Abstract: A functionalized silica product includes particles of a hydrophobated silica having a coating of a polymer. A ratio of the hydrophobated silica to the polymer is from about 0.3/1 to about 100/1. The functionalized silica product may be in the form of a friable crumb or a powder, or in the form of a bale, that may be mixed into an elastomer formulation for a rubber article, such as a tire component.

Abstract: A process to increase the fluidity of metal powders by surface modification with alkylsilane reagents. This invention generally discloses that the most efficient process results from treatment with methyltrichlorosilane in hexane. In particular, the fluidity of aluminum powders having mean diameters smaller than 10 micrometers was considerably improved by the process of embodiments of the invention.

Abstract: Hydrophobic silica particles are produced by reacting them with a hydrosiloxane agent.

Abstract: Provided is a resin blend including a first resin and a second resin, the second resin having a hydrophobic functional group in a side chain and having a surface energy difference of 0.1 to 20 mN/m from the first resin at 25° C., the resin blend being capable of forming a layer separation structure. Also, provided are a pellet, a method for preparing the same, and a resin molding article having a specific layer separation structure. The resin blend may not only improve mechanical properties and surface hardness of the molding article but also shorten process time, increase productivity and reduce production cost by omitting an additional surface coating step.

Abstract: A metal-containing particle aggregate of an embodiment of the present invention includes a plurality of core-shell particles. Each of the core-shell particles includes: a core portion that contains at least one magnetic metal element selected from the first group consisting of Fe, Co, and Ni, and at least one metal element selected from the second group consisting of Mg, Al, Si, Ca, Zr, Ti, Hf, Zn, Mn, rare-earth elements, Ba, and Sr; and a shell layer that includes a carbon-containing material layer and an oxide layer that covers at least part of the core portion and includes at least one metal element that belongs to the second group and is contained in the core portion.

Abstract: Zinc oxide particles having high transparency in visible light and high shielding properties in a ultraviolet region, with surface treatment of inactivating photocatalytic activity applied thereto, and a dispersion thereof. A manufacturing method of surface treated zinc oxide particles, including: a first step of mixing a dispersion liquid with zinc oxide particles dispersed in a solvent, and silicone resin having polysiloxane bond with at least one or more silicon atoms having a silanol group (Si—OH) and/or alkoxy silyl group (Si—OR, wherein R is alkyl group); obtaining a mixed solution containing a surface treated zinc oxide particles precursor, with the silicone resin adsorbed on the surface of each zinc oxide particle and the solvent, and drying and solidifying the mixed solution by applying heat treatment thereto, to thereby manufacture a dried body; and a second step of pulverizing the dried body, to thereby manufacture the surface treated zinc oxide particles.

Abstract: An aluminum chelate-based latent curing agent having excellent latency and thermal response includes a latent curing agent in which an aluminum chelating agent is retained in a porous resin obtained by interfacial polymerization of a polyfunctional isocyanate compound, and an enzyme-treated gelatin film coating such latent curing agent. This microcapsule-type latent curing agent can be produced by dissolving an aluminum chelating agent and a polyfunctional isocyanate compound in a volatile organic solvent, charging the obtained solution into a gelatin-containing aqueous phase, carrying out interfacial polymerization by heating and stirring, and subjecting the gelatin to an enzyme treatment by adding an enzyme to the obtained polymerization reaction mixture.

Abstract: The present invention provides a process for making silica-filled rubber masterbatch using silica hydrophobated with a trimethoxy silane coupling agent that is soluble in an alcohol-water solution containing at least about 70 wt % water. One embodiment uses a mixture of trimethoxy silanes, one or more of which react with rubber to bond the silica to the rubber, and one or more of which do not react with rubber, but do hydrophobate the silica. Hydrophobated silica is mixed with latex polymer and incorporated into rubber during coagulation of the latex, which is preferably coagulated with calcium chloride. The present invention further provides a process for making the trimethoxy silane coupling agents. Preferred trimethoxy silane coupling agents include bis-(3-trimethoxysilylpropyl)-disulfide and bis-(3-trimethoxysilylpropyl)-tetrasulfide.

Abstract: The present invention relates to a nano-graphite plate structure with N graphene layers stacked together, where N is 30 to 300. The nanometer nano-graphite structure has a tap density of 0.1 g/cm3 to 0.01 cm3, a thickness of 10 nm to 100 nm, and a lateral dimension of 1 ?m to 100 ?m. The ratio of the lateral dimension to the thickness is between 10 and 10,000. The oxygen content is less than 3 wt %, and the carbon content is larger than 95 wt %. The nano-graphite plate structure has both the excellent features of the graphene and the original advantages of easy processability of the natural graphite so as to be broadly used in various application fields.

Abstract: The present invention provides a surface-covered inorganic powder having novel physical properties. The surface-covered inorganic powder is an inorganic powder covered with a monolayer formed by at least one structural unit represented by formula (I): (wherein R1 represents an alkyl group having 1 to 30 carbon atoms and optionally having a substituent, X1 and X2 each independently represent a hydroxyl group, or an OR2 or O—Si bond, and . represents a binding site to an atom on the inorganic powder side), wherein the monolayer is at least partially crystalline.

Abstract: Methods of making a fiber-reinforced composite article are described. The methods may include providing fibers to an article template, where the fibers have been treated with a coupling-initiator compound. They may further include providing a pre-polymerized mixture that includes a monomer and a catalyst to the article template. The combination of the fibers and the pre-polymerized mixture may be heated to a polymerization temperature where the monomers polymerize around the fibers and form at least a portion of the composite article. The article may then be removed from the article template. Examples of the fiber-reinforced composite articles may include wind turbine blades for electric power generation.

Abstract: The present invention is directed to a process for producing treated filler including (a) treating a slurry of untreated filler which has not been previously dried, with a treating composition including an organosilane material of specified structure (I); and (b) drying the treated filler slurry. The present invention also is directed to treated filler prepared by the process, as well as rubber compounding compositions and tires including the treated filler.

Abstract: Novel material for chromatographic separations, processes for its preparation, and separations devices containing the chromatographic material. In particular, the disclosure describes porous inorganic/organic hybrid particles having a chromatographically-enhancing pore geometry, which desirably may be surface modified, and that offer more efficient chromatographic separations than that known in the art.

Abstract: A process for making a silica-polyolefin composite. The process has the steps of (a) reacting silica particles and an alkyl halosilane in the presence of a solvent and a catalyst to form silane-functionalized silica particles and (b) reacting the silane-functionalized silica particles with a vinyl-terminated polyolefin. There are other processes for making a silica-polyolefin composites. There are other processes for making metal phosphate-polyolefin composites.

Abstract: Superparmagnetic acid-functionalized nanoparticle catalysts are provided along with methods of using the same to protonate an oxygen atom of a carbon-oxygen bond. Particularly, the catalysts comprise a nanoparticle having a ferromagentic core surrounded by a metal oxide shell. The nanoparticle is at least partially coated with an acid-functionalized siloxane compound. The acid-functionalized nanoparticles may be used to catalyze any number of reactions that can be catalyzed in the presence of protons. The ferromagnetic core permits the nanoparticle catalyst material to be separated from the reaction medium through application of a magnetic field and reused.

Abstract: A coating containing pigment particles and a polymer matrix is provided. The coating contains pigment particles that have a scattering coefficient with a linear or quasi-linear relationship to the pigment volume concentration of those pigment particles. The coating has improved hiding and is useful as a protective coating or an aesthetic coating on an underlying substrate. Also provided are compositions useful for preparing the coating, including covalently bonded composite particles and aqueous dispersions containing composite particles. The composite particles each contain a pigment particle with a plurality of polymer particles attached by adsorption on the outer surface of the pigment particle or by covalent bonding to the pigment particle through a coupling agent. Methods to prepare the composite particles and coating compositions containing the composite particles are also provided.

Abstract: Composite particles and a method of forming composite particles are described. The composite particles comprise at least one inorganic nanoparticle covalently bound to at least one inorganic microparticle with a linking compound. Lubricant compositions and sprayable dispersion compositions comprising composite particles are also described.

Abstract: A functionalized silica product includes particles of a hydrophobated silica having a thin coating of an emulsion polymer. A ratio of the hydrophobated silica to the emulsion polymer is from about 4/1 to about 50/1. The functionalized silica product is in the form of a friable crumb or a powder that may be mixed into a elastomer formulation for a rubber article, such as a tire component.

Abstract: Exemplary embodiments provide materials and methods for a nanocomposite material and a fuser member containing the nanocomposite material in a fusing system, wherein the nanocomposite material can contain a plurality of carbon nanotubes (CNTs) and a plurality of inorganic nano-fillers (INFs) disposed in a polymer matrix to provide the nanocomposite material with desirable properties.

Abstract: Roofing granules include a core having an average ultraviolet transmission of greater than sixty percent and an average near infrared reflectance of greater than sixty percent and a UV coating layer on the exterior surface. The coating provides UV opacity, while the core provides near infrared reflectance.

Abstract: A composite magnet wire includes, in an exemplary embodiment, a metal wire and a coating applied to an outer surface of the wire. The coating includes a polyimide polymer and a plurality of alumina nano particles dispersed in the polyimide polymer. The alumina nano particles have a surface treatment applied to outer surfaces of the alumina nano particles, where the surface treatment includes a phenyl-silane. The composite magnet wire has a thermal degradation temperature index of at least 300° C. as calculated in accordance with ASTM E1641 or D2307.

Abstract: The invention relates to a material composed of nanoparticles essentially comprising a spin transition compound. The compound corresponds to the formula [ ( Fe 1 - y ? M y ? L 3 ) w ? L 3 ] [ X 2 x ? ( 1 - z x ? ) ? Y 2 ? ? z x ? ] w in which L represents a 1,2,4-triazole ligand carrying an R substituent on the nitrogen in the 4 position; X is an anion having the valency x, 1?x?2; Y is an anion other than X having the valency x?, 1?x??2; R is an alkyl group or an R1R2N— group in which R1 and R2 represent, each independently of the other, H or an alkyl radical; M is a metal having a 3d4, 3d5, 3d6 or 3d7 configuration, other than Fe; 0?y?1; 0?z?2; 3?w?1500. Applications: thermochromic pigment, data storage, optical limiters, contrast agent.

Abstract: Modified zirconia fine particles which are stable in an acidic region as well as in an alkaline region, and which may be readily adjusted in refractive index in a predetermined range are disclosed. Also disclosed is a substrate with a hard coat film excellent in adhesiveness with the substrate, abrasion resistance, scratch strength, pencil hardness and the like without interference fringes and a coating solution which may form the hard coat film. The substrate with a hard coat film is composed of composite oxide particles formed on at least one surface of the substrate and a matrix component, wherein the composite oxide particles are composite oxide particles having a core-shell structure composed of a core formed from zirconium oxide and a shell formed from antimony pentoxide and/or silica.

Abstract: Coated particles comprise a core of fumed or precipitated inorganic metal oxide having a surface area of about 50 to about 500 square meters per gram and a shell consisting of an array of fluoroalkyl molecular chains at a density of at least 1 chain per square nanometer, joined to the core by covalent chemical bonds and with a total organic content of at least 9.9 percent by weight. These particles are formed by the chemical attachment of fluoroalkyl-alkylsilanes after exposure to an alkylamine and followed by an extraction to remove any organic material not covalently bound. The dense packing of molecular chains in the fluoroalkyl shell combined with a mesoporous structure imparts a very low surface energy, a very high specific surface area, and surface texture over a wide range of length scales. Such features are highly desirable for the creation of, for example, superhydrophobic and superoleophobic surfaces, separation media, and release films.

Abstract: The present invention relates to particles which have been modified by a modifier and a dispersion medium comprising the modified particles.

Abstract: A particle is formed from a dispersion and includes a compound and a metal disposed on the particle. The compound has the chemical formula R—Si—H. In this formula, R is an organic or inorganic moiety. The particle is also included in a corresponding dispersion. The particle is formed from a method that includes the step of forming the dispersion. The method also includes the step of disposing the metal on the particle.

Abstract: A tire dressing composition is provided that includes at least one silicone fluid having a viscosity of between 40 and 500,000 centiStokes at room temperature. A fluorinated acrylate polymer is provided in the composition to limit the amount of streaking in a coating formed from the composition upon application to a tire surface. The coating is formed through the evaporation of a solvent in the composition containing the at least one silicone fluid and the fluorinated acrylate polymer. A process is provided for dressing a tire having a previous silicone coating thereon, the process including applying the tire dressing composition and allowing the solvent to evaporate from the composition to form a tire dressing coating. The coating producing an initial gloss of greater than 110 units. A gloss of greater than 110 units is maintained for at least two weeks subsequent to the application under normal vehicle operation conditions.

Abstract: A silicone rubber composition comprising (A) an organopolysiloxane composition of the organic peroxide cure or addition reaction cure type, (B) a normally solid organic compound having at least two ester bonds per molecule, and (C) particulate aluminum hydroxide having an average particle size of up to 20 ?m is suited for use as high-voltage electric insulator since it maintains insulating properties for a long term in outdoor service and has acid resistance and a long lifetime even in polluted areas.

Abstract: Provided is a fluororesin film comprising a fluororesin film body which contains hydrophobized silicon oxide-coated metal oxide particles and a fluororesin. The fluororesin film also contains a coating film in direct contact with the fluororesin film body and made of a coating film-forming composition containing at least one resin selected from the group consisting of a polyester, acryl polyol, acryl resin, acryl urethane resin, acryl silicone resin, vinyl acetate resin and a fluororesin, formed on one side of the fluororesin film body.

Abstract: Exemplary embodiments are directed to a contact material for a vacuum interrupter, and method of making the contact material. In achieving precise control of the Si concentration of Cu/Cr contact materials, the exemplary contact material has a chromium content which is above 10 wt. % and that the material is doped with silicon below 0.2 wt. % (2000 ppm Si) and the remainder is copper Cu.

Abstract: Solar-reflective roofing granules having deep-tone colors are formed by coating base mineral particles with a coating composition including an infrared-reflective pigment. Color is provided by a colored infrared pigment, a light-interference platelet pigment, or a metal oxide.

Abstract: The present invention relates to a conductive paste in which fine metal particles are dispersed into a chemical adsorption liquid produced from a mixture of at least an alkoxysilane compound, a silanol condensation catalyst, and a nonaqueous organic solvent to form an organic thin film comprising molecules covalently bound to the surface of the fine metal particle by having the surface of the fine metal particle react with the alkoxysilane compound, so that fine metal particles that are given a reactive function to the surface are produced while almost maintaining the original conductivity of the fine metal particles, and further the particles are pasted with an organic solvent.

Abstract: The invention provides a treated powder having improved loose bulk density comprising a silanized inorganic powder treated with a long chain fatty acid or salts thereof, wherein the amount of the long chain fatty acid is about 0.25% to about 2 wt %, based on the total weight of the treated powder.

Abstract: An antireflection laminate for use mainly in displays such as LCDs and PDPs, which has a refractive index layer that has, while comprising hollow and solid particles, excellent abrasion resistance, a refractive index of 1.45 or less, and low reflectivity is disclosed. The refractive index layer is obtained by irradiating a refractive index layer forming composition with ionizing radiation, the composition including an ionizing radiation curable resin, a crosslinkable hollow particle having an inside that is porous or hollow and is covered with an outer shell layer and having a surface that is modified with a crosslinkable group(s), and a crosslinkable solid particle having an inside that is neither porous nor hollow and having a surface that is modified with a crosslinkable group(s). The crosslinkable groups comprise an ionizing radiation curable group each and have an identical structure or a very similar structure.

Abstract: A hydrophobic precipitated silica having a BET of less than 110 m2/g, a CTAB of less than 150 m2/g, a BET/CTAB ratio of less than 3, a carbon content of greater than 3.1%, a pH of 9.7 to 10.5, a DBP of less than 230 g/(100 g), and a methanol wettability of more than 50%. The hydrophobic precipitated silica is used in compositions including defoamers, silicone rubber and HTV crosslinkable silicone rubber compositions. The hydrophobic precipitated silica is also useful as a flow assistant and carrier or anti-blocking agent.

Abstract: The invention provides vulcanizable rubber compound having improved tensile mechanical and dynamic viscoelastic properties. The compounds are formed by mixing an elastomer, containing unsaturated carbon-carbon bonds in its molecular structure, with a reinforcing inorganic filler silica in the presence of an alkyl alkoxysilane and a non-sulfur coupling agent that binds to the rubber backbone with an “ene” linkage or a 1,3 dipolar addition linkage. In particular, the coupling agent and the alkyl alkoxysilane are present in the compound in a weight ratio of about 0.0001:1 to about 1:1.

Abstract: Compositions containing a nanostructure, preferably a nanocrystal, are provided. The nanostructures have ligands bound to the surface. Such ligands are preferably siloxane containing ligands having at least one —COON group, although ligands having various ?P?O groups are also contemplated. The nanostructures can be embedded into a polymer such as a silicone polymer.

Abstract: Fluoroalkylsilane-treated metal oxide particles and a fluoroelastomeric binder are dispersed in a fluorinated solvent with a low boiling point and applied to a substrate via spray deposition. The spray deposition process rapidly produces a conformal coating that features low surface energy and surface topography with a large range of characteristic length scales and re-entrant curvature, thereby imparting superoleophobicity. The degree of superoleophobicity is readily adjusted by means of altering the ratio of particles to binder. The choice of particle and binder result in coatings with thermal stability for thousands of hours at temperatures up to 200 degrees Celsius as well as desirable mechanical characteristics.

Abstract: Provided are a coated metal pigment which can satisfy both the coating stability in use as an aqueous coating, i.e., water resistance, and the chemical resistance of coating films produced by application thereof at practically satisfactory levels; a method for producing the same; and an aqueous coating containing the same. The invention relates to a coated metal pigment including a metal pigment and a composite coating layer, wherein the composite coating layer includes an adhesion layer which is disposed on the surface of the metal pigment either in contact with the metal pigment or at an interposition of another layer and contains polysiloxane and/or silica, and a resin layer which is disposed on the surface of the adhesion layer either in contact with the adhesion layer or at an interposition of another layer.

Abstract: A polymer-coated particulate material having: a particulate substrate; and an applied compound, wherein the applied compound coats at least 50% of the surface of the particulate substrate, and wherein, at the time of application, the applied compound includes a dispersion including: a thermoplastic polymer; and a stabilizing compound. In another aspect, embodiments disclosed herein relate to a method of forming a polymer-coated particulate material, the method including the steps of: incorporating a particulate substrate and a dispersion, the dispersion comprising: a thermoplastic polymer; a stabilizing compound; and a dispersion medium selected from the group consisting of an organic solvent, water, and combinations thereof; removing at least a portion of the dispersion medium.

Abstract: A Raman-active nanoparticle is provided that includes a dish-shape plasmonically active metal base, and a plasmonically active metal pillar disposed on the plasmonically active metal base, where the plasmonically active metal pillar is disposed within the dish-shape plasmonically active metal base and normal to a bottom of the dish-shape plasmonically active metal base, where a circular gap is disposed between the dish-shape plasmonically active metal pillar and inner walls of the dish-shape plasmonically active metal base. In one embodiment a Raman-active nanoparticle is provided that includes a dish-shape base having a dielectric material, an electrically conductive layer disposed on the inner surface of the dish-shape base, and an electrically conductive pillar disposed on the conductive layer, and within the dish-shape and perpendicular to a bottom of the dish-shape base, where a circular gap is disposed between the conductive pillar and inner walls of the dish-shape base.

Abstract: Microspheres, populations of microspheres, and methods for forming microspheres are provided. One microsphere configured to exhibit fluorescent and magnetic properties includes a core microsphere and a magnetic material coupled to a surface of the core microsphere. About 50% or less of the surface of the core microsphere is covered by the magnetic material. The microsphere also includes a polymer layer surrounding the magnetic material and the core microsphere. One population of microspheres configured to exhibit fluorescent and magnetic properties includes two or more subsets of microspheres. The two or more subsets of microspheres are configured to exhibit different fluorescent and/or magnetic properties. Individual microspheres in the two or more subsets are configured as described above.

Abstract: Disclosed are a functional reinforcing filler including inorganic particles surface-modified with an alkenylsilanol obtained by hydrolyzing an alkenylalkoxysilane compound, and a method for preparing the same. Since the disclosed functional reinforcing filler has a functional group having a double bond, it has good reactivity for styrene-butadiene rubber and sulfur. Thus, when used as a functional reinforcing filler in the manufacture of rubber, it allows improvement of physical properties through adjustment of the addition amount of sulfur without additional use of the coupling agent. In addition, because of superior hydrolysis reactivity, the problem of alcohol can be solved and a rubber mixture with long scorch time can be prepared. In particular, when the functional reinforcing filler of the present invention is used in the manufacture of tires, improvement in modulus, tensile strength, rotational resistance and wet traction performance can be expected.

Abstract: Ligand compositions for use in preparing discrete coated nanostructures are provided, as well as the coated nanostructures themselves and devices incorporating same. Methods for post-deposition shell formation on a nanostructure, for reversibly modifying nanostructures, and for manipulating the electronic properties of nanostructures are also provided. The ligands and coated nanostructures of the present invention are particularly useful for close packed nanostructure compositions, which can have improved quantum confinement and/or reduced cross-talk between nanostructures. Ligands of the present invention are also useful for manipulating the electronic properties of nanostructure compositions (e.g., by modulating energy levels, creating internal bias fields, reducing charge transfer or leakage, etc.).

Abstract: A room temperature curable organopolysiloxane composition is provided. The composition comprises (I) an organopolysiloxane which is a condensation product of component (A) (an organopolysiloxane comprising R3SiO1/2 unit and SiO4/2 unit and containing 0.02 to 0.12 mol/100 g of hydroxy group bonded to the silicon atom) and component (B) (a diorganopolysiloxane raw rubber having hydroxy group on opposite ends thereof), (II) an organosilane compound having at least 2 hydrolyzable groups bonded to the silicon atom on average per molecule, and/or its partial hydrolytic condensate, (III) a solvent, and (IV) a silica nano particle having its surface modified by a branch structure. The composition is capable of providing a high strength film without incorporating reinforcement fillers, with no curing inhibition by the inorganic nano particles, and without inhibiting gas separation performance realized by the inorganic nano particles.

Abstract: Solar-reflective roofing granules having deep-tone colors are formed by coating base mineral particles with a coating composition including an infrared-reflective pigment. Color is provided by colored infrared pigment, light-interference platelet pigment, or a metal oxide.

Abstract: The invention relates to surface-modified particles, more particularly inorganic-based particles having reactive surfaces, more particularly surfaces containing silane-reactive and/or siloxane-reactive groups, preferably hydroxyl-containing surfaces and/or particles comprising or consisting of metal and/or semi-metal oxides and/or hydroxides, preferably nanoparticles, which on their surface have a polysiloxane-based modifier having more particularly been reacted on their surface with a polysiloxane-based modifier, preferably with the formation of chemical bonds, more particularly covalent bonds, and also to a method of producing these surface-modified particles.

Abstract: Multilayer expanded polypropylene resin beads that are heat moldable at low steam pressure and can provide an expanded mold with sufficient rigidity and heat resistance. The beads are formed from a polypropylene resin and a coating layer formed from a different polypropylene resin. The multilayer expanded resin beads can be molded in-mold at a steam pressure lower than the steam pressure for molding single-layer expanded beads made from the polypropylene resin which forms the core layer. The coating layer to core layer resin weight ratio in the multi-layer resin beads is not less than 0.001 and not greater than 0.040 and the expansion ratio of the expanded beads, the average value of the thickness of the coating layer of the expanded beads, calculated based on the coating weight ratio of the multi-layer resin beads, is not less than 0.1 ?m and not greater than 3.0 ?m.

Abstract: Surface-modified, pyrogenically prepared silica is prepared by subjecting the pyrogenically prepared silica, which is in the form of aggregates of primary particles having a BET surface area of 300±25 m2/g and the aggregates have an average area of 4800-6000 nm2, an average equivalent circle diameter (ECD) of 60-80 nm and an average circumference of 580-750 nm, to surface-modification in a known way. It can be used as a filler for controlling the rheology of liquid silicone rubber (LSR) systems.

Abstract: Surface-modified, pyrogenically prepared silica is prepared by subjecting the pyrogenically prepared silica, which is in the form of aggregates of primary particles and possesses a BET surface area of 150±15 m2/g, the aggregates having an average area of 12 000-20 000 nm2, an average equivalent circle diameter (ECD) of 90-120 nm and an average circumference of 1150-1700 nm, to surface-modification in a known way. It can be used as a filler for thickening liquid systems.