Bisulfate Patents (Class 423/520)
  • Patent number: 10647074
    Abstract: An aerospace vessel including a fuselage, a means for causing the fuselage to fly coupled to the fuselage, and an environmental control system within the fuselage. The environmental control system includes a duct made of closed cell thermoplastic foam, such as polyvinylidene fluoride foam.
    Type: Grant
    Filed: December 6, 2016
    Date of Patent: May 12, 2020
    Assignee: The Boeing Company
    Inventors: Walter Forrest Frantz, Jayant D. Patel, Douglas Dean Maben, Bruce Whitman, Douglas E. Freeman
  • Publication number: 20130171048
    Abstract: A solution mining method for recovering alkali values from a cavity of an underground ore formation comprising trona and/or wegscheiderite; a manufacturing process using such method to make sodium-based product(s); and a sodium-based product obtained therefrom. The method comprises: an ore dissolution phase (a) in which the incongruent double-salt in trona and/or wegscheiderite is dissolved from an ore face in a first solvent, and a cavity cleaning phase (b) in which sodium bicarbonate deposited on the ore face during the dissolution phase (a) is dissolved into a second aqueous solvent having a higher pH, hydroxide content, and/or temperature and is partly or completely converted in situ to sodium carbonate. The method further comprises withdrawing a liquor resulting from either phase to the ground surface, optionally recycling some liquor to the cavity; and passing some liquor through a crystallizer, a reactor, and/or an electrodialyser, to form at least one sodium-based product which is recovered.
    Type: Application
    Filed: December 21, 2012
    Publication date: July 4, 2013
    Applicant: SOLVAY SA
    Inventor: SOLVAY SA
  • Publication number: 20090130474
    Abstract: Regarding the scavenger for aldehyde(s) used at the time of manufacturing a woody panel using woody materials and formaldehyde-based binders, the scavenger for aldehyde(s) without lowering of trapping properly even when a surface of said woody panel is sanded and having an excellent trapping property of trapping formaldehyde is provided. Further, the method of manufacturing a woody panel using a scavenger for aldehyde(s) and a woody panel are provided. At least one kind of compound for trapping aldehyde(s) being solid at a room temperature is included and said compound for trapping aldehyde(s) is defined to be a powdery scavenger for aldehyde(s) having a property of generating acidic gas, in particular, sulfurous acid gas by heating and said compound for trapping aldehyde(s) is added to a binder or woody materials followed by a hot press, thereby manufacturing a woody panel.
    Type: Application
    Filed: June 29, 2006
    Publication date: May 21, 2009
    Applicant: IPPOSHA OIL INDUSTRIES CO., LTD.
    Inventors: Kenichi Ishimoto, Yukio Shirakami, Nobuyuki Shimada, Tomoyuki Mabuchi, Toshiya Takeuchi, Takashi Ikeda
  • Patent number: 7288235
    Abstract: The invention relates to a method and an installation for separating sulphur dioxide from exhaust gas, wherein sea water is added to the exhaust gas in an absorption column and the sea water charged with sulphur compounds is extracted from the liquid sump of the absorption column and fresh sea water is added thereto. In order to omit the very expensive and large secondary reaction basis according to the state of the art, it is proposed to extract the liquid, which contains the bisulphates, from the liquid sump of the absorption column and to mix it with fresh sea water in a pipeline for the purpose of sulphate formation and pH adjustment (neutralization). The invention is based upon the finding that the sulphate formation and pH adjustment are completed after a reaction time comprised between 1 and 2 minutes. Thus, the large and expensive secondary reaction basin can be omitted.
    Type: Grant
    Filed: October 1, 2004
    Date of Patent: October 30, 2007
    Assignee: Lentjes GmbH
    Inventors: Andreas Schleicher, Gabriele Böhm, Matthias Küper
  • Patent number: 7067094
    Abstract: The process for the brightening of continuously produced sodium hydrogensulfate obtained in the reaction of sodium chloride and concentrated sulfuric acid in molten sodium hydrogensulfate in a circulation reactor, wherein evolved hydrogen chloride and heating gases generated by an immersion burner are withdrawn at various sites and seed crystals are added for a faster conversion of initially formed metastable phases, is that from 0.01 to 0.05% by weight of aluminium oxide and/or from 0.5 to 1.5% by weight of magnesium oxide and/or magnesium sulfate and, optionally, additionally calcium sulfate are added as seed crystals.
    Type: Grant
    Filed: August 30, 2004
    Date of Patent: June 27, 2006
    Assignee: Grillo-Werke AG
    Inventors: Klaus Driemel, Ingo Biertümpel, Horst Kirsch
  • Patent number: 7045111
    Abstract: A process for co-producing anhydrous hydrogen bromide and a purified bisulfate salt by (a) reacting a bromide salt with sulfuric acid to produce crude hydrogen bromide and crude bisulfate salt; (b) purifying the crude hydrogen bromide to produce anhydrous hydrogen bromide; and (c) removing bromide from the crude bisulfate salt to form a purified bisulfate salt. There are also provided improvements in the bisulfate purification and bromine removal, whereby bromine is removed from the system by a distillation process and the bromide is removed from the crude bisulfate via a spray drying process.
    Type: Grant
    Filed: August 11, 2005
    Date of Patent: May 16, 2006
    Assignee: Poly Systems USA, Inc.
    Inventors: Richard J. DeGroot, Dov Shellef
  • Patent number: 7045109
    Abstract: Process for the conversion of sodium bromide to anhydrous hydrobromic acid and sodium bisulfate, said process with the following sequential steps: reaction of sodium bromide and sulfuric acid in a solution of water to produce hydrobromic acid and sodium bisulfate wherein the conversion of sodium bromide is greater than about 99%; adsorption of iron bromide onto a solid adsorbent; separation of hydrobromic acid and water from the sodium bisulfate; separation and drying of hydrobromic acid; and solidification of the sodium bisulfate into a flaked or granular form.
    Type: Grant
    Filed: November 19, 2004
    Date of Patent: May 16, 2006
    Assignee: Procter & Gamble
    Inventors: Jared John Schaefer, Corey James Kenneally, Daniel Martin Bourgeois, Deborah Jean Back
  • Patent number: 7045110
    Abstract: A batch process for co-producing anhydrous hydrogen bromide and a purified bisulfate salt comprising: (a) charging a batch reactor with a bromide salt slurry, wherein the slurry is more than 50% by weight bromide salt; (b) reacting the slurry with sulfuric acid in a batch reaction wherein bromide salt is consumed to produce crude aqueous hydrogen bromide and crude bisulfate salt, the crude bisulfate salt containing bromine; (c) prior to or concurrently with step (b) adding hydrogen bromide to the reactor; (d) purifying the crude hydrogen bromide to produce anhydrous hydrogen bromide; and (e) removing bromine from the crude bisulfate salt to form a purified bisulfate salt.
    Type: Grant
    Filed: January 5, 2005
    Date of Patent: May 16, 2006
    Assignee: Poly Systems USA, Inc.
    Inventors: Richard J. DeGroot, Dov Shellef
  • Patent number: 6811763
    Abstract: Process for the conversion of sodium bromide to anhydrous hydrobromic acid and sodium bisulfate, said process with the following sequential steps: reaction of sodium bromide and sulfuric acid in a solution of water to produce hydrobromic acid and sodium bisulfate wherein the conversion rate is greater than about 95%; separation of hydrobromic acid and water from the sodium bisulfate; separation of hydrobromic acid from water; and drying of hydrobromic acid.
    Type: Grant
    Filed: October 7, 2002
    Date of Patent: November 2, 2004
    Assignee: The Procter & Gamble Company
    Inventors: Daniel Martin Bourgeois, Corey James Kenneally
  • Publication number: 20010033823
    Abstract: An object of the invention is to provide: a treated manganese ore for use in manganese sulfate production therefrom which has a high degree of manganese dissolution when dissolved in sulfuric acid and which can hence be effective in reducing the amount of slags generating in a production step and can be reduced in potassium content according to need; a process for producing the treated manganese ore easily and economically; manganese dioxide which is useful in primary batteries, secondary batteries, etc.; and a process for easily producing the manganese dioxide. A treated manganese ore for use in producing manganese sulfate therefrom, the treated ore having a degree of manganese dissolution of 98.0% by weight or higher based on the manganese contained in the treated manganese ore when dissolved in sulfuric acid; a process for producing the treated ore; manganese dioxide obtained from the treated ore; and a process for producing the manganese dioxide are described.
    Type: Application
    Filed: April 4, 2001
    Publication date: October 25, 2001
    Applicant: TOSOH CORPORATION
    Inventors: Minoru Kuniyoshi, Kouya Honjo
  • Patent number: 4822575
    Abstract: The invention concerns processes for the preparation of zirconium compositions which on calcination form zirconia. The zirconium compositions are prepared by the addition of an ammonia source to an aqueous zirconium sulfate solution to give a solution pH in the range of from 0.1 to 2.5 and preferably 1.0 to 2.0. The zirconium composition precipitated from solution appears crystalline, is readily collected by filtration and has low levels of metallic impurities. Therefore, the process of the invention may be used to advantage in the purification zirconium compounds.The invention also includes the zirconium compositions and processes for the purification of zirconium compounds including zirconia.
    Type: Grant
    Filed: January 2, 1987
    Date of Patent: April 18, 1989
    Assignee: ICI Australia Limited
    Inventors: Kian F. Ngian, Angus J. Hartshorn, David H. Jenkins
  • Patent number: 4686097
    Abstract: Process for the removal of the residual sulfuric acid from the reaction mixture which has been obtained in the reaction of paraffin with sulfur dioxide, oxygen and water under irradiation by UV light and which has been freed from sulfur dioxide by degassing at an elevated temperature and from which the bulk of the sulfuric acid has been removed by concentration, by warming this concentrated product and adding as much of an alkali metal carbonate, peroxide, hydroxide, sulfate or sulfonate as is required to convert the residual sulfuric acid into an alkali metal bisulfate.
    Type: Grant
    Filed: April 2, 1985
    Date of Patent: August 11, 1987
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Ernst Horoldt, Adam Urschel
  • Patent number: 4588573
    Abstract: Potassium chloride and sulfuric acid are reacted in a recycled aqueous solution in the stoichiometric ratio required for potassium sulfate production. Hydrogen chloride produced by the reaction of the potassium chloride and sulfuric acid is evaporated in admixture with water or in anhdrous form. The resulting solution is cooled to crystallize a potassium sulfate salt, preferably potassium bisulfate. The potassium sulfate salt is separated from the mother liquor and the mother liquor is recycled to the reaction step. The potassium sulfate salt is dissolved in an aqueous solution and sequentially decomposed to produce potassium sulfate and a mother liquor rich in sulfuric acid. The mother liquor rich in sulfuric acid is concentrated and recycled to the reaction step.
    Type: Grant
    Filed: April 19, 1984
    Date of Patent: May 13, 1986
    Assignee: Prodeco, Inc.
    Inventors: Ralph E. Worthington, Alex Magdics, Donald B. Stain
  • Patent number: 4554139
    Abstract: A process for producing K.sub.2 SO.sub.4 from potassium chloride salts, calcium sulfate salts and another sulfate source wherein syngenite is formed and then decomposed with mineral acid to produce crystalline K.sub.3 H(SO.sub.4).sub.2. The K.sub.3 H(SO.sub.4).sub.2 crystals are recrystallized to produce K.sub.2 SO.sub.4 crystals.
    Type: Grant
    Filed: June 7, 1984
    Date of Patent: November 19, 1985
    Assignee: Prodeco, Inc.
    Inventors: Ralph E. Worthington, Alex Magdics
  • Patent number: 4554151
    Abstract: A process for producing K.sub.2 SO.sub.4 from potassium chloride salts, calcium sulfate salts and another sulfate source wherein syngenite is formed and then decomposed with mineral acid to produce crystalline K.sub.3 H(SO.sub.4).sub.2. The K.sub.3 H(SO.sub.4).sub.2 crystals are recrystallized to produce K.sub.2 SO.sub.4 crystals.
    Type: Grant
    Filed: September 27, 1983
    Date of Patent: November 19, 1985
    Assignee: Prodeco, Inc.
    Inventors: Ralph E. Worthington, Alex Magdics, Donald B. Stain
  • Patent number: 4465658
    Abstract: Chlorine dioxide is formed at high efficiency from a solution of acid sodium chlorate at high sulphuric acid normality in excess of 9 normal to which methanol is fed. The reaction medium is at its boiling point under a subatmospheric pressure. The incidence of white-outs is avoided by feeding chloride ions to the reaction medium, while the efficiency of chlorine dioxide production remains high.
    Type: Grant
    Filed: June 13, 1983
    Date of Patent: August 14, 1984
    Assignee: Erco Industries Limited
    Inventor: Maurice C. J. Fredette
  • Patent number: 4431625
    Abstract: Chromium trioxide is made by reacting sodium dichromate with sulphuric acid in an aqueous reaction mixture, evaporating the resultant liquor to cause crystallization of most of the chromium trioxide and to cause the concentration of sodium sulphates to be close to but below that at which sulphate crystals start to form, and separating the chromium trioxide crystals from the evaporated liquor. The liquor may then be cooled so as to cause crystallization of sodium sulphates, generally as sodium bisulphate, and the resultant liquor, after separation of the crystals, may be recycled to the reaction mixture containing dichromate and sulphuric acid.
    Type: Grant
    Filed: June 28, 1983
    Date of Patent: February 14, 1984
    Assignee: British Chrome & Chemicals Limited
    Inventors: Michael A. Marshall, Danvers A. Swales
  • Patent number: 4342737
    Abstract: A process of producing a potassium sulfate salt comprising reacting sulfuric acid with potassium chloride at an equivalent ratio of sulfuric acid to potassium chloride of 1.07 to 1.40 at a temperature of from the melting point of potassium bisulfate to about 500.degree. C. while allowing the resulting solid-liquid mixture at the final reaction stage to be substantially in a state of wet cake, said potassium bisulfate being present in the reaction system until the termination of the reaction because of the excess sulfuric acid. In such a process, the reaction proceeds smoothly at a relatively low temperature and is completed in an extremely shortened period of time to produce a potassium sulfate salt with an extremely low chlorine content which is useful as a raw material for the production of potassium-containing chemical manures to be suitably applied onto the farmland of tobacco etc. which are apt to have their growth hampered by chlorine values.
    Type: Grant
    Filed: December 17, 1979
    Date of Patent: August 3, 1982
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Hidemaro Iwashita, Kenichi Hayashi
  • Patent number: 4293532
    Abstract: A process for producing hydrogen chloride and ammonia, comprising the steps of carrying out the reaction of ammonium chloride with ammonium hydrogen sulfate in the state of molten salt to produce hydrogen chloride, and heating the reaction system at the above-mentioned reaction carrying step at a temperature of 300.degree. C. or higher to produce ammonia gas, thereby hydrogen chloride and ammonia can be obtained in high yields, overcoming problems encountered in conventional corresponding processes.
    Type: Grant
    Filed: May 29, 1980
    Date of Patent: October 6, 1981
    Assignee: Central Glass Company, Limited
    Inventors: Hiromi Sasaki, Yoshiyuki Takahara
  • Patent number: 4191736
    Abstract: The foaming tendencies of continuous liquid-solid reactions which evolve gas are reduced by subjecting the reactant stream simultaneously to non-turbulent flow through an enclosed conduit having a vapor space above the flowing stream and to mild agitation to increase the liquid-solid and gas-liquid interface areas.
    Type: Grant
    Filed: November 19, 1975
    Date of Patent: March 4, 1980
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Dong M. Chay
  • Patent number: 4107015
    Abstract: Removal of sulfur dioxide from an aqueous solution containing the same is effected by subjecting the solution to electrodialytic water splitting. In particular SO.sub.2 is removed from dilute gas streams by means of alkaline solution scrubbing, regeneration of the scrubbing solution and liberation of concentrated SO.sub.2 by means of a membrane water splitter. Waste sulfate produced in the process may be converted to sulfuric acid in a separate membrane water splitter or otherwise processed by conventional means.
    Type: Grant
    Filed: July 18, 1977
    Date of Patent: August 15, 1978
    Assignee: Allied Chemical Corporation
    Inventors: Frederick P. Chlanda, Krishnamurthy Nagasubramanian, Kang-Jen Liu
  • Patent number: 4081520
    Abstract: The efficiency of the Solvay chlorine dioxide producing process is enhanced by the use of a high total acid normality and a single vessel generator-evaporator-crystallizer.
    Type: Grant
    Filed: February 22, 1977
    Date of Patent: March 28, 1978
    Assignee: ERCO Industries Limited
    Inventors: Richard Swindells, Maurice C. J. Fredette
  • Patent number: 4045543
    Abstract: Potassium sulfate (K.sub.2 SO.sub.4) is prepared by reaction of potassium chloride and sulfuric acid in an aqueous medium by initially removing evolved HCl in the gaseous form at temperatures of about 65.degree.-120.degree. C., then removing the remaining HCl as an HCl/water azeotrope at temperatures of about 90.degree. to 110.degree. C., restoring to the reaction mixture the amount of water removed with the azeotrope, and permitting the potassium sulfate to crystallize from the solution.
    Type: Grant
    Filed: November 12, 1975
    Date of Patent: August 30, 1977
    Assignee: Pennzoil Company
    Inventor: John B. Sardisco
  • Patent number: 4039705
    Abstract: There are provided curable anaerobic pressure sensitive adhesive stocks in the form of sheets and tapes in which the adhesive is contained between two differential release surfaces. This construction permits total pressure sensitive adhesive transfer to a substrate which is to be firmly secured to another substrate upon the exclusion of oxygen and initiation of cure of the anaerobic resin.The compositions are those, based on the total weight of the composition, containing from about 4 to about 40 percent by weight of a first anaerobic resin having a viscosity up to about 1000 cps at 25.degree. C from 0 to about 80 percent by weight of a second anaerobic resin having a viscosity greater than about 1000 cps at 25.degree. C, from about 9 to 95 percent by weight of a thermoplastic resin system, from 0 to about 10 percent of a latent accelerator and about 0.1 to about 10 percent of a hydroperoxide catalyst, the composition having static shear at 0.25 in.sup.
    Type: Grant
    Filed: September 13, 1976
    Date of Patent: August 2, 1977
    Assignees: Avery International Corporation, Loctite Corporation
    Inventors: Maurice Douek, Gustav A. Schmidt, Bernard M. Malofsky, Martin Hauser
  • Patent number: 3993737
    Abstract: A dry alkaline earth metal metasilicate or an alkali metal metasilicate is chemically reacted with a concentrated mineral acid in the ratio of 1:3 mols to produce silicoformic hydrogen salts and an alkali hydrogen salt. The silicoformic hydrogen salt is washed with water then filtered to remove the salt and mineral acid, thereby producing silicoformic acid.
    Type: Grant
    Filed: September 12, 1975
    Date of Patent: November 23, 1976
    Inventor: David H. Blount
  • Patent number: 3993815
    Abstract: There are provided curable anaerobic pressure sensitive adhesive stocks in the form of sheets and tapes in which the adhesive is contained between two differential release surfaces. This construction permits total pressure sensitive adhesive transfer to a substrate which is to be firmly secured to another substrate upon the exclusion of oxygen and initiation of cure of the anaerobic resin.The adhesive layer provided may be homogeneous or heterogeneous, and there may be contained within the adhesive layer a support layer.The release liner employed is preferably impervious to migration of contained compounds which serve as the accelerators for cure of the curable anaerobic resin.
    Type: Grant
    Filed: October 7, 1974
    Date of Patent: November 23, 1976
    Assignees: Avery Products Corporation, Loctite Corporation
    Inventors: Maurice Douek, Gustav A. Schmidt, Bernard M. Malofsky, Martin Hauser
  • Patent number: 3984466
    Abstract: Alpha-resorcylic acid is produced by the hydrolysis of 3,5-diamino benzoic acid in an aqueous solution of ammonium bisulfate. The reactants are contacted at an elevated temperature for a period of time sufficient to hydrolyze the 3,5-diamino benzoic acid to alpha-resorcylic acid and the alpha-resorcylic acid so produced is separated from the reaction mixture. The ammonium sulfate is regenerated to ammonium bisulfate by removing the water and thermally decomposing the by-product ammonium sulfate at an elevated temperature.
    Type: Grant
    Filed: January 17, 1975
    Date of Patent: October 5, 1976
    Assignee: Koppers Company, Inc.
    Inventor: Nicholas P. Greco
  • Patent number: 3974266
    Abstract: An improved process for the production of chlorine dioxide wherein an alkali metal chlorate and sulfuric acid are reacted in a single vessel, and the resultant alkali metal sulfate converted to alkali metal chloride in a metathesis column by reaction with hydrochloric acid.
    Type: Grant
    Filed: October 7, 1975
    Date of Patent: August 10, 1976
    Assignee: Hooker Chemicals & Plastics Corporation
    Inventor: Willard A. Fuller
  • Patent number: 3961028
    Abstract: Method of preparing cuprous sulfate and bisulfate solutions from materials containing copper and impurities by a leaching process are disclosed. The leaching composition contains sulfuric acid, cupric ions, water and an organic nitrile. The leaching composition may be used with copper sulfide ores in particulate form. The cuprous solutions resulting from the leaching can be treated by disproportionation methods to recover pure copper.
    Type: Grant
    Filed: December 17, 1974
    Date of Patent: June 1, 1976
    Assignee: Anumin Pty. Limited
    Inventors: Alan James Parker, Winfield Earle Waghorne, Dion Ewing Giles, John Howard Sharp, Robert Alexander, David Michael Muir
  • Patent number: 3954941
    Abstract: A dry alkaline earth metal silicate or an alkali metal silicate is reacted with a concentrated mineral acid, forming a white granular mixture. The mineral acid is then neutralized with a dry alkali metal carbonate or hydroxide producing monosilanal and monosilanic acid. Monosilanal will react with water to produce monosilandiol.
    Type: Grant
    Filed: August 16, 1974
    Date of Patent: May 4, 1976
    Inventor: David H. Blount
  • Patent number: 3937782
    Abstract: A dry alkaline earth metal silicate or an alkali metal silicate is reacted with a concentrated mineral acid to form silico-formic acid and hydrogen salt. The acid and hydrogen salt is reacted with a dry alkali metal carbonate or hydroxide to produce monosilanal. Monosilanol is reacted with water to produce monosilandiol.
    Type: Grant
    Filed: March 24, 1975
    Date of Patent: February 10, 1976
    Inventor: David H. Blount
  • Patent number: 3933925
    Abstract: Methyl resorcinols are produced by the hydrolysis of toluene diamines in an aqueous excess of ammonium bisulfate. The reactants are contacted at an elevated temperature for a period of time sufficient to hydrolyze the toluene diamines to methyl resorcinols. The methyl resorcinols so produced are separated from the reaction mixture. The ammonium sulfate is regenerated to ammonium bisulfate by removing the water and thermally decomposing the by-product ammonium sulfate at an elevated temperature.
    Type: Grant
    Filed: January 17, 1975
    Date of Patent: January 20, 1976
    Assignee: Koppers Company, Inc.
    Inventor: Nicholas P. Greco