Rare Earth, Magnesium Or Alkaline Earth Metal Containing Patents (Class 420/443)
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Publication number: 20090321405Abstract: A nickel (Ni), chromium (Cr), cobalt (Co), iron (Fe), molybdenum (Mo), manganese (Mn), aluminum (Al), titanium (Ti), niobium (Nb), silicon (Si) welding alloy, articles made therefrom for use in producing weldments and methods for producing these weldments. The welding alloy contains in % by weight about: 23.5 to 25.5% Cr, 15 to 22% Co, up to 3% Fe, up to 1% Mo, up to 1% Mn, 1.1 to 2.0% Al, 0.8 to 1.8% Ti, 0.8 to 2.2% Nb, 0.05 to 0.28% Si, up to 0.3% Ta, up to 0.3% W, 0.005 to 0.08% C, 0.001 to 0.3% Zr, 0.0008 to 0.006% B, up to 0.05% rare earth metals, up to 0.025% Mg plus optional Ca and the balance Ni including trace additions and impurities.Type: ApplicationFiled: June 22, 2009Publication date: December 31, 2009Applicant: HUNTINGTON ALLOYS CORPORATIONInventors: Brian A. Baker, Gaylord D. Smith, Ronald D. Gollihue
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Publication number: 20090317287Abstract: Single crystal nickel-based superalloy compositions, single crystal nickel-based superalloy components, and methods of fabricating such components are provided. In an embodiment, by way of example only, a single crystal nickel-based superalloy composition consists essentially of, in weight percent from about 3.8 to about 4.2 percent chromium, from about 10.0 to about 10.5 percent cobalt, from about 1.8 to about 2.2 percent molybdenum, from about 4.8 to about 5.2 percent tungsten, from about 5.8 to about 6.2 percent rhenium, from about 5.5 to about 5.8 percent aluminum, from about 5.8 to about 6.2 percent tantalum, from about 3.8 to about 4.2 percent ruthenium, from about 0.13 to about 0.17 percent hafnium, and a balance of nickel.Type: ApplicationFiled: June 24, 2008Publication date: December 24, 2009Applicant: HONEYWELL INTERNATIONAL INC.Inventor: Yiping Hu
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Publication number: 20090257908Abstract: A high temperature, high strength Ni—Co—Cr alloy possessing essentially fissure-free weldability for long-life service at 538° C. to 816° C. contains in % by weight about: 23.5 to 25.5% Cr, 15-22% Co, 1.1 to 2.0% Al, 1.0 to 1.8 % Ti, 0.95 to 2.2% Nb, less than 1.0% Mo, less than 1.0% Mn, less than 0.3% Si, less than 3% Fe, less than 0.3% Ta, less than 0.3% W, 0.005 to 0.08% C, 0.01 to 0.3% Zr, 0.0008 to 0.006% B, up to 0.05% rare earth metals, 0.005% to 0.025% Mg plus optional Ca and the balance Ni including trace additions and impurities. The strength and stability is assured at 760° C. when the Al/Ti ratio is constrained to between 0.95 and 1.25. Further, the sum of Al+Ti is constrained to between 2.25 and 3.0. The upper limits for Nb and Si are defined by the relationship: (% Nb+0.95)+3.32(% Si)<3.16.Type: ApplicationFiled: April 8, 2009Publication date: October 15, 2009Applicant: HUNTINGTON ALLOYS CORPORATIONInventors: Brian A. Baker, Gaylord D. Smith, Ronald D. Gollihue
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Publication number: 20090196760Abstract: A nickel-base superalloy having excellent oxidation resistance is provided. It is useful as high-temperature members such as turbine blades and turbine vanes for jet engines or gas turbines. The nickel-base superalloy has a composition containing Co: 0.1 to 15% by weight, Cr: 0.1 to 10% by weight, Mo: 0.1 to 4.5% by weight, W: 0.1 to 15% by weight, Al: 2 to 8% by weight, Ta+Nb+Ti: 0 to 16% by weight, Hf: 0 to 5% by weight, Re: 0.1 to 16% by weight, Ru: 0.1 to 16% by weight, Si: 0.2 to 5% by weight and a balance made of Ni and unavoidable impurities.Type: ApplicationFiled: September 27, 2006Publication date: August 6, 2009Inventors: Hiroshi Harada, Kyoko Kawagishi, Toshiharu Kobayashi, Yutaka Koizumi, Atsushi Sato
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Publication number: 20090175755Abstract: Alloy composition for the manufacture of protective coatings, comprising cobalt, nickel, chromium, aluminium, yttrium and iridium in amounts so as to obtain the phases ?, ? and ?, in particular for coating a super-alloy article. Preferably, such super-alloy article is a turbine component.Type: ApplicationFiled: December 28, 2005Publication date: July 9, 2009Applicant: ANSALDO ENERGIA S.P.AInventors: Sergio Corcoruto, Tatiana Falcinelli, Fabrizio Casadei
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Publication number: 20090155119Abstract: A weldable, high temperature oxidation resistant alloy with low solidification crack sensitivity and good resistance to strain age cracking. The alloy contains by weight percent, 25% to 32% iron, 18% to 25% chromium, 3.0% to 4.5% aluminum, 0.2% to 0.6% titanium, 0.2% to 0.4% silicon, 0.2% to 0.5% manganese and the balance nickel plus impurities. The Al+Ti content should be between 3.4 and 4.2 and the Cr/Al ratio should be from about 4.5 to 8.Type: ApplicationFiled: December 12, 2007Publication date: June 18, 2009Inventors: Dwaine L. Klarstrom, Steven J. Matthews, Venkat R. Ishwar
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Publication number: 20090136769Abstract: Disclosed is a protective layer having the composition 1.5% to 2.5% rhenium, 11% to 13% cobalt, 20% to 22% chrome, 10.5% to 11.5% aluminum, 0.3% to 0.5% yttrium and or at least one equivalent metal selected from the group comprising scandium and the rare earths and the remainder consists of nickel. Existing protective layers which have a high Al and/or Cr content and which are additionally reinforced by Re-forming brittle phases that, during use, additionally embrittle under the influence of carbon. The present invention hardly exhibits a brittleness by Cr/Re depositions.Type: ApplicationFiled: October 6, 2006Publication date: May 28, 2009Inventor: Werner Stamm
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Publication number: 20090041615Abstract: Disclosed are novel nickel-base alloy compositions that may be cast as a single crystal or directionally solidified alloy consisting essentially of, by weight: 8-12% Cr, 10-14% Co, 0.3-0.9% Mo, 3-7% W, 2-8% Ta, 2.0-5.5% Al, 1.5-5.0% Ti, up to 2% Nb, less than 0.1% B, less than 0.1% Zr, 0.05-0.15% C, less than 0.5% Hf, 2-4% Re, 0.05-0.2% Si, up to 0.015% S, up to 0.1% La, up to 0.1% Y, up to 0.1% Ce, up to 0.1% Nd, up to 0.1% Dy, up to 0.1% Pr, up to 0.1% Gd, balance is Ni, and wherein (La+Y+Ce+Nd+Dy+Pr+Gd) is 0.001-0.1%. The compositions for the nickel-base superalloy have a balance between oxidation resistance, corrosion resistance, castability, and mechanical properties, such as creep resistance and thermo-mechanical fatigue resistance.Type: ApplicationFiled: July 16, 2008Publication date: February 12, 2009Applicant: SIEMENS POWER GENERATION, INC.Inventors: Allister W. James, Gerhard E. Fuchs, Douglas J. Arrell
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Patent number: 7485199Abstract: A Ni based alloy with a composition including Cr: from more than 43% to 50% or less, Mo: 0.1% to 2%, Mg: 0.001% to 0.05%, N: 0.001% to 0.04%, Mn: 0.05% to 0.5%, and where necessary also including either one, or both, of Fe: 0.05% to 1.0% and Si: 0.01% to 0.1%, and the remainder as Ni and unavoidable impurities, in which the quantity of C amongst the unavoidable impurities is restricted to 0.05% or less. It has excellent corrosion resistance relative to supercritical water environments containing inorganic acids. Also provided is a member for a supercritical water process reaction apparatus comprises the Ni based alloy.Type: GrantFiled: January 8, 2003Date of Patent: February 3, 2009Assignee: Mitsubishi Materials CorporationInventor: Katsuo Sugahara
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Publication number: 20090016926Abstract: A nickel-chromium casting alloy comprising, in weight percent, up to 0.8% of carbon, up to 1% of silicon, up to 0.2% of manganese, 15 to 40% of chromium, 0.5 to 13% of iron, 1.5 to 7% of aluminum, up to 2.5% of niobium, up to 1.5% of titanium, 0.01 to 0.4% of zirconium, up to 0.06% of nitrogen, up to 12% of cobalt, up to 5% of molybdenum, up to 6% of tungsten and from 0.01 to 0.1% of yttrium, remainder nickel, has a high resistance to carburization and oxidation even at temperatures of over 1130° C. in a carburizing and oxidizing atmosphere, as well as a high thermal stability, in particular creep rupture strength.Type: ApplicationFiled: July 8, 2008Publication date: January 15, 2009Applicant: Schmidt + Clemens GmbH + Co. KGInventors: Rolf KIRCHHEINER, Dietlinde JAKOBI, Petra BECKER, Ricky DURHAM
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Publication number: 20090004043Abstract: The corrosion-resistant nickel-base alloy combines thermal stability with corrosion resistance and mechanical strength. The alloy contains balanced proportions of nickel, molybdenum, chromium, and iron with an effective amount of yttrium to stabilize grain boundaries against unwanted reactions, which might degrade corrosion resistance, and an effective amount of boron to maintain an acceptable level of ductility. The alloy may contain minor amounts of additives or impurities, such as silicon, manganese, and aluminum. The alloy may contain between about 25-45% molybdenum, 2-6% chromium, 2-4% iron, 0.01-0.03% boron, 0.005-0.015% yttrium, and up to a maximum of 1% manganese, silicon, and aluminum, respectively, by weight, the balance being nickel. It is preferred that the combined ratio of molybdenum, chromium, and iron to nickel be in the range of about 25% to 45%.Type: ApplicationFiled: June 28, 2007Publication date: January 1, 2009Inventor: Hani M. Tawancy
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Publication number: 20080260572Abstract: A nickel-based superalloy having a good balance between corrosion and oxidation resistance. The alloy provides good mechanical properties. The superalloy is suited for directional solidification casting but can also be used for conventional or single crystal casting techniques. The superalloy is well suited for the hot section components such as blades, vanes and ring segments for gas turbine engines.Type: ApplicationFiled: April 19, 2007Publication date: October 23, 2008Inventors: Allister W. James, Douglas J. Arrell
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Publication number: 20080260571Abstract: A nickel-based superalloy that forms a chromia scale in an oxidizing environment is disclosed. The alloy provides good oxidation resistance at temperatures below 900° C. in a dry or moist atmosphere. The superalloy is well-suited for components of gas or steam turbine engines including blades and vanes.Type: ApplicationFiled: April 19, 2007Publication date: October 23, 2008Inventors: Douglas J. Arrell, Allister W. James
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Publication number: 20080253923Abstract: A nickel-based superalloy that forms a chromia scale in an oxidizing environment is disclosed. The alloy provides good oxidation resistance at temperatures below 900° C. in a dry or moist atmosphere. The superalloy is suited for components of gas or steam turbine engines including blades and vanes.Type: ApplicationFiled: April 10, 2007Publication date: October 16, 2008Inventors: Douglas J. Arrell, Allister W. James
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Publication number: 20080240926Abstract: There is provided a Co-free Ni-base superalloy having a composition containing 1.0 to 10.0 wt % of Cr, 0.1 to 3.5 wt % of Mo, 7.5 to 10.0 wt % of W, 4.0 to 8.0 wt % of Al, 12.0 wt % or less of at least one species of Ta, Nb and Ti, 0 to 2.0 wt % of Hf, 0.1 to 5.0 wt % of Re and the remainder comprised of Ni and unavoidable impurities. The Co-free Ni-base superalloy exhibits high composition stability over a long period of time and is excellent in creep properties at high temperature, and also suitable as a turbine blade or turbine vane of atomic power generation in which maintenance for radioactive contamination and so forth are easy.Type: ApplicationFiled: March 24, 2006Publication date: October 2, 2008Inventors: Toshiharu Kobayashi, Yutaka Koizumi, Hiroshi Harada, Tadaharu Yokokawa
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Publication number: 20080241580Abstract: An alloy for use as a welding overlay for boiler tubes in a low NOx coal-fired boiler comprising in % by weight: 36 to 43% Cr, 0.2 to 5.0% Fe, 0-2.0% Nb, 0-1% Mo, 0.3 to 1% Ti, 0.5 to 2% Al, 0.005 to 0.05% C, 0.005 to 0.020% (Mg+Ca), 0-1% Mn, 0-0.5% Si, less than 0.01% S, balance substantially Ni and trace additions and impurities. The alloy provides exceptional coal ash corrosion resistance in low partial pressures of oxygen. The alloy also increases in hardness and in thermal conductivity at service temperature over time. The increased hardness improves erosion resistance of the tubes while the increased thermal conductivity improves the thermal efficiency of the boiler and its power generation capabilities.Type: ApplicationFiled: November 19, 2007Publication date: October 2, 2008Applicant: HUNTINGTON ALLOYS CORPORATIONInventors: Samuel D. Kiser, Brian A. Baker
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Publication number: 20080206089Abstract: The present application relates to an alloy for use at high temperature. The invention is characterized in that the alloy consists principally of Ni, Cr and Fe and in that the alloy has a principal composition such that the levels of the elements Fe, Si, C, Nb and Mo lie within the following intervals, given in percentage by weight: Fe 5-13 Si 1-3 C <0.1 Nb <0.2 Mo <1.0 and in that Ni comprises the balance, while its level does not exceed 69% and in that the level of Cr is greater than Cr=15% and in that it is less than the lower of the two values Cr=5*Si?2.5*Fe +42.Type: ApplicationFiled: June 16, 2006Publication date: August 28, 2008Applicant: SANDVIK INTELLECTUAL PROPERTY ABInventor: Rikard Norling
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Publication number: 20080101981Abstract: The invention concerns a Ni based alloy suitable for single crystalline, directionally solidified or polycrystalline components to be used at high temperatures. The alloy is a ??/? alloy and consists of different alloying elements within defined ranges. Among other defined ranges of elements, the alloy contains Pd in a significant amount sufficient to provide the alloy with an improved resistance against hydrogen embrittlement. The invention also concerns a component designed for use as a component in a high temperature environment. Furthermore, the invention concerns a gas turbine arrangement. Moreover, the invention concerns the use of Pd for providing an alloy with improved resistance against hydrogen embrittlement.Type: ApplicationFiled: December 21, 2005Publication date: May 1, 2008Inventors: Douglas James Arrell, Magnus Hasselqvist
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Publication number: 20080038148Abstract: A nickel-molybdenum-chromium alloy, capable of withstanding both strong oxidizing and strong reducing acid solutions, contains 20.0 to 23.5 wt. % molybdenum and 13.0 to 16.5 wt. % chromium with the balance being nickel plus impurities and residuals of elements used for control of oxygen and sulfur.Type: ApplicationFiled: May 14, 2007Publication date: February 14, 2008Inventor: Paul Crook
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Patent number: 7306682Abstract: An object of this invention is to provide a single-crystal nickel-based superalloy having high creep rupture strength at high temperatures and excel at corrosion resistance and oxidation resistance at high temperatures. Single-crystal nickel-based superalloys with high temperature strength, hot corrosion resistance and oxidation resistance comprising by weight, 3.0 to 7.0% Cr, 9.5 to 15.0% Co, 4.5 to 8.0% W, 3.3 to 6.0% Re, 4.0 to 8.0% Ta, 0.8 to 2.0% Ti, 4.5 to 6.5% Al, 0.01 to 0.2% Hf, less than 0.5% Mo, 0.01% or less C, 0.005% or less B, 0.01% or less Zr, 0.005% or less O, 0.005% or less N, and balance substantially Ni.Type: GrantFiled: August 10, 2004Date of Patent: December 11, 2007Assignees: Hitachi, Ltd., The Kansai Electric Power Co., Inc., Masahiko Morinaga, Yoshinori MurataInventors: Akira Yoshinari, Ryokichi Hashizume, Masahiko Morinaga, Yoshinori Murata
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Publication number: 20070221298Abstract: The present invention provides a Ni-based super alloy including, by mass %, C: 0.01 to 0.15%; Si: 1% or less; Mn: 1% or less; P: 0.02% or less; S: 0.01% or less; Co: less than 0.10%; Cr: 16 to 22%; Mo: 4 to 10%; W: 5% or less; Al: 1.2 to 2.5%; Ti: 2.4 to 4%; B: 0.001 to 0.05%; Zr: 0.01 to 0.5%; Fe: 1% or less; and a balance of Ni and inevitable impurities.Type: ApplicationFiled: March 20, 2007Publication date: September 27, 2007Applicant: DAIDO TOKUSHUKO KABUSHIKI KAISHAInventors: Seiji Kurata, Shigeki Ueta, Tetsuya Shimizu
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Patent number: 7273662Abstract: An alloy including a Pt-group metal, Ni and Al in relative concentration to provide a ?-Ni+??-Ni3Al phase constitution, and a coating including the alloy.Type: GrantFiled: May 16, 2003Date of Patent: September 25, 2007Assignee: Iowa State University Research Foundation, Inc.Inventors: Brian Gleeson, Daniel Sordelet, Wen Wang
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Patent number: 7261783Abstract: A nickel-base superalloy article for use in turbines has increased creep resistance and lower density. The superalloy article includes, as measured in % by weight, 6.0-12.0% Mo, 5.5-6.5% Al, 3.0-7.0% Ta, 0-15% Co, 2.0-6.0% Cr, 1.0-4.0% Re, 0-1.5% W, 0-1.5% Ru, 0-2.0%-Ti, 0-3.0% Nb, 0-0.2% Hf, 0-0.02% Y, 0.001-0.005% B, 0.01-0.04% C, and a remainder including nickel plus impurities.Type: GrantFiled: September 22, 2004Date of Patent: August 28, 2007Assignee: The United States of America as Represented by the Administrator of NASAInventors: Rebecca A. MacKay, Timothy P. Gabb, James L Smialek, Michael V. Nathal
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Patent number: 7179540Abstract: A plate type heat exchanger wherein contacting portions of laminated plural plates and fins or contacting portions of laminated plural plates are brazed to form a heat exchange area, characterized in that at least the surface of a plate or fin contacting with a fluid is covered with an alloy comprising in weight ratio 25–35% of chromium, 5–7% of phosphorus, 3–5% of silicon, 0.001–0.1% of at least one selected from the group consisting of aluminum, calcium, yttrium and mischmetal, and balance containing mainly nickel. The alloy may contain 15% or less of iron and or 10% or less of molybdenum. The plate type exchanger exhibits enhanced pressure resistance and is excellent in corrosion resistance.Type: GrantFiled: December 6, 2001Date of Patent: February 20, 2007Assignees: Brazing Co., LTD., Fukuda Metal Foil & Power Co., LTD.Inventor: Kaoru Tada
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Patent number: 7172661Abstract: A high precision alloy, and in particular, high-strength nickel-based amorphous compositions for fabrication of glass-coated microwires.Type: GrantFiled: September 20, 2004Date of Patent: February 6, 2007Assignee: Global Micro Wire Technologies Ltd.Inventors: Eliezer Adar, Ehud Yaffe
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Patent number: 7169241Abstract: A Ni-based alloy hardened with the ?? phase, which is able to exhibit not only superior strength at high temperatures, but also excellent hot corrosion resistance and oxidation resistance at high temperatures in spite of containing no Re or reducing the amount of Re. The Ni-based superalloy contains, by weight, C: 0.01 to 0.5%, B: 0.01 to 0.04%, Hf: 0.1 to 2.5%, Co: 0.8 to 15%, Ta: more than 0% but less than 8.5%, Cr: 1.5 to 16%, Mo: more than 0% but less than 1.0%, W: 5 to 14%, Ti: 0.1 to 4.75%, Al: 2.5 to 7%, Nb: more than 0% but less than 4%, V: 0 to less than 1.0%, Zr: 0 to less than 0.1%, Re: 0 to less than 9%, at least one of platinum group elements: 0 to less than 0.5% in total, at least one of rare earth elements: 0 to less than 0.1% in total, and the rest being Ni except for unavoidable impurities.Type: GrantFiled: March 19, 2004Date of Patent: January 30, 2007Assignee: Hitachi, Ltd.Inventors: Hideki Tamaki, Akira Yoshinari, Akira Okayama, Tsuyoshi Takano, Hiroyuki Doi
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Patent number: 7165325Abstract: A welding material composition, which is a nickel based super alloy having ?? phase and chromium carbides precipitated. The composition comprising 18 to 25% by weight of Co, 15 to 20% by weight of Cr, 1.5 to 5.5% by weight of Al, 5 to 14% by weight of W, 0.05 to 0.15% by weight of C, 0 to 0.02% by weight of B, 0 to 1% by weight of at least one of Ta, Nb, Ti, Mo, Re and Fe, 0 to 0.5% by weight of at least one of V, Zr, rare earth elements and Y, 0 to 1% by weight of Mn, 0 to 0.5% by weight of Si, and the balance being Ni.Type: GrantFiled: August 7, 2003Date of Patent: January 23, 2007Assignee: Hitachi, Ltd.Inventors: Shinya Imano, Hiroyuki Doi, Kunihiro Ichikawa, Hideaki Ishii
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Patent number: 7141128Abstract: The invention discloses an intermetallic material consisting of the following composition by weight percent: 10% Al, 22% Cr, 36% Co, 0.2% Y, 0.2% Hf, 2% Ta, 3% Fe, remainder Ni and inevitable impurities. The invention also describes its use as a layer protecting against high temperatures and at locations of thermal turbomachines which are subject to friction or vibration.Type: GrantFiled: July 24, 2003Date of Patent: November 28, 2006Assignee: Alstom Technology LtdInventors: Andreas Kuenzler, Mohamed Nazmy, Markus Staubli
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Patent number: 6968991Abstract: A diffusion bond mixture paint and method for repairing a single-crystal superalloy article that minimizes the amount of braze alloy applied to the article. The amount of boron and eutectic brittle borides of the wide gap brazing processes is minimized, resulting in a more robust repair. The braze paint includes an alloy powder mixture, a binder, and a carrier to thin the paint.Type: GrantFiled: July 3, 2002Date of Patent: November 29, 2005Assignee: Honeywell International, Inc.Inventors: Federico Renteria, William F Hehmann
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Patent number: 6924046Abstract: A protective layer has the composition 0.5 to 2% of rhenium, 15 to 21% of chromium, 9 to 11.5% of aluminum, 0.05 to 0.7% of yttrium and/or at least one equivalent metal from the group consisting of scandium and the rare earths, 0 to 1% of ruthenium, remainder cobalt and/or nickel and production-related impurities, and is scarcely subject to any embrittlement from Cr/Re precipitations.Type: GrantFiled: November 5, 2003Date of Patent: August 2, 2005Assignee: Siemens AktiengesellschaftInventor: Werner Stamm
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Patent number: 6852177Abstract: A nickel-based alloy is provided for provide parts and members of improved oxidation-resistance and high temperature strength for use in an oxidation atmosphere at high temperatures, such as automobile parts including an electrode for an ignition plug, power plant facility parts including a gas turbine nozzle, inner parts of heat treat furnaces, and fuel cell parts. The alloy improved in oxidation-resistance, high temperature strength and hot workability consists essentially of, in mass percentage, C: 0.003 to 0.1%, Si: 1.0% or less, Mn: 2.0% or less, Cr: 12 to 32%, Fe: 20% or less, Mg: 0.001 to 0.04%, at least one element, of not more than 2.5% in total, selected from the group consisting of Nb, Ta and V, impurity elements of S: 0.01% or less, but the ratio of the Mg-content to the S-content (Mg/S) being 1 or more, and Ti: 0 inclusive to 0.02%, and the rest being Ni and incidental impurities.Type: GrantFiled: December 19, 2002Date of Patent: February 8, 2005Assignee: Hitachi Metals Ltd.Inventors: Satoshi Kubota, Toshihiro Uehara, Motoi Yamaguchi, Akihiro Toji
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Patent number: 6846575Abstract: An article includes turbulation material bonded to a surface of a substrate via a bonding agent, such as a braze alloy. In an embodiment, the turbulation material includes a particulate phase of discrete metal alloy particles having an average particle size within a range of about 125 microns to about 4000 microns. Other embodiments include methods for applying turbulation and articles for forming turbulation.Type: GrantFiled: June 5, 2003Date of Patent: January 25, 2005Assignee: General Electric CompanyInventors: Wayne Charles Hasz, Robert Alan Johnson, Ching-Pang Lee, Mark Gerard Rettig, Nesim Abuaf, John Howard Starkweather
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Publication number: 20040234410Abstract: A nickel alloy composition, having particular utility for forming an oxidation resistant blade tip on a turbine blade, preferably has a composition substantially as defined by the nominal composition Cr 4.5 wt %; Al 6 wt %; Co 4 wt %; Ta 6 wt %; Re 4 wt %; Hf 0.15 wt %; C 0.05 wt %; Si 0.1 wt %; B 0.005 wt %; W 2 wt %; La 0.003-0.005 wt %; and Y 0 0.003 to 0.Type: ApplicationFiled: February 18, 2004Publication date: November 25, 2004Applicant: ROLLS-ROYCE PLCInventors: Mark H. Shipton, Robert W. Broomfield
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Publication number: 20040229072Abstract: Nickel base superalloy consisting essentially of, in weight %, about 3% to about 12% Cr, up to about 15% Co, up to about 3% Mo, about 3% to about 10% W, up to about 6% Re, about 5% to about 7% Al, up to about 2% Ti, up to about 1% Fe, up to about 2% Nb, about 3% to about 12% Ta, up to about 0.07% C, about 0.030% to about 0.80% Hf, up to about 0.10% Zr, up to about 0.02% B, up to about 0.050% of an element selected from the group consisting of Y and Lanthanide series elements, and balance Ni and incidental impurities with a S concentration preferably of 2 ppm by weight or less. The nickel base superalloy pursuant to the invention possesses improved high temperature oxidation resistance. The nickel base superalloy as a substrate can be coated with an outwardly grown diffusion aluminide bondcoat followed by deposition of a ceramic thermal barrier coating (TBC) on the bondcoat.Type: ApplicationFiled: December 11, 2003Publication date: November 18, 2004Inventor: Kenneth S. Murphy
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Publication number: 20040180233Abstract: A product (1), in particular a gas-turbine blade (1), has a metallic basic body (2) to which a protective layer (3, 4) for protecting against corrosion is bonded. The protective layer (3, 4) has an inner layer (3) of a first MCrAlY alloy and an outer layer (4) having a second MCrAlY alloy, which is bonded to the inner layer (3). The second MCrAlY alloy is predominantly in the &ggr;-phase and includes 24% to 26% by weight of cobalt. According to a process for producing a protective layer (3, 4), the outer layer (4) is produced by re-melting a region of the inner layer (3) or by deposition of an MCrAlY alloy from a liquid phase.Type: ApplicationFiled: March 30, 2004Publication date: September 16, 2004Applicant: Siemens AktiengesellschaftInventor: Werner Stamm
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Publication number: 20040170521Abstract: Protective coatings known in the state of art can reveal either good corrosion resistance or good mechanical properties.Type: ApplicationFiled: January 9, 2004Publication date: September 2, 2004Inventor: Werner Stamm
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Patent number: 6761854Abstract: A nickel-base alloy consisting of, in weight percent, 42 to 58 nickel, 21 to 28 chromium, 12 to 18 cobalt, 4 to 9.5 molybdenum, 2 to 3.5 aluminum, 0.05 to 2 titanium, at least one microalloying agent selected from the group consisting of 0.005 to 0.1 yttrium and 0.01 to 0.6 zirconium, 0.01 to 0.15 carbon, 0 to 0.01 boron, 0 to 4 iron, 0 to 1 manganese, 0 to 1 silicon, 0 to 1 hafnium, 0 to 0.4 niobium, 0 to 0.1 nitrogen, incidental impurities and deoxidizers.Type: GrantFiled: September 4, 1998Date of Patent: July 13, 2004Assignee: Huntington Alloys CorporationInventors: Gaylord Darrell Smith, Curtis Steven Tassen
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Patent number: 6702906Abstract: A Ni-base heat resistant alloy excellent in weldability and strength at elevated temperatures and suited for use in manufacturing cracking furnace tubes and reformer furnace tubes to be used in ethylene plants as well as a welded joint therefor is provided. The alloy of the invention is a Ni-base heat-resistant alloy, which comprises C: not more than 0.1%, Si: not more than 2%, Mn: not more than 2%, P: not more than 0.025%, S: not more than 0.005%, N: not more than 0.04%, Cr: 10 to 30%, Al: 2.1 to less than 4.5%, and Mo: 2.5 to 15% or W: 2.5 to 9% or Mo and W: 2.5 to 15% in total, and satisfies the relation (1) given below: (104Si+1980P+1980S+9Al+15Ti+11Nb+1.8W+11600B)≦{1.Type: GrantFiled: July 11, 2002Date of Patent: March 9, 2004Assignee: Sumitomo Metal Industries, Ltd.Inventors: Kazuhiro Ogawa, Kazuyuki Kitamura, Hirokazu Okada, Yoshitaka Nishiyama
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Patent number: 6696176Abstract: A fusion weldable superalloy containing 0.005-0.5 wt. % scandium. In one embodiment, the superalloy may have a composition similar to IN-939 alloy, but having added scandium and having only 0.005-0.040 wt. % zirconium. A gas turbine component may be formed by an investment casting of such a scandium-containing superalloy, and may include a fusion weld repaired area. A scandium-containing nickel-based superalloy coated with an MCrAlY bond coat will have improved cyclic oxidation resistance due to the sulfur-gettering effect of the scandium.Type: GrantFiled: March 6, 2002Date of Patent: February 24, 2004Assignee: Siemens Westinghouse Power CorporationInventors: David B. Allen, Gregg P. Wagner, Brij B. Seth
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Patent number: 6696017Abstract: The present invention relates to a Ni-base brazing alloy. The alloy has a good wettability toward a material to be brazed when melting, an excellent corrosion resistance and a high strength. The alloy is used for process of joining two pieces of metal such as stainless steel. The alloy contains Cr in an mount of 25 to 35% by weight, P in an amount of 4 to 8% by weight, Si in an amount of 3 to 6% by weight, wherein the total amount of P and Si is 9 to 11.5% by weight, at least one selected from a group consisting of Al, Ca, Y and misch metal in an amount of 0.01 to 0.10% by weight, and the balance of Ni and unavoidable impurities.Type: GrantFiled: June 12, 2001Date of Patent: February 24, 2004Assignee: Fukuda Metal Foil & Powder Co., Ltd.Inventors: Shozo Nagai, Kanichi Tanaka, Kensuke Hidaka
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Patent number: 6673308Abstract: A nickel-base single-crystal superalloy, essentially consists of, in percentages by weight, 4.0% to 11.0% of cobalt, 3.5% to less than 5.0% of chromium, 0.5% to 3.0% of molybdenum, 7.0% to 10.0% of tungsten, 4.5% to 6.0% of aluminum, 0.1% to 2.0% of titanium, 5.0% to 8.0% of tantalum, 1.0% to 3.0% of rhenium, 0.01% to 0.5% of hafnium, 0.01% to 0.1% of silicon, and a balance being nickel and inevitable impurity, a total amount of rhenium and chromium being not less than 4.0% and a total amount of rhenium, molybdenum, tungsten and chromium being not more than 18.0%.Type: GrantFiled: August 30, 2001Date of Patent: January 6, 2004Assignees: Kabushiki Kaisha Toshiba, Independent Administrative Institution National Institute for Material ScienceInventors: Takehisa Hino, Yutaka Koizumi, Toshiharu Kobayashi, Shizuo Nakazawa, Hiroshi Harada, Yutaka Ishiwata, Yomei Yoshioka
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Patent number: 6660431Abstract: The present invention relates to a hydrogen storage alloy electrode composed of a hydrogen storage alloy having a CaCu5 region and a Ce2Ni7 region in the crystal structure and satisfies the relational formula: p:q=1:(4+a), where p is the sum of the mole fraction of an element occupying the Ca site of the CaCu5 region and the mole fraction of an element occupying the Ce site of the Ce2Ni7 region, q is the sum of the mole fraction of an element occupying the Cu site of the CaCu5 region and the mole fraction of an element occupying the Ni site of the Ce2Ni7 region, and −0.2≦a≦0.4. Accordingly, although the hydrogen storage alloy electrode contains a little or no Co, it is possible to obtain an electrode having little deterioration due to pulverization of the alloy and a high capacity.Type: GrantFiled: August 8, 2001Date of Patent: December 9, 2003Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Sou Kuranaka, Akihiro Maeda, Yoshio Moriwaki
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Patent number: 6652991Abstract: The addition of small amounts of CeO2 and Cr to intermetallic compositions of NiAl and FeAl improves ductility, thermal stability, thermal shock resistance, and resistance to oxidation, sulphidization and carburization.Type: GrantFiled: October 9, 2002Date of Patent: November 25, 2003Assignee: The Governors of the University of AlbertaInventors: You Wang, Weixing Chen
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Publication number: 20030211356Abstract: The present invention relates to a metallic coating to be deposited on gas turbine engine components. The metallic coating comprises up to 18 wt % cobalt, 3.0 to 18 wt % chromium, 5.0 to 15 wt % aluminum, 0.1 to 1.0 wt % yttrium, up to 0.6 wt % hafnium, up to 0.3 wt % silicon, 3.0 to 10 wt % tantalum, up to 9.0 wt % tungsten, 1.0 to 6.0 wt % rhenium, up to 10 wt % molybdenum, and the balance nickel.Type: ApplicationFiled: May 7, 2002Publication date: November 13, 2003Inventors: Russell Albert Beers, Allan A. Noetzel, Abdus Khan
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Publication number: 20030118469Abstract: A nickel-based alloy is provided for provide parts and members of improved oxidation-resistance and high temperature strength for use in an oxidation atmosphere at high temperatures, such as automobile parts including an electrode for an ignition plug, power plant facility parts including a gas turbine nozzle, inner parts of heat treat furnaces, and fuel cell parts. The alloy improved in oxidation-resistance, high temperature strength and hot workability consists essentially of, in mass percentage, C: 0.003 to 0.1%, Si: 1.0% or less, Mn: 2.0% or less, Cr: 12 to 32%, Fe: 20% or less, Mg: 0.001 to 0.04%, at least one element, of not more than 2.5% in total, selected from the group consisting of Nb, Ta and V, impurity elements of S: 0.01% or less, but the ratio of the Mg-content to the S-content (Mg/S) being 1 or more, and Ti: 0 inclusive to 0.02%, and the rest being Ni and incidental impurities.Type: ApplicationFiled: December 19, 2002Publication date: June 26, 2003Applicant: HITACHI METALS, LTD.Inventors: Satoshi Kubota, Toshihiro Uehara, Motoi Yamaguchi, Akihiro Toji
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Patent number: 6537393Abstract: A nickel base alloy for high temperature thermal processing hardware requiring ultra-low spallation and metal loss rates in oxidizing and nitriding atmospheres for use in wire mesh belting, thermocouple sheathing, resistive heating elements, heat sensing cables, furnace internals and like hardware. The compositional range of the alloy is 15.0-23.0 % Cr, 0.5-2.0 % Si, 0.0-4.0% Mo, 0.0-1.2 % Nb, 0.0-3.0 % Fe, 0.0-0.5 % Ti, 0.0-0.5 % Al, 0.0-0.3 % Mn, 0.0-0.1 % Zr, 0.0-0.06 % Ce, 0.005-0.025 % Mg, 0.0005-0.005 % B, 0.005-0.3 % C, 0.0-20.0 % Co, balance Ni. The alloy possesses a high degree of hot and cold workability, phase stability and strength retention at elevated temperatures.Type: GrantFiled: August 29, 2001Date of Patent: March 25, 2003Assignee: INCO Alloys International, Inc.Inventors: Norman C. Farr, Gaylord D. Smith
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Publication number: 20030041930Abstract: The present invention relates to an improved single crystal nickel base superalloy and a process for making same. The single crystal nickel base superalloy has a composition comprising 3 to 12 wt % chromium, up to 3 wt % molybdenum, 3 to 10 wt % tungsten, up to 5 wt % rhenium, 6 to 12 wt % tantalum, 4 to 7 wt % aluminum, up to 15 wt % cobalt, up to 0.05 wt % carbon, up to 0.02 wt % boron, up to 0.1 wt % zirconium, up to 0.8 wt % hafnium, up to 2.0 wt % niobium, up to 1.0 wt % vanadium, up to 0.7 wt % titanium, up to 10 wt % of at least one element selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, and mixtures thereof, and the balance essentially nickel. The single crystal nickel base superalloy has a microstructure which is pore-free and eutectic &ggr;-&ggr;′ free and which has a gamma prime morphology with a bimodal &ggr;′ distribution.Type: ApplicationFiled: August 30, 2001Publication date: March 6, 2003Inventors: Daniel P. DeLuca, Charles M. Biondo
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Patent number: 6524745Abstract: An electrochemically stabilized Ca—Ni hydrogen storage alloy material for use as the active negative electrode material of an alkaline electrochemical cell. The alloy material includes at least one modifier element which stabilizes the alloy material from degradation during electrochemical cycling in an alkaline cell, by protecting calcium within the alloy and preventing dissolution of calcium into the alkaline electrolyte. The alloy has the formula (Ca1−x−yMxNi2y)Ni5−zQz, where M is at least one element selected from the group consisting of misch metal, rare earth metals, zirconium and mixtures of Zr with Ti or V, Q is at least one element selected form the group consisting of Si, Al, Ge, Sn, In, Cu, Zn, Co, and mixtures thereof, x ranges between about 0.02 and 0.2, y ranges between about 0.02 and 0.4, and z ranges from about 0.05 to about 1.00.Type: GrantFiled: May 19, 1999Date of Patent: February 25, 2003Assignee: Energy Conversion Devices, Inc.Inventors: Stanford R. Ovshinsky, Rosa T. Young
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Patent number: 6491769Abstract: A high strength, corrosion resistant Cr—Co—Ni base alloy for long-life service at 530° C. to 820° C. containing in % by weight about 23.5-25.5% Cr, 15.0-22.0% Co, 0.2-2.0% Al, 0.5-2.5% Ti, 0.5-2.5% Nb, up to 2.0% Mo, up to 1.0% Mn, 0.3-1.0% Si, up to 3.0% Fe, up to 0.3% Ta, up to 0.3% W, 0.005-0.08% C, 0.01-0.3 % Zr, 0.001-0.01% B, up to 0.05% rare earth as misch metal, 0.005-0.025% Mg plus optional Ca, balance Ni including trace additions and impurities. The alloy provides a combination of strength, ductility, stability, toughness and oxidation/sulfidation resistance so as to render the alloy range uniquely suitable for engineering applications where oxygen/sulfur-containing atmospheres are life limiting, in applications such as exhaust valves for diesel engines and in tubes for coal-fired steam boilers.Type: GrantFiled: August 29, 2001Date of Patent: December 10, 2002Assignee: Inco Alloys International, Inc.Inventors: Gaylord D. Smith, Brian A. Baker
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Publication number: 20020085943Abstract: The present invention relates to a Ni-base brazing alloy. The alloy has a good wettability toward a material to be brazed when melting, an excellent corrosion resistance and a high strength. The alloy is used for process of joining two pieces of metal such as stainless steel. The alloy contains Cr in an mount of 25 to 35% by weight, P in an amount of 4 to 8% by weight, Si in an amount of 3 to 6% by weight, wherein the total amount of P and Si is 9 to 11.5% by weight, at least one selected from a group consisting of Al, Ca, Y and misch metal in an amount of 0.01 to 0.10% by weight, and the balance of Ni and unavoidable impurities.Type: ApplicationFiled: June 12, 2001Publication date: July 4, 2002Applicant: Fukuda Metal Foil & Powder Co., Ltd.Inventors: Shozo Nagai, Kanichi Tanaka, Kensuke Hidaka