Retroreflector (e.g., Light Reflecting Small Spherical Beads, Etc.) Patents (Class 427/163.4)
  • Publication number: 20100112340
    Abstract: A quantity of retroreflective granules includes glass members each having a refractive index of at least about 1.5. The quantity of retroreflective granules can be partially embedded into a binder material applied on the surface of a structure to provide a visual aid. A structure includes a retroreflective surface having an inclined face defined on at least a portion of the structure. The retroreflective surface also includes a binder material applied to at least a portion of the inclined face of the structure. The binder material has a thickness dimension of at least about 10 mil. The retroreflective surface further includes a plurality of retroreflective granules partially embedded in the binder material. The plurality of retroreflective granules have a density of at least about 0.06 pounds/square foot as embedded in the binder material. Each retroreflective granule includes a glass member having a refractive index of at least about 1.5.
    Type: Application
    Filed: October 31, 2008
    Publication date: May 6, 2010
    Applicant: Potters Industries Inc.
    Inventor: Thomas Reuben Bell
  • Publication number: 20100053639
    Abstract: A retro-reflector for image-guided operation systems, comprising eight cube corners, wherein the tips of the cube corners are adjacent to each other and each cube corner is formed from three reflective faces, comprising a protection against contamination which prevents dirt from being deposited in the cube corners.
    Type: Application
    Filed: September 3, 2009
    Publication date: March 4, 2010
    Inventor: Christian Maier
  • Patent number: 7658980
    Abstract: A tamper-indicating printable sheet. A preferred embodiment of the invention provides a tamper-indicating printable sheet comprising a retroreflective layer comprising a plurality of microbeads partially embedded in an inkjet receptive beadbond layer; and a reflector layer between one of the microbeads and the inkjet receptive beadbond layer. The present invention provides a method of making a tamper-indicating printable sheet.
    Type: Grant
    Filed: August 3, 2005
    Date of Patent: February 9, 2010
    Assignee: 3M Innovative Properties Company
    Inventors: Richard J. Kuo, Mathias Detjen, Brian W. Dunne, Paul E. Marecki, Tadesse G. Nigatu, Kenneth M. White
  • Patent number: 7646956
    Abstract: An optical waveguide sheet that has an auxiliary layer for preventing light transmitted through the waveguide sheet from leaking or being lost and a manufacturing method thereof. The waveguide sheet transmits light from a light emitting element thereinto, and has a reflecting pattern for reflecting light forward. At least one auxiliary layer for providing a total reflection condition for preventing the light from leaking or being lost when the light is transmitted into the waveguide sheet is coated on the waveguide sheet.
    Type: Grant
    Filed: January 30, 2008
    Date of Patent: January 12, 2010
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Yong-Wook Hwao, Chang-Youn Hwang, Young-Ki Kim, Shin-Chul Kang, Ki-Duk Jang
  • Publication number: 20090141359
    Abstract: A polymer film with an optical interference system. The optical interference system comprises at least two layers of different refractive index, which layers comprise nanoscale inorganic particles having organic surface groups that are polymerizable and/or polycondensable. The layers are at least partially crosslinked through the organic surface groups.
    Type: Application
    Filed: February 10, 2009
    Publication date: June 4, 2009
    Inventors: Anette BERNI, Martin MENNIG, Peter W. OLIVEIRA, Helmut SCHMIDT
  • Publication number: 20090065583
    Abstract: A retro-emissive marking system that returns a coded-spectrum optical signal to a source of an interrogation beam is described. The system is valuable for applications such track-and-trace systems, vehicle markings, anti-counterfeit/security, inventory control, animal ear tags, product authentication, identification cards, and security systems; and it also has value as a remotely readable sensor of chemical or biological agents.
    Type: Application
    Filed: March 10, 2006
    Publication date: March 12, 2009
    Inventor: Stephen P. McGrew
  • Publication number: 20090015908
    Abstract: The infrared reflective device includes infrared reflective members which reflect infrared rays. The infrared reflective members include colloidal particles arranged at regular spacing, and a filler material intervening in the spaces between the colloidal particles. The difference between the refractive index of the colloidal particles and the refractive index of the filler material is set so as to be 0.05 or less in the visible light region and 0.1 or above in the infrared region, whereby visible light is transmitted while infrared rays are reflected.
    Type: Application
    Filed: July 10, 2008
    Publication date: January 15, 2009
    Applicant: TOYODA GOSEI., LTD.
    Inventors: Hiroaki Ando, Takeshi Miyazaki, Hiroshi Nakamura, Masahiko Ishii
  • Publication number: 20080206458
    Abstract: A method for producing an anti-glare film includes applying a coating composition including at least a resin, a solvent, and fine particles to a substrate; drying the coating composition applied to the substrate so that a Benard cell structure is formed in the surface of the coating layer due to convection caused during volatilization of the solvent; and curing the resin contained in the coating composition having formed therein a Benard cell structure to form an anti-glare layer having fine irregularities with a moderate surface waviness. The anti-glare layer has a degree of white muddiness of 1.7 or less, as measured by quantitatively determining a diffuse reflection component of the diffused light incident upon the surface of the anti-glare layer.
    Type: Application
    Filed: March 14, 2008
    Publication date: August 28, 2008
    Applicant: SONY CORPORATION
    Inventors: Hitoshi Watanabe, Yumi Haga, Tsutomu Nagahama, Shinichi Matsumura
  • Publication number: 20080198460
    Abstract: The present invention includes conformable retroreflective structures. In some embodiments, the conformable retroreflective structures are also shrink resistant. The conformable retroreflective structures include a transparent plasticized polyvinyl chloride film having a first side and a second side; a first transparent polymer layer overlying the first side of the plasticized polyvinyl chloride film; a second transparent polymer layer overlying the second side of the plasticized polyvinyl chloride film; an array of retroreflective cube-corner elements underlying the second transparent polymer layer; and a plasticizer resistant adhesive underlying the array of retroreflective cube-corner elements. In some embodiments, the first and second transparent polymer layers are transparent, radiation-cured polymer layers.
    Type: Application
    Filed: April 24, 2008
    Publication date: August 21, 2008
    Applicant: Reflexite Corporation
    Inventor: Leo Moreau
  • Publication number: 20080063862
    Abstract: In a lighting device for a vehicle including a reflector in which an aluminum deposited layer is formed on a surface of a resin member, the resin member is molded through a resin obtained by adding, to a crystalline resin, a filler having a size smaller than a wavelength of a visible light, and a smooth surface and a fine concavo-convex surface are mixed into a surface of the reflector (the resin member) which is molded. The aluminum deposited layer is directly deposited on the surface of the resin, and the smooth surface is formed as a mirror finished surface and the fine concavo-convex surface is formed as a semiglossy surface. As compared with a case in which the reflector is constituted by only the simple mirror finished surface, the semiglossy surface designed to have a proper area is present so that a sense of gloss can be suppressed as a whole and a sense of high quality can be given.
    Type: Application
    Filed: September 13, 2007
    Publication date: March 13, 2008
    Applicant: KOITO MANUFACTURING CO., LTD.
    Inventors: Toshimasa IKEDA, Takahiro KOHATA
  • Patent number: 7323217
    Abstract: An optical-interference type reflective panel and a method for making the same are disclosed, wherein the display panel has a substrate on which multiple supporting layers are firstly formed. Then, a plurality of first conductive optical film stacks, spacing layers and multiple second conductive optical film stacks are sequentially formed on the substrate. Finally, once the spacing layers are removed, optical-interference regulators are formed. Since said supporting layers forming step is prior to the first conductive optical film stacks, a precise back-side exposing step is not necessary so that the making procedure of the panel is simplified.
    Type: Grant
    Filed: October 31, 2005
    Date of Patent: January 29, 2008
    Assignee: QUALCOMM MEMS Technologies, Inc.
    Inventors: Wen-Jian Lin, Hsiung-Kuang Tsai
  • Patent number: 7286111
    Abstract: A display writer for writing on a light writable display of the type having a layer of cholesteric liquid crystal material disposed between two conductors, the cholesteric liquid crystal material having multiple stable optical states at zero electrical field; and a light absorber for forming an image wise thermal pattern in the cholesteric liquid crystal sufficient to change the optical state of the cholesteric liquid crystal in response to an image wise pattern of light, the display writer including a flash lamp; a reflective light modulator for modulating light from the flash lamp an image wise pattern; optics for directing the image wise modulated light onto the light writable display; and means for applying an electrical field to the conductors of the display in conjunction with activation of the flash lamp.
    Type: Grant
    Filed: November 13, 2003
    Date of Patent: October 23, 2007
    Assignee: Eastman Kodak Company
    Inventor: Stanley W. Stephenson, III
  • Patent number: 7252864
    Abstract: Disclosed is an optical film that comprises certain radiation cured (meth)acrylate binders and, desirably, irregular semicrystalline asymmetric particles.
    Type: Grant
    Filed: November 12, 2002
    Date of Patent: August 7, 2007
    Assignee: Eastman Kodak Company
    Inventors: Mridula Nair, Tamara K. Jones, Bradley M. Houghtaling, Joseph S. Sedita, Gary A. Rakes
  • Patent number: 7235280
    Abstract: A target for use in photogrammetric analysis that does not distort the object to be analyzed has been developed. The target is formed by mixing a diffuse material with a solvent and then applying the mixture to the surface of the object to be analyzed. The object is then coated with a reflective material so that the diffuse material forms a reflective target suitable for use in photogrammetric analysis.
    Type: Grant
    Filed: November 12, 2003
    Date of Patent: June 26, 2007
    Assignee: SRS Technologies, Inc.
    Inventors: Paul Gierow, Greg Laue, William Clayton, David Murphy
  • Patent number: 7229663
    Abstract: A method of making a liquid-crystal sheet material, useful for displays, having polymer-dispersed cholesteric liquid crystals, comprising the steps of providing a emulsion comprising dispersed cholesteric liquid crystal domain and a solution comprising gelatin and a hardening agent, coating said emulsion onto a substrate; and drying said emulsion to form polymer-dispersed liquid-crystal domains dispersed in a continuous matrix comprising hardened gelatin. The invention is also directed to a display having an imaging layer comprising domains of polymer-dispersed cholesteric liquid-crystal material dispersed in a continuous matrix comprising hardened gelatin, said imaging layer disposed between first and second conductors. The invention is advantageous in reducing sensitivity to temperature and/or high humidity, especially in thin displays or displays that are open to the environment.
    Type: Grant
    Filed: July 14, 2003
    Date of Patent: June 12, 2007
    Assignee: Eastman Kodak Company
    Inventors: Stanley W. Stephenson, Charles M. Rankin
  • Patent number: 7201939
    Abstract: An optical member (for example, optical fiber) is dipped in a coating solution having a film forming material dissolved therein to form an antireflection film on the end surface of the optical member. When the optical member is pulled up from the coating solution, the angle formed by the level of the coating solution and the end surface of the optical member, or the pulling speed is varied to adjust the film thickness or reflectance of the antireflection film to be formed on the end surface of the optical member. The film forming material is a fluorine-containing compound. The antireflection film is formed by dipping. The film thickness of the antireflection film is uneven.
    Type: Grant
    Filed: July 21, 2003
    Date of Patent: April 10, 2007
    Assignee: Kabushiki Kaisha Topcon
    Inventors: Takashi Takahashi, Masakazu Komine, Kazumii Kokubo, You Umeda
  • Patent number: 7182829
    Abstract: Retroreflective sheeting includes a body layer having a structured surface with recessed faces forming cube corner cavities. A reflective film is disposed at least on the recessed faces, and a fill material fills the cube corner cavities. The fill material comprises radiation-curable materials, adhesives, or both, and preferably transparent radiation-curable pressure-sensitive adhesives. The fill material preferably forms a continuous layer covering both the recessed faces and upper portions of the structured surface. A transparent cover layer preferably contacts the fill material layer.
    Type: Grant
    Filed: May 30, 2001
    Date of Patent: February 27, 2007
    Assignee: 3M Innovative Properties Company
    Inventors: Kenneth L. Smith, Gerald M. Benson, Michele A. Craton, Michael P. Daniels, Roger E. Luehrs
  • Patent number: 7136562
    Abstract: A process for forming a light guide plate with a reflection film includes: (a) providing a light guide plate (30), which has a light input surface (303) with light incident portions (3032), a bottom surface (304), a light output surface (301), and side surfaces (302); (b) attaching protection film (32) on the light incident portions and the light output surface; (c) providing a reflection solution; (d) dipping the light guide plate in the reflection solution; (e) removing the light guide plate from the reflection solution, and solidifying a portion of the reflection solution remaining on the light guide plate to thereby form a reflection film; and (f) removing the protection film to expose the light incident portions and the light output surface. Because the reflection film is directly attached to the light guide plate, there is no gap and no attendant leakage of light.
    Type: Grant
    Filed: August 23, 2004
    Date of Patent: November 14, 2006
    Assignee: Hon Hai Precision Ind. Co., Ltd.
    Inventors: Chun-Yu Lee, Ming-Chiang Tsai, Tsung-Wei Chiang
  • Patent number: 7063872
    Abstract: A film having a high transmittance and matt property is disclosed which has, on a transparent support 1, a hard coat layer 2 incorporated therein particles 4 of a particle size of 1.0 to 10 ?m that is larger than the layer thickness thereof, and a low-refractive-index layer 3 having a refractive index of 1.45 or less and covering said hard coat layer, wherein a haze value is 1.0% or more, and a total transmittance of light is 93.5% or more. The film having a high transmittance can prevent occurrence of unevenness of display due to thermal expansion of a light-tuning film and occurrence of unevenness of brightness peculiar to the light-tuning film.
    Type: Grant
    Filed: February 4, 2000
    Date of Patent: June 20, 2006
    Assignee: Fuji Photo Co., Ltd.
    Inventors: Ichiro Amimori, Hiroshi Inoue, Hidetoshi Watanabe
  • Patent number: 7011913
    Abstract: A method of making a reflective film includes the steps of: (a) preparing a cholesteric mixture that includes a cholesteric liquid crystal material and at least one type of polymerizable compound; (b) forming a cholesteric mixture layer in which the cholesteric liquid crystal material forms a helical structure, having continuously changing helical pitches, approximately along a normal to the layer; and (c) exposing the cholesteric mixture layer to an actinic ray at a temperature, at which the cholesteric mixture exhibits a cholesteric phase, thereby polymerizing the at least one type of polymerizable compound. In this method, a Tni point of the cholesteric mixture increases by performing the step (c).
    Type: Grant
    Filed: August 12, 2002
    Date of Patent: March 14, 2006
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Tomoko Teranishi, Sayuri Fujiwara
  • Patent number: 6933019
    Abstract: A method of applying a polymer coating uses a nebulized aerosol of solubilized polymer solution having high-viscosity droplets and low-viscosity droplets to form a textured antireflective surface. Air or other gas is used to direct the nebulized aerosol toward the surface of an object. In some embodiments, heated or dried air, such as from an air curtain, is used to promote the formation of high-viscosity droplets. In a particular embodiment, multiple ultrasonic nebulizers are used in combination with synchronized air jets to apply a uniform polymer coating onto a glass panel used in a large-format display system. Dye is optionally added to the solubilized polymer solution to provide a notch filter at 585 nm and/or infrared filter.
    Type: Grant
    Filed: November 6, 2003
    Date of Patent: August 23, 2005
    Assignee: JDS Uniphase Corporation
    Inventors: Thomas Mayer, Hiren V. Shah, Brad A. Duffy, Richard K. Zoborowski
  • Patent number: 6929830
    Abstract: A method for treating a non-planar surface of an object by employing a plasma treatment apparatus in which a microwave dielectric has a non-planar surface corresponding to the surface of the object. A method for forming an optical part is also provided.
    Type: Grant
    Filed: June 2, 2003
    Date of Patent: August 16, 2005
    Assignee: Canon Kabushiki Kaisha
    Inventors: Goushu Tei, Nobuyoshi Tanaka, Tadahiro Ohmi, Masaki Hirayama
  • Patent number: 6852376
    Abstract: An antiglare film applicable to polarizers or displays includes a light-transparent resin, first light-transparent particles dispersed on surface of the light-transparent resin and second light-transparent particles dispersed inside the resin. The first light-transparent particles have a same refractive index as that of the resin and particle diameters of 9 to 500 nanometers that provide a less roughness surface of the resin in order to prevent from large angle diffusion to the interior light and improve clarity of image. The second particles have a different refractive index from the resin so as to diffuse the exterior light that comes to the antiglare film so as to decrease glare. The antiglare film can be made by one time of coating. The two layer light-transparent particles provide light interference and achieve a low reflectivity.
    Type: Grant
    Filed: April 1, 2003
    Date of Patent: February 8, 2005
    Assignee: Optimax Technology Corporation
    Inventors: Jung-Chen Chien, Ta-Wang Lai, Bor-Ping Wang, Hung-Chi Chen
  • Patent number: 6800365
    Abstract: An antifogging article includes a substrate and an antifogging film covering the substrate. This antifogging film contains a water-absorbing organic polymer and an inorganic substance and has a water repellent finishing on a surface of the antifogging film. Another antifogging article includes (1) a substrate, (2) a water-absorbing, antifogging film covering the substrate, and (3) a water-permeable, protective film covering the antifogging film. This antifogging film contains (a) a polyvinyl acetal resin having a degree of acetalization of not greater than 10 mol % and (b) a hydrolysate or partial hydrolysate of an alkylsilylisocyanate represented by the general formula R2nSiR14−n where R1 is an alkyl group having a carbon atom number of 1 or 2, R2 is an isocyanate group, and n is 1 or 2. These antifogging articles are superior in antifogging property and abrasion resistance.
    Type: Grant
    Filed: May 21, 2002
    Date of Patent: October 5, 2004
    Assignee: Central Glass Company, Limited
    Inventors: Seiji Yamazaki, Noboru Murata, Hideki Yamamoto
  • Patent number: 6737103
    Abstract: A portable, self-contained, electronic radioscopic imaging system uses a pulsed X-ray source, a remote X-ray sensor, and a self-contained, display and controller unit to produce, store, and/or display digital radioscopic images of an object under investigation in low voltage imaging environments such as medical applications including mammography and tissue imaging, and industrial radiography of low-density structures, or the like. The radiographic system uses an X-ray converter screen for converting impinging X-ray radiation to visible light, and thus each point impinged on the screen by X-ray radiation scintillates visible light emissions diverging from the screen. An image sensor, i.e., a CCD camera, is configured to sense the visible light from the screen. An aspheric objective lens operable with the CCD camera spatially senses visible light within a collection cone directed outwardly from the image sensor. An emission modification lens layer, e.g.
    Type: Grant
    Filed: April 9, 2002
    Date of Patent: May 18, 2004
    Assignee: Science Applications International Corporation
    Inventors: Raulf M. Polichar, Richard C. Schirato, Janis Baltgalvis
  • Patent number: 6623793
    Abstract: A process for forming a retroreflective layer on a powder coated substrate is provided. The substrate is powder coated and the powder coating is subsequently partially cured. Reflective elements are then partially embedded in the semi-cured powder. The powder is then fully cured to permanently bond the reflective elements with the powder coating. The resultant retroreflective assembly can be used in any application requiring high detectability in poor visibility conditions, such as road signs and the like.
    Type: Grant
    Filed: August 16, 2001
    Date of Patent: September 23, 2003
    Assignee: Litetech, Inc.
    Inventors: Daniel Mushett, Randall Craft
  • Publication number: 20030148026
    Abstract: A process for forming a retroreflective layer on a powder coated substrate is provided. The substrate is powder coated and the powder coating is subsequently partially cured. Reflective elements are then partially embedded in the semi-cured powder. The powder is then fully cured to permanently bond the reflective elements with the powder coating. The resultant retroreflective assembly can be used in any application requiring high detectability in poor visibility conditions, such as road signs and the like.
    Type: Application
    Filed: January 30, 2003
    Publication date: August 7, 2003
    Applicant: LITETECH, INC.
    Inventors: Daniel Mushett, Randall Craft
  • Patent number: 6587263
    Abstract: An method, and method of production thereof, which provides excellent performance, reduced cost, and reduced breakage due to reduced manual handling. The present invention comprises a substrate, a bond layer coating the substrate, a reflective layer coating the bond layer, and a radiative layer coating the reflective layer. Preferably, the radiative layer comprises SiO2, Si3N4 or SiOxNy, low absorbency of electromagnetic radiation having wavelengths of approximately 200 nm to approximately 2500 nm and high absorbency and emissivity electromagnetic radiation having wavelengths of approximately 2.5 &mgr;m to approximately 25 &mgr;m. Preferably, the bond layer comprises chromium, titanium, or titanium-tungsten and the substrate comprises aluminum, aluminum alloys, polyimide, carbon-filled polyimide, or carbon composite.
    Type: Grant
    Filed: March 31, 2000
    Date of Patent: July 1, 2003
    Assignee: Lockheed Martin Corporation
    Inventors: Charles Dominic Iacovangelo, Yiqun Pan, Chang Wei, Mao Chen
  • Patent number: 6582759
    Abstract: The present invention relates to optical elements comprising fluorochemical surface treatments. The invention further relates to materials such as retroreflective sheetings, pavement markings and beaded projection screens comprising a binder and the surface treated optical elements.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: June 24, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Zai-Ming Qiu, Naiyong Jing
  • Patent number: 6531215
    Abstract: An antifogging article includes a substrate and an antifogging film covering the substrate. This antifogging film contains a water-absorbing organic polymer and an inorganic substance and has a water repellent finishing on a surface of the antifogging film. Another antifogging article includes (1) a substrate, (2) a water-absorbing, antifogging film covering the substrate, and (3) a water-permeable, protective film covering the antifogging film. This antifogging film contains (a) a polyvinyl acetal resin having a degree of acetalization of not greater than 10 mol % and (b) a hydrolysate or partial hydrolysate of an alkylsilylisocyanate. This constituent (b) can be replaced with at least one of a silylisocyanate, its hydrolysate, and its partial condensate. These antifogging articles are superior in antifogging property and abrasion resistance.
    Type: Grant
    Filed: April 17, 2001
    Date of Patent: March 11, 2003
    Assignee: Central Glass Company, Limited
    Inventors: Seiji Yamazaki, Noboru Murata, Hideki Yamamoto
  • Patent number: 6517166
    Abstract: A wheel rim includes a transparent adhesive layer provided on the surface of the wheel rim, a light-reflective particle layer which is substantially free of any superimposed or overlapping particles and which is formed by spreading solely and uniformly dry light-reflective particles on the transparent adhesive layer and contacting directly the particles with the transparent adhesive layer, the particles having dimensions larger than the thickness of the transparent adhesive layer so that some of the dry light-reflective particles which do not contact the transparent adhesive layer can be allowed to fall off the transparent adhesive layer by gravity, and a transparent protective layer provided on the light-reflective particle layer.
    Type: Grant
    Filed: February 7, 2002
    Date of Patent: February 11, 2003
    Assignee: Giant Manufacturing Co., Ltd.
    Inventor: Jeff Chen
  • Publication number: 20030017263
    Abstract: An image forming element is disclosed which is easy to manufacture, which can form images easily and at a low cost, and which is stable without fear of environmental problems arising at a time of disposal. Also disclosed is an image forming device which utilizes the image forming element and which can form color images. The image forming element contains at least a film in which rod-shaped bodies are oriented and which reflects incident light as colored interference light. The image forming device is equipped with at least the image forming element, and a means for irradiating light for irradiating light onto the image forming element. The image forming element reflects, as interference light, light irradiated by the means for irradiating light. The wavelength of the interference light is 300 to 810 nm.
    Type: Application
    Filed: March 25, 2002
    Publication date: January 23, 2003
    Applicant: FUJI PHOTO FILM CO., LTD.
    Inventor: Shintaro Washizu
  • Patent number: 6451408
    Abstract: A retroreflective article that exhibits suitable retroreflective luminance under dry and dynamic wet conditions. The article includes an enclosed-lens retroreflective sheeting that, under dry conditions, exhibits a coefficient of retroreflective luminance of about 40 (millicandela/m2)/lux as measured by ASTM D 4061-94 and, under dynamic wet conditions the sheeting increases in coefficient of retroreflective luminance. The article further includes a plurality of retroreflective elements partially embedded in a light transmissible bonding layer on the front, reflective surface of the retroreflective sheeting.
    Type: Grant
    Filed: April 2, 1999
    Date of Patent: September 17, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Dale H. Haunschild, John L. Ethen, Mark D. Zender, Robert A. Haenggi, Larry K. Stump
  • Publication number: 20020114883
    Abstract: A process for forming a retroreflective layer on a powder coated substrate is provided. The substrate is powder coated and the powder coating is subsequently partially cured. Reflective elements are then partially embedded in the semi-cured powder. The powder is then fully cured to permanently bond the reflective elements with the powder coating. The resultant retroreflective assembly can be used in any application requiring high detectability in poor visibility conditions, such as road signs and the like.
    Type: Application
    Filed: August 16, 2001
    Publication date: August 22, 2002
    Inventors: Daniel Mushett, Randall Craft
  • Patent number: 6423368
    Abstract: A light-modulating, electrically responsive sheet including a substrate and an electrically conductive layer formed over the substrate. The sheet further includes, in an aqueous bath, an immiscible, field responsive light-modulating material along with a quantity of colloidal particles wherein the colloidal particles limit coalesced domain size and a binder; blending the constituents of the aqueous bath to form a dispersion of said field-responsive, light-modulating material below a coalescence size which sets to form limited coalescence domains having a uniform size; coating said material over the substrate; and drying said coated material to form a set of uniform domains so that such dispersion coalesces to form a set of uniform limited coalescence domains having a plurality of electrically responsive optical states.
    Type: Grant
    Filed: January 6, 2000
    Date of Patent: July 23, 2002
    Assignee: Eastman Kodak Company
    Inventors: Stanley W. Stephenson, John W. Boettcher, David J. Giacherio
  • Patent number: 6420020
    Abstract: An antifogging article includes a substrate and an antifogging film covering the substrate. This antifogging film contains a water-absorbing organic polymer and an inorganic substance and has a water repellent finishing on a surface of the antifogging film. Another antifogging article includes (1) a substrate, (2) a water-absorbing, antifogging film covering the substrate, and (3) a water-permeable, protective film covering the antifogging film. This antifogging film contains (a) a polyvinyl acetal resin having a degree of acetalization of not greater than 10 mol % and (b) a hydrolysate or partial hydrolysate of an alkylsilylisocyanate represented by the general formula R2nSiR14−n where R1 is an alkyl group having a carbon atom number of 1 or 2, R2 is an isocyanate group, and n is 1 or 2. These antifogging articles are superior in antifogging property and abrasion resistance.
    Type: Grant
    Filed: November 17, 2000
    Date of Patent: July 16, 2002
    Assignee: Central Glass Company Limited
    Inventors: Seiji Yamazaki, Noboru Murata, Hideki Yamamoto
  • Publication number: 20020090515
    Abstract: The present invention relates to optical elements comprising fluorochemical surface treatments. The invention further relates to materials such as retroreflective sheetings, pavement markings and beaded projection screens comprising a binder and the surface treated optical elements. The fluorochemical surface treatment is substantially free of perfluoroalkyl groups having more than four carbon atoms. Preferably, the surface treatment is a polyfluoropolyether-based compound comprising at least one polar group or polar group-containing organic radical.
    Type: Application
    Filed: October 24, 2001
    Publication date: July 11, 2002
    Applicant: 3M Innovative Properties Company
    Inventors: Mark J. Pellerite, Susannah C. Clear, Cheryl L. Elsbernd, Richard M. Flynn, George Van Dyke Tiers, Naiyong Jing
  • Patent number: 6416911
    Abstract: A coating for a retroreflective document is provided which renders the surface of the document receptive to toners and inks printed thereon while not substantially interfering with the retroreflective properties of the underlying substrate. Methods for fabricating the document are also provided.
    Type: Grant
    Filed: November 13, 2001
    Date of Patent: July 9, 2002
    Assignee: The Standard Register Company
    Inventors: Rajendra Mehta, A. Dale Lakes, Richard Lynn Shields
  • Patent number: 6376009
    Abstract: A first compound is applied to the polymeric coating of the display unit and the polymeric coating is ground with the first compound to even out a surface of the polymer coating. A second compound is then applied to the polymeric coating and ground on the polymeric coating to form a protective coating on the polymeric coating with the second compound. The protective coating is cleaned and a first polishing compound is applied to an oscillating polishing machine to polish the protective coating with the first polishing compound. A second polishing compound is then applied on the polishing machine and the protective coating is polished with the second polishing compound to form a polishing surface coating on the protective coating so that the retro reflection is at least 11 candela/m2/lux.
    Type: Grant
    Filed: November 1, 1999
    Date of Patent: April 23, 2002
    Inventor: Hans Bergvall
  • Patent number: 6376135
    Abstract: A coating for a retroreflective document is provided which renders the surface of the document receptive to toners and inks printed thereon while not substantially interfering with the retroreflective properties of the underlying substrate. Methods for fabricating the document are also provided.
    Type: Grant
    Filed: May 11, 1999
    Date of Patent: April 23, 2002
    Assignee: The Standard Register Company
    Inventors: Rajendra Mehta, A. Dale Lakes, Richard Lynn Shields
  • Patent number: 6368660
    Abstract: Retroreflecting road marking system comprising applying a coating layer which is composed of a binder, glass beads, one or more pigments, and fillers, on which immediately after its application and prior to its complete cooling, drying and/or curing glass beads have been introduced, the coating layer comprising a composition composed of: 30-70 wt. % of glass beads having a particle size distribution in the range of 0.8 to 3.5 mm, 3-30 wt. % of TiO2, 5-40 wt. % of fillers and/or aggregate, as well as 10-40 wt. % of binder, and the particle size distribution of the glass beads introduced immediately after application being in the range of 100 to 600 &mgr;m, preferably in the range of 100 to 300 &mgr;m. Through the effect of traffic the retroreflecting road marking system according to the invention attains good retroreflecting properties soon after application and also in the wet state and loses these properties far less quickly, even after busy traffic.
    Type: Grant
    Filed: November 19, 1999
    Date of Patent: April 9, 2002
    Assignee: Akzo Nobel N.V.
    Inventors: Hendrik Stoffers, Klaas Nieuwenhuis
  • Patent number: 6355302
    Abstract: Simplified continuous processes are disclosed for converting standard woven or nonwoven fabric into reflectorized fabric in a continuous fashion and in bulk quantities. These processes are easily capable of achieving reflectivities of well over 100 cd/(lux·m2). In the processes, an extended length of fabric is provided such as by unwinding an input roll of fabric to be reflectorized, and the fabric is passed through a station that applies a coating of binder material to the fabric. The fabric then passes through a station where aluminum-coated beads are applied to the coating of binder material. An etching station removes exposed portions of the aluminum coating from the beads after the binder material is allowed to substantially solidify. End-use materials other than fabrics but suitable for enhancing personal conspicuity can be reflectorized in the same way.
    Type: Grant
    Filed: December 10, 1999
    Date of Patent: March 12, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: John L. Vandenberg, Britton G. Billingsley, Joey L. Reule, Frederick J. Fox
  • Publication number: 20020006559
    Abstract: A coating for a retroreflective document is provided which renders the surface of the document receptive to toners and inks printed thereon while not substantially interfering with the retroreflective properties of the underlying substrate. Methods for fabricating the document are also provided.
    Type: Application
    Filed: May 11, 1999
    Publication date: January 17, 2002
    Inventors: RAJENDRA MEHTA, A. DALE LAKES, RICHARD LYNN SHIELDS
  • Patent number: 6333070
    Abstract: The invention relates to a method for producing on a flexible film reflecting images which can be hot-transferred to a plurality of different materials, the method comprising a first processing step in which a polyester film is processed by a thermoplastic resin in a aromatic solution, a second processing step in which on the film are deposited a plurality of glass beads, in an adjoining relationship, a resin priming processing step for allowing the glass beads to be properly retained in place, a processing step of using a vinylchloride-vinylacetate-aromatic solvent solution with an addition of a metal powder having high mirror-like properties in order to allow the glass beads to refract the light, and a color printing step for printing any desired colors on desired regions, as well as a further leveling processing step for the images, and a final processing step of using a thermo-transfering solution in order to allow the printed images to be transferred under temperature and pressure.
    Type: Grant
    Filed: December 22, 1999
    Date of Patent: December 25, 2001
    Assignee: Illinois Tool Works, Inc.
    Inventor: Mario Ferro
  • Patent number: 6326053
    Abstract: Retroreflective article (10), e.g., in the form of a pavement marking, having raised, nonintegral protuberances (16) that exhibit good dry retroreflectivity and recover retroreflectivity quickly after exposure to water. The protuberance comprise a thermoplastic polymer body. Partially embedded in the protuberance are optical elements (14) which are in optical association with a light scattering agent. The protuberance is disposed on top of a conformable base sheet (12).
    Type: Grant
    Filed: June 29, 1999
    Date of Patent: December 4, 2001
    Assignee: 3M Innovative Properties Company
    Inventors: Larry K. Stump, Gregory F. Jacobs
  • Patent number: 6306459
    Abstract: Exposed lens retroreflective article 10 that comprises a colored layer 14 and a layer of optical elements 12 that are partially embedded in the colored layer 14. The colored layer 14 comprises reflective flakes 16 and a dye that is covalently bonded to a polymer 18. The articles can retain their color after multiple industrial wash cycles. The use of a reactive dye, reflective flakes, and/or polymer precursor during the preparation of the colored layer enables a launderably-durable colored retroreflective article to be made without the use of a solvent and without the use of a temporary carrier.
    Type: Grant
    Filed: December 2, 1999
    Date of Patent: October 23, 2001
    Assignee: 3M Innovative Properties Company
    Inventor: Robert J. Fleming
  • Patent number: 6291586
    Abstract: An ultraviolet light absorbing material that resists blooming and migration is made up of a polyurethane or polyurea polymer and an amide functional ultraviolet light absorbing compound, wherein the polymer and the amide functional ultraviolet light absorbing compound are hydrogen bonded to one another. Polymeric films that contain a polymeric matrix and the ultraviolet light absorbing material are useful as the top layer in multilayer constructions such as retroreflective sheetings and conformable marking sheets.
    Type: Grant
    Filed: October 31, 1997
    Date of Patent: September 18, 2001
    Assignee: 3M Innovative Properties Company
    Inventors: James E. Lasch, David B. Olson, David M. Burns
  • Patent number: 6224219
    Abstract: A method for making retroreflective articles that have a layer of optical elements and a multilayer reflective coating disposed on the optical elements. The reflective coating reflects light back into the optical elements so that it can be returned toward the light source. The multilayer reflective coating has at least one polymer layer made by condensing a curing a pre-polymer vapor.
    Type: Grant
    Filed: April 10, 2000
    Date of Patent: May 1, 2001
    Assignee: 3M Innovative Properties Company
    Inventors: Robert J. Fleming, Joseph M. McGrath, Christopher S. Lyons