Abstract: An anode material for lithium-ion batteries is provided that comprises an elongated core structure capable of forming an alloy with lithium; and a plurality of nanostructures placed on a surface of the core structure, with each nanostructure being capable of forming an alloy with lithium and spaced at a predetermined distance from adjacent nanostructures.

Abstract: A method for preparing a positive active material for a rechargeable lithium battery includes: a) providing a furnace and a crucible that is included in the furnace; b) putting a mixture of a composite metal precursor and a lithium compound into the crucible; and c) preparing a positive active material for a rechargeable lithium battery by firing the mixture in the crucible, wherein during the process b), the mixture in the crucible is positioned so that a minimum distance from a predetermined position inside the mixture to an exterior of the mixture in the crucible is about 5 cm or less. A rechargeable lithium made by this method is disclosed.

Abstract: A grid network for a battery plate is provided. The grid network includes a plurality of spaced apart grid wire elements, each grid wire element having opposed ends joined to one of a plurality of nodes. Each node includes the juncture of one of the opposed ends of a plurality of the grid wire elements to define a plurality of open spaces in the grid network. At least one of the grid wire elements has a first transverse cross-section intermediate its opposed ends that is a different shape than a second transverse cross-section at at least one of the grid wire element's opposed ends.

Abstract: The present invention relates to one or more electrode plates, which are installed with current collecting terminals at two or more sides thereof, and joined to an auxiliary conductor made of a material having a conductivity that is higher than that of the electrode plates. Current collecting terminals are installed at two or more sides of the auxiliary conductor, for linking with current collecting terminals installed at two or more sides of the electrode plates, and at least one of linked terminals is used as a general current collecting terminal to output current to an external part or to receive input current from the external part. Finally, insulators installed between the auxiliary conductor and the electrode plates to constitute an electrode unit.

Abstract: A battery grid is provided having a frame that includes a top element, a bottom element, a first side element, and a second side element. A current collection lug is coupled to the top element. The battery grid includes a plurality of wires provided within the frame and defining a plurality of open areas. The plurality of wires includes a plurality of linear vertical wire members which extend from the top element toward the bottom element, first side element, or second side element. At least one of the linear vertical wire members includes a discontinuity terminating the linear vertical wire member before reaching the bottom element, first side element, or second side element, the discontinuity being defined by parallel horizontal wire members defining an open space.

Abstract: A method of forming battery grids or plates that includes the step of mechanically reshaping or refinishing battery grid wires to improve adhesion between the battery paste and the grid wires. The method is particularly useful in improving the past adhesion to battery grids formed by a continuous batter grid making process (such as strip expansion, strip stamping, continuous casting) that produces grid wires and nodes with smooth surfaces and rectangular cross-section. In a preferred version of the method, the grid wires of battery grids produced by a stamping process are deformed such that the grid wires have a cross-section other than the rectangular cross-section produced by the stamping process. The method increases the cycle life of a battery.

Abstract: A grid network for a battery plate is provided. The grid network includes a plurality of spaced apart grid wire elements, each grid wire element having opposed ends joined to one of a plurality of nodes. Each node includes the juncture of one of the opposed ends of a plurality of the grid wire elements to define a plurality of open spaces in the grid network. At least one of the grid wire elements has a first transverse cross-section intermediate its opposed ends that is a different shape than a second transverse cross-section at least one of the grid wire element's opposed ends.

Abstract: A method of forming battery grids or plates that includes the step of mechanically reshaping or refinishing battery grid wires to improve adhesion between the battery paste and the grid wires. The method is particularly useful in improving the paste adhesion to battery grids formed by a continuous battery grid making process (such as strip expansion, strip stamping, continuous casting) that produces grid wires and nodes with smooth surfaces and a rectangular cross-section. In a preferred version of the method, the grid wires of battery grids produced by a stamping process are deformed such that the grid wires have a cross-section other than the rectangular cross-section produced by the stamping process. The method increases the cycle life of a battery.

Abstract: A battery grid includes a frame that includes a top element, a bottom element, a first side element, and a second side element. The battery grid also includes a plurality of wires provided within the frame and defining a plurality of open areas and a current collection lug extending from the top element in a first direction. The battery grid further includes at least one feature provided in the battery grid that is configured to reduce the amount of growth of the battery grid in the first direction due to corrosion of the battery grid during the life of the battery grid.

Abstract: A new cathode design has a first cathode active material of a relatively low energy density but of a relatively high rate capability contacted to the outer sides of first and second cathode current collectors and a second cathode active material having a relatively high energy density but of a relatively low rate capability in contact with the inner sides of the current collectors. The first and second current collectors have a thickness in the range of from about 0.001 inches to about 0.002 inches. A conventional Li/SVO cell powering an implantable medical device has the cathode with a current collector of about 0.003 inches. Even though the present current collectors are about one-half as thick as that of a conventional cell, their combined thickness means that the cell has no reduction in current carrying capacity.

Abstract: The invention provides an anode capable of relaxing stress due to expansion and shrinkage of an anode active material layer associated with charge and discharge, or an anode capable of reducing structural destruction of the anode active material layer and reactivity between the anode active material layer and an electrolyte associated with charge and discharge, and a battery using it. The anode active material layer contains an element capable of forming an alloy with Li, for example, at least one from the group consisting of simple substances, alloys, and compounds of Si or Ge. An interlayer containing a material having superelasticity or shape-memory effect is provided between an anode current collector and the anode active material layer. Otherwise, the anode current collector is made of the material having superelasticity or shape-memory effect. Otherwise, a thin film layer containing the material having superelasticity or shape-memory effect is formed on the anode active material layer.

Abstract: A battery providing a storage of electrical energy with electrolytic processes of charging and discharging, comprising a first vessel having a front wall formed as an electrode, a second vessel having a front wall formed as an electrode, the vessels being arranged so that the front walls formed as electrodes face one another, the vessels being filled with an electrolyte, the vessels having other walls which are composed of dielectric.

Abstract: An electrode according to the present invention employs the metal plate having the specified structure as the electrode substrate. The metal plate 51 has a plurality of protuberances 54 that are alternately protruded on both front and back sides thereof. Each of the protuberances 54 is formed in a pyramid shape in which an area of upper bottom 52 (a protruded part) thereof is smaller than that of a lower bottom 53. The upper bottom 52 in each of the protuberances 54 is formed with an aperture 56 having blanking burr 55 blinked in a substantially pyramid shape along a direction from the upper bottom 52 to the lower bottom 53 so that an opening 52a of the upper bottom part is formed in a polygon shape. Further, the size of each portions is set in accordance with c>s?0.1 mm2 and 0.2?h/d?0.

Abstract: Provided is a battery capable of improving cycle characteristics without increasing the thickness of an anode current collector. An anode active material layer including at least one kind selected from the group consisting of Sn and compounds thereof is formed on an anode current collector having a projection on a substrate through a vapor deposition method, a liquid-phase deposition method or a sintering method, and the anode current collector and the anode active material layer are alloyed with each other in at least a portion of an interface therebetween. By a function of the projection, the anode current collector can be prevented from being cracked into small pieces due to expansion and shrinkage of the anode active material layer. Further, a stress on the anode active material layer due to the expansion and the shrinkage can be spread out so that cracks produced in the anode active material layer can be scattered in various directions to reduce the size of the cracks.

Abstract: A method for treating electrode tabs of a crude cell for a lithium secondary battery, crude cell for a lithium secondary battery manufactured according to the method, and a lithium secondary battery employing the crude cell are disclosed.

Abstract: A battery unit for a secondary battery that includes a positive electrode plate, a positive electrode tab, a negative electrode plate, a negative electrode tab, a separator, and short circuit preventing units, wherein the short circuit preventing units are formed on corresponding uncoated areas of the positive and negative electrode current collectors where the positive and negative electrode sheets are not formed, each short circuit preventing unit having a corresponding width greater than a width of the corresponding positive and negative electrode current collectors.

Abstract: A new cathode design has a first cathode active material of a relatively low energy density but of a relatively high rate capability contacted to the outer sides of first and second cathode current collectors and a second cathode active material having a relatively high energy density but of a relatively low rate capability in contact with the inner sides of the current collectors. The second cathode active material has a greater peripheral extend than the current collectors and the opposed layers of the first cathode active material between which it is sandwiched. This construction helps prevent delamination by promoting improved contact of the respective active materials to the current collectors. The present cathode design is useful for powering an implantable medical device requiring a high rate discharge application.

Abstract: A method of making a battery includes forming a strip of interconnected grids from a grid material by feeding a continuous strip of the grid material along a linear path aligned with the longitudinal direction of the strip and punching grid material out of the strip. Each interconnected grid includes a plurality of wires, with each wire having opposed ends joined to one of a plurality of nodes to define a plurality of open spaces. The method also includes modifying at least one of the wires at a position intermediate the opposed ends of the wire such that a first transverse cross-section taken intermediate the opposed ends of the wire differs from a second transverse cross-section of the wire taken at one of the opposed ends of the wire. The method further includes applying paste to the strip and cutting the strip to form a plurality of plates.

Abstract: The present invention relates to a current collector for an electrochemical cell. The current collector has a unique grid structure comprised of a frame supporting a plurality of radial strands as conductors radiating outwardly from a focal point on a connector tab. The frame and radial conductors are maintained in a fan-like orientation with respect to each other by two groups of concentric conductor strands, one located adjacent to the tab, the other spaced a substantial distance therefrom. The radiating conductors provide a more direct path to the connector tab for electron flow. This results in the current collector having reduced internal resistance in comparison to conventional current collector designs.

Abstract: Concave portions and convex portion are formed on a peripheral surface of a thin metal sheet by applying a pressing force thereto while the metal sheet is being embossed; pores are each formed on an apex of each of the concave portions and convex portions and burrs each projecting outward from a peripheral edge of each of the pores are generated by the pressing force, the metal sheets having the concave portions and convex portions formed thereon are layered on each other; the burr at the apex of each convex portion of a lower-layer metal sheet is interlocked with the burr at the apex of each concave portion of a upper-layer metal sheet adjacent to the lower-layer metal sheet to integrate the metal sheets with each other; and an active substance is charged into spaces between the upper-layer sheet and the lower-layer metal sheet through and aperture at the apex of each of the concave portions and convex portions.

Abstract: The invention is directed to an electrochemical cell having at least one of its electrodes produced by coating a slurry mixture of an active material, possibly a conductive additive, and a binder dispersed in a solvent and contacted to a perforated current collector foil. It is particularly important that the active slurry does not move through the perforations of the current collector. For this reason, a barrier is placed against the opposite side of the current collector to block the perforations as the current collector is being coated with the slurry. After volatilizing the solvent, a second, different active material is coated to the opposite side of the current collector, either as a slurry, a pressed powder, a pellet or a free standing sheet. An example of this is a cathode having a configuration of: SVO/current collector CFx. The opposed active materials on the current collector can also be of the same chemistry.

Abstract: In a nonaqueous electrolyte secondary cell comprising a rolled-up electrode unit 4 encased in a cell can 1, a striplike current collector forming an electrode has an edge 48 projecting from at least one of opposite ends of the electrode unit. A current collecting plate 5 is joined to the current collector edge 48. A plurality of circular-arc protrusions 52 projecting in a circular-arc cross section and a plurality of slit pieces 53 are formed radially on the current collecting plate 5 and opposed to the current collector edge 48. The collecting plate 5 is welded to the current collector edge 48, with the protrusions 52 and the slit pieces 53 biting into the current collector edge 48, whereby high current collecting performance is available.

Abstract: The invention relates to an essentially flat electrode of an electrochemical system, such as a battery or a capacitor. Said electrode is comprised of at least one conductive (3) and of a storage layer (4), which is connected to said conductive layer, has a lattice structure, is comprised of woven or knit plastic threads (5) that are rendered conductive, and in which electro-active material is embedded. The aim of the invention is to improve the volumetric and gravimetric energy density with an adequate mechanical stability and simplified production.

Abstract: A new sandwich cathode design having a second cathode active material of a relatively high energy density but of a relatively low rate capability sandwiched between two current collectors and with a first cathode active material having a relatively low energy density but of a relatively high rate capability in contact with the opposite sides of the two current collectors, is described. The present cathode design is useful for powering an implantable medical device requiring a high rate discharge application.

Abstract: An encapsulated electrode assembly which retains a highly reactive material to enhance reaction efficiency within a liquid electrolyte battery cell. The electrode assembly comprises a structural member of a first active material formed into a chamber within which is retained a highly reactive non-structural second active material that preferably comprises a particulated form of reactive material which provides increased electrochemical reaction per unit area in relation to the first reactive material. By way of example, when the invention is practiced within a lead-acid battery, the electrode pouch preferably comprises a reactive structural lead alloy, and the highly reactive material comprises lead containing compounds that support charge generation within the battery. The encapsulated electrode may additionally incorporate grids within, and in contact with, the chamber to further reduce current density within the electrode.

Abstract: An electrode includes an expanded grid and an active material provided on the grid, the thickness of the grid is the same as the strand and connecting sections of the strand, presenting a waveform as a whole. When this grid is used in the electrode as a current collector, the connecting sections are located near the center of the thickness direction of the electrode and strand are arranged by projecting upward and downward, respectively, from the boundary where the connecting sections are situated. Accordingly, a lead-acid storage battery having long life characteristics is made available.

Abstract: A lithium secondary battery capable of improving high temperature cycle life characteristic effectively without decreasing discharge capacity. Amorphous carbon powder with a specific surface area of 10.0 m2/g and a mean particle diameter of 7.0 &mgr;m is used as negative electrode active material and lithium manganate with a Li/Mn ratio of 0.58 is used as positive electrode active material. Since a surface area of the negative electrode active material layer is made large by setting the mean particle diameter of the amorphous carbon powder to 10 &mgr;m or less, the surface area of the negative electrode active material layer is sufficiently large that, even when inert coating is formed on the surface of the negative electrode due to manganese deposition caused by manganese elution from the positive electrode, high temperature cycle life characteristic can be improved without high temperature deterioration.

Abstract: A fuel cell corrugated current collector having successive spaced rows of corrugations, with the corrugations in a given row establishing successive peak and valley regions along the given row and the spaced rows of corrugations being adapted so that corresponding peak regions from row-to-row establish through passages for receiving and supporting solid catalyst elements. The spaced rows of corrugations are such that there is a given pitch between successive peak regions. The corrugations in the rows are also such that corresponding peak regions from row-to-row have a finite off-set which is less than 50 percent of the pitch. This establishes a plurality of through passages in the current collector each extending from row-to-row for receiving and supporting the solid catalyst elements. Also, the off-set is based on the catalyst dimensions and is set such that the corrugations engage the catalyst elements.

Abstract: A primed current collector for use in an electrochemical cell comprising a current collector having a first surface and a second surface, and a primer applied to at least a portion of the first and/or second surfaces of the current collector, wherein the primer comprises a uniform layer of lithium polysilicate.

Abstract: A lithium secondary battery includes an internal electrode body including a positive electrode, a negative electrode, and a separator. The positive electrode and the negative electrode are wound or laminated via the separator so that the positive electrode and the negative electrode are not brought into direct contact with each other. At least a plurality of tabs for current collecting were provided to have a total cross-sectional area of the tabs be not less than a constant area in accordance with the quality of the material to be used for the tabs so that the tabs to be connected to each of the positive and negative electrodes may not respectively fuse when at least 100 A current has flown through the lithium secondary battery. The lithium secondary battery maintains a good charge-discharge cycle characteristics, and safety may be secured with electricity being cut off when an excess current has occurred due to external short circuit, etc., so that the battery may not be exploded nor be ignited.

Abstract: An electrode comprises a porous three-dimensional conductive support and at least one reinforcing metal band fixed along a longitudinal edge portion of the support and having a coefficient of elongation to rupture equal to at least 20% in a direction parallel to the edge portion of the support. Two longitudinal edge portions of the band are bent against the same face of the band, at least part of whose surface is pressed against the support.

Abstract: A method of forming battery grids or plates that includes the step of mechanically reshaping or refinishing battery grid wires to improve adhesion between the battery paste and the grid wires. The method is particularly useful in improving the paste adhesion to battery grids formed by a continuous battery grid making process (such as strip expansion, strip stamping, continuous casting) that produces grid wires and nodes with smooth surfaces and a rectangular cross-section. In a preferred version of the method, the grid wires of battery grids produced by a stamping process are deformed such that the grid wires have a cross-section other than the rectangular cross-section produced by the stamping process. The method increases the cycle life of a battery.

Abstract: A cylindrical alkaline storage battery including a spiraled electrode body composed of a pair of opposed electrodes spirally rolled up through a separator and coupled within a cylindrical casing, at least one of the electrodes being in the form of a non-sintered type electrode composed of an active material retention substrate of three dimensionally meshed structure impregnated with paste of an active material, and a current collector formed with a disc portion for connection to one end portion of the non-sintered type electrode and a lead portion for connection to a terminal, wherein the one end portion of the non-sintered type electrode is formed without impregnation of the paste of the active material, and wherein a perforated sheet metal welded to the one end portion of the non-sintered type electrode is welded at its side edge to the disc portion of the current collector.

Abstract: A plate-like current collector and the method of producing the same, said collector comprising a metal foil having a plurality of bowl-like projections, each projection projecting downwardly from the front side thereof to the reverse side thereof and having a penetrated hole in the center of the projection, a turning peripheral portion of the central penetrated hole formed to curve upwardly to a level positioning beneath the front side of the metal foil, wherein the penetrated hole may be enlarged or contracted using the elastic deformation of the turning peripheral portion.

Abstract: A primer material for use with an electrode. The primer includes a fluid medium and electrochemically inert particulate having a dimensional thickness greater than the dimensional thickness of the fluid medium after the fluid medium is at least partially dried.

Abstract: A current collector for an electrode with two halves. The current collector has a first layer positioned on the first half of the electrode, a second layer positioned on the second half of said electrode, and a third layer positioned between the first and the second halves of the electrode.

Abstract: An electrochemical cell system including an anode compartment and a cathode compartment separated by a membrane and electrode structure. This structure has an anode surface with a plurality of anodes in a side-by-side arrangement exposed to the anode compartment and a cathode surface with a plurality of cathodes in a side-by-side arrangement exposed to the cathode compartment. The anodes and cathodes are separated by a layer of ion exchange polymer and register with each other so that opposing pairs of anodes and cathodes form cells. The membrane and electrode structure further includes a plurality of current collector screens. The current collector screens have an anode contact area in contact with the anode, a cathode contact area in contact with the cathode and a feed through area extending between cells and crossing from the anode contact area to the cathode contact area to connect the anode and cathode of adjacent cells.

Abstract: Electrodes, particularly useful in bipolar plates of lead-acid batteries, include a metal-containing substrate, an electrically conductive material secured to the first side of the substrate, an electrically conductive layer including a polymer secured to the second side of the substrate; and a metallic layer secured to the electrically conductive layer so that the electrically conductive layer is located between the metallic layer and the substrate. Bipolar plates are provided and include an electrically conductive electrode element, a grid spaced apart from the electrode in proximity to the first side of the electrode element, positive active material in contact with the first side or second side of the electrode element and negative active material in contact with the first side or second side of the electrode element which is not in contact with the positive active material.

Abstract: Electrical connection is maintained between an electrical conductor element (32) and a fragile expanded-metal grid current collector element (12) of a flexible laminate structure rechargeable battery (10) by means of thermally-activated adhesive sheet material (34) which provides physical reinforcement as well as maintaining stable electrically-conductive contact between the elements, Such adhesive materials comprising a metal foil surface (46) may also provide direct electrical connection between current collector or battery electrode elements and external utilization devices.

Abstract: An electrolytic cell having an electrolyte, a first and second electrode and a primer comprised of lithium polysilicate and carbon, applied to at least one of the first and second electrodes, wherein the primer is chemically and electrochemically stable and electronically conductive so as to decrease interfacial resistance in the cell to enhance columbic efficiency.

Abstract: The present invention is directed to a method of manufacturing battery grids. In particular, a method of simultaneously casting multiple battery grid strips on a continuous casting machine is provided. The mold includes a bipartite grid cavity having a pair of adjacent grid cavity segments which communicate with each other through a common groove such that the resultant dual grid strip formed thereon includes a corresponding pair of grid strip segments that are interconnected by a series of flexible or frangible nodes. A dual grid strip can be folded along the flexible or frangible nodes to form a layered grid strip. The layered grid strip is then pasted with an active material and cut into individual battery plates.

Abstract: A current collector for use in a cell. The current collector has a thin sheet of conductive material having oppositely directed planar faces. The sheet is preferably graphite. The current collector also has a metal tab having oppositely directed planar faces. A face of the tab is in planar contact with a face of the sheet. The current collector may further have a second thin sheet of conductive material, preferably graphite, having oppositely directed planar faces. The second sheet is placed in planar contact with the tab such that the tab is disposed between the two conductive sheets.

Abstract: A battery separator composed of a microporous sheet product having first and second major surfaces and a thickness of less than about 50 mils, formed from a uniform mixture of a thermoplastic polyurethane polymer having a high degree of hard segments with a filler or said polyurethane with a structure enhancing agent, said sheet product having a sheet embedded within said mixture and between the first and second major surfaces. The sheet product has porosity of at least about 50 volume percent composed of pores such that the nominal pore diameter increases from each major surface towards the interior, center of the sheet product's thickness.

Abstract: Air is blown into filter tow during or immediately after the application of plasticizer; this foams and distributes the plasticizer in the tow. Air may be delivered from a porous plate closely adjacent to the path of the tow or from nozzles in an air injecting unit. Alternatively air may be used to foam plasticizer at a location remote from the tow and foamed plasticizer subsequently conveyed to and into the tow by a roller.

Abstract: A tranquillo-sedative substituted 1,3,4,5-tetrahydro-2H-1,4-benzodiazepine-2-one of the formula (I), ##STR1## wherein R.sub.1 is halogen or nitro,R.sub.2 is hydrogen or methyl,R.sub.3 is --CONH.sub.2 or --CONHCH.sub.3, andR.sub.6 is phenyl or halophenyl.

Abstract: This invention relates to a battery plate grid of the type that are cast from lead and which have a perimeter frame and a lattice network of bars formed integrally with the frame. The plate grid has protuberances spaced apart on one side only of the lattice network and formed integrally therewith. The perimeter frame has a greater thickness than the lattice network and the principal plane of the lattice network is between the spaced apart planes of opposed face surfaces of the perimeter frame. The protuberances on one side of the lattice network have a height of about one-half the difference in thickness between the lattice network and the perimeter frame so that the outer extremities of the protuberances are in the plane of one face of the frame and serve to rigidify the lattice network during application of the paste.