Abstract: ZSM-22 zeolite which is particularly pure and whose synthesis does not require the synthesis mixture to be stirred can be produced by the addition to the synthesis mixture of a small quantity e.g. 1000 ppm, of preformed ZSM-22 zeolite seed crystals.
Type:
Grant
Filed:
December 9, 1994
Date of Patent:
February 2, 1999
Assignee:
Exxon Chemical Patents, Inc.
Inventors:
Johannes Petrus Verduijn, Luc Roger Marc Martens
Abstract: Crystalline zeolites are prepared using a small quantity of an organic templating compound and a larger quantity of an amine component containing at least one amine having from one to eight carbon atoms, ammonium hydroxide, or mixtures thereof.
Abstract: ZSM-22 zeolite which is particularly pure and whose synthesis does not require the synthesis mixture to be stirred can be produced by the addition to the synthesis mixture of a small quantity e.g. 1000 ppm, of preformed ZSM-22 zeolite seed crystals.
Type:
Grant
Filed:
October 16, 1996
Date of Patent:
July 21, 1998
Assignee:
Exxon Chemical Patents Inc.
Inventors:
Johannes Petrus Verduijn, Luc Roger Marc Martens
Abstract: The invention concerns a composition comprising at least one matrix, at least one faujasite type zeolite and at least one TON type zeolite. The TON type zeolite can be Nu-10, THETA-1, KZ-2, or ISI-1. The catalyst also contains at least one hydrogenating element from groups VIII and VI.The catalyst is particularly for use for hydrocracking to maximize the yield of middle distillates (kerosine and gas oil).
Type:
Grant
Filed:
January 21, 1997
Date of Patent:
June 9, 1998
Assignee:
Institut Francais du Petrole
Inventors:
Eric Benazzi, Samuel Mignard, Nathalie George-Marchal, Slavik Kasztelan
Abstract: Silica-bound extruded zeolites may be converted into binder-free zeolite aggregates by aging the zeolite in an aqueous ionic solution which contains hydroxy ions such that the initial molar ratio of OH.sup.- :SiO.sub.2 is up to 1.2 and which causes the silica binder to be converted substantially to zeolite of the type initially bound. Such extrudates have excellent mechanical strength and show advantageous properties such as adsorption comparable with non-extruded zeolite powder.
Abstract: Silica-bound extruded zeolites may be converted into binder-free zeolite aggregates by aging the zeolite in an aqueous ionic solution which contains hydroxy ions such that the initial molar ratio of OH-:SiO.sub.2 is up to 1.2 and which causes the silica binder to be converted substantially to zeolite of the type initially bound. Such extrudates have excellent mechanical strength and show advantageous properties such as adsorption comparable with non-extruded zeolite powder.
Abstract: A process for the selective surface dealumination of a zeolite having a Constraint Index greater than 1 by contacting the zeolite with dicarboxylic acid, such as oxalic acid.