Alkaline Earth Metal Containing (mg, Ca, Sr, Or Ba) Patents (Class 423/331)
  • Patent number: 11352264
    Abstract: The invention relates to a method for preparing synthetic mineral particles with formula (AlyM1-y)2(SixGe1-x)2O5(OH)4, wherein M designates at least one trivalent metal selected from the group made up of gallium and the rare earths, which comprises the following steps: preparing a gel which is a precursor of said synthetic mineral particles by a co-precipitation reaction of at least one salt of metal selected among aluminium and M with at least one silicon source selected from the group made up of potassium metasilicate, sodium metasilicate, potassium metagermanate and sodium metagermanate, the molar ratio of (AlyM1-y) to (SixGe1-x) during the preparation of said precursor gel being equal to 1, at least one base being added during said co-precipitation reaction; and performing a solvothermal treatment of said precursor gel at a temperature of 250° C. to 600° C.
    Type: Grant
    Filed: September 27, 2016
    Date of Patent: June 7, 2022
    Assignees: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, UNIVERSITE PAUL SABATIER TOULOUSE III
    Inventors: François Martin, Christophe Le Roux, Pierre Micoud, Marie Claverie, Cyril Aymonier
  • Patent number: 11344934
    Abstract: A method for harmlessly pretreating an organic solid waste based on combination of calcium ion and hydrothermal treatment, including: preliminarily screening the organic solid waste followed by addition of calcium ions and hydrothermal treatment to make the organic solid waste harmless.
    Type: Grant
    Filed: December 29, 2021
    Date of Patent: May 31, 2022
    Assignee: Tongji University
    Inventors: Xiaohu Dai, Yu Hua
  • Patent number: 11332847
    Abstract: The present invention relates to solvothermal vapor synthesis methods for the crystallization of a phase from a mixture of selected inorganic or organic precursors in an unsaturated vapor-phase reaction medium.
    Type: Grant
    Filed: December 29, 2016
    Date of Patent: May 17, 2022
    Assignee: RUTGERS, THE STATE UNIVERSITY OF NEW JERSEY
    Inventors: Richard E. Riman, Daniel Kopp
  • Patent number: 11286384
    Abstract: The present invention, in an aspect, provides a resin composition that contains a vinyl polymer and a smectite with partially immobilized lithium.
    Type: Grant
    Filed: March 14, 2018
    Date of Patent: March 29, 2022
    Assignees: DIC Corporation, National Institute of Advanced Industrial Science and Technology
    Inventors: Yusaku Goto, Tomoki Dohi, Michiya Nakashima, Yusho Usami, Takeo Ebina, Ryo Ishii, Takafumi Aizawa
  • Patent number: 11279624
    Abstract: A method for producing forsterite microparticles having a primary particle size of 1, to 50 nm, as determined through electron microscopy. The method includes spray-drying, in an atmosphere of 50° C. or higher and lower than 300° C., a solution containing a water-soluble magnesium salt and colloidal silica at a mole ratio of magnesium atoms to silicon atoms (Mg/Si) of 2; and subsequently, firing the spray-dried product in air at 800 to 1,000° C.
    Type: Grant
    Filed: April 25, 2018
    Date of Patent: March 22, 2022
    Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.
    Inventors: Tadayuki Isaji, Takashi Ogihara, Takayuki Kodera
  • Patent number: 11114654
    Abstract: Disclosed are a negative electrode active material including lithium titanium oxide particles, wherein the lithium titanium oxide particles have an average particle diameter (D50) of 0.5-9 ?m, a specific surface area of 3-7 m2/g, and a pellet density of 1.7 g/cc or more under a pressure of 64 MPa, and a lithium secondary battery including the same.
    Type: Grant
    Filed: March 21, 2018
    Date of Patent: September 7, 2021
    Assignee: LG CHEM, LTD.
    Inventors: Bo-Ram Lee, Sung-Bin Park, Ji-Young Park, Chi-Ho Jo, Jung-Min Han, Hyuck Hur, Wang-Mo Jung
  • Patent number: 10882752
    Abstract: The present invention relates to a low-temperature/atmospheric-pressure method for producing synthetic hectorite and synthetic hectorite produced using the same, and more particularly, provides a method for producing synthetic hectorite at a low temperature and atmospheric pressure and synthetic hectorite produced using the same such that: a crystallization reaction may be carried out under a low-temperature/atmospheric-pressure condition by introducing a step of forming a precipitate and using a weak basic catalyst when the Li—Mg precipitates are formed; a reaction time may be reduced; synthetic hectorite with excellent major application properties may be prepared; and the properties may be easily controlled by controlling a composition ratio of a reactant.
    Type: Grant
    Filed: September 29, 2017
    Date of Patent: January 5, 2021
    Assignee: LG CHEM, LTD.
    Inventors: Jong Hun Kim, Je Kyun Lee
  • Patent number: 10626052
    Abstract: The invention provides novel, microstructured clinker and cement materials that are characterized by superior grindability and reactivity. The disclosed clinker and cement materials are based on carbonatable calcium silicate and can be made from widely available, low cost raw materials via a process suitable for large-scale production. The method of the invention is flexible in equipment and processing requirements and is readily adaptable to manufacturing facilities of conventional Portland cement.
    Type: Grant
    Filed: February 12, 2018
    Date of Patent: April 21, 2020
    Assignees: SOLIDIA TECHNOLOGIES, INC., HOLCIM TECHNOLOGY LTD.
    Inventors: Sadananda Sahu, Sean Quinn, Vahit Atakan, Nicholas DeCristofaro, Vincent Meyer, Cédric Comparet, Günther Walenta
  • Patent number: 10517825
    Abstract: Provided is a powder composition containing an oily substance, the powder composition having good oxidation stability and excellent compression moldability. The powder composition containing an oily substance contains a powdery calcium silicate-based material, and an oily substance impregnated into the material. In the material, a cumulative pore volume for a pore size of 10 to 70 nm is 1.1 cc/g or more, and a cumulative pore volume for a pore size of 70 to 500 nm is 2.0 cc/g or less.
    Type: Grant
    Filed: May 27, 2016
    Date of Patent: December 31, 2019
    Assignee: TOMITA PHARMACEUTICAL CO., LTD.
    Inventors: Takanori Taniwaki, Kazuki Kamai, Yuuta Tsumura, Daichi Masaki
  • Patent number: 10406083
    Abstract: A cosmetic having excellent properties in transparency, spreadability, smoothness, skin compatibility and safety is prepared using a synthetic talc that is flake-like particles containing 2:1-type laminar crystals of silicate which have a basic structure of an octahedron sheet sandwiched between two tetrahedron sheets. The flake-like particle has a mean volume particle diameter of 0.5 to 100 ?m, and 0.3° or less of half width at half maximum of peak present at 2? equal to 9.4°±1° when measured by unoriented powder X-ray diffractometry (XRD) using CuK? rays, and the cosmetic is substantially free of Mg3Si2O5(OH)4.
    Type: Grant
    Filed: January 28, 2016
    Date of Patent: September 10, 2019
    Assignee: JO Cosmetics Co., Ltd.
    Inventor: Hiroko Kimura
  • Patent number: 10196325
    Abstract: The present invention relates to a multistage process and catalyst system therefor to convert syngas to aromatics. In a first stage, syngas is converted to a C1-C4 alcohol mixture by contacting syngas with a first catalyst comprising rhodium or copper at moderate temperature. In a second stage, the C1-C4 alcohol mixture is converted into an aromatic product by contact with a second catalyst comprising a molecular sieve and at least one Group 8-14 element, the molecular sieve having a Constraint Index about 1 to 12 and a silica to alumina ratio of about 10 to 100 at effective conversion conditions. The final aromatic product is rich in benzene, toluene, and xylenes (e.g. greater than 50% aromatics on a hydrocarbon basis).
    Type: Grant
    Filed: December 10, 2015
    Date of Patent: February 5, 2019
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Nikolaos Soultanidis, Mayank Shekhar, John S. Coleman
  • Patent number: 10155665
    Abstract: Methods are provided for synthesis of various types of zeolites using synthesis mixtures that contain a dominant structure directing agent and one or more secondary structure directing agents. Advantageously, the secondary structure directing agents may substantially not alter the crystal structure and/or morphology of the crystals generated by a synthesis mixture in the presence of the dominant structure directing agent.
    Type: Grant
    Filed: October 20, 2015
    Date of Patent: December 18, 2018
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Wenyih Frank Lai, Nicholas S. Rollman, Jenna L. Walp, William W. Lonergan
  • Patent number: 10016747
    Abstract: Methods are provided for using a dewaxing catalyst formed using at least two structure directing agents for production of a lubricant base stock. For example, ZSM-48 crystals formed using multiple directing agents (and/or formulated catalysts made using such crystals) can have an increased activity and/or can provide an improved yield during catalytic production of lubricant base stocks. Additionally or alternately, ZSM-48 crystals formed using multiple directing agents (and/or formulated catalysts made using such crystals) can provide improved aromatic saturation during processing of a feed for lubricant base stock production.
    Type: Grant
    Filed: October 20, 2015
    Date of Patent: July 10, 2018
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Lei Zhang, Sylvain Hantzer, Wenyih F. Lai, Stephen J. McCarthy, Tracie L. Owens
  • Patent number: 9988278
    Abstract: A method for producing forsterite microparticles having a primary particle size of 1 to 200 nm, as determined through electron microscopy, characterized in that the method includes spray-drying, at 50° C. or higher and lower than 300° C., a solution containing a water-soluble magnesium salt and colloidal silica at a mole ratio of magnesium atoms to silicon atoms (Mg/Si) of 2; and subsequently, firing the spray-dried product in air at 800 to 1,000° C.
    Type: Grant
    Filed: March 24, 2015
    Date of Patent: June 5, 2018
    Assignee: NISSAN CHEMICAL INDUSTRIES, LTD.
    Inventors: Tadayuki Isaji, Takashi Ogihara, Takayuki Kodera
  • Patent number: 9926235
    Abstract: The invention provides novel, microstructured clinker and cement materials that are characterized by superior grindability and reactivity. The disclosed clinker and cement materials are based on carbonatable calcium silicate and can be made from widely available, low cost raw materials via a process suitable for large-scale production. The method of the invention is flexible in equipment and processing requirements and is readily adaptable to manufacturing facilities of conventional Portland cement.
    Type: Grant
    Filed: March 18, 2016
    Date of Patent: March 27, 2018
    Assignees: Solidia Technologies, Inc., LAFARGE
    Inventors: Sadananda Sahu, Sean Quinn, Vahit Atakan, Nicholas DeCristofaro, Vincent Meyer, Cédric Comparet, Günther Walenta
  • Patent number: 9802830
    Abstract: A family of new crystalline molecular sieves designated SSZ-91 is disclosed. Molecular sieve SSZ-91 is structurally similar to sieves falling within the ZSM-48 family of molecular sieves, and is characterized as: (1) having a low degree of faulting, (2) a low aspect ratio that inhibits hydrocracking as compared to conventional ZSM-48 materials having an aspect ratio of greater than 8, and (3) is substantially phase pure.
    Type: Grant
    Filed: August 27, 2015
    Date of Patent: October 31, 2017
    Assignee: Chevron U.S.A. Inc.
    Inventors: Adeola Florence Ojo, Dan Xie, Yihua Zhang, Guan-Dao Lei
  • Patent number: 9340465
    Abstract: An alkali metal ion source with a moderate rate of release of the ion (e.g. potassium) is formed by a method that includes: 1) combining an particulate ore that contains at least one of an alkali metal ion-bearing framework silicate (e.g. syenite ore) with at least one of an oxide and hydroxide of at least one of an alkali metal and alkaline earth metal such as calcium hydroxide; 2) milling the mixture of these two components optionally, with water, optionally, milling the dry components separately and blended thereafter, optionally, with water; 3) forming a mixture by adding water to the solid mixture after milling, if water was not added before milling; 4) exposing the mixture to an elevated temperature and pressure to form a gel that includes silica and the alkali metal of the framework silicate.
    Type: Grant
    Filed: May 6, 2014
    Date of Patent: May 17, 2016
    Assignee: Massachusetts Institute of Technology, Inc.
    Inventors: Taisiya Skorina, Antoine Allanore
  • Patent number: 9293446
    Abstract: A low profile module is provided that has a high functionality achieved by increasing the component mounting density. In spite of achieving high functionality in a module 100 by respectively mounting components such as a semiconductor substrate 104 and chip components 105 on the two main surfaces 101a and 101b of a wiring substrate 101, the low-profile module 100 can be provided which has a high functionality as a result of increasing its component mounting density by forming a thickness Ha of a first component layer 102 formed by mounting only the semiconductor substrate 104 face down on one main surface 101a of the wiring substrate 101 so as to be smaller than the thickness of a second component layer 103 formed by mounting a plurality of chip components 105 on the other main surface 101b of the wiring substrate 101.
    Type: Grant
    Filed: January 23, 2015
    Date of Patent: March 22, 2016
    Assignee: MURATA MANUFACTURING CO., LTD.
    Inventors: Mitsuhiro Matsumoto, Yoichi Takagi, Tadashi Nomura, Akihiko Kamada, Nobuaki Ogawa, Kensei Nishida
  • Patent number: 8980330
    Abstract: Provided is a method that enables a calcium silicate-based material to be produced more efficiently. The method of producing a calcium silicate-based material comprises: (1) a step of obtaining a reaction product by reacting raw materials containing a calcium component, a silicon component and an aluminum component in an aqueous medium; and (2) a step of forming calcium silicate by subjecting the reaction product to hydrothermal treatment.
    Type: Grant
    Filed: February 27, 2013
    Date of Patent: March 17, 2015
    Assignee: Tomita Pharmaceutical Co., Ltd.
    Inventors: Koh Konishi, Yuta Tsumura, Seiki Shinomiya, Masashi Konishi, Yukinori Konishi
  • Patent number: 8961821
    Abstract: A process of treating a gas stream containing mercury and acid gas pollutants is disclosed. The process includes applying a sorbent composition into a gas stream in order to adsorb mercury containing compounds and acid gas pollutants. The sorbent composition includes a compound having the formula (SiO2)x(OH)yMzSaF.B. The combination of basic inorganic solids for the adsorption of acid gases, and metal sulfide-doped silica for the adsorption of mercury provides dual sorbent functionality, along with additional benefits for each individual sorbent: silica for moisture retention on the surface of the basic inorganic particle and adsorption of acid gas, which will improve metal sulfide performance at higher operating temperatures. The use of a hygroscopic solid effectively dries the metal sulfide-doped silica slurry without the use of filtration of drying equipment, providing significant economic benefit for the manufacture of metal sulfide-doped silica material.
    Type: Grant
    Filed: November 25, 2013
    Date of Patent: February 24, 2015
    Assignee: Ecolab USA Inc.
    Inventors: Nicholas S. Ergang, Ian Saratovsky, Tommy Chen
  • Patent number: 8916121
    Abstract: The present invention is directed to a process for the treatment of talc, comprising the steps of (a) providing a talc having a first brightness value B1, measured according to ISO 2469, and forming a suspension of the talc in a liquid phase, the liquid phase of the suspension comprising at least one organic solvent, (b) delaminating and/or reducing the weight median particle size d50 of the talc, wherein the treated talc has a brightness value B2, measured according to ISO 2469, and B2?B1.
    Type: Grant
    Filed: May 27, 2008
    Date of Patent: December 23, 2014
    Assignee: Mondo Minerals B.V.
    Inventors: Patrick A. C. Gane, Daniel Gantenbein, Joachim Schoelkopf
  • Patent number: 8894888
    Abstract: A conductive paste composition contains a source of an electrically conductive metal, a fusible material, a synthetic clay additive, and an optional etchant additive, dispersed in an organic medium. An article such as a photovoltaic cell is formed by a process having the steps of deposition of the paste composition on a semiconductor substrate by a process such as screen printing and firing the paste to remove the organic medium and sinter the metal and fusible material. The synthetic clay additive aids in establishing a low resistance electrical contact between the front side metallization and underlying semiconductor substrate during firing.
    Type: Grant
    Filed: December 21, 2011
    Date of Patent: November 25, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Steven Dale Ittel, John Graeme Pepin
  • Publication number: 20140291712
    Abstract: A phosphor and a light emitting device are provided. The phosphor comprises a composition having a formula of (BaaSr1-a)2-zSi5ObNn:EuZ, 0.03<a<0.75, 0<b<1, 7<n<9, and 0.03<z<0.3.
    Type: Application
    Filed: November 12, 2013
    Publication date: October 2, 2014
    Applicant: Chi Mei Corporation
    Inventors: Yuan-Ren Juang, Jen-Shrong Uen
  • Publication number: 20140205528
    Abstract: A process for preparing a composition including synthetic mineral particles, in which a hydrogel which is a precursor of the synthetic mineral particles is prepared via a coprecipitation reaction between at least one compound including silicon, and at least one compound including at least one metal element, characterized in that the coprecipitation reaction takes place in the presence of at least one carboxylate salt of formula R2—COOM? in which: —M? denotes a metal chosen from the group made up of Na and K, and —R2 is chosen from H and alkyl groups including fewer than 5 carbon atoms. A composition including synthetic mineral particles which is obtained by such a process is also described.
    Type: Application
    Filed: July 6, 2012
    Publication date: July 24, 2014
    Applicants: UNIVERSITE PAUL SABATIER (TOULOUSE III), CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.)
    Inventors: Christophe Le Roux, Francois Martin, Pierre Micoud, Angela Dumas
  • Patent number: 8765163
    Abstract: The present invention relates to a biocompatible ceramic material comprising Sr, Mg or Ba doped Hardystonite (Ca2ZnSi2O7), and a method for its synthetic preparation. The present invention also relates to an implantable medical device comprising biocompatible doped Hardystonite, and a method for its production. The present invention further relates to a method for improving the long term stability of an implantable medical device and an implantable drug delivery device comprising doped Hardystonite. Further, the present invention relates to the use of comprising biocompatible doped Hardystonite in the regeneration or resurfacing of tissue.
    Type: Grant
    Filed: July 10, 2009
    Date of Patent: July 1, 2014
    Assignee: The University of Sydney
    Inventors: Hala Zreiqat, Chengtie Wu, Colin Dunstan
  • Patent number: 8734680
    Abstract: There are provide a silicate-based phosphor excellent in emission intensity and a manufacturing method of the same. A manufacturing method of a silicate-based phosphor is characterized by: introducing in a vessel raw material powders having a compound containing light-emitting ions selected from at least one of Eu, Ce, Mn, and Tb; and firing the raw material powders while supplying SiOx (0.5?x?1.9, preferably, 0.8?x?1.2) in a gas phase. The raw material powders preferably further contains at least one of an alkali metal compound, an alkaline-earth metal compound, a magnesium compound, and a rare-earth compound. The silicate-based phosphor is preferably M2SiO4:Eu2+ (wherein M is one or more selected from a group consisting of Ca, Sr and Ba). The firing is preferably performed by supplying the SiOx to the raw material powders in a gas atmosphere at a temperature of 1200 to 1700° C. and subjecting the raw material powders to a gas-solid phase reaction at a temperature of 700 to 1700° C.
    Type: Grant
    Filed: April 12, 2011
    Date of Patent: May 27, 2014
    Assignees: Lead Chemical Company, Limited, Niigata University
    Inventors: Kenji Toda, Mineo Sato, Kazuyoshi Uematsu, Tadashi Ishigaki, Hideo Suda, Etsuko Minegishi, Yoshiaki Kudo
  • Patent number: 8716164
    Abstract: This invention is directed to hydrodemetallization catalysts and hydrodemetallization processes employing a magnesium aluminosilicate clay. The magnesium aluminosilicate clay has a characteristic 29Si NMR spectrum. The magnesium aluminosilicate clay is the product of a series of specific reaction steps. Briefly, the magnesium aluminosilicate clay employed in the catalyst and process of the invention is made by combining a silicon component, an aluminum component, and a magnesium component, under aqueous conditions and at an acidic pH, to form a first reaction mixture and subsequently the pH of the first reaction mixture is adjusted to greater than about 7.5 to form a second reaction mixture. The second reaction mixture is allowed to react under conditions sufficient to form the magnesium aluminosilicate clay. The resulting magnesium aluminosilicate clay combines high surface area and activity for use in hydrodemetallization catalysts and processes.
    Type: Grant
    Filed: September 19, 2011
    Date of Patent: May 6, 2014
    Assignee: Chevron U.S.A. Inc.
    Inventors: Christopher J. Dillon, Theodorus Maesen, Alexander E. Kuperman
  • Publication number: 20140120022
    Abstract: A process for the mineralization of carbon dioxide to form a magnesium carbonate compound, which process includes contacting the carbon dioxide, in the free form, or in the form of an alkali metal carbonate or bicarbonate, with an alkali metal magnesium silicate to produce the magnesium carbonate compound.
    Type: Application
    Filed: June 4, 2012
    Publication date: May 1, 2014
    Applicant: LAFARGE
    Inventors: Ellis Gartner, Alexander Pisch
  • Publication number: 20140097385
    Abstract: The invention relates to an inorganic scintillator material of formula Lu(2-y)Y(y-z-x)CexMzSi(1-v)M?vO5, in which: M represents a divalent alkaline earth metal and M? represents a trivalent metal, (z+v) being greater than or equal to 0.0001 and less than or equal to 0.2; z being greater than or equal to 0 and less than or equal to 0.2; v being greater than or equal to 0 and less than or equal to 0.2; x being greater than or equal to 0.0001 and less than 0.1; and y ranging from (x+z) to 1. In particular, this material may equip scintillation detectors for applications in industry, for the medical field (scanners) and/or for detection in oil drilling. The presence of Ca in the crystal reduces the afterglow, while stopping power for high-energy radiation remains high.
    Type: Application
    Filed: September 27, 2013
    Publication date: April 10, 2014
    Applicant: SAINT-GOBAIN CRISTAUX ET DETECTEURS
    Inventors: Bernard FERRAND, Bruno VIANA, Ludivine PIDOL, Pieter DORENBOS
  • Patent number: 8691172
    Abstract: High temperature fusion of olivine to produce forsterite in the presence of a reducing agent such as carbon can produce improved refractories when in addition to MgO additional, particular oxidation and/or oxidative reaction environments beyond the use of Carbon are employed.
    Type: Grant
    Filed: February 25, 2009
    Date of Patent: April 8, 2014
    Assignee: KBI Enterprises, LLC
    Inventors: Dale F. DeSanto, Robert A. Pattillo
  • Patent number: 8679547
    Abstract: Provided is a method that enables a calcium silicate-based material to be produced more efficiently. The method of producing a calcium silicate-based material comprises: (1) a step of obtaining a reaction product by reacting raw materials containing a calcium component, a silicon component and an aluminum component in an aqueous medium; and (2) a step of forming calcium silicate by subjecting the reaction product to hydrothermal treatment.
    Type: Grant
    Filed: October 20, 2011
    Date of Patent: March 25, 2014
    Assignee: Tomita Pharmaceutical Co., Ltd.
    Inventors: Koh Konishi, Yuta Tsumura, Seiki Shinomiya, Masashi Konishi, Yukinori Konishi
  • Patent number: 8652430
    Abstract: The present invention provides an organic dispersion of inorganic platelets, which includes an organic solvent and H-form inorganic platelets dispersed therein. The H-form inorganic platelets have a particle size of between about 20 and 80 mm and the organic dispersion has a sold content of between about 1 and 20 wt %. A method for forming the organic dispersion is also provided.
    Type: Grant
    Filed: September 12, 2011
    Date of Patent: February 18, 2014
    Assignee: Industrial Technology Research Institute
    Inventors: Chih-Jen Yang, Chyi-Ming Leu, Chun-Wei Su
  • Publication number: 20140044637
    Abstract: A method of pre treating lizardite for use in the mineral sequestration of carbon dioxide, the method including heating the lizardite at a temperature of less than 600° C. until the lizardite contains between about 10% to about 40% residual hydroxyls.
    Type: Application
    Filed: November 25, 2011
    Publication date: February 13, 2014
    Inventors: Bogdan Z. Dlugogorski, Reydick Balucan, Eric M. Kennedy
  • Patent number: 8621889
    Abstract: The invention relates to a process for manufacturing compounds based on one or more silicates of alkali metals and/or of alkaline-earth metals, optionally in the form of mixed silicates that combine at least two of these elements, said process involving: (i) preferably a conversion reaction (1) in which halides of said alkali metals and/or of said rare earths and/or of said alkaline-earth metals are converted into the corresponding sulfates; (iii) a conversion reaction (2) in which said sulfates together with silica are converted into the corresponding silicates, the heat supply needed for this conversion being provided, at least in part, by a combustion reaction (3) using a submerged burner or a plurality of submerged burners.
    Type: Grant
    Filed: September 29, 2008
    Date of Patent: January 7, 2014
    Assignee: Saint-Gobain Glass France
    Inventors: Pierre Jeanvoine, Arnaud Le Verge
  • Publication number: 20130343980
    Abstract: A method for preparing a composition including synthetic mineral particles, in which: a hydrogel that is a precursor of the synthetic mineral particles is prepared, and the hydrogel is subjected to a hydrothermal treatment, characterized in that at least one step of the hydrothermal treatment is carried out with the addition of at least one carboxylate salt to the treatment medium, the carboxylate salt having the formula R—COOM?, where M? denotes a metal selected from the group consisting of Na and K, and R is selected from H and the alkyl groups that include fewer than 10 carbon atoms.
    Type: Application
    Filed: December 22, 2011
    Publication date: December 26, 2013
    Applicants: CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (C.N.R.S.), UNIVERSITE PAUL SABATIER TOULOUSE III
    Inventors: Christophe Le Roux, Francois Martin, Pierre Micoud, Angela Dumas
  • Publication number: 20130340650
    Abstract: Plant and process for cement clinker production includes preheating a raw meal, a calcination step where the raw meal is brought to a temperature of about 800-850° C. to substantially decompose its mineral constituents into their oxides, and a sintering step where the load is brought to a temperature of 1300 to 1450° C. to form Ca2SiO4 (or (CaO)2.SiO2), to further decompose calcium carbonate and partially melt the load to form Ca3.SiO5 (or (CaO)3.SiO2) in a rotarykiln, followed by cooling the resulting clinker, and optionally milling it, wherein untreated oil sludge is supplied into an injection zone of the calcination zone operated at a material temperature of approx. 800-850° C., the injection zone including the bottom discharge of the lowest cyclone stages and/or of the precalciner, if appropriate, the feed-in slope of the rotary kiln and the gas phase over the mineral bed at the material inlet end of the rotary kiln.
    Type: Application
    Filed: June 20, 2013
    Publication date: December 26, 2013
    Inventors: Christian Meyers, Hans Ericsson
  • Publication number: 20130288312
    Abstract: Disclosed is a treatment method of biomass to maximize sugar yield, which uses a specific additive which can effectively adsorb lignin-derived compounds and various inhibitors of the enzymatic activity to promote saccharification of cellulose catalyzed by cellulose hydrolases, and thus can maximize sugar yield from pretreated biomass.
    Type: Application
    Filed: December 23, 2011
    Publication date: October 31, 2013
    Applicant: KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY
    Inventors: Ju Hyun Yu, Chan Duck Jung, In Yong Eom, Kyung Sik Hong, Bong Keun Song
  • Patent number: 8563456
    Abstract: This invention is directed to hydrodemetallization catalysts and hydrodemetallization processes employing a magnesium aluminosilicate clay. The magnesium aluminosilicate clay has a characteristic 29Si NMR spectrum. The magnesium aluminosilicate clay is the product of a series of specific reaction steps. Briefly, the magnesium aluminosilicate clay employed in the catalyst and process of the invention is made by combining a silicon component, an aluminum component, and a magnesium component, under aqueous conditions and at an acidic pH, to form a first reaction mixture and subsequently the pH of the first reaction mixture is adjusted to greater than about 7.5 to form a second reaction mixture. The second reaction mixture is allowed to react under conditions sufficient to form the magnesium aluminosilicate clay. The resulting magnesium aluminosilicate clay combines high surface area and activity for use in hydrodemetallization catalysts and processes.
    Type: Grant
    Filed: October 3, 2008
    Date of Patent: October 22, 2013
    Assignee: Chevron U.S.A. Inc.
    Inventors: Christopher J. Dillon, Theodorus Maesen, Alexander E. Kuperman
  • Publication number: 20130194348
    Abstract: The present invention provides an image forming method and an ink composition whereby deterioration of a head plate, which is formed of silicon, is suppressed, and an image with higher precision is formed stably, the ink composition including an inorganic silicate compound and being ejected to form an image from an ink-jet head having a nozzle plate where a C8F17C2H4SiCl3 film (fluorocarbon film) is provided on the surface thereof at a side toward the ink ejection direction of a nozzle.
    Type: Application
    Filed: March 12, 2013
    Publication date: August 1, 2013
    Applicant: FUJIFILM CORPORATION
    Inventor: FUJIFILM CORPORATION
  • Patent number: 8496897
    Abstract: A carbon dioxide sequestration process includes the following steps. In a first stage, a slurry of a metal silicate rock is mixed with ammonia so as to produce a ammonia/water/metal silicate slurry. In a second stage, the process includes scrubbing a gas stream containing carbon dioxide with the solution from the first stage to thereby absorb the carbon dioxide into a reactive slurry. In a third stage, the reactive slurry from the second stage is passed through a reactor that is controlled so as to promote the reaction between the carbon dioxide and the metal silicate to thereby produce a metal carbonate.
    Type: Grant
    Filed: February 20, 2008
    Date of Patent: July 30, 2013
    Inventor: Richard J Hunwick
  • Patent number: 8444946
    Abstract: The invention relates to a method for preparing a composition, that is a talcose composition, comprising synthetic mineral particles which contain silicon, germanium and metal, have a crystalline and lamellar structure, and are of formula (SixGe1?x)4M3O10(OH)2, wherein M is at least one divalent metal and is of formula Mgy(1)COy(2)Zny(3)Cuy(4)Mny(5)Fey(6)Niy(7)Cry(8), and x is a real number of the interval [0; 1]. According to said method, a gel containing silicon, germanium and metal, of formula —(SixGe1?x)4M3O11, n?H2O—, in the liquid state, is subjected to a hydrothermal treatment over a defined period of time and at a temperature of between 300° C. and 600° C., said time and temperature being selected according to the desired particle size and structural stability for the mineral particles containing silicon, germanium and metal, to be prepared.
    Type: Grant
    Filed: July 13, 2007
    Date of Patent: May 21, 2013
    Assignees: Imerys Talc Europe, Centre National de la Recherche Scientifique (C.N.R.S.)
    Inventors: Francois Martin, Jocelyne Ferret, Cedric Lebre, Sabine Petit, Olivier Grauby, Jean-Pierre Bonino, Didier Arseguel, Alain Decarreau, Eric Ferrage
  • Publication number: 20130101685
    Abstract: Provided is a method that enables a calcium silicate-based material to be produced more efficiently. The method of producing a calcium silicate-based material comprises: (1) a step of obtaining a reaction product by reacting raw materials containing a calcium component, a silicon component and an aluminum component in an aqueous medium; and (2) a step of forming calcium silicate by subjecting the reaction product to hydrothermal treatment.
    Type: Application
    Filed: October 20, 2011
    Publication date: April 25, 2013
    Applicant: TOMITA PHARMACEUTICAL CO., LTD.
    Inventors: Koh Konishi, Yuta Tsumura, Seiki Shinomiya, Masashi Konishi, Yukinori Konishi
  • Publication number: 20130078519
    Abstract: A production process for lithium-silicate-based compound according to the present invention is characterized in that: a lithium-silicate compound being expressed by Li2SiO3 is reacted with a transition-metal-element-containing substance including at least one member being selected from the group consisting of iron and manganese at 550° C. or less within a molten salt including at least one member being selected from the group consisting of alkali-metal nitrates as well as alkali-metal hydroxides in an atmosphere in the presence of a mixed gas including carbon dioxide and a reducing gas. In accordance with the present invention, it is possible to produce lithium-silicate-based materials, which are useful as a positive-electrode active material for lithium-ion secondary battery, and the like, at low temperatures by means of relatively easy means.
    Type: Application
    Filed: June 17, 2011
    Publication date: March 28, 2013
    Applicants: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY, KABUSHIKI KAISHA TOYOTA JIDOSHOKKI
    Inventors: Toshikatsu Kojima, Takuhiro Miyuki, Tetsuo Sakai, Akira Kojima, Junichi Niwa, Hitotoshi Murase, Kazuhito Kawasumi
  • Publication number: 20130052116
    Abstract: Inclusion of a needle structured clay or the plate structured clay sodium montmorillonite in a chitosan film was found to reduce shrinkage of the film. The needle structured clay is purified and processed into a substantially dispersed form by subjecting an aqueous slurry of the clay with water-soluble phosphate dispersant to a high pressure, high shear mixing process or to sonication. Laminates fabricated from chitosan film including dispersed clay can be used in make a variety of finished articles that can be used to provide protection from hazardous chemical and biological agents.
    Type: Application
    Filed: September 14, 2012
    Publication date: February 28, 2013
    Inventors: Nathaniel A. Barney, Mark Gary Weinberg, Bryan Benedict Sauer
  • Patent number: 8377194
    Abstract: A silica-containing composition is disclosed. The composition comprises a compound having the following formula: (SiO2)x(OH)yMzSaF.B. M comprises at least one metal or metalloid cation S is a sulfur-based species. F optionally exists and F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of about 0.01 to about 100%. The molar ratio of y/x is equal to about 0.01 to about 0.5, the molar ratio of x/z is equal to about 0.5 to about 300 or from about 0.5 to about 100, and the molar ratio of a/z is about 0.5 to about 5. B is a hygroscopic solid at a water to solid molar ratio of 0.1-6 and preferably comprises at least one alkaline earth oxide or lanthanide oxide.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: February 19, 2013
    Assignee: Nalco Company
    Inventors: Nicholas S. Ergang, Ian Saratovsky, Hung-Ting Chen
  • Patent number: 8333835
    Abstract: A silica-containing composition is disclosed. The composition comprises a compound having the following formula: (SiO2)x(OH)yMzSaF. M comprises at least one metal or metalloid cation S is a sulfur-based species optionally exists and F is at least one of the following: a functionalized organosilane, a sulfur-containing organosilane, an amine-containing organosilane, and an alkyl-containing organosilane at a surface area coverage of about 0.01 to about 100%. The molar ratio of y/x is equal to about 0.01 to about 0.5, the molar ratio of x/z is equal to about 0.5 to about 300 or from about 0.5 to about 100, and the molar ratio of a/z is about 0.5 to about 5.
    Type: Grant
    Filed: September 23, 2011
    Date of Patent: December 18, 2012
    Assignee: Nalco Company
    Inventors: Nicholas S. Ergang, Bruce A. Keiser, Richard Mimna
  • Publication number: 20120288431
    Abstract: Increasing the activity of a hydrous magnesium silicate with respect to sequestration of carbon dioxide by mineral carbonation includes rapid heating of the hydrous magnesium silicate. Rapid heating of the hydrous magnesium silicate includes heating a quantity of particles of hydrous magnesium silicate with flame conditions to substantially dehydroxylate the particles. The dehydroxylated particles can be contacted with carbon dioxide in a sequestration process to form magnesium carbonate.
    Type: Application
    Filed: September 16, 2010
    Publication date: November 15, 2012
    Inventors: Andrew V.G. Chizmeshya, Geoffrey Frederick Brent
  • Patent number: 8268286
    Abstract: Disclosed herein is a spinel article. The article comprises a spinel material, wherein the spinel material has a monomodal grain size distribution with average grain sizes of less than or equal to about 15 micrometers, and a biaxial flexural strength of greater than or equal to about 300 megapascals when measured by a ring-on-ring flexural test as per ASTM Standard C1499-08. Disclosed herein too is a spinel article manufactured by a method comprising calcining a spinel powder; milling the powder in a milling medium; granulating the powder; screening the powder to a mesh size of about 40 to about 200 mesh; pressing the powder to form an article; burning out organics from the article; sintering the article; and hot isostatically pressing the article.
    Type: Grant
    Filed: November 6, 2008
    Date of Patent: September 18, 2012
    Assignee: General Electric Company
    Inventors: Milivoj Konstantin Brun, Anteneh Kebbede, Sean Michael Sweeney, Timothy James Yosenick
  • Patent number: 8202501
    Abstract: The invention relates to a method for preparing a synthetic talc composition. According to said method, a kerolite composition is subjected to an anhydrous thermal treatment carried out at a pressure lower than 5 bar, from over a few hours up to over a few days, at a treatment temperature higher than 300° C. The invention also relates to a synthetic talc composition prepared in this way, the synthetic talc particles of the composition being exclusively of chemical formula —(Si4)Mg3O10(OH)2— and identifiable, during X-ray diffraction, by the presence of a characteristic diffraction peak located at a distance of between 9.40-9.68 and corresponding to a plane (001). Said synthetic talc particles also have a thermally stable crystalline structure of stacked laminae, which is very similar to that of a natural talc and has a particle size smaller than approximately ten micrometers.
    Type: Grant
    Filed: July 13, 2007
    Date of Patent: June 19, 2012
    Assignees: Luzenac Europe SAS, Centre National de la Recherche Scientifique (C.N.R.S.)
    Inventors: Francois Martin, Jocelyne Ferret, Cedric Lebre, Sabine Petit, Olivier Grauby, Jean-Pierre Bonino, Didier Arseguel, Alain Decarreau, Eric Ferrage
  • Publication number: 20120131973
    Abstract: A filter for treating CO2 from a CO2-emitting industrial plant, takes advantage of the fact that peridotite igneous rocks (or material of similar chemical content: basalt, gabbro, dunite, amphibolites, artificially produced Ca, Mg oxides) which are abundant on and close to the Earth's surface, can absorb and contain CO2 gases resultant from industrial activity. This chemical process occurs naturally, but has not been utilized to capture high concentrations of CO2 emitted into the atmosphere. Calcium and magnesium oxides of the peridotite react with CO2 to form stable carbonate minerals. The invention enhances and expedites this natural process for the remediation of industrial pollutants such as CO2 from the oil, gas, coal, cement/concrete and like CO2-emitting industries, and provides a resource for materials in construction (concrete), steel, aviation and agricultural and other industries.
    Type: Application
    Filed: November 28, 2011
    Publication date: May 31, 2012
    Inventors: Darius Greenidge, Jean Greenidge