And Reactant Flow Distributor Upstream Of Contact Means And Within Reaction Chamber Modifying Velocity Profile Of Reactant Flow Patents (Class 422/220)
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Patent number: 7815873Abstract: The overall efficiency of a regenerative bed reverse flow reactor system is increased where the location of the exothermic reaction used for regeneration is suitably controlled. The present invention provides a method and apparatus for controlling the combustion to improve the thermal efficiency of bed regeneration in a cyclic reaction/regeneration processes. The process for thermal regeneration of a regenerative reactor bed entails (a) supplying the first reactant through a first channel means in a first regenerative bed and supplying at least a second reactant through a second channel means in the first regenerative bed, (b) combining said first and second reactants by a gas mixing means situated at an exit of the first regenerative bed and reacting the combined gas to produce a heated reaction product, (c) passing the heated reaction product through a second regenerative bed thereby transferring heat from the reaction product to the second regenerative bed.Type: GrantFiled: December 13, 2007Date of Patent: October 19, 2010Assignee: ExxonMobil Research and Engineering CompanyInventors: Krishnan Sankaranarayanan, Frank Hershkowitz, Jeffrey W. Frederick, Rajeev Agnihotri
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Patent number: 7807860Abstract: The present invention provides a reactor design that enables an auto-thermal cracking process to be conducted at any suitable pressure wherein the gaseous reactants are preheated separately before mixing and then presented to the reaction zone in a uniformly distributed manner.Type: GrantFiled: February 6, 2004Date of Patent: October 5, 2010Assignee: Ineos Europe LimitedInventors: Derek Alan Colman, Michael John Alexander Matthewman, Ian Allan Beattie Reid, Vaughan Clifford Williams, William Terence Woodfin
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Patent number: 7807116Abstract: A shell-and-tube reactor is disclosed. Contact tubes are disposed within a cylindrical housing and are secured to tube plates. Gas and liquid phases are received via a feed opening in a lower end cap and discharged via an upper end cap in the housing. A distributor device is disposed in the housing, such that the tube plates serve as a horizontal plate for the distributor device to back up the gas phase and form a gas cushion, and vertical elements extend from the contact tubes. The vertical elements are adapted to conduct the liquid phase, are open in the upstream direction, and project outward in the direction of the feed opening through the gas cushion. The vertical elements further include at least one first opening on the circumference for the gas phase and at least one second opening for the liquid phase.Type: GrantFiled: October 18, 2006Date of Patent: October 5, 2010Assignee: BASF SEInventors: Wolfgang Gerlinger, Torsten Mattke, Oliver Bey
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Patent number: 7803334Abstract: A hydrocracking process and apparatus wherein the feedstock is hydrotreated and the liquid and gaseous effluent from the hydrotreater is directly introduced into the upper end of a hydrocracking vessel which provides a liquid seal to prevent the passage of the gaseous stream containing hydrogen sulfide and ammonia from the hydrotreater to enter the hydrocracking zone containing hydrocracking catalyst. Fresh hydrogen is then introduced into the hydrocracking zone.Type: GrantFiled: July 11, 2006Date of Patent: September 28, 2010Assignee: UOP LLCInventors: Richard K. Hoehn, Vasant P. Thakkar, Vedula K. Murty, Douglas W. Kocher-Cowan, Jennifer L. Anderson
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Publication number: 20100216631Abstract: A method and apparatus for fluid-liquid reactions including gas-liquid and liquid-liquid reactions. The method and apparatus is suitable for mixing a fluid phase species and a liquid phase species to facilitate chemical reaction between said phases. The apparatus comprises a reactor vessel with a plurality of orificed plates and flow control means which initiates and maintains uniform mixing and efficient dispersion of a fluid-liquid mixture within the reactor vessel.Type: ApplicationFiled: June 23, 2004Publication date: August 26, 2010Inventors: Xiong-Wei NI, Andrew Fitch, Ian Laird
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Patent number: 7780929Abstract: The present invention provides a fluid mixing apparatus having a numbering-up mechanism that distributes plural kinds of fluids and concurrently performs multiple mixing or reactions, comprising: a rectifying section having a plurality of annular channels that rectify the plural kinds of fluids into respective concentric annular flows; a distribution section having a plurality of distribution channels that distribute the plural kinds of fluids rectified by the rectifying section into a plurality of flows; a converging section having a plurality of converging channels that converge different kinds of fluids among the plural kinds of fluids distributed by the distribution section; and a mixing/reaction section having a plurality of mixing/reaction channels that cause mixing or reaction of the plural kinds of fluids converged by the converging section, wherein a plurality of pressure loss increasing devices are provided in the distribution channels.Type: GrantFiled: March 28, 2007Date of Patent: August 24, 2010Assignee: FUJIFILM CorporationInventors: Takayuki Fujiwara, Kazuo Okutsu
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Patent number: 7780928Abstract: An improved radial or cross flow moving bed regenerator or reactor, in which the solid particle residence time in the vessels can be changed in different section of the regenerator or reactor. The improvement results from the placement of one or multiple screen inserts which divides the radial or cross flow bed into separate solid flow channels. The residence time of the solid in each solid flow channels are optimized based on the regeneration or reaction requirement by changing the location, orientation and geometry of the screen inserts. As a result of the optimization of solid residence time in different section in the radial flow bed, the efficiency of a regenerator or a reactor is improved.Type: GrantFiled: October 29, 2007Date of Patent: August 24, 2010Inventor: Leon Yuan
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Patent number: 7776289Abstract: A method of producing decabromodiphenyl alkanes includes the steps of charging a reaction vessel with bromine and a bromination catalyst and introducing a diphenyl alkane into the vessel at a location above the level of the charge bromine and catalyst. A dip tube apparatus for introducing the diphenyl alkane includes an inner tube and an outer tube, each of which are disposed above the surface of the bromine reaction vessel. The inner tube is fitted with a plug having an opening. Diphenyl alkane flows through the inner tube, out the opening in the plug, and into the reactor. The outer tube is disposed around and along the inner tube. Reaction mass from the vessel is recirculated from the vessel, through the outer tube and back to the vessel so as to form a curtain of reaction mass around the stream of diphenyl alkane being simultaneously fed into the reaction vessel.Type: GrantFiled: December 30, 2004Date of Patent: August 17, 2010Assignee: Chemtura CorporationInventors: Stephen B Falloon, Samuel U Mulligan, Donavon M McElveen, Ray W Atwell
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Publication number: 20100202940Abstract: Catalyst regeneration vessels including a chlorination zone that includes an outer mixing chamber, an inner mixing chamber, and a catalyst bed. The outer mixing chamber can include a lower portion and an upper portion, the lower portion of the outer mixing chamber including at least one air nozzle that injects a drying air stream into the outer mixing chamber, at least one chlorine input nozzle that injects a chlorine input stream into the outer mixing chamber, and at least a first baffle. The chlorination zone can also contain a second baffle that directs the mixed drying air stream and chlorine input stream from the outer mixing chamber to the inner mixing chamber.Type: ApplicationFiled: February 6, 2009Publication date: August 12, 2010Inventors: Bing Sun, Paul Alvin Sechrist
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Patent number: 7771668Abstract: A vertical multi-stage fluidized bed apparatus including a plurality of horizontal perforated partitioning plates disposed therein so as to partition the apparatus is provided, wherein an upper horizontal perforated partitioning plate is set to have a larger aperture rate than a lower horizontal perforated partitioning plate. From a lower part of the apparatus, feed carbon and fluidizing gas are continuously supplied so as to provide a gas superficial velocity in the fluidized bed which is 2-4 times a minimum fluidizing velocity of the feed carbon, thereby subjecting the feed carbon to fluidization with the fluidizing gas and activation with steam at 750-950° C. simultaneously to discharge activated carbon continuously from an upper part of the apparatus. As a result, activated carbon of even a high degree of activation is produced at a high yield comparable to that obtained in a batchwise operation.Type: GrantFiled: May 15, 2006Date of Patent: August 10, 2010Assignee: Kureha CorporationInventors: Hiroaki Ohashi, Yasuyoshi Yamanobe
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Publication number: 20100185032Abstract: A reactor (R) for carrying out a three-phase reaction of a liquid phase (1) and a gaseous phase (2) over a fixed catalyst bed (F), with the fixed catalyst bed (F) being arranged horizontally in the reactor (R) and the liquid phase (1) and the gaseous phase (2) being passed through the reactor (R) in cocurrent from the top downward via a mixing and distribution device (MD) over the fixed catalyst bed (F), wherein the mixing and distribution device (MD) comprises a trough distributor (TD) for the liquid phase (1) having trough-shaped channels (C) and outlet tubes (O) in the trough-shaped channels (C) for the liquid phase (1) and a distributor plate (P) which is arranged with a spacing below the trough distributor (TD) and in which vertical nozzles (N) having one or more openings (P1) for entry of the gaseous phase (2) and one or more openings (P2), which are arranged below the openings (P1) for entry of the gaseous phase, for entry of the liquid phase (1) into the nozzles (N) are installed, with the number andType: ApplicationFiled: June 20, 2008Publication date: July 22, 2010Applicant: BASF SEInventors: Stefan Iselborn, Andreas Daiss, Reiner Geier, Marcus Bechtel, Michael Wille, Benjamin Hepfer
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Publication number: 20100172805Abstract: In order to provide a gas generation apparatus such as a hydrogen gas generation apparatus for a fuel cell or an oxygen gas generation apparatus used in medical sites and at the time of disasters in which a solid gas generating agent such as metal is brought into contact with a reaction liquid to generate hydrogen gas or oxygen gas, a gas generation apparatus A having a solid gas generating agent and a reaction liquid in which the solid gas generating agent and the reaction liquid are stored respectively in separate storing vessels 21, 31 and in which the reaction liquid is supplied into the gas generating agent-storing vessel to generate gas by capillary-active connection of the respective storing vessels assumes a constitution in which capillary-active connection is shut off when a pressure of the gas is raised.Type: ApplicationFiled: July 3, 2008Publication date: July 8, 2010Applicant: Mitsubishi Pencil Company, LimitedInventor: Toshimi Kamitani
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Patent number: 7749467Abstract: A radial flow reactor fluid duct distribution apparatus is presented. The apparatus includes a plate of sufficient thickness to impart strength to the fluid flow duct and is milled to have narrow slots allowing fluid to flow through the plate, while preventing the passage of catalyst through the plate.Type: GrantFiled: December 18, 2007Date of Patent: July 6, 2010Assignee: UOP LLCInventors: Christopher Naunheimer, Michael J. Vetter
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Patent number: 7744831Abstract: Disclosed is an annular distributor having: an annular slit layer that is mounted on an inner circumferential surface of the annular distributor and has at least one slit discharging or introducing a fluid; at least one opening that is formed on an outer circumferential surface of the annular distributor and is connected with any one of a fluid supply duct and a fluid discharge duct; and at least one guide vane selected from three types of guide vanes that are installed in the annular distributor, and splits a flow rate of the fluid supplied from the duct or collects a flow rate of the fluid discharged to the duct. And disclosed are a reactor or heat exchanger has the annular distributor, and a method of producing unsaturated aldehyde or unsaturated acid from olefin by catalytic gas phase oxidation in the reactor.Type: GrantFiled: February 26, 2007Date of Patent: June 29, 2010Assignee: LG Chem, Ltd.Inventors: Sang Baek Shin, Sang Phil Han, Ye Hoon Im, Young Bae Kim, Jung Hoon Chang
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Publication number: 20100137670Abstract: Synthesis reactor comprising an apparatus for injecting oxygen, which can be initially charged in pure form, as air, or mixed with inert gas or water vapor, into a reaction gas which can flow through the synthesis reactor which finds use, for example, in an oxydehydrogenation plant, wherein oxygen and reaction gas have different temperatures, wherein a distribution element is provided upstream of the device for accommodating a catalyst charge in flow direction of the reaction gas, said distributor element comprising a distributor body, two tube plates and a multitude of gas guide tubes for passing the reaction gas through, and the oxygen can be supplied to the chamber between the gas guide tubes, wherein at least one baffle plate is arranged orthogonally to the gas guide tubes and divides the intermediate space into at least two distributor chambers, wherein the distributor chambers are connected to one another or merge into one another fluidically through one or more orifices, at least one gas line leads intType: ApplicationFiled: November 5, 2007Publication date: June 3, 2010Applicant: UHDE GMBHInventors: Max Heinritz-Adrian, Stefan Hamel, Lothar Semrau
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Patent number: 7718146Abstract: An apparatus for use in radial flow reactors is presented. The apparatus includes a plate of sufficient thickness to impart strength in supporting a solid particle bed, and is milled to have narrow slots allowing the flow of fluid through the plate, while preventing the passage of catalyst through the plate.Type: GrantFiled: May 13, 2008Date of Patent: May 18, 2010Assignee: UOP LLCInventors: Christopher Naunheimer, Paul A. Sechrist, Michael A. Schultz
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Patent number: 7695696Abstract: An apparatus for contacting a bed of particulate material with a cross flowing fluid, which maintains the bed of particulate material within a retention volume. The apparatus includes partitions for retaining particles, with apertures disposed within the partitions. The apertures are covered by louvers that extend above the edges of the apertures to prevent solid particles from spilling through inlet apertures.Type: GrantFiled: July 19, 2006Date of Patent: April 13, 2010Assignee: UOP LLCInventors: Bryan K. Glover, Guy B. Woodle, Joseph E. Zimmermann, John J. Senetar
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Patent number: 7682579Abstract: The invention relates to a method and device for the injection of oxygen in a reformer reactor, for example, for oxydehydrogenation, with an essentially radial throughflow of the gas mixture through a catalytic packing, whereby the incorporation and mixing of the oxygen before entry into the catalyst is significantly improved, in particular for oxydehydrogenation methods. The above is achieved, whereby the oxygen is introduced in pure form, as air, or mixed with inert gas, or with steam, into an annular distribution system (5) and injected out of a number of outlet openings (6) in the annular distribution system, at an angle to the perpendicular, onto the catalyst surface (3).Type: GrantFiled: January 15, 2005Date of Patent: March 23, 2010Assignee: Uhde GmbHInventor: Johannes Kowoll
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Publication number: 20100068128Abstract: The invention relates to a reactor (1) and a process for continuously preparing H2S by converting a reactant mixture which comprises essentially gaseous sulfur and hydrogen over a catalyst, comprising a sulfur melt (9) at least in a lower subregion (8) of the reactor (1), into which gaseous hydrogen is introduced. The catalyst is arranged in at least one U-shaped tube (21) which is partly in contact with the sulfur melt (9), the at least one U-shaped tube (21) having at least one entry orifice (23) on a limb (26) above the sulfur melt (9), through which the reactant mixture can enter the U-shaped tube (21) from a reactant region (10) of the reactor (1), having a flow path within the at least one U-shaped tube, along which the reactant mixture can be converted in a reaction region comprising the catalyst (22), and having at least one exit orifice (24) in another limb (27) through which a product can exit into a product region (7).Type: ApplicationFiled: January 14, 2008Publication date: March 18, 2010Applicant: BASF SEInventors: Andreas Wölfert, Herald Jachow, Heinz Driess
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Patent number: 7666367Abstract: The invention relates to a device equipped with a burner for combusting a fuel/oxidant mixture inside a combustion chamber in which a material (3, 3?, 3?, 3??) is provided that endures a maximum temperature. The inventive device also comprises one or more supply lines (25, 26) for the fuel as well as for the oxidant which are provided for supplying the same into the combustion chamber. The inventive device is characterized in that it is designed for carrying out a combustion with a combustion temperature of the fuel/oxidant mixture that exceeds the maximum temperature. The device is designed in such a way that at least one additional supply line (30) is provided via which an additional gas having, in particular, a low calorific value can be supplied to the combustion chamber. Said additional gas enables the temperature during combustion to be lowered to a value that is less than the maximum temperature.Type: GrantFiled: July 3, 2000Date of Patent: February 23, 2010Assignee: SGL Carbon AGInventors: Franz Durst, Jürgen Künzel
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Patent number: 7651076Abstract: A device for distributing a poly-phase mixture having a gas phase and liquid phase which mixture is in downflow mode through at least one bed of granular solid. The device has at least one tray (P) located above one of the beds of granular solid. It further has mixer conduits (21) for the liquid and gas phases, each conduit having an upper cross section for flow (22) allowing the passage of the majority of the gas phase, and a lower cross section for flow (23) allowing the mixture formed inside the conduits to communicate with a bed of granular solid. The mixer conduits (21) also having one or more lateral cross sections for flow (26) over at least a portion of their height to allow the passage of the liquid phase and possibly a minor portion of the gas phase inside the mixer conduits. The device also has a jet breaker type dispersive system (28) having a controlled porosity disposed below the lower cross section for flow (23) and above the bed of granular solids.Type: GrantFiled: October 25, 2002Date of Patent: January 26, 2010Assignee: Institut Francais du PetroleInventors: Isabelle Harter, Robert Agoero
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Publication number: 20100015018Abstract: The present invention relates to a treatment or hydrotreatment reactor comprising at least one granular bed (12), an essentially liquid phase (L) and an essentially gaseous phase (G) present in the bottom of the reactor and separated by an interface (38), and a distribution plate (20) with at least one main chimney (32) allowing circulation of liquid phase (L) towards the bed and at least one passage (30) for feeding gas phase (G) into said bed. According to the invention, plate (20) also comprises at least one mixed chimney (34) for circulation of the liquid phase towards the bed or for feeding the gas phase into said bed.Type: ApplicationFiled: July 15, 2009Publication date: January 21, 2010Inventors: Frederic AUGIER, Christophe Boyer
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Publication number: 20090318586Abstract: In a method for manufacturing a dispersion which includes a dispersion medium and particles dispersed therein, the method includes bringing at least two types of liquids into contact with each other to form a reaction product comprising the particles, wherein the liquids are ejected from respective nozzles to be brought into contact with each other and then to flow in an integrated manner while forming a spiral flow.Type: ApplicationFiled: June 22, 2009Publication date: December 24, 2009Applicant: CANON KABUSHIKI KAISHAInventors: Takayuki Teshima, Tetsuo Hino, Yukio Hanyu
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Publication number: 20090311143Abstract: A micro reactor having micro flow-guiding blocks includes a first gas flow channel, a second gas flow channel and a catalytic converter. There are several flow-guiding portions disposed on the first gas flow channel. Each flow-guiding portion has micro flow-guiding blocks, flow-impact recesses, and catalytic portions. The function of the micro flow-guiding block is to guide a flowing direction of the flow toward the catalytic portion on the flow-impact recess in order to increase a possibility of contacting and chemical reaction with the catalytic portion. So, guiding the flow direction toward the catalytic portion can increase the overall reaction efficiency. More turbulence is generated to obtain a better mixing. Plus, its structure is simple.Type: ApplicationFiled: September 4, 2007Publication date: December 17, 2009Inventors: Chi-Yuan Lee, Shuo-Jen Lee, Chin-Hua Wu, Guan-Wei Wu
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Patent number: 7622089Abstract: An apparatus for contacting a bed of particulate material with a cross flowing fluid, which maintains the bed of particulate material within a retention volume. The apparatus includes partitions for retaining particles, with apertures disposed within the partitions. The apertures are covered by shrouds that extend above the edges of the apertures to prevent solid particles from spilling through inlet apertures.Type: GrantFiled: July 19, 2006Date of Patent: November 24, 2009Assignee: UOP LLCInventor: Bryan K. Glover
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Patent number: 7618597Abstract: Embodiments of a nozzle reactor of the type useable to inject a first material feed stock and a second material feed stock to cause interaction between the first material feed stock and second material feed stock are described herein. According to one embodiment, the nozzle reactor includes a reactor body having a reactor body passage with an injection end and an ejection end. The nozzle reactor also includes a first material injector having a first material injection passage and being mounted in the nozzle reactor in material injecting communication with the injection end of the reactor body. The first material injection passage can have an enlarged volume injection section, an enlarged volume ejection section, and a reduced volume mid-section intermediate the enlarged volume injection section and the enlarged volume ejection section. The first material injection passage can also have a material injection end and a material ejection end in injecting communication with the reactor body passage.Type: GrantFiled: September 21, 2005Date of Patent: November 17, 2009Assignee: Marathon Oil Canada CorporationInventors: Willem Duyvesteyn, Gordon R. Wicker
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Patent number: 7611683Abstract: A reactor, which is capable of accommodating a reaction in which at least three phases are present and at least one gaseous starting material and at least one liquid starting material are reacted in cocurrent over a fixed-bed catalyst to give one or more product(s), contains at least one first zone in which a catalyst is present as a fixed bed; and at least one second zone whose size corresponds to a reactor cross section and which is separated from the at least one first zone by a distributor plate provided with at least one hole and in which at least one liquid and at least one gaseous starting material enter the reactor. The distributor plate is provided with at least one static mixer which is located in the at least one hole on at least one side of the distributor plate.Type: GrantFiled: April 29, 2005Date of Patent: November 3, 2009Assignee: OXENO Olefinchemie GmbHInventors: Gerda Grund, Stefan Jelko, Wilfried Büschken, Udo Peters
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Patent number: 7588740Abstract: A method for in-situ modernization of a heterogeneous synthesis reactor, comprises the steps of providing an unperforated cylindrical wall (15) coaxial to the gas outlet wall (8) in a catalytic bed (6) of the radial or axial-radial type, the unperforated cylindrical wall (15) extending from an upper end (8a) of the gas outlet wall (8) for a portion of the same of a prefixed length, so as to define a free-space (16) between the gas outlet wall (8) and the unperforated wall (15), for the passage of a part of the gas leaving said catalytic bed (6), and of providing means of closing the free-space (16) between the unperforated wall (15) and the gas outlet wall (8), in proximity of the upper end (8a) of the latter, preventing thereby a bypass of the catalytic bed or a recycling to the same of the gas entering respectively leaving the reactor.Type: GrantFiled: January 15, 1999Date of Patent: September 15, 2009Assignee: Ammonia Casale S.A.Inventors: Giuseppe Guarino, Ermanno Filippi
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Patent number: 7563419Abstract: A support system for catalyst gauzes in an ammonia oxidation burner and a method of reducing movement of particulate ceramic material due to thermal dilatation includes the catalyst gauzes (1) and possibly support screens (2) being supported by ceramic fillings contained in a burner basket with metal walls and a perforated bottom plate. A “wave breaker” (9, 11) is fixed to the metal wall (4) and/or the outer part/periphery of the bottom plate (5).Type: GrantFiled: September 20, 2002Date of Patent: July 21, 2009Assignee: Yara International ASAInventors: Halvor Øien, Leif Grønstad, Øystein Nirisen, Per Ivar Karlsen, Magne Slåen
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Patent number: 7544335Abstract: A radial flow reactor comprising a floating top cover plate assembly. A method of operating a radial flow reactor comprising floating a top cover plate assembly within the reactor.Type: GrantFiled: May 25, 2005Date of Patent: June 9, 2009Assignee: Chevron Phillips Chemical Company LPInventors: Geoffrey E. Scanlon, Daniel B. Knorr, Jr.
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Patent number: 7531024Abstract: A method and apparatus for operating a pressure vessel containing a bed of particulate material comprising substantially leveling the bed and employing a plug-flow inducer in the bed.Type: GrantFiled: May 17, 2006Date of Patent: May 12, 2009Assignee: Equistar Chemicals, LPInventors: Alberto Buchelli, William G. Todd, Jeffrey R. Golden
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Patent number: 7531015Abstract: A system for converting fuel and air into reformate with a reformer which has a reaction space, a nozzle for supplying a fuel/air mixture to the reaction space, and a fuel feed for supplying fuel to the nozzle. In the reaction space, there is a breaker body for a fuel/air mixture supplied through the nozzle.Type: GrantFiled: October 18, 2001Date of Patent: May 12, 2009Assignee: Webasto AGInventors: Felix Wolf, Christian Baecker, Sybille Miklos, Christine Sallinger, Marcus Neumueller, Stefan Kunz, Martin Wegner, Florian Metz, Bernd Mittmann, Johann Sperl, Thomas Kerscher, Josef Amann
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Patent number: 7521027Abstract: The invention relates to a device for circulation of a gaseous and/or liquid fluid through at least one solid particle bed equipped with at least one bypass means acting on at least one part of said fluid through at least one part of a solid particle bed, said bypass means comprising: a pipe whose top end discharges above the upper surface of the catalyst bed and whose bottom end discharges below said surface, and a valve that is made to be actuated in the open position when the differential pressure through the solid particle bed is greater than a predetermined value, said valve including means allowing the automatic variation of the passage section of the fluid based on the fluid flow rate.Type: GrantFiled: September 28, 2005Date of Patent: April 21, 2009Assignee: Institut Francais Due PetroleInventors: Christophe Boyer, Abdelhakim Koudil
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Patent number: 7517373Abstract: A device to reform a raw material gas into a synthesis gas rich in hydrogen and carbon monoxide is disclosed. The device includes a vessel, a floating head, a plurality of reaction tubes, inlets and outlets for raw material and heating gases, and a cooled fixed tube plate.Type: GrantFiled: June 29, 2005Date of Patent: April 14, 2009Assignee: Toyo Engineering CorporationInventors: Kenji Sakai, Kunio Hirotani
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Patent number: 7510689Abstract: The invention provides a method and apparatus for introducing a high-density hydrocarbon liquid into a hydrocracking reactor. The method comprises atomizing the high-density hydrocarbon liquid and injecting the atomized liquid into the hydrocracking reactor. The method may also comprise mixing hydrogen with the high-density hydrocarbon liquid prior to atomizing the high-density hydrocarbon liquid. The apparatus comprises an injection valve for introducing a high-density hydrocarbon liquid into a hydrocracking reactor comprises an atomizer coupled to receive the high-density hydrocarbon liquid. The atomizer comprises a nozzle configured to atomize the high-density hydrocarbon liquid and inject the high-density hydrocarbon liquid into the hydrocracking reactor. The injection valve may also comprise a mixer coupled to receive hydrogen and the high-density hydrocarbon liquid. The mixer may be configured to mix the hydrogen and high-density hydrocarbon liquid and deliver the mixture to the atomizer.Type: GrantFiled: December 21, 2005Date of Patent: March 31, 2009Assignee: Genoil Inc.Inventor: Paul Costinel
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Patent number: 7510688Abstract: A stack type reactor that can adjust a length of channel (reaction time) to react raw substances with each other for a sufficient time and mix completely raw substances to maximize the reaction efficiency. The stack type reactor comprises an upper block with at least two inlets that introduce different kinds of raw substances and a lower channel fluidly connected to the inlets and formed at a lower surface thereof; a unit block including an upper channel corresponding to the lower channel of the upper block and formed on an upper surface thereof, the unit block including a lower channel formed at a lower surface thereof and fluidly connected with the upper channel via a connecting flow passage. The upper block and unit block form a flow path for the raw substances by connecting to the lower channel of the upper block to the upper channel of the unit block.Type: GrantFiled: September 26, 2006Date of Patent: March 31, 2009Assignee: LG Chem, Ltd.Inventors: Jae Hoon Choe, Jung Uk Choi, Young Woon Kwon, Kwang Cheon Park, Jung Hyun Seo, Jun Yeon Cho, Yoo Seok Kim, Kwang Ho Song
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Patent number: 7491259Abstract: A method and apparatus for operating a pressure vessel containing a bed of particulate material comprising substantially leveling the bed and employing a fluid flow distributor above the bed.Type: GrantFiled: May 9, 2006Date of Patent: February 17, 2009Assignee: Equistar Chemicals, LPInventors: Alberto Buchelli, William G. Todd
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Publication number: 20090032440Abstract: One exemplary embodiment can include a method of controlling a catalyst transfer vessel cycle of loading and unloading based on an expected level of a catalyst in a downstream vessel for a hydrocarbon conversion unit. The method can include calculating an expected catalyst level in the downstream vessel based on the unloading of the catalyst transfer vessel to adjust a setpoint to change the catalyst transfer vessel cycle of loading and unloading.Type: ApplicationFiled: August 1, 2007Publication date: February 5, 2009Inventors: David J. Fecteau, Christopher Naunheimer
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Patent number: 7481982Abstract: A carbon monoxide oxidizer comprises an oxidant supply unit (4) that supplies an oxidant gas to a reformate gas, a mixing unit (5) that mixes the reformate gas with the oxidant gas, and a preferential oxidation catalyst unit (6) that removes carbon monoxide from a mixed gas using catalytic action. The mixing unit (5) comprises a stacked body (9) of plates (100A-100F). A rotating passage (101) that is formed in the stacked body (9) to rotate the flow of the mixed gas, thereby promoting mixing of the reformate gas with the oxidant gas by a rotating flow formed by the rotating passage (101).Type: GrantFiled: December 11, 2003Date of Patent: January 27, 2009Assignee: Nissan Motor Co., Ltd.Inventor: Yasushi Ichikawa
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Patent number: 7473405Abstract: The invention in one embodiment is a nozzle device for coupling with a fluid distribution conduit for improving the distribution of an upward or downwardly flowing poly-phase mixture including at least one gas phase and at least one liquid phase, above at least one packed bed of granular solid or fluidized bed. The fluid distribution conduit for receiving liquid and gas phases has one or more lateral openings for flow over an upper portion of its height through which a gas phase can enter and has fluid distribution conduit having one or more lateral openings for flow over at least a lower portion of its height through which a liquid phase can enter the fluid distribution conduit. It also has at least one lower cross section for flow through which a mixture of gas and liquid communicate with a packed bed of granular solid or a fluidized bed.Type: GrantFiled: October 13, 2004Date of Patent: January 6, 2009Assignee: Chevron U.S.A. Inc.Inventors: Abdenour Kemoun, Krishniah Parimi, Duyen T. Nguyen
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Patent number: 7470405Abstract: A microchannel reactor is disclosed that provides superior performance for three-phase (gas/liquid/solid-catalyst) reactions. The reactor may be used, for example, in industrial-scale catalysis, e.g., in large-scale chemical production, and also in catalyst screening. Each microchannel in the reactor has a separate micro-outlet to supply gas to the channel. Each microchannel is open on both ends, so that liquid may freely flow through the channels in both directions. Oscillatory forcing is applied to the liquid outside the microreactor. The combined effect of the separate gas inlets for each microchannel, the open nature of the microchannels on both ends, and oscillatory forcing results in highly efficient transport of both gas and liquid through all of the microchannels, promotes efficient mixing, and enhances catalysis.Type: GrantFiled: January 25, 2005Date of Patent: December 30, 2008Assignee: Board of Supervisors of Louisiana State University And Agricultural and Mechanical CollegeInventors: Frederick Carl Knopf, Virbert Paul Rodriguez
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Patent number: 7470410Abstract: The invention is a support system for use with a reactor vessel that defines a reactor zone and has an inlet manway providing an opening into the reactor zone. The support system comprises a manway insert that is supported by the inlet manway and extends through the opening of the inlet manway and into the reactor zone. Attached to the manway insert is attachment means for connecting a support hanger to the manway insert and for transferring the load from the support hanger to the manway insert. The support hanger has an upper end and a lower end with the upper end being fixedly attached to the attachment means and the lower end being fixedly attached to support structure means for supporting a load.Type: GrantFiled: February 22, 2006Date of Patent: December 30, 2008Assignee: Shell Oil CompanyInventor: Eric Sevenhuijsen
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Patent number: 7470408Abstract: The present invention provides methods, systems and apparatus in which one fluid passes through an orifice or orifices and mixes with another fluid as it flows through a microchannel.Type: GrantFiled: May 17, 2004Date of Patent: December 30, 2008Assignee: VelocysInventors: Anna Lee Tonkovich, Kai Jarosch, David J. Hesse, Sean P. Fitzgerald
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Publication number: 20080306295Abstract: A method and a device for the sulfonation or the sulfation of organic liquid raw materials with an S03/air mixture and other reaction gases in order to perform rapid, highly exothermic gas-liquid reactions in conventional thin-layer falling-film reactors are disclosed. The introduction of the S03/air mixture occurs through several feed locations, which are located within (along) the reaction tube or reaction tubes or in the annular gap of annular-gap falling-film reactors. High peak temperatures, undesirable byproducts, worsening of the color and local oversulfation or oversulfonation, which leads to side reactions, are largely avoided.Type: ApplicationFiled: December 20, 2006Publication date: December 11, 2008Applicant: THE CHEMITHON CORPORATIONInventors: Rudolf Aigner, Horst Reuner
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Patent number: 7459132Abstract: The present invention discloses a process and apparatus for improving the catalyst life and efficiency in a gas flow catalyst bed reactor assembly. The reactor comprises an outer reaction vessel, an inner displacement cylinder, and an annular catalyst bed surrounding the displacement cylinder having a top half and a bottom half. Fluid flow improvement is achieved by adding at least one baffle to the top half of the displacement cylinder to improve uniformity of fluid flow in the reaction vessel and across the catalyst bed. Also disclosed is a process for improving fluid flow uniformity in a gas phase reactor comprising an outer reaction vessel, an inner displacement vessel having a top half and a bottom half and a reaction outer surface and an inert inner space, and an annular catalyst bed. The process comprises conducting fluid flow simulations using actual reactor conditions. During simulation, baffles are added on the outer reaction surface of the displacement reactor to improve simulated fluid flow.Type: GrantFiled: April 1, 2004Date of Patent: December 2, 2008Assignee: Fina Technology, Inc.Inventors: Kelli E. Prince, Marcus E. Ledoux, Honn Tudor, L. Mark Gremillion
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Publication number: 20080241023Abstract: The invention relates to a method and device for the injection of oxygen in a reformer reactor, for example, for oxydehydrogenation, with an essentially radial throughflow of the gas mixture through a catalytic packing, whereby the incorporation and mixing of the oxygen before entry into the catalyst is significantly improved, in particular for oxydehydrogenation methods. The above is achieved, whereby the oxygen is introduced in pure form, as air, or mixed with inert gas, or with steam, into an annular distribution system (5) and injected out of a number of outlet openings (6) in the annular distribution system, at an angle to the perpendicular, onto the catalyst surface (3).Type: ApplicationFiled: January 15, 2005Publication date: October 2, 2008Inventor: Johannes Kowoll
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Publication number: 20080145285Abstract: A reactor (1) for carrying out a reaction between two fluid starting materials (2, 3) over a catalyst bed (4) with premixing of the fluid starting materials (2, 3) before introduction into the catalyst bed within a delay time of less than 150 ms in a mixing-in device (5), wherein the mixing-in device (5) is made up of the following elements which are arranged essentially transverse to the inflow direction of the first fluid starting material stream (2): two or three rows arranged behind one another of tubes (6) which have turbulence generators on the outside and constrict the flow cross section for the first fluid starting material stream (2) to from ½ to 1/10, with the second fluid starting material stream (3) being passed through the interiors of the tubes (6) and injected via openings (7) in the tubes (6) into the first fluid starting material stream (2), and a perforated plate (10) upstream of the tubes (6) and a perforated plate (11) downstream of the tubes (6), is proposed.Type: ApplicationFiled: December 18, 2007Publication date: June 19, 2008Applicant: BASF AktiengesellschaftInventors: Gerhard Olbert, Franz Corr, Sven Crone
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Patent number: 7350962Abstract: A catalytic hydrocracking reactor vessel includes enhanced components for the conversion of a hydrogen gas and fossil fuel feedstream to light liquid hydrocarbons. The reactor vessel comprises one or more of a reactor cup riser with a helical cyclonic separator conduit for separating a liquid and vapor product stream to provide an essentially vapor-free liquid recycle stream; a grid plate bubble cap with wall housing having serrated edges for producing small hydrogen bubbles of increased total surface area of bubbles at lower pressure drop; a feedstream inlet pipe sparger containing rows of downward directed slots for even distribution of the feedstream across the cross-sectional area of the reactor and providing free drain of solid particles from the sparger; and optionally a liquid recycle inlet distributor containing vertically curved plates for creating a whirling motion in the liquid recycle stream for better mixing with the feedstream with minimal solids settling.Type: GrantFiled: January 27, 2005Date of Patent: April 1, 2008Assignee: Hydrocarbon Technologies Innovation Group, Inc.Inventors: Thomas Kao, Robert Chang
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Publication number: 20080056963Abstract: A nozzle arrangement for a fluidized bed gasifier or combustor. The nozzle arrangement includes a nozzle piece attached to a nozzle tube for forming one entity with the nozzle tube, which nozzle piece includes a nozzle chamber and a horizontally extending nozzle channel ending to a blow opening of the nozzle. The nozzle chamber and nozzle channel are limited from above by a lid. The nozzle arrangement further includes a protecting cover attached outside the lid for minimizing cooling of the outer surface of the nozzle piece due to fluidizing gas blown through the nozzle into the fluidized bed gasifier or combustor.Type: ApplicationFiled: April 4, 2005Publication date: March 6, 2008Applicant: FOSTER WHEELER ENERGIA OYInventor: Pekka Lehtonen
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Patent number: 7338645Abstract: Disclosed is a method and system for reducing the formation of metal catalyzed side-reaction byproducts formed in the feed vaporization and introduction system of a methanol to olefin reactor system by forming and/or coating one or more of the heating devices, feed lines or feed introduction nozzles of/with a material that is resistant to the formation of metal catalyzed side reaction byproducts. The invention also may include monitoring and/or maintaining the temperature of at least a portion of the feed vaporization and introduction system and/or of the feedstock contained therein below about 400° C., 350° C., 300° C., 250° C., 200° C. or below about 150° C. The temperature can be maintained in the desired range by jacketing at least a portion of the feed vaporization and introduction system, such as at least a portion of the feed introduction nozzle, with a thermally insulating material or by implementing a cooling system.Type: GrantFiled: January 21, 2004Date of Patent: March 4, 2008Assignee: ExxonMobil Chemical Patents Inc.Inventors: Jeffrey P. Jones, Kenneth Ray Clem, Stephen N. Vaughn, Teng Xu, Jeffrey L. White