Coagulating Or Jelling The Coating Patents (Class 427/246)
  • Patent number: 11524479
    Abstract: There is described a nonwoven material comprising a multilayered stack, the multilayered stack comprising discrete interconnected layers, each of the layers, which may be the same or different, comprising a composite fibre of from about 80 to 100% w/w leaf or stem fibre and from about 1 to 20% w/w of a polymer, wherein the polymer is fusible at a temperature of about 180° C. or less. There is also described a novel method of enzyme degumming leaf and/or stem fibres.
    Type: Grant
    Filed: May 25, 2011
    Date of Patent: December 13, 2022
    Inventors: Carmen Hijosa, Anna Ribé Gallart, Javier Jiménez Romero, Roshan Paul, Marolda Brouta-Agnésa
  • Patent number: 11274044
    Abstract: The present invention relates to a method for producing an aerogel blanket exhibiting excellent hydrophobicity at high temperatures and an aerogel blanket produced thereby. The present invention uses a mixture of silica sol and a hydrophobic aerogel powder as an aerogel precursor and thus can achieve hydrophobicity in the internal structure as well as on the surface of the aerogel included in the aerogel blanket. Accordingly, the aerogel blanket can attain high hydrophobicity and thus can exhibit excellent hydrophobicity retention ability even in high-temperature applications.
    Type: Grant
    Filed: March 8, 2017
    Date of Patent: March 15, 2022
    Assignee: LG CHEM, LTD.
    Inventors: Mi Ri Kim, Kyoung Shil Oh, Je Kyun Lee, Young Hun Kim
  • Patent number: 10920367
    Abstract: A thermal insulation sheet is used that includes a fiber, a silica aerogel contained in the fiber, and a fibrous cavity. A method for manufacturing a thermal insulation sheet is used that includes: an impregnation step of impregnating a silica aerosol in a nonwoven fabric substrate containing a fiber that is insoluble in an acidic solution, and a fiber that is soluble in the acidic solution; a gelling step of gelling the silica aerosol; a hydrophobizing step of hydrophobizing the gel; and a drying step of drying the gel. The fiber that is soluble in the acidic solution is dissolved in the hydrophobizing step.
    Type: Grant
    Filed: March 7, 2017
    Date of Patent: February 16, 2021
    Assignee: PANASONIC INTELLECTUAL PROPERTY MANAGEMENT CO., LTD.
    Inventors: Tatsuhiro Ooshiro, Takashi Tsuruta
  • Patent number: 10821714
    Abstract: A method for manufacturing a panel including a reinforcement sheet comprises the steps of: providing a first layer of thermoplastic material, providing a reinforcement sheet, laying the reinforcement sheet and the first layer onto each other, applying a second layer of thermoplastic material on top of the reinforcement sheet at a side facing away from the first layer, at least partially melting the thermoplastic materials of the first layer and the second layer, adhering the at least partially melted first layer, the at least partially melted second layer and the reinforcement sheet to each other so as to form the panel, wherein the reinforcement sheet and the first layer are adhered to each other by pressing them together after at least partially melting the thermoplastic material of the first layer, but before applying the second layer of thermoplastic material onto the reinforcement sheet.
    Type: Grant
    Filed: November 20, 2014
    Date of Patent: November 3, 2020
    Assignee: IVC B.V.
    Inventors: Kristof Van Vlassenrode, Filip Gilbert Lucien Bossuyt
  • Patent number: 10384946
    Abstract: The present invention relates to a low-dust, high insulation aerogel blanket and a method for producing the same. More specifically, the present invention provides a method for producing a low-dust, high insulation aerogel blanket, wherein a plate type Mg(OH)2.MgO.SiO2 powder is added to a silica sol, thereby being capable of reducing the generation of dust with excellent flame retardancy and thermal conductivity, and an aerogel blanket produced thereby.
    Type: Grant
    Filed: October 10, 2017
    Date of Patent: August 20, 2019
    Assignee: LG CHEM, LTD.
    Inventors: Kyoung Shil Oh, Je Kyun Lee, Sung Min Yu
  • Patent number: 10344484
    Abstract: The invention relates to an insulated building wall comprising a composite thermal insulation system and an external building wall, where the composite thermal insulation system is affixed to the side of the building wall facing away from the building, the composite thermal insulation system comprising an at least two-layer thermal insulation cladding, with at least two layers each containing from 25 to 95% by weight of aerogel and from 5 to 75% by weight of inorganic fibers and from 0 to 70% by weight of inorganic fillers, wherein the layers of the thermal insulation cladding are joined to one another by means of an inorganic binder and the composite thermal insulation system has a gross calorific potential of less than 3 MJ per kilogram.
    Type: Grant
    Filed: January 12, 2012
    Date of Patent: July 9, 2019
    Assignee: BASF SE
    Inventors: Sven Moennig, Stefan Rossmayer, Stephan Detrois, Thomas Gastner
  • Patent number: 10259099
    Abstract: The method forms a porous polyurethane polishing pad by coagulating thermoplastic polyurethane to create a porous matrix having large pores extending upward from a base surface and open to an upper surface. The large pores are interconnected with small pores. Heating a press to temperature below or above the softening onset temperature of the thermoplastic polyurethane forms a series of pillows. Plastic deforming side walls of the pillow structures forms downwardly sloped side walls. The downwardly sloped side walls extend from all sides of the pillow structures. The large pores open to the downwardly sloped sidewalls are less vertical than the large pores open to the top polishing surface and are offset 10 to 60 degrees from the vertical direction.
    Type: Grant
    Filed: August 4, 2016
    Date of Patent: April 16, 2019
    Assignee: Rohm and Haas Electronic Materials CMP Holdings, Inc.
    Inventors: Koichi Yoshida, Kazutaka Miyamoto, Katsumasa Kawabata, Henry Sanford-Crane, Hui Bin Huang, George C. Jacob, Shuiyuan Luo
  • Patent number: 10046545
    Abstract: A film capable of covering an article having a three-dimensional shape by heat expansion provided by one embodiment of the present disclosure comprises an outermost layer disposed on an outermost surface, and a polyurethane thermal adhesive layer, which contains a thermoplastic polyurethane selected from the group consisting of polyester-based polyurethanes and polycarbonate-based polyurethanes and is thermally adhered to the article during the heat expansion, wherein the fracture strength of the polyurethane thermal adhesive layer is not less than 1 MPa at 135° C., and the storage modulus at 150° C. and frequency 1.0 Hz is from 5×103 Pa to 5×105 Pa, and the coefficient of loss tan ? is not less than 0.1.
    Type: Grant
    Filed: December 21, 2015
    Date of Patent: August 14, 2018
    Assignee: 3M INNOVATIVE PROPERTIES COMPANY
    Inventors: Yorinobu Takamatsu, Akihiko Nakayama, Daigo Yasuda, Minori Kawagoe
  • Patent number: 9957346
    Abstract: A polyurea or polyurea-urethane elastomer comprises a soft polymer segment and a hard polymer segment, wherein the hard polymer segment includes polyurea groups in combination with H-bond accepting chain extenders (HACEs) to reduce the flow temperature (Tflow) while maintaining the excellent mechanical properties such that the resulting polyurea elatomer is rendered melt-processable.
    Type: Grant
    Filed: February 23, 2012
    Date of Patent: May 1, 2018
    Assignee: The University of Akron
    Inventors: Joseph Kennedy, Jungmee Kang, Gabor Erdodi
  • Patent number: 9920460
    Abstract: A down-proof woven fabric includes a cloth composed of synthetic fibers with a yarn fineness of 33 decitex or less and having a weight per unit area of 50 g/m2 or less and a cover factor of 1,400 to 1,800, wherein the cloth is coated at least on one surface thereof with a resin by an amount of 0.1 g/m2 to 5 g/m2 as a solid component.
    Type: Grant
    Filed: June 17, 2010
    Date of Patent: March 20, 2018
    Assignee: Toray Industries, Inc.
    Inventors: Tsunemitsu Kitagawa, Shintaro Kazahaya, Hiroyasu Kitajima
  • Patent number: 9649600
    Abstract: Disclosed is a method for manufacturing a composite porous film having a stable film quality and a desired hollow shape by controlling the entrance of a film-forming resin solution into a hollow part of a hollow reinforcement support. The method is provided with a step of adhering a film-forming resin solution to the outer peripheral surface of the hollow reinforcement support and thereby forming a film intermediate, a step of adhering a coagulating liquid to the outer peripheral surface of the film intermediate, and a step of flowing the coagulating liquid along the outer peripheral surface of the film intermediate so that at least a part of the outermost interface of the coagulating liquid in the circumferential direction is a free surface and thereby coagulating the film-forming resin solution adhering to the outer peripheral surface of the hollow reinforcement support.
    Type: Grant
    Filed: April 23, 2010
    Date of Patent: May 16, 2017
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Hiroyuki Fujiki, Toshinori Sumi, Yasuo Hiromoto, Masaki Kurashina
  • Patent number: 9574154
    Abstract: The present invention provides a sheet that has excellent lubricity and good touch feeling under wet conditions and suffers from little drop of the lubricity even if the sheet is used repeatedly. In the sheet of the present invention, a layer of modified polyalkylene oxide obtainable by reacting a polyalkylene oxide compound, a diol compound, and a diisocyanate compound together is directly formed on a surface of a substrate.
    Type: Grant
    Filed: January 7, 2011
    Date of Patent: February 21, 2017
    Assignee: SUMITOMO SEIKA CHEMICALS CO., LTD.
    Inventors: Hitoshi Ozawa, Tatsuo Ohtani, Yusuke Nishikawa
  • Patent number: 9029471
    Abstract: Various fluoropolymers have been proposed for imparting oil and water repellency to leather. Commonly, these fluoropolymers are amphiphilic; i.e., they are made from at least one monomer which is hydrophobic and at least one monomer which is hydrophilic. The present invention identifies and remedies disadvantages associated with the ability of amphiphilic fluoropolymers to impart oil and water repellency to leather. Contrary to conventional thinking, it has now been discovered that the incorporation of hydrophilic groups in a fluoropolymer undesirably reduces its ability to impart water resistance to leather. Correspondingly, it has also been discovered that a fluoropolymer incorporating fewer or no hydrophilic groups imparts superior oil and water repellency to leather when compared to fluoropolymers incorporating more hydrophilic groups. Therefore, this invention provides fluoropolymers which incorporate reduced levels of hydrophilic groups.
    Type: Grant
    Filed: September 30, 2008
    Date of Patent: May 12, 2015
    Assignee: E I du Pont du Nemours and Company
    Inventors: Romain Severac, Agnes Ibos, Lamia Heuze, Renaud Laloux-Walther
  • Patent number: 9010546
    Abstract: The present invention is an integral multilayered composite membrane having at least one ultrafiltration layer made by cocasting or sequentially casting a plurality of polymer solutions onto a support to form a multilayered liquid sheet and immersing the sheet into a liquid coagulation bath to effect phase separation and form a multilayered composite membrane having at least one ultrafiltration layer.
    Type: Grant
    Filed: February 25, 2014
    Date of Patent: April 21, 2015
    Assignee: EMD Millipore Corporation
    Inventors: Gabriel Tkacik, Philip Goddard, Willem Kools, Nitin Satav
  • Patent number: 9010545
    Abstract: The present invention is an integral multilayered composite membrane having at least one ultrafiltration layer made by cocasting or sequentially casting a plurality of polymer solutions onto a support to form a multilayered liquid sheet and immersing the sheet into a liquid coagulation bath to effect phase separation and form a multilayered composite membrane having at least one ultrafiltration layer.
    Type: Grant
    Filed: December 6, 2011
    Date of Patent: April 21, 2015
    Assignee: EMD Millipore Corporation
    Inventors: Gabriel Tkacik, Philip Goddard, Willem Kools, Nitin Satav
  • Patent number: 8752713
    Abstract: A hollow porous membrane with a reduced cost and excellent separation characteristic, water permeability, and mechanical strength and a process of producing the hollow porous membrane with an excellent adhesive property between a support and a porous membrane layer at a low cost are provided. The hollow porous membrane includes a porous membrane layer in which dense layers are disposed in the vicinities of an outer surface and an inner surface. In the process of producing the hollow porous membrane, membrane-forming dopes of a first membrane-forming dope and a second membrane-forming dope, which contain the material of the porous membrane layer and a solvent, are successively applied and stacked onto the outer circumferential surface of a hollow support and the applied membrane-forming dopes are simultaneously coagulated.
    Type: Grant
    Filed: May 21, 2009
    Date of Patent: June 17, 2014
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Masashi Teramachi, Kei Murase, Toshinori Sumi, Yasuo Hiromoto, Hiroyuki Fujiki, Masaki Kurashina, Masakazu Minagawa
  • Patent number: 8722146
    Abstract: A method for making a liquid separation membrane, including: (1) providing a polyvinylidene fluoride liquid separation membrane or polypropylene liquid separation membrane prepared by a thermally induced phase separation method as a substrate membrane, soaking the substrate membrane with water or a weak polar organic liquid to make membrane pores of the substrate membrane filled with the liquid, the soaking time being between 0.5 s and 1 min, and the weak polar organic liquid being indissolvable and compatible with the polyvinylidene fluoride liquid separation membrane or polypropylene liquid separation membrane; (2) coating a casting solution of polyvinylidene fluoride on the surface of the soaked substrate membrane obtained in step (1), and quickly soaking the substrate membrane in a coagulating bath heated to a temperature of 60-100° C. for curing to yield the liquid separation membrane.
    Type: Grant
    Filed: July 2, 2012
    Date of Patent: May 13, 2014
    Assignee: Tianjin Motimo Membrane Technology Co., Ltd.
    Inventors: Jianli Liu, Changfa Xiao, Xiaoyu Hu, Wujiang Zhang, Ruobing Hou
  • Patent number: 8550256
    Abstract: A method of photo-grafting onto a separation membrane a copolymer includes at least one of: and; For example, in Structure 1A, x1?2 and y1?1; R1 and R2 are independently selected from the group consisting of CH3 and H; R3 is independently selected from the group consisting of poly(oxyalkylene), quaternary ammonium salts, pyridinium salts, sulfonium salts, sulfobetaines, carboxybetaines, alcohols, phenols, tertiary amines, aryl groups; linear, branched and cyclic alkylenes; linear, branched and cyclic heteroalkylenes; linear, branched and cyclic fluoroalkylenes; and siloxyl; R4 is independently selected from the group consisting of linear, branched, and cyclic alkylenes; linear, branched and cyclic hetroalkylenes; linear, branched and cyclic fluoroalkylenes; phenyl; and siloxyl; and Z1 is 0 or 1.
    Type: Grant
    Filed: July 27, 2012
    Date of Patent: October 8, 2013
    Assignee: International Business Machines Corporation
    Inventors: Jacquana T. Diep, Young-Hye Na, Ankit Vora
  • Patent number: 8544658
    Abstract: The present invention relates to a method of preparing RAFT, ATRP or NMRP functionalized thin film composite (TFC) polyamide membranes on a microporous substrate. A further aspect of the invention is the subsequent modification of the thin film composite polyamide membrane by controlled free radical polymerization (CFRP) to yield membranes having new chemical and physical properties, e.g. antifouling and/or antibacterial properties. Further aspects of the invention are the functionalized thin film composite (TFC) polyamide membranes on the microporous substrate itself and the membranes modified by controlled free radical polymerization.
    Type: Grant
    Filed: August 3, 2009
    Date of Patent: October 1, 2013
    Assignee: Polymers CRC Limited
    Inventors: Marina H. Stenzel, Ricardo Godoy-Lopez, Simon Harrisson, Ezio Rizzardo
  • Patent number: 8511482
    Abstract: A method of producing a porous membrane, the method comprising: casting a polymer solution, in which a polymer is dissolved in a mixture of a good solvent, a poor solvent and a non-solvent, over a support, so as to form a casted polymer solution; drying the casted polymer solution, so as to form a cast film; and subjecting the cast film to a phase separation, wherein the porous membrane is produced under a condition where a temperature of a casted surface is lower than a temperature of the polymer solution, and each of a temperature change of the polymer solution and a temperature change of the casted surface is kept within ±3.0° C.
    Type: Grant
    Filed: September 15, 2005
    Date of Patent: August 20, 2013
    Assignee: Kurashiki Boseki Kabushiki Kaisha
    Inventors: Hideaki Tanaka, Yoshihiko Makino
  • Patent number: 8505746
    Abstract: A dope solution for membrane production comprising polyethersulfone having high strength, high water permeability, a high rejecting ability and excellent contamination resistance, a separation membrane, and a process for producing the separation membrane are provided. The dope solution for membrane production contains a polyethersulfone and a solvent for thermally induced phase separation selected from the group consisting of 3-pyridinemethanol, 4-methyl-1,3-dioxolane-2-one, 4-benzylpiperidine, trimethyl phosphate, 1,3-dioxolane-2-one and mixtures thereof.
    Type: Grant
    Filed: September 30, 2008
    Date of Patent: August 13, 2013
    Assignee: Kawasaki Jukogyo Kabushiki Kaisha
    Inventors: Masaki Tsuzawa, Hideto Matsuyama
  • Patent number: 8475868
    Abstract: Articles having porous or foam-like elements are provided. The design, fabrication and structures of the articles exploit properties of reactive composite materials (RCM) and their reaction products. In particular, fluids generated by reacting RCM are utilized to create or fill voids in the porous or foam-like elements.
    Type: Grant
    Filed: November 12, 2008
    Date of Patent: July 2, 2013
    Inventors: Roderick A. Hyde, Muriel Y. Ishikawa, Edward K. Y. Jung, Jordin T. Kare, Alois A. Langer, Eric C. Leuthardt, Nathan P. Myhrvold, Thomas J. Nugent, Jr., Clarence T. Tegreene, Charles Whitmer, Lowell L. Wood, Jr., Richard N. Zare
  • Patent number: 8465800
    Abstract: The invention is to provide a leather-like sheet having a fine image drawn by an inkjet printing method, etc., on its surface and having practically sufficient physical properties. This invention includes a leather-like sheet including (i) a fibrous substrate and (ii) a porous layer thereon, the porous layer having a surface having open pores with a diameter of 1 ?m or more and the porous layer having the surface having an image whose definition is 5 dots/mm or more, and a process for the production thereof.
    Type: Grant
    Filed: February 26, 2008
    Date of Patent: June 18, 2013
    Assignee: Teijin Cordley Limited
    Inventors: Kunihiko Sasaki, Toshihiko Sakamoto
  • Patent number: 8393478
    Abstract: An inorganic membrane having an improved pore structure. The membrane has a mean pore size of up to about 100 nm and a mean particle size in a range from about 10 nm to about 100 nm. In one embodiment, the membrane comprises ?-alumina and is formed by providing a coating slip comprising ?-alumina; applying the coating slip to a support surface to form a coating layer; drying the coating layer; and firing the dried coating layer at a temperature of at least about 1000° C. to convert at least a portion of the ?-alumina to ?-alumina and form the inorganic membrane.
    Type: Grant
    Filed: August 20, 2007
    Date of Patent: March 12, 2013
    Assignee: Corning Incorporated
    Inventors: Curtis Robert Fekety, Wei Liu, Zhen Song, Joseph Marc Whalen
  • Publication number: 20130015122
    Abstract: The nanocomposite membrane includes a composite of carbon nanotubes coated or chemically bonded with metal oxide nanoparticles. This composite is embedded within a polymeric matrix via interfacial polymerization on a polysulfone support. The metal oxide particles are selected to exhibit catalytic activity when filtering pollutants from water in a water treatment system, or for separating a gas from a liquid, or for selectively separating particles or ions from solution for reverse osmosis (e.g., for desalination systems), or other filtration requirements. A method of fabricating the nanocomposite membrane is also included herein.
    Type: Application
    Filed: July 11, 2011
    Publication date: January 17, 2013
    Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS
    Inventor: TAWFIK ABDO SALEH AWADH
  • Patent number: 8276764
    Abstract: The invention relates to a process for producing a polymer membrane, the polymer membrane being produced from a solution, in particular a casting solution, comprising at least one first polymer. The invention further relates to a polymer membrane. The process of the invention is distinguished by the fact that a water-soluble second polymer and/or oligomer that forms phases in the solution is part of the solution. The polymer membrane of the invention, preferably produced by the process of the invention, has an oil flow rate, in particular of a refined edible oil, of greater than 200 l/m2 h bar at 60° C.
    Type: Grant
    Filed: September 6, 2007
    Date of Patent: October 2, 2012
    Assignee: Helmholtz-Zentrum Geesthacht Zentrum fur Material-und Kustenforschung GmbH
    Inventors: Detlev Fritsch, Gisela Bengtson, Katrin Ebert, Joachim Koll, Petra Merten
  • Patent number: 8256626
    Abstract: A composite membrane is provided for the separation of water with at least one separation layer of cross-linked polyvinyl alcohol, with the separation layer being subjected in a separate process step to a post-crosslinking operation with an acid or an acid-releasing compound and at least one dialdehyde.
    Type: Grant
    Filed: September 18, 2009
    Date of Patent: September 4, 2012
    Assignee: Souzer Chemtech GmbH
    Inventors: Andreas Hübner, Elena Gonzalez Diaz, Michael Frania
  • Patent number: 8210361
    Abstract: A thermally, heat and chemically stable polyimide asymmetric ultrafiltration membrane, is a porous film or a hollow fiber, having an anisotropic structure a selective surface layer and a substrate, wherein the selective ultraporous surface layer has size of pores 70-800 ? with thickness 0.1-10 mcm and is composed of insoluble rigid-chain aromatic (co)polyimide based on dianhydride of aromatic tetracarbonic acid and aromatic diamine and located on the microporous substrate with thickness 50-250 mcm, and the membrane has water permeability Q=(2?500)·10?4 cm/sec atm and nominal molecular weight cutoff ML=(5?500)·103 g/mol, and method for producing an ultrafiltration membrane as disclosed.
    Type: Grant
    Filed: September 18, 2007
    Date of Patent: July 3, 2012
    Inventors: Galina A. Polotskaya, Tamara K. Meleshko, Alexandr E. Polotsky, Andrey N. Cherkasov
  • Publication number: 20120103661
    Abstract: The present invention aims to provide an electrical insulating sheet having excellent heat resistance, electrical insulating properties, impregnating property with resin and insulating oil, mechanical strength and dimensional stability which is demanded for rotating electric machines, stationary electric machines (such as a transformer) and electric wire cables. According to the present invention, there is provided an electrical insulating sheet which uses, as a support, a woven or nonwoven fabric comprising polyester fiber and/or polyphenylene sulfide fiber, characterized in that the voids among the fibers of the support are filled with a heat resistant resin having continuous pores.
    Type: Application
    Filed: July 8, 2010
    Publication date: May 3, 2012
    Inventors: Haruhiko Narusawa, Atsushi Nakajima
  • Publication number: 20120045580
    Abstract: Disclosed is a method for manufacturing a composite porous film having a stable film quality and a desired hollow shape by controlling the entrance of a film-forming resin solution into a hollow part of a hollow reinforcement support. The method is provided with a step of adhering a film-forming resin solution to the outer peripheral surface of the hollow reinforcement support and thereby forming a film intermediate, a step of adhering a coagulating liquid to the outer peripheral surface of the film intermediate, and a step of flowing the coagulating liquid along the outer peripheral surface of the film intermediate so that at least a part of the outermost interface of the coagulating liquid in the circumferential direction is a free surface and thereby coagulating the film-forming resin solution adhering to the outer peripheral surface of the hollow reinforcement support.
    Type: Application
    Filed: April 23, 2010
    Publication date: February 23, 2012
    Applicant: MITSUBISHI RAYON CO., LTD,
    Inventors: Hiroyuki Fujiki, Toshinori Sumi, Yasuo Hiromoto, Masaki Kurashina
  • Patent number: 8119200
    Abstract: A method to prepare a flexible and breathable protective glove having excellent grip in both aqueous and oil environments includes coating an electrolyte treated glove liner substrate with a non-foamed dispersion of a polymeric material. The resulting semi-gelled polymeric coating which partially penetrates the depth of the glove liner substrate, is treated with a foamed solution of a surfactant, tenside or aerosol solution and the foam treated coating is overcoated with an electrolyte solution. In a resulting chemical or physical reaction, fine pores and cavities are formed in and on the polymer coating.
    Type: Grant
    Filed: April 23, 2009
    Date of Patent: February 21, 2012
    Assignee: Midas Safety Inc.
    Inventors: Mikhail Kassam, Akil Jaffer, Jamshed Amjad, Basheer Ali
  • Patent number: 8096424
    Abstract: Using the methods of the invention, an elastomeric polymer is dissolved in a suitable solvent, cast in one of the membrane casting techniques using a phase inversion technique, and immersed in a coagulation bath comprised of suitable solvent/non-solvent pairs (e.g., THF/water and ethanol). Asymmetric membranes having a dense discriminating layer and a thicker porous support layer suitable for application in pervaporation processes were obtained in a single step. An increase of the polymer concentration in the casting solution gives a more dense layer. When cast as formed using the methods of the invention, the membrane obtained is an integrally skinned membrane comprising a thin, dense separation layer over a porous support layer (asymmetric membrane) formed in a single casting operation. The resulting membrane is homogenous with respect to chemical composition.
    Type: Grant
    Filed: November 14, 2006
    Date of Patent: January 17, 2012
    Assignee: The United States of America as represented by the Environmental Protection Agency
    Inventors: Subhas K. Sikdar, John O. Burckle, Binay K. Dutta, Alberto Figoli, Enrico Drioli
  • Publication number: 20120009840
    Abstract: Disclosed are certain partially fluorinated amide compounds and composite materials containing the compounds. Also disclosed are methods for making the composite materials.
    Type: Application
    Filed: September 20, 2011
    Publication date: January 12, 2012
    Applicant: E.I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Keith Ward Hutchenson, Anilkumar Raghavanpillai, Stefan Reinartz
  • Publication number: 20120004434
    Abstract: The present invention provides germania-silica-based sol-gel monoliths that form the solid-phase material for extraction, isolation, preconcentration, and separation of analytes. In one embodiment, the germania-silica-based sol-gel monolith can be used to coat surfaces of the inner walls of extraction and chromatographic columns. In a preferred embodiment, the sol-gel germania-silica monolith of the present invention is formed from hydrolysis and polycondensation of precursors comprising tetraethoxygermane, tetramethoxysilane, and polyethylene glycol. Also provided are methods of preparing the germania-silica-based sol-gel monolith of the present invention.
    Type: Application
    Filed: June 3, 2011
    Publication date: January 5, 2012
    Applicant: University of South Florida
    Inventors: Abdul Malik, Erica B. Turner, Scott S. Segro
  • Patent number: 8080291
    Abstract: An ink jet recording medium having a gas-permeable substrate, and an ink receiving layer and a surface layer provided in that order on the gas-permeable substrate, wherein the surface layer is formed through the steps of (1) applying a coating liquid comprising a first inorganic pigment and a binder onto the ink receiving layer, and (2) applying a coagulating liquid comprising a coagulant and a second inorganic pigment having a refractive index higher by 0.30 or more than that of the above first inorganic pigment and an average particle size of 100 nm or less onto the applied coating liquid to subject the coating liquid to a coagulating treatment followed by pressing a coating layer including the coating liquid and the coagulating liquid against a heated casting drum while the coating layer is in a wet condition to subject the coating layer to a cast treatment.
    Type: Grant
    Filed: April 28, 2010
    Date of Patent: December 20, 2011
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takatoshi Tanaka, Hiroshi Asakawa, Hitoshi Nagashima, Takeshi Tsurusaki, Saki Suzuki
  • Patent number: 8043694
    Abstract: Porous ceramic part comprising a porous ceramic foam having a total porosity of between 50 and 92% and an intergranular porosity of at least 5%, walls of at least some of the cells of the ceramic foam being at least partly covered with an impregnation material. The invention relates in particular to a recrystallized silicon carbide foam impregnated with silicon.
    Type: Grant
    Filed: January 30, 2007
    Date of Patent: October 25, 2011
    Assignee: Saint Gobain Centre de Recherches et d'Etudes Europeen
    Inventors: Christian Claude His, Franceline Villermaux, Nicolas Raffin, Michel Dussaulx
  • Patent number: 8025838
    Abstract: The invention provides a process of making porous structures or materials, including the colloidal processing (e.g. slip casting, pressure casting, tape casting or electrophoretic deposition) of solid particle emulsions to form a green body that can be directly sintered without a de-binding step.
    Type: Grant
    Filed: June 27, 2006
    Date of Patent: September 27, 2011
    Assignee: K.U. Leuven Research & Development
    Inventors: Bram Neirinck, Jozef Vleugels, Jan Fransaer, Omer Van Der Biest
  • Patent number: 7942274
    Abstract: A microporous asymmetrical membrane formed of one or more layers wherein the “tight” side of the membrane has an “opened” face or otherwise highly-porous reticulated surface is described. The microporous asymmetrical membrane has high throughput and high flux, even when used for filtering viscous materials, such as serum or plasma. The membrane's surface can be formed by ablation or solvation, or in a two or more layered structure, through an appropriate selection of casting dopes.
    Type: Grant
    Filed: December 14, 2006
    Date of Patent: May 17, 2011
    Assignee: Millipore Corporation
    Inventors: Willem Kools, Claire Marie Goulding, Daniel Calnan, Timothy Dolan
  • Patent number: 7918349
    Abstract: Composite membranes that exhibit long-term resistance to biofouling comprise a porous support and a crosslinked polyamide discriminating layer having an external surface, the discriminating layer comprising a branched poly(alkylene oxide) (PAO) polymer attached to its external surface. The branched PAO polymer typically has the structure of a molecular comb or brush, and is made by polymerization of a PAO macromonomer of the following formula: RO—[(CHR?)n—O]m—V in which R is hydrogen or a C1-20 aliphatic or aromatic group, V is any group containing a polymerizable site, each R? is independently hydrogen or a short chain alkyl group, n is an integer of 1-6, and m is an integer of 1 to about 200. The ? end group can be either polymerized or copolymerized.
    Type: Grant
    Filed: March 16, 2009
    Date of Patent: April 5, 2011
    Assignee: Dow Global Technologies LLC
    Inventors: William E. Mickols, Qingshan Jason Niu
  • Patent number: 7882962
    Abstract: A hydrophilizing agent for a hydrophobic porous membrane, wherein the agent contains a surfactant, and the surfactant has a frothability such that the bubble height immediately after frothing, as measured according to the Ross-Miles method (JIS K 3362), using a 0.1 wt % aqueous solution of the surfactant at 25° C., is 40 mm or less, and preferably has a frothability such that the bubble height five minutes after frothing is 20 mm or less; a method for hydrophilizing a hydrophobic porous membrane using this hydrophilizing agent; and a method for testing and hydrophilizing a membrane module using this hydrophilizing agent.
    Type: Grant
    Filed: May 9, 2007
    Date of Patent: February 8, 2011
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Noritaka Shibata, Makoto Ideguchi, Wataru Fujii
  • Patent number: 7807221
    Abstract: An object of the present invention is to provide a composite porous membrane, which has not only excellent filtration capacity, but also excellent adhesion between a porous membrane and a braid and mechanical properties, and a method for producing the composite porous membrane. The present invention relates to a composite porous membrane comprising a braid, and a membrane material; wherein the membrane material comprises a first porous layer comprising a dense layer which is arranged on the outer surface of the braid, and a second porous layer comprising a dense layer which is arranged on the first porous layer, and a method for producing the composite porous membrane.
    Type: Grant
    Filed: June 21, 2007
    Date of Patent: October 5, 2010
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Katsuhiko Shinada, Kei Murase, Teruyuki Yamada, Yuuichi Shirasu, Masahiko Mizuta, Hiroyuki Fujiki
  • Publication number: 20100247894
    Abstract: The present invention provides microporous polymers and methods for producing and using the same. In particular, microporous polymers of the present invention are highly porous as indicated by a Gurley air permeability flow rate of about 4 seconds or less per mL of air flow per 25 micron of microporous polymer thickness per square inch.
    Type: Application
    Filed: June 9, 2010
    Publication date: September 30, 2010
    Applicant: POROUS POWER TECHNOLOGIES, LLC
    Inventor: Kirby W. Beard
  • Publication number: 20100108599
    Abstract: A membrane generally comprises a tubular support, and a polymeric membrane film on the support. The polymeric membrane film comprises three zones cast simultaneously from a single dope. The three zones include an inner zone on the support comprising macro-void pores, an intermediate zone on the inner zone comprising macro-void pores smaller than the macro-void pores of the inner zone, and a skin on the intermediate zone comprising pores of less than 1 micron.
    Type: Application
    Filed: November 3, 2008
    Publication date: May 6, 2010
    Inventors: Kristof Vizvardi, Mailvaganam Mahendran, Krisztina Pelle, Geert-Henk Koops, Andras Gyorgy Pozsgay
  • Publication number: 20090269491
    Abstract: One aspect of the invention provides ion-exchange and gas-diffusion membranes, fabricated by a layer-by-layer approach, for use, e.g., in electrochemical cells; a process for making membrane electrode assemblies fabricated using porous frameworks, LBL composite membranes and LBL carbon-Polymer electrodes; and the application of the membrane and electrode assemblies to a variety of devices, both electrochemical and otherwise.
    Type: Application
    Filed: April 30, 2009
    Publication date: October 29, 2009
    Applicant: Massachusetts Institute of Technology
    Inventors: Paula T. Hammond-Cunningham, Tarek R. Farhat
  • Publication number: 20090239103
    Abstract: A polymer thin film 30 includes a continuous phase 10 primarily composed of polymers of a first monomer 11 and cylindrical microdomains each of which is primarily composed of a polymer of a second monomer 21, the cylindrical microdomains 20 being distributed in the continuous phase 10 and oriented along the penetration direction through the film, wherein the polymer thin film 30 contains block copolymers 31 which include at least respective first segments 12 formed by polymerization of the first monomer 11 and respective second segments 22 formed by polymerization of the second monomer 21, and polymers 13 compatible with the first segments.
    Type: Application
    Filed: November 17, 2006
    Publication date: September 24, 2009
    Inventors: Hirokazu Hasegawa, Mikihito Takenaka, Hiroshi Yoshida
  • Publication number: 20090226683
    Abstract: A microporous fire resistant film coated or laminated composite textile may be uses as an upholstery fabric or mattress ticking which provides an air permeable microporous barrier to liquid, allergen or pathogen particle, or biological organism penetration. The microporous cellular structure of the coated or laminated film backing may provide a high capacity reservoir which may contain additives such as antimicrobial, UV absorbing, scent dispersing, or organism repelling particles or other functional agents, while maintaining superior barrier and air permeability properties in the finished product constructions. Applications may include any seating and bedding products where a combination of two or more of the above properties is desired.
    Type: Application
    Filed: March 5, 2009
    Publication date: September 10, 2009
    Inventors: Bernard Perry, Ray L. Hauser, Kirby Beard
  • Patent number: 7560024
    Abstract: This invention provides for a method to control the pore size or bubble point of porous membranes made by phase inversion in a continuous manufacturing process by blending two or more solutions each capable of producing a porous membrane with different pore size or bubble point than the pore size or bubble point of the desired membrane, and blending these solutions by the method of this invention to produce the desired pore size or bubble point. This invention also provides for a method to monitor membrane pore size in a continuous process and adjust pore size during the continuous manufacturing process.
    Type: Grant
    Filed: April 21, 2003
    Date of Patent: July 14, 2009
    Assignee: Millipore Corporation
    Inventors: Willem Franciscus Catherina Kools, Ronald Tuccelli, Gabriel Tkacik
  • Publication number: 20080299357
    Abstract: This invention provides a fabric having a foamed layer. The fabric is obtained by the foaming method which prevents to expand heat expansible micro capsules in a cross-linked resin. A foamed layer is laminated on the fabric material. The foamed layer is comprising of heat expanded micro capsules, a synthetic resin holding the capsules on the fabric material, silica fine powders which are hydrophilic and fine porous. The fabric is obtained by the following method. A synthetic resin solution comprising of heat expansible micro capsules and the silica fine powders is prepared. The solution is applied on the fabric material at all surface or pattered surface. The synthetic resin layer is formed after drying. After that, the heat expansible micro capsules are expanded by heating.
    Type: Application
    Filed: July 16, 2008
    Publication date: December 4, 2008
    Applicants: UNITIKA FIBERS LTD., SEIREN CO., LTD.
    Inventors: Kiyoshi Nakagawa, Yoshiaki Kurushima, Masahiro Mizuma
  • Patent number: 7435348
    Abstract: The present invention provides a polyvinyl chloride hollow filtration membrane, which mainly comprises the following components: 30-95 wt. % of polyvinyl chloride and 5-70 wt. % of vinyl chloride-vinyl acetate-maleic anhydride terpolymer, wherein the polymerization degree of polyvinyl chloride is from 700 to 2500; the content of vinyl acetate is 10-19 % and the content of maleic anhydride is 18-40 % on a basis of total weight of the terpolymer; and the absolute viscosity of the terpolymer is 1.2-1.9 mPa·s. A method for preparing such a polyvinyl chloride hollow filtration membrane is also provided in the present invention.
    Type: Grant
    Filed: August 2, 2004
    Date of Patent: October 14, 2008
    Assignee: Shanghai Litree Purifying Equipment Co., Ltd.
    Inventor: Lianggang Chen
  • Patent number: 7381441
    Abstract: The invention relates to the production of nanoporous silica dielectric films and to semiconductor devices and integrated circuits comprising these improved films. The nanoporous films of the invention are prepared using silicon containing pre-polymers and are prepared by a process that allows crosslinking at lowered gel temperatures by means of a metal-ion-free onium or nucleophile catalyst.
    Type: Grant
    Filed: April 10, 2002
    Date of Patent: June 3, 2008
    Assignee: Honeywell International Inc.
    Inventors: Roger Y. Leung, Eric Deng, Songyuan Xie, Victor Y. Lu