Abstract: A battery voltage equalizer circuit for equalizing battery voltages among a plurality of battery cells in a serial connection is disclosed. The battery voltage equalizer circuit includes a battery voltage equalizer unit having a plurality of equalizer parts, wherein each equalizer part, coupled to a positive terminal and a negative terminal of a corresponding battery cell, is conducted with an equalization current upon a receipt of an equalization signal, and a battery voltage detector unit, coupled to the positive and negative terminals of the plurality of battery cells, generates the equalization signal so as to conduct the battery voltage equalizer unit as long as a voltage of any one of the battery cells reaches an equalization voltage.

Abstract: The disclosure provides an alkali metal-metal halide battery cell. The alkali metal-metal halide battery cell comprises a separator; a cathode compartment; and an anode compartment disposed on the opposite side of said separator; wherein the cathode current collector is one of an over-sized current collector, a brush-like current collector, or a combination thereof. The battery cell has improved propertied, such as reduced internal resistance and improved discharging properties.

Abstract: Disclosed is an organic/inorganic composite porous film comprising: (a) inorganic particles; and (b) a binder polymer coating layer formed partially or totally on surfaces of the inorganic particles, wherein the inorganic particles are interconnected among themselves and are fixed by the binder polymer, and interstitial volumes among the inorganic particles form a micropore structure. A method for manufacturing the same film and an electrochemical device including the same film are also disclosed. An electrochemical device comprising the organic/inorganic composite porous film shows improved safety and quality.

Abstract: A eutectic formulation of KOH and NaOH is used as an electrolyte or an electrolyte-separator. An anode, and/or a cathode can contain the eutectic formulation of KOH and NaOH. A battery can contain an electrolyte-separator, an anode, and/or a cathode with the eutectic formulation of KOH and NaOH. The electrolyte in the electrolyte-separator can have a melting point from about 170° C. to about 300° C. making it suitable for use in a thermal battery that does not require a pyrotechnic device for certain high-temperature applications.

Abstract: A nonaqueous electrolyte composition includes: a nonaqueous solvent; an electrolyte salt; a matrix resin; a filler; and a surfactant.

Abstract: A main object of the present invention is to provide an ion conductor which has excellent ion conductivity and high electrochemical stability. The present invention resolves the problem by providing an ion conductor represented by a general formula: (AxM1-x-yM?y)Al2O4 (“A” is a monovalent metal, “M” is a bivalent metal, “M?” is a trivalent metal, and “x” and “y” satisfy relations: 0<x<1, 0<y<1, and x+y<1) and having a spinel structure.

Abstract: A main object of the present invention is to provide a solid electrolyte material having excellent Li ion conductivity. To attain the object, the present invention provides a solid electrolyte material represented by a general formula: Lix(La1-aM1a)y(Ti1-bM2b)zO?, wherein “x”, “y”, and “z” satisfy relations of x+y+z=1, 0.850?x/(x+y+z)?0.930, and 0.087?y/(y+z)?0.115; “a” is 0?a?1; “b” is 0?b?1; “67 ” is 0.8???1.2; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga.

Abstract: A composite solid electrolyte includes a monolithic solid electrolyte base component that is a continuous matrix of an inorganic active metal ion conductor and a filler component used to eliminate through porosity in the solid electrolyte. In this way a solid electrolyte produced by any process that yields residual through porosity can be modified by the incorporation of a filler to form a substantially impervious composite solid electrolyte and eliminate through porosity in the base component. Such composites may be made by disclosed techniques. The composites are generally useful in electrochemical cell structures such as battery cells and in particular protected active metal anodes, particularly lithium anodes, that are protected with a protective membrane architecture incorporating the composite solid electrolyte.

Abstract: A main object of the present invention is to provide a Li-La-Ti-O based solid electrolyte material having high Li ion conductivity in the crystal grain boundary. The present invention attains the object by providing solid electrolyte material represented by a general formula: Li3x(La(2/3?x)?aM1a) (Ti1?bM2b)O3, wherein “x” is 0<x<0.17; “a” is 0?a?0.5; “b” is 0?b?0.5; “M1” is at least one selected from the group consisting of Sr, Na, Nd, Pr, Sm, Gd, Dy, Y, Eu, Tb, and Ba; and “M2” is at least one selected from the group consisting of Mg, W, Mn, Al, Ge, Ru, Nb, Ta, Co, Zr, Hf, Fe, Cr, and Ga, and wherein the solid electrolyte material is a crystalline material, is in thin film form, and has a thickness of 250 nm to 850 nm.

Abstract: In the all-solid secondary battery of the present invention, a positive electrode layer and a negative electrode layer are disposed on both sides of a solid electrolyte layer, a first inorganic solid electrolyte and a second inorganic solid electrolyte are included into at least one of the positive electrode layer, the negative electrode layer, and the solid electrolyte layer, the content of transition metal in the first inorganic solid electrolyte is less than 15% by mass on oxide basis, and the content of transition metal in the second inorganic solid electrolyte is 15% by mass or more on oxide basis.

Abstract: The invention relates to a unique battery having a physicochemically active membrane separator/electrolyte-electrode monolith and method of making the same. The Applicant's invented battery employs a physicochemically active membrane separator/electrolyte-electrode that acts as a separator, electrolyte, and electrode, within the same monolithic structure. The chemical composition, physical arrangement of molecules, and physical geometry of the pores play a role in the sequestration and conduction of ions. In one preferred embodiment, ions are transported via the ion-hoping mechanism where the oxygens of the Al2O3 wall are available for positive ion coordination (i.e. Li+). This active membrane-electrode composite can be adjusted to a desired level of ion conductivity by manipulating the chemical composition and structure of the pore wall to either increase or decrease ion conduction.

Abstract: A solid electrolyte is disclosed. The solid electrolyte includes a main portion that includes ?-alumina or ??-alumina, and an edge portion integrally provided with the main portion. The edge portion has a mixed portion that includes ?-alumina and includes ? alumina or ??-alumina. A concentration gradient of the ?-alumina in the edge portion decreases in a first direction from the edge portion to the main portion.

Abstract: A beta alumina solid electrolyte (BASE) and a method of preparing the same are provided. When the method is used, evaporation of sodium is suppressed and thus a beta alumina solid electrolyte having a high density, a low porosity, and a composition that is near a desired (target) composition is produced.

Abstract: An automotive power supply system comprises a battery module that includes serially connected battery groups each constituted with serially connected battery cells, integrated circuits each disposed in correspondence to one of the battery groups, a control circuit, a transmission path through which the integrated circuits are connected to the control circuit and a relay circuit via which an electrical current is supplied from the battery module. In response to a start signal instructing an operation start and received via the transmission path, each integrated circuit measures terminal voltages at the individual battery cells in the corresponding battery group and executes an abnormality diagnosis. If abnormality diagnosis results provided by the integrated circuits indicate no abnormality, the control circuit closes the relay, enabling supply of electrical current from the battery module and subsequently, the control circuit receives measurement results from the integrated circuits via the transmission path.

Abstract: Electrochemical energy storage devices having a metal anode and a solid-state, metal-ion exchange membrane and are characterized by an interfacial layer between the anode and the membrane, wherein the interfacial layer is a solid solution comprising the metal anode and a metallic interfacial conducting agent.

Abstract: The invention relates to a unique battery having an active, porous membrane and method of making the same. More specifically the invention relates to a sealed battery system having a porous, metal oxide membrane with uniform, physicochemically functionalized ion channels capable of adjustable ionic interaction. The physicochemically-active porous membrane purports dual functions: an electronic insulator (separator) and a unidirectional ion-transporter (electrolyte). The electrochemical cell membrane is activated for the transport of ions by contiguous ion coordination sites on the interior two-dimensional surfaces of the trans-membrane unidirectional pores. The membrane material is designed to have physicochemical interaction with ions. Control of the extent of the interactions between the ions and the interior pore walls of the membrane and other materials, chemicals, or structures contained within the pores provides adjustability of the ionic conductivity of the membrane.

Abstract: A solid lithium ion secondary battery with high safety and high capacity, and an electrode for the solid lithium ion secondary battery. At least one of positive and negative electrodes of the solid lithium ion secondary battery includes a lithium salt of a cyclic imide compound.

Abstract: A negative active material for a rechargeable lithium battery and a rechargeable lithium battery including the same, the negative active material including a metal-based active material; and a solid electrolyte having an ion conductivity of about 1.0×10?4 S/cm or greater.

Abstract: The invention relates to a cathode (A) for lithium ion accumulators, comprising (a1) at least one current collector, (a2) at least one layer comprising at least one cathode-active material which stores/releases lithium ions, at least part of layer (a2) having been compacted and/or the side of layer (a2) facing the anode having at least one layer (a3) which comprises at least one solid electrolyte which conducts lithium ions, said solid electrolyte being selected from the group consisting of inorganic solid electrolytes and mixtures thereof and being insoluble in the electrolyte system (B) used in the lithium ion accumulator, to lithium ion accumulators comprising the cathode (A) and to a process for producing the cathode (A).

Abstract: An inorganic solid electrolyte glass phase composite is provided comprising a substance of the general formula La2/3-xLi3xTiO3 wherein x ranges from about 0.04 to about 0.17, and a glass material. The glass material is one or more compounds selected from Li2O, Li2S, Li2SO4, Li3PO4, B2O3, P2O5, P2O3, Al2O3, SiO2, CaO, MgO, BaO, TiO2, GeO2, SiS2, Sb2O3, SnS, TaS2, P2S5, B2S3, and a combination of two or more thereof. A lithium-ion conducting solid electrolyte composite is disclosed comprising a lithium-ion conductive substance of the general formula La2/3-xLi3xTiO3—Z wherein x ranges form about 0.04 to 0.17, and wherein “Z” is the glass material identified above. A battery is disclosed having at least one cathode and anode and an inorganic solid electrolyte glass phase composite as described above disposed on or between at least one of the cathode and the anode.

Abstract: Hybrid solid-liquid electrolyte lithium-ion battery devices are disclosed. Certain devices comprise anodes and cathodes conformally coated with an electron insulating and lithium ion conductive solid electrolyte layer.

Abstract: An all solid state battery having high output performance and a manufacturing method thereof are provided. The all solid state battery of the present invention comprises a negative electrode layer, a positive electrode layer, and a solid electrolyte layer having a lithium ion conductivity. At least one layer of the solid electrolyte, the positive electrode layer, and the negative electrode layer includes a lithium ion conductive crystal and AxByOz (A is one or more selected from the group consisting of Al, Ti, Li, Ge, and Si. B is one or more selected from the group consisting of P, N, and C, wherein 1?X?4, 1?Y?5, and 1?Z?7). The solid electrolyte material to which a preferable sintering additive is added in a predetermined ratio is densified by firing at relatively low temperature in the manufacturing process. The ion conductivity thereof is also high.

Abstract: The invention relates to a cathodic sputtering target composition comprising at least a solid lithium-based electrolyte and an inorganic carbon free polymer, and to a method for the manufacturing of cathodic solid sputtering targets using such a composition. The invention also relates to solid sputtering targets obtained by such a method and to their use for the preparation of solid thin films by a sputtering physical vapour deposition process, in particular for the preparation of solid electrolyte thin films inside thin film batteries.

Abstract: An energy storage device is provided. The energy storage device includes a cathode material and a separator in electrical communication with the cathode material. The cathode material includes zinc. The separator has a first surface that defines at least a portion of a first chamber, and a second surface that defines a second chamber. The first chamber is in ionic communication with the second chamber through the separator. The separator includes an alkali-metal-ion conducting material and a toughening material. A method for operating the energy storage device is also provided. Furthermore, an energy storage system including the energy storage device is provided.

Abstract: An all-solid secondary battery having excellent output characteristics and cycle characteristics, and a positive electrode used therefor includes a positive electrode active material which includes LiMeO2. The Me includes at least one metal element. A variation rate of the lattice constant a and a variation rate of the lattice constant c between LiMeO2 before the deintercalation of Li and Li1-xMeO2 (0<X<0.8) after the deintercalation of Li are 1% or less, respectively.

Abstract: A lithium metal thin-film battery composite structure is provided that includes a combination of a thin, stable, solid electrolyte layer [18] such as Lipon, designed in use to be in contact with a lithium metal anode layer; and a rapid-deposit solid electrolyte layer [16] such as LiAlF4 in contact with the thin, stable, solid electrolyte layer [18]. Batteries made up of or containing these structures are more efficient to produce than other lithium metal batteries that use only a single solid electrolyte. They are also more resistant to stress and strain than batteries made using layers of only the stable, solid electrolyte materials. Furthermore, lithium anode batteries as disclosed herein are useful as rechargeable batteries.

Abstract: Provided herein is an electrochemical cell for a secondary battery, which includes a positive electrode having an active intercalation cathode material of treated bentonite; a negative electrode material having an active anode material containing one of magnesium and sodium; an electrolyte positioned in contact with at least one of the positive electrode and the negative electrode; wherein, when the active anode material contains magnesium, the electrolyte is a solid gel polymeric electrolyte; and wherein, when the active anode material is sodium, the electrolyte is a salt electrolyte, both the anode material and the electrolyte are molten at the operating temperature of the battery, and the cell further comprises a beta alumina solid electrolyte separator between the negative electrode and the electrolyte.

Abstract: The present invention is a method for balancing voltages of a serially connected plurality of cells in a battery pack provided with the plurality of cells. In this method, the voltages are balanced by: connecting a pair of a resistor and a switch, which are serially connected with each other, in a parallel relationship to one of the plurality of cells; switching the switch from an open state to a closed state when a voltage of the one cell increases to a prescribed balance operation starting voltage; and maintaining a state where the cell is charged by a voltage of the same magnitude as a voltage that is applied to both ends of the pair after switching of the switch to the closed state.

Abstract: A nonaqueous electrolyte composition includes an electrolyte salt, a nonaqueous solvent, a matrix polymer, and a ceramic powder, wherein the ceramic powder has an average particle size of 0.1 to 2.5 ?m and a BET specific surface area of 0.5 to 11 m2/g.

Abstract: High electrical energy density storage devices are disclosed. The devices include electrochemical capacitors, electrolytic capacitors, hybrid electrochemical-electrolytic capacitors, secondary batteries and batcaps. Advantageously, the energy storage devices may employ core-shell protonated perovskite submicron or nano particles in composite films that have one or more shell coatings on a protonated perovskite core particle, proton bearing and proton conductive. The shells may be formed of proton barrier materials as well as of electrochemically active materials in various configurations.

Abstract: The silicon as an anode material for use in lithium ion batteries according to the present invention provides a method for cell manufacturing. The degree to which the silicon is lithiated during cycling can be controlled, thereby lowering the volume expansion while maintaining an acceptable volumetric capacity, and reducing the failure rate of the silicon containing anodes in lithium ion batteries. The crystalline silicon anode is first charged so that the anode becomes partially lithiated. The voltage of the anode during this charging step is typically less than the lithiation potential of crystalline silicon at ambient temperatures, for example, less than 170 mV versus lithium metal. The total number of charge-discharge cycles during conditioning is at least two or more.

Abstract: A solid composite electrolyte membrane for use in a lithium battery is provided which exhibits a conductivity ranging from about 10?4 S cm?1 to about 10?3 S cm?1 at ambient temperature. The membrane is formed by providing a glass or glass-ceramic powder formed from a mixture of lithium carbonate, alumina, titanium dioxide, and ammonium dihydrogen phosphate. The powder is mixed with a conditioning agent and at least one solvent, followed by the addition of a binder and one or more plasticizers. The resulting slurry is cast into a tape which is then subjected to a binder burn-off and sintering process to form the membrane. The resulting membrane may be a glass-ceramic composite having a porosity ranging from 0 to 50%, or the membrane may be further infiltrated with a polymer to form a water-impermeable polymeric-ceramic composite membrane.

Abstract: Provided herein are methods for manufacturing lithium-metal anode [18] assemblies for thin-film, thick-film and hulk secondary batteries that use liquid or gel-type electrolytes [14], and lithium-metal anode [18] assemblies for thick-film and bulk secondary batteries that use solid electrolytes [18]. These methods involve electrolytic formation of a lithium metal anode [18] between a protecting lithium-stable, solid electrolyte [18] material and an eieethcaiiy-Gonductive substance [20]. Secondary lithium_ batteries made by these methods aw also provided.

Abstract: The present invention generally relates to metal oxide fibers and nanofibers, the processes for making same, and uses thereof. Such metal oxide nanofibers possess the ability to absorb and decompose chemical warfare agents and other toxic chemicals. These nanofibers can be incorporated into protective clothing and devices for breathing or in another example may be used in lithium-ion batteries. In one embodiment, the present invention relates to titania, alumina, and/or magnesia fibers and nanofibers, and to processes for making same. In another instance, alpha-phase aluminum oxide is utilized as one material in nanofibers.

Abstract: Liquid-free lithium-air cells are provided which incorporate a solid electrolyte having enhanced ionic transport and catalytic activity. The solid electrolyte is positioned between a lithium anode and an oxygen cathode, and comprises a glass-ceramic and/or a polymer-ceramic electrolyte including a dielectric additive.

Abstract: A solid state battery comprising: a solid electrolyte; a positive electrode containing an active material; and a negative electrode containing an active material is provided. The solid electrolyte is disposed between the positive electrode and the negative electrode. At least one of the positive electrode active material and the negative electrode active material contains a metal oxide.

Abstract: [Problem] A non-aqueous electrolyte battery is provided that shows good cycle performance and good storage performance under high temperature conditions and exhibits high reliability even with a battery configuration featuring high capacity. A method of manufacturing the battery is also provided.

Abstract: A sulfide-based lithium-ion-conducting solid electrolyte glass is formed from sulfide-based lithium-ion-conducting solid electrolyte, and ?-alumina.

Abstract: A solid electrolyte material of conducting a lithium ion comprises a sulfide-based lithium-ion conductor and ?-alumina. Such a solid electrolyte material exhibits superior lithium-ion conductivity. Further, a battery device provided with such a solid electrolyte material is also provided. Furthermore, an all-solid lithium-ion secondary battery provided with such a battery device is also provided.

Abstract: A lithium ion secondary battery including: a positive electrode including a lithium composite oxide; a negative electrode capable of charging and discharging lithium ion; a non-aqueous liquid electrolyte; and a solid electrolyte layer interposed between the positive electrode and the negative electrode, wherein the solid electrolyte layer includes solid electrolyte particles and a binder. The solid electrolyte layer may include an inorganic oxide filler. The solid electrolyte particles is, for example, at least one selected from the group consisting of LiCl—Li2O—P2O5, LiTi2(PO4)3—AlPO4, LiI—Li2S—SiS4, LiI—Li2S—B2S3, LiI—Li2S—P2O5 and Li3N.

Abstract: An all-solid-state lithium-ion secondary battery has an anode, a cathode, a solid electrolyte layer disposed between the anode and the cathode, and at least one of a first mixed region formed at an interface between the anode and the solid electrolyte layer and containing a constituent material of the anode and a constituent material of the solid electrolyte layer, and a second mixed region formed at an interface between the cathode and the solid electrolyte layer and containing a constituent material of the cathode and a constituent material of the solid electrolyte layer.

Abstract: A lithium ion conductive solid electrolyte formed by sintering a molding product containing an inorganic powder and having a porosity of 10 vol % or less, which is obtained by preparing a molding product comprising an inorganic powder as a main ingredient and sintering the molding product after pressing and/or sintering the same while pressing, the lithium ion conductive solid electrolyte providing a solid electrolyte having high battery capacity without using a liquid electrolyte, usable stably for a long time and simple and convenient in manufacture and handling also in industrial manufacture in the application use of secondary lithium ion battery or primary lithium battery, a solid electrolyte having good charge/discharge cyclic characteristic in the application use of the secondary lithium ion battery a solid electrolyte with less water permeation and being safe when used for lithium metal-air battery in the application use of primary lithium battery, a manufacturing method of the solid electrolyte, and a

Abstract: Provided are a composite polymer electrolyte for a lithium secondary battery that includes a composite polymer matrix structure having a single ion conductor-containing polymer matrix to enhance ionic conductivity and a method of manufacturing the same. The composite polymer electrolyte includes a first polymer matrix made of a first porous polymer with a first pore size; a second polymer matrix made of a single ion conductor, an inorganic material, and a second porous polymer with a second pore size smaller than the first pore size. The second polymer matrix is coated on a surface of the first polymer matrix. The composite polymer matrix structure can increase mechanical properties. The single ion conductor-containing porous polymer matrix of a submicro-scale can enhance ionic conductivity and the charge/discharge cycle stability.

Abstract: There are provided glass-ceramics having a high lithium ion conductivity which include in mol %: P2O5 38–40% TiO2 25–45% M2O3 (where M is Al or Ga) ?5–15% Li2O 10–20% and contain Li1+X(Al, Ga)XTi2?X(PO4)3 (where 0<X<0.8) as a main crystal phases. There are also provided glass-ceramics having a high lithium ion conductivity which include in mol %: P2O5 ?26–40% SiO2 0.5–12% TiO2 ?30–45% M2O3 (where M is Al or Ga) ??5–10% Li2O ?10–18% and contain Li1+X+YMXTi2?XSiYP3?YO12 (where 0<X?0.4 and 0<Y?0.6) as a main crystal phase. There are also provided solid electrolytes for an electric cell and a gas sensor using alkali ion conductive glass-ceramics, and a solid electric cell and a gas sensor using alkali ion conductive glass-ceramics as a solid electrolyte.

Abstract: A battery pack of a series combination of cell units is connected with a motor drive control circuit to drive a traction motor for a vehicle. A current sensor senses a discharge/charge current of the battery pack, and a voltage detecting circuit senses a voltage between two separate points in the series combination of the battery pack. A memory section stores a reference voltage drop quantity representing a decrease in voltage during a predetermined time interval between the two separate points. An offset detecting section compares an actual voltage drop quantity sensed by the voltage detecting circuit, with the reference voltage drop quantity, thereby detects a non-discharge/charge-current state of the current sensor, and reserves an output of the current sensor, as an offset quantity upon the detection. A correcting section corrects a sensed value of the discharge/charge current with the reserved offset quantity.

Abstract: A polymer electrolyte includes a substrate polymer, a branched polymer, and a lithium salt. The branched polymer has a main chain whose repeating unit is composed of an oligoethylene oxide chain and a connector molecule bonded to the oligoethylene oxide chain. The branched polymer can be a hyperbranched polymer. The polymer electrolyte can further include a composite oxide and/or a boroxine compound. The polymer electrolyte is good in terms of the ionic conductivity, and exhibits a high ionic conductivity especially at low temperatures. When the polymer electrolyte is used to make polymer lithium batteries, the resulting polymer lithium batteries shows improved charge-discharge cycle characteristics. In particular, it is possible to operate the polymer lithium batteries at low temperatures.

Abstract: Disclosed are compositions and methods for alleviating the problem of reaction of lithium or other alkali or alkaline earth metals with incompatible processing and operating environments by creating a ionically conductive chemical protective layer on the lithium or other reactive metal surface. Such a chemically produced surface layer can protect lithium metal from reacting with oxygen, nitrogen or moisture in ambient atmosphere thereby allowing the lithium material to be handled outside of a controlled atmosphere, such as a dry room. Production processes involving lithium are thereby very considerably simplified. One example of such a process in the processing of lithium to form negative electrodes for lithium metal batteries.

Abstract: Conventional batteries are disadvantageous in that a firm outer case must be used to maintain an electrical connection between electrodes, which has been an obstacle to size reduction. Those in which each electrode and a separator are joined with an adhesive resin suffer from conflict between adhesive strength and battery characteristics, particularly ion conductivity and internal resistivity. To solve these problems, it is an object of the invention to reduce resistance between electrodes, i.e., internal resistance of a battery to improve battery characteristics while securing both insulation function against electron conduction and ion conductivity between electrodes and also to maintain adhesive strength enough to firmly join the electrodes thereby to provide a light, compact and thin battery. The internal resistivity can be diminished by joining a positive electrode and a negative electrode with an adhesive resin layer having at least one adhesive resin layer containing a filler.

Abstract: Disclosed are ionically conductive membranes for protection of active metal anodes and methods for their fabrication. The membranes may be incorporated in active metal negative electrode (anode) structures and battery cells. In accordance with the invention, the membrane has the desired properties of high overall ionic conductivity and chemical stability towards the anode, the cathode and ambient conditions encountered in battery manufacturing. The membrane is capable of protecting an active metal anode from deleterious reaction with other battery components or ambient conditions while providing a high level of ionic conductivity to facilitate manufacture and/or enhance performance of a battery cell in which the membrane is incorporated.

Abstract: Disclosed are ionically conductive composites for protection of active metal anodes and methods for their fabrication. The composites may be incorporated in active metal negative electrode (anode) structures and battery cells. In accordance with the invention, the properties of different ionic conductors are combined in a composite material that has the desired properties of high overall ionic conductivity and chemical stability towards the anode, the cathode and ambient conditions encountered in battery manufacturing. The composite is capable of protecting an active metal anode from deleterious reaction with other battery components or ambient conditions while providing a high level of ionic conductivity to facilitate manufacture and/or enhance performance of a battery cell in which the composite is incorporated.