Lead, Bismuth, Selenium, Tellurium Or Calcium Containing Patents (Class 420/84)
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Patent number: 6783728Abstract: Disclosed is a free-cutting steel for machine structural use which always exhibits desired machinability, particularly, machinability by cutting with cemented carbide tools. This free-cutting steel is produced by preparing a molten alloy of the composition consisting essentially of, by weight %, C: 0.05-0.8%, Si: 0.01-2.5%, Mn: 0.1-3.5% and O: 0.0005-0.01%, the balance being Fe and inevitable, and adjusting the addition amounts of Al and Ca in such a manner as to satisfy the above ranges, S: 0.01-0.2%, Al: 0.001-0.020% and Ca: 0.0005-0.02%, and the conditions of [S]/[O]: 8-40 [Ca]×[S]: 1×10−5−1×10−3 [Ca]/[S]: 0.01-20 and [Al]: 0.001-0.020% to obtain a steel characterized in that the area in microscopic field occupied by the sulfide inclusions containing Ca of 1.0% or more neighboring to oxide inclusions containing CaO of 8-62% is 2.0×10−4 mm2 or more per 3.5 mm2.Type: GrantFiled: June 7, 2002Date of Patent: August 31, 2004Assignee: Daido Steel Co., Ltd.Inventors: Takashi Kano, Yutaka Kurebayashi
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Patent number: 6773661Abstract: Disclosed is a free-cutting steel containing Ti- and/or Zr-carbosulfide as inclusion and having good machinability both in turning and drilling. The free-cutting steel consists essentially of, in mass %, C: 0.05-0.80%, Si: 0.01-2.5%, Mn: 0.1-3.5%, Ti+0.52Zr: 0.03-1.2%, S:0.015-0.6% and the balance of Fe and inevitable impurities, and is characterized in that the contents of Ti, Zr and S meet the condition of (Ti+0.52Zr)/S<2. The free-cutting steel may contain, in addition to the above basic alloy composition, Ca: 0.0005-0.02% and/or Mg: 0.0003-0.02%. The latter steel exhibits much more improved machinability.Type: GrantFiled: May 31, 2002Date of Patent: August 10, 2004Assignee: Daido Steel Co., Ltd.Inventors: Masakazu Hayaishi, Yutaka Kurebayashi
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Patent number: 6761853Abstract: A free-cutting tool steel is provided containing Fe and C in an amount of 0.1 to 2.5 wt %, Ti and or Zr where WTi+0.52WZr constitutes 0.03 to 3.5 wt %, and WTi represents Ti content and WZr represents Zr content, at least any one of S, Se and Te where WS+0.4WSe+0.25WTe constitutes 0.01 to 1.0 wt %, and (WTi+0.52WZr)/(WS+0.4WSe+0.25WTe) constitutes 1 to 4, and WS represents S content, WSe represents Se content and WTe represents Te content; and dispersed therein a texture thereof from 0.1 to 10% in terms of area ratio in a section of a machinability improving compound phase of a metallic element component of Ti and/or Zr as major components, and a binding component for the metallic element component containing C and any one of S, Se and Te.Type: GrantFiled: February 28, 2002Date of Patent: July 13, 2004Assignees: Dokuritsu Gyousei Houjin Sangyo Gijutsu Sougo Kenkyusho, Daido Tokushuko Kabushiki KaishaInventors: Kiyohito Ishida, Katsunari Oikawa, Toshimitsu Fujii, Yukinori Matsuda, Kozo Ozaki, Seiji Kurata, Takayuki Shimizu
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Patent number: 6667005Abstract: Disclosed is a corrosion resistant steel having good machinability with sufficient corrosion resistance in the ordinary indoor circumstances and suitable for manufacturing shafts of various small motors and OA-machines. The steel comprises, by weight %, C: 0.005-0.200%, P: up to 0.05%, Cu: up to 2.0%, Ni: up to 2.0%, Cr: 2.0-9.0%, one or both of Ti and Zr: in such an amount as [Ti %]+0.52[Zr %]: 0.03-1.20%, one or both of S: 0.01-0.50% and Se: 0.01-0.40%, N: up to 0.050% and O: up to 0.030%, the balance being Fe and inevitable impurities. The steel is characterized by the inclusion therein, which are Ti-based, Zr-based or Ti-Zr-based compound or compounds containing C and one or both of S and Se.Type: GrantFiled: May 15, 2002Date of Patent: December 23, 2003Assignees: Dokuritsu Gyousei Houjin Sangyo Gijutsu Sougo Kenkyusho, Daido Steel Co., LTDInventors: Kiyohito Ishida, Katsunari Oikawa, Takashi Ebata, Koichi Ishikawa, Toshiharu Noda, Tetsuya Shimizu
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Patent number: 6649125Abstract: Disclosed is a free-cutting steel which exhibits good machinability in turning and small roughness of the turned surfaces, and in which substantially no macro-streak-flaw occurs. The free-cutting steel contains, by weight %, C: 0.03-0.20%, Mn: 0.5-3.0%, P: 0.02-0.40%, S: more than 0.2% up to 1.0%, one or both of Ti and Zr (in case of both, the total amount): 0.01-3.0%, O: 0.0005-0.0050% and Pb: less than 0.01%, the balance being Fe and inevitable impurities. The steel is characterized in that it contains, as the inclusion therein, Ti-based and/or Zr-based carbosulfide compound or compounds. The steel may further contain at least one from the group of Bi: up to 0.4%, Se: up to 0.5% and Te: up to 0.1%.Type: GrantFiled: May 31, 2002Date of Patent: November 18, 2003Assignee: Daido Steel Co., Ltd.Inventors: Masakazu Hayaishi, Yutaka Kurebayashi
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Patent number: 6599469Abstract: Disclosed is a non-heat treated steel for soft niriding, which can provide forged parts exhibiting equal to or larger than the limit strain at which cracks occur in straightening by bending and equal to or larger than the fatigue strength when compared with the parts of conventional heat treated steel, such as S48C. The non-heat treated steel for soft nitriding consists essentially of, by weight, C: 0.2-0.6%, Si: 0.05-1.0%, Mn: 0.25-1.0%, S: 0.03-0.2%, Cr: up to 0.2%, sol-Al: up to 0.045%, Ti: 0.002-0.01%, N: 0.005-0.025%, and O: 0.001-0.005%; provided that the conditions, 0.12[Ti%]<[O%]<2.5[Ti%] and 0.04[N%]<[O%]<0.75[N%], are met; the balance being Fe and inevitable impurities; and the structure after hot forging being a mixed structure of ferrite and pearlite.Type: GrantFiled: January 29, 2002Date of Patent: July 29, 2003Assignee: Daido Steel Co., Ltd.Inventors: Kazuhisa Ishida, Koichiro Inoue
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Patent number: 6596227Abstract: A machine structure steel superior in chip disposability and mechanical properties which contains sulfide-type inclusions such that those particles of sulfide-type inclusions with major axes not shorter than 5 &mgr;m have an average aspect ratio not larger than 5.2 and which also contains coarse particles of sulfide-type inclusions such that the relation a/b≦0.25 is satisfied, where a denotes the number of particles of sulfide-type inclusions with major axes not shorter than 20 &mgr;m, and b denotes the number of particles of sulfide-type inclusions with major axes not shorter than 5 &mgr;m. The machine structure steel exhibits good chip disposability and mechanical properties despite its freedom from lead.Type: GrantFiled: August 24, 2001Date of Patent: July 22, 2003Assignee: Kobe Steel, Ltd.Inventors: Yosuke Shindo, Hiroshi Yaguchi, Takehiro Tsuchida, Koichi Sakamoto, Masato Kaiso, Masami Somekawa, Ikuo Hoshikawa, Sei Kimura
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Publication number: 20030118468Abstract: An iron-nickel-cobalt alloy is described which has the following weight percent composition: 1 Carbon 0.04 max. Manganese 0.50 max. Silicon 0.20 max. Sulfur 0.020 max. Cobalt 16-18 Nickel 28-31 Boron 0.020 max.Type: ApplicationFiled: July 22, 2002Publication date: June 26, 2003Inventor: Lin Li
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Publication number: 20030113223Abstract: Disclosed is a free-cutting steel for machine structural use which always exhibits desired machinability, particularly, machinability by cutting with cemented carbide tools. This free-cutting steel is produced by preparing a molten alloy of the composition consisting essentially of, by weight %, C: 0.05-0.8%, Si: 0.01-2.5%, Mn: 0.1-3.5% and O: 0.0005-0.01%, the balance being Fe and inevitable, and adjusting the addition amounts of Al and Ca in such a manner as to satisfy the above ranges, S: 0.01-0.2%, Al: 0.001-0.020% and Ca: 0.00050-0.02%, and the conditions of [S]/[O]: 8-40 [Ca]×[S]: 1×10−5−1×10−3 [Ca]/[S]: 0.01-20 and [Al]: 0001-0.020% to obtain a steel characterized in that the area in microscopic field occupied by the sulfide inclusions containing Ca of 1.0% or more neighboring to oxide inclusions containing CaO of 8-62% is 2.0×10−4 mm2 or more per 3.5 mm2.Type: ApplicationFiled: June 7, 2002Publication date: June 19, 2003Inventors: Takashi Kano, Yutaka Kurebayashi
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Patent number: 6558483Abstract: The Cu precipitation strengthened steel of the invention comprises, on the mass percent basis, C: 0.02-0.10%, Mn: 0.3-2.5%, Cu: 0.50-2.0%, Ni: 0.3-4.0% and Ti: 0.004-0.03% and further comprises Si: 0.01-0.4% and/or Al: 0.001-0.1%, with the contents of incidental impurities being P: not more than 0.025%, S: not more than 0.01%, N: not more than 0.006% and Se: not more than 0.005%, with the value of Pcm defined by the formula (1) given below being not more than 0.28. The steel material made of this Cu precipitation strengthened steel has good and stable CTOD toughness and is suited for use as a steel material for the construction of large industrial machines, ships, marine structures, line pipes, tanks, bridges and like welded structures.Type: GrantFiled: June 7, 2001Date of Patent: May 6, 2003Assignee: Sumitomo Metal Industries, Ltd.Inventors: Hirofumi Nakamura, Jun Furukawa
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Patent number: 6511553Abstract: The present invention provides a steel for steel sheets excellent in workability and showing significantly decreased formation of surface defects, and a method of deoxidizing molten steel for the steel for steel sheets which prevents nozzle clogging during continuous-casting the molten steel. That is, the steel for steel sheets excellent in workability, comprises, based on weight, 0.0001 to 0.0030% of C, up to 0.03% of Si, 0.05 to 0.30% of Mn, up to 0.015% of P, 0.001 to 0.015% of S, up to 0.008% of Al, 0.02 to 0.08% of Ti, 0.0005 to 0.0020% of Ca, 0.0005 to 0.01% of N, optionally containing at least one of 0.001 to 0.02 wt % of Nb and 0.0001 to 0.0010 wt % of B, and the balance of Fe and unavoidable impurities.Type: GrantFiled: October 15, 1999Date of Patent: January 28, 2003Assignee: Nippon Steel CorporationInventors: Junji Nakashima, Takashi Sawai, Mitsuo Uchimura, Wataru Yamada, Shigenori Tanaka, Yasuharu Sakuma, Akinobu Murasato
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Publication number: 20020197531Abstract: A negative electrode active material includes a composition A-B-C containing a first element A which is at least one selected from copper and iron, a second element B which is at least one selected from silicon and tin, and a third element C which is at least one selected from the group consisting of indium, antimony, bismuth, and lead. A nonaqueous electrolyte battery includes a negative electrode containing the negative electrode active material, a positive electrode containing a positive electrode active material, and a nonaqueous electrolyte. The nonaqueous electrolyte battery has a large discharge capacity and excellent cycle performance.Type: ApplicationFiled: November 7, 2001Publication date: December 26, 2002Inventors: Hiroshi Inoue, Shinichiro Yamada, Takuya Endo
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Patent number: 6475305Abstract: The present invention is directed to a steel product for machine structural use having excellent machinability and to a structural steel part for machinery manufactured from the steel product. More particularly, the invention is directed to a steel product for machine structural use having excellent machinability, particularly bringing about excellent “drill life” and exhibiting excellent “chip disposability” in the course of drilling, as well as to a structural steel part for machinery manufactured from the steel product. The steel product for machine structural use has a chemical composition comprising, in mass percent, C: 0.05% to 0.55%; Si: 0.50% to 2.5%; Mn: 0.01% to 2.00%; P: not greater than 0.035%; S: 0.005% to 0.2%; N: not greater than 0.0150%; elements to be added as needed: Cu, Ni, Cr, Mo, V, Nb, Ti, B, Al, Bi, Ca, Pb, Te, Nd, and Se; −23C+Si(5−2Si)−4Mn+104S−3Cr−9V+10≧0; 3.2C+0.8Mn+5.2S+0.5Cr−120N+2.Type: GrantFiled: September 26, 2000Date of Patent: November 5, 2002Assignee: Sumitomo Metal Industries, Ltd.Inventors: Koji Watari, Yasutaka Okada
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Patent number: 6464935Abstract: A steel for shaft, which has corrosion resistance, machinability, and straightness at substantially the same levels as those of free cutting steel 12L14 plated with Ni, which has conventionally been used as a steel for shaft, and need not be plated on its surfaces, thus making it possible to reduce the production cost therefor, and which comprises: 0.05% by mass or less of C; 0.15% by mass or less of Si; 0.40% by mass or less of Mn; 6.0 to 10.0% by mass of Cr; 0.10% by mass or less of S; 0.30 to 0.80% by mass of Ni; 0.10 to 0.30% by mass of Pb; 0.001 to 0.10% by mass of N; and the balance of Fe and an unavoidable impurity; and a steel shaft composed of said steel.Type: GrantFiled: August 31, 2001Date of Patent: October 15, 2002Assignee: Daido Tokushuko Kabushiki KaishaInventors: Yasuhiro Hazama, Kenji Takahashi, Michio Okabe
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Patent number: 6355212Abstract: The invention is directed to anti-corrosive alloys and relates in particular to an alloy containing cobalt, chromium, aluminum, yttrium, silicon, a metal from the second main group, together with the corresponding oxide, in the following proportions: chromium (Cr) 26.0-30%; aluminum (Al) 5.5-13.0%; yttrium (Y) 0.3-1.5%; silicon (Si) 1.5-4.5%; metal from the second main group (magnesium, calcium, barium, strontium) 0.1-2.0%; oxide of the corresponding metal from the second main group 0.1-2.0%; cobalt (Co) remaining percentage. Preferably, tantalum (Ta) is also added in a proportion of 0.5-4.0%, and the remaining percentage of cobalt is replaced by a remaining percentage of Me, Me being understood to mean a metal which may be nickel (Ni) or iron (Fe) or cobalt (Co) or a composition comprising Ni—Fe—Co, Ni—Fe, Ni—Co, Co—Fe.Type: GrantFiled: January 5, 2000Date of Patent: March 12, 2002Assignee: Turbocoating SpAInventor: Nelso Antolotti
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Patent number: 6344093Abstract: A high tensile strength steel product for high heat input welding having excellent toughness in the heat-affected zone and having a tensile strength of at least 490 MPa contains, in terms of percent by weight, from about 0.05% to about 0.18% of C, 0.6% or less of Si, from about 0.80% to about 1.80% of Mn, 0.005% or less of Al, 0.030% or less of P, 0.004% or less of S, 0.005% or less of Nb, from about 0.04% to about 0.15% of V, from about 0.0050% to about 0.00150% of N, and from about 0.010% to about 0.050% of Ti, the ratio of the Ti content to the Al content, Ti/Al, satisfying 5.0 or more, and further contains at least one of from about 0.0010% to about 0.0100% of Ca and from about 0.0010% to about 0.0100% of REM, and the balance being Fe and incidental impurities.Type: GrantFiled: May 9, 2000Date of Patent: February 5, 2002Assignee: Kawasaki Steel CorporationInventors: Akio Ohmori, Fumimaru Kawabata, Keniti Amano
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Patent number: 6299833Abstract: The application describes a steel composition consisting essentially of Carbon 0.50-0.70 weight % Silicon up to 0.40 weight % Manganese 0.55-1.00 weight % Phosphorus 0.030-0.070 weight % Sulphur 0.055 to 0.110 weight % Chromium up to 0.50 weight % Molybdenum up to 0.10 weight % Nickel up to 0.5 weight % Copper up to 0.50 weight % Aluminium up to 0.050 weight % Optionally, Vanadium sufficient to maintain yield strength Nitrogen up to 0.030 weight %, together with, optionally, lead up to 0.4 weight %, and unavoidable impurities, the balance being iron. This steel composition exhibits mechanical properties which are suitable for use in connecting rods but which provide both good fracture splitting performance and good machinability when compared to C70S6 alloys. The application also refers to a fracture splittable steel including between 0.50 to 0.70 wt % C, 0.55 to 1.00 wt % Mn, 0.030 to 0.070 wt % P and 0.055 to 0.Type: GrantFiled: May 31, 2000Date of Patent: October 9, 2001Assignees: Corus UK Limited, United Engineering Forgings LimitedInventors: Michael Cristinacce, Katrina Sarah Blackie, Philip Edward Reynolds, Robert Murray Gardner
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Patent number: 6210496Abstract: A cold rolled steel sheet having high strength and high formability and having excellent crushing performance can include 0.05-0.40 mass % of C, 1.0-3.0 mass % of Si, 0.6-3.0 mass % of Mn, 0.02-1.5 mass % of Cr, 0.010-0.20 mass % of P and 0.01-0.3 mass % of Al, with the remainder consisting essentially of Fe. The steel sheet includes a ferrite major phase and a minor phase consisting of martensite, acicular ferrite and retained austenite. The cold rolled steel sheet can be used in automobiles.Type: GrantFiled: February 12, 1999Date of Patent: April 3, 2001Assignee: Kawasaki Steel CorporationInventors: Syusaku Takagi, Kazuya Miura, Osamu Furukimi, Kei Sakata, Takashi Obara
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Patent number: 6200527Abstract: A carbon or low-alloy steel is provided with improved machinability. The carbon content of the steel is less than 1.5% and the sum of the alloy elements contained therein is less than 9%. The steel contains oxide and sulfide inclusions, and the chemical composition of the steel includes 0.1%≦Mn, 0.01%≦Al≦0.05%, 0.025%≦S≦0.3%,0.002%≦Ca, O≦0.0015% by weight; the “KO oxides” cleanness index is less than 30, all the oxides are lime aluminates, and the average calcium content of type 2, type 3, type 4 and type 5 inclusions is less than 30%. A process of manufacturing such steel and an oxide-core wire for its manufacture are also provided.Type: GrantFiled: July 6, 1998Date of Patent: March 13, 2001Assignee: AscometalInventors: Philippe Damie, Christian Turrel
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Patent number: 6162389Abstract: A non heat-treated steel of high strength, toughness and machinability which can be used in its as-worked state without calling for any special treatment after working. It contains less than 0.05 wt % C, 0.005 to 2.0 wt % Si, 0.5 to 5.0 wt % Mn, 0.1 to 10.0 wt % Ni, more than 1.0 to 4.0 wt % Cu, 0.0002 to 1.0 wt % Al, 0.005 to 0.50 wt % S and 0.0010 to 0.0200 wt % N.Type: GrantFiled: May 26, 1998Date of Patent: December 19, 2000Assignee: Kawasaki Steel CorporationInventors: Kazukuni Hase, Takashi Iwamoto, Yasuhiro Omori, Toshiyuki Hoshino, Tohru Hayashi, Keniti Amano, Toshio Fujita
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Patent number: 6149862Abstract: An alloy and alloy product has about 1.3% to 1.7% by weight concentration of silicon, along with iron, alloying elements, and inevitable impurities and exhibits improved resistance to hydrogen embrittlement and sulfide stress cracking in an intensive hydrogen-charged medium wherein H from the medium acts as an alloying element. The alloy is characterized by an Fe--Si--H system wherein Fe is a donor element with respect to Si and Si is an acceptor element with respect to Fe. Further, the alloying elements are Fe--Si noninteractive elements with respect to Fe and Si, such that the presence of the alloying elements are not donor or acceptor elements with respect to Fe or Si. In several alloy compositions, the alloy has between about 1.38% to 1.63% weight Si. The alloy may further include between about 0.10% to 0.25% weight of C. In one particular alloy, the alloy composition includes about 0.18% of C; although, in one alloy product, an alloy is used having about 0.16% to 0.24% weight of C.Type: GrantFiled: May 18, 1999Date of Patent: November 21, 2000Assignee: The Atri Group Ltd.Inventors: Naum I. Gliklad, Avgust B. Kuslitskiy, Leonid A. Kuslitskiy
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Patent number: 6143242Abstract: A steel for machine structural use which realizes excellent fracture splitability and fatigue strength in its as-hot forged formed articles, and which comprises, based on weight, 0.2 to less than 0.35% of C, 0.1 to 1.1% of Si, 0.1 to less than 0.3% of Mn, 0.01 to 0.2% of P, 0.01 to 0.2% of S, greater than 0.2 to 0.5% of V, 0.01 to 0.1% of Ti, 0.005 to 0.02% of N and the balance of Fe and unavoidable impurities. The steel further comprises, if necessary, one or at least two of the following elements in the following amount or amounts: 0.005 to 0.05% of Al and/or 0.05 to 0.5% of Nb, 0.1 to 0.5% of Cr and 0.1 to 0.5% of Mo.Type: GrantFiled: April 30, 1999Date of Patent: November 7, 2000Assignees: Nippon Steel Corporation, Toyoda Jidosha Kabushiki KaishaInventors: Hiromasa Takada, Masayuki Shibata, Motohide Mori, Atsuo Tanaka
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Patent number: 6117389Abstract: Titanium killed steel sheets which are not troubled by nozzle clogging while they are produced in a continuous casting process, have few surface defects caused by cluster-type inclusions, and are highly rust resistant, and are formed from a melt of titanium killed steel that contains any one or two of Ca and metals REM in an amount of not smaller than 0.0005% by weight, and wherein the steel contains major oxide inclusions of any one or two of CaO and REM oxides in an amount of from about 5 to 50% by weight, Ti oxides in an amount of not larger than about 90% by weight, and Al.sub.2 O.sub.3 in an amount of not larger than about 70% by weight.Type: GrantFiled: September 24, 1998Date of Patent: September 12, 2000Assignee: Kawasaki Steel CorporationInventors: Seiji Nabeshima, Hirokazu Tozawa, Kenichi Sorimachi
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Patent number: 6036790Abstract: The medium carbon, microalloyed forging steel for machine structural use has a small deformation upon fracture in a hot-rolled, hot-forged, or any other hot-worked state, has an inexpensive ferrite-pearlitic microstructure and consists of C: 0.3 to 0.6 wt %, Si: 0.1 to 2.0 wt %, Mn: 0.1 wt % or more and less than 0.4 wt %, P: 0.01 to 0.1 wt %, S: 0.01 to 0.2 wt %, V: more than 0.15 wt % and up to 0.4 wt %, and the balance: Fe and unavoidable impurities, in which the unavoidable impurities include less than 0.005 wt % N. The microalloyed forging steel for machine structural use may further contain Al: 0.005 to 0.05 wt %, one or both of Ti: 0.005 to 0.05 wt % and Nb: 0.05 to 0.2 wt %, and/or one or both of Cr: 0.1 to 0.5 wt % and Mo: 0.1 to 0.5 wt %.Type: GrantFiled: January 25, 1999Date of Patent: March 14, 2000Assignee: Nippon Steel CorporationInventors: Hiromasa Takada, Tetsuro Hashiguchi, Hideo Kanisawa
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Patent number: 5855845Abstract: Steel for the manufacture of molds for injection molding of plastics, wherein its chemical composition contains, by weight: 0.35%.ltoreq.C.ltoreq.0.5%, 0%.ltoreq.Si.ltoreq.0.5%, 0.2%.ltoreq.Mn.ltoreq.2.5%, 0%.ltoreq.Ni.ltoreq.4%, 0%.ltoreq.Cr.ltoreq.4%, 0%.ltoreq.Mo+W/2.ltoreq.2%, 0%.ltoreq.Cu.ltoreq.1%, 0%.ltoreq.V+Nb/2+Ta/4.ltoreq.0.5%, 0.005%.ltoreq.Al.ltoreq.0.2%, 0%.ltoreq.B.ltoreq.0.015%, 0%.ltoreq.Ti+Zr/2.ltoreq.0.3%, 0%.ltoreq.S+Se+Te .ltoreq.0.2%, 0%.ltoreq.Pb+Bi.ltoreq.0.2%, 0%.ltoreq.Ca.ltoreq.0.1%, the remainder being iron and impurities resulting from the production, the analysis simultaneously satisfying the following relationships: Cr+3.times.(Mo+W/2)+10.times.(V+Nb/2+Ta/4).gtoreq.1, R=3.8.times.C+10.times.Si+3.3.times.Mn+2.4.times.Ni+1.4.times.(Cr+Mo+W/2). ltoreq.11, Qu=3.8.times.C+1.1.times.Mn+0.7.times.Ni+0.6.times.Cr+1.6.times.(Mo+W/2)+k B.gtoreq.3, with kB=0.5 if B.gtoreq.0.0005% and kB=0 if not, and: R.ltoreq.Max(2.33.times.Qu-1, 0.9.times.Qu+4).Type: GrantFiled: April 29, 1997Date of Patent: January 5, 1999Assignee: Creusot Loire Industrie Societe AnonymeInventors: Jean Beguinot, Gilbert Primon, Frederic Chenou
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Patent number: 5711914Abstract: The properties of conventional steels for rails, check rails and railroad rolling components can be improved by small amounts of tellurium. This applies particularly to the wear resistance and the mechanical properties in the transverse direction and at oxygen contents of less than 0.0015% and sulfur contents up to 0.007%.Type: GrantFiled: November 18, 1994Date of Patent: January 27, 1998Assignee: NMH Stahwerke GmbHInventor: Wilhelm Heller
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Patent number: 5643532Abstract: A spring steel of medium strength and sufficient corrosion resistance prepared by simple procedures, and therefore, at a low cost, is provided. The spring steel has the alloy composition of: C 0.3-0.6%, Si 1.0-2.0%, Mn 0.1% to less than 0.5%, Cr 0.4-1.0%, V 0.1-0.3%, Ni more than 0.5% to 1.2%, Cu 0.1-0.3% and the balance of Fe, wherein S being at highest 0.005%, and [O], at highest 0.0015%. Addition of Ca 0.001-0.005% is preferable. In order to ensure clearly improved fatigue limit under corrosive environment to the conventional steel, SUP7, specific contents of S, Ni, Cr, Cu and V are chosen in the range set forth above. For the purpose of obtaining such a low hardness after normalizing at which annealing prior to processing is unnecessary contents of C, Si, Mn, Cr and Ni are further chosen in the above ranges.Type: GrantFiled: September 29, 1995Date of Patent: July 1, 1997Assignee: Daido Tokushuko Kabushiki KaishaInventor: Yukio Ito
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Patent number: 5518685Abstract: A steel for darburized gear having softening resistance, consisting essentially of, in weight percentages, 0.18 to 0.25% C, 0.45 to 1.00% Si, 0.40 to 0.70% Mn, 0.30 to 0.70% Ni, 1.00 to 1.50% Cr, 0.30 to 0.70% Mo, up to 0.50% Cu, 0.015 to 0.030% A1, 0.03 to 0.30% V, 0.010 to 0.030% Nb, up to 0.0015% O, 0.0100 to 0.0200% N and the balance consisting of Fe and inevitable impurity elements, wherein quenching at 820.degree. C. or higher after carburization does not cause any ferrite to be formed in a hardened structure of the core part of the carburized steel, and wherein, while tempering is generally performed at 160.degree. to 180.degree. C. after the quenching, reheating at any of temperatures inclusive of the tempering temperature and up to 300.degree. C. does not cause the hardness of a carburized case of the carburized steel to decrease by HV 50 or more from the one after the carburization, quenching and tempering.Type: GrantFiled: March 2, 1995Date of Patent: May 21, 1996Assignee: Mitsubishi Steel Mfg. Co., Ltd.Inventors: Kazuo Sakamoto, Tatsuo Fukuzumi, Hideo Ueno
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Patent number: 5470528Abstract: A low decarburization spring steel consisting essentially of, in weight percentages, 0.40 to 0.75% C, 0.15 to 2.50% Si, 0.30 to 1.20% Mn, 0.005 to 0.100% Al and 0.005 to 0.100% Se, and optionally at least one selected from the group consisting of 0.50 to 2.50% Ni, 0.20 to 1.50% Cr, 0.05 to 1.50% Mo and/or at least one selected from the group consisting of 0.01 to 0.50% V and 0.01 to 0.50% Nb, the balance being Fe and inevitable impurities. The spring steels of this invention considerably reduce decarburization during hot working or heat treatment without recourse to anti-decarburizing agents or special heat treatment equipment.Type: GrantFiled: July 27, 1994Date of Patent: November 28, 1995Assignee: Mitsubishi Steel Mfg. Co., Ltd.Inventors: Hiroharu Motomura, Soichi Takasaki, Kenji Kinoshita
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Patent number: 5403545Abstract: A bearing steel having long rolling life comprising, by weight, 0.65 to 0.90% of C, 0.15 to 0.50% of Si, 0.15 to 1.0% of Mn and 2.0 to 5.0% of Cr, and the balance of Fe. Austenite grain size can be prevented from becoming coarser to make hardening in high temperature possible by further adding one or more of 0.0090 to 0.0200% of N, 0.010 to 0.050% of Al and 0.005 to 0.500% of Nb as optional elements to the steel. Further, rolling fatigue life can be improved by further adding one or more of 0.20 to 0.50% of Ni, 0.10 to 2.00% Of Mo and 0.05 to 1.00% of V as optional elements, and machinability can be improved by further adding one or more of 0.02 to 0.05% of S, 0.005 to 0.10% of rare earth elements, 0.02 to 0.30% of Pb, 0.0005 to 0.0100% of Ca, 0.001 to 0.200% of Bi, 0.005 to 0.20% of Se and 0.005 to 0.100% of Te in the steel as optional elements.Type: GrantFiled: December 14, 1992Date of Patent: April 4, 1995Assignees: Aichi Steel Works, Ltd., Koyo Seiko K.K., Nippondenso Co., Ltd.Inventors: Yatsuka Takata, Akira Muroga, Yoshihiro Wakikado, Takao Ooki, Masao Goto, Hazime Tazumi, Teruo Hoshino, Masayuki Kitamura, Toshihiro Kawaguchi, Yoshitaka Natsume, Akihiro Mizutani
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Patent number: 5372778Abstract: An electromagnetic stainless steel consists essentially of not more than 0.015 wt % of C, not more than 3.0 wt % of Si, not more than 0.5 wt % of Mn, not more than 0.030 wt % of P, not more than 0.030 wt % of S, 4-20 wt % of Cr, 0.2-7.0 wt % of Al, 0.02-0.50 wt % of Bi and the remainder being Fe and inevitable impurity and has excellent magnetic properties, electric resistance, cold forgeability and machinability.Type: GrantFiled: December 9, 1993Date of Patent: December 13, 1994Assignee: Daido Tokushuko Kabushiki KaishaInventors: Shinichiro Yahagi, Akihiko Saito
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Patent number: 5362338Abstract: A non-heat-treating steel for hot forging which does not require heat treatment and still yields high static strength, toughness and fatigue resistance only by air cooling after hot forging. The main ingredients are, by weight %, 0.10-0.30% C, 0.05-0.50% Si, 0.80-2.00% Mn, 0.30-1.50% Cr, 0.05-0.50% Mo, 0.002-0.060% Al, 0.05-0.50% V, 0.008-0,020% N, and the balance Fe and inevitable impurities, where contents of some component elements should satisfy the following conditions,%Mo+%V.gtoreq.0.20(%),1.8.times.%Mn+%Cr+0.5.times.%Mo.ltoreq.20.times.%C, andBs.gtoreq.550(.degree.C.)where Bs represents the bainite transformation temperature and is defined by Bs=830-270.times.C%-90.times.Mn%-70.times.Cr%-83.times.Mo%. Since the mechanical properties are obtained through air cooling, the mechanical properties are stable albeit the size of the forged article and the forging conditions. The non-heat-treating steel is especially suited for use in chassis parts of automobiles and hydraulic parts of construction machines.Type: GrantFiled: March 4, 1993Date of Patent: November 8, 1994Assignee: Aichi Steel Works Ltd.Inventors: Naoki Iwama, Ichie Nomura
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Patent number: 5310432Abstract: A toothed wheel for use in automobiles and a method for its manufacture are disclosed. The toothed gear is of a dish-shaped disk having a thickened peripheral edge portion in an outer and/or inner side of which gear teeth are shaped, at least the surface area of the gear teeth being of a martensite structure, the disk being made of a steel comprising a ferrite-cementite-graphite structure in which 50% or more of cementite has been changed to graphite, the steel composition of the disk consisting essentially of, by weight %:C: 0.20-0.70%, Si: 0.05-1.00%, Mn: 0.05-0.50%, sol. Al: 0.01-1.00%, N: 0.002-0.010%, B: 0.0003-0.0050%, Ca: 0-0.01%, Cu: 0-1.00%, Ni: 0-2.00%,and a balance of Fe and incidental impurities in which the content of P is restricted to not larger than 0.020% and the content of S is restricted to not larger than 0.010%.Type: GrantFiled: June 29, 1993Date of Patent: May 10, 1994Assignees: Sumitomo Metal Industries, Ltd., Kubota Iron Works Co., Ltd.Inventors: Kiyoshi Fukui, Shigeaki Yamanaka
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Patent number: 5244626Abstract: A low alloy steel product having high hardenability and good machaniability in the presence of a relatively low S content, and utilizing minimal quantities of the currently expensive elements Ni and Mo is disclosed, the product having the following approximate composition:______________________________________ C from about .42 to about .52 Si from about .15 to about .35 Ni from about .65 to about .95 Cr from about 1.40 to about 1.60 Mo from about .30 to about .50 Mn from about .75 to about .95 V from about .04 to about .10 S from about .010 to about .025 Ti from about .003 to about .075 Al from about .015 to about .030 Ca about 15% of Al H 2.Type: GrantFiled: August 3, 1992Date of Patent: September 14, 1993Assignee: A. Finkl & Sons Co.Inventors: Charles W. Finkl, Nicholas Cerwin
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Patent number: 5232660Abstract: A low alloy steel having a medium carbon content, and less than about 5% and less than about 1% Mn, which has hardenability approaching unity derived from the presence of N in an amount of from about 100-400 ppm, and a method of manufacturing such a steel which preferably contains the processing step in the late stages of manufacture of bubbling nitrogen gas through the molten steel.Type: GrantFiled: September 8, 1992Date of Patent: August 3, 1993Assignee: A. Finkl & Sons Co.Inventors: Charles W. Finkl, Albert L. Lehman
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Patent number: 5223049Abstract: A steel having such a good machinability that it can be directly cut without being annealed and a good induction hardenability. The steel consists essentially of C: 0.37-0.45%, Si: up to 0.35%, Mn: more than 1.0% - up to 1.5%, B: 0.0005-0.0035%, Ti: 0.01-0.05%, Al: 0.01-0.06% and the balance of Fe, the content of N being up to 0.022 and has a fine structure of ferrite crystal grain size number 6 or more as defined by JIS-G0552. In addition to the above basic composition, the alloy may further contain some optional alloying elements.The material is suitable for manufacturing machine structural parts such as drive shafts of automobiles.Type: GrantFiled: November 8, 1991Date of Patent: June 29, 1993Assignees: Daido Tokushuko Kabushiki Kaisha, NTN CorporationInventors: Tatsumi Urita, Kunio Namiki
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Patent number: 5213633Abstract: An electric resistance welded steel pipe for machine structural use exhibiting excellent machinability comprises, in weight percent, 0.02-0.60% C, not more than 0.4% Si, 0.20-2.0% Mn, not more than 0.030% P, not more than 0.040% S, 0.001--0.030% T.Al, 0.0020-0.0100% N, not more than 0.0060% O, and one or both of not more than 0.040% Bi, not more than 0.040% Pb and not, Te and provided that the total amount of Bi and pb is not more than 0.050%, the remainder being Fe and unavoidable impurities. It may further comprise one or both of 0.10-1.50% Cr and 0.10-0.60% Mo and/or not more than 0.020% Ca, provided that Ca%/(1.25.times.0%+0.625.times.S%).gtoreq.0.05.Type: GrantFiled: November 20, 1991Date of Patent: May 25, 1993Assignee: Nippon Steel CorporationInventors: Kenji Hada, Yasuo Kimiya, Daigo Sumimoto
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Patent number: 5139737Abstract: Disclosed is a steel for plastics molds superior in weldability. The steel consists essentially of C: 0.1 to 0.3%, Mn: 0.5 to 3.5%, Cr: 1.0 to 3.0%, Mo:0.03 to 2.0%, V:0.1 to 1.0% and S: 0.01 to 0.10%; Si: not more than 0.25%, P: not more than 0.2%, and B: not more than 0.002%; the balance being substantially Fe. The alloy composition should satisfy the following formula:BH=326.0+847.3 (C%)+18.3 (Si%) -8.6 (Mn%)-12.5 (Cr%).ltoreq.460The steel can be welded in the process of manufacturing a plastics mold without reqiring preheating and postheating.Type: GrantFiled: December 5, 1990Date of Patent: August 18, 1992Assignee: Dadio Tokushuko Kabushiki KaishaInventors: Koichi Sudo, Masaru Nagata
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Patent number: 5017248Abstract: A hot rolled steel sheet with a high strength and a distinguished formability, and a process for producing the same are disclosed. The steel sheet comprises 0.15 to 0.4% by weight of C, 0.5 to 2.0% by weight of Si, and 0.5 to 2.0% by weight of Mn, the balance being iron and inevitable impurities, and has a microstructure composed of ferrite, bainite and retained austenite phases with the ferrite phase being in a ratio (V.sub.PF /d.sub.PF) of polygonal ferrite volume fraction V.sub.PF (%) to polygonal ferrite average grain size d.sub.PF (.mu.m) of 7 or more and the retained austenite phase being contained in an amount of 5% by volume or more on the basis of the total phases. The steel sheet can be produced with a high productiviity and without requiring special alloy elements.Type: GrantFiled: November 27, 1989Date of Patent: May 21, 1991Assignee: Nippon Steel CorporationInventors: Osamu Kawano, Manabu Takahashi, Junichi Wakita, Kazuyoshi Esaka
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Patent number: 4999158Abstract: This invention relates to iron-base alloy compositions, nickel containing austenitic ferrous alloy compositions (especially low nickel compositions) and dopants added to low nickel austenitic alloys as a means of improving the elevated temperature oxidation resistance of the resultant material.Type: GrantFiled: November 2, 1988Date of Patent: March 12, 1991Assignee: Chrysler CorporationInventor: John M. Corwin
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Patent number: 4978499Abstract: A soft steel for machine cutting with high machinability performances having a content of C.ltoreq.0.25%, a content of Mn of 0.8 to 1.5%, a content of P of .ltoreq.0.1%, a content of S of 0.15 to 0.40%, and a content of Si of 0.05 to 0.40%, expressed in percentages by weight. After finishing of the metal, the inclusions of manganese sulfide are surrounded by a plastic oxide layer of an average composition SiO.sub.2 : 35 to 45%; Al.sub.2 O.sub.3 : 10 to 20%; CaO: 15 to 25%; MnO: 10 to 20%. In producing this grade, after the addition of silicon and manganese, the liquid metal is agitated in the presence of a slag of a composition CaO: 20 to 55%; SiO.sub.2 : 35 to 65%; Al.sub.2 O.sub.3 : 15 to 40%; with a CaO %/SiO.sub.2 % ratio of about 1.Type: GrantFiled: December 1, 1989Date of Patent: December 18, 1990Assignee: UnimetalInventors: Gilles Pierson, Louis Payraudeau, Jean Bellot
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Patent number: 4957699Abstract: The present invention relates to a soft magnetic steel improved in electric resistance, coercive force, magnetic flux density, magnetic response, cold forgeability, machinability, and corrosion resistance, which is characterized by the composition containing by weight, 0.015% or lower C+N, 0.20% or lower Si, 0.20% or lower Mn, 7 to 13% Cr, 2 to 5% Al, and balance of Fe with impurities, which is applicable to core materials of electronic fuel injection systems, solenoid valves, electromagnetic sensors, etc.Type: GrantFiled: April 28, 1989Date of Patent: September 18, 1990Assignee: Aichi Steel Works Ltd.Inventors: Yoshinobu Honkura, Hideki Fujii, Koji Murata
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Patent number: 4946645Abstract: A steel composition for gears, consisting of: 0.10-0.30% by weight of C; less than 0.15% by weight of Si; no more than 1.5% by weight of Mn; no more than 0.015% by weight of P; no more than 0.005% by weight of S; 0.50-1.50% by weight of Cr; 0.005-0.06% by weight of Pb; and the balance being Fe and inevitably included impurities.Type: GrantFiled: March 28, 1989Date of Patent: August 7, 1990Assignees: Daido Tokushuko Kabushiki Kaisha, Honda Giken Kogyo Kabushiki KaishaInventors: Kunio Namiki, Atsuyoshi Kumura, Sukehisa Niwa, Toshihiko Matsubara
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Patent number: 4915900Abstract: A free-cutting steel having a high fatigue strength which consists essentially of 0.30-0.50% C, 0.10-0.50% Si, 0.50-1.00% Mn, 0.04-0.12% S, 0.005-0.20% V, 0.005-0.018% Al, 0.05-0.30% Pb, and 0.001-0.006% Ca by weight, and as the remainder, Fe and inevitable impurities. It may additionally contain 0.50% or less of Cr.Type: GrantFiled: October 14, 1988Date of Patent: April 10, 1990Assignees: Aichi Steel Works, Ltd., Toyota Jidosha Kabushiki KaishaInventors: Itie Nomura, Takao Ooki, Yoshihiro Wakikado
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Patent number: 4880479Abstract: A resulfurized and rephosphorized free-machining steel bar formed by cold drawing a hot rolled steel bar has the composition, by weight, C up to 0.08%; Mn 0.6% to 1.4%; Si up to 0.1%; P at least 0.03%; S 0.25% to 0/50%; Cb 0.02% to 0.10%; the sum of Ni, Cr, Mo and Cu up to 0.15%; balance iron. The ratio of %Mn/%S is from 1.6 to 4.0, and the ratio of [%Mn-(1.62.times.%S)]/%Cb is from 2 to 50. The yield strength of the steel bar is further determined by the draft in cold drawing the bar from the hot rolled state and the size and cross section of the bar after draft. The relationship between strength and ductility is further improved by heavy drafting in cold drawing the bar from the hot rolled state.Type: GrantFiled: June 9, 1988Date of Patent: November 14, 1989Assignee: Stanadyne, Inc.Inventors: Stephen P. Birman, Richard B. Smith, Richard L. Thompson
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Patent number: 4865805Abstract: Composition and method for producing a low-sulphur, free-machining steel, substantially free of lead and including in weight percent about 0.05-0.40 copper, 0.005-0.040 tellurium, 0.002-0.35 bismuth, 0.002-0.05 tin, up to 0.55 carbon, and less than 0.25 sulphur, traces (up to about 0.005 weight percent) of barium, and the balance being iron. The elements bismuth, tellurium and tin are added as a molten alloy to the molten steel and uniformly distributed therethrough. The elements copper and barium can be added separately into the steel stream ahead of the molten addition inflow. The mass is then cooled to provide a solid metal casting substantially free of blemishes and free of surface checking and tearing. The casting is characterized by enhanced machining properties.Type: GrantFiled: November 15, 1988Date of Patent: September 12, 1989Assignee: Frema, Inc.Inventor: Michael O. Holowaty
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Patent number: 4863684Abstract: A vertical first stream of molten metal flows from a ladle into the tundish of a continuous casting apparatus. A second stream composed of solid, particulate alloying ingredient and a non-oxidizing carrier gas is directed into the first stream with a nozzle. The two streams each have unenclosed parts exposed to the atmosphere surrounding the ladle and the tundish. The nozzle is cooled with a non-oxidizing gas flowing through a nozzle cooling jacket and exhausted at the outlet end of the nozzle. The nozzle interior has a converging downstream end portion for converging the second stream just before it leaves the nozzle.Type: GrantFiled: January 13, 1989Date of Patent: September 5, 1989Assignee: Inland Steel CompanyInventor: Mark A. Hubbard
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Patent number: 4842816Abstract: A steel composition particularly suitable for the manufacture of electric resistance welded pipes for use in most hostile environments and able to display excellent sour resistance and high toughness. The aluminum content of the steel composition is reduced to not more than 0.005%, while from 0.006 to 0.2% in total of one or both of titanium and zirconium is used instead for steel containing 0.0005 to 0.008% Ca. The steel, apart from iron and unavoidable impurities further contains:0.01 to 0.35% C0.02 to 0.5% Si0.1 to 1.8% Mnnot more than 0.015% P, andnot more than 0.003% SCu, Ni, Cr, Mo, Nb and V may be added in appropriate amounts to enhance the steel performance.Type: GrantFiled: July 27, 1987Date of Patent: June 27, 1989Assignee: Nippon Steel CorporationInventors: Akihiro Miyasaka, Hiroyo Haga, Takeshi Terasawa
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Patent number: 4806304Abstract: Sulfur-containing free-cutting steel may have an improved machinability and fewer defects by adding certain amounts of Te, Pb and Bi to prevent elongation of sulfide inclusion particles, and by lowering Al-content to decrease Al.sub.2 O.sub.3 of oxide inclusions or by lowering O-content to decrease large Al.sub.2 O.sub.3 inclusion particles. The free-cutting steel may be produced by continuous casting.Type: GrantFiled: June 17, 1985Date of Patent: February 21, 1989Assignee: Daido Tokushuko Kabushiki KaishaInventors: Atsuyoshi Kimura, Sadayuki Nakamura, Makoto Saito
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Patent number: 4786466Abstract: Composition and continuous casting method for producing a low-sulphur, free-machining steel, substantially free of lead and including in weight percent about 0.05-0.40 copper, 0.005-0.040 tellurium, 0.002-0.15 bismuth, 0.002-0.05 tin, up to 0.55 carbon, and less than 0.25 sulphur, traces (up to about 0.005 weight percent) of barium, and the balance being iron. The elements bismuth, tellurium and tin are added as a molten alloy to the molten steel and uniformly distributed therethrough. The elements copper and barium can be added separately into the steel stream ahead of the molten addition inflow. The mass is then cooled to provide a solid metal casting substantially free of blemishes and relatively free of surface checking and tearing. The casting is characterized by enhanced machining properties.Type: GrantFiled: February 19, 1987Date of Patent: November 22, 1988Assignee: Frema, Inc.Inventor: Michael O. Holowaty