Abstract: The present invention provides a surface coating of platinum in which the coating is formed from platinum in a black modification. This can be obtained by applying an organic platinum complex compound with platinum in the oxidation state 0 that decomposes thermally at temperatures below 200° C., or a coating composition which consists substantially of such a platinum complex compound, to the surface of a substrate and then thermally decomposing the platinum complex compound. The surface coatings can be used in many ways, for example as protective layers against mechanical and/or chemical and/or thermal effects, as antiadhesion layers, as antireflective layers or as catalytically active layers.

Abstract: The invention is directed to intermetallic compounds for use as catalysts for chemical reactions and catalytic systems. The structure of ordered intermetallic compounds enables such compounds to function as highly efficient catalysts. The ordered intermetallic compounds may be used to catalyze reactions in fuel cells (e.g., hydrogen fuel cells), amongst numerous other applications.

Abstract: The present invention is a precious metal-based amorphous alloy having a Pt—Cu—P based structure including in atomic %: 50≦Pt≦75%, 5≦Cu≦35%, and 15≦P≦25% and is a precious metal-based amorphous alloy having a Pt—Pd—Cu—P based structure including in atomic %: 5≦Pt≦70%, 5≦Pd≦50%, 5≦Cu≦50%, and 5≦P≦30%. Preferably, cooling rates for manufacturing the alloys having these compositions are 10−1 to 102° C./sec. for the Pt—Cu—P based structure and 101 to 102° C./sec. for the Pt—Pd—Cu—P based structure.

Abstract: A novel method for preparing fine particles comprising a transition metal and a noble metal which are monodispersed and have almost no particle diameter distribution, and are transferable to a CuAu-I type L10 ordered phase, with safety and at a low cost, wherein a salt or a complex of at least one transition metal selected from Fe and Co and a salt or a complex of at least one transition metal selected from Pt and Pd (exclusive of the combination of Co-Pd) is dissolved in an organic solvent miscible with water or an alcohol in the presence of an organic protecting agent, and the resultant solution is heated under reflux in the presence of an alcohol in an inert atmosphere, to thereby prepare a binary alloy comprising a transition metal and a noble metal, or a salt or a complex of at least one element selected from the group consisting of Cu, Bi, Sb, Sn, Pb and Ag is further dissolved in the above solvent and the resultant solution is heated under reflux in the presence of an alcohol in an inert atmosphere, to

Abstract: The present invention offers a minute-sized magnet with superior magnetic energy product (BH)max and coercivity iHc, as well as superior anti-corrosive properties. This magnet is comprised of an alloy comprised of 35-55 atomic % platinum, 0.001-10 atomic % third element, which is one or more elements from groups IVa, Va, IIIb, or IVb, and a remainder of iron and other unavoidable impurities. The average crystal size of this FePt alloy is 0.3 &mgr;m. By mixing an FePt alloy with a specific element in a designated ratio, an FePt magnet with more excellent characteristics than ones made from previous alloys was successfully made.

Abstract: A gold-free platinum material that is dispersion-strengthened by small, finely dispersed particles of base metal oxide. The base metal is either 0.01-0.5 wt. % Sc or a mixture/alloy of Sc and at least one metal from the group consisting of Zr, Y, and Ce with a total base metal content of 0.05-0.5 wt. %.

Abstract: A new jewelry component alloy and articles of jewelry formed therefrom wherein the components and articles include precious metal alloys of platinum and cobalt that have magnetic properties and high hardnesses so that the various forms of fine jewelry that possess new and unusual visual and functional properties. When these alloys are formed into jewelry articles or components, the magnetic properties enable the components to either be attracted to or repelled by other components of different or like polarities. The jewelry designer is thus able to create pieces with levitating or suspended components, or to make magnetically connected components. The high hardness imparts exceptional durability to these components.

Abstract: A heating conductor, in particular for a sensor for determining at least one gas component in the exhaust gases of internal combustion engines. The heating conductor formed from a cermet which contains platinum, at least one metal oxide, and at least two further precious metals. A method for manufacturing the heating conductor by applying a paste containing a platinum powder, a metal oxide powder, and at least two further precious metals, to a ceramic foil and sintering the paste and ceramic foil combination.

Abstract: A lining material for glass melting furnaces comprises platinum or platinum alloy as a base material containing osmium as an impurity in an amount no more than 20 ppm. The lining material is used for that part of the melting furnace which comes into contact with molten glass. The low osmium content prevents the formation of bubbles in molten glass, thereby providing high-quality glass products.

Abstract: Disclosed herein are electrodes, sensors, and methods for making and using the same. In one embodiment, the sensor comprises: a co-fired sensing electrode comprising the reaction product of about 50 wt % to about 95 wt % noble metal, about 0.5 wt % to about 15.0 wt % yttria-stabilized zirconia, and about 1 wt % to about 6 wt % yttria, based upon a total combined weight of the noble metal, yttria-stabilized zirconia, and yttria, a reference electrode, and a co-fired electrolyte disposed between and in ionic communication with the co-fired sensing electrode and the reference electrode.

Abstract: An improved noble metal alloy composition for a fuel cell catalyst, a ternary alloy composition containing platinum, ruthenium and palladium. The alloy shows increased activity as compared to well-known catalysts.

Abstract: A hard precious metal alloy member is constituted of a gold alloy, which has a gold Au content of from 37.50 to 98.45 wt %, and contains a hardening additive in a range of not less than 50 ppm but less than 15,000 ppm, wherein the hardening additive is constituted of gadolinium Gd only, or gadolinium Gd and at least one element selected from the group consisting of rare-earth elements other than Gd, alkaline-earth elements, silicon Si, aluminum Al, and boron B.

Abstract: The present invention is a precious metal-based amorphous alloy having a Pt—Cu—P based structure including in atomic %: 50≦Pt≦75%, 5≦Cu≦35%, and 15≦P≦25% and is a precious metal-based amorphous alloy having a Pt—Pd—Cu—P based structure including in atomic %: 5≦Pt≦70%, 5≦Pd≦50%, 5≦Cu≦50%, and 5≦P≦30%. Preferably, cooling rates for manufacturing the alloys having these compositions are 10−1 to 102° C./sec. for the Pt—Cu—P based structure and 101 to 102° C./sec. for the Pt—Pd—Cu—P based structure.

Abstract: A lining material for glass melting furnaces comprises platinum or platinum alloy as a base material containing osmium as an impurity in an amount no more than 20 ppm. The lining material is used for that part of the melting furnace which comes into contact with molten glass. The low osmium content prevents the formation of bubbles in molten glass, thereby providing high-quality glass products.

Abstract: Platinum—iron alloys that contain 95-96 wt % Pt, 2-3 wt % Fe, and 20-3 wt % Ru and/or Ir, and are suitable especially for the fabrication of jewelry.

Abstract: A lining material for glass melting furnaces comprises platinum or platinum alloy as a base material containing osmium as an impurity in an amount no more than 20 ppm. The lining material is used for that part of the melting furnace which comes into contact with molten glass. The low osmium content prevents the formation of bubbles in molten glass, thereby providing high-quality glass products.

Abstract: A solder composition for repairing jewelry having a platinum content of up to about 95% by weight contains about 90% to about 95% by weight platinum and about 5% to about 10% by weight of an alloy that provides the solder composition with a melting temperature in a range from about 1300° C. to about 1500° C. Preferably, the alloy consists essentially of about 3% to about 6% by weight gallium, about 1.5% to about 3% by weight indium, and about 0.5% to about 1.0% by weight copper. An alloy for lowering the melting point of platinum to provide a solder composition having a reduced melting point contains gallium, indium and copper in a respective weight ratio of approximately 6:3:1. The solder composition is used to assemble, repair, or size high platinum content jewelry at a workable melting temperature without creating a color difference between the jewelry and the applied solder composition.

Abstract: A method for preparing a highly crystallized metal powder, comprising: supplying at least one heat-decomposable metal compound powder into a reaction vessel using a carrier gas; and forming a metal powder by heating the metal compound powder in a state in which the metal compound powder is dispersed in a gas phase at a concentration of no more than 10 g/liter, at a temperature that is over the decomposition temperature of the metal compound powder and at least (Tm −200)° C. when the melting point of the metal contained in the metal compound powder is Tm° C. The method provides a high-purity, high-density, highly dispersible, fine, highly crystallized metal powder consisting of spherical particles of uniform size, which is suited to use in thick film pastes, and particularly conductor pastes and the like used in the preparation of multilayer ceramic electronic parts.

Abstract: Platinum, silver and gold solder compositions for repairing, assembling, or sizing jewelry. Platinum compositions having about 90% to about 95% by weight platinum. Silver compositions having at least 92.5% by weight silver. Gold solder compositions having about 25% to about 91.6% gold. The platinum and silver solder compositions further consisting of about 8.3% to about 75% by weight of an alloy consisting essentially of gallium, indium and copper in respective ratios of 6:3:1. The gold solder compositions further consisting of about 2% to about 14% by weight of an alloy consisting essentially of gallium, indium, and copper in respective ratios of 6:3:1. The melting temperature ranges of the respective solder compositions are from about 1300° C. to about 1500° C. for platinum, from about 1000° F. to about 1400° F. for silver, and from about 1100° F. to about 1550° F.

Abstract: Mn alloy materials for magnetic materials contain 500 ppm or less, preferably 100 ppm or less, oxygen, 100 ppm or less, probably 20 ppm or less, sulfur, and preferably a total of 1000 ppm or less, more preferably 500 ppm or less, impurities (elements other than Mn and the alloying component). The alloying component that forms an alloy with Mn is one or two or more elements selected from the group consisting of Fe, Ir, Pt, pd, Rh, Ru, Ni, Cr and Co. Sputtering targets formed from the Mn alloy materials for use in depositing magnetic thin film, and the thin films so produced.

Abstract: The invention relates to a composition and a process for the reactive brazing of ceramic materials containing alumina. This composition comprises at least one precious metal chosen from among Pd, Pt and Au, as well as magnesium, preferably at the most 5 wt. % magnesium. Brazing takes place at a temperature of 1300 to 1600° C., in the absence of hydrogen.

Abstract: A decorative artifact made of a precious metal composition containing 3-9% by weight aluminum, 1-6% by weight titanium, and the balance being platinum, in which the hardness of the composition is at least 600 on the Vickers scale.

Abstract: The invention relates to a method of manufacturing a bushing baseplate, and to a bushing baseplate. The bushing baseplate is characterized in that it comprises tips (18) constituted by hollow tubular elements of outside diameter slightly smaller than the inside diameter of holes (16) in the plate (12) forming the bushing baseplate, which tips are subjected to a step of being expanded radially relative to their axes. The method is simpler and less expensive.

Abstract: A method of producing high coercivity FePt—Si3N4 granular composite thin films for magnetic recording media is invented. The method includes magnetron co-sputtering of FePt and Si3N4 targets at controlled sputtering power and sputtering argon gas pressure to form a selective composition of granular FePt—Si3N4 thin film on a low temperature substrate, then post-annealed in vacuum at selective time period and temperature. Two kinds of FePt targets can be used. One is the FePt alloy target. The other one is a composite target consisting of an iron disk overlaid with small Pt pieces. This arrangement provides a wide range of effective target compositions and therefore film compositions. FePt—Si3N4 films were deposited on natural oxidized silicon wafer or quartz glass substrate at room temperature. The as-deposited film has soft magnetic properties and granular structure with soft magnetic &ggr;-FePt particles dispersed in amorphous Si3N4 matrix.

Abstract: This invention pertains to improved formulations of platinum--molybdenum alloys for use as anode catalysts. These electrocatalysts find utility as a constituent of gas diffusion electrodes for use in fuel cells that operate at less than 180.degree. C. or in applications whereupon hydrogen is oxidized in the presence of carbon monoxide or other platinum inhibiting substances. The new formulations derive unexpected activity through creating highly dispersed alloy particles of up to approximately 300 .ANG. on carbon supports. The desired activity is achieved by carefully controlling the platinum to molybdenum ratio during preparation and judiciously selecting a proper loading of alloy on the carbon support.

Abstract: An improved platinum alloy composition is provided. The platinum alloy composition comprises platinum in an amount of about 58.5 weight percent, palladium as a filler metal in an amount between about 26.5 and 36.5 weight percent, and at least one of iridium, cobalt and ruthenium in an amount between about 5 and 15 weight percent.

Abstract: The present invention relates to a novel platinum palladium alloy catalyst useful in hydrofinishing and hydrocracking non low sulfur content feedstock and the process of hydrofinishing and hydrocracking such non low sulfur content feedstock feeds. The catalyst maintains the activity of a palladium catalyst with the sulfur tolerance of a platinum catalyst without the need for the higher reaction temperatures normally associated with platinum based catalysts and thus avoid the higher rates of undesirable cracking reactions in the fabrication of a lubricating base oil stock.

Abstract: A novel catalyst comprising a Pt--M alloy wherein M is one or more metals selected from the transition metal elements or from Groups IIIA or IVA of the Periodic Table in "Handbook of Chemistry and Physics" 64th Edition, CRC Press, and Y wherein Y is a bronze forming element or an oxide thereof, characterised in that the Pt--M alloy is in intimate contact with Y, and provided that M is not Ru if Y is WO.sub.3 is disclosed and which may be used as a poison tolerant catalyst for use in fuel cells, specifically as the anode of a PEM fuel cell.

Abstract: Disclosed is an anode electrocatalyst for a fuel cell comprising an alloy essentially consisting of at least one of tin, germanium and molybdenum, and one or more noble metals selected from platinum, palladium and ruthenium.The tin, germanium and/or molybdenum gas the ability of depressing the poisioning of the noble metal with carbon monoxide so that fuel containing a relatively high content of the carbon monoxide may be supplied to a fuel cell equipped with anode in accordance with the present invention which is otherwise liable to be poisioned.

Abstract: A heat-resistant platinum material with more than 99.5% by weight platinum, with high long-term creep resistance and low grain growth at high temperature contains 0.1 to 0.35% by weight zirconium and/or zirconium oxide and 0.002 to 0.02% by weight boron and/or boron oxide.

Abstract: A magneto-optical layer sensitive to a light with a short wavelength such as 400 to 550 nm and having a perpendicular magnetization can be deposited on a substrate at a room temperature. The magneto-optical layer is of a tertiary polycrystalline having a composition, for example, Co.sub. aPt.sub.b Ru.sub.c where 20.ltoreq.a.ltoreq.70, 10.ltoreq.b.ltoreq.70, 10.ltoreq.c.ltoreq.60 and a+b+c=100 or Co.sub.d Pt.sub.e Re.sub.f where d.ltoreq.80, 5.ltoreq.e, 5.ltoreq.f, 40.ltoreq.4d-5f and d+e+f=100, and has an easy magnetization axis perpendicular to the main surface of the layer.

Abstract: Hard and scratch-proof objects of platinum and palladium or their alloys comprise a boron-containing surface layer which is 20 to 500 .mu.m thick and contains 0.3 to 1.5% by weight boron embedded in the metal lattice.

Abstract: Material comprising an effective amount of a novel intermetallic bulk superconductor compound is disclosed. The compound has the composition LnNi.sub.2 B.sub.2 C, with Ln being Y or a rare earth (atomic number 57-71), preferably Tm, Er, Ho or Ln. A compound of composition XPt.sub.2 B.sub.2 C, with X=Y and/or La, is also a superconductor.

Abstract: A sputtering target of platinum-cobalt alloy is disclosed which contains 10 to 55% by weight of platinum; 1 to 15% by weight of a first additional element selected from the group consisting of nickel and tantalum; no more than 1.5% by weight of a second additional element selected from the group consisting of boron, titanium, lanthanum, cerium, neodymium, beryllium, calcium, zirconium, and silicon; no more than 20% by weight of chromium; and balance cobalt. A method for manufacturing the sputtering target is also disclosed. In the method, a platinum-cobalt alloy containing specific ingredients in predetermined amounts is first prepared. Then, the platinum-cobalt alloy is subjected to hot plastic working with a thickness reduction of no less than 30%. Subsequently, the alloy thus hot worked is subjected to a cold plastic working with a thickness reduction of no less than 5% at a temperature less than the recrystallization temperature of the alloy.

Abstract: Intermetallic compounds and hydrides thereof, characterized in that they have been prepared by reacting hydrides of the elements of the main groups I, II, III and IV of the Periodic Table, magnesium hydridehalides or magnesium dialkyls having the general formula MgR.sub.2 (R=alkyl) in a solvent with bisallyl metal compounds of the metals of the subgroup VIII of the Periodic Table or of zinc or with the homologues of the bisallyl compounds of said metals, and processes for preparing said compounds.

Abstract: Intermetallic compounds and hydrides thereof, characterized in that they have been prepared by reacting hydrides of the elements of the main groups I, II, III and IV of the Periodic Table, magnesium hydridehalides or magnesium dialkyls having the general formula MgR.sub.2 (R=alkyl) in a solvent with bisallyl metal compounds of the metals of the subgroup VIII of the Periodic Table or of zinc or with the homologues of the bisallyl compounds of said metals, and processes for preparing said compounds.

Abstract: Intermetallic compounds are disclosed in which a platinum/aluminium compound includes copper in proportions chosen to provide desirable color, from yellow through orange to copper/red, to the compound. The compound contains from 50 to 81, preferably 57 to 80% by weight platinum; from 5 to 30, preferably 12.5 to 30% by weight aluminium; and from 1 to 47.5 and preferably 5 to 30% by weight copper.

Abstract: Alloys suitable for dental or medical devices are disclosed. A typical alloy comprises about 35 to about 60% by weight of zirconium, about 1 to about 60% by weight of palladium and about 1 to about 60% by weight of ruthenium.

Abstract: A thin film of an amorphous alloy comprising (i) at least one element selected from Fe and Co, (ii) at least one element selected from Pt and Pd and (iii) at least one element selected from (a) 3d transition elements other than Fe and Co, (b) 4d transition elements other than Pd, (c) 5d transition elements other than Pt, (d) light rare earth elements, (e) Group III B elements, (f) Group IV B elements, (g) Group V B elements, and (h) Group VI B elements, and the film having an easy axis of magnetization perpendicular to the film face. The thin film has excellent magnetooptical characteristics including increased coercive force and large Kerr-rotation angle and Faraday-rotation angle, and is excellent in resistance to oxidation and in consequence the coercive force and Kerr-angle of the film do not substantially change with time. The film has a high reflectance as well.

Abstract: The coercivity of magnetic alloys formed from platinum, cobalt, and boron is enhanced by incorporating from 12 to 14 percent of boron together with amounts of platinum and cobalt such that the ratio of platinum to cobalt is from 0.90 to 1.2. The magnetic alloy is formed by rapid solidification of a homogeneous melt, and the solidified casting is heat treated to improve microstructure and increase coercivity.

Abstract: The invention provides an alloy useful particularly in dentistry.The alloy of the invention in its broadest aspect contains from about 0.05 to about 8% by weight of indium and from about 8 to about 20% by weight of iridium, the balance essentially being platinum. Preferably, however, the allow consists essentially of platinum, iridium and indium, and contains from about 0.05 to about 8% by weight of indium, with the weight ratio of platinum to iridium being from about 84 to about 86:15.The alloy is useful in forming dental prostheses with aluminous porcelain or with a castable ceramic.

Abstract: Relatively large structures are fabricated from oxide dispersion strengthened platinum or alloys by working a plurality of pieces to thin, wide layers, and then laminating the layers such as by hammer welding so as not to disturb the grain structure or oxide dispersion.

Abstract: The disclosed permanent magnet has a coercive force of larger than 500 Oe, a residual magnetic flux density of larger than 5 kG, and a maximum energy product of larger than 2 MGOe, and it consisting essentially of 48.about.66.9 Atm % of iron, 33.about.47 Atm % of platinum, and 0.1.about.10 Atm % of niobium. It includes a crystal structure of an incomplete single .gamma..sub.1 phase of a face-centered tetragonal system due to either the composition thereof or heat treatment applied thereto. The permanent magnet is made by heating an alloy of the above main composition at 900.degree..about.400.degree. for one minute to ten hours and quenching the alloy at a high speed of faster than 30.degree. C./minute but slower than 2,000.degree. C./sec.

Abstract: Noble metal alloys are used to produce attachments that can be cast-on, particularly in dental technology, having a melting range above 1500.degree. C. The alloys comprise about 40-70% platinum, about 10-40% palladium, about 5-20% iridium, about 0.5-10% gold, about 0-13 3% silver and about 0-1% each of ruthenium and rhodium.

Abstract: A metal composition usable as a brazing material for bonding a metal to a non-oxide ceramic. The brazing material contains, at least, one or more metals selected from a first group of transition metals consisting of Pt, Pd, Rh, Ir, Ru and Os, and one or more metals selected from a second group of transition metals consisting of Cr, Mn, Fe, Co, Ni and Cu. The material may further contain one or more elements selected from a third group of elements consisting of B, C, Si and P.

Abstract: A platinum alloy electrocatalyst, composed of a platinum-copper alloy containing 15 to 50 atomic percent of copper (the balance being platinum) and supported on a suitable carrier, shows high activity over long periods because of the enhanced specific activity of supported metal and improved maintainability of its specific surface area. Thus acid-electrolyte fuel cells using the electrode comprising such an electrocatalyst feature better output performances and longer service life than fuel cells using conventional electrodes.

Abstract: A magneto-optical device for varying the state of polarization of a reflected or transmitted light beam having a wavelength which lies in particular in the range between 0.6 and 0.9 microns. The device has a magneto-optically active layer formed from a platinum-manganese-antimony alloy, at least 80 atomic percent of which has the composition Pt.sub.1 Mn.sub.1 Sb.sub.1 and has a C1.sub.b crystal structure.

Abstract: A hard alloy including at least one hard phase and a binary or multicomponent binder metal alloy, in which the hard substance comprises a finely dispersed, homogeneous distribution in the binder metal. The hard phase comprises a carbide of a Group IVb, Vb or VIb transition metal, and the binder metal alloy comprises a solid alloy of a Group IVb, Vb or VIb transition metal, with Re, Ru, Rh, Pd, Os, Ir, or Pt.

Abstract: The disclosed permanent magnet has a coercive force of 500 Oe or more, a idual magnetic flux density of 5 kG or more, and a maximum energy product of 2 MG. Oe or more. The magnet alloy consists essentially of platinum and iron, and has an initial state of homogeneous dispersion of .gamma..sub.1 phase of face-centered tetragonal type in a .gamma. phase matrix of face-centered cubic type. To produce the magnet, the alloy is heated at 900.degree. to 1,400.degree. C. for 1 minute to 100 hours for homogenizing solid solution treatment, and quenched in water or in air at a rate of 30.degree. C./minute to 2,000.degree. C./second.

Abstract: An amorphous alloy is prepared by rapid quenching from the liquid state and consists of(1) 10 to 40 atomic percent of P and/or Si(2) 90 to 60 atomic percent of two or more of Pd, Rh and Pt.The amorphous alloy is used for an electrode for an electrolysis.