Abstract: A fluid catalytic reactor vessel having at its upper end a single centrally positioned primary cyclone having a gas-solids inlet fluidly connected to the downstream end of a fluid catalytic riser, which riser is positioned externally from a fluid catalytic reactor vessel. The primary cyclone is further provided with a gas outlet conduit at its upper end fluidly connected to one or more secondary cyclone separators, which secondary cyclone separators are positioned in the space between the centrally positioned primary cyclone and the wall of the reactor vessel and which secondary cyclones have means to discharge solids to the lower end of the reactor vessel and means to discharge a gaseous stream poor in solids to a gas outlet of the reactor vessel. The primary cyclone is further provided with a primary stripping zone at its lower end and means to discharge pre-stripped solids from the primary cyclone to the lower end of the reactor vessel.

Abstract: A grid construction for a fluidized bed reactor, the reactor including a reaction chamber defined by substantially vertical walls, in which a fluidized bed of solid particles is maintained, and a windbox under the reaction chamber, in a lower portion of the reactor. The grid construction is positioned between the reaction chamber and the windbox and includes (a) multiple continuous nozzle lines for distributing fluidizing gas from the windbox into the reaction chamber, for suspending the fluidized bed in the reaction chamber, and (b) continuous trenches between the nozzle lines. The nozzle lines include multiple gas outlets, having a main gas flow direction, at side faces of said nozzle lines, for directing fluidizing gas jets towards an adjacent trench.

Abstract: A fluidized bed apparatus for batch-by-batch or continuous process control is provided that allows the processes in the fluidization region to be influenced as desired, especially in terms of material movement and dwell time. The fluidized bed apparatus is formed from at least two processing regions and the processing regions are connected to each other by overflow channels. The first processing region is provided with a solids inlet and the last processing region is provided with a solids outlet. For influencing the dwell time, the material to be treated is supplied to at least two processing regions one after the other and flows through these regions, wherein the material transport direction is a cross flow relative to the flow of the fluidization means.

Abstract: Ethylenically unsaturated monomers are polymerized in a gas-phase fluidized-bed reactor comprising a reactor space (1) in the form of a vertical tube, a calming zone (2) adjoining the upper part of the reactor space, a circulated gas line (3), a circulated gas compressor (4), a cooling apparatus (5), a gas distributor plate (6) which forms the lower boundary of the reactor space and, if desired, a flow divider (7), wherein the gas distributor plate (6) has a plurality of gas flow orifices (8) whose outlet sides are widened conically.

Abstract: A downflow catalytic cracking reactor, comprising the following components: catalyst delivery pipe (1), reactor top cover (2), feed nozzle (3), reactor vessel (6), downflow reaction pipe (9), the upper end of the outer body is close connected to top cover (2) along the direction of circumference; the bottom of the outer wall body is close connected to the outer wall of the downflow reaction pipe; the upper section of the downflow reaction pipe is located inside the reaction vessel, while the lower section extends from the bottom of the outer body; feed nozzle (3) is located on the top cover (2) and/or side wall of the reactor vessel (6) with the outlet of the feed nozzle being above the inlet of the downflow reaction pipe; catalyst delivery pipe (1) is fixedly joined to the reactor vessel and in communication with catalyst lifting zone (7) formed by the reaction vessel and the downflow reaction pipe.

Abstract: Described is a catalyst regenerator system that includes a regenerator vessel within which is a verticaliy extending partition that divides a fluidized bed zone of the regenerator vessel into a dense phase fluidized bed zone and a fast-fluidized bed zone. Apparatus is provided to introduce spent catalyst into the fast-fluidized bed zone and to remove regenerated catalyst from the dense phase fluidized bed zone. The partition is equipped with openings that provide for the flow of catalyst from the dense phase fluidized bed zone to the fast-fluidized bed zone.

Abstract: Uranium trioxide is reduced to uranium dioxide using microwave radiation or radiofrequency radiation directed in such a way that the radiation encounters an interface between uranium trioxide and the uranium-containing reduction product without first having passed through that product. By this method, and also using a reducing gas, it is possible to obtain UO2 with an O:U ratio less than 2.04:1.

Abstract: A bitumen/steam pre-mixer and atomizing nozzle combine to produce a jet of minute liquid droplets (bitumen) in carrier gas (steam). The jet is injected into a draft tube mixer positioned in a fluid bed of hot coke particles suspended in steam and contained within a fluid coking reactor. The movement of the jet through the draft tube passageway induces a stream of coke particles in steam to be drawn into the passageway, where the jet and stream mix vigorously and bitumen droplets have an enhanced probability of contacting coke particles.

Abstract: A method and system for recovering fines from a light FCC-type effluent gas. Cracked gases from the reactor are cooled by direct contact with circulating oil in an oil quench tower. The circulating oil also washes out the catalyst fines carried with the reactor effluent gas. A flow of the oil from the quench tower bottoms is sent through one of a pair of filters to remove fines and recycled to the tower. The other filter is in backwash operation using a compressed gas to remove the fines therefrom and into a surge drum. Fuel oil or quench oil is added to the drum to form a slurry, which carries the catalyst fines to the regenerator where the oil is combusted to supply the FCC system heat requirements. Since a minimum amount of fuel oil is generated in the FCC, fuel oil is imported to inventory the quench tower.

Abstract: A method and an apparatus in a fluidized bed heat exchanger including a heat exchange chamber having a fluidized bed of solid particles, heat transfer surfaces, an inlet, and an outlet. Particles are fed through the inlet onto the upper surface of the bed of solid particles by a guiding channel. The guiding channel, which extends from above the upper surface of the bed of solid particles to the surface thereof, or to below the surface, passes the solid particles to the restricted area of the surface. The outlet is formed in the area of the guiding channel to remove particles from the area delimited by the guiding channel. Uncooled particles can thus be removed from the heat exchange chamber.

Abstract: Ethylenically unsaturated monomers are polymerized in a gas-phase fluidized-bed reactor comprising a reactor space (1) in the form of a vertical tube, a calming zone (2) adjoining the upper part of the reactor space, a circulated gas line (3), a circulated gas compressor (4), a cooling apparatus (5), a gas distributor plate (6) which forms the lower boundary of the reactor space and, if desired, a flow divider (7), wherein the gas distributor plate (6) has a plurality of gas flow orifices (8) whose outlet sides are widened conically.

Abstract: A catalyst support structure e.g. for use in an ammonia oxidation reactor, comprising a series of primary supports (19) disposed above a catalyst bed, a lattice assembly disposed beneath the catalyst bed and on which the catalyst bed rests, said lattice assembly being suspended from the primary supports (19) by suspending means (27) extending through the catalyst bed. Preferably the support structure includes a static start-up burner arrangement in the form of one or more perforated tubes (24) adjacent the primary supports (19).

Abstract: The present invention relates to a partitioned jetting fluidized bed with double nozzles, especially to a jetting fluidized-bed reactor with gas distributor, where a inclined nozzle is fixed at the side wall of the jetting fluidized bed above the gas distributor, and the gas pre-distribution chamber with gas distributor consists of a gas pre-distribution chamber with combined gas distributor and a gas pre-distribution chamber with perforated distributor. The two gas pre-distribution chambers are separated by a partition plate. The present invention can not only avoid the local agglomeration of the particles and the operation termination accident, but also broadens the adjustable range of the jet gas velocity and the distributor fluidization velocity. The excellent particle circulation can be reached in this jetting fluidized bed.

Abstract: The present invention relates to a method for continuous production of carbon nanotubes in a nano-agglomerate fluidized bed, which comprises the following steps: loading transition metal compounds on a support, obtaining supported nanosized metal catalysts by reducing or dissociating, catalytically decomposing a carbon-source gas, and growing carbon nanotubes on the catalyst support by chemical vapor deposition of carbon atoms. The carbon nanotubes are 4˜100 nm in diameter and 0.5˜1000 &mgr;m in length. The carbon nanotube agglomerates, ranged between 1˜1000 &mgr;m, are smoothly fluidized under 0.005 to 2 m/s superficial gas velocity and 20˜800 kg/m3 bed density in the fluidized-bed reactor. The apparatus is simple and easy to operate, has a high reaction rate, and it can be used to produce carbon nanotubes with high degree of crystallization, high purity, and high yield.

Abstract: In order to produce granules granulometrically polidispersed in a very little range, a fluid bed granulation process of the type comprising the steps of preparing a fluid bed of seeds (S1) of the substance to be granulated, having a free surface (P) substantially horizontal; and feeding a continuos flow (L) of a fluid comprising a growth liquid, provides in the fluid bed for a continuous vortex (V) with a substantially horizontal axis, in which an upper zone (Z1) of seeds wetting and evaporation of possible solvent contained in the flow (L) and a lower zone (Z2) of solidification/consolidation of the growth liquid are identified.

Abstract: The present invention is directed to a hydrocarbon conversion apparatus and process. The apparatus comprises the following: a plurality of riser reactors, each having a first end into which a catalyst is fed, a second end through which the catalyst can exit, and optionally a center axis extending therebetween. The apparatus also includes a separation zone having a plurality of inlets, each inlet not being oriented along the center axes of the riser reactors, the separation zone being provided to separate the catalyst from products of a reaction conducted in the hydrocarbon conversion apparatus. A plurality of deviating members are also provided, each deviating member being in fluid communication between the second end of a respective riser reactor and a respective inlet of the separation zone. The apparatus also includes a catalyst retention zone provided to contain catalyst, which is fed to the riser reactors.

Abstract: A novel flow deflector employed in a fluidized bed reactor for olefin polymerization is disclosed, which is installed on the entry conduit of the reactor, comprising an annular plate and a cone plate and providing at least three paths for the recycle stream to enter the mixing chamber, thereby permitting all the liquid and/or solid material to achieve a more complete and uniform mixing.

Abstract: A catalyst regenerator for regenerating spent light FCC catalyst and heating the catalyst to supply heat to an FCC reactor. The regenerator has discharge outlets for catalyst and off gas and a valve for introducing spent catalyst through a central stand pipe portion. The regenerator houses a dense phase catalyst bed. A centerwell receives a lower end of the standpipe portion and defines an annulus therebetween. The spent catalyst is introduced through the standpipe portion into the annulus. A fuel distributor introduces fuel into the centerwell for mixing with the catalyst in the annulus. A fluidization distributor introduces fluidization gas into the centerwell for fluidizing the catalyst in the annulus. A radial slot in the centerwell introduces the catalyst and fuel mixture from the annulus below the upper surface of the dense phase bed. An air distributor located below the radial slot introduces combustion air into the dense phase bed.

Abstract: A fluidized bed reactor (10) for chemically transforming reactants to generate a desired product, having a hollow, elongated, vertically oriented reactor housing (12) for confining the reaction and an unobstructed collection path (18) below the reaction zone for funneling the residue of the process to an exit port (32). A central gas inlet (22) proximate the bottom of the reaction zone within the housing directs gas parallel to the vertical axis of the housing to maintain the raw materials in suspension. A plurality of individually controlled peripheral gas jets (24) positioned at least two elevations along the elongated dimension of the reaction housing (12), and located circumferentially around the housing (12) at each elevation, introduce gas at an angle to promote mixing of the entrained materials in suspension. The clog-free collection path (18) below the reaction zone funnels the residue of the process to an exit port (32) where it is continuously removed by a screw feeder (34).

Abstract: A bitumen/steam pre-mixer and atomizing nozzle combine to produce a jet of minute liquid droplets (bitumen) in carrier gas (steam). The jet is injected into a draft tube mixer positioned in a fluid bed of hot coke particles suspended in steam and contained within a fluid coking reactor. The movement of the jet through the draft tube passageway induces a stream of coke particles in steam to be drawn into the passageway, where the jet and stream mix vigorously and bitumen droplets have an enhanced probability of contacting coke particles.

Abstract: Combustibles such as wastes are gasified in a fluidized bed. A fluidized-bed furnace has a heat recovery region in addition to a combustion region. The temperature of a fluidized bed or the temperature of a freeboard is controlled so as to be kept at a predetermined value by adjusting the heat recovery rate in the heat recovery region.

Abstract: A catalyst activator vessel for heat conditioning a catalyst is disclosed. The activator vessel includes inner and outer vessels, a perforated, normally generally horizontal grid plate within the inner vessel, and a fluid path extending through the grid plate within the vessel. The inner vessel can have an inside diameter of at least 50 inches (1.27 m). The space between the inner and outer vessels defines a flue. The perforated grid plate within the inner vessel can have an upper surface perforated with a pattern of overlapping, generally conical depressions and a lower surface, optionally overlapping by at least 17%. The fluid path extends upwardly through the perforated grid plate and is a conduit along which a fluid flows through the grid plate. The fluid will fluidize a particulate material, such as a catalyst, disposed above the grid plate in the inner vessel.

Abstract: A fluidized bed reactor includes at least one furnace section delimited by side walls and a bottom grid, the at least one furnace section provided for containing a bed of fluidized solid particles therein, and a supply for introducing a gas into the at least one furnace section at a level above the bottom grid. The supply includes (i) a gas source chamber, (ii) at least one opening in at least one of the side walls at a level above the bottom grid, and (iii) at least one conduit, having a first end connected to the at least one opening at a first vertical level and a second end connected to the gas source chamber for introducing gas from the gas source chamber to the at least one furnace section. The at least one conduit provides a solid flow preventing element for preventing solid particles from flowing backward from the at least one furnace section into the at least one conduit.

Abstract: Ethylenically unsaturated monomers are polymerized in a gas-phase fluidized-bed reactor comprising a reactor space (1) in the form of a vertical tube, a calming zone (2) adjoining the upper part of the reactor space, a circulated gas line (3), a circulated gas compressor (4), a cooling apparatus (5), a gas distributor plate (6) which forms the lower boundary of the reactor space and, if desired, a flow divider (7), wherein the gas distributor plate (6) has a plurality of gas flow orifices (8) whose outlet sides are widened conically.

Abstract: A fluid bed processing system for particles with an agitation system includes a product chamber with an interior and a plurality of elongated structures. The elongated structures extend at least partially across the interior of the product chamber and are positioned in the product chamber where the particles are located. The fluid bed processing system also includes a system for engaging the elongated structures to agitate the particles in the product chamber.

Abstract: The invention relates to a process for carrying out reactions in fluidized beds with transversal introduction of a reactant selected from oxygen or an oxygen-containing gas and a combustible reactant into a fluidized particle bed by transversal injection at supersonic speed by supersonic nozzles.

Abstract: A fluid bed processing system with a spraying apparatus in accordance with one embodiment of the present invention includes an expansion chamber and at least one spraying apparatus which extends into the expansion chamber. The spraying apparatus has a plurality of single nozzles which are spaced along the spraying apparatus and has at least one fluid passage connected to each of the single nozzles.

Abstract: Fluid/solids contacting in a fluidization reactor is enhanced by passing the fluidization fluid through a fine screen positioned below the fluidized bed of solid particulates, thereby decreasing axial dispersion in the reactor.

Abstract: A fluid inlet nozzle distributor for a downflow fixed bed reactor which is a cylindrical housing having inlet and outlet openings and a swirl chamber disposed within said housing, whereby said swirl chamber imparts rotational motion to a fluid exiting said inlet nozzle.

Abstract: The present invention relates to a nozzle for the injection of a liquid under pressure (3), comprising a vertical feed pipe (1) surmounted by a hollow head (3), the liquid under pressure being conducted between the outer wall (4) of the vertical feed pipe (1) and an inner tube (5), the upper part of the nozzle comprising at least one lateral orifice (6) for expelling the liquid under pressure (3).

Abstract: The invention concerns a stripping method for extracting solid fluidized particles whereby the particles to be stripped are subjected to a first stripping in a first chamber (9), then at least a second stripping in a second chamber (10) wherein are provided solid/gas separating means allowing the gaseous fluids derived from the second stripping to directly pass through from the bottom to the top but preventing them from going up again into the first chamber (9). The invention also concerns a device for implementing said method.

Abstract: The present invention relates to a device for injecting a hydrocarbon charge into a catalytic cracking reactor comprising in particular an envelope (1), a main (liquid) charge feed tube (3), and an inlet (2) for an auxiliary gaseous fluid. According to the invention, charge feed tube (3) is divided, inside envelope (1), into at least two secondary lines (4) designed to distribute said charge uniformly, each secondary line (4) terminates coaxially with the inlet of an element (7) of the venturi type, and the auxiliary gaseous fluid is mixed with the charge at the inlet of said venturi (7). The present invention applies in particular to catalytic cracking of heavy hydrocarbon charges.

Abstract: A grid construction for a fluidized bed reactor, the reactor including a reaction chamber defined by substantially vertical walls, in which a fluidized bed of solid particles is maintained, and a windbox under the reaction chamber, in a lower portion of the reactor. The grid construction is positioned between the reaction chamber and the windbox and includes (a) multiple continuous nozzle lines for distributing fluidizing gas from the windbox into the reaction chamber, for suspending the fluidized bed in the reaction chamber, and (b) continuous trenches between the nozzle lines. The nozzle lines include multiple gas outlets, having a main gas flow direction, at side faces of said nozzle lines, for directing fluidizing gas jets towards an adjacent trench.

Abstract: A method and apparatus for removing sulfur from a hydrocarbon-containing fluid stream wherein desulfurization is enhanced by improving the contacting of the hydrocarbon-containing fluid stream and sulfur-sorbing solid particulates in a fluidized bed reactor.

Abstract: Apparatus and process for heat exchange with fluid beds comprises heat-exchange tubes located longitudinally with respect to the axis of a fluidization zone with a rectangular pitch, one side of which having a length at least one and a half times the length of the other side and/or with a triangular pitch, having two sides each at least one and a half times the length of the shortest side reduces the impact of the heat-exchange tubes on the fluidization characteristics of the fluid bed. The invention is particularly suitable for oxidation reactions using molecular oxygen-containing gas in the presence of a fluid bed of fluidizable catalyst, such as (a) the acetoxylation of olefins, (b) the oxidation of ethylene to acetic acid and/or the oxidation of ethane to ethylene and/or acetic acid, (c) the ammoxidation of propylene and/or propane to acrylonitrile and (d) the oxidation of C4's to maleic anhydride.

Abstract: Disclosed is an apparatus for the calcination of materials using low temperature heating and indirect heating for calcination. Also disclosed are a variety of processes for calcination of materials which have reduced emissions of pollutants compared to conventional processes.

Abstract: This invention is to a circulating fluid bed reactor that is designed so as to have the ability to adjust catalyst holdup within the reaction zone of the reactor while maintaining substantially constant catalyst circulation rate through the reaction zone. The ability to adjust catalyst hold up independently of catalyst circulation rate provides an advantage of having the ability to maintain a constant conversion level as catalyst activity or feed rates change.

Abstract: Staged combustion in a single regenerator of a FCC unit is disclosed. The regenerator has a spent catalyst distributor at the top of the catalyst bed, and an air grid at the lower end of the bed. A baffle separates the catalyst bed into upper and lower stages. Excess oxygen is present in the lower bed; partial CO combustion mode is maintained in the upper bed. The baffle inhibits backmixing flux to achieve sufficient staging to burn the catalyst clean under partial CO combustion. This achieves a clean burn of the catalyst in a single regenerator vessel in the partial CO combustion operating mode. Surprisingly, the baffle also reduces catalyst entrainment in the dilute phase, thereby cutting particulate emissions from the regenerator and reducing cyclone wear.

Abstract: CaS oxidation has CaS particles oxidized into CaSO4 completely as far as to the interior of the particle. The interior of an oxidation apparatus 1 is partially partitioned by a partition 22 to thereby form a first fluidized bed 20 on the inner side, a second fluidized bed 21 on the outer side and a space portion 23 thereabove. A heat exchanger 27 having a baffle plate is disposed on the inner side of the partition 22 and an in-bed heat exchanger 33 is disposed on the outer side of same. A desulfurizing product-containing fine powder 204 and coarse powder 205 and a mixture gas 206 of nitrogen, oxygen and steam are supplied into the second fluidized bed 21. Also, coal 200 and coal char 201 are supplied into the first fluidized bed 20 from below.

Abstract: A method of combustion and a combustion plant in which absorbent is regenerated is described herein. During the combustion of a fuel in a combustion chamber enclosing a fluidized bed, a fuel and an absorbent are supplied to the fluidized bed. The combustion gases generated during the combustion are collected and purified in a separating member by separation of solid material from the combustion gases. The separated solid material is recirculated to the fluidized bed through a channel, and a gaseous medium is supplied in a controlled manner to the separated solid material present in the channel in order to displace the combustion gases and provide a chemical reaction.

Abstract: The invention comprises an OCR catalyst reactor which includes passive spheres and catalyst particles having substantially the same size and separated on opposite sides of a distributor cone by a screen. The use of passive spheres of substantially the same size to the catalyst particles provides for a more uniform distribution of the gas liquid reactants charged into the reactor vessel. The screen is configured such that it provides a separation of the catalyst and the passive spheres while being sized to prevent plugging.

Abstract: A falling film of water is applied around the periphery of a fluid bed olefin polymerization reactor to cool the wall and reduce the temperature in the fluid bed near the inside surface of the wall. Cooling has the effect of reducing static in the reactor, which in turn ameliorates a sheeting problem and can enhance production by facilitating control of the relation of the reactor temperature and the dew point of recycled gas. The process may be used concurrently with a gas cooling and condensing recycle system wherein at least some of the condensed recycle gas is injected in the vicinity of the internal wall surface.

Abstract: The present invention relates to a partitioned jetting fluidized bed with double nozzles, especially to a jetting fluidized-bed reactor with gas distributor, where a inclined nozzle is fixed at the side wall of the jetting fluidized bed above the gas distributor, and the gas pre-distribution chamber with gas distributor consists of a gas pre-distribution chamber with combined gas distributor and a gas pre-distribution chamber with perforated distributor. The two gas pre-distribution chambers are separated by a partition plate. The present invention can not only avoid the local agglomeration of the particles and the operation termination accident, but also broaden the adjustable range of the jet gas velocity and the distributor fluidization velocity. The excellent particle circulation can be reached in this jetting fluidized bed.

Abstract: A process and apparatus for contacting (a) at least one gaseous reactant and (b) at least one liquid selected from the group consisting of reactants, coolants and mixtures thereof in the presence of a fluidized bed of catalyst, in which the liquid is introduced into the reactor through at least one inlet located within the fluidization zone and the gaseous reactant is introduced into the reactor through at least one inlet located within the fluidization zone adjacent the support means.

Abstract: A quench zone mixing apparatus is supported within a vessel of a reactor by a support structure that includes a concentric hub, which may be formed to act as a torsion tube, and at least a first set of radial beams extending radially outward from the hub and terminating at a support ring that is attached to the reactor vessel wall. In particular, the radial beams comprise a flange that supports the redistribution tray and a web of the beams preferably includes a plurality of openings to allow the passage of fluids across the vessel. In addition, the webs also carry the channels. The radial beams also support the mixing chamber and, in the area between the wall of the mixing chamber and the vessel wall, the radial beams may have a vertical height that slopes downward from the vessel wall to the mixing chamber wall.

Abstract: A device for distributing a poly-phase mixture comprises:

Abstract: A fluid bed processing system with a spraying apparatus in accordance with one embodiment of the present invention includes an expansion chamber and at least one spraying apparatus which extends into the expansion chamber. The spraying apparatus has a plurality of single nozzles which are spaced along the spraying apparatus and has at least one fluid passage connected to each of the single nozzles.

Abstract: In order to prevent material from passing into a plenum chamber, an assembly for fluidizing the material includes a deck supported above the plenum chamber. The plenum chamber has an intake in communication with a source of pressurized air, and the deck includes an inverted channel for distributing the pressurized air to the material in a preselected air distribution pattern and an inverted channel for supporting the material in a position generally above and in spaced relation to the air distributing channel. With this arrangement, the material supporting channel is disposed in spaced relation to the air distributing channel to permit the pressurized air from the plenum chamber to fluidize the material.

Abstract: A pressurized vertically-oriented catalytic reactor vessel has a fluid flow distribution grid plate fixedly mounted transversely in the reactor lower portion for supporting a bed of particulate catalyst above the grid plate, and has at least one elongated conduit for catalyst addition/withdrawal extending upwardly through the reactor lower head and the grid plate. The catalyst addition/withdrawal conduit has a concentric bellows type expansion unit sealably attached at its lower end to the upper side of the grid plate, the bellows unit being sealably attached at its upper end to the catalyst conduit, so that the conduit can thermally expand vertically, and gas leakage cannot occur around the conduit and the grid plate into the catalyst bed.

Abstract: A gas-solid fluidized bed is formed within a contacting element having pairs of planar portions arranged in intersecting planes, each planar portion being formed by one or more webs and one or more open slots adjacent each web, the webs and slots being arranged such that a web in one of the planar portions intersects a slot in the paired planar portion. The fluidized bed can be catalyst particles fluidized by a gas stream, such as in a catalyst stripper and/or regenerator in an FCC system.