By Precipitating Patents (Class 423/339)
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Publication number: 20110129401Abstract: A unique method for preparing precipitated silica entails reacting a silicate with an acidifying agent to obtain a suspension of precipitated silica, and separating and drying the suspension, and further wherein the precipitation includes contacting a silicate with an acidifying agent in an acidic medium in a fast blender.Type: ApplicationFiled: December 21, 2007Publication date: June 2, 2011Inventors: Elise Fournier, Jean-Claude Magne, Francois Nicol
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Patent number: 7887779Abstract: The disclosure pertains to a process for making anatase titanium dioxide particles, comprising: vigorously mixing (a) a volume of a first component comprising a major proportion of an alcohol, a minor proportion of a titanium alkoxide and a minor proportion of a titanium alkoxide activator selected from the group consisting of water and a first aqueous base, and (b) a second component selected from the group consisting of water and a second aqueous base, at least one of the first component or the second component having, a base therein, the second component being substantially free of alcohol, to form a mixture comprising a suspension of finely divided titanium (IV) oxide particles, the mixture having a water to titanium molar ratio ranging from about 40 to about 1 to about 5000 to about 1, wherein the proportion of the titanium alkoxide, the proportion of the activator, the mixing vigor, and a ratio of the volume of the first component to the second component are effective for the suspension of the finelyType: GrantFiled: December 20, 2007Date of Patent: February 15, 2011Assignee: E. I. du Pont de Nemours and CompanyInventors: David M. Scott, Carmine Torardi, Vladimir Grushin
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Publication number: 20110021801Abstract: The present invention relates to precipitated silicic acids, which have a particularly narrow particle size distribution in combination with a special pore size distribution, to a method for the production thereof, and to the use thereof as a filler for rubber mixtures.Type: ApplicationFiled: March 19, 2009Publication date: January 27, 2011Applicant: EVONIK DEGUSSA GmbHInventors: Andre Wehmeier, Oleg Stenzel, Weicheng Wu, Christian Goetz, Werner Niedermeier, Marinus Haddeman, Anke Blume
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Patent number: 7871588Abstract: Precipitated silica or silicates, obtainable by acid precipitation of aqueous silicate solutions while maintaining a constant alkali number of at least 1.Type: GrantFiled: February 22, 2002Date of Patent: January 18, 2011Assignee: Evonik Degussa GmbHInventors: Gottlieb-Georg Lindner, Robert Kuhlmann, Claus-Peter Drexel
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Patent number: 7858553Abstract: The disclosure relates to a process for making a surface treated suspension of finely divided titanium (IV) oxide particles, typically, finely divided titanium (IV) oxide nanoparticles, comprising: vigorously mixing (a) a volume of a first component comprising a major proportion of alcohol, a minor proportion of titanium alkoxide and a minor proportion of a titanium alkoxide activator selected from the group consisting of water and a first aqueous base, and b) a volume of a second component selected from the group consisting of water and a second aqueous base, at least one of the first component or the second component having a base therein, the second component being substantially free of alcohol, to form a mixture comprising a suspension of finely divided titanium (IV) oxide particle, the mixture having a water to titanium molar ratio ranging from about 40 to about 1 to about 5000 to about 1, wherein the proportion of the titanium alkoxide, the proportion of the activator, the mixing vigor, and the ratioType: GrantFiled: December 20, 2007Date of Patent: December 28, 2010Assignee: E.I. du Pont de Nemours and CompanyInventors: David M Scott, Carmine Torardi, Vladimir Grushin
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Patent number: 7855248Abstract: The present invention relates to a highly disperse precipitated silica which has a high surface area, to a process for preparing it, and to its use as a tire filler for commercial vehicles, motorbikes, and high-speed vehicles.Type: GrantFiled: July 23, 2003Date of Patent: December 21, 2010Assignee: Evonik Degussa GmbHInventors: Oleg Stenzel, Stefan Uhrlandt, Hans-Detlef Luginsland, André Wehmeier
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Publication number: 20100292386Abstract: Described herein is microporous precipitated silica having the following physico-chemical parameters: a CTAB surface area of 50 to 300 square meters/gram, a BET/CTAB ratio of ?1.3, and a relative breadth ? of pore size distribution of ?3.5. The precipitated silica can also have a Sears number of from 10 to 28 and a Sears number/CTAB ratio of ?0.16. Also described herein are vulcanizable and vulcanized elastomer compositions, e.g., tires, containing the microporous precipitated silica.Type: ApplicationFiled: May 3, 2010Publication date: November 18, 2010Applicant: PPG IDUSTRIES OHIO, I NC.Inventor: Timothy A. Okel
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Patent number: 7824644Abstract: There is provided particulate silica which can be suitably used as a viscoelasticity modifier such as a thickener which is added to liquid such as water, a liquid resin or paint to adjust its viscoelastic properties such as viscosity and thixotropic nature, a reinforcer or filler for silicone rubber or sealants, a polishing agent for CMP (Chemical Mechanical Polishing) or a surface coating agent for ink-jet printing paper. The particulate silica has a BET specific surface area S of 130 to 380 m2/g, and its fractal shape parameter ?1 in an ?-value analysis target range of 20 to 30 nm satisfies the following equation (1) and its fractal shape parameter ?2 in an ?-value analysis target range of 30 to 50 nm satisfies the following equation (2). ?1+0.00175S<2.518??(1) ?2+0.00174S<2.Type: GrantFiled: May 19, 2005Date of Patent: November 2, 2010Assignee: Tokuyama CorporationInventors: Yasuhiro Nagatani, Ryuji Ishimoto, Masao Ariyuki
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Publication number: 20100247415Abstract: A method of preferentially removing or recovering silica from a source, including aqueous sources such as ground and potable water, which utilizes a modified ion exchange material that holds or captures the silica by ion exchange with a metal contained in the exchange material whereby the method includes the steps of: providing an ion exchange material; immobilizing a metal complex to form at least a portion of a metal containing substance inside the ionic exchange material; and contacting the source with at least a portion of the metal containing ionic exchange material.Type: ApplicationFiled: March 26, 2009Publication date: September 30, 2010Inventors: Michael C Gottlieb, Peter S. Meyers
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Patent number: 7803343Abstract: New silica gel materials and novel methods of producing such are provided. The method itself entails a manner of mixing the reactants together in a one-pot process such that the time required for aging is reduced without compromising the ability to target pore size production. In such a way, the pH of the reaction drives pore size development, thereby permitting a more efficient process to be followed in terms of expensive drying/heating steps being reduced timewise, if not altogether. Furthermore, in one embodiment, the resultant gel materials exhibit a certain pore size minimum while simultaneously exhibiting a degree of softness heretofore unavailable. As such, not only is this novel method more efficient in silica gel manufacture, but the resultant materials are completely novel as well. The gel materials made therefrom may be utilized in a variety of different end uses, such as cooking oil filtration, soft skin cleansers, dental abrasives, and the like.Type: GrantFiled: June 27, 2007Date of Patent: September 28, 2010Assignee: J.M. Huber CorporationInventors: Duen-Wu Hua, Michael C. Withiam, Francis R. W. Godwin, Fitzgerald A. Sinclair
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Patent number: 7799304Abstract: The invention relates to a highly-structured precipitated silica having a low water uptake and high dispersibility in different pasty or solid matrices or media, elastomers or silicon, and to the preparation method thereof. The invention also relates to the use of said silica, for example, as a reinforcing filler in matrices based on elastomers (clear or semi-clear for shoe soles), in silicon matrices (in particular, for the coating of electric cables), as a filler and/or support and/or vehicle in different compositions (food compositions, cosmetic compositions, pharmaceutical compositions, compositions for the production of paints or paper, compositions for the production of porous membrane separators for batteries) or as a thickening agent in toothpastes.Type: GrantFiled: December 20, 2004Date of Patent: September 21, 2010Assignee: Rhodia ChimieInventors: Adrien Dromard, Yvonick Chevallier, Rémi Valero, Dominique Petit
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Patent number: 7794681Abstract: An efficient method for producing a silicon oxide powder at a low cost is provided. This method comprises the steps of heating a powder mixture of a silicon dioxide powder and a metal silicon powder to a temperature of 1,100 to 1,450° C. in an inert gas or under reduced pressure to generate silicon monoxide gas, and precipitating the silicon monoxide gas on a surface of a substrate to produce the silicon oxide powder, and in this method, the silicon dioxide powder has an average particle diameter of up to 1 ?m, and the metal silicon powder has an average particle diameter of 30 ?m.Type: GrantFiled: April 23, 2007Date of Patent: September 14, 2010Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Hirofumi Fukuoka, Mikio Aramata, Satoru Miyawaki
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Patent number: 7790138Abstract: The present invention relates to a process for preparing TiO2/SiO2 mixed oxides or the hydrates and/or oxide hydrates thereof comprised of 0.5 to 95 wt % SiO2 and the balance as TiO2, each referring to the completely calcined product, by using titanium alcoholates and aqueous silica sol. Moreover, the invention relates to the use of these mixed oxides as catalyst carriers.Type: GrantFiled: May 4, 2006Date of Patent: September 7, 2010Assignee: Sasol Germany GmbHInventors: Jurgen Schimanski, Kai Dallmann, Sohnke Rolfs, Kai Dolling, Andrea Brasch, Ute Freese
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Patent number: 7767180Abstract: Precipitated silicas having an SiOHisolated absorbance ratio of greater than or equal to 1, may be used as reinforcers and thickeners for sealants.Type: GrantFiled: May 29, 2007Date of Patent: August 3, 2010Assignee: Degussa GmbHInventors: Christian Panz, Helga Obladen, Rene Allerdisse, Karl Meier, Markus Ruf, Michael Kempf, Mario Scholz, Dieter Kuhn
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Patent number: 7763564Abstract: The invention relates to a process for the preparation of a titanium catalyst which process comprises: (a) drying a silica carrier at a temperature of from 300 to 800° C. to obtain a dried carrier; (b) contacting the dried carrier obtained in step (a) with a gas stream containing titanium halide at a temperature in the range from 125° C. lower to 125° C. higher than the drying temperature of step (a) and at a pressure higher than 0.8 bar to obtain an impregnated carrier; (c) calcining the impregnated carrier obtained in step (b) to obtain the titanium catalyst.Type: GrantFiled: May 1, 2007Date of Patent: July 27, 2010Assignee: Shell Oil CompanyInventors: Jan Karel Frederik Buijink, Johannes Jacobus Maria Van Vlaanderen
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Patent number: 7731790Abstract: The invention concerns a conditioned composition comprising at least a liquid absorbed on a support containing a precipitated silica, said silica being in the form of substantially spherical beads and having: a mean pellet size greater than 150 ?m; a filling density in compact state(DRT) greater than 0.29; an oversize rate for a grid with mesh aperture size of 75 ?m of at least 92% by weight. The invention also concerns the use of such a silica as a support for liquid.Type: GrantFiled: February 18, 2005Date of Patent: June 8, 2010Assignee: Rhodia ChimieInventor: Jean-François Viot
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Patent number: 7704470Abstract: The present invention is drawn to a method for removing colloidal titanium dioxide and titanium oxychloride from by-product hydrochloric acid. The method includes adding phosphate ion source and quaternary amine to the by-product acid to cause the titanium dioxide and the titanium oxychloride to form a precipitate. The precipitate can then be separated from the acid, thus producing a decontaminated hydrochloric acid product with reduced levels of titanium.Type: GrantFiled: April 24, 2007Date of Patent: April 27, 2010Assignee: Haydock Consulting Services, LCInventor: Frederick Haydock
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Patent number: 7700062Abstract: The synthesis of precipitated silica having improved chemical and physical properties of use as a reinforcing filler in polymeric matrices is described. Improvements in the properties result from the synthesis of the silica al a reduced ionic strength. In particular, the use of silicia acid during synthesis, provides a solution of reduced ionic strength, which favors the formation of improved colloidal structure via increased aggregation and reduced agglomeration. In addition, the surface of the silica precipitate formed may be modified by the addition of surface modifying agents, during synthesis to further enhance the desired reinforcing properties of the precipitated silica. The invention also embodies polymeric compositions of improved tensile and elongation strengths, with the compositions including precipitated silica, synthesized at reduced ionic strengths and having modified surfaces, in combination with a polymeric compound.Type: GrantFiled: October 12, 2001Date of Patent: April 20, 2010Assignee: University of CincinnatiInventors: Dale W. Schaefer, Chunyan Chen, Arthur Jing-Min Yang
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Publication number: 20100083876Abstract: Precipitated silica specifically useful in the paper industry and in particular in paper-coating applications for inject printing, is characterized by an uptake of DOP oil lower than 260 ml/100 g, a pore volume (Vd25) of greater than 0.8 ml/g formed by pores having a diameter of less than 25 nm, a CTAB specific surface area of greater than 280 m2/g.Type: ApplicationFiled: June 27, 2007Publication date: April 8, 2010Inventors: Pierre-Yves Lahary, Yvonick Chevallier, Rémi Valero
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Publication number: 20100069237Abstract: The present invention relates to (1) hollow silica particles including an outer shell portion having a mesoporous structure with an average pore size of from 1 to 10 nm, wherein the silica particles have an average particle diameter of from 0.05 to 10 ?m, and 80% or more of the whole silica particles have a particle diameter falling within the range of ±30% of the average particle diameter; (2) composite silica particles including silica particles which include an outer shell portion having a mesoporous structure with an average pore size of from 1 to 10 nm, and have a BET specific surface area of 100 m2/g or more, and a hydrophobic organic compound or a polymeric organic compound incorporated inside of the silica particles; and a process for producing the hollow silica particles.Type: ApplicationFiled: October 15, 2007Publication date: March 18, 2010Applicant: KAO CORPORATIONInventors: Toshihiro Yano, Takuya Sawada
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Publication number: 20090311154Abstract: The present invention relates to a zero-waste process for extraction of alumina from different types of bauxite ores and red mud residues and of titanium dioxide from ilmenite. Iron oxide is first reduced to metallic iron above the melting point of C-saturated cast iron alloy which yields a high-C iron alloy and an Al and Ti metal oxide rich slag which is then treated with alkali carbonate to form alkali aluminates and titanates. The alkali aluminates are separated by water leaching from which the hydroxide of alumina is precipitated by bubbling CO2. The residue from water leaching is treated with sulphuric acid and TiO2 is precipitated via a hydrolysis route. The process recovers most of the metal values and generates only small quantities of silicious residues at pH4-5 which can be used for soil conditioning.Type: ApplicationFiled: June 11, 2004Publication date: December 17, 2009Applicant: Urquhart-Dykes & Lord LLPInventors: Animesh Jha, Pailo Antony Malpan, Vilas Dattatray Tathavadkar
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Patent number: 7615206Abstract: Methods for the production of shaped nanoscale-to-microscale structures, wherein a nanoscale-to-microscale template is provided having an original chemical composition and an original shape, and the nanoscale-to-microscale template subjected to a chemical reaction, so as to partially or completely convert the nanoscale-to-microscale template into the shaped nanoscale-to-microscale structure having a chemical composition different than the original chemical composition and having substantially the same shape as the original shape, being a scaled version of the original shape. The shaped nanoscale-to-microscale structure formed comprises an element (such as silicon), a metallic alloy (such as a silicon alloy), or a non-oxide compound (such as silicon carbide or silicon nitride).Type: GrantFiled: August 13, 2007Date of Patent: November 10, 2009Assignee: Georgia Tech Research CorporationInventors: Kenneth Henry Sandhage, Zhihao Bao
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Patent number: 7608234Abstract: Precipitated silicas useful, for example, as fillers in elastomer mixtures or vulcanizates have a particularly broad pore size distribution of the pores with a pore diameter smaller than that of the maximum of the derivative of the pore volume distribution function, and have simultaneously very low microporosity and high rubber activity.Type: GrantFiled: September 8, 2006Date of Patent: October 27, 2009Assignee: Degussa AGInventors: Oleg Stenzel, Hans-Detlef Luginsland, Stefan Uhrlandt, Andre Wehmeier
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Publication number: 20090263657Abstract: Process for the production of precipitated silica from olivine including the following steps:—providing olivine particles with a particle size preferably below 1 mm in diameter,—preferably mixing olivine and water to form an olivine/water slurry,—mixing the olivine/water slurry with hydrochloric acid (HCl), preferably at a concentration at 18 wt % or above, and at a temperature preferably between 50-130° C., and reacting for a period of time, preferably between 20-360 minutes,—removal of coarse mineral impurities (sand product),—separation of precipitated silica from mother solution,—mechanical treatment of the separated precipitated silica and optionally some water to obtain a slurry,—preparation of a low viscosity slurry by adding sodium aluminate or another suitable aluminate, preferably to 100-6000 p.p.m., and adjusting the pH, preferably to values between 4-9—ageing at a temperature between 50-150° C.Type: ApplicationFiled: January 13, 2005Publication date: October 22, 2009Inventors: Gudmundur Gunnarsson, Oddmund Wallevik, Lars Ekornrod, Birger Langseth, Per Engseth
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Patent number: 7572424Abstract: This disclosure describes a self-assembly templating of a cationic surfactant in the presence of a silica precursor that is free of an excessive variability of the assembled shapes and has a yield approaching one hundred percent. This disclosure describes a self-assembly process that includes cooling and keeping a resultant solution at cold temperatures during the synthesis.Type: GrantFiled: November 29, 2005Date of Patent: August 11, 2009Assignee: Clarkson UniversityInventors: Igor Sokolov, Yaroslav Kievsky
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Patent number: 7566433Abstract: Precipitated silicas which have a broad pore size distribution of the pores with a pore diameter smaller than that of the maximum of the derivative of the pore volume distribution function are useful, for example, for tires.Type: GrantFiled: September 8, 2006Date of Patent: July 28, 2009Assignee: Degussa AGInventors: Oleg Stenzel, Anke Blume, Hans-Detlef Luginsland, Ralf Schmoll, Herbert Thoma, Stefan Uhrlandt, Andre Wehmeier
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Publication number: 20090136672Abstract: A precipitated silica having a d50-value of from 150 to 2000 nm, a d90-value of from 500 to 7000 nm, a silanol group density of from 2.5 to 8 OH/nm2, and a modified tapped density of less than or equal to 70 g/l is useful for thickening and providing thixotropy in liquid systems and shows superior efficiency at thickening and creating thixotropy compared to existing grades of precipitated silica. The precipitated silica functions best as a thixotrope in non-polar or intermediate polar liquid systems such as unsaturated polyester (UPE) resin systems.Type: ApplicationFiled: November 26, 2007Publication date: May 28, 2009Applicant: Evonik Degussa CorporationInventors: Christian Panz, Karl Meier, James Toth, Guido Titz, Matt Romaine, Mario Scholz
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Patent number: 7524478Abstract: The invention concerns a method for preparing low water uptake precipitated silicas, comprising successive steps which consist in: (a) producing an initial starter including a silicate, the silicate concentration in said starter, expressed in SiO2 equivalent, being less than 15 g/L; (b) bringing the medium pH to a value ranging between 7 and 8 by adding an acidifying agent, (c) in the resulting medium, simultaneously adding a silicate and an acidifying agent the respective amounts of silicate and acidifying agent added in time being specifically such that, during the entire addition (1) the reaction medium pH stays between 7 and 8, and (ii) the silicon concentration in the medium, expressed in SiO2 equivalent, stays below 35 g/L; (d) adding an acidifying agent in the medium resulting from step (c), so as to bring the medium to a pH ranging between 3 and 6.5; and (e) filtering the resulting aqueous silica dispersion, then drying the filter cake obtained at the end of the filtering step.Type: GrantFiled: December 24, 2002Date of Patent: April 28, 2009Inventors: Remi Valero, Yvonick Chevallier
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Publication number: 20090101866Abstract: Highly efficient matting agents based on precipitated silicas and wax-coated precipitated silicas, their preparation, and their use in inks and paints.Type: ApplicationFiled: December 23, 2008Publication date: April 23, 2009Applicant: DEGUSSA AGInventors: Juergen SCHUBERT, Robert Kuhlmann, Hans Dieter Christian
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Publication number: 20090081105Abstract: A method of producing silica from geothermal fluid containing low concentration of the silica of less than 275 ppm includes the steps of treating the geothermal fluid containing the silica by reverse osmosis treatment thereby producing a concentrated fluid containing the silica, seasoning the concentrated fluid thereby producing a slurry having precipitated colloids containing the silica, and separating the silica from the slurry.Type: ApplicationFiled: September 3, 2008Publication date: March 26, 2009Inventors: William L. Bourcier, Carol J. Bruton
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Publication number: 20090074640Abstract: The present invention relates generally to a process for removing dissolved or colloidal silica from a pregnant leach solution (“PLS”). More particularly, an exemplary embodiment of the present invention relates to a process which mixes PLS with an acid source, preferably lean electrolyte, to induce formation of colloidal silica that can then be collected and removed. Additionally, in an exemplary embodiment of the present invention, at least one silica seeding agent is added to induce formation of colloidal silica, at least one flocculant is added to induce aggregation of the colloidal silica, and a solid-liquid separation process is utilized to remove advantageous amounts or substantially all of the colloidal silica, thereby providing relief from supersaturation of dissolved silica in the metal recovery processes.Type: ApplicationFiled: September 19, 2007Publication date: March 19, 2009Applicant: PHELPS DODGE CORPORATIONInventors: James D. Gillaspie, David R. Baughman, Dennis D. Gertenbach, Wayne W. Hazen, George Owusu, John C. Wilmot
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Publication number: 20090060816Abstract: A process for wet pulverizing mesoporous silica particles while a surfactant exists in mesopores, and mesoporous silica particles having an average particle diameter of 1 ?m or less, wherein the volume of mesopores having a diameter of 2 to 50 nm is 0.7 mL/g or more and the geometric standard deviation of a mesopore distribution is 2.0 or less. Mesoporous silica particles having a particle diameter in a submicron order can be obtained at a high yield without causing the marked collapse of mesopores and can be produced efficiently by using an ordinary pulverizer and safely by using an aqueous medium. The mesoporous silica particles having an average particle diameter of 1 ?m or less are useful as an ink absorbent for ink jet recording paper, low-dielectric film, catalyst support, separating agent, adsorbent and medical carrier for medicines.Type: ApplicationFiled: August 14, 2008Publication date: March 5, 2009Inventors: Kentaro FUKUDA, Kenji Fukunaga, Hiroya Yamashita
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Publication number: 20090010832Abstract: The present invention provides a process for the preparation of finely divided precipitated silica. Finely divided precipitated silica is prepared by neutralization of alkali silicate solution, under continuous stirring, at 60° to 90° C. in presence of alkali metal salt as coagulating agent, in various neutralization steps during which neutralization is interrupted for specific time. Further acidic silica sol, is added until 60 to 80% of total alkali is neutralized. The reaction mixture is then aged at least for 3 minute under continuous agitation, followed by circulation through centrifugal pump at an appropriate rate.Type: ApplicationFiled: April 30, 2008Publication date: January 8, 2009Inventors: Raksh Vir JASRA, Haresh Mahipatlal Mody, Rajesh Shantilal Somani, Hari Chand Bajaj, Dipak Balwantrai Shukla, Niraj Rameshchandra Vyas
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Publication number: 20080305027Abstract: This invention relates to the preparation, functionalisation and use of a novel nano structured silicate, generally a calcium silicate which may be hydrated. It also relates to novel methods of producing nano structured silicates. The novel nano-structured silicate material comprises a calcium silicate in the form of platelets of about 5-10 nm thick and about 50-500 nm wide or wider stacked together in a poorly ordered framework type structure as illustrated in FIG. 1. The novel material can be prepared by reacting a calcium ion containing solution with a silicate containing solution under controlled conditions and then allowing the calcium silicate to age. The novel silicate has pores of a high volume and which are readily accessible. This provides a high oil absorption capacity and high surface area. Novel nano-structured silicate materials are produced by the invention having an oil absorption capacity up to 700 g.oil.100 g?1 silicate and a surface area up to 600 m2g?1.Type: ApplicationFiled: January 17, 2006Publication date: December 11, 2008Inventors: James Howard Johnston, Andrew James McFarlane, Thomas Borrmann
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Publication number: 20080267853Abstract: To provide a process for producing inorganic spheres having a substantially uniform particle size with high productivity. In a process for producing inorganic spheres, which comprises a step of injecting an alkaline aqueous liquid containing an inorganic compound into a laminar flow of an organic liquid containing a surfactant through micropores to form a W/O type emulsion, and a step of solidifying droplets of the aqueous liquid containing an inorganic compound in the W/O type emulsion by an acid to form inorganic spheres, as the organic liquid, one which is brought into contact with an acid in a state of the W/O type emulsion or after separated from the W/O type emulsion, or one which is brought into contact with the aqueous liquid and then separated and recovered, is used.Type: ApplicationFiled: June 26, 2008Publication date: October 30, 2008Applicant: Asahi Glass Company, LimitedInventors: Toshiya Matsubara, Masaharu Tanaka, Hajime Katayama, Kenji Yamada
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Patent number: 7442356Abstract: To provide a process for producing inorganic spheres having a substantially uniform particle size with high productivity. In a process for producing inorganic spheres, which comprises a step of injecting an alkaline aqueous liquid containing an inorganic compound into a laminar flow of an organic liquid containing a surfactant through micropores to form a W/O type emulsion, and a step of solidifying droplets of the aqueous liquid containing an inorganic compound in the W/O type emulsion by an acid to form inorganic spheres, as the organic liquid, one which is brought into contact with an acid in a state of the W/O type emulsion or after separated from the W/O type emulsion, or one which is brought into contact with the aqueous liquid and then separated and recovered, is used.Type: GrantFiled: November 14, 2005Date of Patent: October 28, 2008Assignee: Asahi Glass Company, LimitedInventors: Toshiya Matsubara, Masaharu Tanaka, Hajime Katayama, Kenji Yamada
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Publication number: 20080199384Abstract: The present invention provides a process for producing silica, sodium sulfite and sodium hydrogen sulfite with sodium sulfate, wherein quartz sand, sodium sulfate and carbon are mixed and charged into a furnace for reaction and the obtained solid sodium silicate and sulfur dioxide are used to prepare silica, sodium sulfite and sodium hydrogen sulfite according to the following steps: 1) To produce silica: said solid sodium silicate is dissolved in water and filtered to produce a water glass solution; then sulfuric acid is reacted with said water glass solution to produce precipitated silica and sodium sulfate; and the precipitated silica is washed, filtered, liquefied and dried to produce silica; 2) To produce sodium sulfite: soda is added into a sodium hydrogen sulfite solution to produce sodium sulfite solution; one part of said sodium sulfite solution is concentrated and evaporated to obtain dry sodium sulfite; and the other part of the sodium sulfite solution is reacted with the sulfur dioxide produced duType: ApplicationFiled: June 6, 2006Publication date: August 21, 2008Applicant: EVONIK DEGUSSA WELLINK SILICA (NANPING) CO. LTD.Inventor: Yuanjian Lu
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Publication number: 20080199385Abstract: Provided is a process for producing silica and sodium sulfite with sodium sulfate, wherein a mixture of quartz sand, sodium sulfate and carbon is reacted to produce solid sodium silicate and sulfur dioxide, which are used to produce silica and sodium sulfite through the following steps: (1) Said solid sodium silicate is dissolved in water and then filtered to obtain a sodium silicate solution; a sodium hydrogen sulfite solution is added to said sodium silicate solution to produce precipitated silica and sodium sulfite solution and the resultant mixture is filtered; (2) One part of the filtrate obtained at the end of step (1) is brought into contact with said sulfur dioxide and the product, sodium hydrogen sulfite, is recycled to step (1); (3) The filter cake obtained at the end of step (1) is acidified, followed by filtration, washing and drying to obtain silica; and (4) The other part of the filtrate obtained at the end of step (1) is concentrated and dried to obtain solid sodium sulfite.Type: ApplicationFiled: June 6, 2006Publication date: August 21, 2008Applicant: Evonik Degussa Wellink Silica(Nanping) Co. Ltd.Inventor: Yuanjian Lu
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Publication number: 20080160052Abstract: Precipitated silica comprising porous silica particles having a cumulative surface area for all pores having diameters greater than 500 ? of less than 6 m2/g, as measured by mercury intrusion, and a percentage cetylpyridinium chloride (% CPC) Compatibility of greater than about 85%. The precipitated silica product is especially well-adapted for use in dentifrices containing cetylpyridinium chloride, which do not attach to the low surface area silica product in a meaningful level and thus remain available for antimicrobial action. Processes for making the silica product including the introduction of sodium sulfate powder during different process steps in order to enhance such a compatibility with CPC are provided.Type: ApplicationFiled: December 27, 2006Publication date: July 3, 2008Inventor: Karl Gallis
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Patent number: 7378076Abstract: The invention involves a process for production of macrostructures of a microporous material. The process is characterized by the fact that seeds formed in or introduced by ion exchange or adsorption to a porous organic ion exchanger with the desired size, shape and porosity are made to grow and form a continuous structure by further deposition of inorganic material from a synthesis solution under hydrothermal conditions. The organic ion exchanger can be eliminated by chemical destruction or dissolution and, in so doing, leaves behind an inorganic microporous structure with the size and shape of the employed organic ion exchanger.Type: GrantFiled: August 11, 2005Date of Patent: May 27, 2008Assignee: ExxonMobil Chemical Patents Inc.Inventors: Per Johan Sterte, Lubomira Borislavova Tosheva, Valentin Panov Valtchev
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Patent number: 7378072Abstract: A method for the preparation of aerogels that involves the exchange of the liquid present in the aquagel with xenon and the subsequent extraction thereof.Type: GrantFiled: June 24, 2003Date of Patent: May 27, 2008Assignee: Novara Technology S.R.L.Inventors: Lorenzo Costa, Fulvio Costa
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Publication number: 20080085232Abstract: There is provided a method of preparing silica (SiO2) nanoparticles from siliceous mudstone which is silica mineral sources, using a chemical reaction. The method of preparing silica nanoparticles from siliceous mudstone comprises: solving a silica constituent into a sodium silicate aqueous solution by a sodium hydroxide leaching reaction of the siliceous mudstone (S100); performing ion exchange to remove a sodium constituent from the sodium silicate aqueous solution and to prepare a silicate aqueous solution (S200); and performing flame spray pyrolysis to prepare silica nanoparticles with an average particle dimension being in a range of 9 to 57 nm from the silicate aqueous solution.Type: ApplicationFiled: December 15, 2006Publication date: April 10, 2008Applicant: Korea Institute of Geoscience and Mineral ResourcesInventors: Hee-Dong Jang, Han-Kwon Chang, Ho-Sung Yoon
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Patent number: 7335717Abstract: The in vitro polymerization of silica, silicone, non-silicon metalloid-oxane and metallo-oxane polymer networks, by combining a catalyst and a substrate to polymerize the substrate to form silica, polysiloxanes, polymetalloid-oxanes polymetallo-oxanes (metal oxides), polyorganometalloid oxanes, polyorganometallo oxanes, and the polyhydrido derivatives thereof, at about neutral pH.Type: GrantFiled: March 22, 2004Date of Patent: February 26, 2008Assignee: The Regents of the University of CaliforniaInventors: Daniel E. Morse, David Kisailus, Kristian M. Roth
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Patent number: 7335342Abstract: In the present invention a process for the preparation of sodium silicate from Kimberlite tailing generated as solid waste during diamond mining is disclosed. The process comprises, reacting Kimberlite tailing with mineral acid to remove acid soluble impurities followed by digesting acid treated Kimberlite tailing with alkali solution in a open or closed system to obtain sodium silicate useful for commercial applications.Type: GrantFiled: March 14, 2006Date of Patent: February 26, 2008Assignee: Council of Scientific and Industrial ResearchInventors: Raksh Vir Jasra, Hari Chand Bajaj, Rajesh Shantilal Somani, Haresh Mahipatlal Mody, Jatin Rameshchandra Chunawala, Devendra Lalijibhai Ghelani, Hemal Narendrakumar Ranpara, Dipti Jivanbhai Barochiya, Suresh Chandra, Maharaj Kishan Dhar, C. Kesava Rao, Kamlesh Kumar
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Publication number: 20080019898Abstract: The invention relates to a highly-structured precipitated silica having a low water uptake and high dispersibility in different pasty or solid matrices or media, elastomers or silicon, and to the preparation method thereof. The invention also relates to the use of said silica, for example, as a reinforcing filler in matrices based on elastomers (clear or semi-clear for shoe soles), in silicon matrices (in particular, for the coating of electric cables), as a filler and/or support and/or vehicle in different compositions (food compositions, cosmetic compositions, pharmaceutical compositions, compositions for the production of paints or paper, compositions for the production of porous membrane separators for batteries) or as a thickening agent in toothpastes.Type: ApplicationFiled: December 20, 2004Publication date: January 24, 2008Inventors: Adrien Dromard, Yvonick Chevallier, Remi Valero, Dominique Petit
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Patent number: 7306788Abstract: Unique abrasive and/or thickening materials that are in situ generated compositions of precipitated silicas and silica gels are provided. Such compositions exhibit different beneficial characteristics depending on the structure of the composite in situ generated material. With low structured composites (as measured via linseed oil absorption levels from 40 to 100 ml oil absorbed/100 g composite), simultaneously high pellicle film cleaning properties and moderate dentin abrasion levels are possible in order to accord the user a dentifrice that effectively cleans tooth surfaces without detrimentally abrading such surfaces. Increased amounts of high structure composite materials tend to accord greater viscosity build and thickening benefits together with such desirable abrasion and cleaning properties, albeit to a lesser extent than for the low structure types.Type: GrantFiled: November 24, 2004Date of Patent: December 11, 2007Assignee: J.M. Huber CorporationInventors: Patrick D. McGill, William C. Fultz
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Patent number: 7303742Abstract: Unique abrasive and/or thickening materials that are in situ generated compositions of precipitated silicas and silica gels are provided. Such compositions exhibit different beneficial characteristics depending on the structure of the composite in situ generated material. With low structured composites (as measured via linseed oil absorption levels from 40 to 100 ml oil absorbed/100 g composite), simultaneously high pellicle film cleaning properties and moderate dentin abrasion levels are possible in order to accord the user a dentifrice that effectively cleans tooth surfaces without detrimentally abrading such surfaces. Increased amounts of high structure composite materials tend to accord greater viscosity build and thickening benefits together with such desirable abrasion and cleaning properties, albeit to a lesser extent than for the low structure types.Type: GrantFiled: November 24, 2004Date of Patent: December 4, 2007Assignee: J.M. Huber CorporationInventors: Patrick D. McGill, William C. Fultz
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Patent number: 7270803Abstract: Unique abrasive materials that are in situ generated compositions of precipitated silicas and silica gels are provided. Such compositions exhibit different beneficial, particularly simultaneously high pellicle film cleaning properties and moderate dentin abrasion levels. Such a result thus accords the user a dentifrice that effectively cleans tooth surfaces without detrimentally abrading such surfaces. Furthermore, the produced abrasive materials also exhibit very high and desirable brightness properties that permit easy incorporation and utilization within dentifrices for aesthetic purposes. Encompassed within this invention is a unique method for making such gel/precipitated silica composite materials for such a purpose, particularly under high shear conditions, as well as the different materials within the structure ranges described above and dentifrices comprising such.Type: GrantFiled: March 23, 2006Date of Patent: September 18, 2007Assignee: J.M. Huber CorporationInventor: Patrick D. McGill
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Patent number: 7267814Abstract: Unique abrasive and/or thickening materials that are in situ generated compositions of precipitated silicas and silica gels are provided. Such compositions exhibit different beneficial characteristics depending on the structure of the composite in situ generated material. With low structured composites (as measured via linseed oil absorption levels from 40 to 100 ml oil absorbed/100 g composite), simultaneously high pellicle film cleaning properties and moderate dentin abrasion levels are possible in order to accord the user a dentifrice that effectively cleans tooth surfaces without detrimentally abrading such surfaces. Increased amounts of high structure composite materials tend to accord greater viscosity build and thickening benefits together with such desirable abrasion and cleaning properties, albeit to a lesser extent than for the low structure types.Type: GrantFiled: November 24, 2004Date of Patent: September 11, 2007Assignee: J.M. Huber CorporationInventors: Patrick D. McGill, William C. Fultz
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Patent number: 7255852Abstract: Precipitated silica comprising porous silica particles having a cumulative surface area for all pores having diameters greater than 500 ? of less than 8 m2/g, as measured by mercury intrusion, and a percentage cetylpyridinium chloride (% CPC) Compatibility of greater than about 55%. The precipitated silica product is especially well-adapted for use in dentifrices containing cetylpyridinium chloride, which do not attach to the low surface area silica product in a meaningful level and thus remain available for antimicrobial action. Processes for making the silica product are also provided.Type: GrantFiled: October 3, 2003Date of Patent: August 14, 2007Assignee: J.M. Huber CorporationInventors: Karl W. Gallis, Mark E. Wozniak, John A. Kostinko