Multiple Polymers In Ink-receptive Layer Patents (Class 428/32.38)
  • Publication number: 20110189409
    Abstract: Disclosed is an inkjet recording material comprising at least a base layer and an ink receiving layer. The ink receiving layer is composed of a mixture of a hydrophilic component containing a hydrophilic resin and a hydrophobic resin having hot-melt property. And the mass ratio between said hydrophilic component and said hydrophobic resin having hot-melt adhesive property in the mixture is from 60:40 to 20:80 (the hydrophilic component:hydrophobic resin). The inkjet recording material is excellent in moisture resistance, while exhibiting high ink absorption capacity.
    Type: Application
    Filed: April 12, 2011
    Publication date: August 4, 2011
    Applicant: MITSUBISHI PLASTICS, INC.
    Inventor: Shigeki NISHIMURA
  • Patent number: 7985483
    Abstract: A method of coating low density polyethylene (LDPE) and linear low density polyethylene (LLDPE), or combinations of the two, is disclosed. The method includes treating the polyethylene with a coating and then digitally printing the coated polyethylene substrate. The coated substrate may then be over-coated to protect the printing and the substrate may be formed as desired. The coated substrate may also be coated with a clear thin protective coating and heat-sealed on three sides to form a small tote bag.
    Type: Grant
    Filed: November 16, 2006
    Date of Patent: July 26, 2011
    Assignee: SmartHealth, Inc.
    Inventor: Karl-Michael Klenk
  • Patent number: 7951435
    Abstract: Disclosed is an inkjet recording material comprising at least a base layer and an ink receiving layer. The ink receiving layer is composed of a mixture of a hydrophilic component containing a hydrophilic resin and a hydrophobic resin having hot-melt property. And the mass ratio between said hydrophilic component and said hydrophobic resin having hot-melt adhesive property in the mixture is from 60:40 to 20:80 (the hydrophilic component:hydrophobic resin). The inkjet recording material is excellent in moisture resistance, while exhibiting high ink absorption capacity.
    Type: Grant
    Filed: August 18, 2005
    Date of Patent: May 31, 2011
    Assignee: Mitsubishi Plastics, Inc.
    Inventor: Shigeki Nishimura
  • Patent number: 7943214
    Abstract: An ink-jet transfer system is disclosed, as well as a transfer printed product which is highly wash-resistant, color-fast and environment-friendly, and a process for producing the same and its use in a printing process by means of the disclosed ink-jet transfer system. The disclosed ink-jet transfer system has a substrate, a hot-melt layer applied on the substrate and at least one ink-absorbing layer which comprises a mixture of a highly porous pigment and a binder. The molecules of the pigment and if required of the binder and hot-melt layer can form chemical bonds with the dyeing molecules of the ink.
    Type: Grant
    Filed: June 1, 1999
    Date of Patent: May 17, 2011
    Assignee: Arkwright Advanced Coating, Inc.
    Inventors: Ulf Bamberg, Peter Kummer, Ilona Stiburek
  • Patent number: 7927675
    Abstract: A recording sheet for ink jet printing is provided, which consists of a support having coated thereon at least one ink-receiving layer consisting of binders and at least one nanoporous inorganic compound, wherein the recording sheet contains a polynuclear aluminum hydroxo complex with 30 aluminum atoms. In a preferred embodiment, the surface of the nanoporous inorganic compound is modified by a treatment with the aluminum hydroxo complex with 30 aluminum atoms.
    Type: Grant
    Filed: August 19, 2008
    Date of Patent: April 19, 2011
    Assignee: Ilford Imaging Switzerland GmbH
    Inventors: Robert Beer, Rolf Steiger, Vincent Ruffieux, Dipanjan Banerjee, Gerhard Furrer, Daniel Rentsch, Björn Studer
  • Patent number: 7919156
    Abstract: Disclosed is a material set for recording, including: an ink including a recording material, an organic solvent, and water; and ink receiving particles including an organic resin including hydrophilic monomer components and one or more hydrophobic monomer components, the hydrophilic monomer components including a monomer component having a hydroxyl group and a monomer component having a dissociable group, an absolute value of a difference between a solubility parameter (SP value) of the organic solvent included in the ink and a solubility parameter (SP value) of monomer components included in the organic resin, other than the monomer component having a dissociable group, being less than 5.
    Type: Grant
    Filed: November 21, 2008
    Date of Patent: April 5, 2011
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Takatsugu Doi, Ken Hashimoto
  • Patent number: 7901749
    Abstract: The invention relates to the discovery that pre-treating mineral oxide particles with a silylated polymeric coupling agent prior to suspending the particles in a binder polymer increases the crack resistance and adhesion of particles to a inkjet printing substrate such as paper sheets. Such pretreatment also reduces the amount of binder needed to achieve acceptable performance, leading to improvements in production speed and image quality.
    Type: Grant
    Filed: March 18, 2005
    Date of Patent: March 8, 2011
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Tienteh Chen
  • Patent number: 7868064
    Abstract: Ink receptive particles for receiving ink, including: particles P including hydrophilic polymer particles having a ratio of hydrophilic monomer(s) to the total monomer components thereof of from about 10 mol % to about 90 mol %; and hydrophobic polymer particles, attached to at least a part of a surface of the particles P and having a ratio of hydrophilic monomer(s) to the total monomer components thereof of from about 0 mol % to about 10 mol %.
    Type: Grant
    Filed: October 22, 2009
    Date of Patent: January 11, 2011
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Takatsugu Doi, Masaya Ikuno, Ken Hashimoto
  • Patent number: 7862868
    Abstract: The present invention refers to an ink-jet recording material comprising a support, and at least one ink receiving porous layer coated on the support, wherein at least one porous layer comprises, dispersed therein, an organic solvent having a logP value higher than 2.00, an antifading compound, a non-ionic surfactant having low EDLB, an anionic surfactant, and a carboxylic derivative.
    Type: Grant
    Filed: January 13, 2006
    Date of Patent: January 4, 2011
    Assignee: Ferrania Technologies, S.p.A.
    Inventors: Corrado Balestra, Silvia Biancolini, Raffaella Biavasco, Danilo Ferraro, Alessandro Gunnella, Luisa Tavella
  • Patent number: 7851518
    Abstract: Ink receptive particles for receiving ink, including: particles P including hydrophilic polymer particles having a ratio of hydrophilic monomer(s) to the total monomer components thereof of from about 10 mol % to about 90 mol %; and hydrophobic polymer particles, attached to at least a part of a surface of the particles P and having a ratio of hydrophilic monomer(s) to the total monomer components thereof of from about 0 mol % to about 10 mol %.
    Type: Grant
    Filed: October 22, 2009
    Date of Patent: December 14, 2010
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Takatsugu Doi, Masaya Ikuno, Ken Hashimoto
  • Patent number: 7833590
    Abstract: The present invention is drawn to compositions and coated substrates wherein a hydrophobic backside coating layer can be implemented for use that mitigates ink transfer, surface damage, smudging, and sticking between stacked sheets in output trays of ink-jet ink printers. The backside coating can comprise hydrophobic beads suspended in a polymeric blend having a hydrophilic polymeric binder component and a hydrophobic polymeric binder component. Alternatively, the coating can comprise a hydrophobic binder blended with a natural wax. Either coating can be applied directly to the backside of a media substrate or on top of an existing hydrophilic layer that is typically applied for curl and sheet feed performance.
    Type: Grant
    Filed: October 19, 2004
    Date of Patent: November 16, 2010
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Bor-Jiunn Niu, Stefan Schüttel, Meinrad Schaer
  • Patent number: 7824030
    Abstract: An inkjet recording element comprising a support extrusion coated with a porous hydrophilic material. The composition comprises a hydrophilic thermoplastic polymer and blends thereof. Also disclosed are methods for making and a method of printing on the inkjet recording element.
    Type: Grant
    Filed: August 23, 2005
    Date of Patent: November 2, 2010
    Assignee: Eastman Kodak Company
    Inventors: Thomas M. Laney, Narasimharao Dontula, Kenneth W. Best, Jr.
  • Publication number: 20100272929
    Abstract: An inherently ink printable multi-layer label stock film having a substrate core layer comprising a polymeric material and at least one skin layer which is ink printable, the ink printable skin layer comprising a copolymer of styrene and butadiene and polystyrene in an amount of from 0% to about 30% by weight of the skin layer.
    Type: Application
    Filed: December 17, 2007
    Publication date: October 28, 2010
    Applicant: INNOVIA FILMS LIMITED
    Inventor: Fiona MacIntyre
  • Patent number: 7754297
    Abstract: The present invention provides ink jet recording sheets comprising a colorant receiving layer on a substrate, the colorant receiving layer comprising fine particles, a water soluble resin, and a cationic resin including a unit represented by the following formula (1): Formula (1) wherein, R represents a hydrogen atom or a methyl group; Y represents a divalent linking group; R1 represents an optionally substituted aralkyl or aryl group; R2 and R3 each independently represents an optionally substituted alkyl, aralkyl or aryl group having 1 to 18 carbon atoms; R4 represents an optionally substituted alkylene, aralkylene or arylene group; Q is at least one unit provided from a monomer having an ethylenic double bond, and represents a unit having an inorganic/organic ratio (I/O value) of less than 1 in the organic conceptional chart; X? represents an anion; m represents 20 to 100% by mole; and n represents 0 to 80% by mol.
    Type: Grant
    Filed: November 19, 2003
    Date of Patent: July 13, 2010
    Assignee: FUJIFILM Corporation
    Inventors: Shigetomo Tsujihata, Ryoichi Nakano
  • Publication number: 20100159164
    Abstract: The invention provides an ink jet recording sheet which is highly resistant to printings smearing, running, feathering, color bleeding, or fading when wet, humid, or exposed to intense or continual light. The recording sheet has a solid substrate and a composition coating the solid substrate. The composition comprises a cationic polymer as well as starch, inorganic salt, pigment, and water. The composition can further comprise a non-ionic polymer. The coating tightly binds both pigment based inkjet inks and dye based inkjet inks. The composition is easy to apply and the ink jet recording sheet can be easily formed with a standard size press device.
    Type: Application
    Filed: December 18, 2008
    Publication date: June 24, 2010
    Inventors: Zhiyi Zhang, Angela P. Zagala
  • Patent number: 7718236
    Abstract: An inkjet recording element having a support having thereon in sequence (a) a transparent, non-porous layer that can be swelled by water less than 0.67 of its original weight, and (b) a fusible, porous image-receiving layer. The inkjet recording element exhibits improved adhesion and excellent image quality. A method of inkjet printing is also disclosed.
    Type: Grant
    Filed: March 8, 2004
    Date of Patent: May 18, 2010
    Assignee: Eastman Kodak Company
    Inventors: Hwei-Ling Yau, Wendy S. Krzemien
  • Patent number: 7704575
    Abstract: Anti-bronzing agents are added to ink-jet inks to prevent bronzing of the inks when printed on various types of media. The additive can be an amine anti-bronzing agent that is protonated when the ink-jet ink is printed on the print medium.
    Type: Grant
    Filed: June 16, 2004
    Date of Patent: April 27, 2010
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventors: Linda C. Uhlir-Tsang, John R. Moffatt, Tye J. Dodge
  • Patent number: 7661806
    Abstract: An inkjet recording element comprising a support having thereon in order, from top to bottom, an upper fusible, porous layer comprising fusible polymeric particles, which particles comprise a thermoplastic polymer with reactive functional groups, the inkjet recording element further comprising a lower crosslinker-containing layer in which a polyfunctional compound has complementary reactive functional groups capable of crosslinking the reactive functional groups on the thermoplastic polymer under fusing. Optionally, an ink-carrier-liquid receptive layer is present between the fusible, porous layer and the support. Also disclosed is a method of inkjet printing on the element.
    Type: Grant
    Filed: March 11, 2005
    Date of Patent: February 16, 2010
    Assignee: Eastman Kodak Company
    Inventors: Gregory E. Missell, Lawrence P. DeMejo, Xiaoru Wang
  • Patent number: 7655286
    Abstract: An inkjet recording element comprising a support having thereon in order, from top to bottom, a fusible, porous ink-transporting layer comprising fusible polymeric particles, which particles comprise a thermoplastic polymer with reactive functional groups, the ink-transporting layer further comprising a multifunctional compound having complementary reactive functional groups capable of crosslinking the reactive functional groups on the thermoplastic polymer. The ink-transporting layer is over a fusible dye-trapping layer that preferably comprises a mordant. Optionally, an ink-carrier-liquid receptive layer is present between the dye-trapping layer and the support.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: February 2, 2010
    Assignee: Eastman Kodak Company
    Inventors: Lawrence P. DeMejo, Xiaoru Wang, Gregory E. Missell, Allan Wexler
  • Patent number: 7651748
    Abstract: An inkjet coating composition for coating a substrate to absorb ink from an inkjet printer comprises a combination of (a) polydiallyldimethyl ammonium chloride (pDADMAC), (b) a crosslinkable cationic polymer, (c) colloidal silica, (d) silica gel, (e) a binder, preferably vinyl acetate-ethylene copolymer, and (f) water.
    Type: Grant
    Filed: October 11, 2006
    Date of Patent: January 26, 2010
    Assignee: ISP Investments Inc.
    Inventors: David K. Hood, John G. Mc Kittrick, Surya Kamin
  • Patent number: 7648745
    Abstract: An inkjet recording element comprises a support having thereon in order, from top to bottom, a fusible, porous top layer comprising fusible polymeric particles that comprise a thermoplastic polymer with reactive functional groups, in combination with a multifunctional compound having complementary reactive functional groups capable of crosslinking the reactive functional groups on the thermoplastic polymer. Optionally, an ink-carrier-liquid receptive layer is present between the top layer and the support.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: January 19, 2010
    Assignee: Eastman Kodak Company
    Inventors: Lawrence P. DeMejo, Xiaoru Wang, Sandra D. Nesbitt, Gregory E. Missell
  • Patent number: 7645489
    Abstract: A method for manufacturing an inkjet recording medium comprising the steps of: applying a coating color containing a pigment and a binder as major components to at least one side of a base material using a transfer roll coater, subsequently drying coating layer to form an ink absorbing layer, wherein Hercules viscosity of coating color is 5 m Pa·s to 30 m Pa·s and pigment contains a synthetic silica having an oil absorption of 90 ml/10 g to 200 ml/100 g, a BET specific surface area of 45 m2/g to 200 m2/g and an average particle diameter of 1.0 ?m to 3.0 ?m and/or a precipitated calcium carbonate-silica composite having an oil absorption of 100 ml/10 g to 250 ml/100 g, a BET specific surface area of 5 m2/g to 150 m2/g and an average particle diameter of 1.0 ?m to 10 ?m.
    Type: Grant
    Filed: August 3, 2004
    Date of Patent: January 12, 2010
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Yuji Ozawa, Akinobu Chatani, Kunio Takebayashi, Takashi Ochi, Dai Nagahara, Koichi Yanai
  • Patent number: 7618693
    Abstract: An ink jet recording media system is described which comprises at least one coating layer that comprises a zwitterionic copolymer or cooligomer, which copolymer or cooligomer comprises monomer units derived from at least one monomer selected from the group consisting of the zwitterionic monomers and at least one monomer selected from the group consisting of the hydroxy functional monomers and etherified hydroxy functional monomers. The media system exhibits fast dry times, excellent image quality, low levels of glycol smear, low color coalescence and excellent light fastness.
    Type: Grant
    Filed: July 11, 2007
    Date of Patent: November 17, 2009
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Howard Dungworth, Andrew Naisby, Joseph Suhadolnik, David A. Yale
  • Patent number: 7608338
    Abstract: The invention provides a coating composition that provides high brightness, high gloss and superior print quality. The coated product comprises a substrate coated on at least one side with a coating composition comprising a pigment component and a binder component that is made of mixture of two binder resins. Both binder resins are capable of film forming. The first binder resin provides coating gloss and adhesion properties and the second binder resin enhances coating porosity, adhesion, and anti-static properties. The first binder resin that is used at 60-95% by weight of the total binder resin blend is selected from the group consisting of vinyl acetate acrylate, styrene acrylate and styrene butadiene acrylic copolymers. The second binder resin that is used at 5-40% by weight of the total binder resin blend is selected from the group consisting of anion type polystyrene derivatives, polyethylene glycol and polypropylene glycol.
    Type: Grant
    Filed: June 12, 2003
    Date of Patent: October 27, 2009
    Assignee: International Paper Company
    Inventors: Jay Cheng Song, Sen Yang
  • Publication number: 20090233018
    Abstract: An object of the present invention is to provide an inkjet recording medium which has an excellent ink absorbability, suppresses an ink blur, and has an improved surface glossiness, and a process for manufacturing the medium. The invention provides a process for manufacturing an inkjet recording medium having an ink image-receiving layer having a porous structure on at least one surface of a support, in which the process comprises forming an ink image-receiving layer having a porous structure on at least one surface of the support, and calendar-treating the support having the ink image-receiving layer with a long nip calendar comprising a metal roll and a shoe roll, and a synthetic resin belt therebetween and having a nip width of 10 mm or more. The invention also provides an inkjet recording medium manufactured by the process.
    Type: Application
    Filed: December 6, 2005
    Publication date: September 17, 2009
    Applicant: FUJIFILM CORPORATION
    Inventor: Shigehisa Tamagawa
  • Patent number: 7544402
    Abstract: An ink jet recording media system is described which comprises at least one coating layer that comprises a zwitterionic copolymer or cooligomer, which copolymer or cooligomer comprises monomer units derived from at least one monomer selected from the group consisting of the zwitterionic monomers and at least one monomer selected from the group consisting of the hydroxy functional monomers and etherified hydroxy functional monomers. The media system exhibits fast dry times, excellent image quality, low levels of glycol smear, low color coalescence and excellent light fastness.
    Type: Grant
    Filed: July 8, 2004
    Date of Patent: June 9, 2009
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Howard Dungworth, Andrew Naisby, Joseph Suhadolnik, David A. Yale
  • Patent number: 7521101
    Abstract: An ink jet recording media system is described which comprises at least one coating layer that comprises a copolymer or cooligomer, which copolymer or cooligomer comprises monomer units derived from at least one monomer selected from the group consisting of the acrylate and acrylamide monomers, at least one monomer selected from the group consisting of the amine containing ethylenically unsaturated monomers and at least one monomer selected from the group consisting of the polyacrylates of polyols. The copolymer or cooligomer is at least partially neutralized with acid. The media system exhibits excellent dye wash fastness, fast dry times, high gloss and excellent light fastness.
    Type: Grant
    Filed: July 13, 2004
    Date of Patent: April 21, 2009
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Andrew S. Naisby, Howard R. Dungworth, Donna Pennant, Joseph Suhadolnik
  • Patent number: 7510750
    Abstract: A recording paper containing pulp fibers and filler as main components and containing at least a heterocyclic carboxylic acid and a water-soluble polymer in the surface of the recording paper, wherein the surface contains at least one kind of cationic substance selected from the group consisting of a cationic organic molecule and a metal salt containing a metal cation of valency two or greater.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: March 31, 2009
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Chizuru Koga, Kiyoshi Hosoi, Takashi Ogino, Tsukasa Matsuda
  • Publication number: 20080274309
    Abstract: A ink jet recording medium and, in particular, an ink jet recording medium of photographic quality that in one embodiment exhibits scratch resistance and/or toughness and/or resistance to softening upon printing.
    Type: Application
    Filed: May 3, 2007
    Publication date: November 6, 2008
    Applicant: FUJIFILM MANUFACTURING U.S.A. INC.
    Inventors: Chuan Lee, Ekaterini Bogas Beauvais, Stephen James Rudy
  • Patent number: 7399508
    Abstract: The present invention provides a recording medium including a recording layer on a substrate, wherein the recording layer includes a polymer that has a thioether bond, has a sulfur equivalent of no less than 1.2 meq/g, and has an inorganic/organic ratio (I/O value) represented in an organic-inorganic conceptional diagram of no less than 0.5. According to the invention, the recording medium may be an ink jet recording medium, in which the recording layer is an ink receiving layer.
    Type: Grant
    Filed: May 26, 2004
    Date of Patent: July 15, 2008
    Assignee: FUJIFILM Corporation
    Inventors: Shigetomo Tsujihata, Masanobu Takashima, Shinichiro Serizawa
  • Patent number: 7377631
    Abstract: An aqueous ink, by which stable ink-jet recording can be conducted irrespective of printing environment, a substantially even image having abrasion resistance can be formed, no image soiling is caused even upon double-side printing, and a high-quality image improved in unclearness at a contour portion of the image and free from occurrence of color bleed can be provided, is provided. The aqueous ink is an aqueous ink used in a system that a reaction liquid containing at least a polyvalent metal and an aqueous ink containing at least a pigment dispersion, in which a pigment is dispersed with an anionic polymer dispersant, are used to form an image, wherein the aqueous ink satisfies specific condition.
    Type: Grant
    Filed: September 14, 2005
    Date of Patent: May 27, 2008
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yoichi Takada, Junichi Sakai, Fumiaki Fujioka, Yasuhiro Nito, Masashi Tsujimura, Takashi Imai, Shinichi Hakamada, Sadayuki Sugama, Shinya Mishina
  • Publication number: 20080085385
    Abstract: An ink receptive article including a substrate having applied on at least a portion thereof a layer of an ink receptive coating, wherein the ink receptive coating layer includes a cross-linked polymer and an ink absorbing polymer, wherein the ink absorbing polymer has a solubility parameter of equal to or less than 9 (cal/cm3)1/2.
    Type: Application
    Filed: October 4, 2006
    Publication date: April 10, 2008
    Inventors: Caroline M. Ylitalo, Chester A. Bacon, Christopher K. Haas, James M. Jonza, Mark J. Pellerite
  • Publication number: 20070275191
    Abstract: Methods and aqueous surface coating compositions are provided for producing a high-resolution ink-jet ink printable coating layer on a surface, the composition comprising at least one polymer selected from a water soluble polymer and a water-emulsifiable polymer, wherein the at least one polymer is present in a concentration of up to 10% by weight and at least one surfactant comprising a long hydrophobic moiety, wherein the at least one surfactant is present in a concentration of up to 10% by weight. The high-resolution ink-jet ink printable coating layer is characterized by its ability to be removed by spraying with water, and yet having excellent resistance to heat and acid, when coated with cured legend ink.
    Type: Application
    Filed: May 23, 2007
    Publication date: November 29, 2007
    Inventor: Izhar Halahmi
  • Publication number: 20070196597
    Abstract: The invention provides an inorganic fine particle dispersion having at least an inorganic fine particles, a silane coupling agent, and at least one member selected from the group consisting of a basic inorganic salt and ammonium, the inorganic fine particle dispersion having a pH of 5.0 or less, and a method for forming thereof including at least adjusting the pH by using the basic inorganic salt and/or the ammonium. The invention further provides an ink jet recording medium and a method manufacturing thereof including at least applying an ink-receiving layer coating liquid formed by mixing the inorganic fine particle dispersion and a water-soluble resin onto a support.
    Type: Application
    Filed: February 12, 2007
    Publication date: August 23, 2007
    Applicant: FUJIFILM Corporation
    Inventors: Kentaro Shiratsuchi, Tomoya Kubota
  • Publication number: 20070172608
    Abstract: The present invention provides an inkjet-recording medium having an ink-receiving layer at least containing a cationic polyurethane resin and a water-soluble bivalent metal salt, wherein the coating amount of the cationic polyurethane resin x (g/m2) and the coating amount of the water-soluble bivalent metal salt y (g/m2) satisfy the relationships of 0.3?x?5.0 and 0.01x?y?0.5x.
    Type: Application
    Filed: January 23, 2007
    Publication date: July 26, 2007
    Applicant: FUJIFILM Corporation
    Inventors: Kaoru Tojo, Kentaro Shiratsuchi
  • Patent number: 7235284
    Abstract: There is described a recording sheet for ink jet printing comprising a polyethylene coated paper support having coated onto the front side of said support one ink receiving layer comprising a mixture of gelatin and rice starch.
    Type: Grant
    Filed: March 18, 1998
    Date of Patent: June 26, 2007
    Assignee: Ilford Imaging Switzerland GmbH
    Inventors: Mario Fryberg, Stefan Schuttel, Hiroshi Tomimasu
  • Patent number: 7090903
    Abstract: An ink-jet recording sheet, comprising a support having thereon a porous ink receiving layer, the porous ink receiving layer including inorganic particles, a hydrophilic binder and a polymer, wherein the polymer has a plurality of carbon-carbon unsaturated bonds, provided that the unsaturated bonds are non-aromatic; the polymer has a recurring unit derived from butadiene or isoprene.
    Type: Grant
    Filed: September 26, 2003
    Date of Patent: August 15, 2006
    Assignee: Konica Corporation
    Inventors: Eisaku Katoh, Atsushi Tomotake, Toshihiko Iwasaki, Masayuki Ushiku, Junji Ito, Yukako Taka
  • Patent number: 7087275
    Abstract: A coating fluid for application to a support to prepare an ink jet recording medium comprises an aqueous dispersion of a synthetic polymer hydrogel and gelatin, the amount of the synthetic polymer hydrogel being from 5 to 50% by weight of the combined weight of synthetic polymer and gelatin. Preferably the coating fluid also contains a mordant, an aliphatic alcohol to assist dispersion of the hydrogel polymer and a particulate material to impart a porous structure to the coating. The invention also provides an inkjet recording medium comprising a support on which is an ink-receiving layer comprising the gelatin and a synthetic polymer hydrogel. The amount of the latter may be from 0.3 to 5 g/square meter.
    Type: Grant
    Filed: May 30, 2002
    Date of Patent: August 8, 2006
    Assignee: Eastman Kodak Company
    Inventors: Julie Baker, Malcolm D. Purbrick
  • Patent number: 7015270
    Abstract: A stable, aqueous dispersion, which includes: silicon dioxide mixed-oxide particles dispersed in at least one water-soluble cationic polymer having a mass average molar mass of less than 100,000 g/mol, said mixed-oxide including aluminum oxide or titanium dioxide, wherein said particles are produced by flame hydrolysis, wherein said particles have a BET specific surface area of 5 to 600 m2/g and a negative zeta potential, and wherein the dispersion has a positive zeta potential.
    Type: Grant
    Filed: January 27, 2003
    Date of Patent: March 21, 2006
    Assignee: Degussa AG
    Inventors: Thomas Scharfe, Christoph Batz-Sohn, Wolfgang Lortz
  • Patent number: 6998213
    Abstract: There are provided a thermal transfer film which can yield an image formed object possessing excellent fastness or resistance properties such as excellent abrasion resistance and lightfastness, has good sensitivity in transfer, and is free from blocking during storage in a roll form, a thermal transfer recording medium, and a method for image formation using them. The thermal transfer film comprises: a substrate; and one or a plurality of layers provided on one side of the substrate, the one or plurality of layers including at least a thermal transfer layer, the thermal transfer layer being located on the uppermost surface of the thermal transfer film, the thermal transfer layer comprising at least two polyester resins different from each other in number average molecular weigh.
    Type: Grant
    Filed: September 17, 2002
    Date of Patent: February 14, 2006
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Kenichi Aso, Yoshihiko Tamura
  • Patent number: 6979481
    Abstract: The present invention provides microporous photo quality glossy inkjet receiving media comprising a substrate, an absorbent basecoat layer, and an ink-receptive topcoat. The absorbent basecoat layer is primarily a combination of pigment and binder, and may include deformable particles, such as core-shell polymeric pigments. The ink-receptive topcoat is composed primarily of alumina hydrate, gelatin, and a water-insoluble cationic polymer. The present invention also provides a method for increasing the gloss and surface smoothness presented by the topcoat of a printing medium by including deformable particles in an underlying basecoat followed by calendering of the printing medium. Further, the present invention provides combination matte and gloss inkjet printing media, comprising matte basecoats at least partially coated with the aforementioned ink-receptive topcoat.
    Type: Grant
    Filed: August 19, 2002
    Date of Patent: December 27, 2005
    Assignee: Mohawk Paper Mills, Inc.
    Inventors: Gavin L. Gaynor, Larry G. Venable
  • Patent number: 6936317
    Abstract: Ink jet printing paper carries a pigment coating comprising (a) a major proportion of a finely divided precipitated calcium carbonate (PCC) having a surface area of at least 60 m2g?1, preferably 80 to 90 m2g?1 (b) a minor proportion of a gel-type silica and (c) binder. The silica is preferably present in an amount of 15 to 30% by weight of the total dry weight of silica and PCC. The pigment coating is preferably made up as an aqueous composition having a solids content of 25 to 35% and a Brookfield viscosity of 150 to 2000 mPa s and applied by a blade coating technique.
    Type: Grant
    Filed: December 12, 2000
    Date of Patent: August 30, 2005
    Assignee: Arjo Wiggins Fine Papers Limited
    Inventors: Mark Victor Watson, Gary Paul Westwood
  • Patent number: 6933024
    Abstract: The use and preparation of poly(vinylpyrrolidone (PVP)-co-vinylalcohol (PVA)) as inkjet recording material, the method of making PVP/PVA copolymer comprising the steps of: hydrolyzing PVP/polyvinyl acetate (PVAc) copolymer with a mixture comprising water, at least one alcohol and at least one strong base.
    Type: Grant
    Filed: July 18, 2002
    Date of Patent: August 23, 2005
    Assignee: Hewlett-Packard Development Company, L.P.
    Inventor: Tienteh Chen
  • Patent number: 6924011
    Abstract: An improved ink jet recording material is disclosed comprising a support and an ink receiving layer. This layer contains a pigment and a polymeric binder comprising a structural unit derived from a monomer represented by following formula (I): wherein, R1 is alkyl, R2 is alkyl or aryl, R3 is hydrogen, alkyl or aryl, L is a linking unit selected from CO—NH, CO—O, and CO, and R4 is hydrogen or alkyl. The material is improved for mechanical strength. The finished ink jet image shows high color densities and high gloss without the occurence of cracking.
    Type: Grant
    Filed: May 19, 2003
    Date of Patent: August 2, 2005
    Assignee: AGFA Gevaert
    Inventors: Huub Van Aert, Stefaan Lingier
  • Patent number: 6913801
    Abstract: A recording medium for an inkjet printer includes a substrate and an ink receiving layer formed thereon and has an ink absorbing layer having a pigment and a binder, and an ink fixation layer having the pigment, the binder and polyether siloxane copolymer. The recording medium has good coating surface properties by improving surface wetting, a leveling property and flowability by adding the polyether siloxane copolymer to the ink fixation layer during coating, as a component enhancing physical properties of the ink fixation layer.
    Type: Grant
    Filed: June 2, 2003
    Date of Patent: July 5, 2005
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Jae-hwan Kim, Taekkyong Jung
  • Patent number: 6881458
    Abstract: The invention relates to articles comprising a substrate comprising an ink receptive layer and an ink-jet printed image as well as methods of ink jet printing. The ink receptive layer comprises certain urethane-containing polymers and blends.
    Type: Grant
    Filed: December 23, 2002
    Date of Patent: April 19, 2005
    Assignee: 3M Innovative Properties Company
    Inventors: Bret W. Ludwig, Jeffrey O. Emslander, Caroline M. Ylitalo, Oh Sang Woo, Jennifer L. Lee, Richard L. Severance
  • Patent number: 6869647
    Abstract: Ink-receiving print media products having multiple capabilities including (A) minimal drying time; (B) improved smear-fastness; (C) a high level of water-fastness; (D) the ability to generate high-definition images; and (E) excellent ink compatibility. The media products have at least one ink-receiving layer on a substrate (e.g. paper pre-coated with one or more binders and/or pigments). The ink-receiving layer includes a pigment (boehmite, pseudo-boehmite, or mixtures thereof) optimally combined with a special binder blend [polyvinyl alcohol, a poly(vinyl acetate-ethylene) copolymer, and a poly(vinyl pyrrolidone-vinyl acetate) copolymer]. Also included is a special dye fixative (namely, a cationic emulsion polymer) which provides enhanced water-fastness. This fixative is of a particular type (a quaternary amine) that also allows high pigment levels to be employed (at least about 65% by weight) which further promotes the foregoing benefits.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: March 22, 2005
    Assignee: Hewlett-Packard Development Company L.P.
    Inventors: Loretta Ann Grezzo Page, Richard J. McManus
  • Patent number: 6855381
    Abstract: The present invention describes a transfer system of images produced by an ink jet printer to a textile substrate, comprising a backing and mounted thereon at least one melt transfer ink absorption layer with a matrix comprising at least one meltable polymer material into which fine particles of a filler capable of ink absorption have been embedded.
    Type: Grant
    Filed: August 30, 2001
    Date of Patent: February 15, 2005
    Assignee: Star Coating AG
    Inventors: Jan Dietrich, Peter Kummer, Ilona Stiburek
  • Patent number: 6852378
    Abstract: An ink jet-recording sheet for forming recorded images using liquid ink comprises a combination of specific compounds, for instance, 1,2-bis(2-hydroxyethylthio)ethane and a homopolymers or copolymer of diallylamine type compounds such as poly(diallylamine)hydrochloride, poly(diallylamine)sulfate, poly(diallylamine) phosphate or poly(diallylamine)acetate. The ink jet-recording sheet can ensure a high density of printed images, can provide images having high quality, shows only a slight color change and discoloration of printed images even when exposed to ozone gas and is excellent in the long-term shelf life.
    Type: Grant
    Filed: September 22, 2003
    Date of Patent: February 8, 2005
    Assignee: Oji Paper Co., Ltd.
    Inventors: Tetsuo Tsuchida, Jun Nishio, Masahiro Morie
  • Patent number: 6846524
    Abstract: An inkjet recording medium comprising at least one ink receiving layer on a support, wherein the ink receiving layer which is the outermost layer comprises a pigment and an aqueous polyurethane resin as principal components, the proportion of said aqueous polyurethane resin relative to said pigment in the ink receiving layer which is the outermost layer is 5-80 wt %, said aqueous polyurethane resin is formed by reaction of an active hydrogen compound and an aliphatic and/or alicyclic polyisocyanate compound, said active hydrogen compound contains 40-80 wt % of a polyether polyol compound having a number average molecular weight of 500-3000, and the minimum film-forming temperature of said aqueous polyurethane resin is ?10-50 degree C.
    Type: Grant
    Filed: March 25, 2002
    Date of Patent: January 25, 2005
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Yuji Ozawa, Toshikazu Teramasa, Masashi Seki, Tadashi Saito