Utilizing Liquid Reactant Patents (Class 423/245.2)
  • Patent number: 11535539
    Abstract: A method for treating a wastewater or a wastewater sludge includes adding performic acid to the wastewater and/or the waster sludge as an odor controlling agent and/or corrosion controlling agent.
    Type: Grant
    Filed: November 17, 2017
    Date of Patent: December 27, 2022
    Assignee: Kemira Oyj
    Inventors: James Currie Allen, Tafadzwa Mariga
  • Patent number: 10119077
    Abstract: Tools and techniques for pyroligneous acid production are provided in accordance with various embodiments. For example, a method of pyroligneous acid production is provided. The method may include: introducing a compound that includes at least carbon, oxygen, and hydrogen into a reaction chamber; heating the compound to a temperature of at least 700 degrees Celsius in the reaction chamber such that the compound reacts through a pyrolysis reaction to produce a liquid, where the liquid may include pyroligneous acid; and/or collecting the produced liquid. In some cases, the residence time of the compound may be less than 1,000 seconds. Temperatures above 1,000 degrees Celsius may be utilized in some cases. The produced liquid may be separated into an oil component and a water component that includes the pyroligneous acid. A lighter fraction may be distilled from the water component, where the lighter component includes the pyroligneous acid.
    Type: Grant
    Filed: February 4, 2017
    Date of Patent: November 6, 2018
    Assignee: Proton Power, Inc
    Inventors: Samuel C. Weaver, Priyanka Bhattacharya, Anthony Justin Lundy, Joseph William Hargrove
  • Publication number: 20150086458
    Abstract: The present invention discloses a formaldehyde absorbent and a method for using the same, the chemical composition of the formaldehyde absorbent by weight percentage is, amino acid: 0.1-99.9%; DNA and RNA base 99.9-0.1%. The method comprises the following steps: a. dissolving the formaldehyde absorbent in solvent to form a solution or dissolving the formaldehyde absorbent in solvent and mixing the same onto a solid carrier; b. placing the solution or solid carrier in indoor space that contains formaldehyde; and c. contacting and reacting the formaldehyde-containing air with the solution or the solid carrier and then absorbing the same. The present invention not only achieves not only excellent performance in absorbing hazard gases in the air, but also features low-cost, and further causes no secondary pollution, which therefore creates great social and economical significance in improving quality of human life, safeguarding human health, and protecting environment.
    Type: Application
    Filed: September 29, 2013
    Publication date: March 26, 2015
    Applicant: NINGBO YUCHEN ENVIROCLEAN TECH CO., LTD.
    Inventors: Zuolin Zhu, JiaBao Zhao, Meng Sun, Zhenji Zhu, Kangfu Gu, Shanqing Sun, Tongxing Xie, Wenhai Wang
  • Patent number: 8821822
    Abstract: Disclosed herein is a process and a plant for recovering ammonia from a mixture including ammonia, acid gas containing H2S and/or CO2 and low-boiling water-soluble organic components. To avoid an enrichment of volatile organic compounds in the acid gas absorber, a partial stream of the liquid phase is withdrawn from an acid gas absorber and processed such that gaseous ammonia with a reduced content of volatile organic components is obtained, which is recirculated into the acid gas absorber.
    Type: Grant
    Filed: November 13, 2009
    Date of Patent: September 2, 2014
    Assignee: Lurgi GmbH
    Inventors: Gert Ungar, Matthias Linicus
  • Publication number: 20140230725
    Abstract: In order to provide a method for the thermal conditioning of an auxiliary material, which, to clean a crude gas stream loaded with an organic pollutant, is configured to be introduced into the crude gas stream and together with the organic pollutant forms a stable system of pollutant and auxiliary material, which can be carried out easily and in a resource-saving manner, it is proposed that the method includes the following steps: feeding the system of pollutant and auxiliary material and a carrier gas stream that has been heated in relation to normal conditions into a thermal conditioning device; chemical conversion of at least a part of the organic pollutant to produce a conditioned auxiliary material; separating the conditioned auxiliary material from the auxiliary material loaded with an organic pollutant by transportation by means of a gas flow; and removing the conditioned auxiliary material from the thermal conditioning device.
    Type: Application
    Filed: April 30, 2014
    Publication date: August 21, 2014
    Applicant: Dürr Systems GmbH
    Inventors: Sebastian Holler, Cord Kirschke
  • Publication number: 20140205524
    Abstract: A process for extracting a target gas component from a gas mixture in an apparatus having a pair of capture and release sections is provided. The pair of capture and release sections includes a sorbent capture section and a sorbent release section, each of the sorbent capture section and sorbent release section having a high surface area medium and a sorbent contained therein. A gas mixture is directed through a flow path, the flow path directing the gas mixture through the sorbent release section followed by the sorbent capture section, wherein the sorbent within the pair of capture and release sections extracts the target gas component and reduces the target gas component in the gas mixture.
    Type: Application
    Filed: January 24, 2013
    Publication date: July 24, 2014
    Inventor: David Sevier
  • Patent number: 8269037
    Abstract: An absorption medium for removing acid gases from a fluid stream comprises an aqueous solution of a) of at least one metal salt of an aminocarboxylic acid, and b) of at least one acid promoter, wherein the molar ratio of b) to a) is in the range from 0.0005 to 1.0. The acid promoter is selected from mineral acids, carboxylic acids, sulfonic acids, organic phosphonic acids and partial esters thereof. The absorption medium, compared with absorption media based on amino acid salts, has a reduced regeneration energy requirement without significantly reducing the absorption capacity of the solution for acid gases. In a process for removing acid gases from the fluid stream, the fluid stream is brought into contact with the absorption medium.
    Type: Grant
    Filed: January 28, 2010
    Date of Patent: September 18, 2012
    Assignee: BASF SE
    Inventors: Gerald Vorberg, Torsten Katz, Georg Sieder, Christian Riemann, Rupert Wagner, Ute Lichtfers, Erika Dengler
  • Patent number: 8153091
    Abstract: To provide a simple highly-pure Xe retrieval method and device with high retrieval efficiency by functionally removing such elements as water, CO2 and FCs from waste gases from semiconductor production processes, such as the plasma etching, that contain low-concentration Xe. For samples containing xenon and fluorocarbon, this invention is characterized by having at least first adsorption means (A1) filled with synthetic zeolite with pore size of 4A or smaller and aluminum oxide, arranged serially, gas separation means (A2) composed of silicone or polyethylene hollow fiber gas separation membrane modules 4, second adsorption means (A3) filled with either activated carbon, synthetic zeolite with pore size of 5A or larger, molecular sieving carbon with pore size of 5A or larger, or a combination of these, and reaction means (A4) filled with calcium compounds as reactant.
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: April 10, 2012
    Assignee: L'Air Liquide Societe Anonyme Pour l'Etude Et l'Exploitation des Procedes Georges Claude
    Inventors: Masahiro Kimoto, Terumasa Koura, Yukio Fukuda, Masaki Narazaki, Taiji Hashimoto, Toru Sakai, Kazuo Yokogi
  • Publication number: 20110165663
    Abstract: A device and a method for producing a fine liquid mist and injecting the said mist into a gas stream to capture and remove very fine particulate pollutants. The pressurized gas stream is passed into a droplet generator (20) into which the liquid is sprayed and atomised into a mist which captures particulates and then into a droplet separator (30) to produce a separated liquid/particulate mixture and a gas stream with a reduced concentration of particulates. The main application is the removal of fine particulates from vehicle exhaust streams. Optionally a degassing stage (90) is provided for the removal of residual gases and vapours. The preferred liquid to form the mist is water.
    Type: Application
    Filed: July 11, 2005
    Publication date: July 7, 2011
    Inventor: Howard P. Davis
  • Patent number: 7846406
    Abstract: A scrubber for scrubbing at least one pollutant from flue gas includes a first stage configured to provide a chemical oxidant to a stream of flue gas, and a second stage configured to provide a chemical or chemicals to the stream of flue gas, a scrubbing medium recirculation feature configured to continuously recirculate a slurry used in the second stage, and a by-product processing portion configured to remove a by-product from a stream of slurry withdrawn from the scrubber. The by-product includes reaction products of at least one pollutant.
    Type: Grant
    Filed: August 17, 2009
    Date of Patent: December 7, 2010
    Inventors: Kevin P. Furnary, William Ellison
  • Patent number: 7815879
    Abstract: Methods and apparatuses are described for contacting an oxidizing solution such as an aqueous hydrogen peroxide composition of hydrogen peroxide and at least one additive that catalyzes the decomposition of the hydrogen peroxide into hydroxyl radicals with an atmospheric effluent containing odorous and/or noxious components. These components are absorbed by the aqueous hydrogen peroxide composition to produce an atmospheric effluent having reduced amounts of the odorous and/or noxious components. Various methods are described for adding the hydrogen peroxide and the decomposition additive.
    Type: Grant
    Filed: June 4, 2009
    Date of Patent: October 19, 2010
    Assignee: Steen Research, LLC
    Inventors: Stephen R. Temple, Michael J. Stoltz
  • Publication number: 20100258428
    Abstract: There is provided a method for reducing the content of at least one water soluble volatile organic compound in a gas. The method comprises contacting the gas with an aqueous acidic oxidizing composition comprising H2O2 and a metal catalyst, and submitting the at least one water soluble volatile organic compound and the aqueous acidic oxidizing composition to an UV radiation.
    Type: Application
    Filed: April 14, 2010
    Publication date: October 14, 2010
    Inventors: Pierre-André GIGNAC, Martin BEAULIEU, Yves CHAREST, Stéphane CHABOT, Abderrahman MAHFOUD, Jules LEMAY
  • Patent number: 7811538
    Abstract: The method allows to remove mercaptans contained in a gaseous feed comprising hydrocarbons by carrying out the following stages: a) contacting, in a reactor R1, gaseous feed 1 with a liquid stream 13 comprising olefins, in the presence of a first acid catalyst so that the mercaptans react with the olefins so as to form sulfides, b) discharging an effluent 3 from reactor R1 and separating the effluent into a gas phase and a liquid phase so as to obtain a mercaptan-depleted treated gas 4 and a sulfide-laden liquid, c) separating the sulfide-laden liquid into a first fraction 6 and a second fraction 5, the volume flow rate of first fraction 6 being at least three times higher than the volume flow rate of second fraction 5, d) recycling first fraction 6 to stage a) as a first portion of said liquid stream to be fed into said reactor R1, e) regenerating second fraction 5 by cracking so as to obtain a sulfide-depleted second fraction 2 that is recycled to stage a) as a second portion of said liquid stream.
    Type: Grant
    Filed: March 28, 2008
    Date of Patent: October 12, 2010
    Assignee: Institut Francais du Petrole
    Inventors: Renaud Cadours, Eric Lemaire, Julia Magne-Drisch
  • Patent number: 7803337
    Abstract: A method for treating a fluid to be scrubbed, comprising filling a scrubber with a volume of biodiesel or biomass adequate to cover a sintered permeable membrane in the reaction chamber and a bit more to create a reaction zone in not only a plurality of pores in the membrane with fluid but in a reaction zone above the membrane, then introducing fluid to be scrubbed to the membrane, building up pressure in the reaction chamber, and passing a scrubbed fluid from the reaction zone to an exit port at a rate equal to the rate the fluid to be scrubbed is introduced.
    Type: Grant
    Filed: June 25, 2009
    Date of Patent: September 28, 2010
    Assignee: Vapor Point, LLC
    Inventors: Jefferey St. Amant, Kenneth R. Matheson
  • Patent number: 7740816
    Abstract: A method for treating gases to be scrubbed, comprising filling a scrubber with a volume of lean liquid adequate to cover a sintered permeable membrane in the reaction chamber and a bit more to create a reaction zone in not only a plurality of pores in the membrane with gases but in a reaction zone above the membrane, then introducing gases to be scrubbed to the membrane, building up pressure in the reaction chamber, and passing scrubbed gas from the reaction zone to an exit port at a rate equal to the rate of gases to be scrubbed are introduced.
    Type: Grant
    Filed: February 4, 2009
    Date of Patent: June 22, 2010
    Assignee: Vapor Point, LLC
    Inventors: Jefferey St. Amant, Kenneth R. Matheson
  • Patent number: 7740815
    Abstract: A method of treating a gas stream containing silane or other silicon-containing gas is described, in which the gas stream is conveyed to a liquid ring pump or screw-mechanism pump, to which are also supplied an oxidant for oxidising the silicon-containing gas within the pump, and a liquid for forming a liquid ring or intermittent flushing within the pump. A liquid stream containing said liquid and a by-product of the oxidation of the silicon-containing gas is exhaust from the pump.
    Type: Grant
    Filed: March 13, 2006
    Date of Patent: June 22, 2010
    Assignee: Edwards Limited
    Inventors: James Robert Smith, Gary Peter Knight
  • Publication number: 20100135885
    Abstract: A system removes ethanol and other organic carbons from fermentation exhaust gases. Structurally, the system includes a first scrubber with top and bottom ends. Further, the system includes a second scrubber with a top end and with a bottom end in fluid communication with the first scrubber's top end. During operation, exhaust gases are introduced into the bottom end of the first scrubber. Further, a light alcohol solvent is flowed down from the top end to the bottom end of the first scrubber. As the solvent contacts the exhaust gases, it absorbs the other organic carbons. Thereafter, the exhaust gases enter the second scrubber's bottom end. At the second scrubber's top end, water is introduced and falls into contact with the exhaust gases, absorbing the ethanol. In this manner, ethanol and other organic carbons are removed from the exhaust gases solely through absorption by solvents.
    Type: Application
    Filed: December 1, 2008
    Publication date: June 3, 2010
    Inventors: Ronald G. Patterson, Andrew J. Olds
  • Patent number: 7691268
    Abstract: Waste gas/wastewater treatment equipment treats waste gas in a scrubber 18 by using micronanobubble water produced in a micronanobubble reaction vessel 31 as washing water. Waste gas is efficiently cleaned by the substance surface high-velocity cleaning function which micronanobubbles have. The washing water having been used in the waste gas treatment is reused in wastewater treatment in adjustment tank 1, denitrification tank 3 and nitrification tank 11 which constitute a wastewater treatment section. Thus, the micronanobubbles contained in the washing water are utilized in wastewater treatment, so that efficiency of wastewater treatment is enhanced.
    Type: Grant
    Filed: January 31, 2006
    Date of Patent: April 6, 2010
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Kazuyuki Yamasaki, Keichiro Uda, Kazumi Chuhjoh
  • Publication number: 20100040524
    Abstract: A scrubber for scrubbing at least one pollutant from flue gas includes a first stage configured to provide a chemical oxidant to a stream of flue gas, and a second stage configured to provide a chemical or chemicals to the stream of flue gas, a scrubbing medium recirculation feature configured to continuously recirculate a slurry used in the second stage, and a by-product processing portion configured to remove a by-product from a stream of slurry withdrawn from the scrubber. The by-product includes reaction products of at least one pollutant.
    Type: Application
    Filed: August 17, 2009
    Publication date: February 18, 2010
    Inventors: Kevin P. Furnary, William Ellison
  • Publication number: 20090291872
    Abstract: The present invention provides compositions comprising ionic liquids and an amine compound, and methods for using and producing the same. In some embodiments, the compositions of the invention are useful in reducing the amount of impurities in a fluid medium or a solid substrate.
    Type: Application
    Filed: December 11, 2008
    Publication date: November 26, 2009
    Applicant: The Regents of the University of Colorado
    Inventors: Jason E. Bara, Dean E. Camper, Douglas L. Gin, Richard D. Noble
  • Patent number: 7550123
    Abstract: Methods and apparatuses are described for contacting an oxidizing solution such as an aqueous hydrogen peroxide composition of hydrogen peroxide and at least one additive that catalyzes the decomposition of the hydrogen peroxide into hydroxyl radicals with an atmospheric effluent containing odorous and/or noxious components. These components are absorbed by the aqueous hydrogen peroxide composition to produce an atmospheric effluent having reduced amounts of the odorous and/or noxious components. Various methods are described for adding the hydrogen peroxide and the decomposition additive.
    Type: Grant
    Filed: May 26, 2006
    Date of Patent: June 23, 2009
    Assignee: Steen Research, LLC
    Inventors: Stephen R. Temple, Michael J. Stoltz
  • Patent number: 7498009
    Abstract: A method for reducing or substantially eliminating oxides of nitrogen from an effluent gas stream, that includes providing a source of ultraviolet radiation with a precise wavelength, adding ammonia or an ammonia based reagent to the effluent stream, upstream of the ultraviolet radiation source, controllably operating the ultraviolet radiation source to irradiate the effluent stream flowing in the duct and substantially reducing or eliminating oxides of nitrogen by promotion a reaction of ammonia with the oxides of nitrogen to produce N2 and H2O, and also thereby destroying any surplus ammonia. This process can also be modified to oxidize carbon monoxide and VOC's to CO2 and H2O.
    Type: Grant
    Filed: August 11, 2005
    Date of Patent: March 3, 2009
    Assignee: Dana UV, Inc.
    Inventors: James T. Leach, Michael Lee Fraim
  • Patent number: 7341701
    Abstract: A method and apparatus (22) for treating culinary gaseous effluents (Eg) carried in an air extraction duct of a kitchen, the apparatus includes: a unit (24) for storing in liquid form a nucleophilic active product (Pa), or odour destroyer, able to fix foul-smelling molecules in the form of inert salts, a nebulizing and diffusing unit (26) which vaporizes or sublimates the active product (Pa) coming from the storage unit, and which diffuses the vaporized or sublimated active product (Pa) in an extraction duct (18), at ambient temperature, so as to minimize the discharge of foul-smelling molecules at the outlet of the extraction duct. A plant including this apparatus is also disclosed.
    Type: Grant
    Filed: April 3, 2003
    Date of Patent: March 11, 2008
    Inventor: Henry Abehssera
  • Patent number: 7192565
    Abstract: The gaseous feed flowing in through line 1 is contacted in contacting zone ZA with a liquid solvent flowing in through line 2. The solvent comprises between 0.001% and 100% by weight of a liquid olefin. Contacting in zone ZA is carried out in the presence of an acid catalyst. The purified gaseous feed is discharged from zone ZA through line 3. The sulfide-laden solvent is discharged through line 4, then regenerated in unit RE. The regenerated solvent is recycled through lines 7 and 2 to zone ZA.
    Type: Grant
    Filed: August 2, 2005
    Date of Patent: March 20, 2007
    Assignee: Institut Francais du Petrole
    Inventors: Patrick Briot, Renaud Cadours, Sophie Drozdz, Fabrice Lecomte
  • Patent number: 7022296
    Abstract: A multiple-field precipitator, flue-gas treating device, in accordance with the principles of the invention, includes a first section having a dual-function, sensible-cooling heat exchanger/electrostatic precipitator, a second section having a wet electrostatic precipitator, and a middle section fluidly connecting the first and second sections. In the first section, the exchanger/precipitator sensibly cools the flue gas and collects most of the dust from the flue gas. In the middle section, the dust-reduced flue gas is combined with an alkaline material, thereby forming reaction products. These reaction products and several other pollutants are captured by the wet electrostatic precipitator, in the form of a pollutant-laden liquid. The pollutant-laden liquid is directed to a series of heat exchangers and settling tanks, where various pollutants such as SOx, metals, NOx, and chlorides are removed in different stages.
    Type: Grant
    Filed: November 14, 2000
    Date of Patent: April 4, 2006
    Assignee: University of Cincinnati
    Inventors: Soon-Jai Khang, Timothy Keener
  • Patent number: 6998098
    Abstract: A process is presented for separating and removing acid gases or base gases from a feed gas by use of a gas permeable membrane and a permeate comprising a treatment solution. The treatment solution in the permeate is caustic or acidic and reacts with the base or acid gases respectively to form salts so as to facilitate their removal from the feed gas. The acid gas in an acid feed gas may include HCN, H2S, CO2, COS and/or NOx. The base gas in a base feed gas may include NH3. In another aspect of the present invention, an apparatus for treating a feed gas containing an acid or a base gas comprises a feed gas passage; a treatment solution container containing a treatment solution; and a gas permeable membrane.
    Type: Grant
    Filed: November 11, 2002
    Date of Patent: February 14, 2006
    Assignee: Conocophillips Company
    Inventor: Joe D. Allison
  • Patent number: 6953557
    Abstract: A process and an apparatus for treating exhaust gases, comprising an aeration stirring tank (5) employing an aqueous alkaline liquid, and, as a posterior stage, a gas-liquid contact device (7) and/or a packed column (11). The apparatus can remove at the posterior stage harmful gases that the aeration stirring tank fails to remove, for example, water-soluble organic compounds such as ethanol, halogenated silicon compounds such as SiCl4, and halogen gases such as F2 and Cl2. The process and apparatus are particularly suitable for purifying exhaust gases discharged from a semiconductor production device.
    Type: Grant
    Filed: October 15, 1998
    Date of Patent: October 11, 2005
    Assignee: Ebara Corporation
    Inventors: Hiroshi Ikeda, Yasuhiro Kubota, Takashi Kyotani
  • Patent number: 6645450
    Abstract: Methods and apparatus are described which utilize an aqueous hydrogen peroxide composition of hydrogen peroxide and at least one additive which serves to catalyze the rapid decomposition of the hydrogen peroxide into hydroxyl radicals. When contacted with an atmospheric effluent containing odor and/or noxious components, the hydroxyl radicals formed oxidize the odor and noxious components to non-odor offensive, environmentally acceptable by-product.
    Type: Grant
    Filed: March 2, 2001
    Date of Patent: November 11, 2003
    Assignee: Steen Research, LLC
    Inventors: Michael J. Stoltz, Stephen R. Temple
  • Patent number: 6638488
    Abstract: Method and apparatus for isolating, decomposing, and fixing the organic hazardous substances in a stable manner using chemical techniques and isolating and decomposing the organic hazardous substances from various waste mixtures. The temperature treatment is preferably kept within room temperature range of between 0-30° C. The detoxification of the organic hazardous substances avoids secondary pollution of the environment when the treated materials are released in the soil, atmosphere, or in groundwater.
    Type: Grant
    Filed: March 6, 2000
    Date of Patent: October 28, 2003
    Inventors: Yukoh Akae, Kazuo Kote
  • Patent number: 6503471
    Abstract: Malodorous gases such as amines, organosulfur compounds, hydrogen sulfide, styrene and aldehydes are economically and efficiently treated at ambient temperature and pressure by a catalytic absorption and oxidation process comprising: (a) bringing the malodorous gases into contact with a scrubbing water containing a heterogeneous catalyst to absorb the malodorous components catalytically, and (b) subjecting the resulting solution containing the malodorous components to a catalytic oxidation by contacting it with an oxidizing agent such as hydrogen peroxide, ozone, oxygen, air, nitrogen oxides, and NaOCl in the presence of the catalyst at a temperature ranging from 0 to 100 □ under an ambient pressure, the heterogeneous catalyst comprising an active metal element selected from alkali, alkaline earth and transition metals, and an oxide support material.
    Type: Grant
    Filed: October 6, 2000
    Date of Patent: January 7, 2003
    Assignee: Korea Institute of Science & Technology
    Inventors: Seong-Hwan Han, Kwang-Deog Jung, Oh-Shim Joo, Seong-Hoon Cho, Jun-Woo Oh
  • Patent number: 6491888
    Abstract: The invention relates to a process for the selective recovery of olefins from a mixture of gases by: a) bringing a gaseous mixture having olefins and hydrogen into contact with silver nitrate solution whereby the olefins are absorbed into the silver nitrate solution as a complex; b) separating the solution having complexed olefins from the non-absorbed gases; c) depressurising and heating the olefin complex solution from (b) so as to release the olefins from the complex and regenerate the silver nitrate solution; d) passing the regenerated silver nitrate solution through a bed containing silver oxide so as to maintain the pH value of the silver nitrate at between 3 and 6; and e) recycling the silver nitrate solution regenerated in (d) to step (a).
    Type: Grant
    Filed: April 27, 2001
    Date of Patent: December 10, 2002
    Assignee: BP Chemicals Limited
    Inventors: Peter Simpson Bell, Eric Nicholas Coker, Karen Small
  • Patent number: 6471928
    Abstract: The claimed invention relates to a process for preparing an aqueous formaldehyde solution comprising absorbing a formaldehyde-loaded gas stream, in an absorption zone, in an aqueous solution comprising from 0.000% to 0.01% by weight of a Bronsted base, based on the formaldehyde absorbed. The produced aqueous formaldehyde solution comprises: a) from 10 to 75% by weight of formaldehyde, b) from 0 to 500 ppm by weight of tetroxane, c) from 50 to 400 ppm by weight of formic acid, based on the formaldehyde absorbed, and d) from 0.2 to 5.0% by weight of methanol, based on the formaldehyde absorbed.
    Type: Grant
    Filed: April 27, 2001
    Date of Patent: October 29, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Eckehard Danz, Klaus Pandl
  • Patent number: 6375912
    Abstract: The invention provides an improved point-of-use PFC/HFC abatement process involving an electrochemical route to abatement. PFCs/HFCs are treated with a relatively strong chemical reducing agent, typically an alkali such as lithium, potassium, or sodium, in a system that promotes ionization of the alkali, e.g., by inclusion of ammonia or other compound that promotes dissolution of the alkali to ions. The electrochemical potential arising from the ionization process provides sufficient energy to extract the fluorine atoms from the PFCs/HFCs. The system also contains a weak acid proton donor to provide a hydrogenation source. The weak acid is believed to displace the reaction equilibrium by protonation, to allow the reaction to proceed at a sufficient rate.
    Type: Grant
    Filed: December 21, 1999
    Date of Patent: April 23, 2002
    Assignee: Agere Systems Guardian Corp.
    Inventor: Ralph E Taylor-Smith
  • Publication number: 20020039551
    Abstract: The invention relates to a process for the selective recovery of olefins from a mixture of gases by: a) bringing a gaseous mixture having olefins and hydrogen into contact with silver nitrate solution whereby the olefins are absorbed into the silver nitrate solution as a complex; b) separating the solution having complexed olefins from the non-absorbed gases; c) depressurising and heating the olefin complex solution from (b) so as to release the olefins from the complex and regenerate the silver nitrate solution; d) passing the regenerated silver nitrate solution through a bed containing silver oxide so as to maintain the pH value of the silver nitrate at between 3 and 6; and e) recycling the silver nitrate solution regenerated in (d) to step (a).
    Type: Application
    Filed: April 27, 2001
    Publication date: April 4, 2002
    Inventors: Peter Simpson Bell, Eric Nicholas Coker, Karen Small
  • Publication number: 20010043898
    Abstract: Methods and apparatus are described which utilize an aqueous hydrogen peroxide composition of hydrogen peroxide and at least one additive which serves to catalyze the rapid decomposition of the hydrogen peroxide into hydroxyl radicals. When contacted with an atmospheric effluent containing odor and/or noxious components, the hydroxyl radicals formed oxidize the odor and noxious components to non-odor offensive, environmentally acceptable by-product.
    Type: Application
    Filed: March 2, 2001
    Publication date: November 22, 2001
    Inventors: Michael J. Stoltz, Stephen R. Temple
  • Patent number: 6290923
    Abstract: A stack emission control system utilized to remove organic contaminants as water-soluble solids from air collected from the vicinity of a polyurethane foam line assembly prior to the exhaust of the air into the surrounding atmosphere is described. A conventional packed tower scrubber is utilized containing an inert material as packing and pH-adjusted water as the wash fluid. The pH-adjusted water serves to remove essentially all of the organic contaminants as water-soluble solids from the air prior to exhaust of the air. The contaminant water-soluble solids are then readily separable from the pH-adjusted water by post-treatment to allow for the separate disposal of the essentially contaminant-free water and the contaminant solids.
    Type: Grant
    Filed: September 22, 1994
    Date of Patent: September 18, 2001
    Assignee: Wm. T. Burnett & Co.
    Inventors: Joseph S. Sollers, Roland N. Fracalossi, Walter V. V. Greenhouse, George J. Tolen
  • Patent number: 6280696
    Abstract: A method for removing high boiling point volatile organic compounds from an exhaust gas and an apparatus for performing such operation are described. In the method, a wet scrubber is provided which is equipped with a spent water reservoir at the bottom of the scrubber for collecting spent water that contains the volatile organic compounds dissolved in water used to wash the exhaust gas. An ozone gas at a preset concentration is then flown into the spent water to oxidize the dissolved volatile organic compounds contained in the water. The exhaust gas after being washed in the wet scrubber can be released to the atmosphere together with carbon dioxide generated in the oxidation reaction. In the apparatus, an ozone detector is further provided on the exhaust gas outlet in the wet scrubber chamber to verify a content of ozone in the released exhaust gas which is an indication that all the volatile organic compounds have been oxidized in the spent water reservoir.
    Type: Grant
    Filed: April 5, 2000
    Date of Patent: August 28, 2001
    Assignee: Taiwan Semiconductor Manufacturing Company, Ltd
    Inventors: Hua-Ching Hsu, Ta-Tien Hsiang
  • Patent number: 6277344
    Abstract: Disclosed is a process for the treatment of a plant fluid effluent containing odor compounds including an alkyl mercaptan or an alkyl thiol, an amine compound, ammonia, hydrogen sulfide and mixtures thereof by contacting the plant effluent in either a counterflow or cocurrent flow process. In the process, the effluent is contacted with an aqueous solution comprising a peroxyacid compound and one or more essential oils. When contacted with the peroxyacid, odor compounds in the effluent are oxidized and converted from the gaseous phase into a chemically modified highly aqueous soluble phase in the aqueous treatment. In this way, odor removal from the gas is preferred and odor compounds are efficiently transferred into the aqueous treatment solution. The use of such a process produces a significant improvement in odor quality index as measured by a conventional process using an expert panel when compared to conventional treatment methods.
    Type: Grant
    Filed: November 9, 1999
    Date of Patent: August 21, 2001
    Assignee: Ecolab Inc.
    Inventors: Robert D. P. Hei, Keith D. Lokkesmoe, Louis M. Holzman
  • Patent number: 6207120
    Abstract: An integrated process for vent gas treatment for the abatement of volatile emissions is disclosed. The vent gas comprises dioxygen, carbon monoxide, hydrocarbons and other organic compounds comprising one or more alkyl halide compound of 1 to 5 carbon atoms. In the preferred embodiment, the vent gas is heated and mixed with an amount of combustible fluid. Then the mixture is directed to a catalytic oxidation reactor having a suitable oxidation catalyst disposed therein, wherein the mixture is catalytically oxidized. The effluent from the catalytic oxidation reactor is directed to heat the incoming vent gas and subsequently to a scrubber wherein the effluent is scrubbed of soluble compounds and the resultant treated gas stream is vented. Importantly, the amount of combustible fluid supplied to the vent gas stream is controlled so at to provide sufficient reactants for the catalytic oxidation to maintain reaction temperatures from 200° C. and 600° C.
    Type: Grant
    Filed: June 10, 1997
    Date of Patent: March 27, 2001
    Assignee: BP Amoco Corporation
    Inventors: Frank G. Belmonte, Kenneth J. Abrams, Judith P. Oppenheim
  • Patent number: 6171569
    Abstract: Disclosed is a method of eliminating the odor from a malodorous gas, where the odor is due to the presence of a C10 to C18 fatty acid in the gas. An aqueous solution containing at least a stoichiometric amount of a base that reacts with said C10 to C18 fatty acid to produce a salt is sprayed into the gas.
    Type: Grant
    Filed: November 24, 1999
    Date of Patent: January 9, 2001
    Assignee: Occidental Chemical Corporation
    Inventor: Daniel J. Brandt
  • Patent number: 6168771
    Abstract: Substances to be processed and a hydrogen peroxide aqueous solution are enclosed in a process vessel, and a the process vessel is enclosed in an autoclave together with water. Oxidation processing of the substances is performed by changing the state in the autoclave and the process vessel to a supercritical state which is realized by heating an outer wall of the autoclave with a heater. Further, even if the substances leak from the process vessel, by oxidizing the leaking substances in the autoclave the leaking of the substances to the outside of an oxidation processing apparatus is prevented.
    Type: Grant
    Filed: February 17, 1998
    Date of Patent: January 2, 2001
    Assignee: Hitachi, Ltd.
    Inventors: Norihide Saho, Hisashi Isogami, Minoru Morita, Yoshiki Shibano