Property Of Particle Specified (e.g., Oil Absorbtivity, Surface Area, Pore Size, Etc.) Patents (Class 428/32.37)
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Patent number: 6830790Abstract: A recording medium comprising on a base material an ink-receiving layer containing an alumina hydrate, said ink-receiving layer being formed by applying a coating liquid containing said alumina hydrate to said base material followed by drying to form a layer to be said ink-receiving layer, swelling said layer to be said ink-receiving layer again, and pressing the swollen layer to a heated mirror-finish drum for drying, the glossiness of the surface of the recording medium on the side of the ink-receiving layer as measured at 20° being 20% or more.Type: GrantFiled: August 30, 2000Date of Patent: December 14, 2004Assignee: Canon Kabushiki KaishaInventors: Katsutoshi Misuda, Kenji Onuma, Nobuyuki Hosoi, Kenji Shinjo, Masanobu Asaoka, Ako Takemura
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Patent number: 6824844Abstract: An ink jet recording medium, capable of recording thereon ink images having excellent clarity and sharpness without blotting of ink images, includes an ink receiving layer formed on a support material and containing xerogel porous pigment particle, and has a such a specific feature that when a plurality of ink dots are formed each by successively jetting three coloring ink droplets different in color from each other and equal in droplet volume to each other toward a point of the ink receiving layer, to successively superpose the jetted three coloring ink droplets and to form a mixed colored dot in the point, the average size of the resultant dots is 125% or less based on an average dot size of ink dots each formed from two different coloring ink droplets.Type: GrantFiled: March 1, 2000Date of Patent: November 30, 2004Assignee: OJI Paper Co. Ltd.Inventors: Hiromasa Kondo, Masaki Nishimura, Takaaki Koro
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Patent number: 6815019Abstract: An ink jet recording element having a support having thereon an image-receiving layer of porous polymeric particles in a polymeric binder, said polymeric binder being poly(vinyl alcohol) having a degree of hydrolysis of at least about 95% and having a number average molecular weight of at least about 45,000.Type: GrantFiled: December 4, 2001Date of Patent: November 9, 2004Assignee: Eastman Kodak CompanyInventors: Gregory E. Missell, Paul B. Merkel
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Patent number: 6808769Abstract: The present invention provides an aqueous dispersion containing at least two powder types selected from one or more metal oxide powders and/or one or more non-metal oxide powder. The present invention also provides a coating composition containing this dispersion, an inkjet recording medium containing the coating composition, and methods of making the same.Type: GrantFiled: March 24, 2003Date of Patent: October 26, 2004Assignee: Degussa AGInventors: Christoph Batz-Sohn, Thomas Scharfe, Wolfgang Lortz
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Patent number: 6808768Abstract: The present invention provides an amorphous porous inorganic substance having small particle sizes and uniform pores, a process for synthesizing the same, and use of the same. The invention provides an amorphous porous inorganic substance having pores of a uniform pore diameter, which has an average particle size DL of 10 to 400 nm as measured by a dynamic light scattering method and a specific surface area difference, SB−SL, between a conversion specific surface area SL calculated from DL and a nitrogen adsorption specific surface area SB obtained by the BET method, of 250 m2/g or more. A process for synthesizing the same and use of the same are also disclosed.Type: GrantFiled: December 26, 2002Date of Patent: October 26, 2004Assignee: Asani Kasei Kabushiki KaishaInventors: Seiji Satou, Yasuhide Isobe, Kenzou Onizuka
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Patent number: 6779885Abstract: An ink jet printing method having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with an ink jet recording element having a support having thereon an image-receiving layer of porous polymeric particles in a polymeric binder, the porous polymeric particles being prepared in the presence of an anionic or ationic dispersant, and the image-receiving layer containing a surfactant having a charge opposite to that of the dispersant used to make the porous polymeric particles, the surfactant being present in an amount from about 0.04 parts to about 0.30 parts by weight of the dispersant; C) loading the printer with an ink jet ink composition; and D) printing on the ink jet recording element using the ink jet ink composition in response to the digital data signals.Type: GrantFiled: December 4, 2001Date of Patent: August 24, 2004Assignee: Eastman Kodak CompanyInventors: Gregory E. Missell, Jeanne E. Kaeding, Dennis E. Smith, Paul B. Merkel
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Patent number: 6773770Abstract: An ink jet recording material appropriate to ink recording, preferably pigment ink recording, has an ink receiving layer formed on a support and including a pigment containing amorphous silica, alumina and/or alumino silicate, a binder, and a cationic resin having a cation equivalent of 1.5 to 6 milli equivalent/g, as determined by a colloid titration method.Type: GrantFiled: June 29, 1999Date of Patent: August 10, 2004Assignee: OJI Paper Co., Ltd.Inventors: Naonobu Sugiyama, Kazuo Totani, Hiromasa Kondo
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Patent number: 6753051Abstract: The present invention comprises an ink recording element comprising a support having thereon at least one ink receiving layer, the layer comprising wrinkled particles. The present invention also includes a method of forming a print comprising providing an ink recording element comprising at least one ink receiving layer capable of accepting an ink image, the layer comprising wrinkled particles and printing on the ink recording element utilizing a printer.Type: GrantFiled: July 30, 2002Date of Patent: June 22, 2004Assignee: Eastman Kodak CompanyInventors: Christine J. Landry-Coltrain, Jeffrey W. Leon
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Patent number: 6730375Abstract: An ink-jet recording medium having, on a base material, a porous resin layer containing water-dispersible resin particles B having a minimum film-forming temperature of not lower than 0° C., and water-dispersible resin particles A having a minimum film-forming temperature higher than the film-forming temperature of the water-dispersible resin particles B and having an average particle size larger than the average particle size of the water-dispersible resin particles B.Type: GrantFiled: December 21, 2001Date of Patent: May 4, 2004Assignee: Canon Kabushiki KaishaInventors: Kenichi Moriya, Kenji Shinjo
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Patent number: 6716493Abstract: A transfer sheet for an ink jet printer comprises a support, and a transfer layer which is capable of separating from the support and contains a hot-melt adhesive particle, and the hot-melt adhesive particle comprises a first porous hot-melt adhesive fine particle having an oil absorption of not less than 50 ml/100 g. The transfer layer may further comprise a second hot-melt adhesive fine particle having an oil absorption of less than 50 ml/100 g, a film-forming resin component, and a dye fixing agent. The hot-melt adhesive fine particle may comprise a nylon fine particle, and the average particle size thereof may be 1 to 100 mm.Type: GrantFiled: August 7, 2001Date of Patent: April 6, 2004Assignee: Daicel Chemical Industries, Ltd.Inventors: Kazuo Notsu, Kenji Nakama, Hideki Nakanishi
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Patent number: 6696118Abstract: An ink-jet recording medium comprising a base material and an ink-receiving layer provided thereon. The ink-receiving layer comprises an upper layer containing an aluminum-based pigment and a lower layer containing an aluminum-based pigment having a BET specific surface area larger than that of the aluminum-based pigment contained in the upper layer.Type: GrantFiled: September 24, 2001Date of Patent: February 24, 2004Assignee: Canon Kabushiki KaishaInventors: Masanobu Asaoka, Kenji Onuma, Katsutoshi Misuda
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Patent number: 6689432Abstract: An ink jet recording material having excellent smoothness and gloss and capable of recording thereon ink images having high color density clarity, water resistance and sharpness comparative to the silver salt photographic images has a recording stratum formed on a substrate and comprising a single ink receiving layer or a plurality of ink receiving layers superposed on each other and containing a pigment and a binder, at least one ink receiving layer containing fine particles of at least one pigment selected from silica, aluminosilicate, and &agr;-, &thgr;-, &dgr;- and &ggr;-aluminas and having an average particle size of 1 &mgr;m or less and optionally a light resistance-enhancing agent for images including at least one of phenolic compounds, boric acid, borate salts and cyclodextrin compounds.Type: GrantFiled: January 26, 2001Date of Patent: February 10, 2004Assignee: Oji Paper Co., Ltd.Inventors: Ryu Kitamura, Tomomi Takahashi, Eriko Endo, Kazuaki Ohshima, Shunichiro Mukoyoshi, Tetsuo Tsuchida
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Patent number: 6689430Abstract: An ink jet recording element comprising a support having thereon an image-receiving layer having: (a) inorganic particles having a primary particle size of from about 7 to about 40 nm in diameter which may be aggregated up to about 500 nm; (b) colloidal particles having a mean particle size of from about 20 to about 500 nm; and (c) water-insoluble, cationic, polymeric particles having at least about 20 mole percent of a cationic mordant moiety.Type: GrantFiled: August 31, 2001Date of Patent: February 10, 2004Assignee: Eastman Kodak CompanyInventors: Sridhar Sadasivan, Lixin Chu, John M. Baier, Yongcai Wang, Lori J. Shaw-Klein, Elizabeth A. Gallo
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Patent number: 6689431Abstract: An ink jet recording element comprising a substrate having thereon a porous image-receiving layer having a) organic particles encapsulated with an organic polymer having a Tg of less than about 100° C.; and b) water-insoluble, cationic, polymeric particles.Type: GrantFiled: December 12, 2001Date of Patent: February 10, 2004Assignee: Eastman Kodak CompanyInventors: Sridhar Sadasivan, Elizabeth A. Gallo, Xiaoru Wang
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Patent number: 6686001Abstract: An ink jet printing method having the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with ink jet recording element having a substrate having thereon a porous image-receiving layer of a) organic particles encapsulated with an organic polymer having a Tg of less than about 100 ° C.; and b) water-insoluble, cationic, polymeric particles; C) loading the printer with an ink jet ink composition; and D) printing on the image-receiving layer using the inkjet ink composition in response to the digital data signals.Type: GrantFiled: December 12, 2001Date of Patent: February 3, 2004Assignee: Eastman Kodak CompanyInventors: Elizabeth A. Gallo, Sridhar Sadasivan, Xiaoru Wang
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Patent number: 6685999Abstract: A recording medium for ink jet printing comprises a base material layer such as paper or plastic sheet, a porous lower layer formed on the base material layer, and a porous upper layer formed on the porous lower layer. The porous lower layer contains hydrated alumina showing a boehmite structure. The porous upper layer mainly comprises agglomerates of spherical silica particles with particle diameters ranging between 1 and 100 nm and a binder and contains voids mainly found between the agglomerates, not within the agglomerates. Preferably, a second type of spherical silica particles having smaller particle diameters than the above first type of spherical silica particles are also contained in the porous upper layer, and in this case, the first type particles have particle diameters ranging between 10 and 100 nm and are mostly found outside the agglomerates, while the second type particles have particle diameters ranging between 1 and 10 nm and are mostly found within the agglomerates.Type: GrantFiled: December 28, 1999Date of Patent: February 3, 2004Assignee: Canon Kabushiki KaishaInventors: Hirofumi Ichinose, Tsuyoshi Santo, Hiroshi Tomioka
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Patent number: 6677006Abstract: An ink-jet recording material having on a support at least an ink-receiving layer, with the ink-receiving layer being comprised of a light resistance-imparting layer as a lower layer and a coloration layer as an upper layer. Herein, the light resistance-imparting layer comprises a light-resistance imparting chemical constituted of 1 to 10 parts by weight of a benzotriazole compound as ultraviolet absorbent, 1 to 8 parts by weight of magnesium sulfate and 1 to 10 parts by weight of zinc oxide in combination with 100 parts by weight of an ink absorbing pigment, and besides, the coloration layer contains no light resistance-imparting chemicals.Type: GrantFiled: July 19, 2001Date of Patent: January 13, 2004Assignees: Nippon Paper Industries Co., Ltd., Seiko Epson CororatonInventors: Teiichi Otani, Atsushi Ono, Noboru Kondo, Hiroyuki Onishi, Shinya Yamagata, Masaya Shibatani, Jun Sugiyama
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Patent number: 6677008Abstract: An ink jet recording element having a substrate having thereon an image-receiving layer of a filler and coated particles of a polymeric hard core-polymeric soft shell, the Tg of the polymeric hard core material being greater than about 60° C., the Tg of the polymeric soft shell material being less than about 100° C., and the filler being present in the image-receiving layer in an amount of from about 50 to about 95% by weight, the substrate being paper, resin-coated paper, synthetic paper, impregnated paper, cellulose acetate or a polyester film.Type: GrantFiled: March 25, 2002Date of Patent: January 13, 2004Assignee: Eastman Kodak CompanyInventors: Tienteh Chen, Lixin Chu, Sridhar Sadasivan, Elizabeth A. Gallo, Xiaoru Wang
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Patent number: 6677005Abstract: There is disclosed an ink-jet recording material which comprises a support and a layer containing at least one of a polymer latex and a resin emulsion in combination with solid fine particles, and at least one layer containing fumed silica formed on the above-mentioned layer.Type: GrantFiled: December 19, 2000Date of Patent: January 13, 2004Assignee: Mitsubishi Paper Mills LimitedInventors: Satoshi Kaneko, Norimasa Miyachi
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Patent number: 6660348Abstract: An ink jet coating composition comprising a blend of silicas, a blend of super and/or fully and partially hydrolyzed polyvinyl alcohols, and a cationic resin is provided, where ink jet recording materials prepared from such compositions demonstrate a balance of properties including improved imaging performance and good water resistance.Type: GrantFiled: September 30, 2002Date of Patent: December 9, 2003Assignee: Kanzaki Specialty Papers, Inc.Inventors: Simon R. Cuch, George R. Stevens, Jr., Brian R. Waite
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Patent number: 6652931Abstract: A recording material for ink-jet recording, having on a support a light resistance-imparting layer containing a light resistance-imparting chemical and an image-forming layer free of a light resistance-imparting chemical, which are provided in the order described.Type: GrantFiled: March 30, 2001Date of Patent: November 25, 2003Assignee: Nippon Paper Industries Co., Ltd.Inventors: Teiichi Otani, Atsushi Ono, Noboru Kondo
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Patent number: 6649234Abstract: Provided is a fine powder material for forming an ink-receiving layer on a recording medium, wherein a pore radius maximum exists within a range of from 90 to 120 Å in a pore radius distribution of said fine powder material and wherein a total volume of pores having radii not exceeding 50 Å is not more than 6.0% of a volume of all pores.Type: GrantFiled: February 3, 1999Date of Patent: November 18, 2003Assignee: Canon Kabushiki KaishaInventors: Masanobu Asaoka, Akemi Ishizaki, Nobuyuki Hosoi, Katsutoshi Misuda
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Patent number: 6645582Abstract: A porous ink jet recording element having a support having thereon an image-receiving layer having: (a) inorganic particles having a primary particle size of from about 7 to about 40 nm in diameter which may be aggregated up to about 500 nm; (b) colloidal particles having a mean particle size of from about 20 to about 500 nm; (c) water-insoluble, cationic, polymeric particles having at least about 20 mole percent of a cationic mordant moiety; and (d) inorganic particles encapsulated with an organic polymer having a Tg of less than about 100° C.Type: GrantFiled: August 31, 2001Date of Patent: November 11, 2003Assignee: Eastman Kodak CompanyInventors: Sridhar Sadasivan, Elizabeth A. Gallo, Lixin Chu, John M. Baier, David E. Decker, Xiaoru E. Wang
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Publication number: 20030198761Abstract: An ink recording element is described comprising a support having thereon at least one image-receiving layer comprising polymeric particles in a polymeric binder, wherein said polymeric particle is stabilized by a hydrophobically-capped oligomeric acrylamide dispersant.Type: ApplicationFiled: April 9, 2002Publication date: October 23, 2003Applicant: Eastman Kodak CompanyInventors: Jeanne E. Kaeding, Jeffrey W. Leon, Christine J. Landry-Coltrain, Alan R. Pitt, Trevor J. Wear, Gregory E. Missell, Dennis E. Smith
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Patent number: 6635319Abstract: An ink jet recording element comprising a substrate having thereon an image-receiving layer comprising an inorganic, anionic pigment, an organic, anionic binder, an organic, cationic mordant and thermoplastic polymer particles.Type: GrantFiled: December 1, 1999Date of Patent: October 21, 2003Assignee: Eastman Kodak CompanyInventors: Suresh Sunderrajan, Sridhar Sadasivan, Michelle M. Oakland, Patrick J. Whittaker, John W. Janssen, Craig T. Mollon
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Patent number: 6632488Abstract: An ink jet recording material which includes a paper sheet substrate and an ink receiving layer containing a xerogel porous pigment and has excellent ink-absorption and reproducibility of ink images with high clarity and precision, exhibits a water-dipping expansion of 0.3% or less, determined by the same method as the JAPAN TAPPI No. 27-B method except that the length of the recording material immersed in water is measured 15 seconds after the start of the immersion.Type: GrantFiled: February 22, 1999Date of Patent: October 14, 2003Assignee: OJI Paper Co., LTDInventors: Yoshitaka Okumura, Takaaki Kohro, Yoshiharu Kawashima, Hiromasa Kondo
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Publication number: 20030180483Abstract: A coating composition comprising a relatively low alkali-containing colloidal silica and glossy ink jet recording sheets prepared from such coatings is described. The coating comprises binder and colloidal silica, e.g., having an average particle size in the range of about 1 to about 300 nanometers. The low alkali colloidal silica of this invention comprises ammonia, polydispersed colloidal silica, or both. Polydispersed silicas having a particle size distribution such that the median particle size is in the range of 15 to 100 nanometers and 80% of the particles span a range of at least about 30 to about 70 nanometers are preferred. It has been discovered that coatings prepared from such colloidal silica and applied to conventional ink jet recording sheet supports have a specular gloss of at least 30 at 60° C., and excellent printability at silica solids to binder solids ratio of 1:1 or greater.Type: ApplicationFiled: March 18, 2003Publication date: September 25, 2003Inventors: Daniel Ray Fruge, Demetrius Michos
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Patent number: 6623820Abstract: It is an object of the present invention to obtain a composite sol capable of forming an ink-receiving layer having a high transparency and a high property for fixing dyes. The present invention provides a sol which is a colloidal solution having aggregate particles containing silica and alumina dispersed in an aqueous medium, wherein the silica is such that the primary particles are spherical and the average particle size of the primary particles is from 2 to 200 nm, the average particle size of the aggregate particles is at least twice the average particle size of the silica primary particles and at most 1,000 nm, the &zgr;-potential of the aggregate particles is at least +10 mV, and the pH of the solution is from 3 to 9.Type: GrantFiled: February 11, 2000Date of Patent: September 23, 2003Assignee: Asahi Glass Company Ltd.Inventors: Katsumasa Nakahara, Noriko Torimoto, Hachiro Hirano, Toshiya Matsubara, Shinichi Suzuki, Hisao Inokuma, Hirokazu Wakabayashi
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Publication number: 20030157278Abstract: A recording material for back-printing contains (i) a back-printing sheet comprising a transparent substrate, an ink-absorbing layer that is provided on the transparent substrate, and a porous ink-receiving layer that is provided on the ink-absorbing layer and has filler dispersed in a binder resin, and (ii) a back-printing sheet cover film having a cover substrate, and an adhesive layer that has an adhesive resin and is formed on the cover substrate, the refractive index of the filler and the refractive index of the adhesive resin are different to one another. Specifically, the difference between the refractive index of the filler and the refractive index of the adhesive resin is at least 1.0.Type: ApplicationFiled: January 16, 2003Publication date: August 21, 2003Applicant: SONY CHEMICALS CORP.Inventors: Hideaki Takahashi, Jun Takahashi, Akio Ito, Yukiko Murasawa
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Ink jet recording sheet, method for the preparation of same, and ink jet recording method using same
Publication number: 20030152720Abstract: An ink jet recording sheet includes a substrate, an ink receiving layer, and a clay-containing layer between the paper substrate and the ink receiving layer. The clay-containing layer contains platelet clay particles having an average aspect ratio of at least 10:1, and an orientation such that at least 50% of the platelet clay particles have a major axis within 30° of parallel to the substrate. The sheet exhibits little or no cockle formation, even at high ink laydowns. A method of preparing the ink jet recording sheet and a method of printing using the ink jet recording sheet are also described.Type: ApplicationFiled: August 30, 2002Publication date: August 14, 2003Inventor: Michael Lubar -
Publication number: 20030124045Abstract: A fumed-silica, which can make a slurry having sufficient wettability to a polar liquid, excellent dispersibility, and low viscosity even in the high concentration, and a slurry thereof. A fumed-silica and its slurry are provided, wherein the water content is controlled so that a weight loss after drying Y, and a dynamic wetting rate to water Z, have specified values.Type: ApplicationFiled: December 23, 2002Publication date: July 3, 2003Applicant: NIPPON AEROSIL CO., LTD.Inventors: Hitoshi Kobayashi, Masamichi Murota, Hirokuni Shirono