Indirect Heat-exchange Tube Within Reaction Chamber With A Nonreactant Heat-exchange Fluid Passing Therethrough Patents (Class 422/200)
  • Publication number: 20130084223
    Abstract: A reactor for carrying out a chemical reaction in a three phase slurry system providing a horizontal reaction vessel with a cross sectional area which is dependent on the vessel length, vessel diameter, and axial position. The vessel has a gas inlet at or near the bottom of the reaction vessel and a gas distributor. The gas product exits the vessel by conduit means at or near the top of the reaction vessel. The vessel includes a plurality of horizontal cooling coils to provide a cooling medium to the slurry. In the reaction vessel, the synthesis gas has an average linear velocity which is a function of the vessel cross sectional area.
    Type: Application
    Filed: August 16, 2011
    Publication date: April 4, 2013
    Applicant: EMERGING FUELS TECHNOLOGY, INC.
    Inventors: Rafael Espinoza, Kenneth L. Agee
  • Patent number: 8398846
    Abstract: The invention relates to a process for thermally cracking a hydrocarbon feed in an installation comprising a radiant section and a convection section, wherein a hydrocarbon feed stock is fed to a feed preheater present in the convection section, the heat pick-up of the feed preheater is controlled by regulating the heat exchange capacity of an economiser, said economiser being located in the convection section between the feed preheater and the radiant section, and wherein the feed heated in the preheater is thereafter cracked in the radiant section. The invention further relates to an installation for the cracking of a hydrocarbon feed.
    Type: Grant
    Filed: January 20, 2006
    Date of Patent: March 19, 2013
    Assignee: Technip France
    Inventors: Jacobus Arie Schilleman Overwater, Johannes Pieter Van Der Eijk
  • Patent number: 8398730
    Abstract: A method of producing substitute natural gas (SNG) includes providing a gasification reactor having a cavity defined at least partially by a first wall. The reactor also includes a first passage defined at least partially by at least a portion of the first wall and a second wall, wherein the first passage is in heat transfer communication with the first wall. The reactor further includes a second passage defined at least partially by at least a portion of the second wall and a third wall. The method also includes coupling the cavity in flow communication with the first and second passages. The method further includes producing a first synthetic gas (syngas) stream within the cavity. The method also includes channeling at least a portion of the first syngas stream to the first and second passages.
    Type: Grant
    Filed: July 23, 2008
    Date of Patent: March 19, 2013
    Assignee: General Electric Company
    Inventors: Paul Steven Wallace, Arnaldo Frydman
  • Patent number: 8388813
    Abstract: Improved, fuel-efficient systems are provided for the processing of biomass, such as wood or crop residues, food waste or animal waste in order to selectively obtain torrefied and/or carbonized final products. In general, the processes involve thermally drying incoming biomass using a dryer employing the hot gas output of a fuel-operated burner. Next, the dried product is torrefied in an indirect torrefaction reactor so as to evolve light volatile organic compounds which are used as a gaseous fuel source for the burner. The torrefied product can be recovered, or some or all of the torrefied product may be directed to a carbonization reactor coupled with a reactor burner. Carbonization serves to remove most of the remaining VOCs which are used as a gaseous fuel input to the dryer. In certain instances, portions of the dried biomass are directed to the burners, as an additional source of fuel.
    Type: Grant
    Filed: January 11, 2012
    Date of Patent: March 5, 2013
    Assignee: Earth Care Products, Inc.
    Inventors: Andrew D. Livingston, Bijoy J. Thomas
  • Publication number: 20130052097
    Abstract: A steam cooled chemical reactor (1) comprising a vertical vessel (2), a plate heat exchanger embedded in a catalytic bed, to cool the catalytic bed by evaporation of a cooling water flow, wherein a water inlet and a steam outlet are located underneath the heat exchanger, and the plates and related piping are arranged so that the path of the cooling flow comprises a first ascending path from bottom to top of the catalytic bed, and a second descending path from top to the bottom of catalytic bed, and wherein internal evaporation channels of the plates provide the second descending or the first ascending path, and water upcomers or respectively steam downcomers provide the other of said first and second path.
    Type: Application
    Filed: March 14, 2011
    Publication date: February 28, 2013
    Applicant: Methanol Casale SA
    Inventors: Enrico Rizzi, Ermanno Filippi, Mirco Tarozzo
  • Patent number: 8361422
    Abstract: The invention relates to systems and methods for heating a solid or liquid reducing material such as an urea-containing material for NOx selective catalytic reduction (‘SCR’) using a heat stored in a thermal energy storage material, such as a phase change material. The stored heat may be heat from an exhaust waste, such as from an exhaust gas of an internal combustion engine. The reducing material may be a solid reducing material. Other reducing materials include aqueous solutions such as an aqueous solution containing, consisting essentially of, or consisting of urea and water. In one aspect, the process may include a step of evaporating an aqueous solution of urea for immediate urea hydrolysis.
    Type: Grant
    Filed: August 15, 2011
    Date of Patent: January 29, 2013
    Assignee: Dow Global Technologies LLC
    Inventors: Andrey Soukhojak, David H. Bank
  • Patent number: 8361405
    Abstract: A reactor vessel for subjecting a first gas and a second gas to a chemical reaction to produce a third gas is provided. The reactor vessel includes a catalyst bed, an inlet for receiving the first gas and the second gas, and a first outlet for discharging the third gas. The first outlet includes a selective microporous conduit to separate the third gas from products of incomplete reaction or unreacted first gas and unreacted second gas. A second outlet for discharging one or more of the following: unseparated third gas is also included in this invention. The products of incomplete reaction, unreacted first gas, or unreacted second gas are removed from the system. At least one helical tube is disposed within the reactor vessel and in direct contact with the catalyst bed. The helical tube has an inlet end communicating with a hot gas source, and an outlet end exhausting cooled gas. Indirect heat exchange between the helical tube and the first and second gas, promoted by the catalyst, generates the third gas.
    Type: Grant
    Filed: August 5, 2010
    Date of Patent: January 29, 2013
    Assignee: Air Liquide Process & Construction, Inc.
    Inventor: Albertus J. Ekelmans
  • Patent number: 8323589
    Abstract: A pyrolysis process is provided. The process includes the steps of: depositing a quantity of waste into a porous container, the porous container adapted to allow a convective stream of substantially anaerobic gas to flow therethrough; inserting the porous container into a pyrolysis thermal processor; sealing the thermal processor; circulating the convective stream of gas through the pyrolysis thermal processor; heating the waste according to a first time-temperature profile to pyrolyze the waste and form a carbonaceous char; and cooling the carbonaceous char by circulating the convective stream of gas through a cooler. An oil product and a gaseous hydrocarbon product are produced during the pyrolysis. The carbonaceous char is further processed to form a carbon black product and a recyclable metal product.
    Type: Grant
    Filed: March 28, 2011
    Date of Patent: December 4, 2012
    Assignee: Tellus Technology, Inc.
    Inventors: Kenneth Wesley Hamby, James Brian Kelly, Timothy Joseph Kuhn
  • Patent number: 8314276
    Abstract: A method of hydroprocessing hydrocarbons is provided using a substantially liquid-phase reactor having first and second catalyst beds with a heat transfer section positioned therebetween. The first and second catalyst beds and the heat transfer section are combined within the same reactor vessel. Each catalyst bed having an inlet temperature and an exit temperature and having a hydroprocessing catalyst therein with a maximum operating temperature range.
    Type: Grant
    Filed: July 20, 2011
    Date of Patent: November 20, 2012
    Assignee: UOP LLC
    Inventors: John A. Petri, Peter Kokayeff
  • Patent number: 8307696
    Abstract: The present invention concerns an isothermal reactor (1) comprising a pressure vessel (2) closed at the opposite ends by respective bottoms (3, 4), a reaction zone (9) in said pressure vessel (2) in which at least one catalytic basket (10) is positioned, and at least one heat exchange unit (13) embedded in said at least one catalytic basket (10), each heat exchange unit (13) comprising a plurality of heat exchangers (14) each having an inner chamber intended to be crossed by an operating heat exchange fluid, the reactor being characterized in that it comprises means (17, 18) for picking up samples of operating heat exchange fluid from groups (16) of pre-established exchangers in each heat exchange unit (13), so as to ascertain the possible existence of damaged exchangers (14) in said groups (16) of exchangers through analysis of respective samples of operating heat exchange fluid.
    Type: Grant
    Filed: April 27, 2007
    Date of Patent: November 13, 2012
    Assignee: Methanol Casale S.A.
    Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
  • Patent number: 8303903
    Abstract: A production amount and a yield in a carbon nanotube producing device are improved. Inside a reaction pipe (20) heated so as to become a circumference heating body, a plurality of nozzles (26) for injecting a material and carrier gas into the reactor pipe and at least one internal heating source (24) are arranged. By arranging a plurality of the nozzles, the production amount is increased. The nozzles are arranged so as to be sandwiched by two heating sources (circumference heating element, internal heating source) and a distance to the closest two heating source peripheral walls is “a”. Also, a distance between the adjacent nozzles is “b” (?2a). Flows of the material and the carrier gas injected by the nozzles do not interfere with each other or the heating source wall, and the yield is increased.
    Type: Grant
    Filed: November 11, 2008
    Date of Patent: November 6, 2012
    Assignee: Nikkiso Co., Ltd.
    Inventors: Shuichi Shiraki, Takeji Murai, Yuzo Nakagawa
  • Patent number: 8287824
    Abstract: A micro-reactor system assembly comprises a stack of at least n process modules (1-6), wherein n is an integer equal to or greater than 1, made from a rigid first material and comprising at least one reactive fluid passage (1A, 1B, 2A, 3A, 6A) for accommodating and guiding a reactive fluid, and at least n+1 heat exchange modules (7, 8) made from a ductile second material other than said first material and comprising at least one heat exchange fluid passage (7A, 8A) for accommodating and guiding a heat exchange fluid, wherein each process module (1-6) is sandwiched between two adjacent heat exchange modules (7, 8).
    Type: Grant
    Filed: March 1, 2011
    Date of Patent: October 16, 2012
    Assignee: Lonza AG
    Inventors: Dominique Roberge, Nikolaus Bieler, Bertin Zimmermann, Rainald Forbert
  • Patent number: 8287815
    Abstract: A method and system for preheating a vessel that includes an area of excess heat and a flow of purge fluid that is channeled to an area to be purged wherein the purge fluid is deficient of heat are provided. The system includes a cooling tube assembly positioned between the area of excess heat and the area to be purged and a first heat exchanger coupled in flow communication to the cooling tube assembly, the first heat exchanger configured to transfer heat between a flow of cooling fluid through the cooling tube assembly and the flow of purge fluid wherein the flow of cooling fluid through the cooling tube assembly is maintained sub-cooled and the flow of purge fluid is heated to facilitate reducing a thermal stress in the area purged.
    Type: Grant
    Filed: May 2, 2008
    Date of Patent: October 16, 2012
    Assignee: General Electric Company
    Inventors: Steven Craig Russell, James Michael Storey, Robert Henri Gauthier
  • Patent number: 8257669
    Abstract: A chemical reactor is provided that includes: a plurality of tubes having a catalytic reactor substrate therein, each of the tubes having an inlet at one end for receiving a fluid flow and an outlet at an opposing end for discharging fluid flow, and a longitudinal axis parallel to the direction of fluid flow through the tube, the longitudinal axis of each tube being parallel to one another; and a plurality of heat exchange fins disposed on and extending radially from the exterior surface of each tube; the heat exchange fins on each tube independently having a profile along a cross-section perpendicular to the longitudinal axis of each tube, and the tubes being arranged with respect to one another, such that the heat exchange fin profiles together form a tessellated pattern in a plane that is perpendicular to the longitudinal axes of the tubes.
    Type: Grant
    Filed: December 22, 2010
    Date of Patent: September 4, 2012
    Assignee: Delphi Technologies, Inc.
    Inventor: Paul E. Jankowski
  • Publication number: 20120219467
    Abstract: The apparatus herein provide a catalyst cooler with a vent that communicates fluidizing gas to a lower chamber of a regenerator. Air that is used as fluidizing gas can then be consumed in the regenerator without promoting after burn in the upper chamber.
    Type: Application
    Filed: February 28, 2011
    Publication date: August 30, 2012
    Applicant: UOP LLC
    Inventors: Paolo Palmas, Daniel N. Myers
  • Patent number: 8252241
    Abstract: An apparatus for producing trichlorosilane in which metallurgical grade silicon powder supplied to a reactor is reacted with hydrogen chloride gas while being fluidized by the hydrogen chloride gas, thereby discharging trichlorosilane generated by the reaction from the reactor, includes: a plurality of gas flow controlling members which are installed along a vertical direction in an annular shape R from an inner peripheral wall of the reactor in an internal space of the reactor; and a heat transfer tube which is installed along the vertical direction in the annular space R and through which a heating medium passes.
    Type: Grant
    Filed: January 19, 2010
    Date of Patent: August 28, 2012
    Assignee: Mitsubishi Materials Corporation
    Inventor: Mitsutoshi Narukawa
  • Patent number: 8246915
    Abstract: Disclosed is a removable cooling module (1), for use in a reactor (20) for carrying out an exothermic reaction, comprising a coolant feed tube (2); a distribution chamber (4); a plurality of circulation tubes (5); and a collection chamber (6); said coolant feed tube (2) having at its first end an inlet (3), for charging the coolant module (1) with coolant, and communicating with said distribution chamber (4) at its second end; each of said circulation tubes (5) communicating with the distribution chamber (4) through a first end and communicating with said collection chamber (6) through a second end; the collection chamber (6) having an outlet for discharging coolant. The modular nature of the invention facilitates removal of individual cooling module (1) from a reactor shell (21).
    Type: Grant
    Filed: January 27, 2005
    Date of Patent: August 21, 2012
    Assignee: Shell Oil Company
    Inventors: Anne Boer, Franciscus Johannes Maria Schrauwen
  • Publication number: 20120183470
    Abstract: The present invention relates to a method for continuously preparing mineral particles by means of the thermolysis of mineral precursors in an aqueous medium, comprising contacting: a reactive flow, including mineral precursors at a temperature lower than the conversion temperature thereof; and a coolant flow that is countercurrent to said reactive flow and contains water at a temperature that is sufficient to bring the precursors to a temperature higher than the conversion temperature thereof, the mixture flow that results from said reactive flow and said coolant flow then being conveyed into a tubular reactor, inside of which particles are formed by gradually converting the precursors, and where the reactive flow and the coolant flow are placed in contact with each other inside a mixing chamber, inside of which the reactive flow and the coolant flow are fed by supply pipes having outlet cross-sections that are smaller than the maximum cross-section of said mixing chamber.
    Type: Application
    Filed: July 20, 2010
    Publication date: July 19, 2012
    Applicants: UNIVERSITE DE BOURGOGNE, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.)
    Inventors: Daniel Aymes, Moustapha Ariane, Frédéric Bernard, Hervé Muhr, Frédéric Demolsson
  • Patent number: 8206658
    Abstract: A metallic tube for heating a medium or subject outside thereof or inside it by transfer of heat energy through walls of the tube, in which heat is absorbed or emitted at least to a substantial degree by radiation on one or both of the inner and outer surfaces of the tube, is of a material forming a layer of essentially Al2O3 on the surfaces thereof when heated to at least approximately 750° C. At least one of the external and the internal surface of the tube is coated by one of a metal, metal alloy and metal compound, which after oxidation forms a layer having an emissivity coefficient exceeding 0.7, or by a layer essentially consisting of a metal oxide which has an emissivity coefficient exceeding 0.7.
    Type: Grant
    Filed: November 15, 2006
    Date of Patent: June 26, 2012
    Assignee: Sandvik Intellectual Property AB
    Inventors: Claes Öhngren, Bo Jönsson
  • Publication number: 20120148455
    Abstract: In this disclosure, a reactor system is described. The reaction system comprises (a) a reaction vessel having an inner wall, wherein said reaction vessel is configured to receive reactants and export products and byproducts; (b) a primary quench device (PQD) configured to receive a coolant and disperse said coolant into said reaction vessel; and (c) a secondary quench device (SQD) configured to receive a coolant and disperse said coolant into said reaction vessel; wherein said PQD comprises an array of spray nozzles fixed on the inner wall of said reaction vessel at a first axial position; and wherein said SQD comprises (1) an axially movable pipe having a coolant entry end and a nozzle end, wherein said pipe is configured to be removably fixed inside said reaction vessel; and (2) a spray nozzle that is fluidly connected to said pipe at its nozzle end via a fluid tight seal connection.
    Type: Application
    Filed: February 15, 2012
    Publication date: June 14, 2012
    Applicant: SYNFUELS INTERNATIONAL, INC.
    Inventors: Duane Morrow, Joel Cantrell, Edward R. Peterson
  • Patent number: 8197760
    Abstract: Provided are a heat medium heating-cooling apparatus and a heat medium temperature control method, which can control the heat medium temperature stably and more efficiently. The heat medium heating-cooling apparatus includes a heat medium heating unit (12) as well as a bypass line (19) thereof with switching valves 20a, 20b switching the direction of a flow of the heat medium to the heat medium heating unit or the bypass line. Decisions are made based on the present temperature (PV) in a reactor (11), a preset target temperature (SV), stable temperature range (?) and control switching temperature (?). According to the resulted four decisions of “stable heating”, “stable cooling”, “inclined heating” and “inclined cooling”, the temperature control according to either of the heating control at a heating control unit or the cooling control at a cooling control unit is conducted.
    Type: Grant
    Filed: September 10, 2008
    Date of Patent: June 12, 2012
    Assignee: Taiyo Nippon Sanso Corporation
    Inventors: Yasuaki Akai, Masahiro Yonekura, Masahiro Takeuchi
  • Patent number: 8192694
    Abstract: A polyester production system employing a vertically elongated esterification reactor. The esterification reactor of the present invention is an improvement over conventional CSTR esterification reactors because, for example, in one embodiment, the reactor requires little or no mechanical agitation. Further, in one embodiment, the positioning of the inlets and outlets of the reactor provides improved operational performance and flexibility over CSTRs of the prior art.
    Type: Grant
    Filed: January 7, 2011
    Date of Patent: June 5, 2012
    Assignee: Grupo Petrotemex, S.A. DE C.V.
    Inventor: Bruce Roger DeBruin
  • Patent number: 8191617
    Abstract: A method of assembling a syngas cooler is provided. The method includes coupling at least one cooling tube within the syngas cooler, wherein the at least one cooling tube includes an inner surface that defines a flow passage therethrough, an opposite outer surface, and at least one cooling fin extending outward from the outer surface, and orienting the at least one cooling tube such that the at least one cooling fin is in flow communication within a syngas flow passage defined in the syngas cooler, wherein the cooling fin facilitates enhancing heat transfer between fluid flowing in the at least one cooling tube and a syngas flow.
    Type: Grant
    Filed: August 7, 2007
    Date of Patent: June 5, 2012
    Assignee: General Electric Company
    Inventor: Judeth Helen Brannon Corry
  • Patent number: 8148587
    Abstract: The present invention provides a method for producing Lower olefin from the feed of methanol or/and dimethyl ether, characterized in that methanol or/and dimethyl ether are divided proportionally to be fed at 3 reaction zones; and the desired distribution of the olefin product is obtained by modulating the feeding ratio among the 3 reaction zones and the reaction conditions in each reaction zone.
    Type: Grant
    Filed: July 27, 2007
    Date of Patent: April 3, 2012
    Assignee: Dalian Institute of Chemical Physics, Chinese Academy of Sciences
    Inventors: Yue Qi, Zhongmin Liu, Zhihui Lv, Hua Wang, Changqing He, Lei Xu, Jinling Zhang, Xiangao Wang
  • Patent number: 8133445
    Abstract: This invention relates to a chamber in which a chemical reaction is carried out in the presence of catalyst and reagents, comprising at least one catalytic tube (10) into which is placed an internal tube (12) for evacuating the gas that is produced, means for introducing reagents (15) and means for introducing the catalyst (16) that are located in the upper portion of the chamber (1), means for heating the catalytic tube (10) that are arranged in the lower portion of the chamber (1), and in which the catalytic tube (10) comprises, in its upper portion above the catalyst (13), means that promote heat exchange between the reagents and the gas that is produced. The invention also relates to the process that uses this chamber.
    Type: Grant
    Filed: October 5, 2009
    Date of Patent: March 13, 2012
    Assignee: IFP Energies Nouvelles
    Inventors: Christophe Boyer, Fabrice Giroudiere
  • Publication number: 20120039761
    Abstract: A method of assembling an injection device for use in a reactor injector feed assembly includes extending the injection device at least partially into a cavity. The injection device includes a plurality of substantially concentric conduits coupled to a modular tip that includes a plurality of cooling channels and a plurality of substantially annular nozzles defined therein. The method also includes coupling at least one coolant distribution device in flow communication with the plurality of cooling channels to facilitate removing heat from an outer surface of the injection device.
    Type: Application
    Filed: August 11, 2010
    Publication date: February 16, 2012
    Inventors: Kenneth M. Sprouse, Shahram Farhangi, Robert M. Saxelby, David R. Matthews
  • Publication number: 20120039762
    Abstract: A tube isothermal chemical reactor (1), comprising a vessel (2) with a central axis (A-A), and an annular tube heat exchanger (40) embedded in a catalytic reaction space, the exchanger (40) comprising a plurality of concentric ranks (10, 11) of tube packs (10a), each of said tube packs comprising parallel tubes (30), a respective heat-exchange fluid feeder (20) and a respective heat-exchange fluid collector (21).
    Type: Application
    Filed: March 25, 2010
    Publication date: February 16, 2012
    Applicant: Methanol Casale S.A.
    Inventors: Enrico Rizzi, Ermanno Filippi, Mirco Tarozzo, Fabiano Montini
  • Publication number: 20120035392
    Abstract: A tubular flow type reactor comprising: (1) inflow channels for respective inflow of at least two kinds of fluids to be used in a reaction, (2) an outer tube having a lumen that is capable of merging the fluids and of distributing the merged fluids for the reaction, (3) an outflow channel for outflow of a reaction product from the outer tube, and (4) an inner tube disposed in the lumen of the outer tube, wherein an annular flow channel is formed between the outer tube and the inner tube, and the inflow channels are connected to the outer tube along the direction tangential to the internal circumference of the outer tube in such a manner that the lumens of the inflow channels communicate with the lumen of the outer tube, i.e., the annular flow channel.
    Type: Application
    Filed: March 24, 2010
    Publication date: February 9, 2012
    Applicant: NISSO ENGINEERING CO., LTD.
    Inventors: Eiichiro Kobayashi, Norihira Fukuzawa
  • Patent number: 8101131
    Abstract: Aluminum chloride from a gas containing chlorosilanes produced in a chlorination reactor is effectively removed. A container 1 is filled with sodium chloride and heated by a heating device 17, a gas containing chlorosilanes produced by a reaction between metallurgical grade silicon and hydrogen chloride passes through the sodium chloride layer 16 to generate a double salt of aluminum chloride contained in the gas and the sodium chloride, and the gas from which the double salt is separated is recovered from a gas recovery tube 26.
    Type: Grant
    Filed: March 20, 2009
    Date of Patent: January 24, 2012
    Assignee: Mitsubishi Materials Corporation
    Inventors: Teruhisa Kitagawa, Mitsutoshi Narukawa, Chikara Inaba
  • Patent number: 8101142
    Abstract: A reactor system, plant and a process for the production of methanol from synthesis gas is described in which the reactor system comprises: (a) a first reactor adapted to be maintained under methanol synthesis conditions having inlet means for supply of synthesis gas and outlet means for recovery of a first methanol-containing stream, said first reactor being charged with a first volume of a methanol synthesis catalyst through which the synthesis gas flows and on which in use, partial conversion of the synthesis gas to a product gas mixture comprising methanol and un-reacted synthesis gas will occur adiabatically; and (b) a second reactor adapted to be maintained under methanol synthesis conditions having inlet means for supply of the gaseous first methanol-containing stream, outlet means for recovery of a second methanol-containing stream and cooling means, said second reactor being charged with a second volume of a methanol synthesis catalyst through which the gaseous first methanol-containing stream flows
    Type: Grant
    Filed: May 30, 2002
    Date of Patent: January 24, 2012
    Assignee: Davy Process Technology Limited
    Inventor: Philip Henry Donald Eastland
  • Publication number: 20120001356
    Abstract: Embodiments of a continuous-flow injection reactor and a method for continuous material synthesis are disclosed. The reactor includes a mixing zone unit and a residence time unit removably coupled to the mixing zone unit. The mixing zone unit includes at least one top inlet, a side inlet, and a bottom inlet. An injection tube, or plurality of injection tubes, is inserted through the top inlet and extends past the side inlet while terminating above the bottom outlet. A first reactant solution flows in through the side inlet, and a second reactant solution flows in through the injection tube(s). With reference to nanoparticle synthesis, the reactant solutions combine in a mixing zone and form nucleated nanoparticles. The nucleated nanoparticles flow through the residence time unit. The residence time unit may be a single conduit, or it may include an outer housing and a plurality of inner tubes within the outer housing.
    Type: Application
    Filed: June 10, 2011
    Publication date: January 5, 2012
    Inventors: Chih-hung Chang, Hyungdae Jin
  • Publication number: 20110305604
    Abstract: A reactor that produces polycrystalline silicon using a monosilane process includes a reactor base plate having a multiplicity of nozzles formed therein through which a silicon-containing gas flows, a plurality of filament rods mounted on the reactor base plate, and a gas outlet opening located at a selected distance from the nozzles to feed used monosilane to an enrichment and/or treatment stage, wherein the gas outlet opening is formed at a free end of an inner tube, the inner tube is conducted through the reactor base plate, and the inner tube has an outer wall and an inner wall and thus forms an intermediate space in which at least one cooling water circuit is conducted.
    Type: Application
    Filed: October 9, 2009
    Publication date: December 15, 2011
    Applicant: SCHMID SILICON TECHNOLOGY GMBH
    Inventor: Robert Stöcklinger
  • Patent number: 8075845
    Abstract: The present invention relates to a heat-exchanger reactor comprising a vessel, at least one dividing member selected from plates, walls, or spiral sheets, which dividing member separates heat exchanging fluids into at least one heat exchanging zone from fluids into at least one mixing zone, and at least one flow-directing device having one or more ports or one or more injection ports, which flow-directing device is inserted into the mixing zone. The present invention relates also to uses of the heat-exchanger reactor.
    Type: Grant
    Filed: October 3, 2007
    Date of Patent: December 13, 2011
    Assignee: Alfa Laval Corporate AB
    Inventor: Selim Gülener
  • Patent number: 8071059
    Abstract: A chemical reactor for catalytic reactions, comprises a substantially cylindrical shell (2) closed at the opposite ends by respective covers (3 and 4), at least one reaction zone (7, 8) in which a respective catalytic bed (9, 10) and a plurality of heat exchangers (25) placed in said at least one reaction zone (7, 8) are supported.
    Type: Grant
    Filed: December 30, 2009
    Date of Patent: December 6, 2011
    Assignee: Methanol Casale S.A.
    Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
  • Patent number: 8066954
    Abstract: A plug flow reactor having an inner shell 27 surrounded by outer shell 21 and having at least one annular flow passage 35 therebetween can be used to prepare compositions, including polymers. The plug flow reactor also includes inlet port 36, an outlet port 37 and a plurality of exchanger tubes 26 wherein the exchanger tubes are in fluid communication to the at least one annular flow passage. Polystyrene and high impact polystyrene can be prepared using the reactor.
    Type: Grant
    Filed: December 17, 2008
    Date of Patent: November 29, 2011
    Assignee: Fina Technology, Inc.
    Inventors: Thanh T. Nguyen, Jay L. Reimers
  • Patent number: 8066953
    Abstract: Apparatus and method for hydrolyzing biological material for safe disposal thereof without the necessity of incineration or use of disinfectants are described. An alkaline solution having a concentration and an amount effective for hydrolyzing the biological material is brought into contact therewith by means of rotating paddles which both pound the biological material into small pieces and thoroughly mix the alkaline solution with the material under pressure and at elevated temperature. Following the hydrolysis of the biological material, a chosen portion of the water is removed from the alkaline solution and from the liquefied biological material, such that the resulting product solidifies when cooled. The present safe disposal of the biological material does not require incineration thereof, the addition of disinfectants thereto, or the discharge of liquid effluent containing processed biological material into the sewage system.
    Type: Grant
    Filed: June 15, 2008
    Date of Patent: November 29, 2011
    Assignee: Gyver L. Electric, Inc.
    Inventor: Mark R. Muth
  • Patent number: 8062605
    Abstract: A cooling system for use in a shell-type reactor includes vertically extending double tubes with an inner tube and an outer tube closed at its lower end. The system also includes a distributor for supplying a fluid cooling medium into the upper end of the inner tubes and a horizontally extending plate, which on its upper surface includes at least two upwardly open, parallel grooves. Two adjacent grooves are separated by a common inner wall. At least one outer tube, having an upper end, is disposed in each groove, through the plate. Each outer tube is tightly welded to the plate on the groove base. The upper, open side of each groove is closed with a lid, so that each groove forms a collector for discharging the cooling medium from the outer tubes. Each inner tube opens through the lid into a distributor and is tightly attached to the lid.
    Type: Grant
    Filed: April 1, 2010
    Date of Patent: November 22, 2011
    Assignee: MAN DWE GmbH
    Inventors: Manfred Lehr, Wolfgang Primbs
  • Patent number: 8053992
    Abstract: A plasma reactor includes a honeycomb electrode in which a plurality of cells that function as gas passages are partitioned by a partition wall, and a discharge electrode. The honeycomb electrode includes a first gas circulation section that allows a first gas to pass through, and a second gas circulation section that allows a second gas to pass through. The plasma reactor causes the first gas introduced into the first gas circulation section of the honeycomb electrode through the space between the electrodes to undergo a reaction while causing a plasma discharge between the honeycomb electrode and the discharge electrode, and allows the second gas to be introduced into the second gas circulation section of the honeycomb electrode to transfer heat of the second gas to the first gas circulation section to promote the reaction of the first gas.
    Type: Grant
    Filed: February 10, 2009
    Date of Patent: November 8, 2011
    Assignee: NGK Insulators, Ltd.
    Inventors: Masaaki Masuda, Michio Takahashi, Hiroshi Mizuno
  • Patent number: 8038747
    Abstract: Methods and systems for a gasifier having a partial moderator bypass are provided. The gasifier includes a partial oxidation reactor including an inlet and an outlet and a primary reaction zone extending therebetween, the partial oxidation reactor configured to direct a flow of products of partial oxidation including fuel gases, gaseous byproducts of partial oxidation, and unburned carbon, and a secondary reaction chamber coupled in flow communication with the partial oxidation reactor, the secondary reaction chamber is configured to mix a flow of moderator with the flow of gaseous byproducts of partial oxidation and unburned carbon such that a concentration of fuel gases is increased.
    Type: Grant
    Filed: October 27, 2009
    Date of Patent: October 18, 2011
    Assignee: General Electric Company
    Inventor: Paul Steven Wallace
  • Patent number: 8038959
    Abstract: A reacting device includes a base plate, a first reaction unit provided on the base plate, a reaction material being supplied thereto, the first reaction unit being set at a first temperature, a reaction flow channel being formed such that the reaction material flows therein, the first reaction unit causing a reaction of the reaction material and at least one heating unit which sets the first reaction unit at the first temperature. The first reaction unit has a plurality of reactors that communicate with each other, and the heating unit is provided between the adjacent reactors.
    Type: Grant
    Filed: September 6, 2006
    Date of Patent: October 18, 2011
    Assignee: Casio Computer Co., Ltd.
    Inventors: Naotomo Miyamoto, Tadao Yamamoto, Masaharu Shioya
  • Patent number: 8034308
    Abstract: A multi-stage, multi-tube, shell-and-tube reactor which contains reaction zones and interstage temperature control (cooling/heating) zones in series. The reactor has at least two types of zones which both contribute to removing or supplying heat to the system depending on the system's need. The reactor will have a group of reaction zones which contain tubes packed with catalyst to progress the reaction and remove or supply heat simultaneously. There are also a number of interstage temperature control (cooling/heating) zones which are designed to supply or remove heat to or from the system. The positioning, number, and design of the zones will depend on the amount of temperature control desired and exothermic or endothermic nature of the processes to be conducted in the reactor.
    Type: Grant
    Filed: June 9, 2009
    Date of Patent: October 11, 2011
    Assignee: Honeywell International, Inc.
    Inventors: Yuon Chiu, Stephen A. Cottrell, Richard Durick Horwath, Haluk Kopkalli
  • Patent number: 8029749
    Abstract: The invention relates to piping for use as a pyrolysis tube in a cracking furnace. The tube is formed such that it has at least one section whose centerline curves in three dimensions, to induce swirl flow in the tube. Preferably, the tube is formed as a helix.
    Type: Grant
    Filed: September 19, 2008
    Date of Patent: October 4, 2011
    Assignee: Technip France S.A.S.
    Inventors: Colin G. Caro, Philip L. Birch, William Tallis
  • Patent number: 8007734
    Abstract: The present invention concerns an isothermal reactor (1) for carrying out exothermal or endothermal heterogeneous reactions comprising: —a substantially cylindrical outer shell (2) with longitudinal axis (X), —at least one catalytic bed (6) extending in the shell (2) and comprising opposite perforated side walls (7, 8) respectively for the inlet of a gaseous flow of reactants and for the outlet of a gaseous flow comprising reaction products, and —a heat exchange unit (12) immersed in said at least one catalytic bed (6) and crossed by a heat exchange fluid, characterized in that said heat exchange unit (12) comprises at least one succession of heat exchangers (13) arranged substantially parallel to each other and substantially parallel to the direction in which said at least one catalytic bed (6) is crossed by said gaseous flow of reactants.
    Type: Grant
    Filed: August 20, 2007
    Date of Patent: August 30, 2011
    Assignee: Methanol Casale S.A.
    Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
  • Patent number: 7998427
    Abstract: A method for carrying out chemical reactions in so-called pseudo-isothermal conditions and in a predetermined reaction environment, for example a catalytic bed, comprises the step of arranging in the reaction environment at least one heat exchanger crossed by an operating fluid along a main direction.
    Type: Grant
    Filed: February 5, 2007
    Date of Patent: August 16, 2011
    Assignee: Methanol Casale S.A.
    Inventor: Giuseppe Guarino
  • Patent number: 7988926
    Abstract: In a hydrogen consuming system and a method for the operation thereof wherein the system comprises a hydrogen-consuming unit and a hydrogen storage arrangement comprising a compressed gas storage part and a solid material storage part and a cooling circuit with a radiator extending through the solid material storage part and the consuming unit, hydrogen bypass lines are provided for the solid material storage part and for the hydrogen consuming unit together with control valves for selectively by-passing the solid material storage part and the hydrogen consuming unit.
    Type: Grant
    Filed: October 27, 2008
    Date of Patent: August 2, 2011
    Assignee: Daimler AG
    Inventors: Eberhard Schmidt-Ihn, David Wenger
  • Publication number: 20110174682
    Abstract: The present invention is directed to a process for hydroprocessing of a liquid hydrocarbon feedstock, comprising: (a) mixing liquid, partially vaporized and/or vaporized hydrocarbon feedstock with molecular hydrogen; (b) feeding said mixture into a compression reactor; (c) compressing said mixture to a pressure, a temperature and for a residence time sufficient to: i) thermally crack at least a portion of hydrocarbon molecules in said hydrocarbon feedstock, and ii) react hydrogen in the presence of a hydrogenation catalyst with unstable portions of the cracked molecules, forming a hydroprocessed product; and (d) expanding said mixture to reduce the pressure and temperature thereby reducing subsequent undesirable reactions.
    Type: Application
    Filed: January 18, 2010
    Publication date: July 21, 2011
    Inventor: Larry L. Iaccino
  • Patent number: 7981271
    Abstract: Pseudo-isothermal radial chemical reactor for catalytic reactions, comprising a substantially cylindrical shell closed at the opposite ends by respective base plates, comprising a reaction zone in which a respective catalytic bed is supported and a plurality of heat exchangers placed in said reaction zone.
    Type: Grant
    Filed: January 15, 2004
    Date of Patent: July 19, 2011
    Assignee: Methanol Casale S.A.
    Inventors: Ermanno Filippi, Enrico Rizzi, Mirco Tarozzo
  • Patent number: 7981374
    Abstract: A method is disclosed for treating the effluent from a hydrocarbon pyrolysis process unit to recover heat and remove tar therefrom. The method comprises passing the gaseous effluent to at least one primary heat exchanger, thereby cooling the gaseous effluent and generating high pressure steam. Thereafter, the gaseous effluent is passed through at least one secondary heat exchanger having a heat exchange surface maintained at a temperature such that part of the gaseous effluent condenses to form in situ a liquid coating on said surface, thereby further cooling the remainder of the gaseous effluent to a temperature at which tar, formed by the pyrolysis process, condenses. The condensed tar is then removed from the gaseous effluent in at least one knock-out drum.
    Type: Grant
    Filed: November 17, 2008
    Date of Patent: July 19, 2011
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Robert David Strack, John R. Messinger
  • Patent number: 7972572
    Abstract: A reactor vessel liner system includes a liner having a plurality of first conduits and a plurality of second conduits for conveying a coolant. The plurality of second conduits is located at least partially within corresponding ones of the plurality of first conduits.
    Type: Grant
    Filed: March 4, 2008
    Date of Patent: July 5, 2011
    Assignee: Pratt & Whitney Rocketdyne, Inc.
    Inventors: Steven P. Fusselman, Stephen Arthur Yows, Bryan William McEnerney, Kenneth M. Sprouse
  • Patent number: RE43650
    Abstract: The invention relates to piping for use as a pyrolysis tube in a cracking furnace. The tube is formed such that it has at least one section whose centreline curves in three dimensions, to induce swirl flow in the tube. Preferably, the tube is formed as a helix, more preferably a low-amplitude helix.
    Type: Grant
    Filed: September 15, 2011
    Date of Patent: September 11, 2012
    Assignee: Technip France S.A.S.
    Inventors: Colin Gerald Caro, Philip Lloyd Birch, William Tallis