Using Heavy Metal Or Compound Thereof Patents (Class 422/19)
  • Patent number: 4499003
    Abstract: An aqueous corrosion inhibitor composition of soluble antimony and molybdenum salts in which the weight ratio of soluble antimony salt to molybdenum salt ranges between about 0.01 to 1 and about 5 to 1. This corrosion inhibitor is particularly useful in acid gas scrubbing processes, under alkaline conditions, where alkali metal salts and amine compound promoters are used.
    Type: Grant
    Filed: February 2, 1982
    Date of Patent: February 12, 1985
    Assignee: Exxon Research & Engineering Co.
    Inventor: Z. Andrew Foroulis
  • Patent number: 4497713
    Abstract: A corrosion inhibition and scale control method and composition are disclosed. The method comprises, adding to a cooling water system, for which protection is desired, a water soluble zinc salt, a cellulose gum material and an organo-phosphorus acid compound. Optionally, a corrosion inhibitor compound such as a 1,2,3-triazole or thiazole compound may be added to afford additional protection. Molybdate salts may also be included as optional corrosion inhibitors.
    Type: Grant
    Filed: April 1, 1982
    Date of Patent: February 5, 1985
    Inventor: Gary E. Geiger
  • Patent number: 4487712
    Abstract: Gelation resistant alcohol compositions containing water-soluble silicates are obtained by the use of effective silicate gelation stabilizing amounts of at least one of a polymer of acrylic acid, alkaline earth metal and alkaline earth metal salts thereof; a sugar alcohol; and a water-soluble salt of molybdic, tungstic, or selenic acids.
    Type: Grant
    Filed: May 25, 1983
    Date of Patent: December 11, 1984
    Assignee: BASF Wyandotte Corporation
    Inventors: Joe C. Wilson, Pauls Davis
  • Patent number: 4452758
    Abstract: Antifreeze compositions and a process for inhibiting the corrosion of aluminum in contact with aqueous liquids are disclosed. The antifreeze compositions comprise a combination of an alkanolamine, an alkali metal phosphate, a heterocyclic nitrogen compound, as defined, and a conventional corrosion inhibitor in effective corrosion inhibiting amounts. The aqueous liquid can be an alcohol such as ethylene glycol.
    Type: Grant
    Filed: May 16, 1983
    Date of Patent: June 5, 1984
    Assignee: BASF Wyandotte Corporation
    Inventors: Joe C. Wilson, Stanley T. Hirozawa, Stephen E. Eisenstein, Jerrold F. Maxwell
  • Patent number: 4440721
    Abstract: Compositions for inhibiting mineral scale and the corrosion of metals particularly the cavitation corrosion of aluminum in the presence of aqueous liquids are disclosed. The combination of a water-soluble phosphate with at least one of a water-soluble molybdate, tungstate, or selenate is disclosed as providing a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids.
    Type: Grant
    Filed: February 11, 1983
    Date of Patent: April 3, 1984
    Assignee: BASF Wyandotte Corporation
    Inventors: Joe C. Wilson, Stanley T. Hirozawa, John J. Conville
  • Patent number: 4431563
    Abstract: The corrosion of ferrous metal surfaces in gas conditioning apparatus is inhibited by using a gas conditioning solution such as aqueous alkanolamines which contain thionitrogen compounds such as metal thiocyanates or thioamides. After recycling the gas conditioning solution for a few days, the solution dissolves sufficient amounts of nickel or cobalt or other metals in the equipment to act as a synergist with the thionitrogen compounds. In the event, the equipment does not contain any soluble synergistic metals, these metals may be added to the gas conditioning solution as soluble metal salts. Examples of useful additive metals are cobalt, nickel, calcium, copper, chromium, zinc, tin, aluminum, and magnesium.
    Type: Grant
    Filed: July 21, 1982
    Date of Patent: February 14, 1984
    Assignee: The Dow Chemical Company
    Inventors: Leroy S. Krawczyk, Charles W. Martin, Roscoe L. Pearce
  • Patent number: 4411865
    Abstract: A method for reducing corrosion of metal surfaces is disclosed according to which a specific corrosion inhibitor is utilized. The inhibitor comprises water-soluble zinc compound, water-soluble chromate compound and copolymer of acrylic acid and hydroxylated lower alkyl acrylate. Water-soluble orthophosphate can also be used.
    Type: Grant
    Filed: May 28, 1981
    Date of Patent: October 25, 1983
    Assignee: Betz Laboratories, Inc.
    Inventors: Gary E. Geiger, Roger C. May
  • Patent number: 4409121
    Abstract: Corrosion and scale-inhibiting compositions which are useful in recirculating aqueous systems comprise a mixture of a phosphate compound, a phosphonate compound comprising 1-hydroxyethylidene-1,1-diphosphonic acid or nitrilotris(methylene)triphosphonic acid, an aryl triazole, and a salt of a metal selected from the group consisting of molybdenum, tungsten and chromium. In the preferred embodiment of the invention, the phosphate compound is present in a weight percent ratio in the range of from about 2.5:1 to about 4:1 weight percent per weight percent of the metal salt. An example of an effective anti-corrosion composition comprises a mixture of sodium tripolyphosphate, 1-hydroxyethylidene-1,1-diphosphonic acid, benzotriazole and sodium molybdate, said composition being present in an amount of from about 5 to about 5,000 ppm.
    Type: Grant
    Filed: June 28, 1982
    Date of Patent: October 11, 1983
    Assignee: UOP Inc.
    Inventors: Edwin J. Latos, John C. Payne
  • Patent number: 4406813
    Abstract: A process for preparing a disoxidant, comprising: providing fine powder of a porous filler f-1, such as zeolite, having a particle size not greater than 100 mesh and coarse powder of a porous filler f-2, such as zeolite, having a particle size greater than 100 mesh; adding water to the coarse powder f-2 such that the total water content for the sum of the fine and coarse powder f-1 and f-2 is 20-90% of the amount of saturated water absorption thereof; mixing 20-60% by volume of the fine powder f-1 with 80-40% by volume of the coarse powder f-2; and admixing the resulting mixture F with fine metallic powder M, such as iron, having disoxidation activity and a particle size not greater than 100 mesh, with a volume ratio M/F of the component M to F being in the range of 1/2 to 1/10. Disclosed also is a disoxidant obtained by the above process.
    Type: Grant
    Filed: April 20, 1982
    Date of Patent: September 27, 1983
    Inventors: Daishiro Fujishima, Shinichiro Fujishima
  • Patent number: 4389371
    Abstract: Corrosion inhibited alcohol compositions can be prepared which are suitable for use as anti-freeze compositions in the cooling systems of internal combustion engines. The alcohol is selected from at least one of the group consisting of methanol, ethanol, propanol, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol and glycerol. The corrosion inhibitor comprises an effective amount of a conventional corrosion inhibitor selected from the group consisting of the alkali metal carbonates, borax, the alkali metal dichromates, the alkali metal silicates, phosphorous acid, phosphoric acid, an alkali metal tungstate, benzotriazole, tolyltriazole, an alkali metal salt of benzoic or toluic acid, an alkali metal salt of a phenol, an alkanolamine and an organo-silicone compound in addition to an alkanolamine phosphate and a heterocyclic nitrogen-containing compound. The phosphate is the reaction product of an alkanolamine and phosphoric acid.
    Type: Grant
    Filed: July 8, 1981
    Date of Patent: June 21, 1983
    Assignee: BASF Wyandotte Corporation
    Inventors: Joe C. Wilson, Stephen E. Eisenstein, Jerrold F. Maxwell, Stanley T. Hirozawa
  • Patent number: 4329250
    Abstract: A method and composition are disclosed for treating corroding aqueous mediums to reduce the corrosion of metal surfaces exposed thereto. The treatment comprises water-soluble chromate and a copolymer of acrylic acid and hydroxy alkyl acrylate.
    Type: Grant
    Filed: March 28, 1980
    Date of Patent: May 11, 1982
    Assignee: Laboratories, Inc. Betz
    Inventors: Frederick G. Vogt, deceased, Patricia T. Sparrell
  • Patent number: 4324684
    Abstract: A composition is disclosed comprising a stable aqueous solution of (i) water-soluble zinc compound, (ii) water-soluble chromate compound and (iii) a particular type of water-soluble polymer composed essentially of moieties derived from acrylic acid and hydroxylated lower alkyl acrylates. The composition could additionally comprise (iiii) orthophosphate.
    Type: Grant
    Filed: March 19, 1980
    Date of Patent: April 13, 1982
    Assignee: Betz Laboratories, Inc.
    Inventors: Gary E. Geiger, Roger C. May
  • Patent number: 4299725
    Abstract: Aqueous media having a dissolved content of a small amount, (less than 100 p.p.m.) of a mixture of aminoalkanols of the formula: ##STR1## wherein R.sub.1 and R.sub.2 each represent H and C.sub.1-18 unbranched alkyl substituents (the sum of the carbon atoms in R.sub.1 and R.sub.2 being 9 to 18), R.sub.3 and R.sub.4 each represent H,C.sub.1-4 alkyl and C.sub.2-4 hydroxyalkyl substituents, x represents 2 to 6, and y represents 0 to 1, the ##STR2## units in the aminoalkanols being of at least two different chain lengths in the range of 11 to 20 carbon atoms, possess decreased tendency to corrode iron-containing metals including steel. The mixtures are also useful in salt form. The efficiency of the mixture is improved by various additives which act synergistically therewith.
    Type: Grant
    Filed: March 10, 1978
    Date of Patent: November 10, 1981
    Assignees: Henkel Kommanditgesellschaft auf Aktien, Deutsche Gold- und Silber Scheideanstalt vormals Roessler
    Inventors: Volker Wehle, Wolfgang Rupilius, Jurgen Reiffert, Gabriele Rogall
  • Patent number: 4298568
    Abstract: A method for inhibiting corrosion of nonferrous metals in contact with circulating water comprising the steps of adding to circulating water in contact with non-ferrrous metals from 0.05 to 10 gm/m.sup.3 of at least one 3-amino-5-alkyl-1,2,4-triazole wherein said alkyl has from 2 to 8 carbon atoms and adjusting said water to a pH of from 6 to 10; as well as corrosion inhibiting compositions containing said 3-amino-5-alkyl-1,2,4-triazole.
    Type: Grant
    Filed: August 14, 1980
    Date of Patent: November 3, 1981
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Werner Gerhardt, Volker Wehle, Andreas Syldatk, Gabriele Rogall, Jurgen Reiffert, Jens Conrad
  • Patent number: 4297317
    Abstract: A method and composition are disclosed for treating corroding aqueous mediums to reduce the corrosion of metal surfaces exposed thereto. The treatment comprises water-soluble chromate and a copolymer of acrylic acid and hydroxy alkyl acrylate.
    Type: Grant
    Filed: March 28, 1980
    Date of Patent: October 27, 1981
    Assignee: Betz Laboratories, Inc.
    Inventors: Frederick G. Vogt, deceased, Patricia T. Sparrell
  • Patent number: 4207201
    Abstract: The application is concerned with a process for the manufacture of an aqueous iron (III)-chloride-sulfate solution by the oxidation of iron (II) sulfate with chlorine in aqueous solution.
    Type: Grant
    Filed: March 8, 1978
    Date of Patent: June 10, 1980
    Assignee: Kronos Titan GmbH
    Inventors: Achim Hartmann, Achim Kulling, Dieter Schinkitz, Edgar Klein
  • Patent number: 4176059
    Abstract: A low toxicity, corrosion and scale inhibiting composition for use in recirculating aqueous systems, e.g. in heat exchangers, comprises from about 3-1,000 parts by weight of molybdate, from about 0.5-1,000 parts by weight of an organic cationic or non-ionic surfactant, from about 0.3-1,000 parts by weight of a water soluble polyphosphate and from about 0.05-500 parts by weight of an azole, for example tolyltriazole. The composition is water soluble or water dispersible, and is effective in very small amounts (3-3,500 ppm) for corrosion control of metals such as carbon steel, copper and aluminum exposed to circulating water.
    Type: Grant
    Filed: June 8, 1978
    Date of Patent: November 27, 1979
    Assignee: Quatic Chemicals Limited
    Inventor: Fumiko Suzuki
  • Patent number: 4111830
    Abstract: A method of retarding corrosion of metal parts in an aqueous-containing fluid system which comprises, adding to the aqueous-containing fluid system a mixture of a water-soluble cation of mercury and a water-soluble cation of a Group IB or Group IIB metal.
    Type: Grant
    Filed: September 29, 1976
    Date of Patent: September 5, 1978
    Inventor: Ramon A. Bannister