Lithium And Halogen Containing Compound Patents (Class 429/323)
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Patent number: 8318361Abstract: Disclosed is a composition for a gel polymer electrolyte, the composition comprising: (i) a cyclic compound as a first crosslinking agent, the cyclic compound containing a cyclic group at the center thereof and having at least three double bonds at the end thereof; (ii) a linear or branched compound as a second crosslinking agent, the linear or branched compound containing an oxyalkylene group at the center thereof and having at least two (meth)acryl groups at the end thereof; (iii) an electrolyte solvent; (iv) an electrolyte salt; and (v) a polymerization initiator. Also, disclosed are a gel polymer electrolyte formed by polymerizing the composition for a gel polymer electrolyte, and an electrochemical device comprising the gel polymer electrolyte.Type: GrantFiled: September 7, 2007Date of Patent: November 27, 2012Assignee: LG Chem, Ltd.Inventors: Sung-Hoon Yu, Jeong-Ju Cho, Soo-Jin Kim, Soo-Hyun Ha
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Publication number: 20120251871Abstract: An all-solid-state battery includes: a positive electrode having a positive electrode current collector and a positive electrode layer on the positive electrode current collector; a negative electrode having a negative electrode current collector and a negative electrode layer on the negative electrode current collector; and an electrolyte between the positive and negative electrodes. The electrolyte is made of a first solid-state electrolyte having lithium ionic conductivity. The positive electrode layer includes a base portion and an active material portion. The base portion is made of a second solid-state electrolyte having lithium ionic conductivity in a continuous phase. The active material portion is dispersed in the base portion, and includes a positive electrode active material. The first and second solid-state electrolytes are lithium ionic conductive material having a hydride solid-state electrolyte, respectively.Type: ApplicationFiled: March 28, 2012Publication date: October 4, 2012Applicants: Tohoku University, DENSO CORPORATIONInventors: Gen Suzuki, Kenichirou Kami, Hitoshi Takamura, Shinichi Orimo, Hideki Maekawa, Tamako Maekawa
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Publication number: 20120244444Abstract: The present invention generally relates to batteries or other electrochemical devices, and systems and materials for use in these, including novel electrode materials and designs. In some embodiments, the present invention relates to small-scale batteries or microbatteries. For example, in one aspect of the invention, a battery may have a volume of no more than about 5 mm3, while having an energy density of at least about 400 W h/l. In some cases, the battery may include an electrode comprising a porous electroactive compound. In some embodiments, the pores of the porous electrode may be at least partially filled with a liquid such as a liquid electrolyte. The electrode may be formed from a unitary material. Other aspects of the invention are directed to techniques of making such electrodes or batteries, techniques of forming electrical connections to and packaging such batteries, techniques of using such electrodes or batteries, or the like.Type: ApplicationFiled: February 29, 2012Publication date: September 27, 2012Applicant: Massachusetts Institute of TechnologyInventors: Yet-Ming Chiang, Ryan C. Wartena, Timothy E. Chin, Can K. Erdonmez, Wei Lai
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Patent number: 8247112Abstract: An object of the present invention is to provide an electrolyte solution for lithium-ion secondary batteries comprising a tetraalkylphosphonium salt which improves the cycle characteristics and safety of lithium-ion batteries, and to provide a lithium-ion secondary battery using the electrolyte solution. Disclosed is an electrolyte comprising a tetraalkylphosphonium salt represented by general formula (1) wherein R1 represents a linear, branched or alicyclic alkyl group having 2 to 6 carbon atoms and R2 represents a linear, branched or alicyclic alkyl group having 1 to 14 carbon atoms, provided that R1 and R2 are different from each other and the total number of carbon atoms in the phosphonium cation is 20 or less; and X represents an anion.Type: GrantFiled: September 11, 2007Date of Patent: August 21, 2012Assignee: Nippon Chemical Industrial Co., Ltd.Inventors: Katsuhiko Tsunashima, Masahiro Kikuchi
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Patent number: 8247096Abstract: In a non-aqueous electrolyte secondary battery 1 including a positive electrode 11, a negative electrode 12, a separator 14, a positive electrode lead 15, a negative electrode lead 16, a gasket 17, and a housing case 18, the negative electrode 12 including a negative electrode active material layer 12b including an alloy-formable active material, a resin layer 13 is formed on the surface of the negative electrode active material layer 12b. The resin layer 13 includes a resin component with lithium ion conductivity and an additive for non-aqueous electrolyte. This configuration enables the battery performance to be maintained at a high level and the battery swelling to be suppressed, even when the number of charge/discharge cycles is increased, providing the non-aqueous electrolyte secondary battery 1 with a high level of safety.Type: GrantFiled: February 12, 2010Date of Patent: August 21, 2012Assignee: Panasonic CorporationInventors: Masaya Ugaji, Masahiro Kinoshita, Taisuke Yamamoto, Masaki Deguchi
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Patent number: 8216724Abstract: A polymer electrolyte capable of obtaining superior discharge characteristics and a battery using it are provided. A cathode (21) and an anode (22) are wound with a separator (24) in between. After that, the wound body is contained inside a package member. Then, an electrolytic composition containing a solvent, polyvinyl acetal or the derivative thereof, and lithium hexafluorophosphate is added thereto. Polyvinyl acetal or the derivative thereof is polymerized by using lithium hexafluorophosphate as a catalyst. Thereby, a polymer electrolyte (23) is formed, and the discharge characteristics are improved.Type: GrantFiled: March 10, 2006Date of Patent: July 10, 2012Assignee: Sony CorporationInventors: Yuji Uchida, Takahiro Endo, Tomoyuki Nakamura, Takeru Yamamoto, Takehiko Suwa, Yoshiaki Naruse
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Patent number: 8211578Abstract: An improved electrolyte for a cell having an anode comprising magnesium or magnesium alloy. The cell's cathode may desirably include iron disulfide (FeS2) as cathode active material. The improved electrolyte comprises a magnesium salt, preferably magnesium perchlorate dissolved in an organic solvent which preferably includes acetonitrile or mixture of tetrahydrofuran and propylene carbonate. The electrolyte includes an additive to retard the buildup of deleterious passivation coating on the magnesium anode surface, thereby enhancing cell performance. Such additive may preferably include 1-butyl-3-methylimidazolium tetrafluoroborate (BMIMBF4), 1-butyl-3-methylimidazolium hexafluorophosphate (BMIMPF6), lithium hexafluorophosphate (LiPF6), or aluminum chloride (AlCl3).Type: GrantFiled: June 9, 2009Date of Patent: July 3, 2012Assignee: The Gillette CompanyInventors: Zhiping Jiang, Rimma Sirotina, Nikolay Iltchev
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Patent number: 8153306Abstract: Disclosed are an organic electrolyte for a lithium-ion battery and a lithium-ion battery comprising the same, wherein the electrolyte includes a base electrolyte containing a lithium salt dissolved in an organic solvent, and diphenyloctyl phosphate added thereto in an amount of 0.1 to 20 wt %. As compared to a conventional organic electrolyte using only a carbonate ester-based solvent, such as ethylene carbonate, ethyl methyl carbonate, etc., the lithium-ion battery employing the organic electrolyte can improve thermal stability of an electrolyte solution, high-rate performance, and charge/discharge cyclability of a battery, while maintaining battery performance of the base electrolyte.Type: GrantFiled: June 10, 2008Date of Patent: April 10, 2012Assignee: Sungkyunkwan University Foundation for Corporate CollaborationInventors: Jung Gu Kim, Eun Gi Shim, Tae Heum Nam
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Patent number: 8148006Abstract: A battery capable of improving cycle characteristics is provided. A separator arranged between a cathode and an anode is impregnated with an electrolytic solution. The electrolytic solution includes: a solvent; and an electrolytic salt, in which the solvent includes a compound having a difluoroalkene structure. The content of the compound having a difluoroalkene structure in the solvent is within a range from 1 wt % to 5 wt % both inclusive.Type: GrantFiled: May 20, 2008Date of Patent: April 3, 2012Assignee: Sony CorporationInventors: Masayuki Ihara, Takashi Murakami, Tadahiko Kubota
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Patent number: 8148017Abstract: An electrochemical energy storage device includes a negative electrode which contains a carbon material and has a negative electrode potential of 1.4 V or less relative to a lithium reference when being charged, and a non-aqueous electrolyte solution prepared by dissolving a lithium salt, an ammonium salt, and at least one kind of fluorinated benzene selected among hexafluorobenzene, pentafluorobenzene, 1,2,3,4-tetrafluorobenzene, 1,2,3,5-tetrafluorobenzene, 1,2,4,5-tetrafluorobenzene and 1,2,3-trifluorobenzene, in a non-aqueous solvent.Type: GrantFiled: March 1, 2007Date of Patent: April 3, 2012Assignee: Panasonic CorporationInventors: Tooru Matsui, Masaki Deguchi, Hiroshi Yoshizawa
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Publication number: 20120052397Abstract: Electrolyte materials for use in electrochemical cells, electrochemical cells comprising the same, and methods of making such materials and cells, are generally described. In some embodiments, the materials, processes, and uses described herein relate to electrochemical cells comprising sulfur and lithium such as, for example, lithium sulfur batteries. The electrolyte can comprise a polymeric material and, in some cases, an absorbed auxiliary material. For example, the electrolyte material can be capable of forming a gel, and the auxiliary material can comprise an electrolyte solvent. In some instances, the electrolyte material can comprise at least one organic (co)polymer selected from polyethersulfones, polyvinylalcohols (PVOH) and branched polyimides (HPI). The non-fluid material in the electrolyte, when configured for use, can, alone or in combination with the optional absorbed auxiliary material, have a yield strength greater than that of lithium metal, in some embodiments.Type: ApplicationFiled: August 24, 2011Publication date: March 1, 2012Applicants: BASF SE, Sion Power CorporationInventors: Yuriy V. Mikhaylik, Igor Kovalev, John D. Affinito, Helmut Moehwald, Rudiger Schmidt, Anna Cristadoro, Ingrid Haupt, Raimund Pietruschka
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Patent number: 8119291Abstract: A non-aqueous electrolyte secondary battery including: a positive electrode; a negative electrode; a separator interposed between the positive electrode and the negative electrode; a non-aqueous electrolyte; and a porous insulating film adhered to a surface of at least one selected from the group consisting of the positive electrode and the negative electrode, the porous insulating film including an inorganic oxide filler and a film binder, wherein the ratio R of actual volume to apparent volume of the separator is not less than 0.4 and not greater than 0.7, and wherein the ratio R and a porosity P of the porous insulating film satisfy the relational formula: ?0.10?R?P?0.30.Type: GrantFiled: April 29, 2008Date of Patent: February 21, 2012Assignee: Panasonic CorporationInventors: Kaoru Inoue, Kiyomi Kato, Kohei Suzuki, Shigeo Ikuta, Yusuke Fukumoto, Tetsuya Hayashi
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Publication number: 20120009483Abstract: A negative active material for a rechargeable lithium battery and a rechargeable lithium battery including the same, the negative active material including a metal-based active material; and a solid electrolyte having an ion conductivity of about 1.0×10?4 S/cm or greater.Type: ApplicationFiled: January 7, 2011Publication date: January 12, 2012Inventors: Hee-Young Chu, Sung-Hwan Moon, Jae-Hyuk Kim, Jong-Seo Choi
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Publication number: 20110318624Abstract: A cathode material includes a primary active cathode material and an amount of NiS2. Primary batteries (e.g., thermal batteries) can be provided that contain such a cathode material.Type: ApplicationFiled: June 16, 2011Publication date: December 29, 2011Applicant: EAGLEPICHER TECHNOLOGIES, LLCInventors: Geoffrey SWIFT, Charles LAMB, Jim FERRARO
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Patent number: 8075865Abstract: The invention relates to lithium argyrodite of the general formula (I): Li+(12-n-x)Bn+X2?6-xY?x (I), where Bn+ is selected from the group consisting of P, As, Ge, Ga, Sb, Si, Sn, Al, In, Ti, V, Nb, and Ta; X2? is selected from the group consisting of S, Se, and Te; Y? is selected from the group consisting of Cl, Br, I, F, CN, OCN, SCN, and N3; 0?x?2, and a method for the production thereof, and the use thereof as a lithium-ion electrolyte in primary and secondary electrochemical energy storage.Type: GrantFiled: October 7, 2008Date of Patent: December 13, 2011Assignee: Universitat SeigenInventors: Hans-Jörg Deiseroth, Shiao-Tong Kong, Marc Schlosser, Christof Reiner
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Patent number: 8076029Abstract: A primary cell having an anode comprising lithium and a cathode comprising iron disulfide (FeS2) and carbon particles. The electrolyte comprises a lithium salt dissolved in a solvent mixture which contains 1,3-dioxolane and isosorbide dimethyl ether. The solvent mixture may comprise 1,3-dioxolane, 1,2-dimethoxyethane and additive isosorbide dimethyl ether. The isosorbide dimethyl ether comprises typically between about 2 and 15 percent by weight of the solvent mixture and improves cell service life and performance. A cathode slurry is prepared comprising iron disulfide powder, carbon, binder, and a liquid solvent. The mixture is coated onto a conductive substrate and solvent evaporated leaving a dry cathode coating on the substrate. The anode and cathode can be spirally wound with separator therebetween and inserted into the cell casing with electrolyte then added.Type: GrantFiled: January 20, 2009Date of Patent: December 13, 2011Assignee: The Gillette CompanyInventors: Michael Sliger, Nikolai N. Issaev, Eric Navok, Kenneth E. Yelm
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Patent number: 8053109Abstract: A non-aqueous electrolyte secondary battery has a high initial capacity and excels in cycle characteristics and storage characteristics even when charged until the potential of the positive electrode active material exceeds as high as 4.3V versus lithium. The non-aqueous electrolyte of the secondary battery contains both 1,3-dioxane and a sulfonic acid ester compound.Type: GrantFiled: November 14, 2008Date of Patent: November 8, 2011Assignees: Sanyo Electric Co., Ltd., Ube Industries, Ltd.Inventors: Masato Iwanaga, Noriko Yamashita, Koji Abe, Kazuhiro Miyoshi
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Patent number: 8026000Abstract: A nonaqueous electrolyte secondary battery of the invention has a positive electrode having a positive electrode active material, a negative electrode, and a nonaqueous electrolyte having electrolyte salt in a nonaqueous solvent. The electric potential of the positive electrode active material is 4.4 to 4.6 V relative to lithium, and the nonaqueous electrolyte contains a compound expressed by structural formula (I) below. The quantity of compound added is preferably 0.1% to 2% by mass. Also, the positive electrode active material preferably comprises a mixture of a lithium-cobalt composite oxide which is LiCoO2 containing at least both zirconium and magnesium and a lithium-manganese-nickel composite oxide that has a layer structure and contains at least both manganese and nickel. Thanks to such structure, a nonaqueous electrolyte secondary battery can be provided that is charged to charging termination potential of 4.4 to 4.6 V relative to lithium and that has enhanced overcharging safety.Type: GrantFiled: January 23, 2007Date of Patent: September 27, 2011Assignees: Sanyo Electric Co., Ltd., UBE Industries, Ltd.Inventors: Masato Iwanaga, Yukihiro Oki, Koji Abe, Kazuhiro Miyoshi
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Patent number: 8003259Abstract: A non-aqueous electrolyte secondary battery including: a positive electrode; a negative electrode; a separator interposed between the positive electrode and the negative electrode; a non-aqueous electrolyte; and a porous insulating film adhered to a surface of at least one selected from the group consisting of the positive electrode and the negative electrode, the porous insulating film including an inorganic oxide filler and a film binder, wherein the ratio R of actual volume to apparent volume of the separator is not less than 0.4 and not greater than 0.7, and wherein the ratio R and a porosity P of the porous insulating film satisfy the relational formula: ?0.10?R?P?0.30.Type: GrantFiled: April 29, 2008Date of Patent: August 23, 2011Assignee: Panasonic CorporationInventors: Kaoru Inoue, Kiyomi Kato, Kohei Suzuki, Shigeo Ikuta, Yusuke Fukumoto, Tetsuya Hayashi
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Publication number: 20110171538Abstract: Glass-fiber composites are described that include a substrate containing glass fibers and particles in contact with the glass fiber substrate. The particles may include an alkali-metal containing compound. In addition, batteries are described with an anode, a cathode, and an electrolyte. The cathode may include alkali-metal containing nanoparticles in contact with glass fibers. Also describe are methods of making a glass-fiber composite. The methods may include the steps of forming a wet laid non-woven glass fiber substrate, and contacting alkali-metal containing particles on the substrate.Type: ApplicationFiled: December 29, 2010Publication date: July 14, 2011Inventors: Souvik Nandi, Alan Michael Jaffee, Kristin Franz Goya Obernyer, Albert G. Dietz, III
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Publication number: 20110143174Abstract: Provided is a lithium secondary battery including a positive electrode having a positive electrode active material, a negative electrode having a negative electrode active material, and a polymer electrolyte composition having a polymer electrolyte, a non-aqueous organic solvent, and a lithium salt. The content of the polymer electrolyte is 9 to 20 wt %, based on the total weight of the polymer electrolyte composition.Type: ApplicationFiled: October 22, 2010Publication date: June 16, 2011Applicant: Samsung SDI Co., Ltd.Inventors: Joong-Heon KIM, Cheol-Ho Park, Jin-Uk Lee
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Publication number: 20110117417Abstract: Exemplary flexible thin film solid state lithium ion batteries (10) and methods for making the same are disclosed. An exemplary flexible solid state thin film electrochemical device (10) may include a flexible substrate (12), first (14) and second electrodes (18), and an electrolyte (16) disposed between the first (14) and second electrodes (18). The electrolyte (16) is disposed on the flexible substrate (12). The first electrode (14) is disposed on the electrolyte (16), and the second electrode (18) having been buried between the electrolyte (16) and the substrate (12).Type: ApplicationFiled: February 25, 2008Publication date: May 19, 2011Applicant: Alliance for Sustainable Energy, LLCInventor: John Roland Pitts
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SOLID ELECTROLYTE, METHOD FOR PRODUCING THE SAME, AND SECONDARY BATTERY COMPRISING SOLID ELECTROLYTE
Publication number: 20110117440Abstract: A solid electrolyte comprising: LiBH4; and an alkali metal compound represented by the following formula (1): MX??(1) (in the formula (1), M represents an alkali metal atom, and X represents one selected from the group consisting of halogen atoms, NR2 groups (each R represents a hydrogen atom or an alkyl group) and N2R groups (R represents a hydrogen atom or an alkyl group)).Type: ApplicationFiled: May 12, 2009Publication date: May 19, 2011Applicant: TOHOKU UNIVERSITYInventors: Hideki Maekawa, Hitoshi Takamura, Shinichi Orimo, Motoaki Matsuo, Yuko Nakamori, Mariko Ando, Yasuto Noda, Taiki Karahashi -
Patent number: 7935445Abstract: A lithium ion secondary battery includes: (a) a positive electrode plate comprising an active material part and a current collector carrying the active material part, the active material part comprising a positive electrode active material capable of absorbing or desorbing a lithium ion during charge and discharge; (b) a negative electrode plate comprising an active material part and a current collector carrying the active material part, the active material part comprising a negative electrode active material capable of absorbing or desorbing a lithium ion during charge and discharge; (c) a separator interposed between the positive and negative electrode plates; (d) an electrolyte; and (e) a battery case accommodating the positive and negative electrode plates, the separator, and the electrolyte. The positive and negative electrode plates are wound with the separator interposed therebetween, thereby to form an electrode plate assembly.Type: GrantFiled: May 15, 2006Date of Patent: May 3, 2011Assignee: Panasonic CorporationInventors: Tsuyoshi Kaito, Futoshi Tanigawa, Naoto Arai
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Patent number: 7931987Abstract: A lithium-ion battery includes a positive electrode comprising a current collector and a first active material comprising LiCoO2 and a negative electrode comprising a current collector, a second active material, and a third active material. The second active material comprises a lithium titanate material and the third active material is V2O5. The third active material exhibits charging and discharging capacity below a corrosion potential of the current collector of the negative electrode and above a decomposition potential of the first active material.Type: GrantFiled: May 27, 2010Date of Patent: April 26, 2011Assignee: Medtronic, Inc.Inventors: William G. Howard, Craig L. Schmidt, Erik R. Scott
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Publication number: 20110086277Abstract: An electrochemical cell comprises as an anode, a lithium transition metal oxide or sulphide compound which has a [B2]X4n? spinel-type framework structure of an A[B2]X4 spinel wherein A and B are metal cations selected from Li, Ti, V, Mn, Fe and Co, X is oxygen or sulphur, and n? refers to the overall charge of the structural unit [B2]X4 of the framework structure. The transition metal cation in the fully discharged state has a mean oxidation state greater than +3 for Ti, +3 for V, +3.5 for Mn, +2 for Fe and +2 for Co. The cell includes as a cathode, a lithium metal oxide or sulphide compound. An electrically insulative lithium containing liquid or polymeric electronically conductive electrolyte is provided between the anode and the cathode.Type: ApplicationFiled: December 17, 2010Publication date: April 14, 2011Inventors: Michael M. Thackeray, Rosalind J. Gummow, Ernest E. Ferg
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Publication number: 20110081580Abstract: A solid-state lithium secondary battery includes an electrode body including a positive electrode containing positive electrode active material particles and solid electrolyte particles, a negative electrode, and a solid electrolyte layer composed of solid electrolyte particles and disposed between the positive electrode and the negative electrode. In the solid-state lithium secondary battery, the solid electrolyte particles contained in the positive electrode and the solid electrolyte particles of the solid electrolyte layer are each composed of a lithium ion conductive material represented by chemical formula Li+(12?n?x)Bn+X2?(6?x)Y?x (Bn+ is at least one selected from P, As, Ge, Ga, Sb, Si, Sn, Al, In, Ti, V, Nb, and Ta; X2? is at least one selected from S, Se, and Te; Y? is at least one selected from F, Cl, Br, I, CN, OCN, SCN, and N3; and 0?x?2) and having an argyrodite-type crystal structure, and the positive electrode and the solid electrolyte layer are obtained by firing, at 100 to 400° C.Type: ApplicationFiled: September 30, 2010Publication date: April 7, 2011Applicant: SANYO ELECTRIC CO., LTD.Inventors: Florian Stadler, Christopher Fietzek
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Patent number: 7910015Abstract: A polymer electrolyte for dye sensitized solar cell is provided. The electrolyte contains a porous hybrid polymer (the components were listed in formula (1) and formula (2)) and the electrolyte solution (the components were shown in formula (3)). The weight ratio of PEOPPO to PVDF-HFP is from 1˜80% The weight ratio of EO to PO in PEOPPO is from 30 to 80% EC/PC/LiI/I2/TBP??Formula (3) EC is ethylene carbonate PC is propylene carbonate TBP is 4-tert-butylpyridine The weight ratio of EC to PC is 0.1˜5; the ratio of EC to LiI is 0.1˜2; the ratio of EC to I2 is 0.01˜0.2; the ratio of EC to TBP is 0.1˜1; wherein the range of n and m for PEOPPO is n=20˜150, and m=10˜80.Type: GrantFiled: October 22, 2007Date of Patent: March 22, 2011Assignee: Institute of Nuclear Energy ResearchInventors: Chun-Guey Wu, Ming-Yi Lu, Chwei-Huann Chiou, Yun-Fang Lu
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Patent number: 7883800Abstract: The disclosure herein relates to a lithium ion conducting electrolyte. This electrolytic material has improved ionic conductivity. The material disclosed herein is an amorphous compound of the formula LixSMwOyNz wherein x is between approximately 0.5 and 3, y is between 1 and 6, z is between 0.1 and 1, w is less than 0.3 and M is an element selected from B, Ge, Si, P, As, Cl, Br, I, and combinations thereof. The material can be prepared in the form of a thin film. The electrolyte material can be used in microbatteries and electronic systems.Type: GrantFiled: January 26, 2006Date of Patent: February 8, 2011Assignee: Centre National de la Recherche ScientifiqueInventors: Philippe Vinatier, Alain Levasseur, Brigitte Pecquenard, Kyong-Hee Joo
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Publication number: 20110027662Abstract: A lithium ion secondary battery includes: a cathode that stores/releases lithium ion at a potential not lower than an oxidation-reduction equilibrium potential between halogen ion and halogen; an anode that stores/releases lithium ion, preferably containing carbon; and a non-aqueous electrolytic solution composed of a non-aqueous solvent having dissolved therein an electrolyte. The non-aqueous electrolytic solution contains lithium halide or a halogen molecule. Instead of the non-aqueous electrolytic solution, a polymer solid electrolyte containing lithium halide or halogen molecule may be used.Type: ApplicationFiled: July 30, 2010Publication date: February 3, 2011Inventors: Etsuko NISHIMURA, Katsunori Nishimura, Akihide Tanaka
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Publication number: 20100261067Abstract: Solid state, thin film, electrochemical devices (10) and methods of making the same are disclosed. An exemplary device 10 includes at least one electrode (14) and an electrolyte (16) deposited on the electrode (14). The electrolyte (16) includes at least two homogenous layers of discrete physical properties. The two homogenous layers comprise a first dense layer (15) and a second porous layer (16).Type: ApplicationFiled: February 25, 2008Publication date: October 14, 2010Inventors: J. Roland Pitts, Se-Hee Lee, C. Edwin Tracy, Wenming Li
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Publication number: 20100255383Abstract: A flexible polymer solid electrolyte material useful in battery technology is described. The flexible solid electrolyte comprises a first block that has the ability to solvate alkali metal salts. The flexible solid electrolyte comprises a second block that has the ability to incorporate lithium ions within microphase separated spherical domains, wherein the lithium ions are from a secondary lithium source. The flexible solid electrolyte further comprises a second lithium salt.Type: ApplicationFiled: March 1, 2010Publication date: October 7, 2010Applicant: University of Maryland, College ParkInventors: Peter Kofinas, Ayan Ghosh
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Publication number: 20100136436Abstract: The disclosure herein relates to a lithium ion conducting electrolyte. This electrolytic material has improved ionic conductivity. The material disclosed herein is an amorphous compound of the formula LixSMwOyNz wherein x is between approximately 0.5 and 3, y is between 1 and 6, z is between 0.1 and 1, w is less than 0.3 and M is an element selected from B, Ge, Si, P, As, Cl, Br, I, and combinations thereof. The material can be prepared in the form of a thin film. The electrolyte material can be used in microbatteries and elctronic systems.Type: ApplicationFiled: January 26, 2006Publication date: June 3, 2010Applicant: Centre National de la Recherche ScientifiqueInventors: Philippe Vinatier, Alain Levasseur, Brigitte Pecquenard, Kyong-Hee Joo
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Patent number: 7718319Abstract: The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn2?y?zLiyMzO4 oxide with NH4HF2 at low temperatures of between about 300 and 700° C. for 2 to 8 hours and a ? of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.Type: GrantFiled: September 25, 2007Date of Patent: May 18, 2010Assignee: Board of Regents, The University of Texas SystemInventors: Arumugam Manthiram, Wonchang Choi
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Publication number: 20090202918Abstract: A polymer electrolyte capable of obtaining superior discharge characteristics and a battery using it are provided. A cathode (21) and an anode (22) are wound with a separator (24) in between. After that, the wound body is contained inside a package member. Then, an electrolytic composition containing a solvent, polyvinyl acetal or the derivative thereof, and lithium hexafluorophosphate is added thereto. Polyvinyl acetal or the derivative thereof is polymerized by using lithium hexafluorophosphate as a catalyst. Thereby, a polymer electrolyte (23) is formed, and the discharge characteristics are improved.Type: ApplicationFiled: March 10, 2006Publication date: August 13, 2009Applicant: SONY CORPORATIONInventors: Yuji Uchida, Takahiro Endo, Tomoyuki Nakamura, Takeru Yamamoto, Takehiko Suwa, Yoshiaki Naruse
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Publication number: 20090197181Abstract: [Problem] A non-aqueous electrolyte battery is provided that shows good cycle performance and good storage performance under high temperature conditions and exhibits high reliability even with a battery configuration featuring high capacity. A method of manufacturing the battery is also provided.Type: ApplicationFiled: March 16, 2007Publication date: August 6, 2009Applicant: SANYO ELECTRIC CO., LTD.Inventors: Nobuhiro Sakitani, Takeshi Ogasawara, Hiroshi Minami, Naoki Imachi, Atsushi Kaiduka, Yasunori Baba, Yoshinori Kida, Shin Fujitani
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Patent number: 7504180Abstract: There is obtained a material of a positive electrode for a secondary lithium-ion cell having high cycle durability and high safety in high-voltage and high-capacity applications, which is a particulate positive electrode active material for a secondary lithium-ion cell represented by a general formula, LiaCObAcBdOeFf (A is Al or Mg, B is a group-IV transition element, 0.90?a?1.10, 0.97?b?1.00, 0.0001?c?0.03, 0.0001?d?0.03, 1.98?e?2.02, 0?f?0.02, and 0.0001?c+d?0.03), where element A, element B and fluorine are evenly present in the vicinity of the particle surfaces.Type: GrantFiled: June 6, 2003Date of Patent: March 17, 2009Assignee: Seimi Chemical Co., Ltd.Inventors: Koji Tatsumi, Manabu Suhara, Naoshi Saito, Kazushige Horichi, Yukio Jitsugiri
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Publication number: 20090035664Abstract: The present invention generally relates to batteries or other electrochemical devices, and systems and materials for use in these, including novel electrode materials and designs. In some embodiments, the present invention relates to small-scale batteries or microbatteries. For example, in one aspect of the invention, a battery may have a volume of no more than about 5 mm3, while having an energy density of at least about 400 W h/l. In some cases, the battery may include a electrode comprising a porous electroactive compound. In some embodiments, the pores of the porous electrode may be at least partially filled with a liquid such as a liquid electrolyte. The electrode may be able to withstand repeated charging and discharging. In some cases, the electrode may have a plurality of protrusions and/or a wall (which may surround the protrusions, if present); however, in other cases, there may be no protrusions or walls. The electrode may be formed from a unitary material.Type: ApplicationFiled: May 23, 2008Publication date: February 5, 2009Applicant: Massachusetts Institute of TechnologyInventors: Yet-Ming Chiang, Ryan C. Wartena, Timothy E. Chin, Can K. Erdonmez, Wei Lai
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Patent number: 7482101Abstract: A battery is provided. The battery provides improved battery characteristics such as cycle characteristics. A battery includes a cathode; an anode; and an electrolytic solution, wherein the anode contains a carbon material, the electrolytic solution contains propylene carbonate and 4-fluoroethylene carbonate, and the content of 4-fluoroethylene carbonate is from about 0.0027 g to about 0.056 g per about 1 g of the carbon material.Type: GrantFiled: June 7, 2005Date of Patent: January 27, 2009Assignee: Sony CorporationInventors: Karin Tsuda, Gentaro Kano
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Publication number: 20080268348Abstract: An object of the invention is to provide a lithium secondary battery using a fused salt at ambient temperature where a high capacity is able to be maintained even when it is stored at a high temperature environment or even when it is subjected to charge and discharge repeatedly and also to provide an electrode for a nonaqueous electrolytic lithium secondary battery. There is disclosed a lithium secondary battery using at least a fused salt at ambient temperature having ionic conductivity in which at least one of the positive and negative electrode contains a powder which solely comprises an inorganic solid electrolyte having lithium ionic conductivity. There is also disclosed an electrode for a lithium secondary battery using, at least, a ionic liquid having ionic conductivity which contains a powder solely comprising inorganic solid electrolyte having lithium ionic conductivity.Type: ApplicationFiled: April 22, 2008Publication date: October 30, 2008Applicant: OHARA INC.Inventor: Takashi Katoh
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Patent number: 7419744Abstract: A nonaqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a nonaqueous electrolyte. The negative electrode contains an active material providing a working potential which is nobler by at least 0.5V than a lithium metal potential. Also, the nonaqueous electrolyte contains an ionic liquid and allyl phosphate represented by chemical formula given below: where R denotes hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and n denotes an integer of 1 to 3.Type: GrantFiled: July 25, 2006Date of Patent: September 2, 2008Assignee: Kabushiki Kaisha ToshibaInventors: Takashi Kishi, Hidesato Saruwatari, Takashi Kuboki
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Patent number: 7416813Abstract: A lithium secondary battery is provided with a positive electrode, a negative electrode, and a non-aqueous electrolyte prepared by dissolving a solute in a non-aqueous solvent wherein a positive electrode active material of said positive electrode is composed of lithium-manganese composite oxide having a spinel structure and lithium-transition metal composite oxide having a layer structure containing at least nickel and lithium salt having oxalato complex as anion is admixed to said non-aqueous electrolyte.Type: GrantFiled: February 25, 2005Date of Patent: August 26, 2008Assignee: Sanyo Electric Co., Ltd.Inventors: Toyoki Fujihara, Kazuhisa Takeda, Hideki Kitao, Takaaki Ikemachi, Toshiyuki Nouma, Naoya Nakanishi
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Patent number: 7335448Abstract: A lithium ion secondary battery includes: (a) a positive electrode plate comprising an active material part and a current collector carrying the active material part, the active material part comprising a positive electrode active material capable of absorbing or desorbing a lithium ion during charge and discharge; (b) a negative electrode plate comprising an active material part and a current collector carrying the active material part, the active material part comprising a negative electrode active material capable of absorbing or desorbing a lithium ion during charge and discharge; (c) a separator interposed between the positive and negative electrode plates; (d) an electrolyte; and (e) a battery case accommodating the positive and negative electrode plates, the separator, and the electrolyte. The positive and negative electrode plates are wound with the separator interposed therebetween, thereby to form an electrode plate assembly.Type: GrantFiled: May 21, 2003Date of Patent: February 26, 2008Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Tsuyoshi Kaito, Futoshi Tanigawa, Naoto Arai
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Publication number: 20070172738Abstract: The disclosure herein relates to a lithium ion conducting electrolyte. This electrolytic material has improved ionic conductivity. The material disclosed herein is an amorphous compound of the formula LixSMwOyNz wherein x is between approximately 0.5 and 3, y is between 1 and 6, z is between 0.1 and 1, w is less than 0.3 and M is an element selected from B, Ge, Si, P, As, Cl, Br, I, and combinations thereof. The material can be prepared in the form of a thin film. The electrolyte material can be used in microbatteries and elctronic systems.Type: ApplicationFiled: January 26, 2006Publication date: July 26, 2007Applicant: Centre National de la Recherche ScientifiqueInventors: Philippe Vinatier, Alain Levasseur, Brigitte Pecquenard, Kyong-Hee Joo
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Patent number: 7235331Abstract: An electrolyte with high ion conductivity, a process for producing the same and a battery using the same, and a compound for the electrolyte. The electrolyte is set between a negative electrode and a positive electrode. The electrolyte includes a first polymer compound, a second polymer compound and light metal salt. The first polymer compound has a three-dimensional network structure formed by bridging bridgeable compounds with the bridge groups, which contributes to the high mechanical intensity of the electrolyte. The second polymer compound has no bridge groups and dissolves light metal salt. Each of the first and the second polymer compounds has an ether bond. The first and the second polymer compounds form a semi-interpenetrating polymer network, and achieve higher ion conductivity than that of each polymer compound.Type: GrantFiled: September 27, 2002Date of Patent: June 26, 2007Assignee: Sony CorporationInventors: Kazuhiro Noda, Takeshi Horie, Koji Sekai, Shinichiro Yamada
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Patent number: 7211352Abstract: Provided are a composite polymer electrolyte for a lithium secondary battery that includes a composite polymer matrix structure having a single ion conductor-containing polymer matrix to enhance ionic conductivity and a method of manufacturing the same. The composite polymer electrolyte includes a first polymer matrix made of a first porous polymer with a first pore size; a second polymer matrix made of a single ion conductor, an inorganic material, and a second porous polymer with a second pore size smaller than the first pore size. The second polymer matrix is coated on a surface of the first polymer matrix. The composite polymer matrix structure can increase mechanical properties. The single ion conductor-containing porous polymer matrix of a submicro-scale can enhance ionic conductivity and the charge/discharge cycle stability.Type: GrantFiled: December 30, 2003Date of Patent: May 1, 2007Assignee: Electronics and Telecommunications Research InstituteInventors: Young Gi Lee, Kwang Sun Ryu, Soon Ho Chang
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Patent number: 7070706Abstract: This invention pertains to the composition and method for fabricating nano-tube composite polymer electrolyte. The composite polymer electrolyte is made by blending suitable amount of highly dispersed, nano-tube, such as titanium dioxide (TiO2), with highly amorphous polymer electrolyte, such as polyethylene oxide. The hollow nano-tube structure facilitates salt dissociation, serves temporarily storage for lithium ions, creates new conducting mechanism and improves the conductivity thereof. The subsequent thermal treatment and high electric field arrange the nano-tubes in order for increase of the dielectric constant thereof, which increased ion mobility at room temperature. The mechanical properties are also improved due to the physical cross-linking of the nano-tubes, suitable for industrial processing.Type: GrantFiled: April 7, 2004Date of Patent: July 4, 2006Assignee: National Central UniversityInventors: Po-Jen Chu, Chin-Yeh Chiang
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Patent number: 6893774Abstract: Fluoroalkylphosphate salts of Formula I, described herein, are suitable for use, alone or in mixtures with, e.g., other salts, in electrolytes, primary batteries, secondary batteries, capacitors, supercapacitors or galvanic cells.Type: GrantFiled: February 25, 2002Date of Patent: May 17, 2005Assignee: Merck Patent GmbHInventors: Michael Schmidt, Andreas Kuhner, Nikolai Ignatyev, Peter Sartori
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Patent number: 6878492Abstract: The present invention provides a solid polymer electrolyte; a polymerizable composition having low viscosity and excellent processability for obtaining the solid polymer electrolyte; and a polymerizable compound having low viscosity, and good polymerizability and stability for use in the polymerizable composition. The present invention also provides primary and secondary batteries capable of working with high capacity and current; an electric double-layer capacitor ensuring high output voltage, large takeout current, and good processability; and an electrochromic device favored with high response speed. Each thereof use the solid polymer electrolyte of the present invention and are ensured with long life, excellent safety free of liquid leakage, high reliability and production at a low cost.Type: GrantFiled: July 10, 2001Date of Patent: April 12, 2005Assignee: Showa Denko Kabushiki KaishaInventors: Masataka Takeuchi, Shuichi Naijo, Ayako Nishioka
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Patent number: RE40302Abstract: Provided are a polymeric electrolyte or a nonaqueous electrolyte that can improve a transport rate of charge carrier ions by adding a compound having boron atoms in the structure, preferably one or more selected from the group consisting of compounds represented by the following general formulas (1) to (4), and an electric device such as a cell or the like using the same. wherein R11, R12, R13, R14, R15, R16, R21, R22, R23, R24, R25, R26, R27, R28, R31, R32, R33, R34, R35, R36, R37, R38, R39, R310, R41, R42, R43, R44, R45, R46, R47, R48, R49, R410, R411 and R412 each represent a hydrogen atom, a halogen atom or a monovalent group, or represent groups bound to each other to form a ring, and Ra, Rb, Rc and Rd each represent a group having a site capable of being bound to boron atoms which are the same or different.Type: GrantFiled: August 28, 2000Date of Patent: May 6, 2008Assignee: Dai-Ichi Kogyo Seiyaku Co. Ltd.Inventors: Masahito Nishiura, Michiyuki Kono, Masayoshi Watanabe