Next To Group Ib Metal-base Component Patents (Class 428/647)
  • Patent number: 11761109
    Abstract: A terminal material for a connector provided with a base material in which at least a surface layer is made of copper or copper alloy, a nickel-plating layer made of nickel or nickel alloy and formed on a surface of the base material, a silver-nickel alloy plating layer made of silver-nickel alloy and formed on at least a part of the nickel-plating layer, and a silver-plating layer made of silver and formed on the silver-nickel alloy plating layer; the silver-nickel alloy plating layer has a film thickness 0.05 µm or more and less than 0.50 µm and a nickel content 0.03 at% or more and 1.00 at% or less.
    Type: Grant
    Filed: January 28, 2021
    Date of Patent: September 19, 2023
    Assignee: MITSUBISHI MATERIALS CORPORATION
    Inventors: Yoshie Tarutani, Kenji Kubota, Naoki Katou
  • Patent number: 11572633
    Abstract: A tin-plated copper terminal material in which on a substrate made of copper or copper alloy, a nickel-or-nickel-alloy layer, a copper-tin alloy layer, and a tin layer are laminated in this order; in this material, the tin layer has an average thickness 0.2 ?m to 1.2 ?m inclusive; the copper-tin alloy layer is a compound alloy layer in which Cu6Sn5 is a main ingredient and part of copper in the Cu6Sn5 is substituted with nickel, and an average crystal grain size is 0.2 ?m to 1.5 ?m inclusive; part of the copper-tin alloy layer appears on a surface of the tin layer and tin solidification parts exist like islands; and the tin solidification parts have an average diameter 10 ?m to 1000 ?m inclusive in a direction along the surface of the tin layer and an area ratio to the surface of the tin layer 1% to 90% inclusive.
    Type: Grant
    Filed: March 29, 2019
    Date of Patent: February 7, 2023
    Assignee: MITSUBISHI MATERIALS CORPORATION
    Inventors: Fuyumi Mawatari, Kazunari Maki, Shinichi Funaki, Yuki Inoue, Kiyotaka Nakaya
  • Patent number: 11530490
    Abstract: In a terminal material with a silver coating film including a silver layer on a surface, a terminal and a terminal material having high reliability are easily manufactured with low cost without a heat treatment. A base material formed of copper or a copper alloy; and nickel layer, an intermediate layer, and a silver layer laminated on the base material in this order are included, the nickel layer has a thickness of 0.05 ?m to 5.00 ?m and is formed of nickel or a nickel alloy, the intermediate layer has a thickness of 0.02 ?m to 1.00 ?m and is an alloy layer containing silver (Ag) and a substance X, and the substance X includes one or more kinds of tin, bismuth, gallium, indium, and germanium.
    Type: Grant
    Filed: August 8, 2018
    Date of Patent: December 20, 2022
    Assignee: MITSUBISHI MATERIALS CORPORATION
    Inventors: Kenji Kubota, Tooru Nishimura, Takashi Tamagawa, Kiyotaka Nakaya
  • Patent number: 11527364
    Abstract: A multilayer ceramic electronic component includes multilayer ceramic electronic component bodies which each include a multilayer body and first and second outer electrodes provided on both end surfaces of the multilayer body. The multilayer ceramic electronic component also includes a first metal terminal connected to the first outer electrodes and a second metal terminal connected to the second outer electrodes. Each multilayer ceramic electronic component body includes a dimension in a lamination direction that is less than a dimension in a width direction, and is positioned so that one of the first and second side surfaces faces a mounting surface. The first and second metal terminals extend between the first and second outer electrodes of the multilayer ceramic electronic component bodies. The multilayer bodies, first and second outer electrodes, and at least portions of the first and second metal terminals are covered by a cover material.
    Type: Grant
    Filed: June 18, 2019
    Date of Patent: December 13, 2022
    Assignee: MURATA MANUFACTURING CO., LTD.
    Inventors: Retsu Tahara, Tomohiro Kageyama
  • Patent number: 11396711
    Abstract: The invention relates to a composition for electrolytic nickel plating. In order to provide an improved composition, it is proposed that it comprises one or a plurality of nickel ion sources and a mono-, di- or tri-hydroxybenzene compound, preferably a hydroquinone compound or the salts thereof or mixtures thereof.
    Type: Grant
    Filed: March 18, 2020
    Date of Patent: July 26, 2022
    Assignee: RIAG Oberflächentechnik AG
    Inventor: André Egli
  • Patent number: 11264750
    Abstract: Provided is a tin-plated copper terminal material, a terminal formed from the terminal material, and an electric-wire terminal structure using the terminal: the terminal material has a substrate of copper or a copper alloy; an intermediate zinc layer of a zinc alloy that is formed on the substrate and has a thickness of 0.10 ?m to 5.00 ?m; and a tin layer of tin or a tin alloy that is formed on the intermediate zinc layer and in which the length proportion occupied by low-angle grain boundaries is 2% to 30% with respect to the total length of all crystal grain boundaries; wherein galvanic corrosion is effectively suppressed.
    Type: Grant
    Filed: May 15, 2018
    Date of Patent: March 1, 2022
    Assignee: MITSUBISHI MATERIALS CORPORATION
    Inventors: Kenji Kubota, Yoshie Tarutani, Kiyotaka Nakaya
  • Patent number: 11255000
    Abstract: The present invention discloses a copper alloy, which includes: 5 wt % to 15 wt % of Zn, 0.2 wt % to 2.5 wt % of Sn, 0.1 wt % to 2.0 wt % of Ni, 0.01 wt % to 0.3 wt % of P, 0 to 0.3 wt % of Mg, 0 to 0.5 wt % of Fe, and a balance of Cu and inevitable impurities. Preferably, it is controlled that 1.0 wt %?Ni+Sn?3.5 wt %, the weight ratio of Ni to Sn is 0.08 to 10; the weight ratio of Ni to P is 2 to 15, Ni and P form a NiP compound in a matrix. During the crystal orientation analysis using EBSD measurement, the area in a Brass orientation {011}<211> at a derivation angle of less than 15° accounts for 10% to 25%. The yield strength 600 MPa, the electrical conductivity is ?25% IACS, and the bending machinability is excellent because the value R/t in a GW direction is ?1 and the value R/t in a BW direction is ?2.
    Type: Grant
    Filed: July 19, 2018
    Date of Patent: February 22, 2022
    Assignee: NINGBO POWERWAY ALLOY MATERIAL CO., LTD.
    Inventors: Chaoyong Yang, Jiangang Li, Ning Li, Taisheng Yang, Hongbin Zhao, Yaohua Zhou
  • Patent number: 11231067
    Abstract: A bearing member 1 is provided with a coating layer 3 on an inner circumferential surface of a shaft hole 1A into which a shaft body 2 is to be fitted. The coating layer 3 is composed of a metal base material 3A and a heat conductive material 3B that is dispersed in the base material 3A and that has a thermal conductivity relatively higher than that of the base material 3A. The heat conductive material 3B has lengths Lb and Lc in directions B and C along a surface of the coating layer 3, longer than a length La in a thickness direction A of the coating layer 3, whereby thermal conductive characteristics in the directions B and C along the inner circumferential surface of the shaft hole 1A are enhanced. Thus, heat dissipation is improved, whereby temperature rise due to sliding contact with the shaft body 2 is suppressed, and seizure resistance is improved.
    Type: Grant
    Filed: May 10, 2018
    Date of Patent: January 25, 2022
    Assignee: NISSAN MOTOR CO., LTD.
    Inventors: Hayato Hirayama, Yutaka Mabuchi, Tsuyoshi Higuchi, Takemichi Yamashita
  • Patent number: 11228127
    Abstract: Provided is an electrical contact material that can suppress an increase in contact resistance even if contact pressure with a counterpart material is small. An electrical contact material that includes a base material made of metal, a metal layer provided on a surface of the base material, and an oxide layer provided on a surface of the metal layer. The metal layer is made of metal that contains zinc, copper, and tin, the oxide layer is made of an oxide that contains zinc, copper, and tin, and beneath the oxide layer, a ratio of the atomic concentration of copper to the atomic concentration of tin is less than 1.4.
    Type: Grant
    Filed: June 10, 2020
    Date of Patent: January 18, 2022
    Assignees: AUTONETWORKS TECHNOLOGIES, LTD., SUMITOMO WIRING SYSTEMS, LTD., SUMITOMO ELECTRIC INDUSTRIES, LTD.
    Inventors: Yoshimasa Shirai, Yasushi Saito, Kingo Furukawa, Mitsuhiro Kumondai, Akihisa Hosoe
  • Patent number: 11211729
    Abstract: A terminal material for a connector terminal, using a copper or copper alloy substrate is crimped to an end of wire formed from an aluminum wire material; and a terminal using this terminal material: a zinc layer 4 that is formed of zinc or a zinc alloy and a tin layer 5 that is formed of tin or a tin alloy are sequentially laminated in this order on a substrate 2 that is formed of copper or a copper alloy: with respect to the zinc layer and the tin layer, the adhesion amount of tin contained in the whole layers is from 0.5 mg/cm2 to 7.0 mg/cm2 (inclusive) and the adhesion amount of zinc contained in the whole layers is from 0.07 mg/cm2 to 2.0 mg/cm2 (inclusive), and the content percentage of zinc in the vicinity of the surface is from 0.2% by mass to 10.0% by mass (inclusive).
    Type: Grant
    Filed: January 29, 2018
    Date of Patent: December 28, 2021
    Assignee: MITSUBISHI MATERIALS CORPORATION
    Inventors: Kenji Kubota, Yoshie Tarutani, Kiyotaka Nakaya
  • Patent number: 11088472
    Abstract: On a base member made of copper or a copper alloy, a zinc-nickel alloy layer including zinc and nickel, and a tin layer made of tin alloy are laminated in this order: the zinc-nickel alloy layer has a thickness of 0.1-5 ?m inclusive and has a nickel content of 5-50 mass % inclusive, the tin layer has a zinc concentration of 0.6-15 mass % inclusive, and, under an oxide layer which is the outermost layer, a metal zinc layer, having a zinc concentration of 5-40 at % inclusive and a thickness of 1-10 nm inclusive in SiO2 conversion, is formed on the tin layer.
    Type: Grant
    Filed: November 24, 2016
    Date of Patent: August 10, 2021
    Assignee: MITSUBISHI MATERIALS CORPORATION
    Inventors: Kenji Kubota, Yoshie Tarutani, Kiyotaka Nakaya
  • Patent number: 11078587
    Abstract: A tin-plated product contains: a substrate 10 of copper or a copper alloy; an underlying layer 12 of nickel which is formed on the surface of the substrate 10; and an outermost layer 14 containing tin, the outermost layer 14 being formed on the surface of the underlying layer 12, the outermost layer 14 being composed of a copper-tin alloy layer 14a of a large number of crystal grains of a copper-tin alloy, tin layers 14b of tin having an average thickness of 0.01 to 0.20 micrometers, and a plurality of copper-nickel-tin alloy layers 14c of a copper-nickel-tin alloy, each of the tin layers 14b being formed in a corresponding one of recessed portions between adjacent two of the crystal grains of the copper-tin alloy on the outermost surface of the copper-tin alloy layer, the copper-nickel-tin alloy layers 14c being arranged on the side of the underlying layer 12 in the copper-tin alloy layer 14a so as to be apart from each other.
    Type: Grant
    Filed: August 23, 2016
    Date of Patent: August 3, 2021
    Assignees: Dowa Metaltech Co., Ltd., Yazaki Corporation
    Inventors: Yuta Sonoda, Hiroto Narieda, Hideki Endo, Akira Sugawara, Hirotaka Kotani, Jyun Toyoizumi, Takaya Kondo, Yuya Kishibata
  • Patent number: 10985485
    Abstract: There are provided a tin-plated product which has a zinc plating layer on the surface thereof and which has good corrosion resistance and good adhesion of the zinc plating even if the connecting portion of a terminal of the tin-plated product to an electric wire of aluminum or an aluminum alloy is not processed during press fitting such as swaging (or caulking) when the tin-plated product is used as the material of the terminal which is to be connected to the electric wire by press fitting, and a method for producing the same.
    Type: Grant
    Filed: November 21, 2017
    Date of Patent: April 20, 2021
    Assignee: DOWA METALTECH CO., LTD.
    Inventors: Hiroto Narieda, Yuta Sonoda, Tatsuhiro Doi, Takao Tomiya
  • Patent number: 10923245
    Abstract: A terminal material for connectors, which is obtained by sequentially laminating on a substrate that is formed of copper or a copper alloy, a nickel or nickel alloy layer, a copper-tin alloy layer and a tin layer in this order, and: the tin layer has an average thickness of from 0.2 ?m to 1.2 ?m (inclusive); the copper-tin alloy layer is a compound alloy layer that is mainly composed of Cu6Sn5, with some of the copper in the Cu6Sn5 being substituted by nickel, and has an average crystal grain diameter of from 0.2 ?m to 1.5 ?m (inclusive); a part of the copper-tin alloy layer is exposed from the surface of the tin layer, with the exposure area ratio being from 1% to 60% (inclusive); the nickel or nickel alloy layer has an average thickness of from 0.05 ?m to 1.0 ?m (inclusive) and an average crystal grain diameter of from 0.01 ?m to 0.5 ?m (inclusive).
    Type: Grant
    Filed: January 16, 2018
    Date of Patent: February 16, 2021
    Assignee: MITSUBISHI MATERIALS CORPORATION
    Inventors: Yuki Inoue, Kazunari Maki, Shinichi Funaki, Takashi Tamagawa, Kiyotaka Nakaya
  • Patent number: 10640880
    Abstract: Provided are a plated material having excellent abrasion resistance, electrical conductivity, sliding performance, and low friction, in which a plating layer does not undergo embrittlement properly; and a method for producing the plated material. The method includes a first step of at least partially removing a reflow tin plating layer from a metallic base material having the reflow layer on at least a part thereof and a reactive layer provided at the interface between the reflow layer and the base material; a second step of at least partially subjecting a region in which the reflow tin plating layer has been removed to a nickel plating treatment; a third step of at least partially subjecting the nickel plating layer to a silver strike plating treatment; and a fourth step of at least partially subjecting a region of the silver strike plating to a silver plating treatment.
    Type: Grant
    Filed: December 11, 2017
    Date of Patent: May 5, 2020
    Assignee: Oriental Electro Plating Corporation
    Inventor: Hiroyoshi Takahashi
  • Patent number: 10415130
    Abstract: Disclosed herein is a sheet strip including a copper alloy sheet strip, as a base material, and the surface coating layer containing a Ni layer, a Cu—Sn alloy layer and a Sn layer formed on a surface of the copper alloy sheet strip. The copper alloy sheet strip has a structure in which precipitates are dispersed in a copper alloy matrix. The Cu—Sn alloy layer is partially exposed on the outermost surface of the surface coating layer, and a surface exposed area ratio thereof is in a range of 3 to 75%. The Cu—Sn alloy layer contains 1) a ? layer, or 2) a ? phase and a ? phase, the ? phase existing between the Ni layer and the ? phase.
    Type: Grant
    Filed: February 13, 2015
    Date of Patent: September 17, 2019
    Assignee: Kobe Steel, Ltd.
    Inventors: Masahiro Tsuru, Daisuke Hashimoto
  • Patent number: 10233517
    Abstract: A copper alloy sheet strip with a surface coating layer, including: a copper alloy sheet strip, as a base material, including copper, 1.0 to 4.5% by mass of Ni and/or Co and 0.2 to 1.0% by mass of Si, based on the total amount of the copper alloy sheet strip; and a surface coating layer including a Ni layer, a Cu—Sn alloy layer and a Sn layer formed on a surface of the copper alloy sheet strip in this order. A Cu—Sn alloy layer is partially exposed on an outermost surface of the surface coating layer such that a surface exposed area ratio is from 3 to 75%. A surface roughness of the surface coating layer is 0.15 ?m or more in at least one direction, and 3.0 ?m or less in all directions.
    Type: Grant
    Filed: February 20, 2015
    Date of Patent: March 19, 2019
    Assignee: Kobe Steel, Ltd.
    Inventors: Masahiro Tsuru, Shinya Katsura
  • Patent number: 10177479
    Abstract: A terminal pair including a first terminal provided with a first contact portion and a second terminal provided with a second contact portion. The first contact portion includes a composite covering layer having a Sn—Pd based alloy phase and a Sn phase, and has a surface including the Sn—Pd based alloy phase and the Sn phase. The second contact portion includes a Cu—Sn alloy layer and a Sn layer covering part of the Cu—Sn alloy layer, and has a surface including a Cu—Sn alloy region corresponding to an exposed portion of the Cu—Sn alloy layer and a Sn region corresponding to an exposed portion of the Sn layer. A coefficient of friction for sliding movement between the first contact portion and the second contact portion is lower than a coefficient of friction for sliding movement between the two first contact portions and between the two second contact portions.
    Type: Grant
    Filed: March 25, 2015
    Date of Patent: January 8, 2019
    Assignees: AUTONETWORKS TECHNOLOGIES, LTD., SUMITOMO WIRING SYSTEMS, LTD., SUMITOMO ELECTRIC INDUSTRIES, LTD.
    Inventors: Yoshifumi Saka, Masayuki Ookubo, Hajime Watanabe
  • Patent number: 10092970
    Abstract: There is provided a titanium-copper alloy in which the adhesion strength with solder can be increased. The titanium-copper alloy comprises a base material and a plating layer provided on a surface of the base material, wherein the base material contains 1.5 to 5.0% by mass of Ti with a balance consisting of copper and unavoidable impurities, and the plating layer is selected from the group consisting of a Ni plating layer, a Co plating layer, and a Co—Ni alloy plating layer.
    Type: Grant
    Filed: December 30, 2015
    Date of Patent: October 9, 2018
    Assignee: JX Nippon Mining & Metals Corporation
    Inventor: Kenta Tsujie
  • Patent number: 10036083
    Abstract: A method of pre-placing a reaction material onto a surface of a metal workpiece substrate involves the use of oscillating wire arc welding. The method involves depositing and adhering the reaction material from a consumable electrode rod. In doing so, the reaction material can be deposited at any time before the metal workpiece substrate is ready for joining by reaction metallurgical joining, and the size and shape of the reaction material deposit can be more easily controlled.
    Type: Grant
    Filed: July 1, 2015
    Date of Patent: July 31, 2018
    Assignee: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: James G. Schroth, Thomas A. Perry, Chen Zhou
  • Patent number: 9966163
    Abstract: An electric contact material for a connector includes a base material made of a metal material; an alloy layer that is formed on the base material and made of an alloy containing at least three elements including Sn and Cu as well as at least one metal selected from Zn, Co, Ni, and Pd; and a conductive coating layer formed on the surface of the alloy layer. The alloy layer contains an intermetallic compound obtained by replacing some of the Cu atoms in Cu6Sn5 with at least one metal selected from Zn, Co, Ni, and Pd. It is preferable that the content of at least one metal selected from Zn, Co, Ni, and Pd in the alloy layer is in a range of 1 to 50 atom % when the total content of the metal and Cu is regarded as 100 atom %.
    Type: Grant
    Filed: September 10, 2014
    Date of Patent: May 8, 2018
    Assignees: AUTONETWORKS TECHNOLOGIES, LTD., SUMITOMO WIRING SYSTEMS, LTD., SUMITOMO ELECTRIC INDUSTRIES, LTD.
    Inventor: Shigeru Sawada
  • Patent number: 9790889
    Abstract: A piston for an internal combustion engine may include a surface in a region on a crankshaft side. The piston may include a thermally conductive coating disposed on the surface via thermal spraying.
    Type: Grant
    Filed: October 16, 2012
    Date of Patent: October 17, 2017
    Assignee: Mahle International GmbH
    Inventors: Christoph Beerens, Dieter Emmrich, Christoph Luven, Uwe Mohr, Reinhard Rose
  • Patent number: 9748683
    Abstract: An electroconductive material includes a Cu or Cu alloy base member, a Cu—Sn alloy coating layer, and a Sn coating layer. The Cu—Sn alloy coating layer has a Cu content of 20 to 70 atomic %, and an average thickness of 0.2 to 3.0 ?m. The Sn coating layer has an average thickness of 0.2 to 5.0 ?m. A surface of the electroconductive material has an arithmetic average roughness Ra of at least 0.15 ?m in at least one direction along the surface and 3.0 ?m or less in all directions along the surface. The Cu—Sn alloy coating layer is partially exposed at the surface of the electroconductive material. An area ratio of the Cu—Sn alloy coating layer exposed at the surface of the electroconductive material is 3 to 75%. An average crystal grain size on a surface of the Cu—Sn alloy coating layer is less than 2 ?m.
    Type: Grant
    Filed: March 14, 2014
    Date of Patent: August 29, 2017
    Assignee: Kobe Steel, Ltd.
    Inventor: Masahiro Tsuru
  • Patent number: 9644253
    Abstract: A method includes providing an electronic assembly, where the electronic assembly has at least one electrical connection that includes at least a surface that is substantially pure tin metal and the pure tin metal has tin whiskers formed thereon and the pure tin metal has a thickness. The method includes exposing the tin metal to at least one mitigating agent selected to interact with the tin metal to oxidize the tin whiskers and mechanically removing substantially all the oxidized tin whiskers from the electronic assembly. The electronic assembly is exposed to the mitigating agent under appropriate conditions to oxidize the tin whiskers.
    Type: Grant
    Filed: November 5, 2013
    Date of Patent: May 9, 2017
    Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATION
    Inventor: Eric V. Kline
  • Patent number: 9421644
    Abstract: The invention discloses a soldering structure and process of making the same. The soldering structure comprises: a solder, a Sn—Co—Fe intermetallic compound having a thickness less than 10 ?m and a diffusion barrier layer. The process of making the soldering structure is to react the solder containing Sn with an alloy consisting of 85˜95 wt % of Co and 5˜15 wt % of Fe at the temperature between 250 and 300° C.
    Type: Grant
    Filed: January 28, 2015
    Date of Patent: August 23, 2016
    Assignee: CHUNG YUAN CHRISTIAN UNIVERSITY
    Inventors: Chih-Chi Chen, Yuan-Kai Liang
  • Patent number: 9263814
    Abstract: A metallic material for an electrical electronic includes a CU—Sun alloy layer (2) provided on a conductive base (1). A Cu concentration of the Cu—Sn alloy layer gradually decreases from the base side to the surface (3) side.
    Type: Grant
    Filed: May 29, 2008
    Date of Patent: February 16, 2016
    Assignee: FURUKAWA ELECTRIC CO., LTD.
    Inventors: Kazuo Yoshida, Kyota Susai, Takeo Uno, Shuichi Kitagawa, Kengo Mitose
  • Patent number: 9233521
    Abstract: The present invention relates to a tin whisker mitigation material using thin film metallic glass underlayer, which is a thin film metallic glass (TFMG) formed between a metal substrate and a tin layer. Particularly, the TFMG can be a Zr46Ti26Ni28 underlayer or a Zr51.7Cu32.3Al9Ni underlayer, capable of blocking off the interaction occurring in the interface of a copper layer (the metal substrate) and the tin layer, so as to carry out the inhibition of tin whisker growth. Moreover, a variety of experiment data are proposed for proving that the TFMG of the Zr46Ti26Ni28 or the Zr51.7Cu32.3Al9Ni can indeed be used to replace the conventionally used thick tin layer for being the underlayer between the copper layer (the metal substrate) and the tin layer, and then effectively inhibit the interaction occurring in the Cu/Sn interface and the growth of tin whisker by low manufacturing cost way.
    Type: Grant
    Filed: August 28, 2013
    Date of Patent: January 12, 2016
    Assignee: National Taiwan University Of Science And Technology
    Inventors: Jinn Chu, I Made Wahyu Diyatmika, Yee-Wen Yen, Wen-Zhi Chang
  • Patent number: 9153883
    Abstract: Provided is a terminal, including: a ground metal part made of a first metallic material; an intermediate layer made of a second metallic material having a smaller value of standard electrode potential than that of the first metallic material, and plated thin on at least a part of a surface of the ground metal part; and a surface layer made of a third metallic material having a smaller value of standard electrode potential than that of the second metallic material, and plated thin on at least a part of a surface of the intermediate layer.
    Type: Grant
    Filed: July 31, 2012
    Date of Patent: October 6, 2015
    Assignee: Yazaki Corporation
    Inventor: Kentaro Ohnuma
  • Publication number: 20150147924
    Abstract: The present invention provides metallic materials for electronic components, having low degree of whisker formation, low adhesive wear property and high durability, and connector terminals, connectors and electronic components using such metallic materials.
    Type: Application
    Filed: June 27, 2013
    Publication date: May 28, 2015
    Applicant: JX Nippon Mining & Metals Corporation
    Inventors: Yoshitaka Shibuya, Kazuhiko Fukamachi, Atsushi Kodama
  • Publication number: 20150118515
    Abstract: Tin-plated copper-alloy terminal material including a base material made of Cu alloy; a Sn-based surface layer formed on a surface of the base material and having an average thickness of 0.2 ?m or larger and 0.6 ?m or smaller; a Cu—Sn alloy layer generated between the Sn-based surface layer and the base material; and a Ni-based coating layer, formed of Ni or Ni—Sn alloy having a coating thickness of 0.005 ?m or larger and 0.05 ?m or smaller, in which an oil-sump depth Rvk of the Cu—Sn alloy layer measured when the Cu—Sn alloy layer is appeared on a surface by fusing and removing the Sn-based surface layer is 0.2 ?m or larger; a part of the Cu—Sn alloy layer is exposed from the Sn-based surface layer; the Ni-based coating layer is formed on the exposed Cu—Sn alloy layer; and dynamic friction coefficient of the surface is 0.3 or less.
    Type: Application
    Filed: October 27, 2014
    Publication date: April 30, 2015
    Inventors: Yuki Inoue, Naoki Kato
  • Publication number: 20150056466
    Abstract: A tin-plated copper-alloy terminal material wherein: a Sn-based surface layer formed on a surface of a substrate made of Cu alloy, and a Cu—Sn alloy layer/a Ni—Sn alloy layer/a Ni or Ni alloy layer are formed in sequence from the Sn-based surface layer between the Sn-based surface layer and the substrate; the Cu—Sn alloy layer is a compound-alloy layer containing Cu6Sn5 as a main component and a part of Cu in the Cu6Sn5 is displaced by Ni; the Ni—Sn alloy layer is a compound-alloy layer containing Ni3Sn4 as a main component and a part of Ni in the Ni3Sn4 is displaced by Cu; an arithmetic average roughness Ra of the Cu—Sn alloy layer is 0.3 ?m or more in at least one direction and arithmetic average roughness Ra in all directions is 1.0 ?m or less; an oil-sump depth Rvk of the Cu—Sn alloy layer is 0.5 ?m or more.
    Type: Application
    Filed: August 12, 2014
    Publication date: February 26, 2015
    Inventors: Naoki Kato, Yuki Inoue, Yoshie Tarutani
  • Publication number: 20150047879
    Abstract: The present invention provides a metallic material for electronic components having a low degree of whisker formation and a high durability, and connector terminals, connectors and electronic components using the metallic material. The metallic material for electronic components includes: a base material; on the base material, an lower layer constituted with one or two or more selected from the group consisting of Ni, Cr, Mn, Fe, Co and Cu; on the lower layer, an upper layer constituted with an alloy composed of one or both of Sn and In (constituent elements A) and one or two or more of Ag, Au, Pt, Pd, Ru, Rh, Os and Ir (constituent elements B), wherein the thickness of the lower layer is 0.05 ?m or more; the thickness of the upper layer is 0.005 ?m or more and 0.
    Type: Application
    Filed: January 25, 2013
    Publication date: February 19, 2015
    Inventors: Yoshitaka Shibuya, Kazuhiko Fukamachi, Atsushi Kodama
  • Patent number: 8956735
    Abstract: A mating-type connecting part can be obtained by stamping and surface-roughening a copper sheet into a predetermined shape with depressions as a plurality of parallel lines. The copper sheet then has a roughness of from 0.5 ?m to 4.0 ?m parallel to a sliding direction upon connection, a mean projection-depression interval of from 0.01 mm to 0.3 mm in that direction, a skewness less than 0, and a protrusion peak portion height of 1 ?m or less. The copper sheet is then plated with Cu and Sn, followed by reflowing. The result is a connecting part having a Sn surface coating layer group as a plurality of parallel lines, and a Cu-Sn alloy coating layer adjacent to each side of each Sn surface coating layer.
    Type: Grant
    Filed: March 22, 2011
    Date of Patent: February 17, 2015
    Assignees: Kabushiki Kaisha Kobe Seiko Sho, Shinko Leadmikk Co., Ltd.
    Inventors: Yasushi Masago, Koichi Taira, Toshiyuki Mitsui, Junichi Kakumoto
  • Patent number: 8940404
    Abstract: Tin-plated copper-alloy material for terminal having: a substrate made of Cu or Cu alloy; an Sn-based surface layer formed on a surface of the substrate; and a Cu—Ni—Sn alloy layer including Ni formed between the Sn-based surface layer and the substrate, in which the Cu—Ni—Sn alloy layer is made of: fine Cu—Ni—Sn alloy particles; and coarse Cu—Ni—Sn alloy particles, an average thickness of the Sn-based surface layer is not less than 0.2 ?m and not more than 0.6 ?m, an area ratio of the Cu—Ni—Sn alloy layer exposed at a surface of the Sn-based surface layer is not less than 10% and not more than 40%, and a coefficient of kinetic friction of the tin-plated copper-alloy material for terminal is not more than 0.3.
    Type: Grant
    Filed: January 22, 2013
    Date of Patent: January 27, 2015
    Assignee: Mitsubishi Materials Corporation
    Inventors: Yuki Taninouchi, Naoki Kato, Kenji Kubota
  • Patent number: 8940405
    Abstract: A copper sheet is adjusted to have arithmetic mean roughness Ra of from 0.5 ?m to 4.0 ?m in a direction parallel to a sliding direction upon connection, mean projection-depression interval of from 0.01 mm to 0.3 mm in the direction, skewness of less than 0, and protrusion peak portion height of 1 ?m or less. A Sn surface coating layer group X as a plurality of parallel lines is included, and a Cu—Sn alloy coating layer is adjacent to each side of each Sn coating layer. Maximum height roughness is 10 ?m or less in a direction of part insertion. The sheet is surface-roughened by pressing when stamped, thereby forming depressions as a plurality of parallel lines in its surface. The sheet is then plated with Cu and Sn, followed by reflowing.
    Type: Grant
    Filed: August 9, 2013
    Date of Patent: January 27, 2015
    Assignees: Kobe Steel, Ltd., Shinko Leadmikk Co., Ltd.
    Inventors: Yasushi Masago, Koichi Taira, Toshiyuki Mitsui, Junichi Kakumoto
  • Publication number: 20150010774
    Abstract: The present disclosure generally relates to the field of tin electroplating. More specifically, the present disclosure relates to methods for mitigating tin whisker formation on tin-plated films and tin-plated surfaces by doping the tin with germanium.
    Type: Application
    Filed: July 5, 2013
    Publication date: January 8, 2015
    Inventors: Thomas A. Woodrow, III, Jean A. Nielsen
  • Patent number: 8915761
    Abstract: A connector terminal which can achieve high mechanical connection strength and stabilized low electrical connection resistance when it is crimped to an aluminum electric wire, and in addition, can suppress electrical contact resistance low when it is fitted to a mating connector terminal is provided. In a connector terminal (1A) having an electrical contact section (10) which is brought into contact and conducted with a mating connector terminal by fitting to the mating connector terminal, and a conductor crimping section (12) which is crimped to the conductor of an electric wire, a metal material which constitutes the terminal uses aluminum or an aluminum alloy as a base material (100), a Zn layer (101) having a thickness in the range from 0.1 ?m to 2.0 ?m by electroless plating and a Cu layer (102) having a thickness in the range from 0.5 ?m to 1.0 ?m by electrolytic plating are formed in sequence on the surface of the base material (100), and an Sn layer (105) having a thickness in the range from 0.
    Type: Grant
    Filed: March 24, 2010
    Date of Patent: December 23, 2014
    Assignee: Yazaki Corporation
    Inventor: Naoki Kakuta
  • Publication number: 20140370328
    Abstract: The present invention relates to a tin whisker mitigation material using thin film metallic glass underlayer, which is a thin film metallic glass (TFMG) formed between a metal substrate and a tin layer. Particularly, the TFMG can be a Zr46Ti26Ni28 underlayer or a Zr51.7Cu32.3Al9Ni underlayer, capable of blocking off the interaction occurring in the interface of a copper layer (the metal substrate) and the tin layer, so as to carry out the inhibition of tin whisker growth. Moreover, a variety of experiment data are proposed for proving that the TFMG of the Zr46Ti26Ni28 or the Zr51.7Cu32.3Al9Ni can indeed be used to replace the conventionally used thick tin layer for being the underlayer between the copper layer (the metal substrate) and the tin layer, and then effectively inhibit the interaction occurring in the Cu/Sn interface and the growth of tin whisker by low manufacturing cost way.
    Type: Application
    Filed: August 28, 2013
    Publication date: December 18, 2014
    Applicant: National Taiwan University of Science and Technology
    Inventors: Jinn Chu, I Made Wahyu Diyatmika, Yee-Wen Yen, Wen-Zhi Chang
  • Publication number: 20140353030
    Abstract: The invention relates, in particular, to a composite wire which according to the invention has a structure having a core made of steel or a steel alloy and a copper alloy layer surrounding the core.
    Type: Application
    Filed: May 15, 2014
    Publication date: December 4, 2014
    Applicant: Feindrahtwerk Adolf Edelhoff GmbH & Co. KG
    Inventors: Gerhard BÜRSTNER, Mathias FIOLKA
  • Publication number: 20140329107
    Abstract: There are provided a metal material for electronic component which has low insertability/extractability, low whisker formability, and high durability, and a method for manufacturing the metal material. The metal material 10 for electronic components has a base material 11, an A layer 14 constituting a surface layer on the base material 11 and formed of Sn, In or an alloy thereof, and a B layer 13 constituting a middle layer provided between the base material 11 and the A layer 14 and formed of Ag, Au, Pt, Pd, Ru, Rh, Os, Ir or an alloy thereof, wherein the surface layer (A layer) 14 has a thickness of 0.002 to 0.2 ?m, and the middle layer (B layer) 13 has a thickness of 0.001 to 0.3 ?m.
    Type: Application
    Filed: September 10, 2012
    Publication date: November 6, 2014
    Applicant: JX NIPPON MINING & METALS CORPORATION
    Inventors: Yoshitaka Shibuya, Kazuhiko Fukamachi, Atsushi Kodama
  • Patent number: 8877348
    Abstract: It is an object to provide a surface-treated steel sheet which contains no Cr, which is excellent in wet resin adhesion, and which can be used as an alternative to a conventional tin-free steel sheet and to provide a resin-coated steel sheet produced by coating the surface-treated steel sheet with resin. A surface-treated steel sheet including an adhesive layer which is disposed on at least one surface of the steel sheet and which contains Ti and at least one selected from the group consisting of Co, Fe, Ni, V, Cu, Mn, and Zn, the ratio of the total amount of Co, Fe, Ni, V, Cu, Mn, and Zn to the amount of Ti contained therein being 0.01 to ten on a mass basis, and a method for producing the surface-treated steel sheet.
    Type: Grant
    Filed: October 30, 2008
    Date of Patent: November 4, 2014
    Assignee: JFE Steel Corporation
    Inventors: Yuka Nishihara, Takeshi Suzuki, Noriko Makiishi, Takumi Tanaka, Hiroki Iwasa, Norihiko Nakamura, Kaoru Sato, Takashi Kawano
  • Patent number: 8865319
    Abstract: A reflow Sn plated material, comprising: a substrate consisting of Cu or a Cu base alloy, and a reflow Sn layer formed on the surface of the substrate, wherein an orientation index of a (101) plane on the surface of the reflow Sn layer is from 2.0 or more to 5.0 or less.
    Type: Grant
    Filed: October 26, 2010
    Date of Patent: October 21, 2014
    Assignee: JX Nippon Mining & Metals Corporation
    Inventor: Naofumi Maeda
  • Publication number: 20140308540
    Abstract: Plated contacts and processes of manufacturing plated contacts are disclosed. The processes include providing a metallic substrate, applying tin-containing plating over the metallic substrate, applying corrosion-prevention plating over the first tin-containing plating, applying a second tin-containing plating over the first corrosion-prevention plating, applying a second corrosion-prevention plating over the second tin-containing plating, and applying a gold plating over the second corrosion-prevention plating to form the plated contact. One or both of the first corrosion-prevention plating and the second corrosion-prevention plating includes nickel, a nickel-based alloy, copper, a copper containing alloy, or a combination thereof.
    Type: Application
    Filed: April 12, 2013
    Publication date: October 16, 2014
    Applicant: TYCO ELECTRONICS CORPORATION
    Inventor: George Jyh-Shann CHOU
  • Publication number: 20140295070
    Abstract: An electroconductive material includes a Cu or Cu alloy base member, a Cu—Sn alloy coating layer, and a Sn coating layer. The Cu—Sn alloy coating layer has a Cu content of 20 to 70 atomic %, and an average thickness of 0.2 to 3.0 ?m. The Sn coating layer has an average thickness of 0.2 to 5.0 ?m. A surface of the electroconductive material has an arithmetic average roughness Ra of at least 0.15 ?m in at least one direction along the surface and 3.0 ?m or less in all directions along the surface. The Cu—Sn alloy coating layer is partially exposed at the surface of the electroconductive material. An area ratio of the Cu—Sn alloy coating layer exposed at the surface of the electroconductive material is 3 to 75%. An average crystal grain size on a surface of the Cu—Sn alloy coating layer is less than 2 ?m.
    Type: Application
    Filed: March 14, 2014
    Publication date: October 2, 2014
    Applicant: KABUSHIKI KAISHA KOBE SEIKO SHO (Kobe Steel Ltd.)
    Inventor: Masahiro TSURU
  • Publication number: 20140287262
    Abstract: Tin-plated copper-alloy terminal material in which Sn-based surface layer is formed on a surface of a substrate made of Cu alloy, and a Cu—Sn alloy layer is formed between the Sn-based surface layer and the substrate; the Cu—Sn alloy layer contains Cu6Sn5 as major proportion and has a compound in which a part of Cu in the Cu6Sn5 is substituted by Ni and Si in the vicinity of a boundary face at the substrate side; an arithmetic average roughness Ra of the Cu—Sn alloy layer is 0.3 ?m or more in at least one direction and an arithmetic average roughness Ra in all direction is 1.0 ?m or less; an oil-sump depth Rvk of the Cu—Sn alloy layer is 0.5 ?m or more; and an average thickness of the Sn-based surface layer is 0.4 ?m or more and 1.0 ?m or less and dynamic friction coefficient is 0.3 or less.
    Type: Application
    Filed: March 14, 2014
    Publication date: September 25, 2014
    Applicant: MITSUBISHI MATERIALS CORPORATION
    Inventors: Naoki Kato, Yuki Inoue, Yoshie Tarutani
  • Publication number: 20140178711
    Abstract: A copper substrate for use as a contact having Sn plating, nickel plating and Au plating overlying the substrate. A combination of Sn plating is applied over a copper substrate; nickel plating is applied over the Sn plating; and Au plating is applied over the nickel plating to form a stack. The stack is then processed by a vapor phase Sn reflow step that results in the formation of intermetallics and eliminates stannous oxide layers that may otherwise form on the tin layer. The intermetallic layers provide excellent corrosion resistance, and serve as diffusion barriers to prevent the further migration of either Ni atoms or Cu atoms into the Sn, and Sn atoms outwardly into either the Ni or the Cu. Regardless of the thickness, the interfaces are substantially free of oxides, in particular tin oxide, and not prone to delamination.
    Type: Application
    Filed: December 26, 2012
    Publication date: June 26, 2014
    Applicant: TYCO ELECTRONICS CORPORATION
    Inventor: George Jyh-Shann CHOU
  • Publication number: 20140170436
    Abstract: Tin-plated copper-alloy material for terminal in which: a Sn-based surface layer is formed on a surface of a substrate made of Cu alloy, and a Cu—Sn alloy layer is formed between the Sn-based surface layer and the substrate; the Cu—Sn alloy layer is an alloy layer containing Cu6Sn5 as a major proportion and having a compound in which a part of Cu in the Cu6Sn5 is substituted by Ni and Si in the vicinity of a boundary face at the substrate side; an average thickness of the Sn-based surface layer is 0.2 ?m or more and 0.6 ?m or less; an oil-sump depth Rvk of the Cu—Sn alloy layer is 0.2 ?m or more; an area rate of the Cu—Sn alloy layer exposed at a surface of the Sn-based surface layer is 10% or more and 40% or less; and dynamic friction coefficient is 0.3 or less.
    Type: Application
    Filed: August 10, 2012
    Publication date: June 19, 2014
    Applicant: MITSUBISHI MATERIALS CORPORATION
    Inventors: Yuki Taninouchi, Naoki Kato, Kenji Kubota
  • Patent number: 8728629
    Abstract: A connector terminal, fabricated from a metallic material for connector which material has a tin or tin alloy layer, formed on a copper or copper alloy base material, wherein the thickness of the tin or tin alloy layer at a contact site on the surface of the terminal is smaller than the thickness of the tin or tin alloy layer in the areas other than the contact site, and a copper-tin alloy layer is formed as an under layer of the tin or tin alloy layer at the contact site; and a connector terminal, fabricated from a metallic material for connector which material has a copper or copper alloy base material, wherein a copper-tin alloy layer is formed in a spot shape at a contact site on the surface of the terminal, and a tin or tin alloy layer is formed in the remaining areas on the surface.
    Type: Grant
    Filed: September 17, 2010
    Date of Patent: May 20, 2014
    Assignee: The Furukawa Electric Co., Ltd.
    Inventors: Shuichi Kitagawa, Kengo Mitose, Yoshiaki Kobayashi
  • Patent number: 8709612
    Abstract: A laminated ceramic capacitor includes a rectangular solid-shaped electronic component element. External electrodes of terminal electrodes are disposed at one end surface and the other end surface of the electronic component element. First plated films including a Ni plating are disposed on the surfaces of external electrodes. On the surfaces of the first plated films, second plated films containing Sn are disposed as Sn-plated films defining outermost layers of the external electrodes. The second plated films have a polycrystalline structure, and flake-shaped Sn—Ni alloy grains are located at a Sn crystal grain boundary and within a Sn crystal grain, respectively.
    Type: Grant
    Filed: April 12, 2012
    Date of Patent: April 29, 2014
    Assignee: Murata Manufacturing Co., Ltd.
    Inventors: Akihiro Motoki, Makoto Ogawa, Atsuko Saito, Toshinobu Fujiwara, Kenji Masuko
  • Publication number: 20140065440
    Abstract: A Sn-coated copper alloy strip including a surface coating layer containing a Ni layer, a Cu—Sn intermetallic compound layer, and a Sn layer formed in this order over the surface of a base material containing a copper alloy strip, in which an average thickness of the Ni layer is from 0.1 to 3.0 ?m, an average thickness of the Cu—Sn intermetallic compound layer is from 0.02 to 3.0 ?m, an average thickness of the Sn layer is from 0.01 to 5.0 ?m, and the Cu—Sn intermetallic compound layer contains only an ?-phase or the ?-phase and an ?-phase.
    Type: Application
    Filed: August 28, 2013
    Publication date: March 6, 2014
    Applicant: Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.)
    Inventor: Masahiro TSURU