Abstract: A method of manufacturing crystalline microporous material suitable for manufacturing a variety of crystalline microporous material under mild reaction conditions and under safe working environmental conditions by using simple installation. The crystalline microporous materials obtained by the present invention may be used as adsorbent agent, catalyst or separating material. According to the characterizing features of the manufacturing method of the present invention, there are provided a method of using cation compound or amine as crystallizing modifier and using, in combination, raw material including canemite or silicon dioxide and a further method using raw material including silicon dioxide and aluminum salt. The method includes a step of mixing these components, a solid-liquid separating step for separating produced fine particles, and a crystallizing step for crystallizing the separated solid component.
Type:
Grant
Filed:
May 28, 1999
Date of Patent:
February 8, 2000
Assignees:
Kuboto Corporation, Japan as represented by Director General of Agency of Industrial Science and Technology
Abstract: New synthetic zeolites incorporating alkaline earth elements and routes for preparing those zeolites by hydrothermal alteration of zeolite P1 are disclosed. New methods for producing P1 zeolites are also identified. Synthetic heulandite, brewsterite, epistilbite and harmotome, among other zeolites can be prepared.
Abstract: Methods for using amino acid as a directing agent in zeolite synthesis are disclosed comprising the steps of:(a) forming a reaction mixture containing water, an alumina source, a silica source, an alkali metal oxide source, and an amino acid as an exterior directing agent; and(b) recovering a porous inorganic solid from said reaction mixture of step (a).
Abstract: Molecular sieve compositions are prepared by extracting aluminum and substituting chromium and/or tin for extracted aluminum to give molecular sieve products containing framework chromium and/or tin atoms. The process of preparing the chromium and/or tin-containing molecular sieves involves contacting a starting molecular sieve with a solution or slurry of at least one of a fluoro salt of chromium or a fluoro salt of tin under effective process conditions to provide for aluminum extraction and substitution of chromium and/or tin.
Type:
Grant
Filed:
November 8, 1994
Date of Patent:
May 21, 1996
Assignee:
UOP
Inventors:
Gary W. Skeels, Diane M. Chapman, Edith M. Flanigen
Abstract: Molecular sieve compositions are prepared by extracting aluminum and substituting chromium and/or tin for extracted aluminum to give molecular sieve products containing framework chromium and/or tin atoms. The process of preparing the chromium and/or tin-containing molecular sieves involves contacting a starting molecular sieve with a solution or slurry of at least one of a fluoro salt of chromium or a fluoro salt of tin under effective process conditions to provide for aluminum extraction and substitution of chromium and/or tin.
Type:
Grant
Filed:
June 26, 1992
Date of Patent:
March 28, 1995
Assignee:
UOP
Inventors:
Gary W. Skeels, Diane M. Chapman, Edith M. Flanigen
Abstract: A process for the dealumination of a zeolite having the structure of mordenite by contacting the zeolite with dicarboxylic acid, such as oxalic acid, and steaming. The process is useful for the dealumination of TEA mordenite.
Abstract: The object of the invention is a synthetic crystalline zeolite of the mordenite type characterized by:a) the following approximate general formula:Na.sub.2 O, Al.sub.2 O.sub.3, xSiO.sub.2where x is a number ranging from 9 to 30, andb) an X-ray diffraction diagram represented in table I of the description,c) a fluorine content ranging from about 0.005 to 2.0% by weight,and in that it has been synthetized in a fluoride medium.The invention also relates to a process for preparing said zeolite.This zeolite can notably be utilized in adsorption and in catalysis.
Type:
Grant
Filed:
March 30, 1992
Date of Patent:
June 1, 1993
Assignee:
Institut Francais du Petrole
Inventors:
Philippe Caullet, Jean-Louis Guth, Anne-Catherine Faust, Jean-Francois Joly, Christine Travers, Francis Raatz