Rare Earth, Magnesium Or Alkaline Earth Metal Containing Patents (Class 420/443)
  • Publication number: 20090321405
    Abstract: A nickel (Ni), chromium (Cr), cobalt (Co), iron (Fe), molybdenum (Mo), manganese (Mn), aluminum (Al), titanium (Ti), niobium (Nb), silicon (Si) welding alloy, articles made therefrom for use in producing weldments and methods for producing these weldments. The welding alloy contains in % by weight about: 23.5 to 25.5% Cr, 15 to 22% Co, up to 3% Fe, up to 1% Mo, up to 1% Mn, 1.1 to 2.0% Al, 0.8 to 1.8% Ti, 0.8 to 2.2% Nb, 0.05 to 0.28% Si, up to 0.3% Ta, up to 0.3% W, 0.005 to 0.08% C, 0.001 to 0.3% Zr, 0.0008 to 0.006% B, up to 0.05% rare earth metals, up to 0.025% Mg plus optional Ca and the balance Ni including trace additions and impurities.
    Type: Application
    Filed: June 22, 2009
    Publication date: December 31, 2009
    Applicant: HUNTINGTON ALLOYS CORPORATION
    Inventors: Brian A. Baker, Gaylord D. Smith, Ronald D. Gollihue
  • Publication number: 20090317287
    Abstract: Single crystal nickel-based superalloy compositions, single crystal nickel-based superalloy components, and methods of fabricating such components are provided. In an embodiment, by way of example only, a single crystal nickel-based superalloy composition consists essentially of, in weight percent from about 3.8 to about 4.2 percent chromium, from about 10.0 to about 10.5 percent cobalt, from about 1.8 to about 2.2 percent molybdenum, from about 4.8 to about 5.2 percent tungsten, from about 5.8 to about 6.2 percent rhenium, from about 5.5 to about 5.8 percent aluminum, from about 5.8 to about 6.2 percent tantalum, from about 3.8 to about 4.2 percent ruthenium, from about 0.13 to about 0.17 percent hafnium, and a balance of nickel.
    Type: Application
    Filed: June 24, 2008
    Publication date: December 24, 2009
    Applicant: HONEYWELL INTERNATIONAL INC.
    Inventor: Yiping Hu
  • Publication number: 20090257908
    Abstract: A high temperature, high strength Ni—Co—Cr alloy possessing essentially fissure-free weldability for long-life service at 538° C. to 816° C. contains in % by weight about: 23.5 to 25.5% Cr, 15-22% Co, 1.1 to 2.0% Al, 1.0 to 1.8 % Ti, 0.95 to 2.2% Nb, less than 1.0% Mo, less than 1.0% Mn, less than 0.3% Si, less than 3% Fe, less than 0.3% Ta, less than 0.3% W, 0.005 to 0.08% C, 0.01 to 0.3% Zr, 0.0008 to 0.006% B, up to 0.05% rare earth metals, 0.005% to 0.025% Mg plus optional Ca and the balance Ni including trace additions and impurities. The strength and stability is assured at 760° C. when the Al/Ti ratio is constrained to between 0.95 and 1.25. Further, the sum of Al+Ti is constrained to between 2.25 and 3.0. The upper limits for Nb and Si are defined by the relationship: (% Nb+0.95)+3.32(% Si)<3.16.
    Type: Application
    Filed: April 8, 2009
    Publication date: October 15, 2009
    Applicant: HUNTINGTON ALLOYS CORPORATION
    Inventors: Brian A. Baker, Gaylord D. Smith, Ronald D. Gollihue
  • Publication number: 20090196760
    Abstract: A nickel-base superalloy having excellent oxidation resistance is provided. It is useful as high-temperature members such as turbine blades and turbine vanes for jet engines or gas turbines. The nickel-base superalloy has a composition containing Co: 0.1 to 15% by weight, Cr: 0.1 to 10% by weight, Mo: 0.1 to 4.5% by weight, W: 0.1 to 15% by weight, Al: 2 to 8% by weight, Ta+Nb+Ti: 0 to 16% by weight, Hf: 0 to 5% by weight, Re: 0.1 to 16% by weight, Ru: 0.1 to 16% by weight, Si: 0.2 to 5% by weight and a balance made of Ni and unavoidable impurities.
    Type: Application
    Filed: September 27, 2006
    Publication date: August 6, 2009
    Inventors: Hiroshi Harada, Kyoko Kawagishi, Toshiharu Kobayashi, Yutaka Koizumi, Atsushi Sato
  • Publication number: 20090175755
    Abstract: Alloy composition for the manufacture of protective coatings, comprising cobalt, nickel, chromium, aluminium, yttrium and iridium in amounts so as to obtain the phases ?, ? and ?, in particular for coating a super-alloy article. Preferably, such super-alloy article is a turbine component.
    Type: Application
    Filed: December 28, 2005
    Publication date: July 9, 2009
    Applicant: ANSALDO ENERGIA S.P.A
    Inventors: Sergio Corcoruto, Tatiana Falcinelli, Fabrizio Casadei
  • Publication number: 20090155119
    Abstract: A weldable, high temperature oxidation resistant alloy with low solidification crack sensitivity and good resistance to strain age cracking. The alloy contains by weight percent, 25% to 32% iron, 18% to 25% chromium, 3.0% to 4.5% aluminum, 0.2% to 0.6% titanium, 0.2% to 0.4% silicon, 0.2% to 0.5% manganese and the balance nickel plus impurities. The Al+Ti content should be between 3.4 and 4.2 and the Cr/Al ratio should be from about 4.5 to 8.
    Type: Application
    Filed: December 12, 2007
    Publication date: June 18, 2009
    Inventors: Dwaine L. Klarstrom, Steven J. Matthews, Venkat R. Ishwar
  • Publication number: 20090136769
    Abstract: Disclosed is a protective layer having the composition 1.5% to 2.5% rhenium, 11% to 13% cobalt, 20% to 22% chrome, 10.5% to 11.5% aluminum, 0.3% to 0.5% yttrium and or at least one equivalent metal selected from the group comprising scandium and the rare earths and the remainder consists of nickel. Existing protective layers which have a high Al and/or Cr content and which are additionally reinforced by Re-forming brittle phases that, during use, additionally embrittle under the influence of carbon. The present invention hardly exhibits a brittleness by Cr/Re depositions.
    Type: Application
    Filed: October 6, 2006
    Publication date: May 28, 2009
    Inventor: Werner Stamm
  • Publication number: 20090041615
    Abstract: Disclosed are novel nickel-base alloy compositions that may be cast as a single crystal or directionally solidified alloy consisting essentially of, by weight: 8-12% Cr, 10-14% Co, 0.3-0.9% Mo, 3-7% W, 2-8% Ta, 2.0-5.5% Al, 1.5-5.0% Ti, up to 2% Nb, less than 0.1% B, less than 0.1% Zr, 0.05-0.15% C, less than 0.5% Hf, 2-4% Re, 0.05-0.2% Si, up to 0.015% S, up to 0.1% La, up to 0.1% Y, up to 0.1% Ce, up to 0.1% Nd, up to 0.1% Dy, up to 0.1% Pr, up to 0.1% Gd, balance is Ni, and wherein (La+Y+Ce+Nd+Dy+Pr+Gd) is 0.001-0.1%. The compositions for the nickel-base superalloy have a balance between oxidation resistance, corrosion resistance, castability, and mechanical properties, such as creep resistance and thermo-mechanical fatigue resistance.
    Type: Application
    Filed: July 16, 2008
    Publication date: February 12, 2009
    Applicant: SIEMENS POWER GENERATION, INC.
    Inventors: Allister W. James, Gerhard E. Fuchs, Douglas J. Arrell
  • Patent number: 7485199
    Abstract: A Ni based alloy with a composition including Cr: from more than 43% to 50% or less, Mo: 0.1% to 2%, Mg: 0.001% to 0.05%, N: 0.001% to 0.04%, Mn: 0.05% to 0.5%, and where necessary also including either one, or both, of Fe: 0.05% to 1.0% and Si: 0.01% to 0.1%, and the remainder as Ni and unavoidable impurities, in which the quantity of C amongst the unavoidable impurities is restricted to 0.05% or less. It has excellent corrosion resistance relative to supercritical water environments containing inorganic acids. Also provided is a member for a supercritical water process reaction apparatus comprises the Ni based alloy.
    Type: Grant
    Filed: January 8, 2003
    Date of Patent: February 3, 2009
    Assignee: Mitsubishi Materials Corporation
    Inventor: Katsuo Sugahara
  • Publication number: 20090016926
    Abstract: A nickel-chromium casting alloy comprising, in weight percent, up to 0.8% of carbon, up to 1% of silicon, up to 0.2% of manganese, 15 to 40% of chromium, 0.5 to 13% of iron, 1.5 to 7% of aluminum, up to 2.5% of niobium, up to 1.5% of titanium, 0.01 to 0.4% of zirconium, up to 0.06% of nitrogen, up to 12% of cobalt, up to 5% of molybdenum, up to 6% of tungsten and from 0.01 to 0.1% of yttrium, remainder nickel, has a high resistance to carburization and oxidation even at temperatures of over 1130° C. in a carburizing and oxidizing atmosphere, as well as a high thermal stability, in particular creep rupture strength.
    Type: Application
    Filed: July 8, 2008
    Publication date: January 15, 2009
    Applicant: Schmidt + Clemens GmbH + Co. KG
    Inventors: Rolf KIRCHHEINER, Dietlinde JAKOBI, Petra BECKER, Ricky DURHAM
  • Publication number: 20090004043
    Abstract: The corrosion-resistant nickel-base alloy combines thermal stability with corrosion resistance and mechanical strength. The alloy contains balanced proportions of nickel, molybdenum, chromium, and iron with an effective amount of yttrium to stabilize grain boundaries against unwanted reactions, which might degrade corrosion resistance, and an effective amount of boron to maintain an acceptable level of ductility. The alloy may contain minor amounts of additives or impurities, such as silicon, manganese, and aluminum. The alloy may contain between about 25-45% molybdenum, 2-6% chromium, 2-4% iron, 0.01-0.03% boron, 0.005-0.015% yttrium, and up to a maximum of 1% manganese, silicon, and aluminum, respectively, by weight, the balance being nickel. It is preferred that the combined ratio of molybdenum, chromium, and iron to nickel be in the range of about 25% to 45%.
    Type: Application
    Filed: June 28, 2007
    Publication date: January 1, 2009
    Inventor: Hani M. Tawancy
  • Publication number: 20080260572
    Abstract: A nickel-based superalloy having a good balance between corrosion and oxidation resistance. The alloy provides good mechanical properties. The superalloy is suited for directional solidification casting but can also be used for conventional or single crystal casting techniques. The superalloy is well suited for the hot section components such as blades, vanes and ring segments for gas turbine engines.
    Type: Application
    Filed: April 19, 2007
    Publication date: October 23, 2008
    Inventors: Allister W. James, Douglas J. Arrell
  • Publication number: 20080260571
    Abstract: A nickel-based superalloy that forms a chromia scale in an oxidizing environment is disclosed. The alloy provides good oxidation resistance at temperatures below 900° C. in a dry or moist atmosphere. The superalloy is well-suited for components of gas or steam turbine engines including blades and vanes.
    Type: Application
    Filed: April 19, 2007
    Publication date: October 23, 2008
    Inventors: Douglas J. Arrell, Allister W. James
  • Publication number: 20080253923
    Abstract: A nickel-based superalloy that forms a chromia scale in an oxidizing environment is disclosed. The alloy provides good oxidation resistance at temperatures below 900° C. in a dry or moist atmosphere. The superalloy is suited for components of gas or steam turbine engines including blades and vanes.
    Type: Application
    Filed: April 10, 2007
    Publication date: October 16, 2008
    Inventors: Douglas J. Arrell, Allister W. James
  • Publication number: 20080240926
    Abstract: There is provided a Co-free Ni-base superalloy having a composition containing 1.0 to 10.0 wt % of Cr, 0.1 to 3.5 wt % of Mo, 7.5 to 10.0 wt % of W, 4.0 to 8.0 wt % of Al, 12.0 wt % or less of at least one species of Ta, Nb and Ti, 0 to 2.0 wt % of Hf, 0.1 to 5.0 wt % of Re and the remainder comprised of Ni and unavoidable impurities. The Co-free Ni-base superalloy exhibits high composition stability over a long period of time and is excellent in creep properties at high temperature, and also suitable as a turbine blade or turbine vane of atomic power generation in which maintenance for radioactive contamination and so forth are easy.
    Type: Application
    Filed: March 24, 2006
    Publication date: October 2, 2008
    Inventors: Toshiharu Kobayashi, Yutaka Koizumi, Hiroshi Harada, Tadaharu Yokokawa
  • Publication number: 20080241580
    Abstract: An alloy for use as a welding overlay for boiler tubes in a low NOx coal-fired boiler comprising in % by weight: 36 to 43% Cr, 0.2 to 5.0% Fe, 0-2.0% Nb, 0-1% Mo, 0.3 to 1% Ti, 0.5 to 2% Al, 0.005 to 0.05% C, 0.005 to 0.020% (Mg+Ca), 0-1% Mn, 0-0.5% Si, less than 0.01% S, balance substantially Ni and trace additions and impurities. The alloy provides exceptional coal ash corrosion resistance in low partial pressures of oxygen. The alloy also increases in hardness and in thermal conductivity at service temperature over time. The increased hardness improves erosion resistance of the tubes while the increased thermal conductivity improves the thermal efficiency of the boiler and its power generation capabilities.
    Type: Application
    Filed: November 19, 2007
    Publication date: October 2, 2008
    Applicant: HUNTINGTON ALLOYS CORPORATION
    Inventors: Samuel D. Kiser, Brian A. Baker
  • Publication number: 20080206089
    Abstract: The present application relates to an alloy for use at high temperature. The invention is characterized in that the alloy consists principally of Ni, Cr and Fe and in that the alloy has a principal composition such that the levels of the elements Fe, Si, C, Nb and Mo lie within the following intervals, given in percentage by weight: Fe 5-13 Si 1-3 C <0.1 Nb <0.2 Mo <1.0 and in that Ni comprises the balance, while its level does not exceed 69% and in that the level of Cr is greater than Cr=15% and in that it is less than the lower of the two values Cr=5*Si?2.5*Fe +42.
    Type: Application
    Filed: June 16, 2006
    Publication date: August 28, 2008
    Applicant: SANDVIK INTELLECTUAL PROPERTY AB
    Inventor: Rikard Norling
  • Publication number: 20080101981
    Abstract: The invention concerns a Ni based alloy suitable for single crystalline, directionally solidified or polycrystalline components to be used at high temperatures. The alloy is a ??/? alloy and consists of different alloying elements within defined ranges. Among other defined ranges of elements, the alloy contains Pd in a significant amount sufficient to provide the alloy with an improved resistance against hydrogen embrittlement. The invention also concerns a component designed for use as a component in a high temperature environment. Furthermore, the invention concerns a gas turbine arrangement. Moreover, the invention concerns the use of Pd for providing an alloy with improved resistance against hydrogen embrittlement.
    Type: Application
    Filed: December 21, 2005
    Publication date: May 1, 2008
    Inventors: Douglas James Arrell, Magnus Hasselqvist
  • Publication number: 20080038148
    Abstract: A nickel-molybdenum-chromium alloy, capable of withstanding both strong oxidizing and strong reducing acid solutions, contains 20.0 to 23.5 wt. % molybdenum and 13.0 to 16.5 wt. % chromium with the balance being nickel plus impurities and residuals of elements used for control of oxygen and sulfur.
    Type: Application
    Filed: May 14, 2007
    Publication date: February 14, 2008
    Inventor: Paul Crook
  • Patent number: 7306682
    Abstract: An object of this invention is to provide a single-crystal nickel-based superalloy having high creep rupture strength at high temperatures and excel at corrosion resistance and oxidation resistance at high temperatures. Single-crystal nickel-based superalloys with high temperature strength, hot corrosion resistance and oxidation resistance comprising by weight, 3.0 to 7.0% Cr, 9.5 to 15.0% Co, 4.5 to 8.0% W, 3.3 to 6.0% Re, 4.0 to 8.0% Ta, 0.8 to 2.0% Ti, 4.5 to 6.5% Al, 0.01 to 0.2% Hf, less than 0.5% Mo, 0.01% or less C, 0.005% or less B, 0.01% or less Zr, 0.005% or less O, 0.005% or less N, and balance substantially Ni.
    Type: Grant
    Filed: August 10, 2004
    Date of Patent: December 11, 2007
    Assignees: Hitachi, Ltd., The Kansai Electric Power Co., Inc., Masahiko Morinaga, Yoshinori Murata
    Inventors: Akira Yoshinari, Ryokichi Hashizume, Masahiko Morinaga, Yoshinori Murata
  • Publication number: 20070221298
    Abstract: The present invention provides a Ni-based super alloy including, by mass %, C: 0.01 to 0.15%; Si: 1% or less; Mn: 1% or less; P: 0.02% or less; S: 0.01% or less; Co: less than 0.10%; Cr: 16 to 22%; Mo: 4 to 10%; W: 5% or less; Al: 1.2 to 2.5%; Ti: 2.4 to 4%; B: 0.001 to 0.05%; Zr: 0.01 to 0.5%; Fe: 1% or less; and a balance of Ni and inevitable impurities.
    Type: Application
    Filed: March 20, 2007
    Publication date: September 27, 2007
    Applicant: DAIDO TOKUSHUKO KABUSHIKI KAISHA
    Inventors: Seiji Kurata, Shigeki Ueta, Tetsuya Shimizu
  • Patent number: 7273662
    Abstract: An alloy including a Pt-group metal, Ni and Al in relative concentration to provide a ?-Ni+??-Ni3Al phase constitution, and a coating including the alloy.
    Type: Grant
    Filed: May 16, 2003
    Date of Patent: September 25, 2007
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Brian Gleeson, Daniel Sordelet, Wen Wang
  • Patent number: 7261783
    Abstract: A nickel-base superalloy article for use in turbines has increased creep resistance and lower density. The superalloy article includes, as measured in % by weight, 6.0-12.0% Mo, 5.5-6.5% Al, 3.0-7.0% Ta, 0-15% Co, 2.0-6.0% Cr, 1.0-4.0% Re, 0-1.5% W, 0-1.5% Ru, 0-2.0%-Ti, 0-3.0% Nb, 0-0.2% Hf, 0-0.02% Y, 0.001-0.005% B, 0.01-0.04% C, and a remainder including nickel plus impurities.
    Type: Grant
    Filed: September 22, 2004
    Date of Patent: August 28, 2007
    Assignee: The United States of America as Represented by the Administrator of NASA
    Inventors: Rebecca A. MacKay, Timothy P. Gabb, James L Smialek, Michael V. Nathal
  • Patent number: 7179540
    Abstract: A plate type heat exchanger wherein contacting portions of laminated plural plates and fins or contacting portions of laminated plural plates are brazed to form a heat exchange area, characterized in that at least the surface of a plate or fin contacting with a fluid is covered with an alloy comprising in weight ratio 25–35% of chromium, 5–7% of phosphorus, 3–5% of silicon, 0.001–0.1% of at least one selected from the group consisting of aluminum, calcium, yttrium and mischmetal, and balance containing mainly nickel. The alloy may contain 15% or less of iron and or 10% or less of molybdenum. The plate type exchanger exhibits enhanced pressure resistance and is excellent in corrosion resistance.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: February 20, 2007
    Assignees: Brazing Co., LTD., Fukuda Metal Foil & Power Co., LTD.
    Inventor: Kaoru Tada
  • Patent number: 7172661
    Abstract: A high precision alloy, and in particular, high-strength nickel-based amorphous compositions for fabrication of glass-coated microwires.
    Type: Grant
    Filed: September 20, 2004
    Date of Patent: February 6, 2007
    Assignee: Global Micro Wire Technologies Ltd.
    Inventors: Eliezer Adar, Ehud Yaffe
  • Patent number: 7169241
    Abstract: A Ni-based alloy hardened with the ?? phase, which is able to exhibit not only superior strength at high temperatures, but also excellent hot corrosion resistance and oxidation resistance at high temperatures in spite of containing no Re or reducing the amount of Re. The Ni-based superalloy contains, by weight, C: 0.01 to 0.5%, B: 0.01 to 0.04%, Hf: 0.1 to 2.5%, Co: 0.8 to 15%, Ta: more than 0% but less than 8.5%, Cr: 1.5 to 16%, Mo: more than 0% but less than 1.0%, W: 5 to 14%, Ti: 0.1 to 4.75%, Al: 2.5 to 7%, Nb: more than 0% but less than 4%, V: 0 to less than 1.0%, Zr: 0 to less than 0.1%, Re: 0 to less than 9%, at least one of platinum group elements: 0 to less than 0.5% in total, at least one of rare earth elements: 0 to less than 0.1% in total, and the rest being Ni except for unavoidable impurities.
    Type: Grant
    Filed: March 19, 2004
    Date of Patent: January 30, 2007
    Assignee: Hitachi, Ltd.
    Inventors: Hideki Tamaki, Akira Yoshinari, Akira Okayama, Tsuyoshi Takano, Hiroyuki Doi
  • Patent number: 7165325
    Abstract: A welding material composition, which is a nickel based super alloy having ?? phase and chromium carbides precipitated. The composition comprising 18 to 25% by weight of Co, 15 to 20% by weight of Cr, 1.5 to 5.5% by weight of Al, 5 to 14% by weight of W, 0.05 to 0.15% by weight of C, 0 to 0.02% by weight of B, 0 to 1% by weight of at least one of Ta, Nb, Ti, Mo, Re and Fe, 0 to 0.5% by weight of at least one of V, Zr, rare earth elements and Y, 0 to 1% by weight of Mn, 0 to 0.5% by weight of Si, and the balance being Ni.
    Type: Grant
    Filed: August 7, 2003
    Date of Patent: January 23, 2007
    Assignee: Hitachi, Ltd.
    Inventors: Shinya Imano, Hiroyuki Doi, Kunihiro Ichikawa, Hideaki Ishii
  • Patent number: 7141128
    Abstract: The invention discloses an intermetallic material consisting of the following composition by weight percent: 10% Al, 22% Cr, 36% Co, 0.2% Y, 0.2% Hf, 2% Ta, 3% Fe, remainder Ni and inevitable impurities. The invention also describes its use as a layer protecting against high temperatures and at locations of thermal turbomachines which are subject to friction or vibration.
    Type: Grant
    Filed: July 24, 2003
    Date of Patent: November 28, 2006
    Assignee: Alstom Technology Ltd
    Inventors: Andreas Kuenzler, Mohamed Nazmy, Markus Staubli
  • Patent number: 6968991
    Abstract: A diffusion bond mixture paint and method for repairing a single-crystal superalloy article that minimizes the amount of braze alloy applied to the article. The amount of boron and eutectic brittle borides of the wide gap brazing processes is minimized, resulting in a more robust repair. The braze paint includes an alloy powder mixture, a binder, and a carrier to thin the paint.
    Type: Grant
    Filed: July 3, 2002
    Date of Patent: November 29, 2005
    Assignee: Honeywell International, Inc.
    Inventors: Federico Renteria, William F Hehmann
  • Patent number: 6924046
    Abstract: A protective layer has the composition 0.5 to 2% of rhenium, 15 to 21% of chromium, 9 to 11.5% of aluminum, 0.05 to 0.7% of yttrium and/or at least one equivalent metal from the group consisting of scandium and the rare earths, 0 to 1% of ruthenium, remainder cobalt and/or nickel and production-related impurities, and is scarcely subject to any embrittlement from Cr/Re precipitations.
    Type: Grant
    Filed: November 5, 2003
    Date of Patent: August 2, 2005
    Assignee: Siemens Aktiengesellschaft
    Inventor: Werner Stamm
  • Patent number: 6852177
    Abstract: A nickel-based alloy is provided for provide parts and members of improved oxidation-resistance and high temperature strength for use in an oxidation atmosphere at high temperatures, such as automobile parts including an electrode for an ignition plug, power plant facility parts including a gas turbine nozzle, inner parts of heat treat furnaces, and fuel cell parts. The alloy improved in oxidation-resistance, high temperature strength and hot workability consists essentially of, in mass percentage, C: 0.003 to 0.1%, Si: 1.0% or less, Mn: 2.0% or less, Cr: 12 to 32%, Fe: 20% or less, Mg: 0.001 to 0.04%, at least one element, of not more than 2.5% in total, selected from the group consisting of Nb, Ta and V, impurity elements of S: 0.01% or less, but the ratio of the Mg-content to the S-content (Mg/S) being 1 or more, and Ti: 0 inclusive to 0.02%, and the rest being Ni and incidental impurities.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: February 8, 2005
    Assignee: Hitachi Metals Ltd.
    Inventors: Satoshi Kubota, Toshihiro Uehara, Motoi Yamaguchi, Akihiro Toji
  • Patent number: 6846575
    Abstract: An article includes turbulation material bonded to a surface of a substrate via a bonding agent, such as a braze alloy. In an embodiment, the turbulation material includes a particulate phase of discrete metal alloy particles having an average particle size within a range of about 125 microns to about 4000 microns. Other embodiments include methods for applying turbulation and articles for forming turbulation.
    Type: Grant
    Filed: June 5, 2003
    Date of Patent: January 25, 2005
    Assignee: General Electric Company
    Inventors: Wayne Charles Hasz, Robert Alan Johnson, Ching-Pang Lee, Mark Gerard Rettig, Nesim Abuaf, John Howard Starkweather
  • Publication number: 20040234410
    Abstract: A nickel alloy composition, having particular utility for forming an oxidation resistant blade tip on a turbine blade, preferably has a composition substantially as defined by the nominal composition Cr 4.5 wt %; Al 6 wt %; Co 4 wt %; Ta 6 wt %; Re 4 wt %; Hf 0.15 wt %; C 0.05 wt %; Si 0.1 wt %; B 0.005 wt %; W 2 wt %; La 0.003-0.005 wt %; and Y 0 0.003 to 0.
    Type: Application
    Filed: February 18, 2004
    Publication date: November 25, 2004
    Applicant: ROLLS-ROYCE PLC
    Inventors: Mark H. Shipton, Robert W. Broomfield
  • Publication number: 20040229072
    Abstract: Nickel base superalloy consisting essentially of, in weight %, about 3% to about 12% Cr, up to about 15% Co, up to about 3% Mo, about 3% to about 10% W, up to about 6% Re, about 5% to about 7% Al, up to about 2% Ti, up to about 1% Fe, up to about 2% Nb, about 3% to about 12% Ta, up to about 0.07% C, about 0.030% to about 0.80% Hf, up to about 0.10% Zr, up to about 0.02% B, up to about 0.050% of an element selected from the group consisting of Y and Lanthanide series elements, and balance Ni and incidental impurities with a S concentration preferably of 2 ppm by weight or less. The nickel base superalloy pursuant to the invention possesses improved high temperature oxidation resistance. The nickel base superalloy as a substrate can be coated with an outwardly grown diffusion aluminide bondcoat followed by deposition of a ceramic thermal barrier coating (TBC) on the bondcoat.
    Type: Application
    Filed: December 11, 2003
    Publication date: November 18, 2004
    Inventor: Kenneth S. Murphy
  • Publication number: 20040180233
    Abstract: A product (1), in particular a gas-turbine blade (1), has a metallic basic body (2) to which a protective layer (3, 4) for protecting against corrosion is bonded. The protective layer (3, 4) has an inner layer (3) of a first MCrAlY alloy and an outer layer (4) having a second MCrAlY alloy, which is bonded to the inner layer (3). The second MCrAlY alloy is predominantly in the &ggr;-phase and includes 24% to 26% by weight of cobalt. According to a process for producing a protective layer (3, 4), the outer layer (4) is produced by re-melting a region of the inner layer (3) or by deposition of an MCrAlY alloy from a liquid phase.
    Type: Application
    Filed: March 30, 2004
    Publication date: September 16, 2004
    Applicant: Siemens Aktiengesellschaft
    Inventor: Werner Stamm
  • Publication number: 20040170521
    Abstract: Protective coatings known in the state of art can reveal either good corrosion resistance or good mechanical properties.
    Type: Application
    Filed: January 9, 2004
    Publication date: September 2, 2004
    Inventor: Werner Stamm
  • Patent number: 6761854
    Abstract: A nickel-base alloy consisting of, in weight percent, 42 to 58 nickel, 21 to 28 chromium, 12 to 18 cobalt, 4 to 9.5 molybdenum, 2 to 3.5 aluminum, 0.05 to 2 titanium, at least one microalloying agent selected from the group consisting of 0.005 to 0.1 yttrium and 0.01 to 0.6 zirconium, 0.01 to 0.15 carbon, 0 to 0.01 boron, 0 to 4 iron, 0 to 1 manganese, 0 to 1 silicon, 0 to 1 hafnium, 0 to 0.4 niobium, 0 to 0.1 nitrogen, incidental impurities and deoxidizers.
    Type: Grant
    Filed: September 4, 1998
    Date of Patent: July 13, 2004
    Assignee: Huntington Alloys Corporation
    Inventors: Gaylord Darrell Smith, Curtis Steven Tassen
  • Patent number: 6702906
    Abstract: A Ni-base heat resistant alloy excellent in weldability and strength at elevated temperatures and suited for use in manufacturing cracking furnace tubes and reformer furnace tubes to be used in ethylene plants as well as a welded joint therefor is provided. The alloy of the invention is a Ni-base heat-resistant alloy, which comprises C: not more than 0.1%, Si: not more than 2%, Mn: not more than 2%, P: not more than 0.025%, S: not more than 0.005%, N: not more than 0.04%, Cr: 10 to 30%, Al: 2.1 to less than 4.5%, and Mo: 2.5 to 15% or W: 2.5 to 9% or Mo and W: 2.5 to 15% in total, and satisfies the relation (1) given below: (104Si+1980P+1980S+9Al+15Ti+11Nb+1.8W+11600B)≦{1.
    Type: Grant
    Filed: July 11, 2002
    Date of Patent: March 9, 2004
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Kazuhiro Ogawa, Kazuyuki Kitamura, Hirokazu Okada, Yoshitaka Nishiyama
  • Patent number: 6696176
    Abstract: A fusion weldable superalloy containing 0.005-0.5 wt. % scandium. In one embodiment, the superalloy may have a composition similar to IN-939 alloy, but having added scandium and having only 0.005-0.040 wt. % zirconium. A gas turbine component may be formed by an investment casting of such a scandium-containing superalloy, and may include a fusion weld repaired area. A scandium-containing nickel-based superalloy coated with an MCrAlY bond coat will have improved cyclic oxidation resistance due to the sulfur-gettering effect of the scandium.
    Type: Grant
    Filed: March 6, 2002
    Date of Patent: February 24, 2004
    Assignee: Siemens Westinghouse Power Corporation
    Inventors: David B. Allen, Gregg P. Wagner, Brij B. Seth
  • Patent number: 6696017
    Abstract: The present invention relates to a Ni-base brazing alloy. The alloy has a good wettability toward a material to be brazed when melting, an excellent corrosion resistance and a high strength. The alloy is used for process of joining two pieces of metal such as stainless steel. The alloy contains Cr in an mount of 25 to 35% by weight, P in an amount of 4 to 8% by weight, Si in an amount of 3 to 6% by weight, wherein the total amount of P and Si is 9 to 11.5% by weight, at least one selected from a group consisting of Al, Ca, Y and misch metal in an amount of 0.01 to 0.10% by weight, and the balance of Ni and unavoidable impurities.
    Type: Grant
    Filed: June 12, 2001
    Date of Patent: February 24, 2004
    Assignee: Fukuda Metal Foil & Powder Co., Ltd.
    Inventors: Shozo Nagai, Kanichi Tanaka, Kensuke Hidaka
  • Patent number: 6673308
    Abstract: A nickel-base single-crystal superalloy, essentially consists of, in percentages by weight, 4.0% to 11.0% of cobalt, 3.5% to less than 5.0% of chromium, 0.5% to 3.0% of molybdenum, 7.0% to 10.0% of tungsten, 4.5% to 6.0% of aluminum, 0.1% to 2.0% of titanium, 5.0% to 8.0% of tantalum, 1.0% to 3.0% of rhenium, 0.01% to 0.5% of hafnium, 0.01% to 0.1% of silicon, and a balance being nickel and inevitable impurity, a total amount of rhenium and chromium being not less than 4.0% and a total amount of rhenium, molybdenum, tungsten and chromium being not more than 18.0%.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: January 6, 2004
    Assignees: Kabushiki Kaisha Toshiba, Independent Administrative Institution National Institute for Material Science
    Inventors: Takehisa Hino, Yutaka Koizumi, Toshiharu Kobayashi, Shizuo Nakazawa, Hiroshi Harada, Yutaka Ishiwata, Yomei Yoshioka
  • Patent number: 6660431
    Abstract: The present invention relates to a hydrogen storage alloy electrode composed of a hydrogen storage alloy having a CaCu5 region and a Ce2Ni7 region in the crystal structure and satisfies the relational formula: p:q=1:(4+a), where p is the sum of the mole fraction of an element occupying the Ca site of the CaCu5 region and the mole fraction of an element occupying the Ce site of the Ce2Ni7 region, q is the sum of the mole fraction of an element occupying the Cu site of the CaCu5 region and the mole fraction of an element occupying the Ni site of the Ce2Ni7 region, and −0.2≦a≦0.4. Accordingly, although the hydrogen storage alloy electrode contains a little or no Co, it is possible to obtain an electrode having little deterioration due to pulverization of the alloy and a high capacity.
    Type: Grant
    Filed: August 8, 2001
    Date of Patent: December 9, 2003
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Sou Kuranaka, Akihiro Maeda, Yoshio Moriwaki
  • Patent number: 6652991
    Abstract: The addition of small amounts of CeO2 and Cr to intermetallic compositions of NiAl and FeAl improves ductility, thermal stability, thermal shock resistance, and resistance to oxidation, sulphidization and carburization.
    Type: Grant
    Filed: October 9, 2002
    Date of Patent: November 25, 2003
    Assignee: The Governors of the University of Alberta
    Inventors: You Wang, Weixing Chen
  • Publication number: 20030211356
    Abstract: The present invention relates to a metallic coating to be deposited on gas turbine engine components. The metallic coating comprises up to 18 wt % cobalt, 3.0 to 18 wt % chromium, 5.0 to 15 wt % aluminum, 0.1 to 1.0 wt % yttrium, up to 0.6 wt % hafnium, up to 0.3 wt % silicon, 3.0 to 10 wt % tantalum, up to 9.0 wt % tungsten, 1.0 to 6.0 wt % rhenium, up to 10 wt % molybdenum, and the balance nickel.
    Type: Application
    Filed: May 7, 2002
    Publication date: November 13, 2003
    Inventors: Russell Albert Beers, Allan A. Noetzel, Abdus Khan
  • Publication number: 20030118469
    Abstract: A nickel-based alloy is provided for provide parts and members of improved oxidation-resistance and high temperature strength for use in an oxidation atmosphere at high temperatures, such as automobile parts including an electrode for an ignition plug, power plant facility parts including a gas turbine nozzle, inner parts of heat treat furnaces, and fuel cell parts. The alloy improved in oxidation-resistance, high temperature strength and hot workability consists essentially of, in mass percentage, C: 0.003 to 0.1%, Si: 1.0% or less, Mn: 2.0% or less, Cr: 12 to 32%, Fe: 20% or less, Mg: 0.001 to 0.04%, at least one element, of not more than 2.5% in total, selected from the group consisting of Nb, Ta and V, impurity elements of S: 0.01% or less, but the ratio of the Mg-content to the S-content (Mg/S) being 1 or more, and Ti: 0 inclusive to 0.02%, and the rest being Ni and incidental impurities.
    Type: Application
    Filed: December 19, 2002
    Publication date: June 26, 2003
    Applicant: HITACHI METALS, LTD.
    Inventors: Satoshi Kubota, Toshihiro Uehara, Motoi Yamaguchi, Akihiro Toji
  • Patent number: 6537393
    Abstract: A nickel base alloy for high temperature thermal processing hardware requiring ultra-low spallation and metal loss rates in oxidizing and nitriding atmospheres for use in wire mesh belting, thermocouple sheathing, resistive heating elements, heat sensing cables, furnace internals and like hardware. The compositional range of the alloy is 15.0-23.0 % Cr, 0.5-2.0 % Si, 0.0-4.0% Mo, 0.0-1.2 % Nb, 0.0-3.0 % Fe, 0.0-0.5 % Ti, 0.0-0.5 % Al, 0.0-0.3 % Mn, 0.0-0.1 % Zr, 0.0-0.06 % Ce, 0.005-0.025 % Mg, 0.0005-0.005 % B, 0.005-0.3 % C, 0.0-20.0 % Co, balance Ni. The alloy possesses a high degree of hot and cold workability, phase stability and strength retention at elevated temperatures.
    Type: Grant
    Filed: August 29, 2001
    Date of Patent: March 25, 2003
    Assignee: INCO Alloys International, Inc.
    Inventors: Norman C. Farr, Gaylord D. Smith
  • Publication number: 20030041930
    Abstract: The present invention relates to an improved single crystal nickel base superalloy and a process for making same. The single crystal nickel base superalloy has a composition comprising 3 to 12 wt % chromium, up to 3 wt % molybdenum, 3 to 10 wt % tungsten, up to 5 wt % rhenium, 6 to 12 wt % tantalum, 4 to 7 wt % aluminum, up to 15 wt % cobalt, up to 0.05 wt % carbon, up to 0.02 wt % boron, up to 0.1 wt % zirconium, up to 0.8 wt % hafnium, up to 2.0 wt % niobium, up to 1.0 wt % vanadium, up to 0.7 wt % titanium, up to 10 wt % of at least one element selected from the group consisting of ruthenium, rhodium, palladium, osmium, iridium, platinum, and mixtures thereof, and the balance essentially nickel. The single crystal nickel base superalloy has a microstructure which is pore-free and eutectic &ggr;-&ggr;′ free and which has a gamma prime morphology with a bimodal &ggr;′ distribution.
    Type: Application
    Filed: August 30, 2001
    Publication date: March 6, 2003
    Inventors: Daniel P. DeLuca, Charles M. Biondo
  • Patent number: 6524745
    Abstract: An electrochemically stabilized Ca—Ni hydrogen storage alloy material for use as the active negative electrode material of an alkaline electrochemical cell. The alloy material includes at least one modifier element which stabilizes the alloy material from degradation during electrochemical cycling in an alkaline cell, by protecting calcium within the alloy and preventing dissolution of calcium into the alkaline electrolyte. The alloy has the formula (Ca1−x−yMxNi2y)Ni5−zQz, where M is at least one element selected from the group consisting of misch metal, rare earth metals, zirconium and mixtures of Zr with Ti or V, Q is at least one element selected form the group consisting of Si, Al, Ge, Sn, In, Cu, Zn, Co, and mixtures thereof, x ranges between about 0.02 and 0.2, y ranges between about 0.02 and 0.4, and z ranges from about 0.05 to about 1.00.
    Type: Grant
    Filed: May 19, 1999
    Date of Patent: February 25, 2003
    Assignee: Energy Conversion Devices, Inc.
    Inventors: Stanford R. Ovshinsky, Rosa T. Young
  • Patent number: 6491769
    Abstract: A high strength, corrosion resistant Cr—Co—Ni base alloy for long-life service at 530° C. to 820° C. containing in % by weight about 23.5-25.5% Cr, 15.0-22.0% Co, 0.2-2.0% Al, 0.5-2.5% Ti, 0.5-2.5% Nb, up to 2.0% Mo, up to 1.0% Mn, 0.3-1.0% Si, up to 3.0% Fe, up to 0.3% Ta, up to 0.3% W, 0.005-0.08% C, 0.01-0.3 % Zr, 0.001-0.01% B, up to 0.05% rare earth as misch metal, 0.005-0.025% Mg plus optional Ca, balance Ni including trace additions and impurities. The alloy provides a combination of strength, ductility, stability, toughness and oxidation/sulfidation resistance so as to render the alloy range uniquely suitable for engineering applications where oxygen/sulfur-containing atmospheres are life limiting, in applications such as exhaust valves for diesel engines and in tubes for coal-fired steam boilers.
    Type: Grant
    Filed: August 29, 2001
    Date of Patent: December 10, 2002
    Assignee: Inco Alloys International, Inc.
    Inventors: Gaylord D. Smith, Brian A. Baker
  • Publication number: 20020085943
    Abstract: The present invention relates to a Ni-base brazing alloy. The alloy has a good wettability toward a material to be brazed when melting, an excellent corrosion resistance and a high strength. The alloy is used for process of joining two pieces of metal such as stainless steel. The alloy contains Cr in an mount of 25 to 35% by weight, P in an amount of 4 to 8% by weight, Si in an amount of 3 to 6% by weight, wherein the total amount of P and Si is 9 to 11.5% by weight, at least one selected from a group consisting of Al, Ca, Y and misch metal in an amount of 0.01 to 0.10% by weight, and the balance of Ni and unavoidable impurities.
    Type: Application
    Filed: June 12, 2001
    Publication date: July 4, 2002
    Applicant: Fukuda Metal Foil & Powder Co., Ltd.
    Inventors: Shozo Nagai, Kanichi Tanaka, Kensuke Hidaka