Abstract: A lithium ion battery cell. The lithium ion battery cell includes a lithium-based anode, a cathode, and a solid-state electrolyte positioned between the lithium-based anode and the cathode. The cathode comprises alkylammonium cation lithium phthalocyanine anion complex. The solid-state electrolyte comprises an alkoxyalkylammonium cation lithium phthalocyanine anion complex.

Abstract: A non-aqueous electrolyte secondary battery according to the present invention includes a positive electrode, a negative electrode, and a non-aqueous electrolyte solution. The negative electrode includes a coating derived from lithium bis(oxalate)borate. The coating derived from lithium bis(oxalate)borate includes a coating containing boron element and a coating containing oxalate ion. A ratio of the boron element contained in the coating derived from lithium bis(oxalate)borate to the oxalate ion is equal to or more than 5. Accordingly, it is possible to provide a non-aqueous electrolyte secondary battery capable of reliably obtaining the effect due to the formation of a coating.

Abstract: Primer arrangements that facilitate electrical conduction and adhesive connection between an electroactive material and a current collector are presented. In some embodiments, primer arrangements described herein include first and second primer layers. The first primer layer may be designed to provide good adhesion to a conductive support. In one particular embodiment, the first primer layer comprises a substantially uncrosslinked polymer having hydroxyl functional groups, e.g., polyvinyl alcohol. The materials used to form the second primer layer may be chosen such that the second primer layer adheres well to both the first primer layer and an electroactive layer. In certain embodiments including combinations of first and second primer layers, one or both of the first and second primer layers comprises less than 30% by weight of a crosslinked polymeric material. A primer including only a single layer of polymeric material is also provided.

Abstract: The present disclosure relates to a composite conductive electrode and a manufacturing method thereof, belonging to the field of vanadium battery manufacturing. The method comprises: selecting a carbon felt as a conductive substrate, selecting a conductive resin as the connecting substance for spaces in the carbon felt so as to enhance the conductive properties of the carbon felt; the conductive resin comprises a conductive plastic material or an epoxy resin.

Abstract: A rechargeable lithium-sulfur cell comprising an anode, a separator and/or electrolyte, a sulfur cathode, an optional anode current collector, and an optional cathode current collector, wherein the cathode comprises (a) exfoliated graphite worms that are interconnected to form a porous, conductive graphite flake network comprising pores having a size smaller than 100 nm; and (b) nano-scaled powder or coating of sulfur, sulfur compound, or lithium polysulfide disposed in the pores or coated on graphite flake surfaces wherein the powder or coating has a dimension less than 100 nm. The exfoliated graphite worm amount is in the range of 1% to 90% by weight and the amount of powder or coating is in the range of 99% to 10% by weight based on the total weight of exfoliated graphite worms and sulfur (sulfur compound or lithium polysulfide) combined. The cell exhibits an exceptionally high specific energy and a long cycle life.

Abstract: An aqueous metal-ion battery and a method for constructing same. In one embodiment, the battery includes an aqueous electrolyte and at least one electrode comprising at least one organic electrode material. A method comprises incorporating an organic electrode material into the electrode of an aqueous metal-ion battery. The organic electrode material further comprises at least one material chosen from carbonyl compounds.

Abstract: A nanocomposite includes carbon-encapsulated transition metal oxide nanoparticles. The carbon-encapsulated transition metal oxide nanoparticles comprise a transition metal oxide core having a diameter of from 5 nm to 50 nm covered by a graphitic coating having a thickness of from 1 nm to 5 nm.

Abstract: The present disclosure provides a silicon based composite material, and a preparation method and a use thereof. The silicon based composite material comprises silicon nano-particles and polyaniline coating layers on surfaces of the silicon nano-particles, and Si—C covalent bonds are formed between the silicon nano-particles and the polyaniline coating layers. The silicon based composite material provided by the present disclosure is advantageous in improving the coating effect of polyaniline on silicon particles.

Abstract: An electrode material is provided. The electrode material includes a porous carbon material, wherein the porous carbon material has a half-width of diffraction intensity peak of a (100) face or a (101) face of 4 degrees or less with reference to a diffraction angle 2 theta on a basis of an X-ray diffraction method. An absolute value of a differential value of mass can be obtained when a mixture of the porous carbon material and S8 sulfur mixed at a mass ratio of 1:2 is subjected to thermal analysis, where temperature is employed as a parameter, has a value of more than 0 at 450° C. and a value of 1.9 or more at 400° C. A battery and method of manufacture are also provided.

Abstract: A battery with a sulfur-containing cathode, an anode, and a separator between the cathode and the anode has a coating comprising a single-lithium ion conductor on at least one of the cathode or the separator.

Abstract: A composition for use in a battery electrode including lithium-sulfur particles coated with a transition metal species bonded to a sulfur species. Methods and materials for preparing such a composition. Use of such a compound in a battery.

Abstract: A sulfur-containing electrode has a binder comprising a single-lithium ion conductor. The electrode may be used a cathode in a lithium-sulfur or silicon-sulfur battery.

Abstract: A surface modified lithium titanate and preparation method thereof is provided. In the surface modified lithium titanate, the deactivating groups distributed on the surface of the lithium titanate are —O—P—RR?R?, —O—P—(OR)R?R?, —O—P—(OR)(OR?)R?, and —O—P—(OR)(OR?)(OR?), where R, R? and R? are identical or different C1˜C8 alkyl or alkenyl groups. The deactivating groups are bonded to the lithium titanate via a bond or a bridge. The exemplary surface modified lithium titanate can effectively lower its catalytic activity, reduce the gassing of lithium ion batteries, and therefore improve the high temperature storage and high temperature cycle performance of lithium titanate batteries. The exemplary preparation method is simple, has great repeatability, a low cost, low pollution to the environment, and is suitable for industrial production.

Abstract: In one embodiment, the present disclosure provides a sulfur-hydroxylated graphene nanocomposite including at least one graphene sheet with a surface and a plurality of amorphous sulfur nanoparticles homogeneously distributed on the surface. The nanocomposite substantially lacks sulfur microparticles. In other embodiments, the disclosure provides a cathode and a battery containing the nanocomposite. In still another embodiment, the disclosure provides a method of making a sulfur-hydroxylated graphene nanocomposite by exposing a hydroxylated graphene to a sulfur-containing solution for a time sufficient to allow formation of homogeneously distributed sulfur nanoparticles on a surface of the hydroxylated graphene.

Abstract: The use of fibril materials, such as fibril cellulose materials and other similar materials, in electrochemical cells and components thereof is generally described.

Abstract: An electrode active material has, as a main component, a mixture of an organic compound containing a rubeanic acid and oxamide. The rubeanic acid is represented by the following general formula: In the formula, n indicates an integer between 1 and 20, and R1-R4 indicate hydrogen atoms, halogen atoms, or a prescribed substituent group such as a hydroxide group, a 1-3C alkyl group, an amino group, a phenyl group, a cyclohexyl group, or a sulfo group.

Abstract: An electrode active material has, as a main component, a mixture of an organic compound containing a rubeanic acid and cyanomethanesulfonylamide. The rubeanic acid is represented by the following general formula: In the formula, n indicates an integer between 1 and 20, and R1-R4 indicate hydrogen atoms, halogen atoms, or a prescribed substituent group such as a hydroxide group, a 1-3C alkyl group, an amino group, a phenyl group, a cyclohexyl group, or a sulfo group.

Abstract: Disclosed is a high-capacity electrochemical energy storage device in which a conversion reaction proceeds as the oxidation-reduction reaction, and the separation (hysteresis) between the electrode potentials for oxidation and reduction is small. The electrochemical energy storage device includes a first electrode including a first active material, a second electrode including a second active material, and a non-aqueous electrolyte interposed between the first and second electrodes. At least one of the first and second active materials is a metal salt having a polyatomic anion and a metal ion, and the metal salt is capable of oxidation-reduction reaction involving reversible release and acceptance of the polyatomic anion.

Abstract: Dry process based energy storage device structures and methods for using a dry adhesive therein are disclosed.

Abstract: The loss of sulfur cathode material as a result of polysulfide dissolution causes significant capacity fading in rechargeable lithium/sulfur cells. Embodiments of the invention use a chemical approach to immobilize sulfur and lithium polysulfides via the reactive functional groups on graphene oxide. This approach obtains a uniform and thin (˜tens of nanometers) sulfur coating on graphene oxide sheets by a chemical reaction-deposition strategy and a subsequent low temperature thermal treatment process. Strong interaction between graphene oxide and sulfur or polysulfides demonstrate lithium/sulfur cells with a high reversible capacity of 950-1400 mAh g?1, and stable cycling for more than 50 deep cycles at 0.1 C.

Abstract: Provided are an anode including spherical natural graphite having a surface coated with an amorphous carbon layer, wherein a crystal orientation ratio is in a range of 0.06 to 0.08 at a compressed density of 1.40 g/cc to 1.85 g/cc, and a lithium secondary battery including the anode. Initial efficiency, electrode adhesion, and capacity characteristics of the lithium secondary battery may be improved by using the anode of the present invention in the lithium secondary battery.

Abstract: Disclosed is a composition for electrode comprising (i) a positive electrode active material comprising an iron compound and carbon, and (ii) a copolymer (P) prepared by copolymerization of acrylic acid esters and/or methacrylic acid esters, with an ?,?-unsaturated nitrile compound. Also disclosed is an electrode comprised of an active material layer made of the composition for electrode, and a collector. This electrode can be produced by mixing the positive electrode active material, the copolymer (P), a solvent and an optional thickener, by a mixer to prepare an electrode composition slurry with solid content of 40-90% by weight, coating a collector with the electrode composition slurry, and then, removing the solvent from the thus-formed coating. Further disclosed a battery provided with the electrode.

Abstract: The invention provides a nonaqueous electrolyte secondary battery having a cathode and an anode arranged so as to be opposite to each other, and an electrolyte layer put therebetween; wherein the cathode comprises: (a) a conductive polymer and (b) at least one selected from the group consisting of a polycarboxylic acid and a metal salt thereof, and wherein the anode comprises a material into which a base metal or ions thereof can be inserted and from which a base metal or ions thereof can be extracted. The invention further provides a cathode sheet for use in the nonaqueous electrolyte secondary battery mentioned above.

Abstract: A lithium ion secondary battery includes a cathode and an anode being opposed to each other with a separator in between, and an electrolytic solution. One or more of the cathode, the anode, and the separator contain an organic silicon compound including a compound having a polysilsesquioxane skeleton.

Abstract: A nonaqueous secondary battery electrode contains, as an electrode active material, a layered composition including organic backbone layers containing an aromatic compound that is a dicarboxylic acid anion having two or more aromatic ring structures and having the two carboxylic acid anions of the dicarboxylic acid anion bonded to diagonally opposite positions of the aromatic compound and alkali metal element layers containing an alkali metal element coordinated to oxygen contained in the carboxylic acid anion to form a backbone. The nonaqueous secondary battery electrode is preferably used as a negative electrode. In addition, the layered composition is preferably formed in layers by ?-electron interaction of the aromatic compound and has a monoclinic crystal structure belonging to the space group P21/c.

Abstract: Disclosed are embodiments of active materials for organometallic and organometallic-inorganic hybrid electrodes and particularly active materials for organometallic and organometallic-inorganic hybrid cathodes for lithium-ion batteries. In certain embodiments the organometallic material comprises a ferrocene polymer.

Abstract: Provided is a battery having a high charging/discharging capacity density as compared with a conventional one. The battery (1) is characterized by comprising a positive electrode (2), a negative electrode (3), and an electrolytic solution interposed between the positive electrode (2) and the negative electrode (3) and formed by dissolving an electrolytic solution in a solvent, wherein the positive electrode (2) includes rubeanic acid or a rubeanic acid derivative as an active material and the solvent includes an ionic liquid. In the battery (1), it is possible to neutralize, by anions present in the ions, positive charges generated when rubeanic acid or the rubeanic acid derivative is oxidized. Therefore, rubeanic acid or the rubeanic acid derivative can take three states from an oxidant to a reductant, so that a high charging/discharging capacity density can be obtained in comparison with a conventional one.

Abstract: The present invention pertains to the selection of cathode materials. The cathode materials of concern are the conducting polymer or backbone and the redox active species or sulfur species. The selection of the materials is based on the characteristics of the materials relating to the other components of the batteries and to each other. The present invention also pertains to the resultant cathode materials, particularly a selected cathode material of a single component sulfur-based conducting polymer with the sulfur species covalently linked to the conducting polymer, and most particularly a thiophene based polymer with covalently linked sulfur species. The conducting polymers have been covalently-derivatized with sulfides and/or sulfide-containing groups as battery cathode materials. The present invention also pertains to a battery employing the selection method and resultant cathode materials.

Abstract: Aspects of the invention are directed to a method for forming a hybrid structure. Initially, a wire is received and an encapsulating film is deposited on the wire. Subsequently, the wire is selectively removed to leave a hollow tube formed of the encapsulating film. A plurality of active particles are then placed into the hollow tube by immersing the hollow tube in a suspension comprising the plurality of active particles and a liquid. Lastly, the hollow tube and the plurality of active particles therein are removed from the suspension and allowed to dry so as to form a cluster of active particles at least partially encapsulated by the encapsulating film.

Abstract: The present invention relates generally to high sulfur content polymeric materials and composites, methods for making them, and devices using them such as electrochemical cells and optical elements. In one aspect, a polymeric composition comprising a copolymer of sulfur, at a level in the range of at least about 50 wt % of the copolymer, and one or more monomers each selected from the group consisting of ethylenically unsaturated monomers, epoxide monomers, and thiirane monomers, at a level in the range of about 0.1 wt % to about 50 wt % of the copolymer.

Abstract: A pasted positive nickel hydroxide electrode for use in battery cells (e.g., in nickel zinc cells, and nickel metal hydride cells) includes nickel hydroxide particles, a cobalt metal and/or cobalt compound and a sulfur-containing complexing agent capable of forming a complex with cobalt. The presence of the sulfur-containing complexing agent, such as dialkyldithiocarbamate (e.g., sodium diethyldithiocarbamate) improves lifetime and capacity utilization of the nickel electrode. The resulting pasted nickel hydroxide electrode includes a CoOOH conductive matrix after formation. The surface of the nickel hydroxide particles in the electrode is modified in some embodiments by providing a cobalt-containing coating onto the surface of the nickel hydroxide particles, followed by oxidation with a strong oxidizing agent. The complexing agent can be added before, after, or during the oxidation.

Abstract: A device is presented having reversibly changeable and optically readable optical properties. The device comprises a substrate having an electrically conductive surface and carrying a redox-active layer structure. The redox-active layer structure may be a monolayer or a multi-layer structure and is configured to have at least one predetermined electronic property including at least one of electrodensity and oxidation state. The electronic property of the layer structure defines an optical property of the structure thereby determining an optical response of the structure to certain incident light. This at least one electronic property is changeable by subjecting the redox-active layer structure to an electric field or to a redox-active material. The device thus enables effecting a change in said electronic property that results in a detectable change in the optical response of the layer structure.

Abstract: In an aspect, a positive active material composition for a rechargeable lithium battery including a positive active material coated with a vanadium pentaoxide (V2O5) and an aqueous binder, a positive electrode including the same, and a rechargeable lithium battery including the positive electrode is disclosed.

Abstract: A conductive reinforcing material used to form a negative electrode material is provided in the present invention. The conductive reinforcing material includes metal shavings containing elements selected from a group consisting of group II elements, group III elements and group VII elements. A negative electrode material and a negative electrode both with the conductive reinforcing material are also provided in the present invention.

Abstract: A lithium ion battery includes a cathode, an anode, and an electrolyte sandwiched between the cathode and the anode. The cathode includes a cathode active material. The anode is spaced from the cathode. The cathode active material includes a sulfur grafted poly(pyridinopyridine). The sulfur grafted poly(pyridinopyridine) includes a poly(pyridinopyridine) matrix and sulfur dispersed in the poly(pyridinopyridine) matrix. The sulfur includes a number of poly-sulfur groups or a number of elemental sulfur particles dispersed in the poly(pyridinopyridine) matrix. The electrolyte is a gel electrolyte.

Abstract: Provided is a positive electrode for a power storage device, which has an excellent discharge characteristic irrespective of an oxidized state of polyaniline as a positive active material and which is excellent in storability and handleability. The positive electrode for a power storage device includes polyaniline, where a ratio of a polyaniline oxidized body in the positive electrode is 0.01 to 75% to the entire polyaniline.

Abstract: A protected active metal electrode and a device with the electrode are provided. The protected active metal electrode includes an active metal substrate and a protection layer on a surface of the active metal substrate. The protection layer at least includes a metal thin film covering the surface of the active metal substrate and an electrically-conductive thin film covering a surface of the metal thin film. A material of the metal thin film is Ti, V, Cr, Zr, Nb, Mo, Hf, Ta, or W. A material of the electrically-conductive thin film is selected from nitride of a metal in the metal thin film, carbide of a metal in the metal thin film, a diamond-like carbon (DLC), and a combination thereof.

Abstract: A nonaqueous secondary battery having a positive electrode having a positive electrode mixture layer, a negative electrode, and a nonaqueous electrolyte, in which the positive electrode contains, as an active material, a lithium-containing transition metal oxide containing a metal element selected from the group consisting of Mg, Ti, Zr, Ge, Nb, Al and Sn, the positive electrode mixture layer has a density of 3.

Abstract: A negative electrode for a lithium secondary battery includes a negative-electrode active material having a specific surface area of Sx (m2/g) and an average particle size of Lx (?m), a fibrous conductive material having a specific surface area of Sy (m2/g) and an average length of Ly (?m), and a granular conductive material having a specific surface area of Sz (m2/g) and an average particle size of Lz (?m), in which letting the negative-electrode active material content be X, letting the fibrous conductive material content be Y, and letting the granular conductive material content be Z, Log((SyY+SzZ)/SxX×10?1)×Log((LyY+LzZ)/LxX×101) is defined as an electrode parameter, and the electrode parameter satisfies Log((SyY+SzZ)/SxX×10?1)×Log((LyY+LzZ)/LxX×101)?0.

Abstract: There is provided a method for manufacturing the lithium ion secondary batteries includes a mixing step of mixing a phenol resin and a resin composition containing silica particles so as to obtain a mixture, a spraying step of spraying the mixture obtained in the mixing step so as to form liquid droplets, a first thermal treatment step of carrying out a first thermal treatment on the liquid droplets obtained in the spraying step so as to generate a carbon precursor, and a second thermal treatment step of carrying out a second thermal treatment, which is carried out at a higher temperature than the first thermal treatment, on the carbon precursor obtained in the first thermal treatment step so as to generate a carbon material containing carbon and silicon oxide represented by SiOx (0<X<2).

Abstract: Provided is an anode for use in electrochemical cells, wherein the anode active layer has a first layer comprising lithium metal and a multi-layer structure comprising single ion conducting layers and polymer layers in contact with the first layer comprising lithium metal or in contact with an intermediate protective layer, such as a temporary protective metal layer, on the surface of the lithium-containing first layer. Another aspect of the invention provides an anode active layer formed by the in-situ deposition of lithium vapor and a reactive gas. The anodes of the current invention are particularly useful in electrochemical cells comprising sulfur-containing cathode active materials, such as elemental sulfur.

Abstract: Rechargeable lithium-sulfur batteries having a cathode that includes a graphene-sulfur nanocomposite can exhibit improved characteristics. The graphene-sulfur nanocomposite can be characterized by graphene sheets with particles of sulfur adsorbed to the graphene sheets. The sulfur particles have an average diameter less than 50 nm.

Abstract: A simple and low cost device to detect the presence of mercury or other trace metals in the environment and quantify said concentration by spectrophotometric, colorimetric, or electrical conductivity is disclosed. Owing to its small size, it is suitable for portable mercury detectors or detectors that may be worn as badges in the breathing zone of workers.

Abstract: In a method for preparing a cathode material for an alkali-sulfur cell, e.g., a lithium-sulfur cell, at least one polyacrilonitrile-sulfur composite material and elemental sulfur are mixed, in order to increase the voltage, the capacitance and the energy density.

Abstract: Provided are a composite and a method of preparing an anode slurry including the same. More particularly, the present invention provides a composite including a (semi) metal oxide, a conductive material on a surface of the (semi) metal oxide, and a binder, and a method of preparing an anode slurry including preparing a composite by dispersing a conductive material in an aqueous binder and then mixing with a (semi) metal oxide, and mixing the composite with a carbon material and a non-aqueous binder.

Abstract: A lithium ion battery is provided which contains a cathode, an anode, an electrolyte and a separator, wherein the anode employs polythiocyanogen as an active material.

Abstract: An electrochemical cell including at least one nitrogen-containing compound is disclosed. The at least one nitrogen-containing compound may form part of or be included in: an anode structure, a cathode structure, an electrolyte and/or a separator of the electrochemical cell. Also disclosed is a battery including the electrochemical cell.

Abstract: To provide a sulfur-system positive electrode for lithium-ion battery, sulfur-system positive electrode which is good in the cyclability and the other characteristics, and a lithium-ion secondary battery including that positive electrode. In a positive electrode for lithium-ion secondary battery, the positive electrode having: a current collector; and an electrode layer that is formed on a surface of the current collector, and which includes a binder resin, an active material and a conductive additive, the positive electrode is characterized in that the active material includes a sulfur-modified polyacrylonitrile that is produced by heating a raw-material powder including a sulfur powder and a polyacrylonitrile powder in an enclosed nonoxidizing atmosphere; and the binder resin includes a polyimide resin and/or a polyamide-imide resin.

Abstract: Disclosed is a polyradical compound which can be used as an electrode active material for at least one of a positive electrode and a negative electrode. The polyradical compound has a repeating unit represented by general formula (1) and is crosslinked using a bifunctional crosslinking agent having two polymerizing groups in the molecule represented by general formula (2), wherein R1 to R3 each independently represent hydrogen or methyl group; R4 to R7 each independently represent C1 to C3 alkyl group; X represents single bond, linear, branched or cyclic C1 to C15 alkylenedioxy group, alkylene group, phenylenedioxy group, phenylene group or structure represented by general formula (3); and R8 to R13 each independently represent hydrogen or methyl group, and k represents an integer of 2 to 5.

Abstract: A negative-electrode active material for secondary battery includes a sulfur-modified polyacrylonitrile. The sulfur-modified polyacrylonitrile includes a polyacrylonitrile, and sulfur being introduced into the polyacrylonitrile.