Abstract: Methods for fabricating cored structures are provided. The cored structures may particularly find usefulness as cored battery plates for use in lead/acid batteries. A pre-formed core element is provided, and on its surfaces there is placed a thin layer of an active surface material. That active surface material is one which may enter into a chemical or electrochemical process when in use and in the presence of an electrolyte or other agent which will promote such chemical or electrochemical process. In the case of lead/acid batteries, the active surface is lead or lead oxide. The core element is generally one which does not bond with the active surface material, but will if the active surface material is ion bombarded or neutral atom embedded into the surface of the core, and where the amount of bombardment or embedment is determined by controlling the accelerator voltage.

Abstract: An electrochemical capacitor device (10) including an anode (20) and a cathode (30) separated by a separator (40) and surrounded by an electrolyte (50). The anode (20) and cathode (30) is fabricated from a multi-valent, multiple oxidation state material. The material has a high, an intermediate, and a low oxidation state. In an initial condition, both the anode and cathode are in the intermediate oxidation state. During charging, one electrode will be oxidized to the higher states, while the other electrode will be reduced to the lower state. The processes are reversed during discharge.

Abstract: The invention provides an electrode for a lead-acid battery, formed in an essentially continuous process without the need for curing under controlled temperature and humidity conditions. This is accomplished by using a relatively high metallic lead content precursor powder intermingled with a leady-oxide powder. Another aspect of the invention is the use of relatively high surface area leady-oxide powder which contributes to performance. Another important aspect of the invention is that the active material paste is prepared without the use of an acid in a water based process which provides a simpler pasting chemistry. The process eliminates the complex basic lead sulfate reactions found in present methods.

Abstract: An improved electrochemical cell is provided using a high surface area can electrodes as the negative electrode in an alkali metal hydroxide electrolyte.

Abstract: A continuous method for making starting, lighting and ignition lead-acid battery positive plates and the resulting battery is disclosed which utilizes a direct cast alloy strip wherein the alloy consists essentially of lead, from about 0.02 to 0.05% calcium, from about 0.3 to about 0.5% tin, and from about 0.02 to 0.05% silver, the percentages being based upon the weight of the alloy strip, as well as related alloys utilizing calcium and strontium or strontium in place of calcium.

Abstract: An integral battery electrode structure for lead/acid battery plates is provided. The principle structure material is elemental lead or lead alloyed with antimony or calcium. At least the surface of the lead or alloy has an ion implanted or atomic embedded graded junction of at least one other atomic species, such as titanium, cadmium, or bismuth. Additionally, highly oxidative atomic species such as fluorine, chlorine, or metallic components such as titanium, tin, vanadium, chromium, or rhodium may be added at the surface of the lead or lead alloy. Optionally, an element such as cadmium, arsenic, uranium, barium or bismuth may be added at the surface and within several atomic layers below the surface in such a manner that the concentration may be from 0.05% to about 10.0% of the total mass in that region but that the total concentration in the electrode structure is from about 50 to about 350 parts per billion.

Abstract: Lithium based electrical cells having a new anode electrode construction are described. The cells have a sandwich construction of lithium sheet, conductive foil and lithium sheet, wherein the anode tab is welded directly onto the conductive foil not onto the lithium. Alternatively, the tab is connected onto the lithium in an area where the lithium does not dissolve during discharge, so that the tab will not become disconnected from the anode sheet.

Abstract: A co-doped lead oxide for use in the manufacture of storage battery plates, the use of such lead oxides improving the efficiency of lead-acid batteries, comprising, as co-dopants, based upon the total weight of the lead oxide, copper in an amount of from about 0.01 to 0.1% and either tin in an amount of from about 0.008 to 0.1% or antimony in an amount of from about 0.005 to 0.08%.

Abstract: Automotive SLI lead-acid batteries are disclosed which are characterized by enhanced resistance to positive grid corrosion, even when exposed to the current, relatively high under-the-hood service temperatures in use with recent model automobiles. The grids are formed from either a cast lead-based alloy including from about 0.025 to 0.06% calcium, from about 0.3 to 0.7% tin and from about 0.015 to 0.045% silver, the percentages being based upon the weight of the alloy prior to casting or a wrought lead-based alloy including from about 0.02 to 0.05% calcium, from about 0.3 to 0.5% tin and 0.02 to 0.045% silver, the percentages being based upon the weight of the alloy. Aluminum in an amount of from about 0.008 to about 0.012%, based upon the as-added total weight of the alloy may be used to maintain the desired calcium content during casting.

Abstract: A teflon-bonded thin, flexible .beta."-Al.sub.2 O.sub.3 solid electrolyte parator is provided for use in a high temperature electrochemical cell including a sodium-lead alloy anode (Na.sub.0.9 Pb.sub.0.1) and an FeS.sub.2 cathode.

Abstract: A composition of lead and aluminum is disclosed with particular utility as a battery grid material. Rapid solidification techniques permit manufacture of a composition with between about 0.1% and 20% by weight aluminum, and the balance lead.

Abstract: A rechargeable negative electrode for an electrochemical apparatus using nonaqueous electrolytes, said electrode comprising an alloy comprising (1) at least one metal selected from the group consisting of Sn, Pn, In and Bi and (2) Zn or Zn and Cd, as well as a rechargeable electrochemical apparatus comprising a combination of said negative electrode with a positive electrode having reversibility in charging and discharging. The above-mentioned negative electrode reversibly absorbs and desorbs alkali metal ions, as the result of charge and discharge, in nonaqueous electrolyte containing alkali metal ions. It undergoes no pulverization even after repeated charge and discharge, and maintains its shape stably, so that it has a long charge-and-discharge cycle life. Further, since it can absorb a large quantity of alkali metal per unit volume, it is of high energy density.

Abstract: A rechargeable electrochemical device comprising a cathode (6) composed chiefly of activated carbon, anode (3) composed of a lithium alloy, and an electrolyte composed of an organic solvent in which a lithium salt is dissolved. Lithium content in the lithium alloy forming the anode (3) is selected such that, if converted to the electric capacity under the charged condition, the capacity of this alloy ranges from 3 to 20 times the cathode capacity that is obtained when the cathode is discharged from 3.0V to 2.0V in a single-pole potential with respect to metal lithium. This constitution is able to provide a reliable rechargeable electrochemical device, which is proof against super-discharge and excellent in charge and discharge cycle life.

Abstract: The present invention relates to a composite material comprising a porous lead alloy containing from 0.7 to 1.0% silver or 0.1 to 1.0% calcium or 0.7 to 1.0% silver and 0.1 to 1.0% calcium and having its pores filled by a resin such as epoxy resin. The product has utility as a battery electrode and as a sound absorbing material.

Abstract: A bipolar electrode for generating electrical power in an electrochemical cell includes a base member, which is comprised of a core portion composed of titanium. An integral, substantially continuous and non-porous layer of lead is electroplated onto at least one face surface of the core portion and diffused a selected distance into the core portion. A substantially continuous, residual layer of the titanium alloy in the core portion remains substantially free of lead. A negative-type active mass is connected to a first face surface of the base member, and a positive-type active mass is connected to a second face surface of the base member.

Abstract: Gassing is significantly reduced in electrochemical cells having anodes of polycrystalline metals, such as zinc, by heat treatment of the anode metal at a temperature below that of the melting point of the metal for a period of time sufficient to reduce the number of grains in the polycrystalline metal to at least a third of the original number of grains and thereafter using the metal in the formation of the cell anode. With such gassing reduction, the amount of mercury required for amalgamation with the zinc may also be reduced.

Abstract: A lead-based alloy containing, based upon the total weight of the alloy, 0.8-1.6% antimony, 0.08-0.16% arsenic, 0.006-0.012% silver and, optionally, 0.2-0.5% tin, is disclosed for making lead-acid battery grids using a continuous casting process.

Abstract: A maintenance-free, lead-acid cell that is capable of achieving long cycle life in deep discharge rapid recharge applications is sealed, has positive grids formed from antimony-lead alloys containing no more than about 2 wt. % of antimony, has negative grids formed from alloys that are essentially antimony-free, has highly porous, easily wetted separator material interposed between the plates which is capable of wicking the electrolyte, and provides a sufficient void volume to facilitate gaseous oxygen transport, and has the electrolyte required for operation of the cell substantially completely absorbed in the plates and separators, with the separators not being completely saturated.

Abstract: Wrought, recrystallized, lead-calcium-tin, battery grid alloy consisting essentially of about 0.07% to about 0.11% by weight calcium no more than about 0.35% by weight tin and the balance principally lead.

Abstract: A lead alloy particularly suited for use in lead-acid type storage batteries having the following composition by weight:______________________________________ Strontium 0.01%- 2.0% Tin 0.1%- 5.0% Aluminum 0.005%- 0.1% Copper 0- 0.

Abstract: An electric storage battery grid made from an improved low antimonial content lead alloy is disclosed. The battery grid can be used to manufacture maintenance free lead acid storage batteries. The alloy has an improved combination of low gassing rate and hardness, castability and pasteability and contains less than 2.0%, i.e. approximately 1.3 to 1.9 weight percent antimony, 0.05 to 0.45 percent arsenic and 0.02 to 0.5 weight percent tin as well as small amounts of copper and sulfur.

Abstract: There is disclosed a battery electrode structure made of a lead-calcium-tin alloy comprising 0.075 to 0.13% by weight calcium, 0.005 to 0.99% by weight tin and 0.0001% to 0.1% by weight aluminium, the balance being substantially lead.

Abstract: The invention is a rechargeable voltaic cell in which both the cathodic and anodic reactants are derived from the electrolyte. The cell comprises an anode of lead mercury amalgam, an electrolyte of lead sulfamate and sulfamic acid and a cathodic reactant supported on a stainless steel base.

Abstract: A cadmium-tin-lead alloy composition containing at least 0.4 percent by weight of both cadmium and tin is used for forming the straps employed which weld together the lugs of the grids in lead-acid storage batteries. The relatively small amount of cadmium and tin provide a large volume fraction of a cadmium-tin eutectic phase that is low melting and serves to facilitate the welding. This alloy composition may also be used to form intercell connectors and terminal posts for such batteries.

Abstract: A maintenance-free battery having improved current draw characteristics is provided by adding elemental cadmium, or a cadmium affording compound such as cadmium sulfate to the electrolyte in amounts sufficient to decrease the current draw that would otherwise occur during overcharge.

Abstract: A lead alloy is prepared by dispersing minor amounts by weight of silicon in a continuous lead phase. The alloy has a lesser density than unalloyed lead and has improved strength, excellent corrosion resistance, good electrical conductivity, and satisfactory workability.

Abstract: A lead-antimony alloy is disclosed containing 0.5-3.5% by weight antimony, 0.025-0.3% by weight arsenic, 0.005-0.1% by weight selenium, 0.002-0.05% by weight tin, 0.01-0.1% by weight copper, balance lead. The alloy also preferably contains from 0.025-0.1% by weight silver.

Abstract: Lead alloy for the grids of lead storage batteries, which comprises from 1.0 to 3.5 % antimony, 0.025 to 0.2 % arsenic, 0.005 to 0.1 % selenium, 0.05 to 0.5 % tin, and the remainder lead.Preferably the alloy also contains 0.025 to 0.1 % silver.