Abstract: An apparatus for carrying out a multi-step process of converting hydrocarbon fuel to a substantially pure hydrogen gas feed includes a plurality of reaction zones arranged in an insulated, box-shaped, compact fuel processor. The multi-step process includes preheating the hydrocarbon fuel utilizing integration with the inherent exothermic processes utilized with the fuel processor, reacting the preheated hydrocarbon fuel to form the hydrogen rich gas, and purifying the hydrogen rich gas to produce a gas that is suitable for consumption in a fuel cell.

Abstract: The invention relates to methods of using noble metal-free nickel catalysts to generate a hydrogen-rich gas from gas mixtures containing carbon monoxide and water, such as water-containing syngas mixtures, where the nickel may exist in either a supported or a bulk state. The noble metal-free water gas shift catalyst of the invention comprises Ni in either a supported or a bulk state and at least one of Ge, Cd, In, Sn, Sb, Te, Pb, their oxides and mixtures thereof. The invention is also directed toward noble metal-free nickel catalysts that exhibit both high activity and selectivity to hydrogen generation and carbon monoxide oxidation.

Abstract: A method and catalysts and fuel processing apparatus for producing a hydrogen-rich gas, such as a hydrogen-rich syngas are disclosed. According to the method a CO-containing gas, such as a syngas, contacts a water gas shift (“WGS”) catalyst, in the presence of water, preferably at a temperature of less than about 450° C. to produce a hydrogen-rich gas, such as a hydrogen-rich syngas.

Abstract: There is provided a catalyst for a water gas shift reaction in a hydrogen gas which is able to effectively remove CO in the hydrogen gas within a broader temperature range. Such a catalyst for the water gas shift reaction is characterized in that a metal oxide carrier supports at least platinum. The catalyst can be used for removing carbon monoxide in the hydrogen gas. Particularly, such a catalyst can be used in the water gas shift reaction for removing carbon monoxide in a reformed gas in a fuel cell generation system.

Abstract: The invention disclosed is a method for the reduction of carbon monoxide to carbon dioxide in a gas stream comprising carbon monoxide, hydrogen and water vapor, wherein the carbon monoxide and hydrogen have a mole ratio greater than 5:1, with substantially reduced methanation. The invention utilizes a reactor having at least one channel having a catalyst positioned thereon and a flow rate of the gas stream over the catalyst such that a boundary layer having a thickness less than a maximum thickness boundary is created.

Abstract: A process for producing a high temperature COx-lean product gas from a high temperature COx-containing feed gas, includes: providing a sorption enhanced reactor containing a first adsorbent, a shift catalyst and a second adsorbent; feeding into the reactor a feed gas containing H2, H2O, CO and CO2; contacting the feed gas with the first adsorbent to provide a CO2 depleted feed gas; contacting the CO2 depleted feed gas with the shift catalyst to form a product mixture comprising CO2 and H2; and contacting the product mixture with a mixture of second adsorbent and shift catalyst to produce the product gas, which contains at least 50 vol. % H2, and less than 5 combined vol. % of CO2 and CO. The adsorbent is a high temperature adsorbent for a Sorption Enhanced Reaction process, such as K2CO3 promoted hydrotalcites, modified double-layered hydroxides, spinels, modified spinels, and magnesium oxides.

Abstract: A method for catalytic conversion of carbon monoxide with water to carbon dioxide and water in a hydrogen-containing gas mixture (carbon monoxide conversion) by passing the gas mixture over a shift catalyst that is at an operating temperature for the carbon monoxide conversion. The method is carried out with a shift catalyst based on noble metals that is applied to an inert support element in the form of a coating.

Abstract: Process for the preferential oxidation of carbon monoxide and/or CH3OH in a hydrogen containing process stream by contacting the process stream with a catalyst comprising gold on a support comprising non-reducible magnesium aluminium oxide in form of MgAl2O4 spinel.

Abstract: A method and apparatus for separating gas mixtures containing synthesis gas (syngas) into separate streams of wet hydrogen containing significantly reduced amounts of CO2 and CO, with the CO2 being “sequestration ready” and containing less than 1% fixed gases. In the preferred embodiment, a mixture of limestone and iron oxide circulates between two fluidized beds whereby one bed is fluidized with a gas containing syngas, while the other bed is fluidized with a gas containing steam and oxygen. As the fluidizing gas containing syngas passes through the bed, the CO2 reacts with CaO to form CaCO3. Virtually all of the CO is removed by a water gas shift reaction, forming hydrogen and CO2, with the remainder being removed by reaction with the iron oxide, reducing Fe2O3 to FeO. Some hydrogen is also removed by reaction with the iron oxide, reducing Fe2O3 to FeO, while the remainder of the hydrogen passes through the fluid beds, leaving in a purified state, i.e., PEM fuel cell quality.

Abstract: The reaction of carbon monoxide with steam over an alkali-modified ruthenium-on-zirconia catalyst has been found to yield surprisingly high yields of hydrogen gas at relatively low temperatures. Catalyst structures, reactors, hydrogen production systems, and methods for producing hydrogen utilizing the alkali-modified ruthenium-on-zirconia catalyst are described. Methods of making catalysts are also described.

Abstract: A reformer disposed in the flow path of a reactant fluid includes: a catalyst unit capable of generating hydrogen from a reactant fluid containing an organic compound or carbon monoxide, by catalysis, and an electrically heatable heater unit. An electrically heatable catalyst unit includes: any of a sintered material, a metallic material, a composite material thereof, at least a portion of each of these materials having an electrically heatable property, and a composite material of (1) a heat-resistant material having no electrically heatable property and (2) the sintered material and/or the metallic material, and a catalyst capable of generating hydrogen from a reactant fluid containing an organic compound or carbon monoxide, by catalysis, which catalyst unit has porosity, thereby enables diffusion of a reactant fluid therethrough, and is electrically heatable. The above reformer can generate high-purity hydrogen for use in fuel cell of industrial or automotive application, in a short time.

Abstract: Mono- and bimetallic transition metal carbides, nitrides and borides, and their oxygen containing analogs (e.g. oxycarbides) for use as water gas shift catalysts are described. In a preferred embodiment, the catalysts have the general formula of M1AM2BZCOD, wherein M1 is selected from the group consisting of Mo, W, and combinations thereof; M2 is selected from the group consisting of Fe, Ni, Cu, Co, and combinations thereof; Z is selected from the group consisting of carbon, nitrogen, boron, and combinations thereof; A is an integer; B is 0 or an integer greater than 0; C is an integer; O is oxygen; and D is 0 or an integer greater than 0. The catalysts exhibit good reactivity, stability, and sulfur tolerance, as compared to conventional water shift gas catalysts. These catalysts hold promise for use in conjunction with proton exchange membrane fuel cell powered systems.

Abstract: Reactors and processes are disclosed that can utilize high heat fluxes to obtain fast, steady-state reaction rates. Porous catalysts used in conjunction with microchannel reactors to obtain high rates of heat transfer are also disclosed. Reactors and processes that utilize short contact times, high heat flux and low pressure drop are described. Improved methods of steam reforming are also provided.

Abstract: A process for converting carbon monoxide and water in a reformate stream into carbon dioxide and hydrogen comprising: generating a reformate by reacting a hydrocarbon via partial oxidation, steam reforming, or both, including autothermal reforming; and promoting a water gas shift in the reformate in the presence of a platinum group metal selected from the group consisting of platinum, palladium, iridium, osmium, rhodium and mixtures thereof, supported on zirconium oxide. The platinum group metal advantageously may be supported directly on a monolithic substrate composed of zirconium oxide.

Abstract: A method and apparatus for processing a hydrocarbon fuel comprises: a primary fuel processing reactor for converting a feed stream to a first reformate stream comprising hydrogen; a first hydrogen separator located downstream of the primary fuel processing reactor and fluidly connected thereto for receiving the first reformate stream, the first separator comprising a first membrane for separating the first reformate stream into a first hydrogen-rich stream and a first retentate stream; and a secondary fuel processing reactor fluidly connected to the first separator for receiving and converting the first retentate stream to a second reformate stream comprising hydrogen. A fuel cell power generation system includes the present apparatus and a fuel cell stack fluidly connected thereto for receiving hydrogen-rich streams therefrom.

Abstract: The invention provides a process for carrying out the water gas shift reaction comprising employing a methane production suppressing water gas shift reaction catalyst, wherein the methane production suppressing water gas shift reaction catalyst comprises a methane production suppressing effective amount of a basic metal oxide.

Abstract: A method for conversion of carbon monoxide to carbon dioxide and hydrogen with water in a gas mixture containing hydrogen and other oxidizable components. An oxidation-active noble metal shift catalyst is the catalyst. The necessary operating temperature of the catalyst is established and optionally maintained by partial oxidation of the oxidizable components of the gas mixture.

Abstract: The present invention is a method and apparatus (vessel) for providing a heat transfer rate from a reaction chamber through a wall to a heat transfer chamber substantially matching a local heat transfer rate of a catalytic thermal chemical reaction. The key to the invention is a thermal distance defined on a cross sectional plane through the vessel inclusive of a heat transfer chamber, reaction chamber and a wall between the chambers. The cross sectional plane is perpendicular to a bulk flow direction of the reactant stream, and the thermal distance is a distance between a coolest position and a hottest position on the cross sectional plane. The thermal distance is of a length wherein the heat transfer rate from the reaction chamber to the heat transfer chamber substantially matches the local heat transfer rate.

Abstract: A process for converting carbon monoxide and water in a reformate stream into carbon dioxide and hydrogen comprising: generating a reformate by reacting a hydrocarbon via partial oxidation, steam reforming, or both, including autothermal reforming; and promoting a water gas shift in the reformate in the presence of a platinum group metal selected from the group consisting of platinum, palladium, iridium, osmium, rhodium and mixtures thereof, supported on zirconium oxide. The platinum group metal advantageously may be supported directly on a monolithic substrate composed of zirconium oxide.

Abstract: A process is provided for simultaneously producing a syngas product having a H2/CO ratio of less than 2.5 and a hydrogen gas product. The process includes increasing an amount of carbon dioxide being fed to a secondary reformer with carbon dioxide extracted from: (a) an effluent from a primary reformer and (b) an effluent from the secondary reformer. An apparatus for performing the process is also provided.

Abstract: An auto-oxidation and internal heating type reforming method and apparatus for hydrogen production are disclosed for use in a process in which a gaseous mixture of a hydrocarbon or an aliphatic alcohol with water vapor is fed into contact with a mass of a reforming catalyst to bring about a reforming reaction of the gaseous mixture to produce hydrogen, wherein a small amount of an oxidizing catalyst is admixed with the reforming catalyst in that mass; and a small amount of oxygen is admixed with the gaseous mixture, whereby a portion of the hydrocarbon or aliphatic alcohol is exothermally oxidized to generate a quantity of heat required to reform the gaseous mixture of the hydrocarbon or aliphatic alcohol with water vapor.

Abstract: A high temperature shift process using an iron oxide-containing catalyst wherein the feed gas is contacted with an iron-free, copper-containing, catalyst at an inlet temperature in the range 280-370° C. before contact with the iron oxide-containing catalyst in order to effect some shift reaction and thus avoid conditions conducive to over-reduction of the iron oxide containing catalyst.

Abstract: The present invention is a chemical reactor and method for catalytic chemical reactions having gas phase reactants. The chemical reactor has reactor microchannels for flow of at least one reactant and at least one product, and a catalyst material wherein the at least one reactant contacts the catalyst material and reacts to form the at least one product. The improvement, according to the present invention is: the catalyst material is on a porous material having a porosity that resists bulk flow therethrough and permits molecular diffusion therein. The porous material further has a length, a width and a thickness, the porous material defining at least a portion of one wall of a bulk flow path through which the at least one reactant passes.

Abstract: A CO-shift device includes a main body having therein a space in which a CO-shift catalyst is accommodated, the space being divided into an inner space and an outer space surrounding the inner space; an inlet portion formed at one end portion of the inner space, the inlet portion being supplied with a reformed gas such that the reformed gas flows through the inner space. An outlet portion is formed at one end portion of the outer space and a redirecting portion is provided between the other end portion of the inner space and the other end portion of the redirecting portion, thereby reversing the reformed gas flown into the other end of the inner space in order that the resulting reformed gas passes through the outer space to be exhausted from the outlet portion, the reformed gas being shifted to reduce CO by the CO-shift catalyst during its movement through the inner and outer spaces.

Abstract: A shift converter (16) in a fuel processing subsystem (14, 16, 18) for a fuel cell (12) uses an improved catalyst composition (50) to reduce the amount of carbon monoxide in a process gas for the fuel cell (12). The catalyst composition (50) is a noble metal catalyst having a promoted support of mixed metal oxide, including at least both ceria and zirconia. Cerium is present in the range of 30 to 50 mole %, and zirconium is present in the range of 70 to 50 mole %. Additional metal oxides may also be present. Use of the catalyst composition (50) obviates the requirement for prior reducing of catalysts, and minimizes the need to protect the catalyst from oxygen during operation and/or shutdown.

Abstract: The reaction of carbon monoxide with steam over an alkali-modified ruthenium-on-zirconia catalyst has been found to yield surprisingly high yields of hydrogen gas at relatively low temperatures. Catalyst structures, reactors, hydrogen production systems, and methods for producing hydrogen utilizing the alkali-modified ruthenium-on-zirconia catalyst are described. Methods of making catalysts are also described.

Abstract: The ammonia content of fuel gas in an IGCC power generation system is reduced through ammonia decomposition, thereby reducing the NOx emissions from the plant. The power generation system includes a gasifier, a gas turbine and at least one catalytic reactor arranged between the gasifier and the gas turbine. The catalytic reactor may be either a three stage or two stage device. The three stage reactor includes a first catalyst which promotes water-gas-shift, a second catalyst which promotes CO methanation, and a third catalyst which promotes ammonia decomposition. The two stage reactor includes a first catalyst which promotes water-gas-shift and CO methanation and a second catalyst which promotes ammonia decomposition. The plural catalytic stages may be disposed in a single vessel or successively disposed in individual vessels, and the catalysts may be in a pelletized form or coated on honeycomb structures.

Abstract: The present invention provides a method of producing a CuZnAlZr oxide catalyst consisting of reacting an aqueous NaOH solution and aqueous NACO3 solution with a mixture of aqueous solutions of each nitrate of Cu, Zn, Al, and Zr, producing a precipitate by coprecipitation, aging, filtering, washing and drying this precipitate to prepare a catalyst precursor consisting of a CuZnAlZr layered double hydroxide, and then obtaining a CuZnAlZr oxide by calcining this precursor in an air ambient atmosphere, a CuZnAlZr oxide catalyst, a CuZnZrCe oxide catalyst, a CoCuZnAl oxide catalyst for producing hydrogen by oxidative steam reforming of methanol, and methods of producing hydrogen gas consisting of converting methanol to hydrogen gas by oxidative steam reforming in the presence of air and steam using these oxide catalysts.

Abstract: Sulphides and selenides are prepared by dissolving sulphur or selenium in an aqueous or non-aqueous solution of hydrazine hydrate. The solution is combined with a solution of an appropriate cation to precipitate the corresponding sulphide or selenide. Solutions of two or more cations may be used to produce ternary compounds of sulphur and selenium, for example thio-gallates. Likewise both sulphur and selenium can be used together to produce sulpho-selenides. The method is particularly applicable to the production of doped phosphors by the inclusion of solutions containing the appropriate dopant.

Abstract: A process for recovering hydrogen products from a hydrogen/carbon oxide synthesis gas wherein removal of carbon oxides is accomplished in a pressure swing adsorption unit, by operating the pressure swing adsorption unit until carbon oxides break through into the effluent from the pressure swing adsorption unit, followed by passing the effluent from the pressure swing adsorption unit through a methanator to remove breakthrough carbon oxides from the pressure swing adsorption effluent.

Abstract: A process and apparatus are disclosed for the operation of a compact water gas shift reactor for use in conjunction with fuel cell to generate electric power from a feedstream comprising a hydrocarbon or an alcohol. The fuel cell comprises a proton exchange membrane which produces electric power from a hydrogen product stream which comprises essentially no carbon monoxide. The hydrogen product stream may be produced from the feedstream in a steam reforming of autothermal reforming zone. The compact water gas shift reactor comprises a vertically aligned vessel having a top end, a bottom end opposite, which defines an interior space. The interior space contains a first water spray zone for contacting a reforming effluent stream comprising hydrogen with a first water stream. A first dispersion zone is disposed below the first water spray zone and above a high temperature shift zone. The high temperature shift zone contains a high temperature shift catalyst to produce a high temperature shift effluent stream.

Abstract: The present invention is a method and apparatus (vessel) for providing a heat transfer rate from a reaction chamber through a wall to a heat transfer chamber substantially matching a local heat transfer rate of a catalytic thermal chemical reaction. The key to the invention is a thermal distance defined on a cross sectional plane through the vessel inclusive of a heat transfer chamber, reaction chamber and a wall between the chambers. The cross sectional plane is perpendicular to a bulk flow direction of the reactant stream, and the thermal distance is a distance between a coolest position and a hottest position on the cross sectional plane. The thermal distance is of a length wherein the heat transfer rate from the reaction chamber to the heat transfer chamber substantially matches the local heat transfer rate.

Abstract: Process for the production of a hydrogen rich gas without formation of hydrocarbons comprising water gas shift conversion of a gas containing carbon monoxide and steam at a temperature of between 400° C. and 850° C. in the presence of a catalyst, which catalyst comprises one or more of the elements Mg, Mn, Al, Zr, La, Ce, Pr, and Nd, being able to form basic oxides, and mixtures thereof.

Abstract: A method of forming a hydrogen rich gas from a source of hydrocarbon fuel. A vapor of the hydrocarbon fuel and steam is brought in contact with a two-part catalyst having a dehydrogenation powder portion and an oxide-ion conducting powder portion at a temperature not less than about 770°C. for a time sufficient to generate the hydrogen rich. The H2 content of the hydrogen gas is greater than about 70 percent by volume. The dehydrogenation portion of the catalyst includes a group VIII metal, and the oxide-ion conducting portion is selected from a ceramic oxide from the group crystallizing in the fluorite or perovskite structure and mixtures thereof. The oxide-ion conducting portion of the catalyst is a ceramic powder of one or more of ZrO2, CeO2, Bi2O3, (BiVO)4, and LaGaO3.

Abstract: A high temperature shift process using an iron oxide-containing catalyst wherein the feed gas is contacted with an iron-free, copper-containing, catalyst at an inlet temperature in the range 280-370° C. before contact with the iron oxide-containing catalyst in order to effect some shift reaction and thus avoid conditions conducive to over-reduction of the iron oxide containing catalyst.

Abstract: A process for converting organic compounds using composite materials in membrane reactors. The composite materials include a gas-tight ceramic, a porous metallic support, and an interfacial zone therebetween eliminate the need for mechanical seals between two such dissimilar materials. Oxygen ion-conducting dense ceramic membranes are formed on a porous metallic alloy to provide an interfacial zone identifiable by a gradient of composition in at least one metallic element across the interfacial zone between the dense ceramic membrane and the porous support. Processes using composite materials in accordance with the invention are, for example, used for production of synthesis gas comprising carbon monoxide and molecular hydrogen, whereby the synthesis gas is, advantageously, free of deleterious and/or inert gaseous diluents such as nitrogen.

Abstract: This specification discloses a hydrogen generating apparatus comprising a reformer, a heating section, a fuel supply section, a water supply section, a shift reactor with a shift catalyst layer, a first heat exchanger on the downstream side of the shift catalyst layer, and a temperature detector for the shift catalyst layer. It is the most notable feature of the hydrogen generating apparatus of the present invention that the temperature of the downstream portion of the shift catalyst layer is raised by the action of the heat exchanger compared with the temperature of the same before the amount of the reformed gas is increased. And, the temperature of the downstream portion is lowered compared with the temperature of the same before the amount of the reformed gas is reduced when reducing the amount of the reformed gas.

Abstract: The invention provides a carbon monoxide conversion method for hydrogen-containing gas. The method comprises selective CO conversion in hydrogen-containing gas through contact of CO with steam and oxygen in the presence of a catalyst containing copper, alumina and zinc oxide.

Abstract: A process for the separation and removal, of hydrogen, alone or together with carbon monoxide, if present, from a mixture of these gases with reactive unsaturated hydrocarbons, by contacting the mixture with oxygen over a catalyst at conditions sufficient to oxidize the hydrogen to form water while suppressing reaction of the reactive, unsaturated hydrocarbons. The catalyst contains at least one metal or metal oxide from Groups IB, IIB, IIIB, IVB, VB, VIB, VIIB, and VIII of the Periodic Table, and the temperature of the reaction may range from about 40.degree. C. to about 300.degree. C., the pressure of the reaction ranges from about 14.7 psig to 1,000 psig, and the flow rate of the entering feed ranges from about 1 GHSV to about 50,000 GHSV. Oxygen amounts less than the stoichiometric amount required to react with the hydrogen, and optionally any carbon monoxide, are used.

Abstract: A method of treating wastes includes partially combusting the wastes in a fluidized bed reactor at a relatively low temperature followed by separate gasification of gaseous material and char from the first gasification in a separate relatively high temperature reactor. This forms synthesis gas that is cooled, subjected to a conversion operation to produce hydrogen.

Abstract: The present invention is directed to a process for simultaneously obtaining pure carbon monoxide and pure hydrogen in a steam reformer plant for hydrogen or ammonia generation, having a primary reformer, a secondary reformer and downstream thereof, a CO conversion stage. A part gas stream of the synthesis gas stream, which is discharged from the secondary reformer having a CO content of between 2 and 20 mol. % and is at a temperature of from 200 to 500.degree. C. and a pressure between 15 and 50 bar, is removed between the secondary reformer and the CO conversion stage. The part gas stream is then is cooled to a temperature below 100.degree. C., thereby condensing out the major part of the steam contained in the gas stream. The remaining raw synthesis gas stream is then guided by way of a multistage gas separation plant in which the gas components H.sub.2, residual steam, CH.sub.4, CO.sub.2 and optionally N.sub.2 are separated, either individually or together, from the CO.

Abstract: Disclosed are a catalyst suitable for the conversion of carbon monoxide with steam into carbon dioxide and hydrogen, and a process therewith for said conversion. Said catalyst comprises Co, Ni, Mo and/or W active components, TiO.sub.2 -containing carrier and non-alkali metal element promoter(s). Said process comprises reacting carbon monoxide feed gas containing 0.01% or more of H.sub.2 S by volume with steam in the presence of said catalyst at a temperature between 230 to 500.degree. C. under a pressure between 0 to 10 MPa (absolute) with a relatively high yield, whereby heavy fuel can be used as a source of carbon monoxide feed gas for such a process.

Abstract: A catalyst for the conversion of carbon oxide comprising 30 to 70% CuO, 20 to 90% ZnO, 0.1 to 20% of an element of Group IV-B in the form of an oxide, preferably titanium and/or zirconium, most preferably titanium, about 5 to about 40 percent Al.sub.2 O.sub.3 and preferably 50 to 1000 ppm of a Group 1-A element in the form of an oxide.

Abstract: A method and apparatus for treating wastes by two-stage gasification recovers metals or ash content in the wastes in such a state that they can be recycled, and gases containing carbon monoxide (CO) and hydrogen gas (H.sub.2) for use as synthesis gas for ammonia (NH.sub.3) or production of hydrogen gas. The wastes are gasified in a fluidized-bed reactor at a low temperature. Then, gaseous material and char produced in the fluidized-bed reactor are introduced into a high-temperature combustor, and gasified at a high temperature and ash content is converted into molten slag. After water scrubbing and a CO conversion reaction, the gas is separated into H.sub.2 and residual gas. The residual gas is then supplied to the fluidized-bed reactor as a fluidizing gas.

Abstract: A process for producing hydrogen gas by reacting steam with a gas mixture containing carbon monoxide, carbon dioxide and hydrogen to produce a hydrogen-enriched product gas and subjecting the product gas to pressure swing adsorption to produce a high purity hydrogen product and a hydrogen-depleted waste gas is improved by drying, where necessary, part of the gas mixture and subjecting the dry gas mixture to pressure swing adsorption using a carbon monoxide-selective adsorbent to produce a high purity carbon monoxide product gas and a carbon monoxide-depleted waste gas. Where the gas mixture is produced by endothermic reaction, one or both of the hydrogen-depleted waste gas and the carbon monoxide-depleted waste gas can be used as fuel to supply heat for the endothermic reaction.

Abstract: A method of forming a hydrogen rich gas from a source of hydrocarbon fuel in which the hydrocarbon fuel contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion at a temperature not less than about 400.degree. C. for a time sufficient to generate the hydrogen rich gas while maintaining CO content less than about 5 volume percent. There is also disclosed a method of forming partially oxidized hydrocarbons from ethanes in which ethane gas contacts a two-part catalyst comprising a dehydrogenation portion and an oxide-ion conducting portion for a time and at a temperature sufficient to form an oxide.

Abstract: A method and apparatus for treating wastes by gasification recovers metals or ash content in the wastes in such a state that they can be recycled, and gases containing carbon monoxide (CO) and hydrogen (H.sub.2) for use as synthesis gas of ammonia (NH.sub.3). The wastes are gasified in a fluidized-bed reactor at a relatively low temperature, and gaseous material and char produced in the fluidized-bed reactor are introduced into the high-temperature combustor. The synthesis gas is produced in the high-temperature combustor at a relatively high temperature, CO and H.sub.2 O in the synthesis gas is converted into CO.sub.2 and H.sub.2, and then H.sub.2 is recovered by removing CO.sub.2.

Abstract: A method for conducting a chemical reaction with a catalyst composed of metal oxide particles among which are uniformly incorporated, in order to reduce the operating temperature of the catalyst, palladium particles.

Abstract: The invention relates to a catalyst for conversion of carbon monoxide with steam into hydrogen, carbon dioxide and hydrogen-rich synthesis gases. The conversion can be done at temperatures above roughly 300.degree. C. In addition, a chromium-free catalyst for the aforementioned purpose is described which contains the following in "application form:"(a) 30-98% by weight iron oxide, computed as Fe.sub.2 O.sub.3 ;(b) 0.1-20% by weight copper oxide, computed as CuO;(c) 0.1-20% by weight of an oxide of the rare earth levels computed as Me.sub.2 O.sub.3 (in which Me is a rare earth metal) and/or zirconium oxide, computed as ZrO.sub.2 ;(d) 0.1-30% by weight of at least one oxide of one or several other base metals with an ionic radius from 50 to 72 pm (other than chromium)(e) 0-0.1% by weight of at least one oxide of one or several precious metals from the platinum group;(f) 0-30% by weight barium oxide.

Abstract: Hot exhaust gases from oxygen-based fossil fuel fired-furnaces made up predominantly of steam and carbon dioxide are used for reforming a hydrocarbonaceous substance in the presence or absence of oxygen to produce carbon monoxide and hydrogen. Additional hydrogen can be produced by subjecting the carbon monoxide produced in the reaction to the water gas shift reaction.