Molybdenum Or Tungsten Containing Patents (Class 420/448)
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Patent number: 4765956Abstract: Nickel-chromium alloys consisting essentially of from 30-75 nickel, 12-30% chromium, up to 10% molybdenum, up to 8% tungsten, up to 15% cobalt, up to 5% of niobium and/or tantalum, titanium plus aluminum up to 5%, and carbon nitrogen and silicon in correlated percentages to thereby improve low cycle and thermal fatigue strength, the balance being from 0 to 50% iron.Type: GrantFiled: August 18, 1986Date of Patent: August 23, 1988Assignee: Inco Alloys International, Inc.Inventors: Gaylord D. Smith, Jack M. Wheeler, Stephen C. Tassen
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Patent number: 4727740Abstract: This invention relates to the thermal and wear resistant, tough alloy at elevated temperatures. The alloy consists essentially of carbon, chromium, iron, titanium, aluminum, tungsten, molybdenum, silicon, manganese, cobalt and balance nickel, further the alloy includes optionally at least one selected from the group consisting of nitrogen, niobium and tantalum, further the alloy includes optionally at least one selected from the group consisting of nitrogen, niobium and tantalum, further the alloy includes optionally at least one selected from the group consisting of boron and zirconium. The alloy according to this invention are widely utilized to serve as the alloy for build-up weld and for guide shoe used in the hot rolling apparatus for fabricating seamless steel pipe.Type: GrantFiled: April 24, 1986Date of Patent: March 1, 1988Assignee: Mitsubishi Kinzoku Kabushiki KaishaInventors: Ritsue Yabuki, Junya Ohe, Takumi Kawamura
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Patent number: 4721540Abstract: A single crystal nickel alloy is provided having many of the foundry and performance characteristics of the higher density, single crystal, nickel base super alloys from which the vanes and blades are cast for high performance turbine aircraft engines. The lower density of this alloy permits its use for rebuilding and upgrading the performance of older turbine aircraft engines of designs which cannot withstand the centrifugal forces generated by the new state of the art higher density single crystal super alloys. The alloy for the first time provides a lower density single crystal alloy capable of heat treatment to stabilize its microstructure for high temperature, high stress use. It also provides for the first time a lower density alloy having acceptable resistance to the effects of high temperature sulfidation, salt corrosion and also to have good coating life.Type: GrantFiled: December 4, 1984Date of Patent: January 26, 1988Assignee: Cannon Muskegon CorporationInventors: Kenneth Harris, Gary L. Erickson
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Patent number: 4719080Abstract: A superalloy composition and single crystal articles of the composition are described. The broad range is 3-12% Cr, 0-3% Mo, 3-10% W, 0-5% Re, 6-12% Ta, 4-7% Al, 0-15% Co, 0-0.045% C, 0-0.02% B, 0-0.1% Zr, 0-0.8% Hf, 0-2% Nb, 0-1% V, 0-0.7% Ti, 0-10% (Ru+Rh+Pd+Os+Ir+Pt), balance essentially Ni. An equation is presented to select the most useful specific compositions from within this range. An exemplary preferred composition is 5.0% Cr, 10.0% Co, 2.0% Mo, 6.0% W, 3.1% Re, 5.6% Al, 9.0% Ta, 0.1% Hf, balance essentially Ni.Type: GrantFiled: June 10, 1985Date of Patent: January 12, 1988Assignee: United Technologies CorporationInventors: David N. Duhl, Alan D. Cetel
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Patent number: 4717435Abstract: A gamma-prime precipitation hardening nickel-base yttria particle-dispersion-strengthened superalloy having a composition consisting essentially of, by weight, 3.0 to 6.0% of Al, 8.5 to 10.9% of Co, 3.9 to 7.5% of Cr, 0.5 to 1.2% of Ti, 3.6 to 6.3% of Ta, 11.4 to 13.3% of W, 0.02 to 0.2% of Zr, 1.3 to 2.6% of Mo, 0.001 to 0.1% of C, 0.001 to 0.02% of B, 0.5 to 1.7% of yttria (Y.sub.2 O.sub.3), not more than 0.8% of O and the balance being Ni and having a structure composed of coarse recrystallized grains with a GAR of at least 20 and a short axis diameter of at least 0.Type: GrantFiled: September 3, 1986Date of Patent: January 5, 1988Assignee: National Research Institute for MetalsInventors: Yozo Kawasaki, Katsuyuki Kusunoki, Shizuo Nakazawa, Michio Yamazaki
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Patent number: 4689279Abstract: A solid solution, nonmagnetic, austenitic nickel base alloy class is described. It contains: about 12 to 21 weight percent chromium; a concentration of molybdenum and/or tungsten, such that the sum of the weight percent molybdenum and one third the weight percent tungsten present is between 1 and 7 weight percent and wherein the w % tungsten is less than 12 w %; about 4 to 13 w % iron; small but effective amounts of the desulfurizing agent, manganese; and up to about 2.5 w % silicon. Carbon may be present at levels up to 0.15 w % and cobalt may be present at levels up to 2 w %. The above elements are balanced to provide alloys having a mean thermal expansion coefficient, .alpha..sub.(RT-T), for T.ltoreq.1000.degree. F., of less than 8.3.times.10.sup.-6 in./in./.degree.F., and preferably less than 8.times.10.sup.-6 in./in./.degree.F.In addition, a precipitation hardening, non-magnetic, austenitic nickel base alloy class is also described.Type: GrantFiled: March 7, 1983Date of Patent: August 25, 1987Assignee: Westinghouse Electric Corp.Inventors: Frederick C. Hull, Sun-Keun Hwang
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Patent number: 4685427Abstract: A composite tube structure having an inner substrate alloy and an outer, corrosion resistant alloy suitable for use in fluid-bed coal combustion reactors to form a water wall around at least a portion of the periphery of the fluid bed zone. The outer, corrosion resistant alloy centers around a composition of 0.1% carbon, 0.2% silicon, 0.5% manganese, 22% chromium, 3.8% aluminum, 0.4% titanium, 0.05% nitrogen, 0.2% molybdenum, 32% nickel, balance iron.Type: GrantFiled: December 8, 1986Date of Patent: August 11, 1987Assignee: Inco Alloys International, Inc.Inventors: Curtis S. Tassen, Gaylord D. Smith
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Patent number: 4678635Abstract: A metallic joining material which is provided particularly for the joining of parts of oxide-dispersion-hardened alloys. The metallic joining material in particular is a solder which contains chromium, cobalt, boron, silicon, tungsten, molybdenum, tantalum, aluminum, titanium zirconium with the remainder nickel.Type: GrantFiled: December 17, 1985Date of Patent: July 7, 1987Assignee: BBC Aktiengesellschaft Brown, Boveri & CieInventor: Bernd Jahnke
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Patent number: 4677035Abstract: Disclosed are novel nickel-base single crystal alloy compositions consisting essentially of, by weight, about 8.0-14.0% chromium, 1.5-6.0% cobalt, 0.5-2.0% molybdenum, 3.0-10.0% tungsten, 2.5-7.0% titanium, 2.5-7.0% aluminum, 3.0-6.0% tantalum and the balance nickel.A combination of thermal treatment and coating of the novel alloys to enhance their mechanical properties is also disclosed.Type: GrantFiled: December 6, 1984Date of Patent: June 30, 1987Assignee: Avco Corp.Inventors: Louis J. Fiedler, Subhash K. Naik
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Patent number: 4671931Abstract: A yttrium-free, nickel-chromium-iron-aluminum alloy characterized by excellent oxidation resistance at very high temperatures. The alloy consists essentially of, by weight, from 14 to 18% chromium, from 4 to 6% aluminum, from 1.5 to 8% iron, up to 12% cobalt, up to 1% manganese, up to 1% molybdenum, up to 1% silicon, up to 0.25% carbon, up to 0.03% boron, up to 1% tungsten, up to 0.5% tantalum, up to 0.2% titanium, up to 0.5% hafnium, up to 0.2% zirconium, up to 0.2% rhenium, balance essentially nickel. The nickel plus the cobalt content is at least 66%.Type: GrantFiled: May 11, 1984Date of Patent: June 9, 1987Inventors: Robert B. Herchenroeder, Krishna V. Rao
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Patent number: 4624832Abstract: New nickel alloys are described which are useful for eyeglass frames, which alloys in addition to good resistance to corrosion also have good workability properties. They contain 5 to 20 percent copper and 5 to 30 percent zinc. Optionally, they can also be alloyed in small amounts other metals such as manganese, silicon, beryllium, cobalt, aluminum, niobium, tantalum, or titanium.Type: GrantFiled: November 2, 1984Date of Patent: November 25, 1986Assignee: Degussa AktiengesellschaftInventors: Horst Heidsiek, Gernot Jackel, Horst Becker
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Patent number: 4569824Abstract: Nickel base superalloys intended for use at low to moderate temperatures are provided with improved corrosion resistance by the addition of from 0.2 to 0.6% manganese. The manganese addition also improves the creep properties of the alloys. The manganese modified alloys are suited for use as elements in gas turbine engines for marine environments.Type: GrantFiled: January 22, 1982Date of Patent: February 11, 1986Assignee: United Technologies CorporationInventors: David N. Duhl, Xuan Nguyen-Dinh
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Patent number: 4519979Abstract: A nickel-chromium-cobalt base alloy having an improved combination of creep-rupture strength at elevated temperatures, resistance to corrosion in sulfur and chloride-containing environments, structural stability at elevated temperatures and good castability.Articles and parts cast from the alloy, in particular directionally-solidified castings, are suitable for use in gas turbine engines, e.g., for stationary land-based and marine propulsion turbines.Type: GrantFiled: June 6, 1983Date of Patent: May 28, 1985Assignee: INCO Europe LimitedInventor: Stuart W. K. Shaw
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Patent number: 4492672Abstract: The microstructural stability of nickel base alloys at high temperatures is nhanced by the addition of cobalt within the range of 10.0 to 14.9 weight percent for reducing the precipitation of the sigma phase in alloys with more than 12 weight percent chromium. The nickel-base alloys having cobalt addition in the range as set forth are characterized by an electron vacancy number within the range of 2.4 to 2.7 inclusive.Type: GrantFiled: April 19, 1982Date of Patent: January 8, 1985Assignee: The United States of America as represented by the Secretary of the NavyInventors: David N. Duhl, Xuan Nguyen-Dinh
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Patent number: 4430297Abstract: Disclosed is a hard wear resistant nickel based alloy including a carbide-former, preferably niobium, and essentially cobalt free but which has similar properties to cobalt, chromium, tungsten, carbon alloys. Typically the alloy has a composition, in parts by weight, Cr-34 C-1.2, Mo-10, Fe-3, Si-1, Nb-3, Ni-balance. The alloys of the invention are suitable for surface or welding consumables, and as articles for making hardfacing depositions.Type: GrantFiled: January 7, 1980Date of Patent: February 7, 1984Assignee: Cabot CorporationInventor: Paul Crook
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Patent number: 4421571Abstract: A process for manufacturing high strength deep well casing, tubing, and drill pipes, which have improved resistance to stress corrosion cracking is disclosed. The process comprises the steps of preparing an alloy composition which is:______________________________________ C .ltoreq.0.05% Si .ltoreq.1.0% Mn .ltoreq.2.0% P .ltoreq.0.030% S .ltoreq.0.005% N 0-0.30% Ni 25-60% Cr 15-35% Mo 0-12% W 0-24% Cr (%) + 10Mo (%) + 5W (%) .gtoreq. 50% 1.5% .ltoreq. Mo (%) + 1/2W (%) .ltoreq. 12% Cu 0-2.0% Co 0-2.0% Rare Earths 0-0.10% Y 0-0.20% Mg 0-0.10% Ti 0-0.5% Ca 0-0.10% and incidental impurities balance; ______________________________________applying, after hot working, the solid solution treatment to the alloy at a temperature of from the lower limit temperature (.degree.C.) defined by the following empirical formula: 260 log C(%)+1300 to the upper limit temperature (.degree.C.Type: GrantFiled: June 17, 1982Date of Patent: December 20, 1983Assignee: Sumitomo Metal Industries, Ltd.Inventors: Takeo Kudo, Yasutaka Okada, Taishi Moroishi, Akio Ikeda, Hiroo Ohtani, Kunihiko Yoshikawa
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Patent number: 4415530Abstract: A welding alloy particularly directed to use as a wrought filler metal and contains selected percentages of chromium, molybdenum, manganese, columbium, magnesium, a number of trace elements and the balance essentially nickel.Type: GrantFiled: November 10, 1980Date of Patent: November 15, 1983Assignee: Huntington Alloys, Inc.Inventor: James P. Hunt
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Patent number: 4410489Abstract: Disclosed is a nickel-base alloy which provides excellent corrosion resistance to a variety of severe environments, especially hot phosphoric acid. The alloy preferably contains, in weight percent: about 30 chromium, about 4 molybdenum, about 2 tungsten, about 1 Cb/Ta, about 1.5 copper, about 14 iron and the balance nickel plus the impurities and modifying elements usually found in alloy of this class. The alloy is eminently suited for use as articles in chemical processing apparatus in the manufacture and/or containment of phosphoric acid and sulfuric acid.Type: GrantFiled: July 17, 1981Date of Patent: October 18, 1983Assignee: Cabot CorporationInventors: Aziz I. Asphahani, William L. Silence, Paul E. Manning
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Patent number: 4401622Abstract: A nickel-chromium-iron alloy intended principally for automotive turbocharger applications, the alloy being characterized by good stress - rupture strength, ductility, tensile strength, etc. and containing, generally speaking, 10-15% Cr, 18-30% Fe, 3-4.25% Ti, 2.25-3.5% Al, Ti+Al from 6 to 7.25%, ratio of Ti to Al of at least 0.9 and up to 1.6, 4-6% Mo, 0.01-0.2% B, 0.03-0.3% C, balance essentially nickel.Type: GrantFiled: April 20, 1981Date of Patent: August 30, 1983Assignees: The International Nickel Co., Inc., Howmet CorporationInventors: Raymond C. Benn, John R. Mihalisin, Leroy R. Curwick, Howard F. Merrick
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Patent number: 4379120Abstract: A sulfidation-resistant alloy containing about 0.02-0.08 w/o carbon, 21-24.5 w/o chromium, 52-60 w/o nickel, 1-3.5 w/o molybdenum, 1.75-3.25 w/o titanium, 0.75-2.25 w/o aluminum, 0.50-2 w/o columbium, up to 0.02 w/o boron and the balance iron, the elements being balanced to provide an average electron-vacancy number Nv not greater than 2.54. When so balanced, the alloy is stabilized against the formation of no more than 10 v/o Cr-rich alpha phase. Preferably, the elements are balanced so that Nv is not greater than 2.45 and better yet not greater than 2.40.Type: GrantFiled: July 28, 1980Date of Patent: April 5, 1983Assignee: Carpenter Technology CorporationInventors: C. Raymond Whitney, Andrew R. Walsh
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Patent number: 4374084Abstract: An alloy is described which is suitable for the manufacture of castings which operate under high temperature conditions (such as nozzle guide vanes for gas turbine engines) but which can also be welded satisfactorily. The alloy comprises______________________________________ Chromium 14.5-16.5% Cobalt 9-11% Molybdenum 5.5-8% Aluminium 1.5-3% Titanium 1.5-3% Tantalum 0-1% Niobium 0-1% Boron 0.004-0.008% Iron 0-0.5% Manganese 0-0.4% Silicon 0-0.2% Nitrogen 0-0.5% Carbon 0.11-0.18% ______________________________________The balance being Nickel apart from incidental impurities.Type: GrantFiled: April 1, 1981Date of Patent: February 15, 1983Assignee: Rolls-Royce LimitedInventors: Geoffrey W. Meetham, John D. Gray
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Patent number: 4371404Abstract: A specific composition range and process sequence are described for the production of single crystal superalloy articles which have an exceptional combination of high temperature mechanical properties and resistance to oxidation and hot corrosion. The nominal composition in weight percent is 7.5% Cr, 5.0% Al, 1.0% Ti, 2.0% Mo, 4.0% W, 12.0% Ta, 5% Co, balance nickel. Material of this composition is cast and solidified in single crystal form and heat treated to produce an optimum microstructure.Type: GrantFiled: January 23, 1980Date of Patent: February 1, 1983Assignee: United Technologies CorporationInventors: David N. Duhl, Xuan Nguyen-Dinh
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Patent number: 4358511Abstract: Directed to a nickel-chromium-molybdenum alloy containing about 1.3% to about 3% of aluminum plus titanium, which is particularly useful where corrosion resistance, strength and ductility are required, such as in oil well tubing.Type: GrantFiled: October 31, 1980Date of Patent: November 9, 1982Assignee: Huntington Alloys, Inc.Inventors: Darrell F. Smith, Jr., Edward F. Clatworthy