellent high-temperature resistance, tensile strength, and creep resistance properties. In preferred embodiments, the present invention provides a heat-resistant magnesium alloy for gravity casting with high creep resistance, the magnesium alloy containing magnesium as a main component, 1.00 to 3.00 wt % neodymium, 2.00 to 6.00 wt % misch metal, 0.10 to 1.00 wt % zinc, 0.10 to 1.00 wt % zirconium, 0.01 to 0.50 wt % yttrium, 0.01 to 0.10 wt % calcium, 0.008 wt % silicon, 0.004 wt % iron, 0.003 wt % copper, and 0.001 wt % nickel.Type: ApplicationFiled: November 4, 2010Publication date: December 1, 2011Applicants: SNU R&DB FOUNDATION, HYUNDAI MOTOR COMPANYInventor: Kwang Seon Shin
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Publication number: 20110229365Abstract: Magnesium alloys containing: Y: 2.0-6.0% by weight Nd: 0-4.0% by weight Gd: 0-5.5% by weight Dy: 0-5.5% by weight Er: 0-5.5% by weight Zr: 0.05-1.0% by weight Zn+Mn: <0.11% by weight, optionally other rare earths and heavy rare earths, the balance being magnesium and incidental impurities and the total content of Gd, Dy and Er is in the range of 0.3-12% by weight, wherein either the alloy contains low amounts of Yb and Sm and exhibits a corrosion rate as measured according to ASTM B117 of less than 30 Mpy, and/or the area percentage of any precipitated particles arising when the alloy is processed having an average particle size greater than 1 m and less than 15 m is less than 3%.Type: ApplicationFiled: September 30, 2009Publication date: September 22, 2011Applicant: Magnesium Elektron LimitedInventors: Paul Lyon, Ismet Syed, Anthony James Boden, Kenneth Savage
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Publication number: 20110192500Abstract: A magnesium alloy shown includes magnesium as a principal ingredient, and 0.5 to 8.0 percent ytterbium; 0.1 to 2.0 percent calcium; and 0.2 to 6.0 percent zinc, percentages calculated by weight. The magnesium alloy may be employed as an implant. Examples of implants include a plate, specifically a bone plate, a screw, a nail, a bone nail, a stent, a rod. Implants made of the specified alloy are suitable for implantation in animal or human body.Type: ApplicationFiled: May 21, 2009Publication date: August 11, 2011Applicant: Synthes USA, LLCInventors: Peter Uggowitzer, Petra Gunde, Joerg Loeffler, Thomas Imwinkelried, Stefan Beck, Andrea Montali
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Patent number: 7942986Abstract: A magnesium-based alloy consists of 1.5-4.0% by weight rare earth element(s), 0.3-0.8% by weight zinc, 0.02-0.1% by weight aluminium, and 4-25 ppm beryllium. The alloy optionally contains up to 0.2% by weight zirconium, 0.3% by weight manganese, 0.5% by weight yttrium and 0.1% by weight calcium. The remainder of the alloy is magnesium except for incidental impurities.Type: GrantFiled: August 21, 2009Date of Patent: May 17, 2011Assignee: Cast Centre Pty LtdInventors: Colleen Joyce Bettles, Mark Antony Gibson
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Patent number: 7935304Abstract: This invention relates to magnesium-based alloys particularly suitable for casting applications where good mechanical properties at room and at elevated temperatures are required. The alloys contain: 2 to 4.5% by weight of neodymium; 0.2 to 7.0% of at least one rare earth metal of atomic No. 62 to 71; up to 1.3% by weight of zinc; and 0.2 to 0.7% by weight of zirconium; optionally with one or more other minor component. They are resistant to corrosion, show good age-hardening behaviour, and are also suitable for extrusion and wrought alloy applications.Type: GrantFiled: October 8, 2004Date of Patent: May 3, 2011Assignee: Magnesium Electron Ltd.Inventors: Paul Lyon, John King, Hossein Karimzadeh, Ismet Syed
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Publication number: 20100310409Abstract: A magnesium based alloy consisting of, by weight: 2-5% rare earth elements, wherein the alloy contains lanthanum and cerium as rare earth elements and the lanthanum content is greater than the cerium content; 0.2-0.8% zinc; 0-0.15% aluminium; 0-0.5% yttrium or gadolinium; 0-0.2% zirconium, 0-0.3% manganese; 0-0.1% calcium; 0-25 ppm beryllium; and the remainder being magnesium except for incidental impurities.Type: ApplicationFiled: December 23, 2008Publication date: December 9, 2010Applicant: CAST CRC LIMITEDInventors: Mark Gibson, Mark Easton, Colleen BETTLES
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Publication number: 20100161031Abstract: The present invention relates to compositions and structure of deformable alloys on the basis of magnesium with an optimum combination of mechanical properties (strength, plasticity) and a resistance to corrosion, including in vivo. Alloys of the new group possess an excellent formability at room temperature, high corrosion stability in sodium chloride solution, excellent heat resistance and can be used in various technical applications, particularly in vivo as a structural material for stents.Type: ApplicationFiled: May 5, 2008Publication date: June 24, 2010Inventors: Igor Isakovich Papirov, Anatoliy Ivanovitch Pikalov, Vladimir Sergeevitch Shokurov, Sergey Vladimirovitch Sivtsov
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Patent number: 7718118Abstract: The present invention relates to creep-resistant magnesium-based alloys with low susceptibility to hot tearing, and with improved ductility, impact strength and fracture toughness, and corrosion resistance. The alloys contain at least 96 wt % magnesium, 1.5 to 1.9 wt % neodymium, 0.10 to 0.30 wt % yttrium, 0.35 to 0.70 wt % zirconium, 0.05 to 0.35 wt % zinc, 0.01 to 0.10 wt % calcium, 0.01 to 0.15 wt % strontium, and 0.0000 to 0.0005 wt % beryllium, and they are suitable for low pressure and gravity castings. Articles, that are castings of the alloys, are suitable for applications at temperatures as high as 175-250° C.Type: GrantFiled: September 22, 2006Date of Patent: May 18, 2010Assignee: Dead Sea Magnesium Ltd.Inventors: Boris Bronfin, Nir Moscovitch, Mark Katzir, Soenke Schumann, Rudolph Boehm
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Patent number: 7708937Abstract: A high-strength, high-toughness, weldable and deformable rare earth magnesium alloy comprised of 0.7˜1.7% of Ym, 5.5˜6.4% of Zn, 0.45˜0.8% of Zr, 0.02% or less of the total amount of impurity elements of Si, Fe, Cu and Ni, and the remainder of Mg, based on the total weight of the alloy. During smelting, Y, Ho, Er, Gd and Zr are added in a manner of Mg—Y-rich, Mg—Zr intermediate alloys into a magnesium melt; Zn is added in a manner of pure Zn, and at 690˜720° C., a round bar was cast by a semi-continuous casting or a water cooled mould, then an extrusion molding was performed at 380˜410° C. after cutting. Before the extrusion, the alloy is treated by the solid-solution treatment at 480˜510° C. for 2˜3 hours, however, the alloy can also be extrusion molded directly without the solid-solution treatment.Type: GrantFiled: April 17, 2008Date of Patent: May 4, 2010Assignee: Changchun Institute of Applied Chemistry Chinese Academy of SciencesInventors: Jian Meng, Daqing Fang, Deping Zhang, Dingxiang Tang, Huayi Lu, Lianshan Zhao, Wei Sun, Xin Qiu, Hongjie Zhang
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Publication number: 20100082092Abstract: An implant made in total or in parts of a biodegradable magnesium alloy consisting of Y: 2.0-6.0% by weight, Nd: 1.5-4.5% by weight, Gd: 0-4.0% by weight, Dy: 0-4.0% by weight. Er: 0-4.0% by weight, Zr: 0.1-1.0% by weight, Li:0-0.2% by weight, Al: 0-0.3% by weight, under the condition that a) a total content of Er, Gd and Dy is in the range of 0.5-4.0% by weight and b) a total content of Nd, Er, Gd and Dy is in the range of 2.0-5.5% by weight, the balance being magnesium and incidental impurities up to a total of 0.3% by weight.Type: ApplicationFiled: September 24, 2009Publication date: April 1, 2010Applicant: BIOTRONIK VI PATENT AGInventor: Bodo Gerold
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Patent number: 7682470Abstract: A magnesium-based alloy consists of 1.5-4.0% by weight rare earth element(s), 0.3-0.8% by weight zinc, 0.02-0.1% by weight aluminum, and 4-25 ppm beryllium. The alloy optionally contains up to 0.2% by weight zirconium, 0.3% by weight manganese, 0.5% by weight yttrium and 0.1% by weight calcium. The remainder of the alloy is magnesium except for incidental impurities.Type: GrantFiled: April 4, 2006Date of Patent: March 23, 2010Assignee: Cast Centre Pty LtdInventors: Colleen Joyce Bettles, Mark Antony Gibson
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Publication number: 20100061880Abstract: A magnesium-based alloy consists of 1.5-4.0% by weight rare earth element(s), 0.3-0.8% by weight zinc, 0.02-0.1% by weight aluminium, and 4-25 ppm beryllium. The alloy optionally contains up to 0.2% by weight zirconium, 0.3% by weight manganese, 0.5% by weight yttrium and 0.1% by weight calcium. The remainder of the alloy is magnesium except for incidental impurities.Type: ApplicationFiled: August 21, 2009Publication date: March 11, 2010Applicant: CAST CENTRE PTY LTDInventors: Colleen Joyce Bettles, Mark Antony Gibson
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Publication number: 20090263271Abstract: A high-strength, high-toughness, weldable and deformable rare earth magnesium alloy comprised of 0.7˜1.7% of Ym, 5.5˜6.4% of Zn, 0.45˜0.8% of Zr, 0.02% or less of the total amount of impurity elements of Si, Fe, Cu and Ni, and the remainder of Mg, based on the total weight of the alloy. During smelting, Y, Ho, Er, Gd and Zr are added in a manner of Mg—Y-rich, Mg—Zr intermediate alloys into a magnesium melt; Zn is added in a manner of pure Zn, and at 690˜720° C., a round bar was cast by a semi-continuous casting or a water cooled mould, then an extrusion molding was performed at 380˜410° C. after cutting. Before the extrusion, the alloy is treated by the solid-solution treatment at 480˜510° C. for 2˜3 hours, however, the alloy can also be extrusion molded directly without the solid-solution treatment.Type: ApplicationFiled: April 17, 2008Publication date: October 22, 2009Applicant: CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCESInventors: Jian Meng, Daqing Fang, Deping Zhang, Dingxiang Tang, Huayi Lu, Lianshan Zhao, Wei Sun, Xin Qiu, Hongjie Zhang
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Publication number: 20090214953Abstract: A nickel metal hydride secondary battery includes hydrogen storage alloy particles in a negative electrode. The hydrogen storage alloy has a composition expressed by a general formula (LaaSmbGdc“A”d)1-wMgwNixAly“T”z, where “A” and “T” each represent at least one element selected from a group consisting of Pr, Nd, etc., and a group consisting of V, Nb, etc., respectively; subscripts a, b, c and d satisfy relationship expressed by a>0, b?0, c>0, 0.1>d?0, and a+b+c+d=1; and subscripts w, x, y and z fall in a range expressed by 0.1?w?0.3, 0.05?y?0.35, 0?z?0.5, and 3.2?x+y+z?3.8.Type: ApplicationFiled: February 25, 2009Publication date: August 27, 2009Applicant: SANYO ELECTRIC CO., LTD.Inventors: Masaru KIHARA, Takahiro ENDO, Akira SAGUCHI
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Publication number: 20090175754Abstract: This invention relates to gadolinium-containing magnesium containing alloys, particularly those which possess high strength combined with corrosion resistance, and an optimized balance of strength and ductility. The described alloys consist of 2.0 to 5.0, preferably 2.3 to 4.6, at % in total of gadolinium and at least one of soluble heavy lanthanides and yttrium, wherein the ratio of the aggregate amount of soluble heavy lanthanides and yttrium to the amount of gadolinium is between 1.25:1 and 1.75:1, from 0 up to 0.3 at % of zirconium, preferably at least 0.03 at %, optionally with zinc, wherein when zinc is present the amount of zinc is such that the ratio of the weight of zinc to the weight of zirconium is preferably less than 2:1, all other lanthanides in an aggregate amount of less than at 0.2 at %, the balance being magnesium, with any other element being present in an amount of no more than 0.2 at %.Type: ApplicationFiled: March 12, 2009Publication date: July 9, 2009Applicant: MAGNESIUM ELEKTRON LIMITEDInventors: Timothy Wilks, Sarka Jeremic, Phillip Rogers, Paul Lyon
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Publication number: 20090104527Abstract: A hydrogen storage alloy containing a phase of a chemical composition defined by a general formula A5·xB1+xC24: wherein in the general formula A5·xB1+xC24, A denotes one or more element(s) selected from rare earth elements; B denotes one or more element(s) selected from a group consisting of Mg, Ca, Sr, and Ba; C denotes one or more element(s) selected from a group consisting of Ni, Co, Mn, Al, Cr, Fe, Cu, Zn, Si, Sn, V, Nb, Ta, Ti, Zr, and Hf; and x denotes a numeral in a range from ?0.1 to 0.8: and the phase has a crystal structure belonging to a space group of R-3m and having a length ratio of the c-axis to the a-axis of the lattice constant in a range of 11.5 to 12.5.Type: ApplicationFiled: August 11, 2006Publication date: April 23, 2009Applicant: GS Yuasa CorporationInventors: Tetsuya Ozaki, Tetsuo Sakai, Manabu Kanemoto, Minoru Kuzuhara, Tadashi Kakeya, Masaharu Watada
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Publication number: 20090081313Abstract: Novel magnesium-based compositions-of-matter which can be used for manufacturing implantable medical devices such as orthopedic implants are disclosed. The compositions-of-matter can be used for constructing monolithic, porous and/or multilayered structures which are characterized by biocompatibility, mechanical properties and degradation rate that are highly suitable for medical applications. Articles, such as medical devices, made of these magnesium-based compositions-of-matter and processes of preparing these magnesium-based compositions-of-matter are also disclosed.Type: ApplicationFiled: April 29, 2007Publication date: March 26, 2009Applicant: BioMagnesium Systems Ltd.Inventors: Ernest Eliyahu Aghion, Amir Arnon, Dan Atar, Gal Segal
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Publication number: 20090035171Abstract: Provided is a high-strength and high-toughness magnesium alloy which has practical level of both the strength and the toughness for expanded applications of the magnesium alloys, and is a method for manufacturing thereof. The high-strength and high-toughness magnesium alloy of the present invention contains: a atom % in total of at least one metal of Cu, Ni, and Co; and b atom % in total of at least one element selected from the group consisting of Y, Dy, Er, Ho, Gd, Tb, and Tm, while a and b satisfying the following formulae (1) to (3), 0.2?a?10??(1) 0.2?b?10??(2) 2/3a?2/3<b.Type: ApplicationFiled: March 20, 2007Publication date: February 5, 2009Inventors: Yoshihito Kawamura, Michiaki Yamasaki, Takaomi Itoi, Mitsuji Hirohashi
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Publication number: 20080311423Abstract: The invention is to provide a magnesium alloy material such as a magnesium alloy cast material or a magnesium alloy rolled material, excellent in mechanical characteristics and surface precision, a producing method capable of stably producing such material, a magnesium alloy formed article utilizing the rolled material, and a producing method therefor. The invention provides a producing method for a magnesium alloy material, including a melting step of melting a magnesium alloy in a melting furnace to obtain a molten metal, a transfer step of transferring the molten metal from the melting furnace to a molten metal reservoir, and a casting step of supplying a movable mold with the molten metal from the molten metal reservoir, through a pouring gate, and solidifying the molten metal to continuously produce a cast material. In a process from the melting step to the casting step, parts contacted by the molten metal are formed by a low-oxygen material having an oxygen content of 20 mass % or less.Type: ApplicationFiled: June 28, 2005Publication date: December 18, 2008Inventors: Masatada Numano, Yoshihiro Nakai, Toshiya Ikeda, Taichiro Nishikawa
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Publication number: 20080304997Abstract: Disclosed is a wrought magnesium alloy having excellent strength and extrusion or rolling formability, and a method of producing the same. The wrought magnesium alloy comprises 0.1-1.5 at % group IIIa, 1.0-4.0 at % group IIIb, 0.35 at % or less of one selected from the group consisting of groups IIa, IVa, VIIa, IVb, and a mixture thereof, 1.0 at % or less of group IIb, and a balance of Mg and unavoidable impurities and thus has a second phase composite microstructure. The wrought magnesium alloy of the present invention has high strength, toughness, and formability in addition to the electromagnetic wave shield ability of magnesium. Accordingly, the wrought magnesium alloy is a material useful to portable electronic goods, such as notebook personal computers, mobile phones, digital cameras, camcorders, CD players, PDA, or MP3 players, automotive parts, such as engine room hoods, oil pans, or inner panel of door, or structural parts for airplane.Type: ApplicationFiled: March 11, 2005Publication date: December 11, 2008Applicant: PRIMOMETAL CO., LTD.Inventor: Kang-Hyung Kim
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Publication number: 20080193322Abstract: A magnesium-rare earth-yttrium-zinc alloy consists of 0.2-1.5% by weight zinc and rare earth(s) (RE) and yttrium in amounts which fall within a quadrangle defined by lines AB, BC, CD and DA wherein: A is 1.8% RE-0.05% Y, B is 1.0% RE-0.05% Y, C is 0.2% RE-0.8% Y, and D is 1.8% RE-0.8% Y.Type: ApplicationFiled: May 26, 2006Publication date: August 14, 2008Applicant: CAST CENTRE PTY LTDInventors: Mark Antony Gibson, Colleen Joyce Bettles
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Publication number: 20080041500Abstract: The present invention relates to creep-resistant magnesium-based alloys with low susceptibility to hot tearing, and with improved ductility, impact strength and fracture toughness, and corrosion resistance. The alloys contain at least 96 wt % magnesium, 1.5 to 1.9 wt % neodymium, 0.10 to 0.30 wt % yttrium, 0.35 to 0.70 wt % zirconium, 0.05 to 0.35 wt % zinc, 0.01 to 0.10 wt % calcium, 0.01 to 0.15 wt % strontium, and 0.0000 to 0.0005 wt % beryllium, and they are suitable for low pressure and gravity castings. Articles, that are castings of the alloys, are suitable for applications at temperatures as high as 175-250° C.Type: ApplicationFiled: September 22, 2006Publication date: February 21, 2008Applicants: Dead Sea Magnesium Ltd., Volkswagen AGInventors: Boris Bronfin, Nir Moscovitch, Mark Katzir, Soenke Schumann, Rudolph Boehm
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Patent number: 7153374Abstract: A refractory magnesium alloy includes magnesium as a principal ingredient, and an element having a radius 9–14% larger than a magnesium atom and a maximum concentration of 2 mass % or larger in a solid solution with magnesium is mixed in an amount not exceeding a maximum amount that can be homogeneously mixed in the solid solution with magnesium, whereby internal strength of grains thereof is enhanced. Alternatively, gadolinium with a content thereof ranging from 0.5 to 3.8 mass % is added, so that remaining part other than the gadolinium is composed of the magnesium and unavoidable impurities. This magnesium alloy serves to inhibit decrease in proof stress and creep deformation, especially primary creep deformation when used at high temperatures, typically at 200° C. The magnesium alloy may be employed for a structural material for a vehicle, so that a lightweight and heat-resistant structural material can be obtained.Type: GrantFiled: August 9, 2002Date of Patent: December 26, 2006Assignee: Honda Giken Kogyo Kabushiki KaishaInventors: Kazuo Kikawa, Takashi Shiraishi, Atsushi Fukatsu
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Patent number: 7048812Abstract: A magnesium based alloy consists of, by weight: 1.4–1.9% neodymium, 0.8–1.2% rare earth element(s) other than neodymium, 0.4–0.7% zinc, 0.3–1% zirconium, 0–0.3% manganese, and 0–0.1% oxidation inhibiting element(s) the remainder being magnesium except for incidental impurities.Type: GrantFiled: June 20, 2003Date of Patent: May 23, 2006Assignee: Cast Centre Pty LtdInventors: Colleen Joyce Bettles, Christopher Thomas Forwood
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Publication number: 20030129074Abstract: A magnesium-based alloy containing at least 92 wt % magnesium, 2.7 to 3.3 wt % neodymium, 0.0 to 2.6 wt % yttrium, 0.2 to 0.8 wt % zirconium, 0.2 to 0.8 wt % zinc, 0.03 to 0.25 wt % calcium, and 0.00 to 0.001 wt % beryllium. The alloy may additionally contain up to 0.007 wt % iron, up to 0.002 wt % nickel, up to 0.003 wt % copper, and up to 0.01 wt % silicon, and incidental impurities. The alloy may contain from 0.2 to 0.5 wt % Zn, and from 0.03 to 0.15 wt % Ca, and 2.9-3.2 wt % Nd, 1.9-2.1 wt % Y, 0.3-0.5 wt % Zr, 0.2-0.4 wt % Zn, and 0.03-0.12 wt % Ca.Type: ApplicationFiled: March 14, 2002Publication date: July 10, 2003Inventors: Boris Bronfin, Eliyahu Aghion, Frank Von Buch, Soenke Schumann, Horst Friedrich, Mark Katzir
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Publication number: 20030000608Abstract: A magnesium alloy having excellent castability and creep properties has compositions of 1.0-6.0 wt % Zn, 0.5-3.0 wt % Ca, 1.0 wt % or less Zr, 1.0-5.0 wt % at least one lanthanoid, the remainder being Mg and unavoidable impurities. This magnesium alloy undergoes heat treatment of heating the magnesium alloy to 430-470 ° C., quenching, and then heating to 150-250 ° C. for aging. Hot tearing and temperature strength are improved by the addition of an element which is effective for causing eutectic reaction and peritectic reaction with Mg and making Mg particles divied finely.Type: ApplicationFiled: July 8, 2002Publication date: January 2, 2003Applicant: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHOInventors: Toshio Horie, Hiroaki Iwahori, Yoji Awano
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Patent number: 6495267Abstract: An anodized magnesium piston including a head and skirt for an internal combustion engine. The piston includes a non-fiber-reinforced, magnesium-based alloy including up to 2.5 percent by weight rare earth metals. The piston further includes an external surface, at least a portion of which has a base layer of magnesium fluoride, magnesium oxofluoride, magnesium oxide or a mixture thereof electrochemically anodized thereto.Type: GrantFiled: October 4, 2001Date of Patent: December 17, 2002Assignee: Briggs & Stratton CorporationInventor: Jerry L. Schenkel
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Patent number: 6299834Abstract: A heat-resistant magnesium alloy exhibiting excellent heat resistance and castability, which comprises 1.0 to 6.0 % by weight of zinc, 0.4 to 1.0 % by weight of zirconium, 1.5 to 5.0 % by weight of rare earth element, up to 0.3 % by weight of calcium, magnesium being as the balance, and unavoidable impurities.Type: GrantFiled: June 16, 2000Date of Patent: October 9, 2001Assignee: Kabushiki Kaisha Toyota Chuo KenkyushoInventors: Toshio Horie, Yoshio Sugiyama, Hiroaki Iwahori, Tomoyasu Kitano, Harumi Ueno, Takamasa Suzuki
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Patent number: 6193817Abstract: A magnesium base alloy for high pressure die casting (HPDC), providing good creep and corrosion resistance, comprises: at least 91 weight percent magnesium; 0.1 to 2 weight percent of zinc; 2.1 to 5 percent of a rare earth metal component; 0 to 1 weight percent calcium; 0 to 0.1 weight percent of an oxidation inhibiting element other than calcium (e.g., Be); 0 to 0.4 weight percent zirconium, hafnium and/or titanium; 0 to 0.5 weight percent manganese; no more than 0.001 weight percent strontium; no more than 0.05 weight percent silver and no more than 0.1 weight percent aluminum; any remainder being incidental impurities. For making prototypes, gravity (e.g. sand) cast and HPDC components from the alloy have similar mechanical properties, in particular tensile strength. The temperature dependence of the latter, although negative, is much less so than for some other known alloys.Type: GrantFiled: August 5, 1997Date of Patent: February 27, 2001Assignee: Luxfer Group LimitedInventors: John Frederick King, Paul Lyon, Kevin Nuttall
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Patent number: 5552110Abstract: A magnesium alloy includes 0.1 to 6.0% by weight of Al, 0.25 to 6.0% by weight of Zn, 0.1 to 4.0% by weight of rare earth element (hereinafter referred to as "R.E."), and balance of Mg and inevitable impurities. Preferably, it includes 1.0 to 3.0% by weight of Al ("a"), 0.25 to 3.0% by weight of Zn ("b") and 0.5 to 4.0% by weight of R.E.: wherein when "b" is in a range, 0.25.ltoreq."b".ltoreq.1.0, "a" and "c" satisfy a relationship, "c".ltoreq."a"+1.0; and when "b" is in a range, 1.0.ltoreq."b".ltoreq.3.0, "a," "b" and "c" satisfy a relationship, "c".ltoreq."a"+"b".ltoreq.(1/2)"c"+4.0; in order to further improve creep properties at elevated temperatures while maintaining enhanced tensile strength at room temperature and up to 100.degree. C. at least.Type: GrantFiled: March 25, 1994Date of Patent: September 3, 1996Assignee: Toyota Jidosha Kabushiki KaishaInventors: Hideki Iba, Chikatoshi Maeda, Tadashi Takeuchi, Yasuyuki Suzuki
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Patent number: 5501748Abstract: Procedure for the production of a thixotropic magnesium alloy by adding a grain refiner combined with controlled, rapid solidification with subsequent heating to the two-phase area. It is preferable to use a solidification rate of >1.degree. C./s, more preferably >10.degree. C./s. It is essential that the solidification takes place at such a speed that growth of dendrites is avoided. Heating to the two-phase area is carried out rapidly in 1-30 minutes, preferably 2-5 minutes. By heating an alloy comprising 2-8 weight % Zn, 1.5-5 weight % RE, 0.2-0.8 weight Zr balanced with magnesium to a temperature in the two-phase area after casting, the structure will assume a form in which the .alpha.-phase is globular (RE=rare earth metal). The size of the spheres will be dependent on the temperature and the holding time at that temperature and they will be surrounded by a low-smelting matrix. It is preferable that the alloy has a grain size of not greater than <100 .mu.m, more preferably 50-100 .mu.m.Type: GrantFiled: June 10, 1993Date of Patent: March 26, 1996Assignee: Norsk Hydro A.S.Inventors: Haavard Gjestland, HAkon Westengen
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Patent number: 5336466Abstract: A magnesium alloy includes 0.1 to 6.0% by weight of Al, 1.0 to 6.0% by weight of Zn, 0.1 to 3.0% by weight of rare earth element (hereinafter referred to as "R.E."), and balance of Mg and inevitable impurities. By thusly adding Al and Zn, the castability, especially the die-castability, is improved. At the same time, the room temperature strength can be improved because the Mg-Al-Zn crystals having a reduced brittleness are dispersed uniformly in the crystal grains. Further, by adding R.E. as aforementioned, the high temperature strength is improved because the Mg-Al-Zn-R.E. crystals having a higher melting point and being less likely to melt are present in the crystal grain boundaries between the Mg-Al-Zn crystals. This magnesium alloy is excellent in castability, can be die-cast, has a higher tensile strength at room temperature, and is satisfactory in high temperature properties and creep properties. Moreover, when the magnesium alloy includes R.E. in a reduced amount of 0.1 to 2.Type: GrantFiled: July 24, 1992Date of Patent: August 9, 1994Assignee: Toyota Jidosha Kabushiki KaishaInventors: Hideki Iba, Chikatoshi Maeda
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Patent number: 5250124Abstract: A bulky amorphous magnesium alloy having heat-resistance and toughness is provided by setting the alloy composition as: Mg.sub.a M.sub.b Al.sub.c X.sub.d Z.sub.e (M is at least one element selected from the group consisting of La, Ce, Mm (misch metal) and Y, X is at least one element selected from the group consisting of Ni and Cu, and Z is at least one element selected from the group consisting of Mn, Zn, Zr, and Ti, and, a=70.about.90 at %, b=2.about.15 at %, c=1.about.9 at %, d=2.about.15 at %, e=0.1.about.8 at %, a+b+c+d+e=100 at %).Type: GrantFiled: March 16, 1992Date of Patent: October 5, 1993Assignees: Yoshida Kogyo K.K., Tsuyoshi MasumotoInventors: Hitoshi Yamaguchi, Toshisuke Shibata, Akihisa Inoue, Akira Kato, Tsuyoshi Masumoto
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Patent number: 5143564Abstract: Cast magnesium alloy parts being substantially free of microporosity and having a fine grain size are produced by addition of strontium in an amount of 0.001 to 0.1%, by weight, to the melt of the magnesium alloy, prior to casting; the addition of strontium effects a reduction in the grain size and concentrates the shrinkage microporosity, whereby the microporosity can be shifted by conventional techniques to an appendix of the casting which is subsequently removed.Type: GrantFiled: March 28, 1991Date of Patent: September 1, 1992Assignee: McGill UniversityInventors: John E. Gruzleski, Abdulcelil Aliravci
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Patent number: 4997622Abstract: Magnesium alloy having a breaking load of at least 290 MPa, more particularly at least 330 MPa, having the following composition by weight: Al 2-11%, Zn 0-12%, Mn 0-0.6%, Ca 0-7%, but with the presence of at least Zn and/or Ca, having a mean particle size less than 3 .mu.m, a homogeneous matrix reinforced with intermetallic compounds having a size less than 1 .mu.m precipitated at the grain boundaries, this structure remaining unchanged after storage at 200.degree. C. for 24 hours; and a process for producing it by rapid solidification and consolidation by extrusion at a temperature between 200.degree. and 350.degree. C.Type: GrantFiled: October 25, 1989Date of Patent: March 5, 1991Assignees: Pechiney Electrometallurgie, Norsk Hydro A.S.Inventors: Gilles Regazzoni, Gilles Nussbaum, Haavard T. Gjestland