Abstract: Aquatic organism repellent agents are derived from algae, sponges, tunicates, bryozoans, echinoderms and coelenterates and prevent the attachment and accumulation of microscopic and macroscopic organisms to surfaces in aquatic environments. One or more of the agents may be incorporated into a carrier for release of the agent in the locus to be protected.

Abstract: Wood is modified by impregnating wood with a methylsiloxane oligomer and heating the impregnated wood to cure the oligomer. The oligomer is of the average compositional formula: (CH.sub.3 SiO.sub.3/2).sub.m (MO.sub.3/2).sub.n or [CH.sub.3 SiO.sub.3/2 ].sub.x [(CH.sub.3).sub.a SiO.sub.(4-a)/2 ].sub.y [MO .sub.3/2 ].sub.z wherein M is P, PO and/or B, m and n are positive numbers with an average ratio of m:n ranging from 99:1 to 50:50, x, y, and z are positive numbers with an average ratio of (x+y):z ranging from 99:1 to 50:50 and an average ratio of x:y ranging from 99:1 to 50:50, and a is 2 or 3, and has a hydroxyl group and/or an alkoxyl group at a terminal end. This treatment of wood is safe. Since the methylsilicone resins thus incorporated and fixed within wood are not leached out in water, the modified wood maintains flame retardance for a very long time upon exposure to rain and dew and has water repellence, decay resistance and dimensional stability.

Abstract: The instant invention concerns a wood preservative composition comprising a synergistically effective amount of (a) a cuprammonium compound and (b) tebuconazole to preserve wood.

Abstract: The present invention is directed to producing a smooth hard coating on a wood substrate. A layer of a foamed polymerized latex emulsion is applied on the surface of a wood substrate, such as an oriented strand board. The layer is dried, crushed and then cured to form the coating. If desired the cured coating may be provided with a post cure heat treatment to improve its hardness. The present invention is also directed to applying and drying the layer of the foamed polymerized latex emulsion on a mat of wood fibers or flakes and then crushing and curing the crushed layer and the mat into a hardboard having a smooth hard coating. The coating of the present invention is useful as a sealer coat on a wood substrate. By adding pigment to polymerized emulsion, the sealer coat can be used to provide a finish coat on the wood substrate.

Abstract: A multi-ply structure which includes a release coating sandwiched between two plies of the structure and present in an amount of about 5 to about 25 g/sq yd., one of the plies of the structure being flexible and in contact with the release coating and removable therefrom by the application of a force of between about 90 to about 600 g/in., as determined by the Keil test procedure, including a composition for forming the release coating and comprising an aqueous coating composition which includes a solids portion and which is effective in forming a coating having release properties, the solids portion of the composition comprising a major amount of resin binder and a minor amount of filler, the filler comprising a major amount of clay and a minor amount of magnesium or calcium hydroxide, and including also a continuous process for forming such multi-ply structure, including particularly a structure comprising a poly(vinyl chloride) ply strippable from a support ply.

Abstract: Lumber, plywood and other wood products are preserved from attack by fungi, termites and wood-destroying insects as well as fire and flame by treatment with a novel zirconium borate-containing preservative composition. The preservative can be formed by combination of a source of boron such as boric acid and the water-soluble salts thereof with a water-soluble zirconium salt. The ZrO.sub.2 :B.sub.2 O.sub.3 weight ratio in the preservative composition is in the range of from about 0.75:1 to about 10:1.

Abstract: Wood and other cellulose-based products are preserved with a water-based treating solution containing a phenolic resin prepolymer such as phenol formaldehyde resin prepolymer, a resorcinol formaldehyde resin prepolymer and water. The treatment is carried out by exposing the wood or other cellulose-based product, while submerged in the treating solution, to one or more cycles of reduced pressure (i.e. vacuum) and elevated pressure.

Abstract: Novel aminoplast anchored UV stabilizers are provided. Compared to unanchored stabilizers, the anchored stabilizers disclosed herein have increased compatibility with coating resins and have reduced volatility due to higher molecular weights resulting from anchoring. A process for preparing the anchored stabilizers by the reaction of unanchored stabilizers with alkoxymethylated aminoplasts in a sulfuric acid medium is also provided. The unanchored stabilizers include 2-(2-hydroxyaryl)benzotriazoles, 2-hydroxybenzophenones, 2-(2-hydroxyaryl)-4,6-diaryl-1,3,5-triazines, salicylic acid derivatives, 2-hydroxyoxanilides, and blocked derivatives thereof as well as mixtures of two or more stabilizers. The aminoplasts include alkoxymethylated derivatives of glycolurils, melamines, and benzoguanamines.

Abstract: Wood products impregnated with from 30 to 80% of a polymerizable monomer selected from the group consisting of hexanediol diacrylate and hexanediol dimethacrylate have excellent indent resistance. The wood products are impregnated with the monomer solution by placing the wood under a vacuum to remove air, contacting the wood with a monomer solution containing a polymerizable hexanediol diacrylate and/or hexanediol dimethacrylate monomer and from 0.5 to about 2 percent of a thermally activated free radical source as a polymerization initiator for a period sufficient to achieve the desired polymer loading. The wood is then heated under pressure to polymerize or cure the monomers.

Abstract: This invention is related to improved hardeners for proteinaceous materials. More specifically this invention is related to improved imidazolium hardeners for crosslinking a proteinaceous material for use in a photographic film.

Abstract: The invention concerns a method of protecting wood comprising the steps of (a) treating said wood with a composition consisting essentially of (i) 4,5-dichloro-2-n-octyl-3-isothiazolone and optionally one or more other preservative compounds; (ii) a surfactant system consisting of at least one surfactant selected from the group consisting of sulfated anionics, sulfonated anionics, sulfosuccinated anionics, quaternary ammonium cationics, and amphoterics; and (iii) at least one non-polar organic solvent and (b) allowing said solvent to evaporate from said wood.

Abstract: The invention is directed to synergistic biocidal compositions that combine copper salt and an organic biocide selected from the group of tribromophenol, its salts and chelates, and sodium-omadine, its salts and chelates. Wood treated with the preservative compositions have improved fungi resistance.

Abstract: The invention concerns a method and a preservative for protecting wood against decay. According to the method wood is treated with a wood preservative capable of preventing the growth and spread of fungi, said preservative containing at least one complexing agent which binds at least a portion of those metals, typically iron and manganese, naturally occurring in wood that are essential to the growth of fungi. The complexing agents employed can be, e.g., ethylenediaminetetra-acetate, ethylene diamine-di-o-hydroxyphenylacetate a polyphospate or a siderophore produced by a microorganisms. The wood preservative used in the method is water-borne and specific to the decay fungi attacking wood.

Abstract: A product having a textured surface thereon (and its process of manufacture) is disclosed wherein the textured surface is obtained by relieving the stress in pre-stressed polymeric chips that have been distributed as a single layer throughout a polymeric layer superimposed on a substrate.

Abstract: Polyurea/polyurethane coatings can be applied in situ to the edges of substrates without the need for adding any additives to increase flowability or moldability. The in situ application utilizes the extremely fast cure time of polyurea/polyurethanes to provide a method for efficiently creating an article with a protected edge coat by spray applying polyurea/polyurethane to wood substrates. The polyurea/polyurethane will adhere solidly to the substrate, and is applied with sufficient thickness to provide resistance to chemical, environmental, or physical stresses perpendicularly and angularly directed at the edge. The method utilizes a spray gun at high temperature and pressure, combining isocyanate and amine components of the polyurea/polyurethane coating at the nozzle and impinging the combined components onto the edge to be treated. The product of this process gives off no volatile organic compounds (VOCs), is odor free, peel resistant, and sterilized.

Abstract: The present invention concerns a method of manufacturing decorative board meeting exceptionally high standard concerning abrasion resistance, scratch resistance and impact resistance and which for this pruposes is varnished, electron-beam cured to 60-9.5%, is subjected to a pressing treatment and finally it is electron-beam cured to 100% to provide the disired abrasion resistance, gloss, and surface finish.

Abstract: A method of improving tannin stain blocking in a tannin-containing substrate is disclosed which involves applying to the substrate a blend of:(a) an acid-functional polymer formed from about 0.1% by weight to about 20% by weight, based on the total weight of said polymer, of at least one acid-functional monomer; and(b) about 0.1% by weight to about 20% by weight, based on the weight of said acid-functional polymer, of at least one organosilane having a number average molecular weight of from about 100 to about 10,000.A method of improving the physical properties of the coating composition, including viscosity, adhesion, scrub resistance, water whitening resistance, corrosion resistance, hot block resistance and water, fire, smoke, nicotine, pen and ink stain blocking is also disclosed.

Abstract: A method of treating wood by impregnation of the wood with wood-treating-compositions containing compounds which contain elements selected from copper, chromium and arsenic (CCA) and oxyalkylene polymer additives provides improved properties to the treated wood, better control of oxyalkylene polymer distribution, and reduced leaching of the CCA.

Abstract: A wood protection composition comprising whey saponified with an alkali. The saponification may be carried out using caustic soda solution or sodium carbonate. In particular, diluted whey is used. The wood protection composition is suitable primarily for the treatment of wood shavings for use as insulating material in building construction. A method of manufacturing a wood protection composition according to the present invention is also disclosed.

Abstract: Hardeners for hydrophilic colloid defined by the formula: ##STR1## The hardeners are for crosslinking proteinaceous materials for use in photographic films.

Abstract: An aqueous water repellent composition comprising the reaction product of one or more of a carboxylic acid or anhydride containing from 3 to 22 carbon atoms and a polyfunctional aromatic or aliphatic amine or substituted amine containing from 2 to 25 carbon atoms and a water soluble metal complex crosslinking agent containing one or more metals selected from Groups Ia, IIa, IIla, IVa and the first and second rows of transition metals from the Periodic Table of Elements. The composition may contain wax and is dispersed in water to form a water repellent system.

Abstract: A method for the prevention of fire caused by the application to a flammable substratum of a modified bitumen roofing membrane involving concurrent flame heating of the roofing material and substratum during application. The method comprises applying an aqueous solution of fire retardant chemicals to all flammable surfaces to be roofed and adjacent thereto prior to the flame heating of the modified bitumen membrane and the substratum. The fire retardant solution may be applied by a variety of application techniques on the job site or to the roof components prior to construction assembly. Preferred fire retardant formulations and rates of application are disclosed.

Abstract: A graft copolymer is produced by grafting both at least one perfluoroacrylate and at least one N-(oxymethyl)acrylamide, e.g., IBMA, onto a poly(oxyalkylene) composition. This graft copolymer is water dispersible prior to crosslinking while after crosslinking, it becomes a highly durable hydrophobic and oil repellent coating for fibers, textiles, and the like.

Abstract: The present invention relates to the use of thiadiazoles of the type ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 =hydrogen,alkyl groups having 1-4 carbon atomssubstituted alkyl groups having 1-4 carbon atoms which are substituted by halogen, carboxyl, hydroxyl or nitro group,an alkoxyCN, halogen, NO.sub.2 orCOOR in which R=H or alkyl groups 1-4 carbon atoms,and the use of synergistic combinations of thiadiazoles with other biocidal substances as biocides for material protection. The compounds according to-the invention, which are distinguished by a broad, biocidal action spectrum, can be used in particular for wood preservation for preventing the destruction of wood by fungi or bacteria, for the biocidal treatment of plastics and as preservatives or disinfectants. The recommended concentrations for use are 0.01 to 15 percent by weight-preferably 0.1-3.0 percent by weight.

Abstract: Flame retarding and smoke retarding aqueous solutions consisting essentially of: 70-96 weight % of a mixture of ammonium phosphate and ammonium sulphate, 1-20 weight % NaHCO.sub.3, 1-10 weight % EDTA, and water in an amount resulting in an aqueous solution comprising 11-45 weight % solids on the basis of the total weight of the aqueous solution. Methods of producing and using the flame retarding and smoke retarding aqueous solutions to impregnate absorbent porous materials, such as wood, rayon, cotton, wool and similar textile materials are also taught.

Abstract: A wood preservative comprising a styryl triazole derivative of the formula [I] ##STR1## wherein X represents chlorine or hydrogen as an active ingredient. The present wood preservative has a wood-preservating efficacy equivalent to and remarkably improved light resistance as compared with a conventional organic iodine compound slightly inferior in light resistance, and therefore, exhibits a stabilized wood-preservating efficacy without causing discoloration even under irradiation with light.

Abstract: In a method of treating a raw wood material with a formaldehyde polymer in the presence of sulfur dioxide at a reaction temperature within a reaction vessel to obtain a modified wood material, sulfur dioxide is supplied into the reaction vessel when a gas pressure of the formaldehyde polymer within the reaction vessel is 4.00.times.10.sup.4 Pa or more. In addition, a concentration of the formaldehyde polymer is in a range of 30 to 350 mol/m.sup.3 of formaldehyde monomer, and a molar ratio of the formaldehyde polymer to sulfur dioxide is in a range of 10 to 350. As the formaldehyde polymer, for example, trioxane, tetraoxane, or paraformaldehyde is used. The modified wood material manufactured by the method including the above conditions shows excellent dimensional stability while a discoloration thereof is effectively prevented. Therefore, the modified wood material is particularly fit to use for an interior furniture, musical instrument and a bath tub, etc.

Abstract: A method and apparatus for the ultraviolet curing of pigmented coatings having a thickness from about 1 mm to about 10 mm at a high curing rate and a relatively low energy consumption per unit area of coating cured. A coated substrate is irradiated by a first high UV source having a spectral energy distribution of the discharge which is high in the range from about 350 nm to about 450 nm and by a second UV source having a spectral energy distribution of the discharge which is high in discrete regions through the range of about 200 nm to about 450 nm. Each UV source is powered by at least about 300 watts per inch of width of the coating.

Abstract: Disclosed herein is a process for a coating composition for application at extremely high pressures under conditions which significantly reduce the amount of volatile organic materials which are given off during the spray process. Preferably, the coating composition is based upon a plasticizer wet nitrocellulose lacquer. The composition is utilized in a spray process involving the filling of a spray pump receptacle with the coating wherein the spray pump is operated at pressures above about 2,750 psi and wherein the pump is provided with a temperature control means for assuring that the temperature of the pumped coating is in the range of about 65.degree. F. to 150.degree. F. so that the viscosity of the pumped coating is maintained in the range of about 250 to about 1,000 cps. The resulting coatings may be applied as a top coat, sealer, lacquer, etc. to any desired substrate, although wood is preferred, with the resulting finished coating being equal or superior to existing coating compositions.

Abstract: A crosslinkable resin composition containing:(A) from 10% to 90% by weight of a thermoplastic resin component,(B) from 90% to 10% by weight of a curable resin component, comprising, expressed by reference to the curable resin (100%),(i) 50% to 95% of a (meth)acryloyl derivative, and(ii) 50% to 5% of a (meth)allyloxy derivative, and(C) from 0% to 30% by weight of a plasticiser for the thermoplastic resin component, is disclosed.Also a new crosslinked resin layer and a process for the manufacture of the new crosslinked resin layer on a substrate are described.The crosslinked resin layer herein exhibits a desirable balance between flexibility, resistance to stain and resistance to scuff properties, in combination with outstanding mechanical and chemical properties.The crosslinkable resin composition is particularly suitable for coating application of various substrates such as flooring materials, wall covering materials, coils, wires, and various shaped articles e.g. cars, containers and metallic profiles.

Abstract: A method for uniformly coating the uppermost surface of a fibrous cellulosic decor sheet with an aqueous or melamine-based slurry containing a colorant using a slot coater; a decor sheet prepared by such method; and a laminate employing such decor sheet are described.

Abstract: A method for impregnating a porous, non-metallic construction material with a solid phase-change material is described. The phase-change material in finely divided form is spread onto the surface of the porous material, after which the porous material is exposed to microwave energy for a time sufficient to melt the phase-change material. The melted material is spontaneously absorbed into the pores of the porous material. A sealing chemical may also be included with the phase-change material (or applied subsequent to the phase-change material) to seal the surface of the porous material. Fire retardant chemicals may also be included with the phase-change materials. The treated construction materials are better able to absorb thermal energy and exhibit increased heat storage capacity.

Abstract: Method and process using a supercritical fluid, with or without the aid of entrainers 1) to solubilize a monomer, monomer mixture or polymer which may or may not include additives and entrainers, 2) to carry the supercritical solvent mixture thereby created into the wood matrix, 3) to remove extractives from the wood, 4) to precipitate the monomer or polymer within the wood, and 5) to polymerize the monomer in situ in the wood.

Abstract: Disclosed herein is a process for preparing and applying a coating composition at extremely high pressures under conditions which significantly reduce the amount of volatile organic materials which are given off during the spray process. The spray process involves filling a spray pump receptacle with the coating wherein the spray pump is operable at pressures above about 2,750 psi and wherein the pump is provided with a temperature control means for assuring that the temperature of the pumped coating is in the range of about 65.degree. F. to 120.degree. F. so that the viscosity of the pumped coating is maintained in the range of about 250 to about 1,000 cps. The resulting coatings may be applied as a top coat, sealer, lacquer, etc. to any desired substrate, although wood is preferred, with the resulting finished coating being equal or superior to existing coating compositions.

Abstract: Environmentally preferred water-based coatings can be substituted for solvent-based coatings in commercial wood finishing processes without sacrifice of coating quality. Art-recognized discoloration of water-based coatings due to uneven leaching of chromophoric substances, such as natural tannins, is eliminated by contacting the surface with a water soluble anti-leachate compound selected from the group consisting of carboxylic acid salts, mono/polyfunctional amines and amine derivatives and their acid addition salts. The process allows for marked reduction of VOC emissions from commerical wood finishing operations.

Abstract: Oil-borne preservative-impregnated wood is post-treated by:(A) contacting the preservative-impregnated wood in a closed vessel with steam and collecting a water-containing condensate generated in the vessel;(B) applying a vacuum which is sufficient to reflux water condensate to remove at least some surface deposits from the wood and to distill water out of the vessel leaving an oil-preservative solution in the vessel;(C) releasing the vacuum; and(D) recovering the post-treated wood from the vessel.

Abstract: A process for protecting wood by applying to the wood an aqueous solution of a composition comprising sodium borate and sodium carbonate. Adverse effects on the color of the wood are reduced by including in the composition a component selected from a weakly acidic compound able to form a complex with cellulose; the weakly acidic compound and titanium dioxide; an alkyl ammonium chloride; the weakly acidic compound and an alkyl ammonium chloride; and an alkaline earth metal hydroxide.

Abstract: The present invention relates to a process for protecting stone materials, marble, tiles and cement as well as articles manufactured from these materials from the decay caused by the atmospheric agents and pollutants. The process uses a mixture consisting of:1) polytetrafluoroethylene in the form of an aqueous dispersion,2) an emulsion or a microemulsion of perfluoropolyethers either having or not having functional groups at their ends which is applied onto the surface of the materials or articles.

Abstract: A method for preservation treatment of wood comprises the steps of radiating a laser beam on a part of the surface of the wood at the least to form small holes therein, impregnating the wood with a preservative, and then applying high frequency waves to the wood to dry it by dielectric heating.

Abstract: Retroreflective sheeting has been improved by a coating comprising silica and a transparent polymer selected from aliphatic polyurethanes, polyvinyl chloride copolymers having a minor amount of a comonomer containing at least one carboxylic acid or hydroxyl moiety, and acrylic polymers. Silica comprises 10-80 weight percent (10-70% in the case of polyacrylates) of the transparent protective coating. For example, a solution or dispersion of polyurethane is mixed with a silica sol and possibly other ingredients (e.g. wetting agent, UV light absorber and adhesion promoter), and the composition is coated onto the retroreflective sheet and dried. The coated retroreflective sheeting has superior soil and dew repellancy, retaining a higher percentage of original brightness after exposure to dirt and/or dew conditions.

Abstract: Discoloration of water-based coatings due to uneven leaching of chromophoric substances, such as natural tannins and applied stains, is eliminated by contacting the surface with a water soluble anti-leachate compound selected from the group consisting of carboxylic acid salts, mono/polyfunctional amines and amine derivatives and their acid addition salts.

Abstract: A method and apparatuses for treating railroad ties by injecting a flowable treating material through unused or unoccupied spike holes in railroad rail tie plates which anchor the bottom flange of a railroad rail to the wooden ties. In one embodiment of the invention, the apparatus includes a backpack unit including a tank and pump assembly secured to the back of a user by shoulder straps with a manually manipulated injector device insertable into an unused or unoccupied spike hole in a tie plate in a sealed relationship thereto.

Abstract: The invention comprises a process for the preservation of timber with a boron based compound, such as trimethyl borate. The timer is dried to a low moisture content, is then subjected to a vapor of the boron compound in a suitable treatment vessel, and after vapor treatment is steam conditioned to return the moisture content of the timber to a normal working level. The vapor treatment is preferably carried out under heat and reduced pressure. Timber preserved by the process is also claimed.

Abstract: Method and process using a supercritical fluid, with or without the aid of entrainers (1) to solubilize a monomer, monomer mixture or polymer which may or may not include additives and entrainers, (2) to carry the supercritical solvent mixture thereby created into the wood matrix, (3) to remove extractives from the wood, (4) to precipitate the monomer or polymer within the wood, and (5) to polymerize the monomer in situ in the wood.

Abstract: This invention is concerned with methods for treating wet fir-woods or leaf-woods mainly for reduction of their moisture content and for preservation.The procedure of the invention is conducted in two steps. In the first step, the wet wood is kept in a bath of molten paraffin or a mixture of paraffin with paraffin oil at weight ratios from 90:10 to 10:90 containing 0.05 to 5 percent by weight of colloidal silicon dioxide at 80.degree. to 180.degree. C. for 10 to 50 minutes.In the second step, the wood is transferred into another bath of an emulsion consisting of 10 to 30 parts by weight of an aqueous urea/formaldehyde resin with solid content of 30 to 50 percent by weight in term of the solid content of the resin, 0.1 to 0.8 percent by weight of catalyst, 90 to 70 parts by weight of paraffin or a mixture of paraffin with paraffin oil at weight ratios from 90:10 to 10:90, and optionally 1 to 8 parts by weight of additives, preferably emulsifier, pigment, fungicide, and insecticide.

Abstract: A process for the continuous production of a surface-consolidated lumber, in which the surface layer of a lumber to be treated is hardened and consolidated, is provided. In this process, a lumber to be treated is coated with a thermosetting resin and is then fed between hot-pressing rolls in a plurality of pairs of hot-pressing rolls, and the lumber is continuously heat-compressed between the hot-pressing rolls and simultaneously the thermosetting resin is cured, whereby the surface of the lumber is hardened and consolidated.

Abstract: A composition comprising a silane, siloxane or combination thereof, a catalyst and an ultraviolet radiation absorber. The composition is applied to the surfaces of carbon central structures to diminish the harmful effects thereon of water and ultraviolet radiation. Some examples of carbon central structures as defined herein are fences, decks, awnings, seat covers, umbrellas, carpeting and furniture. The composition is applied to the surface to be treated and allowed a sufficient time in order to penetrate.

Abstract: A wood preservative composition comprises a wood preservative such as a chromated copper arsenate-oil emulsion or an ammoniacal copper arsenate emulsion having about 0.1 to 15 percent chromated copper arsenate, ammoniacal copper arsenate, or ammoniacal copper zinc arsenate, about 1 to 20 percent oil and about 0.3 to 2.5 percent (based on total final emulsion) surfactant material. The first surfactant preferably has a hydrophilic lipophilic balance of about 7 to 9.5 and a second surfactant has a hydrophilic lipophilic balance of about 15 to 20. It is preferred that the first surfactant have an ethoxyl mole ratio less than about 5 and that the second surfactant have a mole ratio greater than about 15. The surfactant material may be composed of a first surfactant having an average mole ratio of about 1 to 5 and a second surfactant having an average mole ratio of about 20 to 100. The composition is storage stable for extended periods and provides a number of beneficial properties for wood products.

Abstract: A novel hardening agent for photographic gelatin coatings comprising a composite solution of a substituted 1,3,5 triazine and formaldehyde, in which the ratio of triazine to formaldehyde ranges from 1:0.1 to 1:0.7. The hardening agent may be added to the gelatin coating in the amount of 0.5 to 4 weight % based upon the gelatin content.

Abstract: A method for preserving wood uses a pressurized solution of concentrated thujone oil. The concentrated thujone oil is applied to the wood to be preserved at a pressure in the range of 120 to 200 p.s.i. Preferably, the wood to be preserved is heated to about 110.degree. before application of the thujone oil. The thujone oil penetrates deep into the wood to provide a long-lasting wood preservative effect. In addition, the wood preservative imparts a cedar aroma to the preserved wood.