Particle (e.g., Pigment, Etc.) Containing Layer Patents (Class 428/32.25)
  • Patent number: 11913839
    Abstract: Embodiments of the present disclosure provide an improved method and apparatus for thermal monitoring for a metal additive manufacturing system. An emissivity value of a top surface of an object to be manufactured is determined based, at least in part, on an arithmetic product of a predetermined roughness value and a predetermined slope-related value. The predetermined roughness value and slope-related values are predetermined based, at least in part, on measurements of a previously manufactured object. The system sinters a metal to form the top surface of the object to be manufactured. An infrared sensor detects radiation from at least a portion of the top surface of the object to be manufactured. A temperature is generated based, at least in part, on the detected infrared radiation and the emissivity value and the generated temperature is applied to a temperature utilization component of the system.
    Type: Grant
    Filed: May 18, 2020
    Date of Patent: February 27, 2024
    Assignee: National Technology & Engineering Solutions of Sandia, LLC
    Inventors: Samantha Taylor, Eric Christopher Forrest
  • Patent number: 11577536
    Abstract: An image is formed on a transfer medium comprising a hydrophilic tackifier. Any portion of the image that is dimensionally insufficient to permanently adhere the image to the receiver substrate is determined, and a colorless liquid ink comprising water is applied to cover and surround the portion of the image that is dimensionally insufficient to permanently adhere the image to the receiver substrate. When heat is applied to the image to transfer the image layer to a receiver substrate, water in the image layer swells the image layer and the hydrophilic tackifier becomes sufficiently tacky to permanently adhere the image to the receiver substrate.
    Type: Grant
    Filed: March 2, 2021
    Date of Patent: February 14, 2023
    Inventors: Ming Xu, Dimple Patel, Alexander Tokarev
  • Patent number: 11401434
    Abstract: A flexible inkjet-printed article is prepared by: A?) providing an ink receptive medium having a substrate and an aqueous-based ink-receptive layer. This layer has: (a) a water-soluble salt of a multivalent metal cation; (b) one or both of a polyvinyl alcohol and a polyvinyl amine (or a copolymer derived from a vinyl alcohol and a vinyl amine) at 0.5-30 weight %; and optionally, (c) a crosslinking agent and (d) silica particles. At least one aqueous pigment-based ink is deposited directly on the aqueous-based ink-receptive layer, each having: a) an anionically-stabilized pigment colorant; and b) a water-miscible humectant at 1-20 weight %, each having a carbon to oxygen atom ratio of ?1.0:1.0 and only two hydroxy groups. After drying, a functional layer with adhesive composition is formed on the inkjet-printed image and a flexible material is laminated to the functional layer, to form a flexible inkjet printed article.
    Type: Grant
    Filed: August 27, 2019
    Date of Patent: August 2, 2022
    Assignee: Eastman kodak company
    Inventors: David D. Putnam, Mark Edward Irving, Douglas Eugene Bugner, Todd Russell Griffin, Barbara Boland Lussier, Allan Francis Sowinski
  • Patent number: 11155076
    Abstract: Inkjet printing is carried out to provide monochrome or polychrome inkjet-printed images. An ink-receptive medium is provided with a substrate with an aqueous-based ink-receptive layer disposed thereon. The aqueous-based ink-receptive layer has: (a) one or more water-soluble salts of a multivalent metal cation in an amount of 0.6-49 weight %; (b) one or both of a polyvinyl alcohol and a polyvinyl amine (or a copolymer of a vinyl alcohol and vinyl amine) in a total amount of 0.5-30 weight %; and optionally, (c) a crosslinking agent and (d) silica particles. One or more aqueous pigment-based inks are inkjet printed onto this aqueous-based ink-receptive layer, each ink comprising: a) one or more anionically-stabilized pigment colorants; b) one or more water-miscible humectants that are present in a total amount of 1-20 weight % and each having a carbon atom to oxygen atom ratio of at least 1.0:1.0 and only two hydroxy groups.
    Type: Grant
    Filed: August 27, 2019
    Date of Patent: October 26, 2021
    Assignee: EASTMAN KODAK COMPANY
    Inventors: Barbara Boland Lussier, Allan Francis Sowinski, Mark Edward Irving, David D. Putnam, Todd Russell Griffin, Douglas Eugene Bugner
  • Patent number: 10450704
    Abstract: A coating composition may include kaolin having a shape factor less than about 70 and calcium carbonate, wherein less than about 90% by weight and greater than about 60% by weight of particles of the calcium carbonate have an equivalent spherical diameter (esd) less than 2 microns. The coating composition may include a thickener present in an amount ranging from about 0.1% to about 0.9% by active dry weight of the composition. A coating composition may include kaolin having a shape factor less than about 70 and calcium carbonate having a mean particle size (d50) of at least about 2.4 microns and a steepness factor of at least about 30. The coating composition may be a paper basecoat composition or a paperboard basecoat composition. A paper or paperboard product may include the coating composition on at least one surface of the paper product or paperboard product.
    Type: Grant
    Filed: October 25, 2016
    Date of Patent: October 22, 2019
    Assignee: Imerys USA, Inc.
    Inventors: Anthony Lyons, Chinmay Peshave
  • Patent number: 9440474
    Abstract: A recording medium includes a substrate, a first ink receiving layer and a second ink receiving layer in that order. The first ink receiving layer contains at least one inorganic pigment selected from the group consisting of alumina, hydrated alumina and fumed silica, polyvinyl alcohol, and a boric acid compound. The second ink receiving layer contains fumed silica, particles having an average particle size in a specific range, polyvinyl alcohol, and a boric acid compound. The boric acid compound content in the first ink receiving layer is in a predetermined range, and the boric acid compound content in the second ink receiving layer is in a predetermined range. The particle content in the second ink receiving layer is in a predetermined range.
    Type: Grant
    Filed: March 31, 2015
    Date of Patent: September 13, 2016
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kazuhiko Araki, Hisao Kamo, Yasuhiro Nito, Tetsuro Noguchi, Ryo Taguri, Isamu Oguri, Olivia Herlambang, Naoya Hatta, Shinya Yumoto
  • Patent number: 9370957
    Abstract: A coated paper having a base paper and at least two coating layers, a first coating layer and a second coating layer, provided on at least one surface of the base paper. The first coating layer is provided on the base paper and contains an organic pigment, a cationic compound, a binder, and a dogtooth-shaped precipitated calcium carbonate having a minor axis of 0.1-0.5 ?m and a major axis of 0.5-2.5 ?m. The second coating layer is provided on the first coating layer and contains at least an inorganic ultrafine particle that is selected from hydrated alumina, gas phase process silica, pulverized wet-process silica, and colloidal silica, and that has a mean particle size of 330 nm or less. The paper has a surface pH of from 5.0 to 7.5, and the coated surface coated with the second coating layer has a 75-degree gloss value of 45% or more.
    Type: Grant
    Filed: August 9, 2013
    Date of Patent: June 21, 2016
    Assignee: MITSUBISHI PAPER MILLS LIMITED
    Inventor: Masanori Nagoshi
  • Publication number: 20150110979
    Abstract: A recording medium includes, in this order, a substrate, a first ink receiving layer containing inorganic particles, polyvinyl alcohol and a boric acid compound, and a resin layer containing a resin. In the first ink receiving layer, hydrated alumina accounts for 70% by mass or more of the inorganic particles. In the recording medium, the ratio of the boric acid compound content to the polyvinyl alcohol content is 30% by mass or more.
    Type: Application
    Filed: October 21, 2014
    Publication date: April 23, 2015
    Inventors: Naoya Hatta, Ryo Taguri, Olivia Herlambang, Hisao Kamo
  • Patent number: 9005725
    Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. Such films do not exhibit excessive ink drying times. These films exhibit high maximum optical densities and have low haze values. These films are useful for medical imaging.
    Type: Grant
    Filed: January 20, 2015
    Date of Patent: April 14, 2015
    Assignee: Carestream Health, Inc.
    Inventors: Sharon M. Simpson, William D. Devine, William J. Ruzinsky
  • Patent number: 8974878
    Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. Such films do not exhibit excessive ink drying times. These films exhibit high maximum optical densities and have low haze values. These films are useful for medical imaging.
    Type: Grant
    Filed: August 9, 2011
    Date of Patent: March 10, 2015
    Assignee: Carestream Health, Inc.
    Inventors: Sharon M. Simpson, William D. Devine, William J. Ruzinsky
  • Patent number: 8974877
    Abstract: The present invention concerns a print medium for inkjet printing and a method of producing such a print medium. In particular, the present invention is directed to a print medium comprising a base layer having a first side and a reverse side, an absorptive layer being in contact with the first side of the base layer, and a topcoat being in contact with the absorptive layer.
    Type: Grant
    Filed: June 30, 2011
    Date of Patent: March 10, 2015
    Assignee: Omya International AG
    Inventors: Patrick A. C. Gane, Vesa Kukkamo, Catherine Jean Ridgway
  • Patent number: 8962111
    Abstract: The present invention provides for a print media comprising an image receiving layer comprising a latex ink film-forming aid. The present invention also provides for a method of forming an image using a latex ink and a print media coated with an image receiving layer comprising a latex ink film-forming aid. The present invention also provides for a printed product comprising a latex ink printed on a print media comprising an image receiving layer comprising a latex ink film-forming aid.
    Type: Grant
    Filed: October 25, 2010
    Date of Patent: February 24, 2015
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Xiaoqi Zhou, Xulong Fu, David Edmondson
  • Publication number: 20150050435
    Abstract: In one example, a print medium includes pigment particles sized less than a hundred nanometers and frictional control additives. An undercoating is disposed between the base material and top coating. The undercoat includes a first sub-layer comprising a pigment fixative agent and a second sub-layer comprising a dye fixative agent The top coating forms a protective and low friction coating over the undercoating.
    Type: Application
    Filed: April 17, 2012
    Publication date: February 19, 2015
    Applicant: HEWLETT-PACKARD DEVELOPMENT COMPANY, L.P.
    Inventors: Lokendra Pal, Xulong Fu, Julio Cesar Alonso
  • Publication number: 20150044396
    Abstract: A recording medium has a base, a first ink receiving layer, and a second ink receiving layer that is the outermost layer in the stated order, in which the first ink receiving layer is a layer adjacent to the second ink receiving layer, the first ink receiving layer contains fumed silica, the second ink receiving layer contains colloidal silica and resin particles, and the area in which the colloidal silica exists in the recording medium surface is 10% or more and 70% or less.
    Type: Application
    Filed: August 4, 2014
    Publication date: February 12, 2015
    Inventors: Tetsuro Noguchi, Hisao Kamo, Isamu Oguri, Shinya Yumoto
  • Patent number: 8945693
    Abstract: Printable articles having a single coating/ink receiving layer are disclosed. In addition, printable articles having a single coating/ink receiving layer disposed on the printable article and a second coating layer disposed on the coating/ink receiving layer are disclosed.
    Type: Grant
    Filed: April 10, 2007
    Date of Patent: February 3, 2015
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Bor-Jiunn Niu, Dheya Alfekri
  • Patent number: 8906477
    Abstract: A recording medium includes a substrate and ink receiving layers including a first ink receiving layer and a second ink receiving layer in that order. The first ink receiving layer contains first inorganic particles including alumina and silica particles, and a first binder. In the first ink receiving layer, the mass ratio of the first binder to the first inorganic particles is from 0.13 to 0.33, and the mass ratio of the alumina particles to the silica particles is from 0.43 to 2.33. The second ink receiving layer contains second inorganic particles and a second binder. The mass ratio of the second binder to the second inorganic particles is from 0.05 to 0.30. The second ink receiving layer has a thickness from 2 ?m to 10 ?m, and the total thickness of ink receiving layers is from 10 ?m to 30 ?m.
    Type: Grant
    Filed: February 14, 2014
    Date of Patent: December 9, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shinya Yumoto, Yasuhiro Nito
  • Patent number: 8900677
    Abstract: A print medium includes a first layer on at least one of a first side and a second side of a substrate and a second layer. The first layer consists essentially of at least 80% by dry weight of one or more particulate inorganic pigments (PIPs). A combination of a particle size and a coat weight of the first layer on the substrate yields an effective pore size of the first layer in a range of about 0.008 to about 0.5 microns. For two or more PIPs in the first layer, the average particle size of one of the PIPs differs by no more than about 50% from the average particle size of another of the PIPs. The second layer is on top of the first layer and includes a particulate inorganic pigment (PIP) having an average particle size of about 0.1 to about 2 microns.
    Type: Grant
    Filed: July 21, 2011
    Date of Patent: December 2, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Jason Swei, Sandeep K Bangaru
  • Patent number: 8883274
    Abstract: An ink jet recording material comprises at least two layers of ink-receptive layers mainly containing inorganic fine particles having an average secondary particle size of 500 nm or less on a resin-coated paper having a resin layer on at least one surface of a base paper, and the ink-receptive layer nearer to the support contains a pearlescent pigment.
    Type: Grant
    Filed: August 11, 2010
    Date of Patent: November 11, 2014
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Masahiro Kawasaki, Toru Kaneko, Satoshi Kaneko, Daichi Miyake
  • Publication number: 20140307025
    Abstract: An inkjet recording material that contains a supporting substrate and an image-receiving layer formed on at least one side of the supporting substrate, said layer including at least one inorganic pigment, and a latex binder having the formula (I). Also disclosed herein are the method of making said inkjet recording material and a method for producing printed images that encompasses using said recording material.
    Type: Application
    Filed: November 18, 2011
    Publication date: October 16, 2014
    Applicant: HEWLETT-PARCKARD DEVELOPMENT COMPANY, L.P.
    Inventors: Steven L. Webb, Christopher Arend Toles
  • Patent number: 8846165
    Abstract: A recording medium includes a substrate and at least one ink-receiving layer, wherein an outermost ink-receiving layer of the recording medium contains inorganic particles, particles other than the inorganic particles, and a binder, the particles other than the inorganic particles have an average primary particle size of 30 nm or more and 100 nm or less, the outermost ink-receiving layer of the recording medium has a thickness of 5 ?m or more, 60% or more and 90% or less of the particles other than the inorganic particles in the outermost ink-receiving layer of the recording medium are present in a region 500 nm or less below the outermost surface of the recording medium, and the area ratio of a region containing the particles other than the inorganic particles to the outermost surface of the recording medium is 30% or more and 80% or less.
    Type: Grant
    Filed: June 25, 2013
    Date of Patent: September 30, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasuhiro Nito, Kazuhiko Araki
  • Patent number: 8846166
    Abstract: The invention provides a recording medium having a substrate, a first ink receiving layer and a second ink receiving layer which is an outermost layer in this order, wherein the first ink receiving layer contains alumina hydrate and polyvinyl alcohol, the second ink receiving layer contains alumina hydrate, polyvinyl alcohol, a cationic polymer particle and a zirconium compound, and the thickness of the second ink receiving layer is 3 ?m or more and 10 ?m or less.
    Type: Grant
    Filed: September 13, 2013
    Date of Patent: September 30, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Olivia Herlambang, Yasuhiro Nito, Hisao Kamo
  • Publication number: 20140285569
    Abstract: An inkjet recording medium includes a substrate having two opposed surfaces, an ink receiving layer disposed on at least one of the two substrate surfaces, and a porous protective layer disposed on the ink receiving layer. The ink receiving layer receives an ink when printed thereon. The protective layer includes: reactive polymer particles that cross-link upon exposure to microwave radiation; non-reactive polymer particles that coalesce upon exposure to microwave radiation; or a combination of the reactive polymer particles and the non-reactive polymer particles, to form a substantially non-porous protective film that covers the printed ink.
    Type: Application
    Filed: October 24, 2011
    Publication date: September 25, 2014
    Inventors: Xiaoqi Zhou, Tao Chen, Eric L. Burch
  • Patent number: 8795798
    Abstract: A method for producing a recording medium, including a step of coating one or more ink receiving layers provided on at least one surface of a substrate with an outermost layer coating liquid to form an outermost layer, where an ink receiving layer of the one or more ink receiving layers, which is nearest to the outermost layer contains alumina hydrate and a binder. The outermost layer coating liquid contains monodispersive and spherical cationic colloidal silica particles having an average particle size of 30 nm or more and 60 nm or less, polyvinyl alcohol having a saponification degree of 75% by mol or more and 85% by mol or less and a viscosity-average polymerization degree of 1,500 or more and 2,200 or less, and cationic polyurethane emulsion particles having an average particle size of 10 nm or more and 100 nm or less.
    Type: Grant
    Filed: November 19, 2010
    Date of Patent: August 5, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Isamu Oguri, Hisao Kamo, Yasuhiro Nito, Tetsuro Noguchi, Ryo Taguri, Olivia Herlambang
  • Patent number: 8784954
    Abstract: A recording medium includes, in sequence, a support; a first ink-receiving layer including an inorganic particle, a water-soluble polymer having a hydroxyl group, a water-soluble polymer not having a hydroxyl group, and a boric acid compound; and a second ink-receiving layer including an inorganic particle, a water-soluble polymer having a hydroxyl group, and a boric acid compound. The second ink-receiving layer does not include the water-soluble polymer not having the hydroxyl group, or the second ink-receiving layer includes the water-soluble polymer not having the hydroxyl group but the content of the water-soluble polymer not having the hydroxyl group relative to that of the inorganic particle in the second ink-receiving layer is smaller than the content of the water-soluble polymer not having the hydroxyl group relative to that of the inorganic particle in the first ink-receiving layer.
    Type: Grant
    Filed: October 10, 2013
    Date of Patent: July 22, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasuhiro Nito, Hisao Kamo, Naoya Hatta
  • Patent number: 8778468
    Abstract: A metalized printable recording medium including a porous metallic reflective top layer, a porous ink-absorbing layer and a bottom supporting substrate. Method to form such printable recording medium and method to form printed images on the metalized printable recording medium are also disclosed.
    Type: Grant
    Filed: October 22, 2010
    Date of Patent: July 15, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Mohammed S. Shaarawi, Vladek Kasperchik, Tienteh Chen
  • Patent number: 8771811
    Abstract: The present invention provides an ink-jet recording material containing: a support; and at least two ink-receiving layers of an ink-receiving underlayer and an ink-receiving top layer, the ink-receiving layers containing a pigment and a binder and being disposed on the support; characterized in that the ink-receiving top layer contains: a finely agglomerated pigment with an average particle diameter of 0.008 to 0.7 ?m, selected from the group consisting of a silica, an alumina, and an alumina hydrate; and a coarse-grained pigment with an average particle diameter of 1 to 30 ?m, the coarse-grained pigment being contained in an amount of 1 to 15 parts by mass with respect to 100 parts by mass of the finely agglomerated pigment.
    Type: Grant
    Filed: May 15, 2012
    Date of Patent: July 8, 2014
    Assignee: Oji Holdings Corporation
    Inventors: Tomomi Takahashi, Ryu Kitamura, Takehiko Kishimoto, Hideo Mitsui, Shigeru Suzuki
  • Patent number: 8765236
    Abstract: A recording medium includes a base, a second ink-receiving layer, and a first ink-receiving layer in this order. The first ink-receiving layer contains gas-phase method silica, a binder, a cationic polymer having a sulfonyl group, and glycol. The second ink-receiving layer contains gas-phase method silica and a binder and (1) does not contain any cationic polymer having a sulfonyl group or (2) contains a cationic polymer having a sulfonyl group in an amount not higher than 0.1 parts by mass based on 100 parts by mass of the gas-phase method silica.
    Type: Grant
    Filed: March 15, 2013
    Date of Patent: July 1, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuro Noguchi, Hisao Kamo, Isamu Oguri, Shinya Yumoto
  • Patent number: 8747968
    Abstract: A recording medium includes, in sequence, a support, a first ink-receiving layer containing a first inorganic particle and a first binder, a second ink-receiving layer containing a second inorganic particle and a second binder, and a third ink-receiving layer which is an outermost surface layer and contains a third inorganic particle, a third binder, and a particle different from the third inorganic particle and having an average secondary particle size of 1.0 to 20.0 ?m. A mass ratio of a content of the first binder to a content of the first inorganic particle is larger than a mass ratio of a content of the second binder to a content of the second inorganic particle. A content of the particle having the specific average secondary particle size is 0.5% by mass or more with respect to a content of the third inorganic particle.
    Type: Grant
    Filed: August 6, 2013
    Date of Patent: June 10, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasuhiro Nito, Hisao Kamo, Tetsuro Noguchi, Ryo Taguri, Isamu Oguri, Olivia Herlambang, Naoya Hatta, Shinya Yumoto, Kazuhiko Araki
  • Patent number: 8741401
    Abstract: A recording medium includes a support; and an ink-receiving layer, the ink-receiving layer having a lower layer and an upper layer, in which the lower layer contains fine inorganic particles, polyvinyl alcohol, and boric acid, the fine inorganic particles including at least one compound selected from alumina, hydrated alumina, and vapor-phase-process silica, in which the upper layer contains fine inorganic particles, polyvinyl alcohol, and boric acid, the fine inorganic particles including at least one compound selected from alumina and hydrated alumina, in which the lower layer has a boric acid content of 2.0% by mass to 7.0% by mass with respect to polyvinyl alcohol, and in which the upper layer has a boric acid content of 10.0% by mass to 30.0% by mass with respect to polyvinyl alcohol.
    Type: Grant
    Filed: February 7, 2012
    Date of Patent: June 3, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuro Noguchi, Hisao Kamo, Yasuhiro Nito, Ryo Taguri, Isamu Oguri, Olivia Herlambang, Naoya Hatta, Shinya Yumoto
  • Patent number: 8709554
    Abstract: Printable articles including a substrate, an image receiving layer over the substrate, and a barrier layer between the substrate and the image receiving layer are useful in the production of fine art reproductions. The image receiving layer comprises at least one pigment and two or more binders, wherein at least one of the two or more binders has a glass transition temperature (Tg) at least 20° C. less than a Tg of at least one other of the two or more binders. Printed articles including a printable article with marking material contained in the image receiving layer may exhibit a textured cracking pattern after application and drying of the marking material or a liquid laminate.
    Type: Grant
    Filed: March 14, 2011
    Date of Patent: April 29, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Dheya M. Alfekri, Ronald J. Selensky
  • Patent number: 8703255
    Abstract: A printed article with optically variable properties that includes a printable media on which a printed feature has been formed with an ink composition. Said ink composition contains metal oxide particles that have an average particle size in the range of about 3 to about 180 nm and that have a refractive index superior or equal to 1.2. The printable media contains a bottom supporting substrate, an ink-absorbing layer and a metallized top layer with pore diameters that are smaller than the size of the metal oxide particles, and the ink composition forms, onto the printable media, a printed feature that exhibits optically variable properties.
    Type: Grant
    Filed: October 22, 2010
    Date of Patent: April 22, 2014
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Vladek Kasperchik, Tienteh Chen, Mohammed S. Shaarawi
  • Publication number: 20140106092
    Abstract: A recording medium includes, in sequence, a support; a first ink-receiving layer including an inorganic particle, a water-soluble polymer having a hydroxyl group, a water-soluble polymer not having a hydroxyl group, and a boric acid compound; and a second ink-receiving layer including an inorganic particle, a water-soluble polymer having a hydroxyl group, and a boric acid compound. The second ink-receiving layer does not include the water-soluble polymer not having the hydroxyl group, or the second ink-receiving layer includes the water-soluble polymer not having the hydroxyl group but the content of the water-soluble polymer not having the hydroxyl group relative to that of the inorganic particle in the second ink-receiving layer is smaller than the content of the water-soluble polymer not having the hydroxyl group relative to that of the inorganic particle in the first ink-receiving layer.
    Type: Application
    Filed: October 10, 2013
    Publication date: April 17, 2014
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Yasuhiro Nito, Hisao Kamo, Naoya Hatta
  • Patent number: 8697204
    Abstract: A method for the preparation of silicium dioxide dispersions is provided, wherein the surface of the silicium dioxide is modified by a treatment with the reaction products, formed in a separate reaction step, of at least one compound of trivalent aluminum or of tetravalent zirconium or a mixture thereof with at least one aminoorganosilane; and the invention also relates to recording sheets for ink jet printing having such a dispersion incorporated in an ink-receiving layer.
    Type: Grant
    Filed: March 2, 2009
    Date of Patent: April 15, 2014
    Assignee: Ilford Imaging Switzerland GmbH
    Inventors: Urs Fürholz, Vincent Ruffieux, Meinrad Schär
  • Publication number: 20140099453
    Abstract: The invention provides a recording medium having a substrate, a first ink receiving layer and a second link receiving layer which is an outermost layer in this order, wherein the first ink receiving layer contains alumina hydrate and polyvinyl alcohol, the second ink receiving layer contains alumina hydrate, polyvinyl alcohol, a cationic polymer particle and a zirconium compound, and the thickness of the second ink receiving layer is 3 ?m or more and 10 ?m or less.
    Type: Application
    Filed: September 13, 2013
    Publication date: April 10, 2014
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Olivia Herlambang, Yasuhiro Nito, Hisao Kamo
  • Patent number: 8679597
    Abstract: A recording medium includes, in sequence, a support, a first ink-receiving layer, and a second ink-receiving layer, in which a content of a boric acid in the first ink-receiving layer is 2.0% by mass or more and 7.0% by mass or less with respect to a content of a polyvinyl alcohol in the first ink-receiving layer, a content of a boric acid in the second ink-receiving layer is 10.0% by mass or more and 30.0% by mass or less with respect to a content of a polyvinyl alcohol in the second ink-receiving layer, an outermost surface layer of the recording medium has a content of particles of 0.5% by mass or more and 5.0% by mass or less, the particles having an average secondary particle size of 1.0 ?m or more and 20.0 ?m or less with respect to a content of an inorganic pigment.
    Type: Grant
    Filed: November 15, 2012
    Date of Patent: March 25, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasuhiro Nito, Hisao Kamo, Tetsuro Noguchi, Ryo Taguri, Isamu Oguri, Olivia Herlambang, Naoya Hatta, Shinya Yumoto, Kazuhiko Araki
  • Publication number: 20140044898
    Abstract: A recording medium includes, in sequence, a support, a first ink-receiving layer containing a first inorganic particle and a first binder, a second ink-receiving layer containing a second inorganic particle and a second binder, and a third ink-receiving layer which is an outermost surface layer and contains a third inorganic particle, a third binder, and a particle different from the third inorganic particle and having an average secondary particle size of 1.0 to 20.0 ?m. A mass ratio of a content of the first binder to a content of the first inorganic particle is larger than a mass ratio of a content of the second binder to a content of the second inorganic particle. A content of the particle having the specific average secondary particle size is 0.5% by mass or more with respect to a content of the third inorganic particle.
    Type: Application
    Filed: August 6, 2013
    Publication date: February 13, 2014
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Yasuhiro Nito, Hisao Kamo, Tetsuro Noguchi, Ryo Taguri, Isamu Oguri, Olivia Herlambang, Naoya Hatta, Shinya Yumoto, Kazuhiko Araki
  • Patent number: 8642143
    Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. Such films exhibit superior resistance to ink-transfer when printed to high optical densities, which is desirable for medical imaging applications.
    Type: Grant
    Filed: August 3, 2012
    Date of Patent: February 4, 2014
    Assignee: Carestream Health, Inc.
    Inventors: Sharon M. Simpson, Heidy M. Vosberg, Daniel P. Leach, William J. Ruzinsky, William D. Devine
  • Patent number: 8628832
    Abstract: A recording medium includes a base and at least one ink-receiving layer. A first ink-receiving layer that is at least one ink-receiving layer contains inorganic particles having an average primary particle size of 1 ?m or less and inorganic particles coated with a metal oxide. The inorganic particles coated with the metal oxide have an average primary particle size of 15.0 ?m or more. When the maximum of a FLOP value of the recording medium is denoted by FLOPMax and the minimum of the FLOP value is denoted by FLOPMin, the FLOPMin is 2.5 or more and a value of FLOPMin/FLOPMax is 0.80 or more and 1.00 or less.
    Type: Grant
    Filed: January 28, 2013
    Date of Patent: January 14, 2014
    Assignee: Canon Kabushiki Kaisha
    Inventors: Ryo Taguri, Hisao Kamo, Tetsuro Noguchi, Yasuhiro Nito, Isamu Oguri, Naoya Hatta, Kazuhiko Araki, Shinya Yumoto
  • Publication number: 20140004282
    Abstract: A recording medium includes a substrate and at least one ink-receiving layer, wherein an outermost ink-receiving layer of the recording medium contains inorganic particles, particles other than the inorganic particles, and a binder, the particles other than the inorganic particles have an average primary particle size of 30 nm or more and 100 nm or less, the outermost ink-receiving layer of the recording medium has a thickness of 5 ?m or more, 60% or more and 90% or less of the particles other than the inorganic particles in the outermost ink-receiving layer of the recording medium are present in a region 500 nm or less below the outermost surface of the recording medium, and the area ratio of a region containing the particles other than the inorganic particles to the outermost surface of the recording medium is 30% or more and 80% or less.
    Type: Application
    Filed: June 25, 2013
    Publication date: January 2, 2014
    Inventors: Yasuhiro Nito, Kazuhiko Araki
  • Patent number: 8609209
    Abstract: An ink jet recording medium including a substrate and an ink receiving layer provided on the substrate and composed of two or more layers of at least an upper layer and a lower layer. The ink receiving layer contains polyvinyl alcohol in an amount of 12.7% by mass or more based on the total mass of the ink receiving layer. The upper layer is a layer most distant from the substrate, contains a pigment and polyvinyl alcohol, the pigment containing 90% by mass or more of alumina hydrate, and has a thickness of 3.0-10.0 ?m. The lower layer is positioned just under the upper layer, contains a pigment and polyvinyl alcohol, the pigment containing 20% by mass or more of silica, and has a thickness 2.5-10 times larger than that of the upper layer and an average pore radius 0.90-1.30 times larger than that of the upper layer.
    Type: Grant
    Filed: September 30, 2011
    Date of Patent: December 17, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Ryo Taguri, Hisao Kamo, Yasuhiro Nito, Tetsuro Noguchi, Isamu Oguri, Olivia Herlambang, Naoya Hatta
  • Patent number: 8609210
    Abstract: The object of the present invention is to provide a coated printing paper used for ink jet printing machines, which has an ink fixing property and ink absorption property corresponding to ink jet printing, which inhibits poor dot diffusion, and which is excellent in abrasion resistance property of printed portions. According to the present invention, provided is a coated printing paper comprising a base paper, an undercoating layer which is applied on at least one surface of the base paper and contains a pigment and a binder, and one or more coating layers on the undercoating layer, wherein the base paper contains at least one selected from a cationic resin and a multivalent cation salt; the uppermost coating layer contains at least a colloidal silica; and the 75° gloss according to JIS Z8741 of the surface of the uppermost coating layer is 40% or more.
    Type: Grant
    Filed: July 13, 2010
    Date of Patent: December 17, 2013
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Masanori Nagoshi, Koji Idei, Hiroshi Matsuda, Kazutoshi Iida, Jun Urasaki
  • Patent number: 8592011
    Abstract: In an ink jet recording medium having at least two ink receiving layers, the total content of boric acid, a borate, and a water-soluble zirconium salt of a lower ink receiving layer located close to a support substrate to the total content of alumina and an alumina hydrate thereof is higher than the total content of boric acid, a borate, and a water-soluble zirconium salt of an upper ink receiving layer located apart from the support substrate to the total content of alumina and an alumina hydrate thereof.
    Type: Grant
    Filed: April 18, 2011
    Date of Patent: November 26, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuro Noguchi, Hisao Kamo, Yasuhiro Nito, Isamu Oguri, Ryo Taguri, Olivia Herlambang, Naoya Hatta
  • Patent number: 8592012
    Abstract: A recording medium includes, in sequence, a support, a first ink-receiving layer, and a second ink-receiving layer, in which the first ink-receiving layer contains at least one selected from an alumina, an alumina hydrate, and a fumed silica, a polyvinyl alcohol, and a boric acid, in which a mass ratio of a content of the boric acid in the first ink-receiving layer to a content of the polyvinyl alcohol in the first ink-receiving layer is 2.0% by mass or more and 7.0% by mass or less, in which the second ink-receiving layer contains a fumed silica, a polyvinyl alcohol, and a boric acid, and in which a mass ratio of a content of the boric acid in the second ink-receiving layer to a content of the polyvinyl alcohol in the second ink-receiving layer is 10.0% by mass or more and 30.0% by mass or less.
    Type: Grant
    Filed: October 25, 2012
    Date of Patent: November 26, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuro Noguchi, Hisao Kamo, Yasuhiro Nito, Ryo Taguri, Isamu Oguri, Olivia Herlambang, Naoya Hatta, Shinya Yumoto
  • Patent number: 8586157
    Abstract: Printable substrates including a base sheet, a tie coating on a first surface of the base sheet, and a printable coating on the tie coating are generally provided. The tie coating can generally include a first crosslinked material formed from a film-forming binder, a first crosslinkable polymeric binder, a first crosslinking agent, and a first crosslinking catalyst. The printable coating can generally include a plurality of inorganic microparticies and a second crosslinked material formed from a second crosslinkable polymeric binder, a second crosslinking agent, and a second crosslinking catalyst. Methods of forming an image on such printable substrates are also generally provided, along with methods for forming such printable substrates.
    Type: Grant
    Filed: November 7, 2011
    Date of Patent: November 19, 2013
    Assignee: Neenah Paper, Inc.
    Inventor: Russell Dolsey
  • Patent number: 8557354
    Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. Such films exhibit improved ink-drying and smudging performance. These films exhibit high maximum optical densities and have low haze values. These films are useful for medical imaging.
    Type: Grant
    Filed: August 12, 2011
    Date of Patent: October 15, 2013
    Inventors: Sharon M. Simpson, John D. Szafraniec, James B. Philip, Jr.
  • Publication number: 20130266747
    Abstract: A recording medium includes a base, a second ink-receiving layer, and a first ink-receiving layer in this order. The first ink-receiving layer contains gas-phase method silica, a binder, a cationic polymer having a sulfonyl group, and glycol. The second ink-receiving layer contains gas-phase method silica and a binder and (1) does not contain any cationic polymer having a sulfonyl group or (2) contains a cationic polymer having a sulfonyl group in an amount not higher than 0.1 parts by mass based on 100 parts by mass of the gas-phase method silica.
    Type: Application
    Filed: March 15, 2013
    Publication date: October 10, 2013
    Applicant: CANON KABUSHIKI KAISHA
    Inventors: Tetsuro Noguchi, Hisao Kamo, Isamu Oguri, Shinya Yumoto
  • Patent number: 8545948
    Abstract: Transparent ink-jet recording films, compositions, and methods are disclosed. Such films do not exhibit excessive ink drying times. These films exhibit high maximum optical densities and have low haze values. These films are useful for medical imaging.
    Type: Grant
    Filed: March 20, 2013
    Date of Patent: October 1, 2013
    Assignee: Carestream Health, Inc.
    Inventors: Sharon M. Simpson, William D. Devine, III, William J. Ruzinsky
  • Patent number: 8524336
    Abstract: The invention provides a recording medium having excellent ink absorbency and capable of forming a sharp image thereon. The recording medium has a substrate, and a first layer and an outermost layer provided on the substrate in this order, wherein the first layer contains at least one of alumina and alumina hydrate, the outermost layer contains a pigment and is lower in refractive index than the first layer, and the absolute dry coating amount of the outermost layer is 0.1 g/m2 or more and 0.5 g/m2 or less.
    Type: Grant
    Filed: April 20, 2011
    Date of Patent: September 3, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventors: Isamu Oguri, Hisao Kamo, Yasuhiro Nito, Tetsuro Noguchi, Ryo Taguri, Olivia Herlambang, Naoya Hatta
  • Publication number: 20130216738
    Abstract: The present invention is directed to a printed substrate including a multilayer film having the following layered configuration: a print layer having a thickness of at least about 0.6 mils, which is receptive to eco-solvent inks, mild-solvent inks, latex inks, UV inks, or combinations thereof, and where the print layer includes one or more of eco-solvent inks, mild-solvent inks, latex inks, UV inks, or combinations thereof; a tie layer; a core layer; and an adhesive layer.
    Type: Application
    Filed: February 20, 2013
    Publication date: August 22, 2013
    Applicant: Avery Dennison Corporation
    Inventor: Avery Dennison Corporation
  • Patent number: 8512826
    Abstract: A recording sheet for ink-jet printing includes a supporting substrate, at least one microporous ink-receptive coating overlying a front surface of said supporting substrate and at least one protective overcoating overlying said microporous coating. The protective overcoating includes at least one compound selected from the group consisting of polysaccharides and polyacrylamides, and fluoropolymer particles. The diameter of the fluoropolymer particles is between about 0.5 and 3 micrometers.
    Type: Grant
    Filed: May 4, 2011
    Date of Patent: August 20, 2013
    Assignee: Oce-Technologies B.V.
    Inventors: Rudolf A. H. M. Sturme, Dorothea M. H. Wijnhoven, Kolja Adamczyk, James A. Foley, Khizyr Kharunovich Khoultchaev