Synthetic Resin Or Polymer Patents (Class 428/394)
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Patent number: 6579616Abstract: A string binder is disclosed which is useful for making reinforcing articles for use in the manufacture of molded composite articles. The string binder, in one embodiment, includes a fibrous carrier substrate material covered with a solidified coating comprising a binder resin material having an acid value of less than about 30 mg KOH/g of resin. Additionally, the coating may include a catalyst applied as a separate layer or in combination with the binder resin material. The string binder may be co-roved with one or more ends of a separate fibrous reinforcing material to make a product suitable for use in various molding applications.Type: GrantFiled: March 30, 1999Date of Patent: June 17, 2003Assignee: Owens Corning Fiberglas Technology, Inc.Inventors: Jay Joseph Beckman, Diane Marie Hulett, William Gerard Hager
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Publication number: 20030096112Abstract: A temperature-sensitive color-changeable composite fiber comprising a phase-(A) thermochromic resin phase formed of a polyolefin resin in which a thermochromic material and an adhesive resin having a molecular weight of 200 to 10,000 or a copolymer resin of an olefin with a unit monomer capable of forming a polymer having a solubility parameter (SP value) of 9.0 or more have been dispersed or dissolved, and a phase-(B) resin phase selected from nylon 12, a copolymer nylon, polyhexamethylene terephthalate and a saturated aliphatic polyester; the phase-(A) and the phase-(B) being joined to each other. This fiber can satisfy the glossiness and touch of fibers, and color changes caused by temperature changes can clearly be sighted thereon. It also can enhance commercial value of various fiber materials and that of wigs for doles and so form, making use of such a fiber.Type: ApplicationFiled: November 21, 2002Publication date: May 22, 2003Applicant: THE PILOT INK CO., LTD.Inventor: Naoya Ishimura
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Patent number: 6565970Abstract: The present invention relates to a method for the production of polypropylene fibers resulting in improved shrinkage percentages and to polypropylene fibers themselves having improved shrinkage percentages. The method includes providing a polypropylene polymer with a melt flow index of no more than about 25 grams per 10 minutes. This polymer should include isotactic polypropylene produced by the polymerization of propylene in the presence of an isospecific metallocene catalyst. The polymer is then heated to a molten state and extruded to form a fiber preform. The preform is spun and subsequently drawn at a take-away speed and a drawing speed providing a draw ratio of no more than about 3, and more preferably no more than about 2.5, to produce a continuous polypropylene fiber.Type: GrantFiled: October 22, 2001Date of Patent: May 20, 2003Assignee: Fina Technology, Inc.Inventors: Mohan Gownder, Jay Nguyen
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Patent number: 6559197Abstract: The invention disclosed includes a coating composition for siliceous surfaces. The coating includes at least one component from the group consisting of poly(alkoxy)silane, poly(halo)silane, alkoxysilane, halosilane, and mixtures thereof and a catalyst compound which generates a proton to hydrolyze the component when exposed to radiation. Preferably, the catalyst is a photo-acid. The invention also includes a method of coating the optical fiber. The aforementioned coating is applied to an exterior surface of the fiber. A proton is generated to promote the hydrolysis of the component. The invention further includes a method of accelerating adhesion between the exterior surface of the article and the coating. The inventive coating is applied to the surface of the fiber and the coating is exposed to a radiation source.Type: GrantFiled: March 28, 2001Date of Patent: May 6, 2003Assignee: Corning IncorporatedInventors: Edward J. Fewkes, Gregory F. Jacobs, Michael J. Winningham
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Publication number: 20030082360Abstract: The present invention relates to an intermediate web comprising of high glass transition polymer fibers. The fibers are spun at low to moderate speeds and have a relative crystallinity of from 10% to 75% of the maximum achievable crystallinity. The intermediate web is a low crystallinity web that exhibits shrinkage of more than 30% and elongation to break of more than 80% at high strain rates. This web can be heat treated to reduce shrinkage to less than 15% while the web is capable of at least about 60% elongation at a strain rate of at least about 50 second−1.Type: ApplicationFiled: August 7, 2002Publication date: May 1, 2003Applicant: The Procter & Gamble CompanyInventors: Hugh Joseph O'Donnell, Eric Bryan Bond, Jody Lynn Hoying
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Publication number: 20030082376Abstract: Synthetic polymer reinforcing fibers provide dispersability and strength in matrix materials such as concrete, masonry, shotcrete, and asphalt. The individual fiber bodies, substantially free of stress fractures and substantially non-fibrillatable, have generally quadrilateral cross-sectional profiles along their elongated lengths.Type: ApplicationFiled: December 11, 2002Publication date: May 1, 2003Applicant: W.R. GRACE & CO.-CONN.Inventors: Klaus Alexander Rieder, Neal S. Berke, Michael B. Macklin, Anandakumar Ranganathan
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Patent number: 6552123Abstract: Provided are melt-spun fibers comprising, as at least one component, a water-soluble polyvinyl alcohol, and a method for producing fibrous structures comprising the fibers. The thermoplastic polyvinyl alcohol fibers comprise, as at least one component, a water-soluble polyvinyl alcohol containing from 0.1 to 25 mol % of C1-4 &agr;-olefin units and/or vinyl ether units, having a molar fraction, based on vinyl alcohol units, of a hydroxyl group of vinyl alcohol unit located at the center of 3 successive vinyl alcohol unit chain in terms of triad expression of being from 70 to 99.9 mol %, having a carboxylic acid and lactone ring content of from 0.02 to 0.15 mol %, and having a melting point falling between 160° C. and 230° C., and contain from 0.0003 to 1 part by weight, relative to 100 parts by weight of the polyvinyl alcohol therein and in terms of sodium ion, of an alkali metal ion.Type: GrantFiled: December 16, 1999Date of Patent: April 22, 2003Assignee: Kuraray Co., Ltd.Inventors: Takashi Katayama, Kazuhiko Tanaka, Naoki Fujiwara, Tomoaki Kimura, Akihiro Hokimoto, Nobuhiro Koga, Hitoshi Nakatsuka, Yoshimi Umemura, Hiroshi Kanehira, Masao Kawamoto, Junyo Nakagawa
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Patent number: 6551707Abstract: The present invention relates to pellets comprising fibers impregnated with resin. The pellets incorporate a mixed lubricant sizing composition comprising at least one cationic lubricant and at least one non-ionic lubricant. These pellets may be consolidated to form fiber reinforced resin composites.Type: GrantFiled: September 30, 2000Date of Patent: April 22, 2003Assignee: Owens Corning Fiberglas Technology, Inc.Inventors: Leonard Joseph Adzima, Robert Arthur Schweizer, Arthur Eloy Lopez, Donald Burton Sage, Jr.
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Patent number: 6541138Abstract: A method of preparing a stain resistant and water repellant textile fabric comprising: a) treating a textile fabric with an aqueous primary treatment composition comprising at least about 5 weight percent of a fluorochemical textile treating agent, based on the weight of the primary treatment composition; b) drying the treated fabric at an elevated temperature to obtain a primarily treated fabric; c) providing a polymeric film on one side of the primarily treated fabric, the film comprising an aqueous secondary treatment composition comprising at least about 4 weight percent of a fluorochemical textile treating agent, based on the weight of the secondary treatment composition; and d) drying the treated fabric with the film at an elevated temperature to obtain a secondarily treated fabric.Type: GrantFiled: May 4, 2001Date of Patent: April 1, 2003Assignee: Hi-Tex, Inc.Inventors: Kyle Bullock, Craig A. Rubin, Randy B. Rubin
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Publication number: 20030057593Abstract: An acrylic fiber having cotton-like properties with modified, internal void structure and optical characteristics, the acrylic fiber comprising a BYK Gardner Luster (BYL) reflectance measurement of less than about 44.Type: ApplicationFiled: September 25, 2001Publication date: March 27, 2003Inventors: Gary J. Capone, Danny W. Carter, C. Wayne Emerson
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Patent number: 6537663Abstract: The present invention is directed to ion-sensitive, hard water dispersible polymers. The present invention is also directed to a method of making ion-sensitive, hard water dispersible polymers and their applicability as binder compositions. The present invention is further directed to fiber-containing fabrics and webs comprising ion-sensitive, hard water dispersible binder compositions and their applicability in water dispersible personal care products.Type: GrantFiled: May 4, 2000Date of Patent: March 25, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Yihua Chang, Dave A. Soerens, Frederick J. Lang
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Patent number: 6537662Abstract: A soil-resistant spin finish composition based on select derivitized polyethers is provided that can be applied to a fiber at the earliest stages of spinning, can remain on the fiber through the entire manufacturing process, and can be left on the fiber in the final article of commerce. The spin finish composition provides excellent fiber lubrication during high-speed spin processing, yet is sufficiently soil resistant to negate the need for scouring the final fiber construction, even absent the presence of additional coatings or agents.Type: GrantFiled: January 11, 1999Date of Patent: March 25, 2003Assignee: 3M Innovative Properties CompanyInventors: Robert F. Kamrath, James E. Lockridge, Edward R. Hauser, Irvin F. Dunsmore, Chetan P. Jariwala, Nicole L. Franchina, Roger R. Alm
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Patent number: 6537661Abstract: The present invention provides melt processable, bleach resistant durable fibers having an elastic recovery above 50% after extension to 160% elongation and a stress relaxation below 50% after extension to 150% for 30 minutes which are formed from a soft polyurethane elastomer. This elastomer is comprised of (a) from 75 to 90% weight of a polydiene diol having up to about two terminal hydroxyl groups per molecule and a number average molecular weight between 500 and 20,000, (b) from 9 to 25% weight of a diisocyanate, and (c) from 0.8 to 5% weight of a chain extender which is a low molecular weight aliphatic diol, or a mixture of the low molecular weight aliphatic diol and from 0.1 to 4.0 mol % of a diamine wherein the hard segment content of the polyurethane elastomer is from about 10 to about 30% weight. The present invention further provides a polyurethane elastomer.Type: GrantFiled: February 20, 2002Date of Patent: March 25, 2003Assignee: Kraton Polymers U.S. LLCInventors: Lie Khong Djiauw, Michael A. Masse
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Publication number: 20030054718Abstract: A poly(lactic acid) fiber has a strength at 90° C. of equal to or more than 0.8 cN/dtex and exhibits significantly satisfactory mechanical properties at high temperatures as compared with conventional poly(lactic acid) fibers.Type: ApplicationFiled: July 29, 2002Publication date: March 20, 2003Applicant: TORAY INDUSTRIES, INC.Inventors: Takashi Ochi, Takaaki Sakai, Yuhei Maeda
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Patent number: 6531522Abstract: The present invention relates to a coating for an optical fiber. The coating includes a monomer. The monomer includes an oxyglycidyl (meth)acrylate component. A coating with the monomeric component has exhibited an excellent polymerization rate. The present invention also relates to methods of making such optical fibers coated in accordance with the invention and the coated glass article.Type: GrantFiled: November 14, 2000Date of Patent: March 11, 2003Assignee: Corning IncorporatedInventor: Michael J. Winningham
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Publication number: 20030045641Abstract: Oxygen scavenging barrier polyamide compositions exhibiting high oxygen scavenging capability as well as good coinjection stretch blow moldability characteristics suitable for making multilayer PET bottles with good clarity and delamination resistance are claimed in this invention. The polyamide compositions of this invention comprise a slow crystallizing polyamide blend comprising (i) an amorphous, semiaromatic polyamide homopolymer, copolymer or mixture thereof and (ii) a semicrystalline, aliphatic polyamide homopolymer, copolymer or mixture thereof wherein in the weight ratio of (i):(ii) ranges from about 99:1 to about 30:70; at least one polyamide-compatible, oxidizable polydiene; and at least one oxidation promoting metal salt catalyst. The multilayer PET bottles, made with the polyamide compositions of this invention as the barrier layer, are suitable for extended shelf-life packaging of oxygen-sensitive food and beverage products such as beer and juices.Type: ApplicationFiled: February 14, 2002Publication date: March 6, 2003Applicant: Honeywell International Inc.Inventors: Murali K. Akkapeddi, Edward P. Socci, Timothy J. Kraft, Darnell C. Worley, Jeffrey D. Pratt, Clark V. Brown
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Publication number: 20030039833Abstract: The elasticity of elastic, absorbent structures, e.g., diapers, is improved without a significant compromise of the absorbency of the structure by the use of bicomponent and/or biconstituent elastic fibers. The absorbent structures typically comprise a staple fiber, e.g., cellulose fibers, and a bicomponent and/or a biconstituent elastic. The bicomponent fiber typically has a core/sheath construction. The core comprises an elastic thermoplastic elastomer, preferably a TPU, and the sheath comprises a homogeneously branched polyolefin, preferably a homogeneously branched substantially linear ethylene polymer. In various embodiments of the invention, the elasticity is improved by preparation techniques that enhance the ratio of elastic fiber:cellulose fiber bonding versus cellulose fiber:cellulose fiber bonding.Type: ApplicationFiled: July 15, 2002Publication date: February 27, 2003Inventors: Ashish Sen, John Klier, Rexford A. Maugans, Kenneth Stewart
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Publication number: 20030035954Abstract: The present invention provides a synthetic fiber to be used for pile products having an appearance and texture near to natural fur, to which a softening agent is adhered, the fiber being obtainable by controlling the adhered amount of an emulsifier to 8 parts by weight or less relative to 100 parts by weight of a softening compound in the softening agent adhered to the synthetic fiber, and the fiber overcoming an insufficient slimy feeling and having a further lowered &mgr;s (F/F) and an improved sliminess. The invention also provides a process for producing the same.Type: ApplicationFiled: August 29, 2002Publication date: February 20, 2003Inventors: Masaaki Miyoshi, Satoru Harada
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Publication number: 20030026987Abstract: The present invention relates to surface modified staple fiber, and more particularly, polyester fiberfill and fiber clusters which are made by a completely coupled bulked continuous filament (BCF) process.Type: ApplicationFiled: September 19, 2002Publication date: February 6, 2003Inventors: John S. Ahn, Fritz Brakelmann, Ilan Marcus
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Publication number: 20030026981Abstract: Disclosed are polyketone fibers which contain a ketone unit represented by —CH2CH2—CO— as a main repeating unit, and have an intrinsic viscosity of not less than 0.5 dl/g, a crystal orientation of not less than 90%, a density of not less than 1.300 g/cm3, an elastic modulus of not less than 200 cN/dtex, and a heat shrinkage of −1 to 3%. The polyketone fibers are high in strength and elastic modulus, and excellent in fatigue resistance, processability, heat resistance, dimensional stability, and, besides, adhesion, and, therefore, can be applied to the fields which require high fatigue resistance, such as tire cords, belts, hoses, ropes, etc.Type: ApplicationFiled: February 26, 2002Publication date: February 6, 2003Applicant: ASAHI KASEI KABUSHIKI KAISHAInventors: Jinichiro Kato, Toru Morita, Ryu Taniguchi
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Publication number: 20030017334Abstract: A composition including an aromatic polyester and a copolyester having a lower melting point than the aromatic polyester. The aromatic polyester and the copolyester can be blended together to form fibers and fibrous webs. The composition can be thermally bonded at a temperature below the melting point of the aromatic polyester.Type: ApplicationFiled: September 18, 2002Publication date: January 23, 2003Inventors: Nina Cecilia Griffith, Xin Ning, Bryon P. Day, Maya Aroch
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Patent number: 6503624Abstract: The carbon fiber precursor fiber bundle of the present invention is an acrylonitrile-based fiber bundle wherein the ratio of the length and width of the fiber cross section of a monofilament (length/width) is 1.05 to 1.6, and the amount of Si measured by ICP (Inductively Coupled Plasma) atomic emission spectrometry is in the range of 500 to 4,000 ppm. This type of carbon fiber precursor fiber bundle has a high compactness, and the carbonizing processing ability is good. Furthermore, for the carbon fiber bundle which is to obtained hereafter, the resin impregnating ability and tow spreading ability are good, the strength increases, and it has bulkiness. Furthermore, the carbon fiber precursor fiber bundle of the present invention is an acrylonitrile-based fiber bundle wherein the liquid content ratio HW is 40 wt. % or more and less than 60 wt. %.Type: GrantFiled: June 22, 2001Date of Patent: January 7, 2003Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Katsuhiko Ikeda, Masakazu Hoshino, Takayoshi Yamamoto, Aritaka Shimotashiro, Toshihiro Makishima, Masashi Okamoto
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Patent number: 6500541Abstract: Synthetic polymeric filaments containing SAP particles adhered to the filament surfaces by an nylon binder which is soluble in alcohols (e.g., lower C1-C3 aliphatic alcohols). Such SAP-coated filaments may then be incorporated into telecommunications cables as a component part thereof to achieve enhanced water-blocking functions. In preferred embodiments, the SAP particles include homopolymers, copolymers, and/or mixtures of sodium and potassium polyacrylates, starch grafted sodium polyacrylates and partial sodium salts of polypropenoic acid which are bound to the yarn surfaces by the nylon binder. Most preferably, the coated multifilamentary yarns of the present invention are made by bringing an uncoated yarn into contact with a nonaqueous liquid coating material comprised of the nylon binder dissolved in an alcohol solvent containing a dispersion of the SAP particles for a time sufficient to coat the yarn with the liquid coating material.Type: GrantFiled: September 18, 2000Date of Patent: December 31, 2002Assignee: Fil-Tech, Inc.Inventors: Vincent E. Schoeck, Jr., Edwin E. Fuller, Andrew Dubnik
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Patent number: 6500540Abstract: The present invention relates to elastic articles comprising a crosslinked or crosslinkable ethylene polymer and a method for making the same. In particular, the invention relates to a shaped article (e.g. film or fiber) characterized by improved elasticity at elevated temperatures and comprising a substantially cured, irradiated, or crosslinked (or curable, irradiated or crosslinkable) homogeneously branched ethylene polymer. The improved elastic article of the present invention is particularly suitable for use in applications where good elasticity must be maintained at elevated temperatures such as, for example, personal hygiene items and disposable infection-control garments at body temperatures of about 100° F. (38° C.).Type: GrantFiled: May 18, 1999Date of Patent: December 31, 2002Assignee: The Dow Chemical CompanyInventors: Michael F. Langohr, Selim Bensason, Rajen M. Patel, Jill M. Martin, Thoi H. Ho, Nancy J. Schrock
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Patent number: 6497953Abstract: Methods of making polymeric fibers are provided and include spinning a solution containing at least one polymer, a modified pigment having attached at least one organic group, and a solvent. The polarity of the solvent and the polarity of the modified pigment are selected such that the polymer is soluble in the solution and the modified pigment is maintained dispersed throughout the solution. The polarity of the modified pigment may be substantially the same as the polarity of the solvent. Fibers of acrylic-containing polymers and other polymeric fibers are also provided. Articles and reinforcing material containing the various fiber(s) are also described.Type: GrantFiled: October 9, 1998Date of Patent: December 24, 2002Assignee: Cabot CorporationInventors: Michael Yu, Eduardo Romero, Curtis E. Adams, Marinus A. Potter, James A. Belmont, Patrick Collins
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Publication number: 20020193553Abstract: A nonwoven web and method of preparing a novel nonwoven web of synthetic fiber are disclosed. An aqueous solution amide crosslinked synthetic precursor polymer is extruded under defined conditions through a plurality of die orifices to form a plurality of threadlines. The threadlines are attenuated with a defined primary gaseous source to form fiber under conditions of controlled macro scale turbulence and under conditions sufficient to permit the viscosity of each threadline, as it leaves a die orifice and for a distance of no more than about 8 cm, to increase incrementally with increasing distance from the die, while substantially maintaining uniformity of viscosity in the radial direction, at a rate sufficient to provide fiber having the desired attenuation and mean fiber diameter without significant fiber breakage. The attenuated threadlines are dried with a defined secondary gaseous source. The resulting fibers are deposited randomly on a moving foraminous surface to form a substantially uniform web.Type: ApplicationFiled: March 1, 2002Publication date: December 19, 2002Inventors: Jian Qin, Yong Li, Wendy Lynn Van Dyke, Anthony John Wisneski, Palani Raj Ramaswami Wallajapet, Hannong Rhim
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Patent number: 6492021Abstract: Described is wet-spun plural-end elastane yarn having a yarn linear density of up to 2500 dtex, high surface luster and a ribbony cross section and formed from bonded-together individual filaments having an oval to circularly round cross section, the width of the elastane yarn in cross section being at least four times the thickness of the elastane yarn.Type: GrantFiled: December 29, 2000Date of Patent: December 10, 2002Assignee: Bayer Faser GmbHInventors: Ulrich Reinehr, Tilo Sehm, Wolfgang Anderheggen, Toni Herbertz, Günter Spilgies
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Patent number: 6492020Abstract: The present invention relates to surface modified staple fiber, and more particularly, polyester fiberfill and fiber clusters which are made by a completely coupled bulked continuous filament (BCF) process.Type: GrantFiled: June 16, 2000Date of Patent: December 10, 2002Assignee: E. I. du Pont de Nemours and CompanyInventors: John S. Ahn, Fritz Brakelmann, Ilan Marcus
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Patent number: 6485828Abstract: The present invention provides a partially or whole flat synthetic fiber which is suitably used for preparing a high strength non-woven fabric even if the basis weight is very small, as well as a non-woven fabric prepared using such flat synthetic fibers. According to the present invention, a flat polybenzazole fiber such as PBO fiber is provided which has a flattened portion having a degree of flatness defined by the ratio of the long diameter/the short diameter of the cross section of the fiber being 2 or higher and having a short diameter being 7 &mgr;m or less. Also, a partially flat synthetic fiber is provided which has a flattened portion along the longitudinal direction of the fiber, wherein the ratio of Wmax (the maximum fiber width)/Wmin (narrowest fiber width) is 2 or higher or wherein the ratio of Wmax (the maximum fiber width)/Wav (average fiber width) is 1.5 or higher.Type: GrantFiled: November 30, 2001Date of Patent: November 26, 2002Assignee: Oji Paper Co., Ltd.Inventors: Tomonari Deguchi, Tomoyuki Terao, Chitose Yoshimura
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Patent number: 6482511Abstract: A polymer monofilament, which includes up to five percent by weight of at least one radiation-sensitive, mark-forming additive, said weight percentage based on the total weight of the polymer and additive only, is marked with a laser. The laser-marked monofilament may be used as a bristle for a brush such as a toothbrush or a paint brush.Type: GrantFiled: August 2, 2000Date of Patent: November 19, 2002Assignee: E.I. du Pont de Nemours & CompanyInventor: Maria Eugenia Martinez Antonio
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Publication number: 20020168521Abstract: A mat of mineral fibers has a random or quasi-random fiber orientation. The fibers have diameters which, for the great majority of them, are 2.5 to 4.5 micrometers, and a length of 2 to 15 cm. Its density is less than 40 kg/m3. Its resistance to compression, for a crushing of 10%, is equal to at least 0.5 kN/m2. The fineness of the fibers and their random distribution imparts to the mat an exceptional lightness and an excellent flexibility, making possible the perfect application of the mat on cylindrical surfaces.Type: ApplicationFiled: October 18, 1999Publication date: November 14, 2002Inventors: PAOLO BARACCHINI, JEAN-PIERRE VULLIEME
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Patent number: 6479143Abstract: To provide the heat-meltable fluorine-containing resin fiber having excellent intermingling property and various materials for fiber products obtained therefrom. The heat-meltable fluorine-containing resin such as ETFE having a branched structure is used solely or mixed to other fiber such as an electrically conductive fiber to be formed into a non-woven fabric.Type: GrantFiled: July 20, 2000Date of Patent: November 12, 2002Assignee: Daikin Industries, Ltd.Inventors: Shinji Tamaru, Katsutoshi Yamamoto, Jun Asano
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Publication number: 20020161163Abstract: Disclosed is a member of nylon 12 having a relative viscosity of from 1.9 to 3.5 when measured in 98% sulfuric acid at a concentration of 10 g/dm3 and at 25° C. and a melt flow rate of 0.1 g/10 min. or more when measured at 235° C.Type: ApplicationFiled: August 7, 2001Publication date: October 31, 2002Applicant: Ube Industries, Ltd.Inventors: Noriyuki Isobe, Tetsuji Hirano, Kouichiro Kurachi, Nobuhiro Ogawa
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Patent number: 6468655Abstract: The present invention discloses a polyester fiber having a birefringence of 0.025 or more, comprising at least 90% by weight of a poly (trimethylene terephthalate), on which a finishing agent composed essentially of (1) an aliphatic hydrocarbon ester having a molecular weight of 300 to 800 and/or a mineral oil having a Redwood viscosity at 30° C. of 40 to 500 seconds, (2) a polyether having a structure containing an ethylene oxide unit and a propylene oxide unit, (3) a nonionic surfactant, and (4) an ionic surfactant in a specific proportion is applied.Type: GrantFiled: July 28, 2000Date of Patent: October 22, 2002Assignee: Asahi Kasei Kabushiki KaishaInventors: Jinichiro Kato, Katsuhiro Fujimoto
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Patent number: 6469130Abstract: A nonwoven web and method of preparing a novel nonwoven web of synthetic fiber are disclosed. An aqueous solution amide crosslinked synthetic precursor polymer is extruded under defined conditions through a plurality of die orifices to form a plurality of threadlines. The threadlines are attenuated with a defined primary gaseous source to form fiber under conditions of controlled macro scale turbulence and under conditions sufficient to permit the viscosity of each threadline, as it leaves a die orifice and for a distance of no more than about 8 cm, to increase incrementally with increasing distance from the die, while substantially maintaining uniformity of viscosity in the radial direction, at a rate sufficient to provide fiber having,the desired attenuation and mean fiber diameter without significant fiber breakage. The attenuated threadlines are dried with a defined secondary gaseous source. The resulting fibers are deposited randomly on a moving foraminous surface to form a substantially uniform web.Type: GrantFiled: July 26, 2000Date of Patent: October 22, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Jian Qin, Yong Li, Wendy Lynn Van Dyke, Anthony John Wisneski, Palani Raj Ramaswami Wallajapet, Hannong Rhim
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Patent number: 6468652Abstract: An improved polyurethane-urea elastic fiber is obtained by incorporating a specific urea compound prepared by reacting the following compounds together: (a) a nitrogen-containing compound having both at least one bifunctional amine group selected from a group consisting of a primary amine group and a secondary amine group and at least one nitrogen-containing group selected from a group consisting of a tertiary nitrogen group and a heterocyclic nitrogen group; (b) an organic diisocyanate; and (c) at least one compound selected from the group consisting of a mono- or di-alkylmonoamine, an alkylmonoalcohol and an organic monoisocyanate. With the incorporation of the specific urea compound, the polyurethane-urea elastic fiber which can be fast dyed exhibits enhanced thermosettability and increased elastic functions can be produced through a stabilized spinning process.Type: GrantFiled: September 18, 2001Date of Patent: October 22, 2002Assignee: Asahi Kasei Kabushiki KaishaInventors: Keisuke Tsuru, Masanori Doi
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Publication number: 20020149131Abstract: A nonwoven web and method of preparing a novel nonwoven web of synthetic fiber are disclosed. An aqueous solution amide crosslinked synthetic precursor polymer is extruded under defined conditions through a plurality of die orifices to form a plurality of threadlines. The threadlines are attenuated with a defined primary gaseous source to form fiber under conditions of controlled macro scale turbulence and under conditions sufficient to permit the viscosity of each threadline, as it leaves a die orifice and for a distance of no more than about 8 cm, to increase incrementally with increasing distance from the die, while substantially maintaining uniformity of viscosity in the radial direction, at a rate sufficient to provide fiber having the desired attenuation and mean fiber diameter without significant fiber breakage. The attenuated threadlines are dried with a defined secondary gaseous source. The resulting fibers are deposited randomly on a moving foraminous surface to form a substantially uniform web.Type: ApplicationFiled: March 4, 2002Publication date: October 17, 2002Inventors: Jian Oin, Yong Li, Wendy Lynn Van Dyke, Anthony John Wisneski, Palani Raj Ramaswami Wallajapet, Hannong Rhim
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Patent number: 6465536Abstract: Superabsorbent fiber and film compositions comprising partially acidified, hydrolyzed, internally plasticized, crosslinked, superabsorbing fibers or film derived from polysuccinimide and processes for preparing same.Type: GrantFiled: August 2, 2001Date of Patent: October 15, 2002Assignee: Solutia, Inc.Inventors: Yueting Chou, Timothy Paul Feast, Jingen Zhang, David J. Sikora
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Patent number: 6458726Abstract: Process of producing skin-core fibers and the resulting fibers and nonwoven materials and articles wherein the fibers are composed of a polymer blend of a polyolefin and polymeric bond curve enhancing agents, such as ethylene vinyl acetate polymers.Type: GrantFiled: July 15, 1999Date of Patent: October 1, 2002Assignee: Fiberco, Inc.Inventors: James H. Harrington, Randall E. Kozulla, John F. L. Newport, Edward J. Engle, Elizabeth L. Fahey, Walter J. Freeman, Rakesh K. Gupta, Carl J. Wust
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Patent number: 6451717Abstract: The present invention comprises an aqueous emulsion for imparting oil and water repellency to textiles prepared by polymerizing a mixture of monomers (a), (b) and (c) as follows: (a) 70-90% polymer chain units derived from a mixture of monomers of the formula: Rf—Q—A—C(O)—C(R)═CH2 wherein Rf is a straight or branched-chain perfluoroalkyl group containing from 2 to about 20 carbon atoms; R is H or CH3; A is O, S, or N(R′); Q is alkylene of 1 to 15 carbon atoms, hydroxyalkylene of 3 to 15 carbon atoms, —(CnH2n)(OCqH2q)m—, —SO2—NR′(CnH2n)—, or —CONR′(CnH2n)—, wherein R′ is H or alkyl of 1 to about 4 carbon atoms, n is 1 to about 15, q is 2 to about 4, and m is 1 to about 15; (b) 5-25% monomer chain units derived from a long-chain alkyl (meth)acrylate of the formula: R″—O—C(O)—C(R)═CH2 wherein R″ is an alkyl group of about 12 to about 24 carbons and R is H or CH3; (cType: GrantFiled: December 14, 1999Date of Patent: September 17, 2002Assignee: E. I. du Pont de Nemours and CompanyInventors: John J. Fitzgerald, Melissa Ann Sherman
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Patent number: 6451429Abstract: The present invention is directed to a novel process of making N-isopropyl acrylamide (NiPAm) polymers based upon the reaction of poly(acrylic acid) and N-isopropylamine. The disclosed method of the present invention uses polyacrylic acid as a starting material to synthesize NiPAm polymers. In one embodiment, the present invention discloses a condensation reaction of an intermediate salt to form homopolymers, copolymers and terpolymers of N-isopropyl acrylamide (NiPAm) with acrylic acid and/or alkyl acrylates in a molten state, which is adaptable to a continuous reactive extrusion process. Binder compositions, water-dispersible products and thermoformable articles containing the NiPAm polymers are also disclosed.Type: GrantFiled: May 18, 2001Date of Patent: September 17, 2002Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Pavneet Singh Mumick, Yihua Chang, James Hongxue Wang
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Publication number: 20020122939Abstract: A hydrophobic polymer fiber having a cationically charged coating thereon, in which the coating includes a functionalized cationic polymer, such as an epichlorohydrin-functionalized polyamine or an epichlorohydrin-functionalized polyamido-amine, which has been crosslinked by heat. The present invention also provides a fibrous filter which includes hydrophobic polymer fibers having the foregoing cationically charged coating thereon. The present invention further provides a method of preparing a fibrous filter.Type: ApplicationFiled: January 18, 2002Publication date: September 5, 2002Applicant: Kimberly-Clark Worldwide, Inc.Inventors: Ning Wei, Robert John Lyng, Monica Graciela Varriale
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Patent number: 6440558Abstract: A process and apparatus are provided for the manufacture of a composite fibrous strand comprising glass fibers. Glass fibers and an additive fibrous material (e.g., thermoplastic polymeric fibers) are each introduced separately into a substantially rotationally symmetric zone that is closed circumferentially except for a longitudinal introduction locale. The glass fibers and the fibers of the additive fibrous material are subjected to a vortex to form a homogeneous composite fibrous strand. Good admixture of the fibrous components is made possible thereby facilitating the ultimate production of composite articles wherein the glass fibers are disposed as reinforcement in a highly uniform manner. Such homogeneity and uniformity provides improved mechanical properties to the end user.Type: GrantFiled: March 23, 2001Date of Patent: August 27, 2002Assignee: Schuller GmbHInventors: Michaela Klaus, Reinhart Dosch, Hans Georg Mann
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Patent number: 6436533Abstract: The present invention relates to melt spun fibers prepared from blends of poly(tetrafluoroethylene) and poly(tetrafluoroethylene-co-perfluoro-alkylvinyl ether).Type: GrantFiled: June 28, 2001Date of Patent: August 20, 2002Assignee: E. I. du Pont de Nemours and CompanyInventors: Glenn William Heffner, William Cheng Uy, Martin Gerald Wagner
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Patent number: 6436855Abstract: A hydrophilic fiber comprising a thermoplastic resin, wherein 0.1-1.5% by weight of a fiber-finishing agent adheres to the fiber, the fiber-finishing agent containing 50-80% by weight of component A consisting of polyoxyethylene alkyl ether represented by the following general formula (1), 10-40% by weight of component B consisting of at least one quaternary ammonium phosphate salt selected from a group of salts represented by following general formulas (2) and (3), and 3-20% by weight of component C consisting of polyorganosiloxane represented by the following general formula (4).Type: GrantFiled: September 11, 2000Date of Patent: August 20, 2002Assignee: Chisso CorporationInventors: Masuo Iwata, Yoshihiro Nakai
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Patent number: 6433093Abstract: A fluoropolymer article containing functionalized fluoropolymer is reinforced with fibrous liquid-crystal polymer.Type: GrantFiled: December 13, 2000Date of Patent: August 13, 2002Assignee: DuPont-Mitsui Flourochemicals Co. Ltd.Inventors: Jeong C Lee, Shosaku Kondo, Hajime Sato
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Patent number: 6428891Abstract: This invention relates to an acrylonitrile-based precursor fiber for carbon fiber which is prepared from an acrylonitrile-based copolymer containing 96.0 to 98.5% by weight of acrylonitrile units, and which is characterized by a tensile strength of not less than 7.0 cN/dtex, an elastic modulus in tension of not less than 130 cN/dtex, an iodine adsorption of not greater than 0.5% by weight based on the weight of the fiber, a degree of crystal orientation (&pgr;) of not less than 90% as determined by wide-angle X-ray analysis, and a degree of variation in tow fineness of not greater than 1.0%. This precursor fiber has a high strength, a high elastic modulus, a high degree of denseness, a high degree of orientation, and a low degree of variation in tow fineness, and can hence be used to form a high-quality carbon fiber inexpensively by oxidation for a shorter period of time.Type: GrantFiled: January 22, 2001Date of Patent: August 6, 2002Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Takahiro Okuya, Mitsuo Hamada, Yoshitaka Kageyama, Takeaki Amakawa
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Patent number: 6426142Abstract: Yarns having a spin finish composition thereon comprising at least about 10 percent by weight based on the spin finish composition of components (a) and (b) having the formula R1(CO)x—O—(CH(R2)—CH2—O)y—(CO)zR3, wherein each of R1 and R3 is selected from the group consisting of hydrogen or an allyl group having from one to 22 carbon atoms or an alkylene hydroxy group having from one to 22 carbon atoms, x is zero or one, R2 may vary within component (a) or component (b) and is selected from the group consisting of hydrogen or an alkyl group having from one to four carbon atoms, y is zero, or fiom one to 25, and z is zero or one, in component (a), x and z are equal to zero and the average molecular weight of component (a) is less than or equal to 1,900 and if R2 varies, component (a) is a random copolymer; and in component (b), at least x or z is equal to one or component (b) is a complex polyoxyethylene glyceride-containing compound having greater than 10 polyoxyethylene units; (c)Type: GrantFiled: October 15, 1999Date of Patent: July 30, 2002Assignee: AlliedSignal Inc.Inventor: Ralf Klein
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Patent number: 6423024Abstract: A device for removing toxins from blood or plasma comprising a cartridge containing a polymeric resin having a coating thereon which renders the resin blood compatible. The resin comprises divinylbenzene monomer which has a porosity, pore size, and surface area suitable for absorption of unhealthy components of blood, such as &bgr;-2-microglobulin.Type: GrantFiled: March 8, 2002Date of Patent: July 23, 2002Assignee: The Dow Chemical CompanyInventors: Robert M. Strom, Daniel J. Murray
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Patent number: 6423817Abstract: A process for preparing inherently light- and heat-stabilized polyamides comprises polymerizing in the presence of at least one triacetonediamine compound of the formula where R is hydrogen or hydrocarbyl having from 1 to 20 carbon atoms, preferably alkyl having from 1 to 18 carbon atoms, or benzyl.Type: GrantFiled: December 31, 1996Date of Patent: July 23, 2002Assignee: BASF AktiengesellschaftInventors: Klaus Weinerth, Karlheinz Mell, Paul Matthies, Ludwig Beer