Using Heavy Metal Or Compound Thereof Patents (Class 422/19)
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Patent number: 4499003Abstract: An aqueous corrosion inhibitor composition of soluble antimony and molybdenum salts in which the weight ratio of soluble antimony salt to molybdenum salt ranges between about 0.01 to 1 and about 5 to 1. This corrosion inhibitor is particularly useful in acid gas scrubbing processes, under alkaline conditions, where alkali metal salts and amine compound promoters are used.Type: GrantFiled: February 2, 1982Date of Patent: February 12, 1985Assignee: Exxon Research & Engineering Co.Inventor: Z. Andrew Foroulis
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Patent number: 4497713Abstract: A corrosion inhibition and scale control method and composition are disclosed. The method comprises, adding to a cooling water system, for which protection is desired, a water soluble zinc salt, a cellulose gum material and an organo-phosphorus acid compound. Optionally, a corrosion inhibitor compound such as a 1,2,3-triazole or thiazole compound may be added to afford additional protection. Molybdate salts may also be included as optional corrosion inhibitors.Type: GrantFiled: April 1, 1982Date of Patent: February 5, 1985Inventor: Gary E. Geiger
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Patent number: 4487712Abstract: Gelation resistant alcohol compositions containing water-soluble silicates are obtained by the use of effective silicate gelation stabilizing amounts of at least one of a polymer of acrylic acid, alkaline earth metal and alkaline earth metal salts thereof; a sugar alcohol; and a water-soluble salt of molybdic, tungstic, or selenic acids.Type: GrantFiled: May 25, 1983Date of Patent: December 11, 1984Assignee: BASF Wyandotte CorporationInventors: Joe C. Wilson, Pauls Davis
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Patent number: 4452758Abstract: Antifreeze compositions and a process for inhibiting the corrosion of aluminum in contact with aqueous liquids are disclosed. The antifreeze compositions comprise a combination of an alkanolamine, an alkali metal phosphate, a heterocyclic nitrogen compound, as defined, and a conventional corrosion inhibitor in effective corrosion inhibiting amounts. The aqueous liquid can be an alcohol such as ethylene glycol.Type: GrantFiled: May 16, 1983Date of Patent: June 5, 1984Assignee: BASF Wyandotte CorporationInventors: Joe C. Wilson, Stanley T. Hirozawa, Stephen E. Eisenstein, Jerrold F. Maxwell
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Patent number: 4440721Abstract: Compositions for inhibiting mineral scale and the corrosion of metals particularly the cavitation corrosion of aluminum in the presence of aqueous liquids are disclosed. The combination of a water-soluble phosphate with at least one of a water-soluble molybdate, tungstate, or selenate is disclosed as providing a synergistic protective effect against the cavitation corrosion of aluminum in aqueous liquids.Type: GrantFiled: February 11, 1983Date of Patent: April 3, 1984Assignee: BASF Wyandotte CorporationInventors: Joe C. Wilson, Stanley T. Hirozawa, John J. Conville
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Patent number: 4431563Abstract: The corrosion of ferrous metal surfaces in gas conditioning apparatus is inhibited by using a gas conditioning solution such as aqueous alkanolamines which contain thionitrogen compounds such as metal thiocyanates or thioamides. After recycling the gas conditioning solution for a few days, the solution dissolves sufficient amounts of nickel or cobalt or other metals in the equipment to act as a synergist with the thionitrogen compounds. In the event, the equipment does not contain any soluble synergistic metals, these metals may be added to the gas conditioning solution as soluble metal salts. Examples of useful additive metals are cobalt, nickel, calcium, copper, chromium, zinc, tin, aluminum, and magnesium.Type: GrantFiled: July 21, 1982Date of Patent: February 14, 1984Assignee: The Dow Chemical CompanyInventors: Leroy S. Krawczyk, Charles W. Martin, Roscoe L. Pearce
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Patent number: 4411865Abstract: A method for reducing corrosion of metal surfaces is disclosed according to which a specific corrosion inhibitor is utilized. The inhibitor comprises water-soluble zinc compound, water-soluble chromate compound and copolymer of acrylic acid and hydroxylated lower alkyl acrylate. Water-soluble orthophosphate can also be used.Type: GrantFiled: May 28, 1981Date of Patent: October 25, 1983Assignee: Betz Laboratories, Inc.Inventors: Gary E. Geiger, Roger C. May
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Patent number: 4409121Abstract: Corrosion and scale-inhibiting compositions which are useful in recirculating aqueous systems comprise a mixture of a phosphate compound, a phosphonate compound comprising 1-hydroxyethylidene-1,1-diphosphonic acid or nitrilotris(methylene)triphosphonic acid, an aryl triazole, and a salt of a metal selected from the group consisting of molybdenum, tungsten and chromium. In the preferred embodiment of the invention, the phosphate compound is present in a weight percent ratio in the range of from about 2.5:1 to about 4:1 weight percent per weight percent of the metal salt. An example of an effective anti-corrosion composition comprises a mixture of sodium tripolyphosphate, 1-hydroxyethylidene-1,1-diphosphonic acid, benzotriazole and sodium molybdate, said composition being present in an amount of from about 5 to about 5,000 ppm.Type: GrantFiled: June 28, 1982Date of Patent: October 11, 1983Assignee: UOP Inc.Inventors: Edwin J. Latos, John C. Payne
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Patent number: 4406813Abstract: A process for preparing a disoxidant, comprising: providing fine powder of a porous filler f-1, such as zeolite, having a particle size not greater than 100 mesh and coarse powder of a porous filler f-2, such as zeolite, having a particle size greater than 100 mesh; adding water to the coarse powder f-2 such that the total water content for the sum of the fine and coarse powder f-1 and f-2 is 20-90% of the amount of saturated water absorption thereof; mixing 20-60% by volume of the fine powder f-1 with 80-40% by volume of the coarse powder f-2; and admixing the resulting mixture F with fine metallic powder M, such as iron, having disoxidation activity and a particle size not greater than 100 mesh, with a volume ratio M/F of the component M to F being in the range of 1/2 to 1/10. Disclosed also is a disoxidant obtained by the above process.Type: GrantFiled: April 20, 1982Date of Patent: September 27, 1983Inventors: Daishiro Fujishima, Shinichiro Fujishima
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Patent number: 4389371Abstract: Corrosion inhibited alcohol compositions can be prepared which are suitable for use as anti-freeze compositions in the cooling systems of internal combustion engines. The alcohol is selected from at least one of the group consisting of methanol, ethanol, propanol, ethylene glycol, diethylene glycol, triethylene glycol, propylene glycol and glycerol. The corrosion inhibitor comprises an effective amount of a conventional corrosion inhibitor selected from the group consisting of the alkali metal carbonates, borax, the alkali metal dichromates, the alkali metal silicates, phosphorous acid, phosphoric acid, an alkali metal tungstate, benzotriazole, tolyltriazole, an alkali metal salt of benzoic or toluic acid, an alkali metal salt of a phenol, an alkanolamine and an organo-silicone compound in addition to an alkanolamine phosphate and a heterocyclic nitrogen-containing compound. The phosphate is the reaction product of an alkanolamine and phosphoric acid.Type: GrantFiled: July 8, 1981Date of Patent: June 21, 1983Assignee: BASF Wyandotte CorporationInventors: Joe C. Wilson, Stephen E. Eisenstein, Jerrold F. Maxwell, Stanley T. Hirozawa
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Patent number: 4329250Abstract: A method and composition are disclosed for treating corroding aqueous mediums to reduce the corrosion of metal surfaces exposed thereto. The treatment comprises water-soluble chromate and a copolymer of acrylic acid and hydroxy alkyl acrylate.Type: GrantFiled: March 28, 1980Date of Patent: May 11, 1982Assignee: Laboratories, Inc. BetzInventors: Frederick G. Vogt, deceased, Patricia T. Sparrell
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Patent number: 4324684Abstract: A composition is disclosed comprising a stable aqueous solution of (i) water-soluble zinc compound, (ii) water-soluble chromate compound and (iii) a particular type of water-soluble polymer composed essentially of moieties derived from acrylic acid and hydroxylated lower alkyl acrylates. The composition could additionally comprise (iiii) orthophosphate.Type: GrantFiled: March 19, 1980Date of Patent: April 13, 1982Assignee: Betz Laboratories, Inc.Inventors: Gary E. Geiger, Roger C. May
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Patent number: 4299725Abstract: Aqueous media having a dissolved content of a small amount, (less than 100 p.p.m.) of a mixture of aminoalkanols of the formula: ##STR1## wherein R.sub.1 and R.sub.2 each represent H and C.sub.1-18 unbranched alkyl substituents (the sum of the carbon atoms in R.sub.1 and R.sub.2 being 9 to 18), R.sub.3 and R.sub.4 each represent H,C.sub.1-4 alkyl and C.sub.2-4 hydroxyalkyl substituents, x represents 2 to 6, and y represents 0 to 1, the ##STR2## units in the aminoalkanols being of at least two different chain lengths in the range of 11 to 20 carbon atoms, possess decreased tendency to corrode iron-containing metals including steel. The mixtures are also useful in salt form. The efficiency of the mixture is improved by various additives which act synergistically therewith.Type: GrantFiled: March 10, 1978Date of Patent: November 10, 1981Assignees: Henkel Kommanditgesellschaft auf Aktien, Deutsche Gold- und Silber Scheideanstalt vormals RoesslerInventors: Volker Wehle, Wolfgang Rupilius, Jurgen Reiffert, Gabriele Rogall
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Patent number: 4298568Abstract: A method for inhibiting corrosion of nonferrous metals in contact with circulating water comprising the steps of adding to circulating water in contact with non-ferrrous metals from 0.05 to 10 gm/m.sup.3 of at least one 3-amino-5-alkyl-1,2,4-triazole wherein said alkyl has from 2 to 8 carbon atoms and adjusting said water to a pH of from 6 to 10; as well as corrosion inhibiting compositions containing said 3-amino-5-alkyl-1,2,4-triazole.Type: GrantFiled: August 14, 1980Date of Patent: November 3, 1981Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Werner Gerhardt, Volker Wehle, Andreas Syldatk, Gabriele Rogall, Jurgen Reiffert, Jens Conrad
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Patent number: 4297317Abstract: A method and composition are disclosed for treating corroding aqueous mediums to reduce the corrosion of metal surfaces exposed thereto. The treatment comprises water-soluble chromate and a copolymer of acrylic acid and hydroxy alkyl acrylate.Type: GrantFiled: March 28, 1980Date of Patent: October 27, 1981Assignee: Betz Laboratories, Inc.Inventors: Frederick G. Vogt, deceased, Patricia T. Sparrell
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Patent number: 4207201Abstract: The application is concerned with a process for the manufacture of an aqueous iron (III)-chloride-sulfate solution by the oxidation of iron (II) sulfate with chlorine in aqueous solution.Type: GrantFiled: March 8, 1978Date of Patent: June 10, 1980Assignee: Kronos Titan GmbHInventors: Achim Hartmann, Achim Kulling, Dieter Schinkitz, Edgar Klein
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Patent number: 4176059Abstract: A low toxicity, corrosion and scale inhibiting composition for use in recirculating aqueous systems, e.g. in heat exchangers, comprises from about 3-1,000 parts by weight of molybdate, from about 0.5-1,000 parts by weight of an organic cationic or non-ionic surfactant, from about 0.3-1,000 parts by weight of a water soluble polyphosphate and from about 0.05-500 parts by weight of an azole, for example tolyltriazole. The composition is water soluble or water dispersible, and is effective in very small amounts (3-3,500 ppm) for corrosion control of metals such as carbon steel, copper and aluminum exposed to circulating water.Type: GrantFiled: June 8, 1978Date of Patent: November 27, 1979Assignee: Quatic Chemicals LimitedInventor: Fumiko Suzuki
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Patent number: 4111830Abstract: A method of retarding corrosion of metal parts in an aqueous-containing fluid system which comprises, adding to the aqueous-containing fluid system a mixture of a water-soluble cation of mercury and a water-soluble cation of a Group IB or Group IIB metal.Type: GrantFiled: September 29, 1976Date of Patent: September 5, 1978Inventor: Ramon A. Bannister