Paper Support Composition Specified Patents (Class 428/32.21)
  • Patent number: 11802205
    Abstract: An aqueous polyurethane resin dispersion includes a cationic group and a polyalkylene oxide in a side chain thereof. The polyurethane resin is obtainable by reacting a polyester polyol, a polyether diol, a polyol containing a quaternary N-atom or tertiary amino group, and a polyisocyanate. The polyester polyol is obtained by reacting an aromatic polycarboxylic acid and a polyol. The polyurethane resin is suitable as a resin in treatment liquids of substrates and images made by inkjet printing.
    Type: Grant
    Filed: November 19, 2018
    Date of Patent: October 31, 2023
    Assignee: AGFA NV
    Inventors: Hubertus Van Aert, Ellen Bertels
  • Patent number: 11781029
    Abstract: The invention relates to a heat-sensitive recording material, comprising a carrier substrate and a heat-sensitive colour-forming layer, which contains at least one colour former and at least one phenol-free colour developer, characterised in that the at least one colour developer is the compound of formula (A), Ar(NH—CO—NH—CO—NH—Ar1)n (A), wherein Ar is an unsubstituted or substituted phenyl or naphthyl group, Ar1 is an unsubstituted or substituted phenyl, naphthyl, pyridyl, thiazolyl or benzothiazolyl group, and n is 1 or 2.
    Type: Grant
    Filed: May 6, 2019
    Date of Patent: October 10, 2023
    Assignee: PAPIERFABRIK AUGUST KOEHLER SE
    Inventors: Michael Horn, Timo Stalling, Kerstin Zieringer
  • Patent number: 11492759
    Abstract: A fiber body forming method includes a step of defibrating a raw material containing fibers to form a defibrated material; a step of depositing the defibrated material to form a web; a step of applying a liquid containing a thermoplastic resin which binds the fibers to the web; and a step of heating the web to which the liquid is applied to form a fiber body, and in the method described above, the fiber body has a storage elastic modulus of 600 MPa or more at 100° C. and a storage elastic modulus of 400 MPa or more at 150° C.
    Type: Grant
    Filed: June 5, 2020
    Date of Patent: November 8, 2022
    Assignee: Seiko Epson Corporation
    Inventor: Shigemi Wakabayashi
  • Patent number: 11162001
    Abstract: The present invention relates to a composition comprising hedgehog shaped particles, at least one binder, and at least one hydrophobizing agent and/or at least one hydrophilizing agent, a method for controlling the wettability of substrate surfaces using these compositions, as well as a material comprising these compositions.
    Type: Grant
    Filed: June 21, 2019
    Date of Patent: November 2, 2021
    Assignee: OMYA INTERNATIONAL AG
    Inventors: Joachim Schoelkopf, Hans-Joachim Weitzel
  • Patent number: 10752741
    Abstract: The present invention relates to an UV blocking film comprising microfibrillated cellulose wherein at least part of the microfibrillated cellulose is microfibrillated cellulose produced from non-chemical modified lignocellulosic material. The invention also relates to a method for producing the film, use of said film as well as a composition having UV blocking properties.
    Type: Grant
    Filed: May 15, 2017
    Date of Patent: August 25, 2020
    Assignee: Stora Enso, OYJ
    Inventors: Isto Heiskanen, Katja Lyytikäinen, Esa Saukkonen, Kaj Backfolk
  • Patent number: 10066117
    Abstract: Paper coatings, coated papers, and printed coated papers are described. The coatings promote adhesion and retention of UV curable printing media such as UV curable inks. Also described are systems and processes for forming the coated papers and printed coated papers.
    Type: Grant
    Filed: September 22, 2015
    Date of Patent: September 4, 2018
    Assignee: Avery Dennison Corporation
    Inventors: Neil Clifford, David W. Whitman, Ronald Wiegers
  • Patent number: 9388532
    Abstract: A water dispersion paper made of wood pulp and/or non-wood pulp is characterized in that purified pulp containing ?-cellulose by 88 percent by weight or more accounts for 15 to 95 percent by weight of all pulp. The water dispersion paper has quick water dispersion property and high strength (printability) and its paper surface pH is 6 to 8 (neutral range).
    Type: Grant
    Filed: August 4, 2014
    Date of Patent: July 12, 2016
    Assignee: NIPPON PAPER PAPYLIA CO., LTD.
    Inventors: Munenaka Koyama, Masaki Kishimoto, Yoshiaki Ishino
  • Publication number: 20150110977
    Abstract: This specification describes a composition for coating on a substrate, such as paper, useful for inkjet printing with ink having an anionic dye. The coating comprises a cationic binder and preferably pigment. The binder may be made of latex forming cationic biopolymer particles, for example made from cationic starch. Cationic biopolymer polymers are used as a cationic fixative. Optionally, a salt with a polyvalent metal ion may be added top the composition. With this addition, the substrate is also suitable for printing with dispersed pigment based inkjet ink.
    Type: Application
    Filed: October 22, 2014
    Publication date: April 23, 2015
    Inventors: Sabina DI RISIO, Ralph DE JONG, Ray CARLSON
  • Patent number: 8974876
    Abstract: Disclosed is a printable paper comprising a water-resistant support having two optionally subbed sides and a single layer on at least one of said optionally subbed sides, wherein said single layer has no substantial compositional variation, has a layer thickness of at least 3 ?m, a pore volume of at least 1.2 mL/m2 and comprises at least one porous pigment. Also disclosed is a process for producing such a printable paper and use thereof in printing.
    Type: Grant
    Filed: August 29, 2012
    Date of Patent: March 10, 2015
    Assignee: Agfa-Gevaert
    Inventors: Dirk Quintens, Dirk Franky Kokkelenberg
  • Publication number: 20150050434
    Abstract: The present invention relates to a sizing composition that, when applied to paper substrate, creates a substrate, preferably suitable for inkjet printing, having increased print density, print sharpness, low HST, and/or image dry time, the substrate preferably having high brightness and reduced color-to-color bleed as well. In addition, the present invention relates to a method of reducing the HST of a paper substrate by applying the sizing composition to at least one surface thereof. Further, the application relates to methods of making and using the sizing composition, as well as methods of making and using the paper containing the sizing composition.
    Type: Application
    Filed: November 3, 2014
    Publication date: February 19, 2015
    Inventors: Jay C. SONG, Sen YANG, Yan C. HUANG, Kapil M. SINGH, Michael F. KOENIG, David B. SHELMIDINE
  • Patent number: 8927073
    Abstract: A recording media containing a raw base wherein said media encompasses, on its image side, a pigmented pre-coating layer and a non-polyolefin barrier coating and, on its backside, a polymeric barrier layer. Also disclosed is a method of making such recording media and methods of forming photographic printed images on said recording media.
    Type: Grant
    Filed: December 23, 2010
    Date of Patent: January 6, 2015
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Xiaoqi Zhou, Xulong Fu, Tao Chen
  • Patent number: 8927110
    Abstract: The present invention provides plain printing paper comprising a paper substrate containing, as main components, cellulose pulp and calcium carbonate as a filler, and an optional cationic resin and a multivalent cation salt attached onto the paper substrate, wherein the total amount of the cationic resin and the multivalent cation salt attached on both surfaces of the paper substrate is 1.0 g/m2 to 5.0 g/m2, both inclusive, and the mass ratio of the cationic resin to the multivalent cation salt is 0:100 to 90:10, both inclusive.
    Type: Grant
    Filed: September 21, 2011
    Date of Patent: January 6, 2015
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Koji Idei, Masanori Nagoshi, Kazutoshi Iida, Atsushi Nakamura
  • Publication number: 20140363581
    Abstract: Provided is a printing coated paper which is advantageous not only in that the coated paper has offset printability and causes no mottling in the printed area even in ink jet printing, but also in that the coated paper exhibits excellent rubbing resistance with respect to the printed area and excellent print density of a dye ink. The task of the present invention is achieved by a printing coated paper having a coating layer comprised mainly of a pigment and a binder formed on at least one side of a base paper, wherein the base paper is a treated base paper which has been subjected to size press using a treatment solution containing at least one member selected from a cationic resin and a water-soluble multivalent cation salt, wherein the total applied amount per each side of the at least one member selected from a cationic resin and a water-soluble multivalent cation salt, in terms of the solids content, is in the range of from 0.1 to 5.
    Type: Application
    Filed: January 15, 2013
    Publication date: December 11, 2014
    Applicant: Mitsubishi Paper Mills Limited
    Inventors: Masanori Nagoshi, Koji Idei, Tetsuya Nishi, Toru Kaneko
  • Patent number: 8906476
    Abstract: A composition is provided, which comprises a water-soluble salt of a divalent metal; a complexing agent having an affinity for the divalent metal; and an optical brightening agent. Methods of using the composition, and recording sheets which include the composition, are also disclosed.
    Type: Grant
    Filed: January 25, 2013
    Date of Patent: December 9, 2014
    Assignee: International Paper Company
    Inventors: Zheng Tan, Sen Yang, Jingxiu Wan, Benny J. Skaggs, Benjamin Thomas Liguzinski
  • Patent number: 8900677
    Abstract: A print medium includes a first layer on at least one of a first side and a second side of a substrate and a second layer. The first layer consists essentially of at least 80% by dry weight of one or more particulate inorganic pigments (PIPs). A combination of a particle size and a coat weight of the first layer on the substrate yields an effective pore size of the first layer in a range of about 0.008 to about 0.5 microns. For two or more PIPs in the first layer, the average particle size of one of the PIPs differs by no more than about 50% from the average particle size of another of the PIPs. The second layer is on top of the first layer and includes a particulate inorganic pigment (PIP) having an average particle size of about 0.1 to about 2 microns.
    Type: Grant
    Filed: July 21, 2011
    Date of Patent: December 2, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Jason Swei, Sandeep K Bangaru
  • Patent number: 8877678
    Abstract: An object of the present invention is to provide a water dispersion paper having quick water dispersion property and high strength (printability) and whose paper surface pH is 6 to 8 (neutral range), and also to provide a water dispersion coated paper designed to ensure quick water dispersion property and prevent discoloration over time. A water dispersion paper made of wood pulp and/or non-wood pulp, wherein said water dispersion paper is characterized in that purified pulp containing ?-cellulose by 88 percent by weight or more accounts for 15 to 95 percent by weight of all pulp, as well as a water dispersion coated paper having a water-soluble coating layer on said water dispersion paper.
    Type: Grant
    Filed: July 28, 2011
    Date of Patent: November 4, 2014
    Assignee: Nippon Paper Papylia Co., Ltd.
    Inventors: Munenaka Koyama, Masaki Kishimoto, Yoshiaki Ishino
  • Patent number: 8865277
    Abstract: In one example, an inkjet media includes a substrate layer with cellulose fibers, synthetic fibers, and a polymeric binder. A barrier layer is disposed on at least one side of the substrate layer, the barrier layer including pigment fillers and at least 30 percent by weight of a polymer resin.
    Type: Grant
    Filed: March 29, 2011
    Date of Patent: October 21, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Xiaoqi Zhou, Xulong Fu, David Edmondson
  • Publication number: 20140308463
    Abstract: A recording medium for manufacturing recorded material in which a face opposing to an image forming face of a recording medium, which has an image formed by an inkjet method, is bonded, includes a base material and an adhesive agent layer including polyisoprene.
    Type: Application
    Filed: March 31, 2014
    Publication date: October 16, 2014
    Applicant: SEIKO EPSON CORPORATION
    Inventors: Kiyohiko TAKEMOTO, Masaru HOSHINO
  • Publication number: 20140307025
    Abstract: An inkjet recording material that contains a supporting substrate and an image-receiving layer formed on at least one side of the supporting substrate, said layer including at least one inorganic pigment, and a latex binder having the formula (I). Also disclosed herein are the method of making said inkjet recording material and a method for producing printed images that encompasses using said recording material.
    Type: Application
    Filed: November 18, 2011
    Publication date: October 16, 2014
    Applicant: HEWLETT-PARCKARD DEVELOPMENT COMPANY, L.P.
    Inventors: Steven L. Webb, Christopher Arend Toles
  • Publication number: 20140300663
    Abstract: This invention is directed to an recording sheet having improved image dry time for use in printing comprising a substrate having in contact with at least one surface thereof one or more water soluble divalent metal salts, preferably admixed with one or more starches, to process of forming such recording sheet, to a method of generating one or more image(s) on said recording sheet in an printing process and to a recording sheet having one or more images on a surface thereof.
    Type: Application
    Filed: June 24, 2014
    Publication date: October 9, 2014
    Inventors: MICHAEL F. KOENIG, SEN YANG, STEVE D. SCHULTZ, WILLIAM R. SPERRY, HAI Q. TRAN, JOHN L. STOFFEL, LAWRENCE E. GIBSON, RICHARD R. HARTMAN, RONALD A. ASKELAND
  • Patent number: 8846138
    Abstract: A method for surface treatment of a paper substrate and a paper product produced therefrom are disclosed herein. The surface treatment method includes applying a salt-containing solution to at least one surface of a paper substrate by aerosol spraying in a separate step, whereby the salt distribution through the thickness of the treated paper substrate is non-uniform with the highest concentration of salt being present in the outermost portion of the paper substrate. The salt-containing solution contains at least one water-soluble metal salt and is void of any optical brightening agent (OBA).
    Type: Grant
    Filed: March 10, 2010
    Date of Patent: September 30, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Xiaoqi Zhou, Xulong Fu, Gracy Wingkono
  • Publication number: 20140285569
    Abstract: An inkjet recording medium includes a substrate having two opposed surfaces, an ink receiving layer disposed on at least one of the two substrate surfaces, and a porous protective layer disposed on the ink receiving layer. The ink receiving layer receives an ink when printed thereon. The protective layer includes: reactive polymer particles that cross-link upon exposure to microwave radiation; non-reactive polymer particles that coalesce upon exposure to microwave radiation; or a combination of the reactive polymer particles and the non-reactive polymer particles, to form a substantially non-porous protective film that covers the printed ink.
    Type: Application
    Filed: October 24, 2011
    Publication date: September 25, 2014
    Inventors: Xiaoqi Zhou, Tao Chen, Eric L. Burch
  • Patent number: 8821997
    Abstract: An inkjet recording medium and a coating composition for forming an inkjet recording medium. In accordance with one aspect of the present invention, an inkjet recording medium is disclosed comprising an inkjet-receptive coating on a paper substrate. The inkjet-receptive coating contains a synergistic combination of pigments, binder and a multivalent metal salt such that the inkjet recording medium exhibits improved inkjet print properties, particularly when printed with a high speed inkjet printer using pigmented inks.
    Type: Grant
    Filed: December 15, 2011
    Date of Patent: September 2, 2014
    Assignee: Newpage Corporation
    Inventors: Charles E. Romano, Jr., James P. Niemiec, Leonard J. Schliesman, Jr.
  • Patent number: 8821998
    Abstract: An inkjet recording medium and a coating composition for forming an inkjet recording medium. In accordance with one aspect of the present invention, an inkjet recording medium is disclosed comprising an inkjet-receptive coating on a paper substrate.
    Type: Grant
    Filed: September 25, 2013
    Date of Patent: September 2, 2014
    Assignee: Newpage Corporation
    Inventor: Charles E. Romano
  • Patent number: 8815375
    Abstract: Support materials for printing electrically conductive structures by means of inkjet printing with inks which contain conductive particles lead to low resistances for the printed structures without thermal post-treatment when they contain a microporous layer with a mean pore size of less than 100 nm as an outer layer.
    Type: Grant
    Filed: September 9, 2010
    Date of Patent: August 26, 2014
    Assignee: Schoeller Technocell GmbH & Co. KG
    Inventors: Wolfgang Schmidt, Kirsten Barth-Gremmel
  • Patent number: 8808815
    Abstract: An inkjet-receptive article comprising a substrate having a coating thereon comprising a vinyl lactam polymer or copolymer and a polymer resin diluent coated from a solvent. A preferred vinyl lactam copolymer is polyvinylcaprolactam (PVCap)—vinyl acetate (VA). Also disclosed are solvent-based compositions for forming an inkjet-receptive coating on a substrate comprising: (i) a vinyl lactam polymer or copolymer; (ii) a solvent; (iii) optionally, a pigment; and (iv) polymer resin diluent.
    Type: Grant
    Filed: August 26, 2011
    Date of Patent: August 19, 2014
    Assignee: ISP Investments Inc.
    Inventors: David K. Hood, Surya Kamin, Karyn Visscher
  • Patent number: 8795796
    Abstract: An article in the form of a paper substrate having a water-swellable substrate coating on at least one of the first and second surfaces at a thickness of less than about 10 microns and. The substrate coating has an amount of a coating pigment sufficient to impart a Parker Print Smoothness value of at least about 4 to the at least one surface and is dispersed in a water-swellable coating pigment binder matrix in a coating pigment to binder matrix weight ratio of at least about 2:1. The coating pigment has larger porous coating pigment particles, and smaller coating pigment particles in a weight ratio of at least about 0.2:1. The substrate coating provides an ink-receptive porous surface. Also, a method for preparing such coated paper substrates, as well as a method for printing an image on the coated paper substrate with an inkjet printer using a lower ink usage level.
    Type: Grant
    Filed: July 22, 2011
    Date of Patent: August 5, 2014
    Assignee: International Paper Company
    Inventor: Michael F. Koenig
  • Patent number: 8734919
    Abstract: A pre-stressed substrate for a photographic paper includes a base paper having a front surface and a back surface; a top pre-stress coat on the front surface, the top pre-stress coat including a first pre-stress mixture containing at least a first pigment, a first binding material including a first water soluble binder and a first water-dispersible binder; and a back pre-stress coat on the back surface, the back pre-stress coating including a second pre-stress mixture containing at least a second pigment, a second binding material including a second water soluble binder. The weight % of the first water soluble binder in the first binding material is less than the weight % of the second water soluble binder in the second binding material. The pre-stressed substrate has a predetermined degree of curvature toward the back surface and is capable of countering curling forces that occur when the pre-stressed substrate is used.
    Type: Grant
    Filed: February 27, 2009
    Date of Patent: May 27, 2014
    Assignee: Hewlett-Packard Development-Company, L.P.
    Inventors: Xulong Fu, Christine E. Steichen, Ronald J. Selensky
  • Patent number: 8727528
    Abstract: An inkjet recording medium and a coating composition for forming an inkjet recording medium. In accordance with one aspect of the present invention, an inkjet recording medium is disclosed comprising an inkjet-receptive coating on a paper substrate. The inkjet-receptive coating contains a synergistic combination of pigments, binder and a multivalent metal salt such that the inkjet recording medium exhibits improved inkjet print properties, particularly when printed with a high speed inkjet printer using pigmented inks.
    Type: Grant
    Filed: February 16, 2012
    Date of Patent: May 20, 2014
    Assignee: Newpage Corporation
    Inventor: Charles E. Romano, Jr.
  • Patent number: 8715794
    Abstract: A recording medium includes a base paper, a polymer layer disposed on the base paper, and an ink-receiving layer disposed on the polymer layer. The base paper has a thickness of 50 ?m or more and 130 ?m or less. The polymer layer has a thickness of 20 ?m or more and 60 ?m or less. The polymer layer has an arithmetic average surface roughness Ra1 of 0.12 ?m or more and 0.18 ?m or less. The polymer layer has a roughness curve element average length RSm of 0.01 mm or more and 0.20 mm or less. The recording medium has an arithmetic average surface roughness Ra2 of 0.13 ?m or less.
    Type: Grant
    Filed: June 25, 2013
    Date of Patent: May 6, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuhiko Araki, Yasuhiro Nito
  • Patent number: 8709555
    Abstract: A media for digital high speed inkjet web press printing has a CD residual tensile energy absorption index greater than 300 J/Kg. The media includes a paper base having a MD/CD tensile stiffness index ratio of less than 2.0 and a tensile energy absorption index of greater than 500 J/Kg. The paper base includes a mixture of fibers having a softwood fiber to hardwood fiber ratio within a range of 3 to 7 to 7 to 1, an internal starch having a cationic starch to fiber ratio greater than 1.0%, and a filler within a range of about 1.0% to about 12.0% of paper base weight. The media further includes an image receiving coating on a side of the paper base.
    Type: Grant
    Filed: April 28, 2011
    Date of Patent: April 29, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Lokendra Pal, Jason Swei, Glenn T. Gentile, Sandeep K. Bangaru
  • Patent number: 8697203
    Abstract: A paper sizing composition is provided, which comprises a water-soluble salt of Ca(II) and at least one organic acid; and starch. Methods of making and using the composition, and methods of making and using the recording sheets which include the composition, are disclosed.
    Type: Grant
    Filed: November 14, 2011
    Date of Patent: April 15, 2014
    Assignee: International Paper Company
    Inventor: Michael F. Koenig
  • Patent number: 8685504
    Abstract: A recording medium includes an ink-receiving layer formed by applying a coating liquid onto at least one surface of a substrate and drying the coating liquid, the coating liquid containing hydrated alumina and a binder, in which the hydrated alumina in the coating liquid has an average particle size of 100 nm to 250 nm, the surface of the ink-receiving layer has an arithmetic average roughness Ra of 0.8 ?m to 2.5 ?m, the arithmetic average roughness Ra being specified by JIS B0601:2001, and the surface of the ink-receiving layer has a specular gloss at 60° of 10.0% or less, the specular gloss at 60° being specified by JIS Z8741.
    Type: Grant
    Filed: June 2, 2011
    Date of Patent: April 1, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hitoshi Nagashima, Hiroshi Asakawa, Takatoshi Tanaka, Masaya Asao
  • Patent number: 8652593
    Abstract: An article in the form of a paper substrate having a first surface and a second surface; an internal paper sizing agent present in an amount sufficient to impart to the paper substrate an HST value of from about 50 to about 250 seconds; one or more optical brightening agents present in an amount below a “green over” effect excess but sufficient to impart an ISO Brightness value of at least about 92; and a metal salt drying agent mixture of multivalent and monovalent metal drying salts in a molar ratio of multivalent to monovalent cations of from about 3:1 to about 1:18 to provide a percent ink transferred (“IT %”) value equal to or less than about 65% and a black print density value of at least about 1.45. Also, a method for treating the optically brightened paper substrate with a mixture of multivalent and monovalent metal drying salts.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: February 18, 2014
    Assignee: International Paper Company
    Inventor: Michael F. Koenig
  • Patent number: 8652594
    Abstract: A recording sheet is provided, which comprises: a paper substrate comprising a plurality of cellulosic fibers; and a sizing agent comprising a water soluble divalent metal salt; wherein the paper substrate and sizing agent cooperate to form an I-beam structure. Methods of making and using the recording sheet are also provided.
    Type: Grant
    Filed: March 31, 2009
    Date of Patent: February 18, 2014
    Assignee: International Paper Company
    Inventors: Michael F. Koenig, Jacob P. John, Thomas R. Arnson, Benjamin T. Liguzinski
  • Publication number: 20140045684
    Abstract: An object of the present invention is to provide a water dispersion paper having quick water dispersion property and high strength (printability) and whose paper surface pH is 6 to 8 (neutral range), and also to provide a water dispersion coated paper designed to ensure quick water dispersion property and prevent discoloration over time. A water dispersion paper made of wood pulp and/or non-wood pulp, wherein said water dispersion paper is characterized in that purified pulp containing ?-cellulose by 88 percent by weight or more accounts for 15 to 95 percent by weight of all pulp, as well as a water dispersion coated paper having a water-soluble coating layer on said water dispersion paper.
    Type: Application
    Filed: July 28, 2011
    Publication date: February 13, 2014
    Applicant: NIPPON PAPER PAPYLIA CO., LTD.
    Inventors: Munenaka Koyama, Masaki Kishimoto, Yoshiaki Ishino
  • Publication number: 20140030451
    Abstract: An inkjet recording medium and a coating composition for forming an inkjet recording medium. In accordance with one aspect of the present invention, an inkjet recording medium is disclosed comprising an inkjet-receptive coating on a paper substrate.
    Type: Application
    Filed: September 25, 2013
    Publication date: January 30, 2014
    Applicant: NEWPAGE CORPORATION
    Inventor: Charles E. Romano
  • Patent number: 8628832
    Abstract: A recording medium includes a base and at least one ink-receiving layer. A first ink-receiving layer that is at least one ink-receiving layer contains inorganic particles having an average primary particle size of 1 ?m or less and inorganic particles coated with a metal oxide. The inorganic particles coated with the metal oxide have an average primary particle size of 15.0 ?m or more. When the maximum of a FLOP value of the recording medium is denoted by FLOPMax and the minimum of the FLOP value is denoted by FLOPMin, the FLOPMin is 2.5 or more and a value of FLOPMin/FLOPMax is 0.80 or more and 1.00 or less.
    Type: Grant
    Filed: January 28, 2013
    Date of Patent: January 14, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Ryo Taguri, Hisao Kamo, Tetsuro Noguchi, Yasuhiro Nito, Isamu Oguri, Naoya Hatta, Kazuhiko Araki, Shinya Yumoto
  • Publication number: 20140010975
    Abstract: In one example, an inkjet media includes a substrate layer with cellulose fibers, synthetic fibers, and a polymeric binder. A barrier layer is disposed on at least one side of the substrate layer, the barrier layer including pigment fillers and at least 30 percent by weight of a polymer resin.
    Type: Application
    Filed: March 29, 2011
    Publication date: January 9, 2014
    Applicant: HEWLETT-PACKARD DEVELOPMENT COMPANY, L.P.
    Inventors: Xiaoqi Zhou, Xulong Fu, David Edmondson
  • Patent number: 8613987
    Abstract: An ink-jet recording medium comprising: a support including a base paper, a first polyolefin resin layer disposed on one side of the base paper, and a second polyolefin resin layer disposed on the other side of the base paper, and an ink receiving layer including inorganic particles and a water-soluble resin, the ink receiving layer being disposed on one side of the support, wherein a first surface of the support at a side that is opposite to a side at which the ink receiving layer is disposed has a centerline average roughness (Ra) of from 0.5 ?m to 1.0 ?m when measured in accordance with JIS-B-0601 with a cutoff value of 0.8 mm, and an average surface roughness (Sra) of 0.3 ?m or less when a cutoff value is from 1 ?m to 25 ?m.
    Type: Grant
    Filed: February 29, 2012
    Date of Patent: December 24, 2013
    Assignee: FUJIFILM Corporation
    Inventors: Ryoichi Nakano, Masashi Yamauchi, Atsushi Osawa
  • Patent number: 8613830
    Abstract: A method of modifying the surface of a substrate which comprises a fibrous material. According to the present invention, the surface is brought into contact with a type of amphiphilic block copolymer which comprises one or several hydrophilic polymeric blocks and one or several hydrophobic polymeric blocks. Approximately 0.01-3 g/m2 of the amphiphilic block copolymer are applied onto the surface. With the help of the present invention, it is possible to effectively modify the surface of paper in such a manner that it produces a good surface for printing, for instance for ink-jet printing.
    Type: Grant
    Filed: December 1, 2006
    Date of Patent: December 24, 2013
    Assignee: Helsinki University of Technology
    Inventors: Jukka Seppälä, Arto Salminen
  • Patent number: 8609209
    Abstract: An ink jet recording medium including a substrate and an ink receiving layer provided on the substrate and composed of two or more layers of at least an upper layer and a lower layer. The ink receiving layer contains polyvinyl alcohol in an amount of 12.7% by mass or more based on the total mass of the ink receiving layer. The upper layer is a layer most distant from the substrate, contains a pigment and polyvinyl alcohol, the pigment containing 90% by mass or more of alumina hydrate, and has a thickness of 3.0-10.0 ?m. The lower layer is positioned just under the upper layer, contains a pigment and polyvinyl alcohol, the pigment containing 20% by mass or more of silica, and has a thickness 2.5-10 times larger than that of the upper layer and an average pore radius 0.90-1.30 times larger than that of the upper layer.
    Type: Grant
    Filed: September 30, 2011
    Date of Patent: December 17, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Ryo Taguri, Hisao Kamo, Yasuhiro Nito, Tetsuro Noguchi, Isamu Oguri, Olivia Herlambang, Naoya Hatta
  • Patent number: 8609210
    Abstract: The object of the present invention is to provide a coated printing paper used for ink jet printing machines, which has an ink fixing property and ink absorption property corresponding to ink jet printing, which inhibits poor dot diffusion, and which is excellent in abrasion resistance property of printed portions. According to the present invention, provided is a coated printing paper comprising a base paper, an undercoating layer which is applied on at least one surface of the base paper and contains a pigment and a binder, and one or more coating layers on the undercoating layer, wherein the base paper contains at least one selected from a cationic resin and a multivalent cation salt; the uppermost coating layer contains at least a colloidal silica; and the 75° gloss according to JIS Z8741 of the surface of the uppermost coating layer is 40% or more.
    Type: Grant
    Filed: July 13, 2010
    Date of Patent: December 17, 2013
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Masanori Nagoshi, Koji Idei, Hiroshi Matsuda, Kazutoshi Iida, Jun Urasaki
  • Publication number: 20130316098
    Abstract: An aqueous cationic polyurethane dispersion for waterborne digital print and other applications comprising an aqueous dispersion of polyurethane having properly positioned tertiary amino groups, e.g., tethered tertiary amino group separated from backbone by at least two intervening atoms or terminal tertiary amino groups with multiple tertiary amino groups per terminus, where said amino groups are optionally partially quaternized and/or neutralized.
    Type: Application
    Filed: October 28, 2011
    Publication date: November 28, 2013
    Applicant: LUBRIZOL ADVANCED MATERIALS, INC.
    Inventors: Alexander V. Lubnin, Dennis N. Malaba
  • Patent number: 8592011
    Abstract: In an ink jet recording medium having at least two ink receiving layers, the total content of boric acid, a borate, and a water-soluble zirconium salt of a lower ink receiving layer located close to a support substrate to the total content of alumina and an alumina hydrate thereof is higher than the total content of boric acid, a borate, and a water-soluble zirconium salt of an upper ink receiving layer located apart from the support substrate to the total content of alumina and an alumina hydrate thereof.
    Type: Grant
    Filed: April 18, 2011
    Date of Patent: November 26, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuro Noguchi, Hisao Kamo, Yasuhiro Nito, Isamu Oguri, Ryo Taguri, Olivia Herlambang, Naoya Hatta
  • Patent number: 8586156
    Abstract: An article in the form of a paper substrate having a first surface and a second surface and an acid-resistant water-swellable substrate coating which provides an ink-receptive porous surface on at least one of the first and second surfaces. The substrate coating has an amount of an acid-resistant coating pigment sufficient to impart a Parker Print Smoothness value of at least about 4 to the at least one of the first and second surfaces and is dispersed in an acid-resistant water-swellable crosslinked polymer coating pigment binder matrix, with the coating pigment having from about 30 to 100% larger coating pigment particles with a mean particle size above about 1 micron in diameter. Also, a method for preparing such coated paper substrates.
    Type: Grant
    Filed: April 8, 2011
    Date of Patent: November 19, 2013
    Assignee: International Paper Company
    Inventors: Michael F. Koenig, Kapil M. Singh
  • Publication number: 20130293647
    Abstract: A coating composition for pre-treating a substrate prior to inkjet printing thereon, and an inkjet receiving medium comprising a substrate and having a topmost layer coated thereon, where the coating composition has a solids content which comprises at least 30 wt % of one or more aqueous soluble salts of multivalent metal cations, and particles comprised primarily of polymer having a Rockwell Hardness of less than R90 and having a mode equivalent spherical diameter of at least about 2 micrometers. When coated, the composition provides at least 0.01 g/m2 of particles comprised primarily of polymer having a Rockwell Hardness of less than R90 and which have an equivalent spherical diameter of i) at least about 2 micrometers and ii) at least 0.1 micrometer greater than the minimum coated thickness of the topmost layer.
    Type: Application
    Filed: May 2, 2012
    Publication date: November 7, 2013
    Inventors: Thomas Joseph Dannhauser, Yang Xiang, Raouf Botros
  • Patent number: 8574690
    Abstract: An article in the form of a paper substrate having a first surface and a second surface; an internal paper sizing agent present in an amount sufficient to impart to the paper substrate an HST value of from about 50 to about 250 seconds; and a metal salt drying agent having at least about 20% by weight of one or more monovalent metal drying salts, wherein the metal salt drying agent is present on at least one of the first and second surfaces in an amount sufficient to provide a percent ink transferred (“IT %”) value equal to or less than about 65% and to provide a black print density value of at least about 1.45. Also, a method for treating the internally sized paper substrate having the HST value of from about 50 to about 250 seconds with the metal salt drying agent.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: November 5, 2013
    Assignee: International Paper Company
    Inventors: Michael F. Koenig, Steven D. Schultz, Krshna Pamidimukkala, Sen Yang
  • Patent number: 8541070
    Abstract: A media suitable for inkjet web press printing is disclosed herein. The media includes a paper substrate and an ink receptive layer coated onto at least one surface of the paper substrate. The ink receptive layer includes: inorganic pigments; at least one water-based binder; a water-soluble metallic salt; a colorant durability enhancer selected from the group consisting of boric acid, borax, sodium tetraborate, phenyl boronic acid, butyl boronic acid and combinations thereof; and a coefficient of friction (COF) reducer selected from the group consisting of polyethylene wax, paraffin wax, carnauba wax, polypropylene wax, polytetrafluoroethylene wax, and combinations thereof.
    Type: Grant
    Filed: April 3, 2009
    Date of Patent: September 24, 2013
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Yongzhong Wang, Xi Zeng, Kelly Ronk
  • Publication number: 20130243978
    Abstract: The invention relates to a use of a composition comprising polyaluminium compound and starch solution for improving inkjet printing properties of a ink jet recording sheet by coating or applying it onto the inkjet recording sheet, the inkjet recording sheet comprising wood or lignocellulosic fibre material. The invention relates also to an ink jet recording sheet.
    Type: Application
    Filed: November 8, 2011
    Publication date: September 19, 2013
    Inventors: Juha Lindfors, Sami Puttonen