Abstract: In a porous composite, a base material has a honeycomb structure whose inside is partitioned into a plurality of cells. In the plurality of cells, a plurality of first cells whose one ends in the longitudinal direction are sealed, and a plurality of second cells whose other ends in the longitudinal direction are sealed are arranged alternately. A collection layer covers inner surfaces of the plurality of first cells. An overall Sa that is an arithmetical mean height Sa indicating a surface roughness of a surface of the collection layer in the plurality of first cells is greater than or equal to 0.1 ?m and less than or equal to 12 ?m. An overall mean thickness that is a mean thickness of the collection layer in the plurality of first cells is greater than or equal to 10 ?m and less than or equal to 40 ?m.

Abstract: A system for mobile carbon capture, preferably including a capture module, a regeneration module, and a storage module 130. The system can optionally include a thermal control module and/or a dehumidifier. A method for mobile carbon capture, preferably including adsorbing a target species, desorbing the target species, and storing the target species. The method can optionally include pre-treating input gas, offloading stored species, and/or regenerating desiccators.

Abstract: An exhaust tract for an internal combustion engine. The exhaust tract has a pipe which is connected for through flow to an exhaust manifold of the internal combustion engine. The exhaust line includes, downstream of the exhaust manifold, a purification unit for reducing pollutant emissions of the internal combustion engine. The purification unit includes at least one catalytic converter, an electrically heatable heating catalytic converter and a supporting catalytic converter supporting the heating catalytic converter. The heating catalytic converter and the supporting catalytic converter are of annular design. The heating catalytic converter is designed for a 48 volt power supply in order to reduce single-cylinder lambda effects.

Abstract: A detoxifying device 100 having an inner wall 104 that forms a flow passage 103 through which treatment gas flows includes a first piping 130 that forms a part of the flow passage 103, a replaceable piping section 170 that forms a part of the flow passage 103 at the position downstream of the first piping 130, and is connected thereto for sprinkling the cleaning water to remove the solid product adhering to the inner wall 104, and a second piping 150 that forms a part of the flow passage 103 at the position downstream of the piping section 170, and is connected thereto.

Abstract: A method for regenerating an NOx removal catalyst, which includes connecting an upstream fixing member (10) to one end of a member to be ground, and connecting a downstream fixing member (20) to the other end; connecting a mixing part (40) for mixing an abrasive with a gas to an upstream portion of the upstream fixing member, and disposing a screen member in the expanded part, and connecting a classification part (70) and a dust-collecting part (80) to the downstream fixing member; and transferring the abrasive which has been mixed with the gas from the mixing part to the upstream fixing member, reducing the flow rate of the mixture in the expanded part, subsequently, causing the mixture to pass through the through-hole of the NOx removal catalyst and the downstream fixing member, and then collecting dust by means of the dust-collecting part via the classification part.

Abstract: An exhaust aftertreatment system for treating exhaust flow from an internal combustion engine, and associated method, allows for independent control of exhaust flow through plural exhaust legs of the exhaust aftertreatment system. The independent control of exhaust flow is carried out by adjusting a valve positioned in each the exhaust legs based on a value of a signal generated by a flow measurement device positioned along at least one of the exhaust legs. The valves can be adjusted to force a target flow in a exhaust leg, relative flow among exhaust legs, exhaust temperature in an exhaust leg, exhaust backpressure and/or imbalance within the exhaust legs.

Abstract: The present invention is based on the application of heating resistors by a temperature regulation circuit in certain points of the catalyzer so that this comes into operation in the least time possible, reducing most of the amount of low molecular stability or environmentally harmful substances. Likewise, little tumult are added to each monolith duct to raise exhaust gas turbulence and increase the contact between the reduction and oxidation agent, whether it be platinum, palladium and rhodium.

Abstract: An object of the invention is to suppress deposition of ash in a wall-flow particulate filter while curtailing drops in a trapping rate of PM. To attain the above object, the invention provides a wall-flow particulate filter delimited by porous partition walls having pores of a size that allows ash and ash aggregates to pass therethrough. In the filter, a coat layer having pores smaller than the pores of the partition walls is provided, at a region of the partition walls, from an upstream end thereof up to a position before a downstream end thereof.

Abstract: The present invention provides (i) a method and system for stabilizing the performance of amine-containing CO2 adsorbents using wet feed gas and/or wet purge gas and (ii) a method for regeneration of deactivated amine-containing CO2 adsorbents via hydrolysis of the urea groups formed during deactivation.

Abstract: The present invention relates to a method for treating flue gas and/or condensates thereof suitable for removal of sulphur-containing compounds by contacting the flue gas condensate with a calcium-containing material to produce a liquid; cooling the liquid to a temperature below 60° C. or less, and adding a second material (such as carbon dioxide) to the cooled liquid to maintain the pH in range of 6 to 9 and separating off the resulting precipitate. The invention also relates to the purified flue gas and to a system for conducting the method according to the invention.

Abstract: In an engine, an exhaust purification catalyst (13) and a hydrocarbon feed valve (15) are arranged in an engine exhaust passage, and, a low pressure exhaust gas recirculation system (LPL) which makes exhaust gas downstream of the exhaust purification catalyst (13) recirculate is provided. If hydrocarbons are injected from the hydrocarbon feed valve (15), a carbon dioxide which is generated at the exhaust purification catalyst (13) is recirculated, and the air-fuel ratio of the exhaust gas which flows into the exhaust purification catalyst (13) temporarily drops. Hydrocarbons are injected from the hydrocarbon feed valve (15) in synchronization with this temporary drop in the air-fuel ratio.

Abstract: A filter for internal combustion engines, includes a rigid external casing provided with at least an inlet for a fluid to be filtered and an outlet for the fluid when filtered, and a filter cartridge located internally of the external casing, which includes a plurality of tubular filter walls arranged parallel to one another which are destined to be crossed by the fluid flowing from the inlet towards the outlet of the external casing; the external casing being conformed such as to delimit a pouch a transversal section of which, performed along a perpendicular plane to axes of the tubular filter walls, exhibits a prevalent line of development and a small width with respect to the prevalent line of development; the tubular filter walls being arranged internally of the pouch, side by side with one another, forming a single row which follows the prevalent line of development of the pouch.

Abstract: A wall flow type particulate filter (24) adapted to be arranged in an exhaust passage of an internal combustion engine in which combustion is performed in an excess of oxygen carries a solid acid. The solid acid has an acid strength which is higher than the acid strength of sulfurous acid and lower than the acid strength of sulfuric acid.

Abstract: An exhaust gas purifying apparatus for a diesel engine includes a diesel particulate filter (DPF) in an exhaust system in the diesel engine. The exhaust gas purifying apparatus is constructed to execute regeneration of the DPF by raising a temperature of the DPF in a case where a predetermined DPF regeneration condition is fulfilled, interrupt the regeneration of the DPF, execute idling stop, automatically restart the diesel engine and then restart the regeneration of the DPF, and when shifting to the idling operation is carried out during regeneration of the DPF, delay execution of the idling stop until a temperature of the DPF at a time at which the idling stop is started becomes not less than a temperature of the DPF at a time at which shifting to an idling operation is carried out even in a case where the predetermined idling stop condition is fulfilled.

Abstract: One exemplary embodiment can be a process for mixing catalyst in a regenerator. The process can include providing a first stream of catalyst, a second stream of catalyst mixed with the first stream of catalyst, and an oxygen-containing gas to a chamber via a distributor of the regenerator. Generally, the chamber imparts a swirl to at least one of the oxygen-containing gas, the first catalyst, and the second catalyst for regenerating the catalyst.

Abstract: [Problem] To provide a filter whose initial collection efficiency can be increased and whose pressure loss increase can be suppressed. [Means to solve the problem] A ceramic filter includes: numerous crystalline masses bound to one another each formed of aggregation of columnar crystals, wherein a number of large diameter pores are present between the numerous crystalline masses, and small diameter pores are present between the numerous columnar crystals forming the crystalline mass.

Abstract: A filtering device features a ceramic filter body for filtering a fluid flow, the filter body consisting of a wavy layer and a flat layer and the wavy and flat layer being wound in a spiral-shaped manner. The wave length of the waves increases from the inside to the outside with increasing distance to the longitudinal axis of the filter body such that the wave troughs and the wave peaks of at least two radially adjacent windings each lie on a common radial plane.

Abstract: A method for separating CO2 from gas mixtures uses a slurried media impregnated with buffer compounds and coating the solid media with a catalyst or enzyme that promotes the transformation of CO2 to carbonic acid. Buffer sorbent pebbles with a catalyst or enzyme coating are provided for rapid separation of CO2 from gas mixtures.

Abstract: An example method includes determining that a selective catalytic reduction (SCR) component having a zeolite-based catalyst is contaminated with platinum (Pt). The method further includes elevating the temperature of the SCR component to at least 600° C. in response to the determining the catalytic component is contaminated with Pt, and maintaining the elevated temperature of the catalytic component for a predetermined time period thereby restoring reduction activity of the catalyst.

Abstract: Described herein is a selective catalytic reduction (SCR) catalyst treatment system that includes a vanadium-based SCR catalyst contaminated with a water-soluble contaminant. The SCR catalyst treatment system also includes a water delivery system that is configured to apply water to the vanadium-based SCR catalyst to remove the water-soluble contaminant from the vanadium-based SCR catalyst.

Abstract: A retaining seal material includes inorganic fibers, inorganic particles adhering to surfaces of the inorganic fibers, a first principal surface, and a second principal surface. A mean particle diameter of the inorganic particles in a vicinity of a center in a thickness direction of the retaining seal material is smaller than at least one of a mean particle diameter of the inorganic particles in a vicinity of the first principal surface and a mean particle diameter of the inorganic particles in a vicinity of the second principal surface.

Abstract: An exhaust gas purification system includes a diesel particulate filter (“DPF”) which collects particulate matter (“PM”) in exhaust gas, an exhaust pipe injector which performs exhaust pipe injection, and a DPF regeneration control unit which performs temperature rise control of an exhaust gas temperature by the exhaust pipe injection to regenerate the DPF when the PM collected by the DPF exceeds a fixed amount and which, during the regeneration, integrates an amount of time during which the exhaust gas temperature exceeds a PM combustion temperature and completes the regeneration when an integrated value thereof reaches a set regeneration completion value. The DPF regeneration control unit aborts the regeneration when, during regeneration, a total amount of the exhaust pipe injection exceeds an upper limit before the integrated value.

Abstract: An exhaust gas purification system with which a frequency of diesel particulate filter (“DPF”) regeneration requests can be reduced during long low idle regeneration, thereby improving convenience, including a control unit that performs regeneration control on a DPF provided at an exhaust pipe of an engine. The control unit includes a particulate matter (“PM”) accumulation amount predictor for predicting the amount of PM accumulated by calculating a cumulated value of the PM in an idling state. The control unit starts calculating the cumulated value of the PM by the PM accumulation amount predictor after a first predetermined time has elapsed since a detection of the idling state.

Abstract: Disclosed are ceramic bodies comprised of composite cordierite aluminum magnesium titanate ceramic compositions and methods for the manufacture of same.

Abstract: A hybrid mounting mat for mounting a catalyst support structure within a housing in an exhaust gas treatment device. The exhaust gas treatment device includes an outer housing, a fragile catalyst support structure, and a mounting mat disposed in the gap between the housing and the fragile catalyst support structure. Additionally disclosed are methods of making the hybrid mounting mat and for making an exhaust gas treatment device incorporating the mounting mat.

Abstract: A holding sealing material includes a mat, an inorganic binder and an organic binder. The mat includes inorganic fibers and has an upper part, a center part, and a lower part in a thickness direction. The inorganic binder is loaded on the mat. The organic binder is loaded mainly on the upper part and the lower part of the mat. The holding sealing material is disposed between an exhaust gas-treating body and a casing for housing the exhaust gas-treating body to form an exhaust gas purifying apparatus.

Abstract: A parallel passage fluid contactor structure for chemical reaction processes has one or more segments, where each segment has a plurality of substantially parallel fluid flow passages oriented in an axial direction; cell walls between each adjacent fluid flow passages and each cell wall has at least two opposite cell wall surfaces. The structure also includes at least one active compound in the cell walls and multiple axially continuous conductive filaments either embedded within the cell walls or situated between the cell wall surfaces. The conductive filaments are at least one of thermally and electrically conductive, are oriented in axially, and are in direct contact with the active compound, and are operable to transfer thermal energy between the active material and the conductive filaments. Heating of the conductive filaments may be used to transfer heat to the active material in the cell walls. Methods of manufacturing the structure are discussed.

Abstract: An exhaust gas purification system with which diesel particulate filter (“DPF”) regeneration can be continued even when deceleration occurs during the DPF regeneration. The system includes a regeneration deceleration period intake/exhaust control unit that, when a vehicle decelerates during the DPF regeneration, increases an exhaust gas flow rate through an exhaust pipe by controlling respective openings of an exhaust gas recirculation (“EGR”) device and an intake throttle and adjusting a turbocharging amount of a high pressure stage turbocharger.

Abstract: A circulating moving bed and process for separating a carbon dioxide from a gas stream is disclosed. The circulating moving bed can include an adsorption reactor and a desorption reactor, and a sorbent that moves through the two reactors. The sorbent can enter the adsorptive reactor and one end and move to an exit point distal to its entry point, while a CO2 feed stream can enter near the distal point and move countercurrently through the sorbent to exit at a position near the entry point of the sorbent. The sorbent can adsorb the CO2 by concentration swing adsorption and adsorptive displacement. The sorbent can then transfer to a regeneration reactor and can move countercurrently against a flow of steam through the regeneration reactor. The sorbent can be regenerated and the carbon dioxide recaptured by desorbing the carbon dioxide from the sorbent using concentration swing desorption and desorptive displacement with steam.

Abstract: A exhaust gas purification device is structured such that it is possible to improve an assembling work ability or a maintenance work ability of gas purifying bodies or exhaust gas purifying cases. In an exhaust gas purification device provided with gas purifying bodies which purify an exhaust gas discharged by an engine, and a gas purifying housing which is provided with the gas purifying bodies therein, the exhaust gas purification device is structured such that a support bracket which supports the gas purifying housing is provided, a bolt hole is formed in the support bracket, an insertion guide is formed in the support bracket, and an attaching bolt is engaged with and disengaged from the bolt hole via the insertion guide.

Abstract: The present invention relates to device and method for reducing soot particles. The device for reducing soot particles includes a first filter provided to an exhaust gas flow passage through which exhaust gas from a diesel engine flows to have a predetermined volume of a plurality of grains to be operated as a volumetric filtration system, and a second filter provided to a predetermined position of the second filter to be operated as a surface filtration system.

Abstract: A method for engine-out soot flow rate prediction of an exhaust gas treatment system is provided. A measured level of oxides of nitrogen in the exhaust gas treatment system is received. An engine fuel injection timing and air-fuel ratio of an engine producing the oxides of nitrogen are also received. An engine timing factor is determined based on the engine fuel injection timing. An engine air-fuel ratio factor is determined based on the engine air-fuel ratio. An engine-out soot flow rate prediction is generated based on the measured level of oxides of nitrogen, the engine timing factor, and the engine air-fuel ratio factor.

Abstract: A ceramic honeycomb structure suitable for particulate filters, having an inlet face and an outlet face, comprising a plurality of inlet cells and a plurality of outlet cells extending through the structure from the inlet face to the outlet face, the inlet cells being open at the inlet face and closed where adjoining the outlet face, and the outlet cells being open at the outlet face and closed where adjoining the inlet face. The inlet and/or outlet cells are quadrangular in cross-section and are arranged in an alternating pattern; the outlet cells may have a cross-sectional area generally smaller than that of inlet cells and no point of a given inlet cell is closer to an adjacent inlet cell than to an adjacent outlet cell. A process for preparing the ceramic honeycomb structure is also disclosed.

Abstract: A device for at least one self-heated and dense ceramic tube for gas separation. The device includes at least one dense ceramic tube in an environment accessible to a mixture of gases, the at least one tube acting as a diffusion membrane for separating at least one gas from the mixture of gases. Two electrical contacts are provided which allow connecting a power supply to the ceramic tube and driving an electric current through the ceramic tube. The contacts can be in the farm of short coils wrapped around the ceramic tube at difference places. When a voltage is applied to the contacts, an electrical current flows from one contact to the other through the ceramic tube. The current in the ceramic tube heats the tube. Thus, the tubes heat themselves. The hot tube allows separating a gas from the mixture of gases. The driving force for the diffusion is achieved by a pressure difference generated by pumping at the side of the separated gas and pressing at the side of the mixture of gases.

Abstract: A method for combustion of a fuel and treatment of the resulting flue gas includes: combusting a fuel to produce a hot flue gas stream containing at least carbon dioxide (CO2) and sulfur dioxide (SO2), bringing the flue gas stream into contact with solid calcium oxide (CaO) in a carbonation reactor operating at a temperature at which CO2 in the flue gas reacts with CaO to form solid calcium carbonate (CaCO3), heating CaCO3 in a calcination reactor operating at a temperature at which CaCO3 is converted to CaO and CO2, and recirculating CaO formed in the calcination reactor back to the carbonation reactor. Heating can be at least partially effected by indirect heat exchange with hot flue gas from the combustion. Flue gas used for the indirect heat exchange can be subsequently subjected to dry desulfurization before it is brought into contact with CaO in the carbonation reactor.

Abstract: An object of the present invention is to detect any breakdown or failure of a particulate filter more appropriately. A failure detecting apparatus for detecting failure of a particulate filter according to the present invention comprises an acquiring section which acquires an amount of PM contained in an exhaust gas allowed to outflow from the particulate filter; a regeneration process executing section which executes a filter regeneration process for oxidizing and removing PM deposited in the particulate filter; and a failure judging section which judges that the particulate filter is in the failure state if a decreased amount of the amount of PM contained in the exhaust gas acquired by the acquiring section, during a predetermined period of time as started from a point in time at which the execution of the filter regeneration process performed by the regeneration process executing section is completed, is not equal to or larger than a predetermined reference amount.

Abstract: An exhaust gas treatment system for an internal combustion engine is provided comprising an exhaust gas conduit, a particulate filter (“PF”) device, a hydrocarbon source and an electronic control module including operative logic which when implemented. The PF has a filter structure for removal of particulates in the exhaust gas and is selectively regenerated based on an amount of particulates trapped within the filter structure of the PF device. The control module is in communication with the internal combustion engine and the hydrocarbon source, and receives a regeneration signal indicating the amount of particulates trapped within the filter structure of the PF device. The electronic control module includes control logic for monitoring the internal combustion engine prior to a regeneration event. The electronic control module includes control logic for determining a plurality operating parameters of the internal combustion engine based on the monitoring.

Abstract: The present invention aims to provide a honeycomb structure capable of preventing a plugging failure and forming cracks by heat shock which are caused by a cell having a small cross-section.

Abstract: The present invention is intended to detect a failure of a PM filter with a higher degree of accuracy. The present invention is provided with: a PM trapping efficiency calculation part to calculate a PM trapping efficiency (which is a proportion of an amount of particulate matter trapped with respect to an amount of inflow particulate matter) based on an amount of inflow particulate matter obtained by an inflow particulate matter obtaining part, and an amount of outflow particulate matter detected by a PM sensor; and a failure detection part to make a determination that a failure has occurred in the PM filter, in cases where there has appeared a tendency for the PM trapping efficiency to decrease during a period of time until the execution of the following filter regeneration processing is started after the completion of execution of the filter regeneration processing.

Abstract: A particulate matter detecting apparatus for an internal combustion engine that can estimate a discharge amount of the particulate matter accurately. The particulate matter detecting apparatus for an internal combustion engine, comprises: a sensor disposed at an exhaust passage of the internal combustion engine, the sensor including a pair of electrodes for detecting particulate matter in an exhaust gas; means for estimating a discharge amount of the particulate matter based on an output of the sensor, and means for acquiring a predetermined parameter that serves as an index for a rate with which the particulate matter in the exhaust gas is deposited on the sensor. The discharge amount estimating means corrects an estimated value of the discharge amount of the particulate matter based on the parameter acquired by the parameter acquiring means.

Abstract: Inner cases are connected to outer cases through joining flanges which protrude toward outer peripheries of the outer cases. A plurality of combinations each including filters, the inner cases, and the outer cases are provided. Both the joining flanges are sandwiched and fixed between a pair of sandwiching flanges, thereby connecting the plurality of outer cases to each other.

Abstract: A thin-walled porous ceramic wall-flow filter is disclosed. The filter produces a relatively lower pressure drop coupled with relatively high initial filtration efficiency (FE0), and may enable packaging the filter in a smaller volume. The filter includes a plurality of porous ceramic walls forming cell channels. At least some of the cells are plugged forcing some exhaust gases through the walls, thereby filtering out entrained particulates. The walls have a wall thickness (Twall) wherein 102 ?m?Twall<279 ?m, and a median pore diameter (MPD), and wherein 10<Twall/MPD, and may also be <40. The relatively small median pore diameter (MPD) in comparison to the wall thickness (Twall) allows the use of thinner ceramic walls that provide less flow resistance than thicker walls while maintaining sufficient initial filtration efficiency (FE0). Furthermore, such thin-walled filter structure coupled with unequal inlet/outlet area ratio (Ai/Ao) may allow filter lengths to be additionally shortened.

Abstract: An exhaust gas emission control system includes a cylindrical inflow body and an inflow pipe into which exhaust gas flows. The exhaust gas emission control system also includes a cylindrical outflow body and an outflow pipe from which the exhaust gas flows. The inflow pipe is provided with a louver member that covers an opening of the inflow body near an upstream side of an exhaust gas flow direction. The louver member is provided with slits and inclined plates capable of changing a flow direction of the exhaust gas passing through the slits into a desired direction.

Abstract: There is provided a honeycomb structure including a honeycomb base material including a porous partition wall parent material; plugged portions; and a porous collecting layer disposed on the surface of the partition wall parent material in the remaining cells. A melting point of a material constituting the collecting layer is higher than that of a material constituting the partition wall parent material, a pore surface area per unit volume of the collecting layer is 2.0 times or more a pore surface area per unit volume of the partition wall parent material, and a thickness of a portion of the collecting layer which penetrates into pores of the partition wall parent material is 6% or smaller of that of each of partition walls including the partition wall parent material and the collecting layer.

Abstract: 1) A first amine, which is a straight chain secondary monoamine, 2) a second amine, which is a cyclic secondary polyamine as a reaction accelerator, and 3) a third amine, which is an amine consisting of one selected from a cyclic amine group constituted from a secondary or tertiary amino group or a straight chain amine group with high steric hindrance are mixed to obtain an absorbent. By the synergistic effect thereof, absorption properties to CO2 and/or H2S are excellent and the absorbed CO2 or H2S emission properties during the regeneration of the absorbent become excellent. Therefore, the water vapor amount used during the regeneration of the absorbent in CO2 recovery equipment can be reduced.

Abstract: A system for treating diesel exhaust is disclosed. The system includes a first filter including layers of filtration material positioned between layers of corrugated metallic foil. The metallic foil defines a honeycomb arrangement of longitudinal passageways from an upstream end to a downstream end and also openings for allowing exhaust to pass between adjacent longitudinal passageways of the metallic foil. The filtration material is positioned such that exhaust between the adjacent longitudinal passageways passes through the filtration material. The metallic foil also includes flow diverting structures to divert flow within the longitudinal passageways through the openings. A second filter is positioned downstream from the first filter. The second filter defines a honeycomb arrangement of longitudinal passageways. The longitudinal passages are selectively plugged adjacent upstream and downstream ends to force flow radially through walls between the longitudinal passages of the second filter.

Abstract: An exhaust gas aftertreatment system for an engine can perform manual regeneration control for regenerating a particulate removal filter by increasing the engine rotation speed. The system can suppress the engine rotation speed increase while maintaining the exhaust gas temperature required to regenerate the particulate removal filter. The system can set the target engine rotation speed to a first set value when a regeneration instruction signal from a manual regeneration switch is received. When, although the engine rotation speed falls within a predetermined engine rotation speed range including the first set value that is the target engine rotation speed for a predetermined time period, the exhaust gas temperature does not reach the filter's regeneration temperature within the predetermined time period, the target engine rotation speed is repeatedly reset by being increased from the first set value by a predetermined rotation speed.

Abstract: A method for cleaning and checking a particle filter of a motor vehicle is provided. In a first step soot particles which have collected in the particle filter are burnt off. In a second step ash located in the particle filter is blown out using compressed air. A cleaning device for a particle filter of a motor vehicle is also provided.

Abstract: Cellular ceramic articles are manufactured from a green cellular ceramic body that includes a binder material and a plurality of channels. At least one of the channels is coated with a slurry that includes a green coating composition and a solvent to form a coating layer. The binder material is insoluble in the solvent.

Abstract: A method of removing ash from a wall flow type particulate filter which is arranged in an exhaust passage of an internal combustion engine in which combustion is performed in an excess of oxygen for trapping particulate matter in exhaust gas, using a solid acid which is carried on the particulate filter, renders the state of the particulate filter a state where the exhaust gas which flows into the particulate filter is lowered in concentration of oxygen and the particulate filter is raised in temperature, and then renders the state of the particulate filter a state where the exhaust gas which flows into the particulate filter in an oxidizing atmosphere contains SOx.