Abstract: There has been provided an electrical component having resistance to oxidation and wear. The component has a copper or copper alloy substrate coated with a relatively thick layer of silver. A thin layer of gold may be deposited on the external surface of the silver coating layer to improve oxidation resistance, lubricity and to serve as a diffusion barrier.

Abstract: A palladium alloy of the form PdNbM where M is at least one element selected from the group consisting of silicon, iron, nickel, copper, cobalt, boron and aluminum is provided. The alloys exhibit oxidation resistance and electrical contact resistance and are particularly suited for electrical applications such as coatings for electrical contacts or connectors. In a preferred embodiment, the alloy contains from about 5 to about 10 atomic percent niobium.

Abstract: A rod made of a hard material is inserted into a pipe made of a relatively soft material, and a two-element arrangement having an intermediate size is obtained by hot-rolling and drawing. In these steps, the cross section is reduced by at least 50%. Subsequently, another pipe of the soft material is fitted onto the two-element arrangement, and the so-obtained three-element arrangement is adjusted to its final size by means of hot or cold rolling followed by cold drawing.

Abstract: A composite body for rotary anodes of X-ray tubes is made from graphite, a carbide-forming, high-melting metal component and a multi-layered intermediate layer. The first layer of the intermediate layer closest to the graphite is made up of a metal or an alloy thereof which does not form a carbide. Applied over the first layer are at least two double layers. Each double layer has one individual layer of at least one carbide-forming metal or at least one carbide thereof, and a second individual layer of a metal or an alloy thereof which does not form a carbide. Preferred carbide-forming metals are tungsten, tantalum, hafnium and niobium. Preferred metals which do not form carbides are rhenium and platinum. In a preferred embodiment, the composite body is a rotary anode for X-ray tubes, with a basic body made of graphite and a burning track made of tungsten or a tungsten-rhenium alloy applied directly to the intermediate layer.

Abstract: A multilayer wiring substrate which includes a glass ceramic section, a wiring layer section having a plurality of wiring layers electrically insulated from each other by a polyimide material, and an intermediate layer made of an inorganic material and arranged between the ceramic section and the wiring layer section.

Abstract: An improved sputtering process for making a platinum/cobalt (Pt/Co) multilayer film comprised of alternating layers of platinum and cobalt, said improvement comprising using as the sputter gas krypton, xenon or a mixture thereof.

Abstract: A body formed of a lead-tin solder alloy is pretreated to deposit palladium thereon prior to soldering to a metallic substrate. It is found that the palladium deposit enhances wetting of the substrate by the solder liquid during reflow and thereby, upon cooling, produces a strong metallurgical bond. In a preferred embodiment, lead-tin solder balls are pretreated by applying tin-palladium colloidal particles and dissociating the particles to form a discontinuous metallic palladium deposit.

Abstract: In an electric contact having a Cu-based layer, a Ni-based layer formed on the Cu-based layer, and a Pd-based layer formed on the Ni-based layer, the Ni-based layer having a thickness of at least 0.8 .mu.m is so formed as to include a noncrystal nickel alloy layer having a thickness of at least 0.08 .mu.m, in order to reduce the thickness of the Pd-based layer down to about 0.08 .mu.m, that is, the cost of the contact without deteriorating the contact durability, as compared with a 0.6 to 2 .mu.m thick prior-art Pd-based layer.

Abstract: A magnetic recording medium which comprises a non-magnetic substrate, a Cr undercoat layer formed on the substrate, and a quaternary alloy layer formed on the undercoat layer. The alloy layer consists of the following composition by atomic percent1.ltoreq.Cr.ltoreq.182.ltoreq.Ta.ltoreq.973.ltoreq.Co.ltoreq.971.ltoreq.Pt.ltoreq.10provided that the atomic percent of Cr, Ta and Co is 100 in total and the atomic percent of Pt is based on the total of Cr, Ta and Co.

Abstract: A metallized article (10) having a non-conductive surface (11) and a plurality of depressions (12) in the surface (11). A first layer of metal (13) being mechanically bonded to the non-conductive surface (11), such that the mechanical bond is enhanced by the interaction of the first layer of metal (13) and the depressions (12). An intermediate layer of metal (14) bonded to the first layer (13). A finish layer of metal (15) being bonded to the intermediate layer (14). The finish layer (15) being a metal which readily accepts a high polish or shine. A process for metallizing such an article having a non-conductive surface including the steps of etching the surface of the article with fluoride containing salts and the depositing of a first layer of metal onto the etched surface. The process further including depositing an intermediate layer of metal in an electroless manner, and then depositing a finish layer of metal by electrolysis.

Abstract: A direct (metal-metal compound eutectic) bond process is improved by disposing a eutectic/substrate-wetting enhancement layer on the substrate prior to performing the direct bond process to bond a metal foil to the substrate. Where the metal is copper, the direct bond process is rendered more effective than prior art direct bond processes on alumina and beryllia and makes the direct bond process effective on tungsten, molybdenum and aluminum nitride, all of which were unusable with the prior art direct bond copper process. A variety of new, useful structures may be produced using this process. The eutectic/substrate-wetting enhancement layer is preferably a noble-like metal or includes a noble-like metal such as platinum, palladium and gold.

Abstract: Alloy compositions suitable for use in protecting refractory base alloy compositions are disclosed. The coating is formed of an alloy containing chromium, ruthenium and aluminum and which may contain iron, cobalt and nickel. The coating is found to be highly resistant to oxidation.

Abstract: A method including aluminization treatment preceded by a palladium predeposition treatment, the palladium being associated with at least one barrier metal selected from nickel, cobalt, and chromium, thereby avoiding hydrogen occlusion.

Abstract: A musical instrument (for example, a flute) or a musical instrument segment (for example, a flute headjoint) having tubing made of a mechanically unitary laminated metal tube which has at least one layer of precious metal alloy bonded to another layer of metal alloy.

Abstract: A dental crown restoration which comprises a metal coping and a relatively thick outer coating of a ceramic dental veneer. The metal coping is composed of a lamination of a low fusing temperature precious metal component substantially or entirely of gold and a high-fusing temperature precious metal component. The high fusing component is formed from three layers with one layer composed of from 90 to 100% palladium bounded on both sides by a gold based layer.

Abstract: A semiconductor die attach system adapted for attaching a semiconductor die to a substrate is provided. A metallic buffer component for dissipating thermal stresses is disposed between the substrate and the semiconductor die to dissipate stresses created from thermal cycling of the substrate and the die. The metallic buffer component is sealed between the substrate and the die with a silver-tin sealing composition. A bonding material may be used alone to bond a die to a substrate and dissipate stresses from thermal cycling.

Abstract: A structure which is resistant to corrosion at high temperatures comprises a ductile layer of a platinum group metal, such as iridium, and a layer of a refractory metal having a high strength at high temperatures, such as rhenium. A solid solution of the two metals is present between and metallurgically bonded to the two metal layers. Further, the structure may include a layer of ceramic such as zirconia or hafnia on the exposed face of the platinum group metal layer.

Abstract: A multiple-layered metallic article useful for example, as costume jewelry having an intermediate "brightening layer" of bronze. A barrier layer selected from the group comprising palladium, tin, tin/zinc, rhodium, or platinum is disposed between the bronze "brightening layer" and a "top coat" layer to avoid migration of the copper component in the bronze layer to the outer surface of the article which, if left unimpeded eventually would result in a tarnishing effect to the article. As a result of the bronze intermediate layer, the article is hypo-allergenic with respect to those people having a skin sensitivity to nickel-plated or nickel-underplated metallic articles.

Abstract: The present invention is directed to a novel anode suitable for producing high purity, pore-free coper foil at high speed and low cost under severe conditions. The anodes of the present invention are capable withstanding high acid concentrations, current densities and temperatures which would rapidly destroy the prior art anodes. This is accomplished by producing the anodes of the present invention by a new and novel process which results in structural superior anodes. The anodes of the present invention are produced by first electrodepositing on a valve metal substrate platinum to a thickness of at least about 150 microinches to about 400 microinches. The next step in the process involves "densification" of the platinum layer by heat treatment so as to close the pores of the platinum layer. This results in a substantially closed pore platinum layer.

Abstract: Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formulaA.sub.a M.sub.b M'.sub.cwhereinA is at least one metal selected from the group consisting of Ag, Au, Hg, Pd and Pt;M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co, Fe, Zn, Cd, Ga and Mn; andM' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; andwhereina ranges from greater than zero to about 0.80;b ranges from zero to about 0.70; andc ranges from about 0.08 to about 0.95;characterized in that (1) a substantial portion of A is disposed on the surface of said material and/or (2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with a bulk storage material comprising a reversible hydrogen storage material.

Abstract: A surface for providing an electrically conductive surface coating on an electrical contact body. The process resulting in such a coating comprises the steps of depositing upon the body surface in sequence, (a) a nickel layer, (b) a first gold layer, (c) a palladium/nickel alloy layer which may be an alloy containing nickel up to a proportion of 50% by weight, and (d) a second gold layer. All the layers may be deposited by an electrodeposition process.The resulting surface coating has excellent corrosion and wear resistance properties.

Abstract: An article of jewelry of platinum and fine gold of the type wherein the two metals are connected to one another by applying the fine gold in the solid state on the platinum and heating the fine gold to its melting temperature. The article of jewelry includes area portions of thin sheets of fine gold and reinforcements of platinum bordering the area portions of fine gold.

Abstract: A thin film noble metal temperature sensor includes adjacent layers of metals and metal oxides on the surface of a component. The most preferred sequence of layers are: a NiCoCrAlY layer applied directly to the component surface; a thermally grown aluminum oxide layer on the NiCoCrAly layer; a sputtered layer of aluminum oxide on the thermally grown layer of aluminum oxide; a FeCrAl layer on the sputtered aluminum oxide layer; and layer of platinum and platinum-rhodium on the FeCrAl layer.

Abstract: A plating bath and process for electroplating coatings of palladium nickel alloys on a conductive substrate at current densities in the range of 10 amps/sq. ft. to 150 amps/sq. ft. wherein the palladium content of the alloy remains substantially constant despite current density variations during plating. The alloy composition stability is achieved by adding at least about 15 parts per million of iodide and/or iodate ions to the plating bath. The as-plated alloy has a thin surface layer which contains iodide at or near the surface.

Abstract: A platinum article, especially an article of jewellery, has its surface region modified to improve its scratch resistance by the addition of at least one element which forms an intermetallic compound with platinum, especially aluminum and chromium. The surface region may be formed by the pack cementation chemical vapor deposition process.

Abstract: Relatively large structures are fabricated from oxide dispersion strengthened platinum or alloys by working a plurality of pieces to thin, wide layers, and then laminating the layers such as by hammer welding so as not to disturb the grain structure or oxide dispersion.

Abstract: An improved thin film metal alloy media for horizontal magnetic recording has a magnetic layer of an alloy comprising cobalt, platinum and chromium, where the chromium concentration in the alloy is greater than 17 at.%. The media exhibits unexpectedly high signal-to-noise ratio (SNR) and minimal time jitter, thereby resulting in a media which is capable for use at high linear recording density. The media also exhibits excellent corrosion resistance because of the chromium present in the alloy, thereby eliminating the need for a barrier layer between the magnetic layer and the protective overcoat.

Abstract: In construction of a Ti core type clad material for ornamental applications presence of one or more intermediate layers made of Cr and/or Mo well deters evolvement of intermetallic compound at the border between core and sheath, thereby significantly improving bonding strength of the product.

Abstract: Erosion resistance is imparted to a metallic substrate without an attendant loss of fatigue life in the substrate in one embodiment by applying to the substrate a first ductile layer comprising a metal from Group VI to Group VIII elements as well as the noble metal group of elements, and a second hard erosion-resistant layer applied on the first layer comprising a boride, carbide, nitride or oxide of a metal selected from Group III to Group VI elements, the first layer capable of retaining substrate integrity and preventing diffusion of material from the second layer into the substrate. Another embodiment defines another layer of a substantially pure metal from Group III to Group VI between the first and second layers. Still another embodiment defines that in the second layer the content of either the carbide, nitride, boride or oxide is graded, i.e.

Abstract: A combination ceramic sealing cover for a semiconductor package has a flat ceramic lid member with metallization applied as a foundation for a seal ring or frame portion. On the metallized layer is a gold-tin solder layer, in the form of either a solder ring that is tack welded on, or solder paste that is screened onto the base metallization and furnace reflowed.

Abstract: Novel amorphous metal alloy electrodes have the formulaePt.sub.p A.sub.a D.sub.dwhereA is Ir, Pd, Rh, Ru and mixtures thereof;D is B, Al, As, P, Sb, Ge, Sn, Si and mixtures thereof;p is from about 40 to 92 percent;a is from about 1 to 40 percent;d is from about 8 to 40 percent; and p+a+d=100; andNi.sub.n E.sub.e F.sub.f G.sub.gwhereE is Mo, W and mixtures thereof;F is Pt, Pd, Rh, Ir, Cr and mixtures thereof;G is Al, Ga and mixtures thereof;n is from about 30 to 90 percent;e is from about 10 to 50 percent;f is from about 0 to 25 percent;g is from about 10 to 40 percent; and n+e+f+g=100.These electrodes are useful for hydrogen formation and oxidation and operate at lower potentials than existing electrodes.

Abstract: The article is provided with a coating resisting wear and corrosion, such coating being for the most part made of a precious metal or alloy of a precious metal, for example gold or an alloy containing gold.The coating is made up of a first layer of such precious metal or alloy thereof comprising discrete inclusions of a metallic compound such as titanium nitride. These inclusions are deposited along with the precious metal in vapor phase and distributed in a substantially homogeneous manner through the entire thickness of the layer, said thickness being equal to or greater than 0.4 .mu.m. A second layer of precious metal or alloy thereof is located between the article and said first layer.The article may be a watch case, a bracelet link or a piece of jewelry.

Abstract: A plating bath and process for electroplating coatings of palladium nickel alloys on a conductive substrate at current densities in the range of 10 amps/sq. ft. to 150 amps/sq. ft. wherein the palladium content of the alloy remains substantially constant despite current density variations during plating. The alloy composition stability is acheived by adding at least about 15 parts per million of iodide ions to the plating bath.

Abstract: Novel materials having the ability to reversibly store hydrogen are amorphous metal alloys of the formulaA.sub.a M.sub.b M'.sub.cwhereinA is at least one metal selected from the group consisting of Ag, Au, Hg, Pd and Pt;M is at least one metal selected from the group consisting of Pb, Ru, Cu, Cr, Mo, Si, W, Ni, Al, Sn, Co. Fe, Zn, Cd, Ga and Mn; andM' is at least one metal selected from the group consisting of Ca, Mg, Ti, Y, Zr, Hf, Nb, V, Ta and the rare earths; andwhereina ranges from greater than zero to about 0.80;b ranges from zero to about 0.70; andc ranges from about 0.08 to about 0.95;characterized in that (1) a substantial portion of A is disposed on the surface of said material and/or (2) that said material functions as an active surface layer for adsorbing/desorbing hydrogen in conjunction with a bulk storage material comprising a reversible hydrogen storage material.

Abstract: X-ray dispersive and reflective structures and materials are provided which exhibit at least one third of the theoretical integral reflection coefficient for the structures in the range of interest without fluorescence or absorption edges. The materials can be thermally activated to control the desired properties, during or post deposition. The structures can be deposited by ion beam absorption techniques to form the structures in a precise manner. The index of the refraction of the structures can be continuously varying throughout the structures.

Abstract: The present invention relates to a high-purity palladium-nickel alloy plating, and particularly to a high-purity palladium-nickel alloy plating solution and process suitable as plating for electronic parts, said plating solution and process producing a deposit having a nickel content of 1 to 15%, an article plated with said alloy, and an article plated with said alloy and plated further with gold or a gold alloy.

Abstract: A magneto optical recording medium comprising laminating a reflective layer, a dielectric undercoat layer and a hexagonal magnetoplumbite-type metal oxide magnetic layer on a substrate in order, characterized by that said magnetic layer is made an excellently C axis - orientated perpendicular magnetic film by putting the crystal misfit between said reflective layer and said dielectric undercoat layer formed thereon within .+-.30% and the crystal misfit between said dielectric undercoat layer and said hexagonal magnetoplumbite -type metal oxide magnetic layer formed thereon within .+-.30%, and thus various characteristics are widely improved.

Abstract: The invention provides a magnetic recording medium comprising a substrate of a nonmagnetic material bearing a thin magnetic layer with perpendicular anistropy. The magnetic thin layer comprises alternate layers of Pd and Co. The signal-to-noise ratio upon reading the stored information is considerably improved in that the thicknesses of the individual layers of Pd are between 0.2 and 2.0 nm and that the individual layers of Co consist of at least one monolayer of Co atoms and have thicknesses which are smaller than 0.3 nm.The thin magnet layer may be manufactured, for example, by electron beam vacuum vapor deposition of the individual layers of Pd and Co.

Abstract: A magnetic recording member with a thin metallic antifriction protection overcoat formed over a magnetic layer. The overcoat is soft ductile and low stress and includes a metal selected from the group consisting of palladium, platinum, silver, gold, cadmium, indium, tin and lead or an alloy of one or more of these metals, and may include less than 20 percent by weight of antimony, bismuth, thallium or copper to improve wear resistance or impede corrosion. In one preferred embodiment the antifriction overcoat is an alloy of silver, lead and antimony formed with N layers where 10.ltoreq.N.ltoreq.40. The even layers are richer in a selected metal of the alloy than the odd layers in order to produce adjacent layers with different lattice or microstructural and associated mechanical properties so that there tends to be parallel shear between adjacent layers under shearing stress of head impact or friction.

Abstract: Plated metal parts, such as sealing lids for semiconductor packages, in which an iron-based alloy layer is electroplated with a first layer of nickel, a first layer of gold is electroplated on the first nickel layer, a second layer of nickel is electroplated onto the first gold layer and a second layer of gold is electroplated onto the second layer of nickel. The resultant plated parts exhibit higher salt atmosphere corrosion resistance than parts plated with a single nickel-gold set. Other metals can be used as the plating layers.

Abstract: The bond strength between a silicon carbide substrate and a metal layer comprised of a series of metal films is improved without detrimentally affecting other properties of such a device by interposing a layer of silicon, Si.sub.2 Mo or mixtures thereof between the substrate and the first metal film in the layer which is preferably Ti, Zr or Hf.

Abstract: An improved cobalt-platinum (CoPt) thin film metal alloy media for horizontal magnetic recording has a coercivity substantially greater than prior CoPt thin film metal alloy media. A tungsten underlayer between the substrate and the CoPt magnetic layer improves the coercivity above that of media wiht conventional underlayers, such as chromium. The coercivity of the CoPt layer can be increased even further if the CoPt film is deposited in such a manner as to form an intermetallic compound of Co.sub.3 W in the interface region between the tungsten underlayer and the CoPt magnetic layer. The tungsten underlayer also improves the magnetic properties of the media when the magnetic layer is an alloy of cobalt-platinum-chromium (CoPtCr).

Abstract: Methods for increasing the ductility and reducing the porosity and cracking tendency of a palladium or palladium-silver electrodeposit which comprises providing an underlayer of a palladium/nickel or palladium/cobalt alloy electrodeposit. Also dual layer composite electroplated deposits and their use in electrical contacts or connectors.

Abstract: A process for metal plating a stainless steel comprising the first step of treating the stainless steel by a cathode electrolysis in an aqueous solution containing free HCl in an amount at least 30 g/l and at least one species of Ni and Co in an amount at least 0.1 g/l; the second step of metal plating the same by Ni or a Ni alloy in a weakly acidic Ni plating bath; and the third step of subsequently plating the same by a noble metal, Cu or an alloy thereof.

Abstract: A foil material for the storage of hydrogen in materials capable of bearing hydrogen, i.e. a hydrogen storageable material. Through the intermediary of a heat-conductive bond between a metal having hydrogen storage capability and a substrate, which is adapted for the absorption and conducting off of the reaction heat produced during hydrogen exchange, and on which the hydrogen storageable metal is applied as a storage layer, there is afforded a rapid heat exchange during the loading and unloading of the storage layer. Employed for this purpose is the heat capacity of the substrate. The material for the substrate and the volume of the latter is so selected that the reaction to heat is exchangeable with the substrate of the storage layer without the need for ancillary heat exchangers; in effect, can be taken up by or given up from the substrate. The storage layer has its exposed surface covered with a protective layer which acts in a corrosion-inhibiting manner and which is permeable to hydrogen.

Abstract: A package having an enclosure for accommodating an electronic device, and the process of producing same. The process comprises the steps of providing a lead frame which has at least a final layer electroplated on the outerlead area thereof; bonding an electronic device in the enclosure; connecting the electronic device with an innerlead area of the lead frame by means of wires; and, thereafter, sealing the enclosure with fused glass in such a manner that the outerlead area extends out of the glass.

Abstract: Layered coherent structures characterized by periodic, alternating layers of cobalt and palladium and/or platinum exhibit perpendicular magnetic anistropy.

Abstract: Low voltage current contacts should have good tarnish resistance and resistance to wear at the smallest possible gold content. Such materials consist of 330 to 50 wt. % palladium, 18 to 48 wt. % silver, 19 to 33 wt. % gold, 0.01 to 1 wt. % iridium, osmium, or a mixture of iridium and osmium and either 0.5 to 5 wt. % lead or a mixture of 0.5 to 3 wt. % lead and 0.1 to 3 wt. % tin.

Abstract: A multilayer wiring substrate composed of organic dielectric layers with wiring layers disposed therein supports large-scale integrated circuit chips and bonding pads. To prevent damage to the wiring layers when wires from the integrated circuit chips are attached to the bonding pads by thermocompression bonding, a metallic layer is interposed between the wiring layers and the bonding pads.

Abstract: An alloy having the nominal composition Ni--30/40 wt % Cr--1/5 wt % Ti--2/8 wt % Al is used for coating gas turbine components to give protection against oxidation--and sulphidation--corrosion. A specific alloy having the composition Ni--37 Cr--3 Ti--2Al is applied to a blade fabricated from a nickel superalloy by sputter ion plating to give an overlay coating up to 100 .mu.m thick. Preferably a platinum intermediate layer is flashed on to the substrate before coating. The coating alloy can additionally include rare earths, hafnium or silicon.