Polyamide Patents (Class 428/1.25)
  • Patent number: 11760838
    Abstract: The polyimide resin precursor in the present embodiment is a polyimide resin precursor obtained by allowing a diamine component and a tetracarboxylic acid anhydride component to react with each other, wherein based on the whole of the diamine component, the content of p-phenylenediamine is 75 mol % or more; the tetracarboxylic acid anhydride component includes an ester-containing tetracarboxylic acid anhydride represented by formula (1), and at least one biphenyltetracarboxylic acid anhydride selected from the group consisting of 3,4,3?,4?-biphenyltetracarboxylic acid dianhydride, 2,3,3?,4?-biphenyltetracarboxylic acid dianhydride and 2,3,2?,3?-biphenyltetracarboxylic acid dianhydride; and based on the whole of the tetracarboxylic acid anhydride component, (i) the total of the content of the ester-containing tetracarboxylic acid anhydride and the content of the biphenyltetracarboxylic acid anhydride is 75 mol % or more, and (ii) the content of the ester-containing tetracarboxylic acid anhydride is 15 to 80 mo
    Type: Grant
    Filed: April 30, 2020
    Date of Patent: September 19, 2023
    Assignee: Arisawa Mfg. Co., Ltd.
    Inventors: Hiroyuki Matsuyama, Yoshinori Sato
  • Patent number: 11347110
    Abstract: Provided are a composition for a liquid crystal alignment agent, a manufacturing method of a liquid crystal alignment film, a liquid crystal alignment film using the same, and a liquid crystal display device including the liquid crystal alignment film. More specifically, there are provided the manufacturing method of a liquid crystal alignment film capable of providing the liquid crystal alignment film in which light irradiation energy is able to be reduced, and alignment characteristic and stability are excellent and the voltage holding ratio and electrical characteristics are also excellent through a simple process including applying and drying the composition for a liquid crystal alignment agent on the substrate, directly performing light irradiation to conduct alignment treatment while a high-temperature heat treatment process is omitted, followed by curing by heat treatment, the liquid crystal alignment film, and the liquid crystal display device including the same.
    Type: Grant
    Filed: April 21, 2017
    Date of Patent: May 31, 2022
    Assignee: LG CHEM, LTD
    Inventors: Jung Ho Jo, Hee Han, Hang Ah Park, Soon Ho Kwon, Jun Young Yoon, Hyeong Seuk Yun
  • Patent number: 10884280
    Abstract: A liquid crystal display device comprising; a first display panel including a first substrate, a second substrate that is disposed in a first direction with respect to the first substrate and includes a color filter, and a first liquid crystal layer disposed between the first substrate and the second substrate; a color conversion unit disposed in a second direction opposite to the first direction with respect to the first display panel; and a backlight disposed in the second direction with respect to the color conversion unit. The color conversion unit converts backlight light emitted from the backlight into light of a color corresponding to the color filter, and emits the light.
    Type: Grant
    Filed: October 23, 2018
    Date of Patent: January 5, 2021
    Assignees: Panasonic Liquid Crystal Display Co., Ltd., Pasona Knowledge Partner Inc.
    Inventor: Kikuo Ono
  • Patent number: 10202491
    Abstract: A liquid crystal photoalignment agent is provided. The liquid crystal photoalignment agent is a copolymer of a cyclobutane dianhydride (“CBDA”) and a CBDA derivative.
    Type: Grant
    Filed: April 24, 2014
    Date of Patent: February 12, 2019
    Assignee: SAMSUNG DISPLAY CO., LTD.
    Inventors: Suk Hoon Kang, Hoi-Lim Kim, Yeong Rong Park, Mi Hwa Lee, Jun Woo Lee, Baek Kyun Jeon
  • Patent number: 10106738
    Abstract: An object of the present invention is to provide a polymerizable liquid crystal composition with which two characteristics of smoothness of a surface of an anisotropic optical body and orientation properties of liquid crystals can be simultaneously improved, when preparing an anisotropic optical body to be obtained by photopolymerization of the polymerizable liquid crystal composition. Specifically, an object of the present invention is to provide a polymerizable liquid crystal composition containing specific polymerizable compounds and a fluorine-based surfactant. In addition, an anisotropic optical body, a retardation film, an antireflective film, and a liquid crystal display element prepared using the polymerizable liquid crystal composition of the present invention are also provided.
    Type: Grant
    Filed: October 7, 2014
    Date of Patent: October 23, 2018
    Assignee: DIC CORPORATION
    Inventors: Koichi Endou, Yasuhiro Kuwana, Hidetoshi Nakata, Mika Yamamoto, Kazuaki Hatsusaka
  • Patent number: 10031382
    Abstract: According to one embodiment, a liquid crystal display device includes a liquid crystal display panel which includes a pixel electrode, a liquid crystal layer and an alignment film, and a driver. The driver drives the pixel electrode at a drive frequency of 1 to 20 Hz. The alignment film has a resistivity of 5×1014 ?·cm or more.
    Type: Grant
    Filed: December 23, 2016
    Date of Patent: July 24, 2018
    Assignee: Japan Display Inc.
    Inventors: Daiichi Suzuki, Yoshifumi Saeki, Yukio Tanaka, Noboru Kunimatsu, Hidehiro Sonoda, Masahiro Kosuge
  • Patent number: 9716116
    Abstract: Provided is a TFT array substrate, which increases the area of a drain electrode of a TFT within a light-shielding zone to have the drain electrode overlapping a portion of a horizontal projection of a common electrode, wherein the drain electrode and the common electrode constitute a first storage capacitor and a pixel electrode and the common electrode constitute a second storage capacitor. The pixel electrode and the drain electrode are electrically connected and thus are of the same potential. The first storage capacitor and the second storage capacitor are connected in parallel and collectively form a storage capacitor such that the storage capacitor has a capacity that is equal to the sum of capacities of the first storage capacitor and the second storage capacitor, whereby, without reducing aperture ratio, the capacity of the storage capacitor is increased, crosstalk and image sticking are alleviated, and product display quality is enhanced.
    Type: Grant
    Filed: April 25, 2016
    Date of Patent: July 25, 2017
    Assignee: WUHAN CHINA STAR OPTOELECTRONICS TECHNOLOGY CO., LTD.
    Inventor: Yuanfu Liu
  • Patent number: 9482902
    Abstract: A liquid crystal display device is fabricated by forming a first alignment layer on a first base substrate. A second alignment layer is formed on a second base substrate. A liquid crystal is disposed on one of the first alignment layer and the second alignment layer. The first base substrate and the second base substrate are combined. At least one of the first alignment layer and the second alignment layer is formed by forming an alignment solution on a corresponding base substrate. An alignment layer is formed by curing the alignment solution. The alignment layer is aligned by radiating a light onto the base substrate, first cleaning the base substrate, and baking the alignment layer.
    Type: Grant
    Filed: December 10, 2013
    Date of Patent: November 1, 2016
    Assignee: SAMSUNG DISPLAY CO., LTD.
    Inventors: Jin-Soo Jung, Junwoo Lee, Baekkyun Jeon, Bongsung Seo
  • Patent number: 9470930
    Abstract: Various layer separation states are generated by the combination of a polyamide acid ester and a polyamide acid and a long residual image characteristic cannot be further improved merely by combining them. A liquid crystal display device comprises a substrate, a liquid crystal layer, and an orientation film placed between the substrate and the liquid crystal layer. The orientation film comprises a polyimide precursor having two or more components. In the polyimide precursor, an octanol-water partition coefficient is defined as log P and the difference in log P (? log P) between the two components having most distant log Ps is set so as to fall within a prescribed range.
    Type: Grant
    Filed: September 3, 2014
    Date of Patent: October 18, 2016
    Assignee: Japan Display Inc.
    Inventors: Masaki Matsumori, Shuji Imazeki, Yasushi Tomioka, Noboru Kunimatsu
  • Patent number: 9188811
    Abstract: An alignment film is given a 2-layer structure comprising a photoalignment film that is photoalignable and a low-resistivity alignment film whose resistivity is smaller than that of the photoalignment film. The photoalignment film is formed by a polyimide whose precursor is polyamide acid alkyl ester, the number molecular weight of the photoalignment film is large, and the stability of alignment of the photoalignment film by photoalignment is excellent. The low-resistivity alignment film is formed by a polyimide whose precursor is polyamide acid, the number molecular weight of the low-resistivity alignment film is small, and the resistivity of the low-resistivity alignment film is small. The 2-layer structure alignment film can be maintaining an excellent photoalignment characteristic, so DC afterimages can be controlled.
    Type: Grant
    Filed: July 16, 2013
    Date of Patent: November 17, 2015
    Assignees: Japan Display Inc., PANASONIC LIQUID CRYSTAL DISPLAY CO., LTD.
    Inventors: Chikae Matsui, Noboru Kunimatsu, Hidehiro Sonoda
  • Patent number: 9028926
    Abstract: An IPS type liquid crystal display device superior in mass productivity and improved in image quality with a higher contrast ratio by decreasing the occurrence of defective display due to the disorder of the initial liquid crystal alignment by the liquid orientation control film and realizing stable alignment of liquid crystals comprises: a pair of substrates, at least one which is transparent; a liquid crystal layer disposed between the pair of substrates; a group of electrodes formed on at least one of the pair of substrates to apply an electric field to the liquid crystal layer; plural active elements connected to the group of electrodes; and an orientation control film disposed on at least one of the pair of substrates, wherein said orientation control film is made of a photosensitive polyimide and a polyamide acid ester and is given orientation control ability by being irradiated with substantially linearly polarized light.
    Type: Grant
    Filed: October 23, 2013
    Date of Patent: May 12, 2015
    Assignees: Japan Display Inc., Panasonic Liquid Crystal Display Co., Ltd.
    Inventors: Masaki Matsumori, Yasushi Tomioka, Noboru Kunimatsu
  • Patent number: 8877303
    Abstract: To form an optical alignment film having large anchoring strength and suppress an AC afterimage of a liquid crystal display device, in a liquid crystal display device of an IPS mode. In an alignment film material subjected to optical alignment processing, polyimide which becomes a rigid high molecule and polyimide which becomes a flexible high molecule are mixed and used. The material of the present invention can easily rotate oligomer after irradiating polarized ultraviolet rays and improve a UV-absorbed two-color ratio of an alignment film. Accordingly, an anchoring strength for liquid crystals by the alignment film is large to suppress an AC afterimage.
    Type: Grant
    Filed: May 9, 2012
    Date of Patent: November 4, 2014
    Assignee: Japan Display Inc.
    Inventors: Shoichi Uchino, Noboru Kunimatsu
  • Patent number: 8865273
    Abstract: A photoalignment compound is represented by the following Chemical Formula 1, wherein “x” represents an integer in a range of 1 to 4, each of R1 and R2 represents —(CH2)n—, “n” represents an integer in a range of 1 to 6, at least one of the (—CH2-)s in R1 is replaceable with R3 represents —(CH2)mCH3, “m” represents an integer in a range of 1 to 12, each hydrogen atom of R3 is replaceable with F or Cl, R4 represents an amino group, aniline group, carboxy group, hydroxyl group, cyano group, alkylene group, or functional groups being represented by the following Chemical Formulas 2, 3, 4, or 5, each hydrogen atom of Chemical Formula 1 is replaceable with —O(CH2)kCH3, —(CH2)kCH3, F, or Cl, and “k” represents an integer in a range of 1 to 3, or 0.
    Type: Grant
    Filed: August 7, 2012
    Date of Patent: October 21, 2014
    Assignee: Samsung Display Co., Ltd.
    Inventors: Sung-Chan Jo, Weon-Eik Oii
  • Patent number: 8771809
    Abstract: A photoalignment material includes a photoalignment polymer having a photosensitive portion represented by the following Chemical Formula 1, R1 represents a cyclic compound, each of R2 and R3 represents a single bond, —(CnH2n)—, —(CxH2x)O(CyH2y)—, or —(CaH2a)O(CbH2b)O(CdH2d)—, “n” represents an integer in the range of 1 to 6, each of “x”, “y”, “a”, “b”, and “d” represents 0 or an integer in the range of 1 to 6, x+y is an integer in the range of 1 to 5, and a+b+d is an integer in the range of 1 to 6. Each hydrogen atom is replaceable with —CH3, —CH2—CH3, —OCH3, —OCH2CH3, —OCH2OCH3, F, or Cl, and each hydrogen atom of —CH3, —CH2—CH3, —OCH3, —OCH2CH3, or —OCH2OCH3 is replaceable with F or Cl.
    Type: Grant
    Filed: February 24, 2009
    Date of Patent: July 8, 2014
    Assignee: Samsung Display Co., Ltd.
    Inventors: Fusayuki Takeshita, Jun-Woo Lee
  • Patent number: 8758871
    Abstract: A liquid crystal display is provided which is capable of reducing the occurrence of defective display due to variations in the initial alignment direction of a liquid crystal alignment control film in a liquid crystal display of an IPS scheme, realizing the stable liquid crystal alignment, providing excellent mass productivity, and having high image quality with a higher contrast ratio. The liquid crystal display has a liquid crystal layer disposed between a pair of substrates, at least one of the substrates being transparent, and an alignment control film formed between the liquid crystal layer and the substrate. At least one of the alignment control films 109 comprises photoreactive polyimide and/or polyamic acid provided with an alignment control ability by irradiation of substantially linearly polarized light.
    Type: Grant
    Filed: August 17, 2011
    Date of Patent: June 24, 2014
    Assignees: Japan Display Inc., Panasonic Liquid Crystal Display Co., Ltd.
    Inventors: Yasushi Tomioka, Hidetoshi Abe, Katsumi Kondo
  • Patent number: 8741397
    Abstract: Disclosed is a liquid crystal display element which is composed of a pair of substrates (1) at least one of which is transparent. The liquid crystal display element comprises, between the pair of substrates, a transparent electrode (2), an aligning agent (3) that contains at least reactive monomers and/or oligomers (5), and a liquid crystal layer. The liquid crystal display element is characterized in that an alignment layer is obtained by polymerizing the reactive monomers or oligomers contained in the aligning agent, and the liquid crystal layer is composed of a liquid crystal composition that contains a compound (4) having at least one benzene ring in each molecule, said benzene ring containing at least one fluorine atom and being disubstituted by halogen atoms.
    Type: Grant
    Filed: October 18, 2010
    Date of Patent: June 3, 2014
    Assignees: JNC Corporation, JNC Petrochemical Corporation
    Inventors: Norikatsu Hattori, Atsuko Fujita
  • Patent number: 8722158
    Abstract: Disclosed is a liquid crystal photo-alignment agent and a liquid crystal photo-alignment film manufactured using the same. The liquid crystal photo-alignment agent includes an epoxy compound represented by Chemical Formula 1, and a polymer including a polyamic acid, a polyimide, or a mixture thereof.
    Type: Grant
    Filed: June 2, 2011
    Date of Patent: May 13, 2014
    Assignee: Cheil Industries Inc.
    Inventors: Hyo-Ju Seo, Tae-Hyoung Kwak, Dong-Seon Uh, Jae-Deuk Yang
  • Patent number: 8709552
    Abstract: The resin composition of the present invention is a resin composition characterized by including (a) a polyimide, a polybenzoxazole, a polyimide precursor or a polybenzoxazole precursor, (b) 1,5-dihydroxynaphthalene, 1,6-dihydroxynaphthalene, 1,7-dihydroxynaphthalene, or 2,3-dihydroxynaphthalene, and (c) a thermal cross-linking agent having a specific structure. By the use of the resin composition of the present invention, it is possible to reduce the transmittance in the visible region of a cured film while maintaining the transmittance of a resin film before curing.
    Type: Grant
    Filed: January 15, 2010
    Date of Patent: April 29, 2014
    Assignee: Toray Industries, Inc.
    Inventors: Kazuto Miyoshi, Mika Koshino, Masao Tomikawa
  • Publication number: 20140106089
    Abstract: A liquid crystal composition, a liquid crystal film and a display device are provided. The liquid crystal composition can be uniformly aligned with no problems such as dewetting in an operation of aligning horizontally alignable liquid crystals. Also, a state of the aligned liquid crystal compound can be stably maintained.
    Type: Application
    Filed: October 18, 2013
    Publication date: April 17, 2014
    Applicant: LG CHEM, LTD.
    Inventors: Dae Hee LEE, Sin Young KIM, Da Mi LEE, Moon Soo PARK
  • Patent number: 8691350
    Abstract: An object of the present invention is to provide a liquid crystal display device in which a risk of generation of a image sticking is reduced. A liquid crystal display device (100) of the present invention includes a pair of glass substrates (11) and (21), a liquid crystal layer (30) provided between the pair of glass substrates (11) and (21), an alignment layer (23) provided between the liquid crystal layer (30) and at least one of the pair of glass substrates (11) and (21), and an alignment sustaining layer (24) for defining a direction in which liquid crystal molecules constituting the liquid crystal layer (30) are inclined, the alignment sustaining layer (24) being provided between the alignment layer (23) and the liquid crystal layer (30), the alignment layer (23) and the alignment sustaining layer (24) being covalently bound to each other.
    Type: Grant
    Filed: April 28, 2010
    Date of Patent: April 8, 2014
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Masanobu Mizusaki, Youhei Nakanishi
  • Patent number: 8681300
    Abstract: A liquid crystal display device includes a pair of substrates, a liquid crystal between substrates and alignment layers disposed on the inner surface sides of the substrates. The alignment layer is made from a material including polyamic acid containing a diamine component and polyimide containing a diamine component different from the diamine component of the polyamic acid. The alignment layer is subjected to alignment treatment by irradiation of light. UV light can be irradiated in the oblique direction onto the alignment layer through a mask having openings. A reflecting plate can be arranged between a UV light source and the mask. Also, bank structures having a thickness from 0.1 to 0.15 ?m can be provided on the alignment layer of the TFT substrate.
    Type: Grant
    Filed: March 7, 2013
    Date of Patent: March 25, 2014
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Hideo Chida, Hidefumi Yoshida, Yasutoshi Tasaka
  • Patent number: 8679596
    Abstract: The present invention provides a liquid crystal display device including a first substrate and a second substrate that are arranged to face each other while sandwiching liquid crystal, wherein: a first electrode and plural second electrodes are formed at a pixel area on the first substrate on the liquid crystal side; an alignment layer is provided which includes a first alignment layer formed on the first substrate on the liquid crystal side to cover the second electrodes and a second alignment layer formed on the first alignment layer on the liquid crystal side; the resistance of the second alignment layer is lower than that of the first alignment layer; and the transmittance of the second alignment layer is lower than that of the first alignment layer.
    Type: Grant
    Filed: February 13, 2013
    Date of Patent: March 25, 2014
    Assignee: Japan Display Inc.
    Inventors: Masato Ito, Masato Sakurai, Takeshi Sato
  • Patent number: 8673177
    Abstract: A liquid crystal alignment agent includes a polymer and an organic solvent for dissolving the polymer. The polymer is obtained by subjecting a diamine composition and a tetracarboxylic dianhydride compound to a polymerization reaction. The diamine composition includes a first diamine compound, a second diamine compound, and a third diamine compound as defined in the specification. A liquid crystal alignment film formed from the liquid crystal alignment agent and a liquid crystal display element including the liquid crystal alignment film are also disclosed.
    Type: Grant
    Filed: September 21, 2011
    Date of Patent: March 18, 2014
    Assignee: Chi Mei Corporation
    Inventor: Tsung-Pei Tsai
  • Patent number: 8592009
    Abstract: A liquid crystal display device superior in mass productivity and improved image quality with a higher contrast ratio by decreasing the occurrence of defective display due to the disorder of the initial liquid crystal alignment and realizing stable alignment of liquid crystals, comprising: a pair of substrates 101 and 102, at least one of which is transparent; a liquid crystal layer 110? disposed between the pair of substrates; a group of electrodes formed on at least one of the pair of substrates to apply an electric field to the liquid crystal layer; plural active elements 115 connected to the group of electrodes; and an orientation control film 109 disposed on at least one of the pair of substrates, wherein said orientation control film made of a photosensitive polyimide, a polyamide acid ester and a polyamide acid is given orientation control ability by being irradiated with substantially linearly polarized light.
    Type: Grant
    Filed: August 15, 2008
    Date of Patent: November 26, 2013
    Assignees: Hitachi Display, Ltd., Panasonic Liquid Crystal Display Co., Ltd.
    Inventors: Masaki Matsumori, Yasushi Tomioka, Noboru Kunimatsu
  • Publication number: 20130265532
    Abstract: A liquid crystal display device and a method for manufacturing the same are disclosed. In an embodiment of the present invention, a liquid crystal display device and a method of manufacturing the liquid crystal display device includes a first substrate that has a first electrode formed thereon, a second substrate that faces the first substrate, a liquid crystal layer that is formed between the first substrate and the second substrate, and a first alignment layer that is formed on the first substrate and is in contact with the liquid crystal layer. Here, the first alignment layer includes a first alignment base layer that is photoaligned, and a first alignment controlling layer that is extended from the inside of the first alignment base layer.
    Type: Application
    Filed: May 22, 2013
    Publication date: October 10, 2013
    Inventor: Jae-Hoon KIM
  • Patent number: 8551581
    Abstract: A liquid crystal display includes: a first substrate and an opposing second substrate; an alignment layer formed on the first substrate and the second substrate; and a liquid crystal layer interposed between the first substrate and the second substrate. The alignment layer includes a copolymer including a dianhydride monomer and a diamine monomer.
    Type: Grant
    Filed: July 13, 2011
    Date of Patent: October 8, 2013
    Assignee: Samsung Display Co., Ltd.
    Inventors: Ho Yun Byun, Duck Jong Suh, Won-Gap Yoon, Na-Young Shin, Sang Hee Yu
  • Patent number: 8545946
    Abstract: A liquid crystal alignment solution is provided, including at least one polymer selected from the group consisting of a polyamide acid-polyamide acid polymer represented by formula (A), a polyimide-polyamide acid polymer represented by formula (B) and a polyimide-polyimide polymer represented by formula (C), as defined in the contexts.
    Type: Grant
    Filed: March 25, 2010
    Date of Patent: October 1, 2013
    Assignee: Daxin Materials Corporation
    Inventors: Min-Ruei Tsai, Wen-Chung Chu, Chia-Wen Chang, Ming-Chih Lai
  • Patent number: 8530008
    Abstract: A liquid crystal display (LCD) device includes at least one substrate; and an alignment layer over the substrate, wherein the alignment layer includes material having a main chain adapted to be aligned by a rubbing process and a photo-reactive side chain adapted to be aligned by irradiation.
    Type: Grant
    Filed: January 31, 2012
    Date of Patent: September 10, 2013
    Assignee: LG Display Co., Ltd.
    Inventor: Su Hyun Park
  • Patent number: 8501286
    Abstract: The present invention discloses a reactive monomer of liquid crystal. The reactive monomer of liquid crystal is added with at least one fluoro group. Because hydrocarbon bonds of a side chain of polyimide surface of an alignment film has a fluorophobic effect, the fluoro group of the reactive monomer of liquid crystal can lower the interaction between the polyimide surface of the alignment film and the reactive monomer of liquid crystal to thus evenly deposit the liquid crystal composition containing the reactive monomers of liquid crystal onto the polyimide surface of the alignment film. Thus, it can avoid from occurring the phenomenon of drop Mura defect occurred during implementing the ODF technology.
    Type: Grant
    Filed: August 11, 2011
    Date of Patent: August 6, 2013
    Assignee: Shenzhen China Star Optoelectronics Technology Co., Ltd.
    Inventors: Chung-Ching Hsieh, Chengming He
  • Patent number: 8496849
    Abstract: Disclosed is a liquid crystal orientating agent which contains a liquid crystal orientating polyorganosiloxane obtained by reacting a specified reactive polyorganosiloxane typified by the hydrolysis condensate of 2-(3,4-epoxycyclohexyl)ethyltrimethoxysilane and a reactive compound which includes a specified compound typified by stearic acid. The liquid crystal orientating agent of this invention can form liquid crystal orientating films which have excellent liquid crystal orientating properties, a high level of heat resistance and light resistance, exhibit little reduction of voltage retention even in high temperature environments and when irradiated with light of high intensity, and excellent residual image characteristics, and it also has excellent storage stability.
    Type: Grant
    Filed: January 29, 2009
    Date of Patent: July 30, 2013
    Assignee: JSR Corporation
    Inventors: Kenichi Sumiya, Toshiyuki Akiike, Tsutomu Kumagai, Eiji Hayashi
  • Patent number: 8497002
    Abstract: An alignment film is given a 2-layer structure comprising a photoalignment film that is photoalignable and a low-resistivity alignment film whose resistivity is smaller than that of the photoalignment film. The photoalignment film is formed by a polyimide whose precursor is polyamide acid alkyl ester, the number molecular weight of the photoalignment film is large, and the stability of alignment of the photoalignment film by photoalignment is excellent. The low-resistivity alignment film is formed by a polyimide whose precursor is polyamide acid, the number molecular weight of the low-resistivity alignment film is small, and the resistivity of the low-resistivity alignment film is small. The 2-layer structure alignment film can be maintaining an excellent photoalignment characteristic, so DC afterimages can be controlled.
    Type: Grant
    Filed: September 16, 2009
    Date of Patent: July 30, 2013
    Assignees: Hitachi Displays, Ltd., Panasonic Liquid Crystal Display Co. Ltd.
    Inventors: Chikae Matsui, Noboru Kunimatsu, Hidehiro Sonoda
  • Patent number: 8491973
    Abstract: A photo-alignment material, a liquid crystal display device using the photo-alignment material, and a manufacturing method. The photo-alignment material is a polymer having a photo-reactive ethenyl group on a main chain. When used as a photo-alignment layer, the photo-alignment material enables improved alignment stability against external shocks, light, and heat. The liquid crystal display device includes a first substrate, a second substrate, a liquid crystal layer formed between the first and second substrates, and a photo-alignment layer formed at least on the first substrate, with the photo-alignment layer formed from a photo-alignment material having an ethenyl group at a main chain.
    Type: Grant
    Filed: April 19, 2007
    Date of Patent: July 23, 2013
    Assignee: LG Display Co., Ltd.
    Inventor: Mi Sook Nam
  • Patent number: 8487069
    Abstract: Disclosed is a liquid crystal photo-alignment agent including polyamic acid or a polyimide including a first structural unit derived from a photo-diamine represented by the following Chemical Formula 1, a second structural unit represented by the following Chemical Formula 2 or a polymer compound combination thereof, and a solvent. In Chemical Formulae 1 and 2, each substituent is the same as defined in the detailed description.
    Type: Grant
    Filed: September 1, 2010
    Date of Patent: July 16, 2013
    Assignee: Cheil Industries Inc.
    Inventors: Jae-Deuk Yang, Hee-Young Oh, Myoung-Youp Shin, Mi-Ra Im, Guk-Pyo Jo, Eun-Ha Kim
  • Patent number: 8470412
    Abstract: Disclosed is a liquid crystal alignment agent that includes a polymer comprising polyamic acid including a repeating unit represented by the following Chemical Formula 1, polyimide including a repeating unit represented by the following Chemical Formula 2, or a combination thereof. In Chemical Formulae 1 and 2, X1, X2, Y1 and Y2 are the same in the detailed description.
    Type: Grant
    Filed: September 21, 2011
    Date of Patent: June 25, 2013
    Assignee: Cheil Industries Inc.
    Inventors: Myoung-Youp Shin, Eun-Ha Kim, Jae-Deuk Yang, Yong-Sik Yoo, Guk-Pyo Jo, Jung-Gon Choi
  • Patent number: 8455062
    Abstract: To provide a liquid crystal display panel that has high contrast and reduced display deficiency, a liquid crystal display panel of the present invention includes: a pair of substrates (1) and (2) facing each other; and a liquid crystal layer (3) sandwiched between the pair of substrates (1) and (2), the pair of substrates (1) and (2) being provided with a pair of respective alignment films (4) and (5) formed thereon and facing each other, the pair of alignment films (4) and (5) being provided with respective polymer films (6) and (7) formed thereon and each made of a monomer in the liquid crystal layer (3), the pair of alignment films (4) and (5) containing a macromolecular compound having a side chain containing a fluorine atom, the liquid crystal layer (3) containing a polymerizable monomer represented by at least one of General Formulae (1) through (3), the polymer films (6) and (7) each being made of the polymerizable monomer represented by at least one of General Formulae (1) through (3), the polymer fil
    Type: Grant
    Filed: March 24, 2010
    Date of Patent: June 4, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Takako Nakai, Masanobu Mizusaki, Youhei Nakanishi
  • Patent number: 8425799
    Abstract: The present invention provides a liquid crystal photoalignment agent that includes a compound selected from the group consisting of a polyamic acid having a predetermined chemical formula, a polyimide polymer having a predetermined chemical formula, and a combination thereof, and a polyimide photopolymer. The liquid crystal photoalignment agent shows a long life-span, stably maintains a pretilt angle, and shows improved after-image characteristics, liquid crystal alignment properties, and chemical resistance.
    Type: Grant
    Filed: December 31, 2007
    Date of Patent: April 23, 2013
    Assignee: Cheil Industries Inc.
    Inventors: Tae-Hyoung Kwak, Dong-Seon Uh, Jae-Min Oh, Jae-Deuk Yang
  • Patent number: 8411238
    Abstract: To provide a liquid crystal display panel that has high contrast and reduced display deficiency, a liquid crystal display panel of the present invention includes: a pair of substrates (1) and (2) facing each other; and a liquid crystal layer (3) sandwiched between the pair of substrates (1) and (2), the pair of substrates (1) and (2) being provided with a pair of respective alignment films (4) and (5) formed thereon and facing each other, the pair of alignment films (4) and (5) being provided with respective polymer films (6) and (7) formed thereon and each made of a monomer in the liquid crystal layer (3), the pair of alignment films (4) and (5) containing a macromolecular compound having a functional group represented by at least one of General Formulae (1) through (5), the liquid crystal layer (3) containing a polymerizable monomer represented by at least one of General Formulae (6) through (8), the polymer films (6) and (7) each being (i) made of the polymerizable monomer represented by at least one of Ge
    Type: Grant
    Filed: March 24, 2010
    Date of Patent: April 2, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Takako Nakai, Masanobu Mizusaki, Youhei Nakanishi
  • Patent number: 8400595
    Abstract: A liquid crystal display device includes a pair of substrates, a liquid crystal between substrates and alignment layers disposed on the inner surface sides of the substrates. The alignment layer is made from a material including polyamic acid containing a diamine component and polyimide containing a diamine component different from the diamine component of the polyamic acid. The alignment layer is subjected to alignment treatment by irradiation of light. UV light can be irradiated in the oblique direction onto the alignment layer through a mask having openings. A reflecting plate can be arranged between a UV light source and the mask. Also, bank structures having a thickness from 0.1 to 0.15 ?m can be provided on the alignment layer of the TFT substrate.
    Type: Grant
    Filed: December 1, 2011
    Date of Patent: March 19, 2013
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Hideo Chida, Hidefumi Yoshida, Yasutoshi Tasaka
  • Patent number: 8329264
    Abstract: Disclosed are a liquid crystal alignment agent, and a liquid crystal alignment film and a liquid crystal display (LCD) including the same. The liquid crystal alignment agent includes a polymer of polyamic acid, a polyimide, or a combination thereof, and an epoxy compound represented by the following Chemical Formula 1. In the above Chemical Formula 1, each substituent is the same as defined in the specification.
    Type: Grant
    Filed: August 19, 2009
    Date of Patent: December 11, 2012
    Assignee: Cheil Industries Inc.
    Inventors: Bum-Jin Lee, Won-Seok Dong, Mi-Ra Im, Dong-Seon Uh
  • Patent number: 8304039
    Abstract: A liquid crystal display is provided that includes a first substrate; a second substrate facing the first substrate; a field generating electrode disposed on at least one of the first substrate and the second substrate; an alignment layer disposed on the field generating electrode; and a liquid crystal layer interposed between the first substrate and the second substrate and including a liquid crystal and an alignment polymer. The alignment layer initially contains an alignment material including an initiator, and the alignment polymer initially contains an alignment aid.
    Type: Grant
    Filed: October 12, 2010
    Date of Patent: November 6, 2012
    Assignee: Samsung Display Co., Ltd.
    Inventors: Ho-Kil Oh, Su-Jeong Kim, Su-Han Woo, Jae-Jin Lyu, Min-Hee Kim
  • Patent number: 8300189
    Abstract: Provided is a liquid crystal (LC) device and method thereof. The device comprises (i) a body of liquid crystal, (ii) a first layer comprising a first material, and (iii) a second layer comprising a second material; wherein the first layer is located between the body of liquid crystal and the second layer; the first layer alone aligns the liquid crystal in a first orientation; the second layer alone aligns the liquid crystal in a second orientation; and the first orientation is different from the second orientation. With optimized first layer thickness, the invention can be used in sensor applications to improve detection sensitivity, and in LCD applications with enhanced control over LC pretilt transition.
    Type: Grant
    Filed: June 26, 2009
    Date of Patent: October 30, 2012
    Assignee: Kent State University
    Inventors: Ke Zhang, Philip J. Bos, Robert J. Twieg, Na Liu
  • Publication number: 20120128899
    Abstract: A liquid crystal display (LCD) device includes at least one substrate; and an alignment layer over the substrate, wherein the alignment layer includes material having a main chain adapted to be aligned by a rubbing process and a photo-reactive side chain adapted to be aligned by irradiation.
    Type: Application
    Filed: January 31, 2012
    Publication date: May 24, 2012
    Inventor: Su Hyun PARK
  • Patent number: 8164725
    Abstract: A liquid crystal device includes: a circuit substrate; a counter substrate disposed so as to be opposed to the circuit substrate; a liquid crystal layer interposed between the circuit substrate and the counter substrate, the liquid crystal layer showing vertical alignment as an initial alignment state; a first alignment layer manufactured on a side of the counter substrate using a coating process, the side facing the liquid crystal layer, the first alignment layer having a vertical alignment function; and a second alignment layer manufactured on a side of the circuit substrate using a vacuum process, the side facing the liquid crystal layer, the second alignment layer generating a pretilt.
    Type: Grant
    Filed: February 6, 2009
    Date of Patent: April 24, 2012
    Assignee: Seiko Epson Corporation
    Inventors: Nobukazu Nagae, Takeshi Miyashita
  • Patent number: 8133409
    Abstract: A method of fabricating a liquid crystal display (LCD) device includes preparing at least a first substrate, coating an alignment material on at least the first substrate, aligning a main chain of the alignment material in a predetermined direction, and irradiating polarized ultraviolet (UV) rays onto the alignment material whose main chain has been aligned in the predetermined direction to form an alignment layer.
    Type: Grant
    Filed: June 13, 2006
    Date of Patent: March 13, 2012
    Assignee: LG Display Co., Ltd.
    Inventor: Su Hyun Park
  • Publication number: 20120013834
    Abstract: Provided are a liquid crystal film, a method of manufacturing a liquid crystal film, a method of controlling an average tilt angle of the liquid crystal film, a polarizing plate, and a liquid crystal display device. A liquid crystal film that has excellent properties including durability and an optical property and is capable of being effectively used for various uses may be provided. In addition, the physical properties of the liquid crystal film may be easily controlled according to a desired use.
    Type: Application
    Filed: July 18, 2011
    Publication date: January 19, 2012
    Applicant: LG CHEM, LTD.
    Inventors: Su Young RYU, Byoung Kun Jeon, Moon Soo Park, Sin Young Kim, Hyuk Yoon, Hyoung Gu Kang, Sang Jun Yoon
  • Patent number: 8088301
    Abstract: Disclosed is an epoxy compound for a liquid crystal photo-alignment agent, a liquid crystal photo-alignment agent, and a liquid crystal photo-alignment film. The epoxy compound is represented by the following Chemical Formula 1. In the above Chemical Formula 1, each substituent is the same as defined in the specification. Since the epoxy compound according to an embodiment of the present invention may be prepared through a simple manufacturing process, it is possible to provide a liquid crystal photo-alignment agent and a liquid crystal photo-alignment film that are economical and have excellent substrate printability and reliability, and superb photoelectric characteristics.
    Type: Grant
    Filed: December 8, 2009
    Date of Patent: January 3, 2012
    Assignee: Cheil Industries Inc.
    Inventors: Jae-Deuk Yang, Dong-Seon Uh, Tae-Hyoung Kwak, Hyo-Ju Seo
  • Patent number: 8057868
    Abstract: The present invention provides: a composition for forming a liquid crystal alignment film capable of forming a liquid crystal alignment film excellent in evenness; and a liquid crystal display device. The present invention provides a composition for forming a liquid crystal alignment film, wherein the composition comprises: a material for forming a liquid crystal alignment film; diethylene glycol diethyl ether; diisobutyl ketone; and at least one of ?-butyrolactone and N-methyl-2-pyrrolidone as solvents.
    Type: Grant
    Filed: January 7, 2009
    Date of Patent: November 15, 2011
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Shinichi Terashita, Eiji Satoh, Iori Aoyama, Shouichi Nakata
  • Patent number: 8057700
    Abstract: One embodiment of the present invention provides a liquid crystal photo-alignment agent that includes a polyamic acid copolymer including a repeating unit having the following Formula 1 and a repeating unit having the following Formula 2; a polyimide copolymer including a repeating unit having the following Formula 3 and a repeating unit having the following Formula 4; or a combination thereof: wherein the definition of R1 to R8 are the same as in the specification. The liquid crystal photo-alignment agent can have improved liquid crystal alignment properties, electrical characteristics such as voltage holding ratio, pretilt angle, residual DC, and the like, printability, cleaning stability, and spot stability, and is capable of unidirectionally aligning liquid crystals by ultraviolet (UV) exposure.
    Type: Grant
    Filed: December 5, 2008
    Date of Patent: November 15, 2011
    Assignee: Cheil Industries, Inc.
    Inventors: Jae-Min Oh, Dong-Seon Uh, Jae-Deuk Yang, Tae-Hyoung Kwak
  • Patent number: 8053041
    Abstract: There has been a need for an overcoat film composition that functions as an overcoat film in terms of high transparency and flatness, and that also functions as an aligning film in terms of liquid crystal molecular alignment. There has also been a need to lower the cost of manufacturing a liquid crystal display element. There is provided an overcoat film composition comprising one or more compounds selected from the group of polyester-polyamic acids (A1) obtained using at least a polyhydric hydroxy compound (a1), a diamine (a2), and a compound having two or more acid anhydride groups (a3), and polyester-polyimides (A2) that are imidization products thereof, and a polyamic acid (B).
    Type: Grant
    Filed: June 28, 2007
    Date of Patent: November 8, 2011
    Assignee: JNC Corporation
    Inventors: Hiroyuki Satou, Takahiro Mori
  • Patent number: 8025939
    Abstract: A liquid crystal display is provided which is capable of reducing the occurrence of defective display due to variations in the initial alignment direction of a liquid crystal alignment control film in a liquid crystal display of an IPS scheme, realizing the stable liquid crystal alignment, providing excellent mass productivity, and having high image quality with a higher contrast ratio. The liquid crystal display has a liquid crystal layer disposed between a pair of substrates, at least one of the substrates being transparent, and an alignment control film formed between the liquid crystal layer and the substrate. At least one of the alignment control films 109 comprises photoreactive polyimide and/or polyamic acid provided with an alignment control ability by irradiation of substantially linearly polarized light.
    Type: Grant
    Filed: May 18, 2010
    Date of Patent: September 27, 2011
    Assignee: Hitachi Displays, Ltd.
    Inventors: Yasushi Tomioka, Hidetoshi Abe, Katsumi Kondo